CN1439046A - Wash cycle unit dose softener - Google Patents
Wash cycle unit dose softener Download PDFInfo
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- CN1439046A CN1439046A CN 01811700 CN01811700A CN1439046A CN 1439046 A CN1439046 A CN 1439046A CN 01811700 CN01811700 CN 01811700 CN 01811700 A CN01811700 A CN 01811700A CN 1439046 A CN1439046 A CN 1439046A
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- China
- Prior art keywords
- unitary dose
- tetramethylolmethane
- compound
- fabric softener
- soft
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0086—Laundry tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/044—Solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatment Of Water By Ion Exchange (AREA)
Abstract
A unit dose wash cycle fabric softening composition for softening or conditioning fabrics in the wash cycle of an automatic washing machine, said unit dose comprising (a) a compacted granular fabric softener composition or (b) an encapsulated liquid and/or granular fabric softener composition, the amount of (a) or (b) being sufficient to form a unit dose capable of providing effective softening or conditioning of fabrics in the wash cycle of said washing machine.
Description
Invention field
The present invention relates to be used for wash cycle unit dose laundry composition softening or the conditioning fabric.More particularly, the present invention relates to the unitary dose fabric sofetening composition, they be applicable to automatic washing machine wash(ing)cycle the dense granule composition or wrap capsular liquid or particulate composition.
Background of invention
The detergent composition of producing the compact detergent powder type is well known in the prior art.For example, US5225100 has described the tablet of the dense powder that contains the anionic detergent immunomodulator compounds, and it will fully disperse in washing water.
Though the detergent composition of the dense granule tablet form of different shape has been subjected to very big attention in patent documentation, using this tablet is unknown to be provided at the washability that wash(ing)cycle, soft or conditioning fabric and not influencing was provided by this detergent composition or the unitary dose fabric softener of other harm washing effect.
The another kind of possible selection that is used for providing the unit dose softener except that wash(ing)cycle is directly to add softening compositions in rinse cycle.But, must satisfy some actual needs for making this series products effective.At first the size of unit-dose container and shape must be easy to be easy to add decollator with the various geometrical shape fits that are used for the rinse cycle decollator of domestic washing machine to guarantee it.In addition, identical with the general application of rinse cycle softening agent, must cleaned at regular intervals rinsing decollator avoiding in decollator, accumulating resistates, or even stop the growth of bacterium simultaneously.
In addition, the units dosage composition that is used for rinse cycle must be mixed with when contacting with water corresponding to unitary dose in the time cycle of the residence time of decollator, promptly enter and flow through in time of rinse cycle decollator and be easy to disperse its component at water.The product that above-mentioned actual needs can not got by any commerce so far successfully satisfies, therefore, still need in the prior art can be in rinse cycle the activatory unit dose softener.
Comprise that further fabric softener is well known in the prior art with laundry detergent composition soft in the wash(ing)cycle that is provided at laundry operations or the conditioning fabric, and in patent documentation, described.US4605506 referring to for example Wixon; The US4569773 of the US4818421 of Boris etc. and Ramachandran etc. all transfers Colgate-Palmolive Co. and transfers the US4851138 of Akzo.The US5972870 of Anderson has described the multilayer laundry tablets that is used to wash, and it can be included in outer field washing composition and at fabric softener or the water-softening agent or the spices of internal layer.But this class multiple-effect product has common shortcoming, promptly, there is intrinsic harm, independent only be used to the detergent composition that cleans and use the independent softish soft compound that only is used for to compare in rinse cycle with using in wash(ing)cycle, the cleaning and the soft effect that are provided by this series products must be provided the user.In fact, the user of this washing composition softener composition does not have ability to regulate the quantity of washing composition and softening agent in the wash(ing)cycle that adds machine separately according to the cleaning of concrete washing load and soft needs.
Having carried out some in the prior art attempts being generally powder type with active fabric softener exploitation wash(ing)cycle.But the product of these types has and uses the identical inconvenience of powder detergent intrinsic, i.e. operational issue, caking and need doser that the REACTIVE SOFTNER material of desired number is provided with the water to washing in container or wash(ing)cycle decollator.We find now; the softness of the clothes of washing can be independent of the handiness of detergent doses and carry out in wash(ing)cycle; with provide great convenience to the human consumer by applying unit dosage softening agent wash(ing)cycle, it has been avoided and has toppled over and operate particle or the relevant FAQs of liquid detergent composition.
Summary of the invention
The invention provides unitary dose fabric sofetening composition wash(ing)cycle that in the wash(ing)cycle of automatic washing machine, is used for softness or conditioning fabric, described unitary dose contains (a) fine and close particle fabric softener composition or (b) encapsulate capsule liquid and/or particle fabric softener composition, (a) or quantity (b) be enough to form the unitary dose that effective softness or conditioning fabric can be provided in the wash(ing)cycle of described washing machine.
In a preferred embodiment, the unitary dose fabric sofetening composition is characterised in that it is tablet form, have the non-discrete skin of forming by alkaline matter around the fabric softener, thus the pH of washing water increase when described skin is dissolved in the described washing water.
In another preferred embodiment, unitary dose contains does not have the dense granule of soap surfactant softener composition basically.
The term that uses when describing fabric softener in this article " particle " be meant comprise be of a size of about 150-2000 micron than coarse particles and be of a size of the 30-50 micron than fine powder.
For simplicity, the term " fabric " softening agent that is used for this paper " be meant the material that softness and/or conditioning effect are provided to fabric wash(ing)cycle at family or automatic washing machine.
Dense granule fabric softener composition of the present invention is preferably by optionally forming with the soft material bonded of organic fatty fabric sofetening clay.Especially preferred fabric softener contains the clay mineral softening agent, and for example wilkinite combines with the tetramethylolmethane ester cpds that hereinafter further describes.The useful composition of this softening agent can be by about 90% clay of about 80%-and the fatty soft material of about 10%-20% by weight by weight, and for example tetramethylolmethane compound (this paper is abbreviated as " PEC " usually) changes.
The encapsulate capsule liquid or the particle fabric softener composition that are used for this paper comprise that the gelatine capsule that contains NON IONIC SOFTNER or clay is to avoid and any reaction that may be present in the anion surfactant of washings.Useful liquid soft compound comprises Fatty Alcohol(C12-C14 and C12-C18), lipid acid, and fatty ester, polysiloxane (straight chain for example, grafting, crosslinked or ethoxylation), polyethylene wax and fatty amide.
The method according to this invention aspect, it provides the method for the clothes of soft or conditioning washing, and it comprises that the clothes that makes washing contacts with the laundry composition of unitary dose as defined above of significant quantity.
The detailed description of invention
The clay of the useful component of product of the present invention is and the material of organic fatty softening agent material acting in conjunction with the enhancing soft effect of clothes that washing is provided.This clay comprises the clay that contains montmorillonite, they have swelling property (in water), and they are smectite structures, thereby they are deposited on fibrous matter, especially cotton and cotton/synthetic mixture material are for example smooth or soft to give this fiber and fabric face by their preparations on cotton/polyester.Being used for best smectic clays of the present invention is wilkinite, and best wilkinite is those wilkinites that have remarkable swelling ability in water, for example sodium and potassium wilkinite.This swelling wilkinite is also referred to as western part or Wyoming wilkinite, and they mainly are sodium bentonites.Other wilkinite, for example calcium bentonite is non-swollen usually, itself is normally unacceptable as fabric softener.Yet, when finding also that this non-swelling wilkinite combines with PEC, we show better fabric sofetening effect than swelling wilkinite, its prerequisite is to have basic metal or other solubilising ion source in soft compound, for example (it can be from the sodium hydroxide that adds composition for sodium, or from sodium salt, for example washing assistant and filler, they can be the function ingredients of composition).Wherein, preferred wilkinite is sodium and potassium wilkinite, and they are swollen and calcium and magnesium wilkinite normally, and they are normally non-swelling.Wherein preferably use calcium (in the presence of the sodium source) and sodium bentonite.The wilkinite that is adopted can be produced in USA, and for example the Wyoming wilkinite is obtained by Europe but also can be used as calcium bentonite, comprises Italy and Spain, and it can use by handling with yellow soda ash to be converted into sodium bentonite or to can be used as calcium bentonite.In addition, the bentonitic as described smectic clays that other contains montmorillonite of character can substitute wilkinite as herein described whole or in part, and can obtain similar fabric sofetening result.
The wilkinite of swellable and similar effective clay are micron orders, the basic granularity of 0.01-20 micron for example, 100-400 number sieve, the true granularity of preferred 140-325 number sieve US sieve series.Wilkinite and other suitable swellable clay can agglomerate into than volume particle size, for example sieve for 60-120 number, but this agglomerate are not preferred, unless they also comprise PEC (in any particulate product).
Composition of the present invention and goods of the present invention, the major constituent that is used in combination with the fabric sofetening clay is the organic fatty softening agent.Organic softening agent can be a negatively charged ion, positively charged ion or nonionic aliphatic chain (C
10-C
22, preferred C
12-C
18).Anionic softener comprises fatty acid soaps, and preferred organic softening agent is non-ionic, for example fatty ester, ethoxylated fat ester, Fatty Alcohol(C12-C14 and C12-C18) and polyhydric alcohol polymer.Organic softening agent most preferably is the high-grade aliphatic ester of tetramethylolmethane compound, and this term is used for the high-grade aliphatic ester of this specification sheets with the rudimentary alkylene oxide derivatives of the high-grade aliphatic ester of the rudimentary alkylene oxide derivatives of the high-grade aliphatic ester of the high-grade aliphatic ester of describing tetramethylolmethane, tetramethylolmethane oligopolymer, tetramethylolmethane, tetramethylolmethane oligopolymer.The tetramethylolmethane compound is abbreviated as PEC usually herein, and its description and abbreviation be applicable to any or all tetramethylolmethane, oligopolymer, their oxidation alkyl derivative, itself or more preferably and more frequently as above hereinafter described ester.
The tetramethylolmethane oligopolymer is 2-5 tetramethylolmethane part preferably, more preferably those oligopolymers of 2 or 3, and these parts link together by ehter bond.Its rudimentary alkylene oxide derivatives is oxyethane or propylene oxide monomer, dipolymer or polymkeric substance preferably, and they are terminal with the hydroxyl, are connected to tetramethylolmethane or tetramethylolmethane oligopolymer by ehter bond.Preferably have 1-10 alkylene oxide part in each this alkylene oxide chain, more preferably 2-6 depends on that will there be 1-10 this group in oligopolymer on PEC.At least 1 PEC OH group, preferably at least 2, for example 1 or 2-4 by higher fatty acid or other higher aliphatic acid estersization, they can be the carbon atoms of odd number.
The high-grade aliphatic ester of tetramethylolmethane compound is the part ester preferably, more preferably has at least two free hydroxyl groups (in tetramethylolmethane, dipolymer or alkoxyalkyl group) behind the esterification process thereon.Usually the number of this free hydroxyl group is 2 or about 2, but it can be 1 sometimes, as under the situation of tetramethylolmethane tristearate.The higher aliphatic or the lipid acid that can be used as esterification acid are that carbonatoms is 8-24, preferred 12-22, the more preferably acid of 12-18, for example lauric acid, tetradecanoic acid, palmitinic acid, oleic acid, stearic acid and docosoic acid.They can be by natural origin, the fatty acid mixt that obtains of butter or Oleum Cocois for example, or obtain by these crude substance that are hydrogenated.The synthetic acid of odd number or even carbon atom also can be used.In lipid acid, lauric acid and stearic acid are normally preferred, and this preferably depends on esterified tetramethylolmethane compound.
The example of some ester (PEC) is as follows among the present invention:
The monopentaerythritol ester Monopentaerythritol dilaurate R
1=CH
3-(CH
2)
10-COO-R
2=CH
3-(CH
2)
10-COO-R
3=OHR
4=OH monopentaerythritol monostearate R
1=CH
3-(CH
2)
16-COO-R
2=OHR
3=OHR
4=OH monopentaerythritol SUNSOFT Q-182S R
1=CH
3-(CH
2)
16-COO-R
2=CH
3-(CH
2)
16-COO-R
3=OHR
4=OH monopentaerythritol tristearate R
1=CH
3-(CH
2)
16-COO-R
2=CH
3-(CH
2)
16-COO-R
3=CH
3-(CH
2)
16-COO-R
4The single docosane acid esters of=OH monopentaerythritol R
1=CH
3-(CH
2)
20-COO-R
2=OHR
3=OHR
4=OH monopentaerythritol two (docosoic acid) ester R
1=CH
3-(CH
2)
20-COO-R
2=CH
3-(CH
2)
20-COO-R
3=OHR
4=OH
Dipentaerythritol ester 
Dipentaerythritol cinnamic acid in April ester R
1=CH
3-(CH
2)
10-CO-R
2=CH
3-(CH
2)
10-CO-R
3=CH
3-(CH
2)
10-CO-R
4=CH
3-(CH
2)
10-CO-Dipentaerythritol tetrastearate R
1=CH
3-(CH
2)
16-CO-R
2=CH
3-(CH
2)
16-CO-R
3=CH
3-(CH
2)
16-CO-R
4=CH
3-(CH
2)
16-CO-
Tetramethylolmethane 10 oxyethane esters 
N+n '=10 monopentaerythritol, 10 oxyethane SUNSOFT Q-182S R wherein
1=CH
3-(CH
2)
16-COO-R
2=CH
3-(CH
2)
16-COO-
Tetramethylolmethane 4 propylene oxide esters 
Monopentaerythritol 4 propylene oxide monostearate R
1=CH
3-(CH
2)
16-COO-R
2=OH monopentaerythritol 4 propylene oxide SUNSOFT Q-182S R
1=CH
3-(CH
2)
16-COO-R
2=CH
3-(CH
2)
16-COO-
Though some the preferred tetramethylolmethane compound that is used for the present invention's practice has been described in the chemical formula that this paper provides, but all other tetramethylolmethane compounds that should understand at specification sheets of the present invention also can adopt, and comprise for example tetramethylolmethane dihydro butter acid esters, tetramethylolmethane two butter acid esters, tetramethylolmethane dipalmitate and Dipentaerythritol four butter acid esters.
For strengthening the soft effect of units dosage composition as herein described, cationic softener, for example conventional quaternary ammonium softening compound thing is optionally with a small amount of adding.
The composition of the soft material of wilkinite and organic fatty is generally about 99% wilkinite of about 10%-and about 1%-about 90% fatty soft material, preferred about 95% wilkinite of about 50%-and about 5%-about 50% fatty soft material, most preferably from about 80%-90% wilkinite and the soft material of about 10%-20% fat.
Other useful component that is used for unitary dose dense granule composition of the present invention comprises that the disintegration material is to strengthen the disintegration of unitary dose at washing water.This material comprises effervesce matrix, for example with sodium bicarbonate bonded citric acid, or for example PVP polymkeric substance and cellulose materials.Can use granulating agent, for example polyoxyethylene glycol; Sterilant, spices, dyestuff and prevent to fade, dye transfer, anti pilling and crease-resistant material.For improving the aesthetic properties of final composition, components of cosmetics, for example dyestuff, mica and wax can be used as and applies composition to improve the look and feel of unitary dose.
The capsule that provides for liquid or soft granules or conditioning materials is gelatin shell preferably, and it is easy to be dissolved in the washing water, and with wash(ing)cycle in the washing composition that uses compatible.Technology well known in the prior art is used in the production of this gelatine capsule, for example describing in the following publication, they classify this paper reference as: " Softgels:Manufacturing Consideratons ", PaulWilkinson and Foo Song Hom, Drugs Pharmaceutical Science (1990), pps409-449, Mediventure Inc., Ann Arbor, MI, USA; " Coating of GelatinCapsules ", Ann Mari Hannula and Peter Speiser, Acta PharmaceuticalTechnology (1988), pps.234-236.
Preferred liquid softening agent of the present invention comprises Fatty Alcohol(C12-C14 and C12-C18), oleyl alcohol for example, lipid acid, for example oil base carboxylic acid; Fatty ester, for example oil base ester or vegetation fat ester, for example sunflower oil; Polysiloxane, polydimethylsiloxane for example, straight chain or crosslinked, ethoxylation or do not have ethoxylation, and optionally comprise the amide functionality; Polyethylene wax has the molecular weight of 8000-60000; And fatty amide, for example two oil base acid amides that form by diethylenetriamine and the elaidin reaction that mainly has following structure:
R wherein
1Expression oil base alkyl carbon chain; And R
2Expression H or (EO)
x, x is 0-6 (ethoxylation degree).
Though for soft effect being provided and disperseing in washing water, the oil base carbon chain lengths is most preferred, other more high-grade alkyl chain length also can be used among the present invention.
The typical flat dosage composition that is used for this paper can be equivalent to the weight (comprising capsular weight) of about 10 grams of about 5-by the about 10 milliliters of variations of about 5-, and the dosage number of each washing is 2.In addition, when using 1 unitary dose/washing, corresponding volume and weight is respectively about 20 milliliters of about 10-, and about 10-about 20 restrains (comprising capsules weight).
Embodiment 1
The dense granule units dosage composition is prepared by following component:
| Weight percentage | |
| Clay/tetramethylolmethane two butter acid esters (PDT), ratio 83%:17% | 79.97％ |
| The effervesce matrix of sodium bicarbonate and citric acid | 17％ |
| Polyvinylpyrolidone (PVP) | 1％ |
| Spices | 2％ |
| Dyestuff | 0.03％ |
Production method is included in all components that mixes in the Loedige type mixing tank except that spices.The mixture that obtains is dry in baking oven, adds spices subsequently in the exsiccant powder.This powder uses alternately subsequently or the press that is loaded with dyestuff of rotation is suppressed.The weight of spherical unitary dose is 60 grams, and this unitary dose is being set at when adding washes in 20 minutes that are beginning to wash under 40 ℃ in the European Miele W832 front-loading washing machine of Program WhiteColors and is being dispersed in the water.
Units dosage composition washs postevaluation to the pliability that uncut pile fabric towel, cotton T-shirt and cotton kitchen-towel provide in accumulation, and contrasts with commercial liquid fabric softener.3 kilograms laundry ballast weights are added in the washing machine, and pliability is used 9 revision test evaluations by the group that 6 identifiers form.The result is as follows:
| Pliability is estimated | |
| Washing articles | Pliability relatively |
| The uncut pile fabric towel | 1 unit dose softener composition of the present invention provides the suitable pliability with commercial liquid FS 10 accumulations after wash(ing)cycle |
| Cotton T-shirt | 1 unit dose softener provides the suitable pliability with commercial liquid FS after 1 wash(ing)cycle |
| Cotton kitchen-towel | 1 unit dose softener provides after 1 wash(ing)cycle than commercial liquid FS enhanced pliability |
Embodiment 2
The gelatin encapsulate capsule unitary dose liquid softener composition of preparation comprises following component:
(1) polydimethylsiloxane
| Composition | % (nominal) |
| ????PDMS (1) | ????19.00 |
| Three oleic acid R-Glyceric acid | ????15.00 |
| Sunflower oil | ????60.70 |
| Spices | ????5.30 |
To in washing machine, the pliability that cotton T-shirt and towel provide being estimated by units dosage composition, and with commercial liquid fabric softener relatively.Units dosage composition provides suitable basically pliability.
Claims (20)
1. unitary dose fabric sofetening composition wash(ing)cycle that in the wash(ing)cycle of automatic washing machine, is used for softness or conditioning fabric, described unitary dose contains (a) fine and close particle fabric softener composition or (b) encapsulate capsule liquid and/or particle fabric softener composition, (a) or quantity (b) be enough to form the unitary dose that effective softness or conditioning fabric can be provided in the wash(ing)cycle of described washing machine.
2. the unitary dose soft compound of claim 1 is characterized in that it is a tablet form, has the non-discrete skin of being made up of alkaline matter around the fabric softener, thus the pH of washing water increase when described skin is dissolved in the described washing water.
3. the unitary dose soft compound of claim 1, it contains does not have the dense granule of soap surfactant fabric softener composition basically.
4. the unitary dose soft compound of claim 1, wherein said fabric softener composition contains mild clay.
5. the unitary dose soft compound of claim 4, wherein said fabric softener composition contain and the soft material bonded of organic fatty mild clay.
6. the unitary dose soft compound of claim 5, wherein said mild clay is the clay that contains montmorillonite, and the soft material of described organic fatty is tetramethylolmethane compound (" PEC "), and it is selected from the rudimentary alkylene oxide derivatives of oligopolymer of oligopolymer, tetramethylolmethane of higher aliphatic acid esters, the tetramethylolmethane of tetramethylolmethane and their mixture.
7. the unitary dose soft compound of claim 5, wherein said mild clay is the clay that contains montmorillonite, and the soft material of described organic fatty is a Fatty Alcohol(C12-C14 and C12-C18).
8. the unitary dose soft compound of claim 5, wherein said mild clay to small part scribble the soft material of described organic fatty, as the carrier of the soft material of this fat.
9. the unitary dose soft compound of claim 5, wherein said mild clay is that wilkinite and described PEC are the higher aliphatic esters of the oligopolymer of tetramethylolmethane or tetramethylolmethane.
10. the unitary dose soft compound of claim 6, the composition of its medium clay soil and fatty soft material contain the wilkinite of about by weight 50%-about 95% and the described PEC of about 5%-about 50%.
11. the unitary dose soft compound of claim 10, the composition of its medium clay soil and fatty soft material contain the wilkinite of about by weight 80%-about 90% and the described PEC of about 10%-about 20%.
12. the unitary dose soft compound of claim 1, wherein said fabric softener contains the liquid aliphatic ester.
13. the unitary dose soft compound of claim 12, wherein said fatty ester is a sunflower oil.
14. the unitary dose soft compound of claim 1, wherein said fabric softener composition contains liquid polysiloxane.
15. the unitary dose soft compound of claim 1, wherein said fabric softener composition contains the liquid oleyl alcohol.
16. be used for the method for the clothes of softness or conditioning washing, it comprises that the clothes that makes washing contacts with the unitary dose soft compound of the claim 1 of significant quantity.
17. the method for claim 16, wherein fabric softener contains and the soft material bonded of organic fatty mild clay.
18. the method for claim 17, wherein said mild clay is a wilkinite, the soft material of described organic fatty comprises Fatty Alcohol(C12-C14 and C12-C18) or tetramethylolmethane compound (" PEC "), and it is selected from the rudimentary alkylene oxide derivatives of oligopolymer of oligopolymer, tetramethylolmethane of higher aliphatic acid esters, the tetramethylolmethane of tetramethylolmethane and their mixture.
19. the method for claim 16, wherein fabric softener composition contains the liquid aliphatic ester.
20. the method for claim 16, wherein said fatty ester is a sunflower oil.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/558,822 | 2000-04-26 | ||
| US09/558,822 US6258767B1 (en) | 2000-04-26 | 2000-04-26 | Spherical compacted unit dose softener |
| US09/620,515 US6294516B1 (en) | 2000-04-26 | 2000-07-20 | Wash cycle unit dose softener |
| US09/620,515 | 2000-07-20 | ||
| US09/821,231 | 2001-03-29 | ||
| US09/821,231 US6589930B2 (en) | 2000-04-26 | 2001-03-29 | Wash cycle unit dose softener |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1439046A true CN1439046A (en) | 2003-08-27 |
Family
ID=27415783
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01811700 Pending CN1439046A (en) | 2000-04-26 | 2001-04-23 | Wash cycle unit dose softener |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP1276837A1 (en) |
| JP (1) | JP2003531311A (en) |
| CN (1) | CN1439046A (en) |
| AU (1) | AU2001255577A1 (en) |
| BR (1) | BR0110354A (en) |
| CA (1) | CA2406174A1 (en) |
| MX (1) | MXPA02010229A (en) |
| WO (1) | WO2001081520A1 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6664226B2 (en) * | 2000-04-26 | 2003-12-16 | Colgate-Palmolive Co | Spherical compacted unit dose softener |
| US6670320B1 (en) * | 2002-06-11 | 2003-12-30 | Colgate-Palmolive | Wash cycle unit dose softener containing a disintegrating agent |
| US6746995B2 (en) * | 2002-06-13 | 2004-06-08 | Colgate-Palmolive Company | Wash cycle unit dose softener containing a controlled amount of moisture |
| US6664222B1 (en) * | 2002-06-13 | 2003-12-16 | Colgate-Palmolive Co. | Wash cycle unit dose softener |
| AU2003259284A1 (en) * | 2002-07-31 | 2004-02-16 | Colgate-Palmolive Company | Unit dose softener disposed in water soluble container |
| AU2003257020A1 (en) * | 2002-07-31 | 2004-02-16 | Colgate-Palmolive Company | Unit dose nonaqueous softener disposed in water soluble container |
| EP1431384B2 (en) | 2002-12-19 | 2009-02-11 | The Procter & Gamble Company | Single compartment unit dose fabric treatment product comprising pouched compositions with non-cationic fabric softener actives |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4081384A (en) * | 1975-07-21 | 1978-03-28 | The Proctor & Gamble Company | Solvent-free capsules and fabric conditioning compositions containing same |
| US4082678A (en) * | 1976-11-10 | 1978-04-04 | The Procter & Gamble Company | Fabric conditioning articles and process |
| US4328110A (en) * | 1980-09-17 | 1982-05-04 | Beecham Inc. | Fabric conditioning articles and methods of use |
| JPS61276896A (en) * | 1985-06-03 | 1986-12-06 | 花王株式会社 | Softener tablet for washing bath |
| US4659496A (en) * | 1986-01-31 | 1987-04-21 | Amway Corporation | Dispensing pouch containing premeasured laundering compositions |
| US5091105A (en) * | 1989-10-10 | 1992-02-25 | Dow Corning Corporation | Liquid detergent fabric softening laundering composition |
| FI921148A (en) * | 1991-09-06 | 1993-03-07 | Colgate Palmolive Co | TYGMJUKGOERANDE PRODUKTER BASERADE PAO EN KOMBINATION AV EN PENTAERYTRITOLFOERINING OCH BENTONIT |
| JPH0987696A (en) * | 1995-09-27 | 1997-03-31 | Lion Corp | Tablet type nonionic detergent composition |
| ZA9886B (en) * | 1997-01-17 | 1998-07-08 | Gordon Glasgow | Washing aid |
| US5972870A (en) * | 1997-08-21 | 1999-10-26 | Vision International Production, Inc. | Multi-layered laundry tablet |
| GB9802390D0 (en) * | 1998-02-04 | 1998-04-01 | Unilever Plc | Detergent compositions |
| EP1048718A1 (en) * | 1999-04-30 | 2000-11-02 | The Procter & Gamble Company | Detergent compositions |
| DE19931399A1 (en) * | 1999-07-07 | 2001-01-11 | Henkel Kgaa | Capsule for the controlled release of active substances |
-
2001
- 2001-04-23 BR BR0110354-7A patent/BR0110354A/en not_active Application Discontinuation
- 2001-04-23 MX MXPA02010229A patent/MXPA02010229A/en active IP Right Grant
- 2001-04-23 AU AU2001255577A patent/AU2001255577A1/en not_active Abandoned
- 2001-04-23 CN CN 01811700 patent/CN1439046A/en active Pending
- 2001-04-23 JP JP2001578592A patent/JP2003531311A/en active Pending
- 2001-04-23 WO PCT/US2001/013007 patent/WO2001081520A1/en not_active Application Discontinuation
- 2001-04-23 EP EP01928752A patent/EP1276837A1/en not_active Withdrawn
- 2001-04-23 CA CA002406174A patent/CA2406174A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA02010229A (en) | 2003-04-25 |
| CA2406174A1 (en) | 2001-11-01 |
| EP1276837A1 (en) | 2003-01-22 |
| AU2001255577A1 (en) | 2001-11-07 |
| WO2001081520A1 (en) | 2001-11-01 |
| BR0110354A (en) | 2003-01-21 |
| JP2003531311A (en) | 2003-10-21 |
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| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication | ||
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