CN1449913A - Nano particle water-proof corrugated paper board - Google Patents
Nano particle water-proof corrugated paper board Download PDFInfo
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- CN1449913A CN1449913A CN02111278A CN02111278A CN1449913A CN 1449913 A CN1449913 A CN 1449913A CN 02111278 A CN02111278 A CN 02111278A CN 02111278 A CN02111278 A CN 02111278A CN 1449913 A CN1449913 A CN 1449913A
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- calcium carbonate
- water
- nanometer grade
- grade calcium
- corrugated paper
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
- Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
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Abstract
The present invention discloses a microparticle water-proof corrugated paper board. It is formed from several layers of kraft liner board and corrugated raw papers which are respectively placed between kraft liner boards. Said kraft liner boards and corrugated raw papers are undergone the processes of soaking in oil and moisture-resisting treatment, then they are bonded together by adopting nano calcium carbonate microparticle adhesive. The composition of said adhesive includes (wt%) 2.5-3.5% of nano-grade calcium carbonate, 10-20 % of corn starch, 1.5-2.5% of modified starch, 0.2-0.6% of flake caustic, 0.2-0.4% of borax and proper quantity of water. Its preparation process includes the procedures: (1) adding water, general strach, modified starch and nano calcium carbonate in carrier; (2). adding water, flare caustic and borax in main body.
Description
Affiliated field
The present invention relates to a kind of corrugated container board, relate in particular to a kind of nanometer grade calcium carbonate particulate waterproof corrugated board and production technology thereof of utilizing nanometer grade calcium carbonate particulate technology to make.
Background technology
Current, this new and high technology of nanotechnology begins to apply, and the application in industries such as plastics, syntheticfibres, magnetic material, coating and printing and dyeing, catalyst, pottery and storage battery mainly should be arranged.Nano material has performances such as physics than traditional material excellence, chemistry, machinery, biology, and the not available performance of many traditional materials arranged, so, nano material is applied in the traditional material, be used for improving effectively the performance and the class of numerous traditional material products, make traditional product obtain updating.And nano material is applied to the fluting board manufacturing, still in the experimental investigation stage.Particularly wrapping corrugated board, application surface is more and more wider, requirement is also increasing, in packing, storage and transportation to bearing big heavy article, more to solve difficult problems such as mechanical strength, moistureproof and waterproof, and the multilayer corrugated packaging box that generally adopts at present also exists intensity low, yielding, non-moistureproof water repellant shortcoming.So, nanotechnology is applied to corrugated board, have a bright future.
Summary of the invention
The objective of the invention is at above-mentioned shortcoming, a kind of nanotechnology of utilizing is provided, nano material is applied to make nano particle water-proof corrugated paper board and the production technology thereof that corrugated case is used.
The present invention is a nano particle water-proof corrugated paper board, for achieving the above object, has mainly adopted following technical scheme.
Nano particle water-proof corrugated paper board is made up of through the kraft liner board of oil immersion water-proofing treatment and the fluting medium of being located at respectively between the kraft liner board through the oil immersion processing several layers, adopts nanometer grade calcium carbonate particulate adhesives bonding between kraft liner board and the fluting medium.
Production technology of the present invention is: open the multiple glue bond oven dry of the body paper quality inspection of singly getting the raw materials ready separation and get rid of the product that are cut into and put in storage.
The weight proportion of every percentage of nanometer grade calcium carbonate particulate adhesives of the present invention is: nanometer grade calcium carbonate 2.5~3.5; Cornstarch 10~20; Converted starch 1.5~2.5; Sheet alkali 0.2~0.6; Borax 0.2~0.4; It is an amount of to add water.
The manufacture craft of above-mentioned nanometer grade calcium carbonate particulate adhesives is: (1), discharge water in carrier+common starch+converted starch+nano-calcium carbonate.(2), in main body, discharge water+sheet alkali+borax.(3), in carrier, put into again after the reaction and send corrugated paper board production line to use after main body stirs.
The present invention has also adopted the moisture resisting agent device for reaching waterproof moisture-proof effect on manufacture craft, promptly set up moisture resisting agent equipment before each single-side machine, and paper soaks moisture resisting agent with entire paper before entering single-side machine and multiple glue and mistake reaches paper front and back moisture resisting agent.Its technological process is: the multiple glue machine of body paper damp-proof device single-side machine.
The present invention compared with prior art has following obvious advantage and good effect.(1), nanometer grade calcium carbonate particulate waterproof corrugated board is made up of through the kraft liner board of oil immersion water-proofing treatment and the fluting medium of handling through oil immersion be located at respectively between the kraft liner board several layers, employing nanometer grade calcium carbonate particulate adhesives is bonding between kraft liner board and the fluting medium.So its waterproof, anti-soak properties are strong especially.(2), nanometer grade calcium carbonate particulate adhesives is a gordian technique of the present utility model, converted starch in its proportioning plays the fast effect of doing, nanometer grade calcium carbonate is the small particulate matter of a kind of scope between 1-100nm, between molecule and atom, its role in adhesives is the adhesive ability that the filler supplementary sum increases adhesives one paper, promptly each is intermolecularly connected filling cornstarch, converted starch, makes the bonding rear surface of adhesives be closed, does not come unstuck when making paper be employed immersion.Its another kind of performance be the thin and paper of adhesives bonding after, close-coupled between paper fibre has improved the bond strength and the adhesive ability of corrugated board.(3), this new and high technology of applying nano technology makes nanometer grade calcium carbonate particulate corrugated board, improved the quality and the performance of cardboard, and the degree of finish, moisture resistance, pull resistance of paper, anti-broken, folding strength etc. all are improved significantly.The intensity that has overcome common corrugated board is low, the shortcoming of moisture-sensitive.(4), the degree of adhesion owing to nanometer grade calcium carbonate particulate adhesives is: just sticking 15~45 seconds, glued 15~20 minutes entirely, so this patent product soaks in water and do not come unstuck in 1 hour.(5), residual degree of the breaking 295Kpa of this patent product, residual vertical compression intensity 1200n/m.So anti-broken folding.The present invention is applicable to wrapper, is specially adapted to packing, storage and the transportation of big heavy article.
Description of drawings
Fig. 1 is integral structure of the present invention and partial cutaway diagrammatic sketch.
Fig. 2 is technological process of production figure of the present invention.
Fig. 3 is nanometer grade calcium carbonate adhesives technological process of production figure of the present invention.
Fig. 4 is a damp-proof device diagram of circuit of the present invention.
The specific embodiment
The present invention is described in further detail below in conjunction with embodiment.
As shown in Figure 1: nano particle water-proof corrugated paper board is made up of through the kraft liner board 1 of oil immersion water-proofing treatment and the fluting medium of being located at respectively between the kraft liner board 13 through the oil immersion processing several layers, adopts nanometer grade calcium carbonate particulate adhesives 2 bonding between kraft liner board 1 and the fluting medium 3.
As shown in Figure 2: production technology of the present invention is: open the multiple glue bond oven dry of the body paper quality inspection of singly getting the raw materials ready separation and get rid of the product that are cut into and put in storage.
As shown in Figure 3: the manufacture craft of above-mentioned nanometer grade calcium carbonate particulate adhesives is: (1), discharge water in carrier+common starch+converted starch+nano-calcium carbonate.(2), in main body, discharge water+sheet alkali+borax.(3), in carrier, put into again after the reaction and send corrugated paper board production line to use after main body stirs.
The weight proportion of every percentage of nanoparticle adhesives of the present invention is: nano-calcium carbonate 2.5~3.5; Cornstarch 10~20; Converted starch 1.5~2.5; Sheet alkali 0.2~0.6; Borax 0.2~0.4; It is an amount of to add water.
As shown in Figure 4: the present invention is for reaching waterproof moisture-proof effect, on manufacture craft, also adopted the moisture resisting agent device, promptly set up moisture resisting agent equipment before each single-side machine, paper soaks moisture resisting agent with entire paper before entering single-side machine and multiple glue and mistake reaches paper front and back moisture resisting agent.Its technological process is: the multiple glue machine of body paper damp-proof device single-side machine.
Embodiment one
Get 35 kilograms of nanometer grade calcium carbonates, 200 kilograms of cornstarch, 15 kilograms of converted starches, sheet nanometer grade calcium carbonate, cornstarch, converted starch, sheet alkali are put into the pond and are stirred, pour another existing containing in the pond of borax soln after waiting to stir again into, add water in 1000 kilograms, stir, nanometer grade calcium carbonate particulate adhesives send corrugated paper board production line.
Kraft liner board and fluting medium are carried out the moistureproof processing of immersion oil respectively earlier before entering single-side machine, entering the multiple glue of multiple glue machine after coating nanometer grade calcium carbonate particulate adhesives through the moistureproof kraft liner board of handling of immersion oil and fluting medium, nanometer grade calcium carbonate particulate waterproof corrugated board.
Embodiment two
Get 30 kilograms of nanometer grade calcium carbonates, 150 kilograms of cornstarch, 20 kilograms of converted starches, 3 kilograms in sheet alkali, 3 kilograms of boraxs and water are stand-by in right amount.In reaction tank, put into earlier an amount of water, nano-calcium carbonate, cornstarch, converted starch, sheet alkali are put into the pond and stirred, pour another existing containing in the pond of borax soln after waiting to stir again into, add water in 1000 kilograms, stir, nanometer grade calcium carbonate particulate adhesives send corrugated paper board production line.
Kraft liner board and fluting medium are being entered moistureproof processing of the respectively advanced immersion oil of single-side machine, entering the multiple glue of multiple glue machine after coating nanometer grade calcium carbonate particulate adhesives through the moistureproof kraft liner board of handling of immersion oil and fluting medium, nanometer grade calcium carbonate particulate waterproof corrugated board.
Embodiment three
Get 25 kilograms of nanometer grade calcium carbonates, 150 kilograms of cornstarch, 25 kilograms of converted starches, 2 kilograms in sheet alkali, 2.5 kilograms of boraxs and water are stand-by in right amount.In reaction tank, put into earlier an amount of water, nano-calcium carbonate, cornstarch, converted starch, sheet alkali are put into the pond and stirred, pour another existing containing in the pond of borax soln after waiting to stir again into, add water in 1000 kilograms, stir, nanometer grade calcium carbonate particulate adhesives send corrugated paper board production line.
Kraft liner board and fluting medium are carried out the moistureproof processing of immersion oil respectively earlier before entering single-side machine, entering the multiple glue of multiple glue machine after coating nanometer grade calcium carbonate particulate adhesives through the moistureproof kraft liner board of handling of immersion oil and fluting medium, nanometer grade calcium carbonate particulate waterproof corrugated board.
The present invention is applicable to packing board, is specially adapted to packing, storage and the transportation of big heavy article.
Claims (4)
1, a kind of nano particle water-proof corrugated paper board, forming through the kraft liner board (1) of the moistureproof processing of immersion oil and the fluting medium of being located at respectively between the kraft liner board (1) (3) that protection against the tide is handled through immersion oil by several layers, it is characterized in that scribbling one deck nanometer grade calcium carbonate particulate adhesives (2) between kraft liner board (1) and the fluting medium (3).
2, nano particle water-proof corrugated paper board according to claim 1 is characterized in that every percent by weight proportioning of described nanometer grade calcium carbonate particulate adhesives (2) is: nanometer grade calcium carbonate 2.5~3.5; Cornstarch 10~20; Converted starch 1.5~2.5; Sheet alkali 0.2~0.6; Borax 0.2~0.4; It is an amount of to add water.
3, nano particle water-proof corrugated paper board according to claim 1 and 2, its feature in the manufacture craft of nanometer grade calcium carbonate particulate adhesives (2) is: discharge water in carrier+common starch+converted starch+nanometer grade calcium carbonate; In main body, discharge water+sheet alkali+borax; Discharging water after the reaction in carrier send corrugated paper board production line to use again after main body stirs.
4, nano particle water-proof corrugated paper board according to claim 1, it is characterized in that kraft liner board (1) and fluting medium (3) at first carried out the immersion oil water-proofing treatment before compound, its technological process is: the multiple glue machine finished product of body paper damp-proof device single-side machine.
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CN02111278A CN1449913A (en) | 2002-04-05 | 2002-04-05 | Nano particle water-proof corrugated paper board |
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CN02111278A CN1449913A (en) | 2002-04-05 | 2002-04-05 | Nano particle water-proof corrugated paper board |
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Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
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CN100586340C (en) * | 2008-06-20 | 2010-02-03 | 深圳市美盈森环保科技股份有限公司 | Green cabinet production method |
CN102040925A (en) * | 2010-12-06 | 2011-05-04 | 张海宽 | Adhesive for paper products and production method thereof |
CN102277796A (en) * | 2011-07-28 | 2011-12-14 | 广东理文造纸有限公司 | Corrugated paper and preparation method thereof |
CN103189460A (en) * | 2010-09-10 | 2013-07-03 | 汉高公司 | Improved adhesive having insulative properties |
WO2013154414A1 (en) | 2012-04-13 | 2013-10-17 | Sigma Alimentos, S. A. De C. V. | Hydrophobic paper or cardboard with self-assembled nanoparticles and method for the production thereof |
CN105647425A (en) * | 2016-01-20 | 2016-06-08 | 南昌大学 | Preparation method of flame-retardant waterproof high-gram-weight paper board |
CN106494764A (en) * | 2016-06-30 | 2017-03-15 | 天津宏达鑫盛科技有限公司 | A kind of moistureproof carton |
CN108237732A (en) * | 2016-12-27 | 2018-07-03 | 江苏广博罗纳斯科技有限公司 | A kind of production technology of corrugated board |
CN109016693A (en) * | 2018-09-20 | 2018-12-18 | 枣阳宏飞纸箱包装厂 | A kind of water proof type corrugated board production technique and its application in corrugated case |
CN110088220A (en) * | 2016-11-01 | 2019-08-02 | 斯道拉恩索公司 | Corrugated board comprising the adhesive containing starch and thin microfibrillated cellulose |
US10815397B2 (en) | 2012-09-27 | 2020-10-27 | Henkel IP & Holding GmbH | Waterborne adhesives for reduced basis weight multilayer substrates and use thereof |
US11773297B2 (en) | 2017-07-18 | 2023-10-03 | Henkel Ag & Co., Kgaa | Dielectric heating of foamable compositions |
US11833788B2 (en) | 2018-02-16 | 2023-12-05 | Henkel Ag & Co, Kgaa | Method for producing a multi-layer substrate |
US11926134B2 (en) | 2017-08-25 | 2024-03-12 | Henkel Ag & Co. Kgaa | Process for forming improved protective eco-friendly pouch and packaging and products made therefrom |
-
2002
- 2002-04-05 CN CN02111278A patent/CN1449913A/en active Pending
Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100586340C (en) * | 2008-06-20 | 2010-02-03 | 深圳市美盈森环保科技股份有限公司 | Green cabinet production method |
US11427963B2 (en) | 2010-09-10 | 2022-08-30 | Henkel Ag & Co, Kgaa | Adhesive having insulative properties |
CN103189460A (en) * | 2010-09-10 | 2013-07-03 | 汉高公司 | Improved adhesive having insulative properties |
CN103189460B (en) * | 2010-09-10 | 2014-10-29 | 汉高公司 | Improved adhesive having insulative properties |
US11649589B2 (en) | 2010-09-10 | 2023-05-16 | Henkel Ag & Co., Kgaa | Adhesive having insulative properties |
CN102040925A (en) * | 2010-12-06 | 2011-05-04 | 张海宽 | Adhesive for paper products and production method thereof |
CN102040925B (en) * | 2010-12-06 | 2012-11-14 | 张海宽 | Adhesive for paper products and production method thereof |
CN102277796A (en) * | 2011-07-28 | 2011-12-14 | 广东理文造纸有限公司 | Corrugated paper and preparation method thereof |
WO2013154414A1 (en) | 2012-04-13 | 2013-10-17 | Sigma Alimentos, S. A. De C. V. | Hydrophobic paper or cardboard with self-assembled nanoparticles and method for the production thereof |
US11459490B2 (en) | 2012-09-27 | 2022-10-04 | Henkel Ag & Co, Kgaa | Waterborne adhesives for reduced basis weight multilayer substrates and use thereof |
US10815397B2 (en) | 2012-09-27 | 2020-10-27 | Henkel IP & Holding GmbH | Waterborne adhesives for reduced basis weight multilayer substrates and use thereof |
US11970634B2 (en) | 2012-09-27 | 2024-04-30 | Henkel Ag & Co. Kgaa | Waterborne adhesives for reduced basis weight multilayer substrates and use thereof |
US11193048B2 (en) | 2012-09-27 | 2021-12-07 | Henkel IP & Holding GmbH | Waterborne adhesives for reduced basis weight multilayer substrates and use thereof |
CN105647425A (en) * | 2016-01-20 | 2016-06-08 | 南昌大学 | Preparation method of flame-retardant waterproof high-gram-weight paper board |
CN105647425B (en) * | 2016-01-20 | 2017-12-15 | 南昌大学 | A kind of preparation method of the high grammes per square metre cardboard of fire-resistant waterproof |
CN106494764A (en) * | 2016-06-30 | 2017-03-15 | 天津宏达鑫盛科技有限公司 | A kind of moistureproof carton |
CN110088220B (en) * | 2016-11-01 | 2020-10-16 | 斯道拉恩索公司 | Corrugated board comprising a binder containing starch and finely fibrillated cellulose |
US10787770B2 (en) | 2016-11-01 | 2020-09-29 | Stora Enso Oyj | Corrugated board comprising an adhesive comprising starch and fine micofibrillated cellulose |
CN110088220A (en) * | 2016-11-01 | 2019-08-02 | 斯道拉恩索公司 | Corrugated board comprising the adhesive containing starch and thin microfibrillated cellulose |
CN108237732A (en) * | 2016-12-27 | 2018-07-03 | 江苏广博罗纳斯科技有限公司 | A kind of production technology of corrugated board |
US11773297B2 (en) | 2017-07-18 | 2023-10-03 | Henkel Ag & Co., Kgaa | Dielectric heating of foamable compositions |
US11926134B2 (en) | 2017-08-25 | 2024-03-12 | Henkel Ag & Co. Kgaa | Process for forming improved protective eco-friendly pouch and packaging and products made therefrom |
US11833788B2 (en) | 2018-02-16 | 2023-12-05 | Henkel Ag & Co, Kgaa | Method for producing a multi-layer substrate |
CN109016693A (en) * | 2018-09-20 | 2018-12-18 | 枣阳宏飞纸箱包装厂 | A kind of water proof type corrugated board production technique and its application in corrugated case |
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