CN1436594A - Prepn process of waste gas purifying catalyst containing noble metal - Google Patents
Prepn process of waste gas purifying catalyst containing noble metal Download PDFInfo
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Abstract
The preparation process of waste gas purifying catalyst containing noble metal includes soaking composite aluminium oxide with solution containing noble metal, drying and baking to obtain base coating material; painting the slurry containing the base coating material onto carrier, drying and baking. The preparation process of the composite aluminum oxide includes mixing and beating pseudo-thin diasphore and the solution of assistant salt to obtain the first slurry containing alumina 10-60 wt% and assistant oxide 5-40 wt%; mixing and beating pseduo-thin diasphore and the solution of assistant salt and adding acid to regulate pH value to 0.5-5.5 to obtain the second slurry containing alumina 10-60 wt% and assistant oxide 5-40 wt%; mixing the first slurry and second slurry in the weight ratio of 0.1-10, drying and roasting to obtain the slurry.
Description
Invention field
Originally the invention relates to a kind of preparation method of exhaust gas purifying catalyst, more particularly, is the preparation method who contains the exhaust gas purifying catalyst of noble metal about a kind of.
Background technology
The waste gas that engine produces contains a large amount of pernicious gases in the tail gas as automobile, these pernicious gases are mainly by carbon monoxide (CO), hydro carbons (HC) and nitrogen oxide (NO
x) form.The increasingly stringent that need require motor exhaust along with environmental protection increases day by day to the demand of exhaust gas purifying catalyst, and the exhaust gas purifying catalyst performance demands is also improved constantly.
The preparation method of exhaust gas purifying catalyst generally includes the slurries of a kind of base coating material of preparation, and the slurries of this base coating material are coated on a kind of honeycomb support, dry and roasting.Described base coating material generally contains a kind of modified heat resistant inorganic oxide (as composite alumina or title modified aluminas) and at least a noble metal.Described modified heat resistant inorganic oxide (as composite alumina) contains heat-resistant inorganic oxide (as aluminium oxide) and auxiliary agent, and described auxiliary agent can be selected from one or more in the oxide of rare earth oxide and zirconium, magnesium, chromium, manganese, iron, cobalt, nickel.
CN1055302A discloses a kind of Catalysts and its preparation method of purifying exhaust air, this catalyst is by the honeycomb support of en-block construction and be coated on this honeycomb support, and the coating that forms one deck carbon monoxide-olefin polymeric forms, described carbon monoxide-olefin polymeric contain a kind of do not have noble metal loading thereon first kind of heat-resistant inorganic oxide of face and at least a average grain diameter at granular second kind of heat-resistant inorganic oxide of 0.5-20 micrometer range.Described second kind of heat-resistant inorganic oxide is at least a following heat-resistant inorganic oxide that is selected from: (a) a kind of heat-resistant inorganic oxide that is selected from least a noble metal in platinum and the palladium of the heavy % of 5-30 and (b) a kind of heat-resistant inorganic oxide that has deposited the heavy % rhodium of 1-20 in the above of having deposited in the above.At least a in the optional self-alumina of described heat-resistant inorganic oxide, silica, titanium oxide, cobalt oxide, alumina silica, aluminium oxide-titanium oxide, aluminium oxide-zirconium oxide, silica-titanium oxide, silica-zirconia, oxidation titania-zirconia, the aluminium oxide-magnesia.Can also contain cerium oxide in this catalyst.This Preparation of catalysts method comprises the honeycomb support that applies en-block construction with a kind of moisture thin pulp that contains carbon monoxide-olefin polymeric, calcine the carrier through applying subsequently, described carbon monoxide-olefin polymeric contains at least a following refractory inorganic oxide that is selected from: (a) a kind of 5-30 that deposited in the above weighs the heat-resistant inorganic oxide that is selected from least a noble metal in platinum and the palladium of % and (b) deposits the heat-resistant inorganic oxide that 1-20 weighs the % rhodium on it.Can mix cerium oxide in the carbon monoxide-olefin polymeric that carrier band has the heat-resistant inorganic oxide of noble metal to make.The deficiency of this catalyst is that catalytic activity is not high enough.
CN1092697 discloses a kind of preparation method of exhaust gas purifying catalyst, and this method comprises the preparation carrier, and catalysis material, coating material and a kind of auxiliary agent are mixed, and to make a kind of washcoat layer slurry, the washcoat layer slurry is coated on the described carrier.Described carrier is a cordierite, and catalysis material is the bond of noble metal or perovskite composite oxides and noble metal, and coating material is γ-Al
2O
3, described auxiliary agent is CeO
2Or ZrO
2-CeO
2, adopt the specific surface of the catalyst that this method prepares after 700 ℃ of roastings, still can remain on 60-70 rice
2/ gram, but adopt the activity of such catalysts and the heat endurance of this method preparation still not high enough, at this catalyst of roasting temperature that surpasses 700 ℃, its specific surface drops to 60 meters
2Below/the gram, therefore activity of such catalysts is lowered.For example, without heat treated catalyst, in the time of 600 ℃, the purifying rate of CO has only 95%, and the purifying rate of the Catalyst for CO after the heat treatment has only 90%.
CN160599A discloses a kind of preparation method of exhaust gas purifying catalyst, this catalyst is done complex carrier with the cellular porcelain body of the en-block construction that scribbles aluminum oxide coating layer, carried noble metal, rare earth metal and transition metal active component, described complex carrier adopts following method preparation: (1) makes the slurries that solid content is the heavy % of 10-15 with boehmite and the decationized Y sieve water of the heavy % of the 25-75 in the scheduled volume, it is 1.5-4.0 that adding hydrochloric acid is transferred its pH, the boehmite that adds surplus again, be stirred to slurries and be equal colloid shape, (2) adding aluminium colloidal sol continuation stirring 30-60 branch plants, (3) 50-70 ℃ aging 1-3 hour, (4) adding accounts for the aqueous solution of the ferrochrome lignosulfonate of butt alumina weight 2.5-15.0%, stir, (5) the cordierite honeycomb carrier is immersed in the above-mentioned slurries, take out the back and blow away slurries unnecessary in the duct with compressed air, dry, roasting, step impregnation method is adopted in the load of described metal active constituent, need dry behind each dipping, roasting, described active metal component is (1) rhodium, platinum, at least a in the palladium, (2) lanthanum, cerium, in the praseodymium one or more and (3) chromium, iron, manganese, cobalt, nickel, in the copper one or both.Adopt this method can suppress the phase transformation of aluminium oxide when high temperature, thereby aluminium oxide at high temperature still have higher specific surface.But this method complicated operation, and the catalyst activity at high temperature of preparation is still not high enough.
US5,081,095 discloses a kind of thermally-stabilised, high-ratio surface, particulate, is applicable to the preparation method of the catalyst carrier that purifies the waste gas that gasoline automobile engine produces, and this method comprises and becomes specific surface to be at least 80 meters the cerous acetate roasting
2The cerium oxide of/gram, to contain the mixture wet-milling of above-mentioned cerium oxide, cerous acetate and high specific surface aluminium, obtain a kind of grained slurry liquid mixture of homogeneous, wherein in cerium oxide and aluminium oxide, the total content of cerium is 20-50: 80-50 with the ratio of the total content of aluminium, described mixture contacts with the catalyst matrix of en-block construction as coating material, and coating dry, that roasting is wet changes into the oxide coating that adheres to.Prepare catalyst with this method and at high temperature still can keep certain specific surface, and have certain initial activity, but the catalytic activity under its high temperature is also not high enough.
CN1239017A discloses a kind of preparation method who contains the exhaust gas purifying catalyst of noble metal and has comprised a kind of base coating material of preparation, the slurries that will contain described base coating material are coated on a kind of carrier, dry also roasting, wherein, the preparation method of described base coating material comprises the steps: that (1) is mixed and made into part boehmite in the scheduled volume and deionized water in the slurries of the heavy % of solid content 10-20, adding a kind of its pH value of acid accent is 1.5-4.0, the boehmite that adds surplus, be stirred to slurries and be equal colloid shape, wherein, in aluminium oxide, successively the weight ratio of the boehmite of Jia Ruing is 0.1-5; (2) under agitation add a kind of hydroxide of auxiliary agent, described auxiliary agent is selected from one or more in rare earth, zirconium, magnesium, chromium, manganese, iron, cobalt, the nickel, and the consumption of auxiliary agent should make the heavy % of the oxide 1-30 that contains auxiliary agent in the base coating material.(3) under agitation add aluminium colloidal sol, in aluminium oxide, the weight ratio of boehmite and aluminium colloidal sol is 1-50.(4) 30-100 ℃ of aging slurries are more than 0.5 hour, and dry and roasting obtains a kind of modified aluminas.(5) modified aluminas that obtains with the solution impregnation that contains noble metal, dry and roasting gets base coating material, and wherein the consumption of noble metal should make to contain the heavy % of noble metal 0.1-30 in the base coating material.Compared with former technology, the preparation method that the key of this invention is described modified aluminas unlike the prior art, the activity of the exhaust gas purifying catalyst of preparing is improved.Yet this method is too complicated, and manufacturing cycle is long, just because of this, in whole process of preparation, the factor that influences the composite alumina character character of base coating material and catalyst (and then influence) is more, the character instability of the exhaust gas purifying catalyst of preparing that contains noble metal.
Summary of the invention
It is too complicated to the objective of the invention is to overcome the existing exhaust gas purifying catalyst preparation method who contains noble metal, and the shortcoming that manufacturing cycle is long provides a kind of preparation method of simple, the exhaust gas purifying catalyst that contains noble metal that manufacturing cycle is short.
The preparation method who contains the exhaust gas purifying catalyst of noble metal provided by the invention comprises with a kind of composite alumina of solution impregnation that contains noble metal, dry also roasting, obtain a kind of base coating material, the slurries that will contain described base coating material are coated on a kind of carrier, dry also roasting, wherein, the preparation method of described composite alumina comprises the aqueous solution making beating of the salt of boehmite and auxiliary agent even, obtaining alumina content is the heavy % of 10-60, and the auxiliary agent oxide content is first kind of slurries of the heavy % of 5-40; With the aqueous solution making beating of the salt of boehmite and auxiliary agent evenly, add pH value that acid regulates slurries to 0.5-5.5, obtaining alumina content is the heavy % of 10-60, and the auxiliary agent oxide content is second kind of slurries of the heavy % of 5-40; First kind of slurries and the second kind of slurries weight ratio by 0.1-10 is mixed; The slurries dry and roasting obtains; Described auxiliary agent is selected from one or more in rare earth element, zirconium, yttrium, magnesium, chromium, manganese, iron, cobalt, the nickel.
Compared with prior art, the present invention has following advantage:
1. the step of Preparation of catalysts method provided by the invention is simplified greatly, and manufacturing cycle shortens greatly.
At first, according to the CN1239017A disclosed method, the used auxiliary agent raw material of preparation catalyst is the hydroxide of auxiliary agent, the hydroxide of auxiliary agent then is to be obtained by the aqueous solution of the salt of auxiliary agent precipitation, in the process of the hydroxide of preparation auxiliary agent, not only needs to add precipitating reagent, wasted raw material, and it is very thin to carry out the hydroxide particles of repeatedly filtration and washing, particularly auxiliary agent to the precipitation that forms, and the time of filtering at every turn and washing is all longer.And in the method provided by the invention, the raw material of auxiliary agent directly adopts the salt of auxiliary agent, has saved all processes of preparation auxiliary agent hydroxide, i.e. precipitation process, multiple times of filtration and washing process, and this is one of method step provided by the invention place of simplifying greatly.
Secondly, according to the CN1239017A disclosed method, in the process of preparation catalyst, need earlier a part of boehmite to be mixed making beating with water and acid, add another part solid boehmite again, also need at last to add aluminium colloidal sol, and stir, not only the step complexity, the used time is long, and because step is loaded down with trivial details, the factor that influences composite alumina character increases.For example, the boehmite hickie that adopts in the composite alumina of this method preparation often appearance not to be fully opened, this catalyst that obtains is not a kind of uniform material, its repeatability is also bad, also often has bigger difference between the character of promptly a collection of catalyst prod and the other a collection of catalyst prod for preparing under identical conditions.And adopt method provided by the invention, and do not need substep to add boehmite, do not need to add again aluminium colloidal sol yet, this is two of the method step provided by the invention place of simplifying greatly.Simplifying greatly of method step provided by the invention makes the factor that influences catalyst property significantly reduce, and the catalyst that obtains is very even, good reproducibility.
2. adopt the composite alumina of method preparation provided by the invention to have higher specific surface and pore volume, therefore, the catalyst that contains this composite alumina also has higher specific surface and pore volume certainly.
For example, adopt the composite alumina of method preparation provided by the invention, when sintering temperature was 850 ℃, specific surface all was not less than 135 meters
2/ gram, pore volume all are not less than 0.34 milliliter/gram, and adopt the modified aluminas (being composite alumina) of CN1239017A disclosed method preparation, and when sintering temperature was 850 ℃, its specific surface all was not more than 135 meters
2/ gram, pore volume all are not more than 0.31 milliliter/gram.The raising of composite alumina specific surface and pore volume must make the specific surface and the pore volume of the catalyst that contains this composite alumina obtain corresponding raising.
3. adopt the catalyst of method preparation provided by the invention to have higher catalytic activity.
The catalytic activity that shows the catalyst that method provided by the invention prepares is apparently higher than the catalyst of forming identical CN1239017A disclosed method preparation.
For example, with containing CO 9000ppm, H
22000ppm, HC 600ppm, CO
210800ppm, NO
x900ppm, O
2The mist of 16000ppm and surplus nitrogen is a reaction raw materials, estimates its exhaust-gas purifying performance, and this mist was with 12000 hours
-1Volume space velocity by quartz tube reactor, the speed that quartz tube reactor divides with 11C/, from room temperature temperature programming to 500 ℃, 20 ℃ of assaying reaction devices of every intensification exit generates CO, HC and the NO in the gas
xThe change in concentration value.When adopting method preparation provided by the invention, when the exhaust gas purifying catalyst of 850 ℃ of roastings after 6 hours, when reaction temperature is 350 ℃, the CO purifying rate is that the heavy % of 98-100, HC purifying rate are that the heavy % of 97-100, NOx purifying rate are the heavy % of 98-100.And when adopting catalyst through the CN1239017A disclosed method preparation of 850 ℃ of roastings after 6 hours, the purifying rate of CO, HC and NOx has only heavy % of 85-95 heavy %, 87-96 and the heavy % of 73-93 respectively.With the function construction of purifying rate, try to achieve CO, HC and NO as temperature
xPurifying rate is respectively 50% o'clock purification temperature T
50Value.When catalyst system therefor is method provided by the invention preparation, when the exhaust gas purifying catalyst of 850 ℃ of roastings after 6 hours, the T of CO
50Be 165-180 ℃, the T of HC
50Be 189-195 ℃, NO
xT
50Be 167-197 ℃.And when adopting catalyst through the CN1239017A disclosed method preparation of 850 ℃ of roastings after 6 hours, the T of CO
50Up to 221-227 ℃, the T of HC
50Up to 250-258 ℃, NO
xT
50Up to 238-248 ℃.
The specific embodiment
According to method provided by the invention, described auxiliary agent is selected from one or more in rare earth element, zirconium, yttrium, magnesium, chromium, manganese, iron, cobalt, the nickel, one or more in preferred rare earth element, zirconium, the yttrium.The salt of described auxiliary agent is selected from one or more in the salt of water-soluble auxiliary agent, the nitrate of preferred rare earth element, zirconium, yttrium, magnesium, chromium, manganese, iron, cobalt, nickel and in the chloride one or more.The chloride of nitrate of rare earth element, rare earth element particularly, one or more in the nitrate of zirconium oxychloride, zirconyl nitrate, yttrium and the chloride of yttrium.Described rare earth element can be single rare earth element, as lanthanum, cerium, also can be the mixture of various rare earth elements.
Alumina content in first kind of slurries and the second kind of slurries is the heavy % of 10-60, is preferably the heavy % of 30-60; The auxiliary agent oxide content is the heavy % of 5-40, is preferably the heavy % of 5-35.
The pH value of second kind of slurries is 0.5-5.5, is preferably 2-5.The used acid of adjusting pH value is one or more in various inorganic acids and the organic acid, one or more in preferred hydrochloric acid, nitric acid and the water-soluble organic acid, preferred especially hydrochloric acid, nitric acid and/or citric acid.
The weight ratio of first kind of slurries and second kind of slurries is 0.1-10, is preferably 0.2-4.
With the aqueous solution making beating of the salt of boehmite and auxiliary agent and the temperature that adds acid for adjusting pH value can be room temperature to 90 ℃, is preferably room temperature to 70 ℃.
The temperature that first kind of slurries mix with second kind of slurries can be a room temperature to 90 ℃, is preferably room temperature to 70 ℃.
Condition dry and the roasting slurries is conventional condition, can be 90-200 ℃ as baking temperature, is preferably 110-150 ℃, and can be more than 0.5 hour drying time, is preferably 1-6 hour.Here " can be more than 0.5 hour drying time " has following implication: because after the solid product drying that obtains, continue dry again, its character no longer changes, though be preferably 1-6 hour drying time, but, in practical operation, if necessary, the dry long time also is fine, and the dry long time can not influence the character of solid product." can be more than 0.5 hour drying time " never is meant the time of dry endless.
The temperature of roasting slurries can be 500-1000 ℃, is preferably 600-900 ℃, and roasting time can be more than 0.5 hour, is preferably 3-8 hour.Here " roasting time can be more than 0.5 hour " has following implication: because the solid product that obtains is after roasting, continue roasting again, its character no longer changes, the character of solid product is just only relevant with the temperature of roasting, though roasting time is preferably 3-8 hour,, in practical operation, if necessary, the long time of roasting also is fine, and the long time of roasting can not influence the character of solid product.Certainly, " roasting time can be more than 0.5 hour " never is meant the time of roasting endless.
According to specific embodiment of the present invention, the preparation method who contains the exhaust gas purifying catalyst of noble metal provided by the invention comprises with a kind of composite alumina of solution impregnation that contains noble metal, dry also roasting, obtain a kind of base coating material, the slurries that will contain described base coating material are coated on a kind of carrier, dry also roasting, wherein, the preparation method of described composite alumina comprises the aqueous solution making beating of the salt of boehmite and auxiliary agent even, obtaining alumina content is the heavy % of 10-60, and the auxiliary agent oxide content is first kind of slurries of the heavy % of 5-40; Take out first kind of slurries that part obtains, add pH value that acid regulates slurries, obtain second kind of slurries, first kind of slurries and the weight ratio of second kind of slurries by 0.1-10 are mixed the slurries that dry also roasting obtains to 0.5-5; Described auxiliary agent is selected from one or more in rare earth element, zirconium, yttrium, magnesium, chromium, manganese, iron, cobalt, the nickel.
The solution impregnation composite alumina that described usefulness contains noble metal can adopt conventional infusion process, composite alumina drying and roasting under normal condition behind the dipping noble metal, dry temperature can from 90 to 300 ℃, preferred 100-200 ℃, drying time is more than 0.5 hour, preferred 1-10 hour, sintering temperature 400-700 ℃, preferred 450-650 ℃, roasting time is more than 0.5 hour, preferred 1-10 hour.Here the implication of " drying time is more than 0.5 hour " and " roasting time is more than 0.5 hour " is with above implication is identical.
It is its conventional content that the solution usage of described noble metal makes the content of the noble metal in the base coating material, in general, it is the heavy % of 0.1-30 that the solution usage of described noble metal makes the content of the noble metal in the base coating material, the heavy % of preferred 0.1-15, the heavy % of more preferred 0.1-5.Described noble metal is selected from one or more in platinum, palladium, rhodium, osmium, iridium, the ruthenium, one or more in preferred platinum, palladium, the rhodium, and the weight ratio of more preferred platinum and rhodium is the platinum of 3-20 and the mixture of rhodium.The solution of described noble metal can be the solution that contains the soluble-salt of noble metal arbitrarily, as chloroplatinic acid, chlorine palladium aqueous acid, and one or more in platinum, palladium, rhodium, osmium, iridium, the muriatic aqueous solution of ruthenium.
The described amount that contains the slurry solid content of base coating material for its routine can be the heavy % of 10-50 as its solid content, the heavy % of preferred 20-40.The method that the described slurries that will contain base coating material are coated on the carrier can adopt the whole bag of tricks of the prior art, is coated with method, infusion process or spray process as water.After applying sizing liquor, condition dry and roasting is its conventional condition, and as the common 100-300 of baking temperature ℃, drying time is more than 0.5 hour, preferably 2-5 hour; Sintering temperature is generally 300-1000 ℃, and preferred 300-900 ℃, roasting time is more than 0.5 hour, preferred 1-10 hour.Here the implication of " drying time is more than 0.5 hour " and " roasting time is more than 0.5 hour " is with above implication is identical.
The following examples will the present invention will be further described.
Example 1
The preparation method of this example explanation composite alumina.
9.47 gram lanthanum concentrate rare earth chlorides (are equivalent to 4.17 gram rare earth oxides, with the rare earth oxide is benchmark, lanthana content is 72.0 heavy %, cerium oxide content is 1.9 heavy %, other rare earth oxide contents are 26.1 heavy %, Beijing Chemical Plant's production), 21.65 gram cerous chlorates (are equivalent to cerium oxide 10 grams, Beijing Chemical Plant's production), 23.55 gram zirconium oxychlorides (contain zirconia 38.22 heavy %, contain yittrium oxide 12.74 heavy %, the Beijing Chemical Plant produces) be dissolved in the 400 gram deionized waters, obtain the aqueous solution of the salt of auxiliary agent.(alumina content is 32 heavy % to add 234.375 gram boehmites in the aqueous solution of the salt of the auxiliary agent that obtains, the Shandong catalyst plant is produced), room temperature (being about 25 ℃) down making beating until evenly, obtain first kind of slurries, alumina content is 48.2 heavy % in the slurries, and the auxiliary agent oxide content is 16.8 heavy %.
33.3% of first kind of slurries gross weight that taking-up obtains, the pH value that adds the hydrochloric acid adjusting slurries of 20 heavy % under room temperature and stirring is 3.5, obtains second kind of slurries.The second kind of slurries and the remaining first kind of slurries that obtain are at room temperature mixed, and the weight ratio of first kind of slurries and second kind of slurries is 2.At 130 ℃ of mixed slurries of oven dry, and, obtain composite alumina A1 850 ℃ of roastings 6 hours.Table 1 has provided specific surface and the pore volume of A1.Table 2 has provided the composition of A1.Specific surface and pore volume adopt cryogenic nitrogen absorption BET method to measure, and form to be got by calculating.
Comparative Examples 1
This Comparative Examples explanation prior art composite alumina preparation method.
In 1000 milliliters of three-necked bottles, add and add 9.47 gram lanthanum concentrate rare earth chlorides (specification is with example 1), 21.65 gram cerous chlorates (specification is with example 1) and 23.55 gram zirconium oxychlorides (specification is with example 1) under 400 ml deionized water, the stirring, make it to dissolve fully.Add ammoniacal liquor under the room temperature, adjust its pH=11, treat that precipitation fully after, be warming up to 80 ℃, aging slurries are 6 hours under this temperature, filter, washing gained filter cake is not to there being acid group, the mixture of auxiliary agent hydroxide is stand-by.
Get 110.68 gram boehmites (specification is with example 1) and add deionized water, stirred 30 minutes, being made into solid content is the slurries of 19 heavy %, and the pH value that adds 1: 1 hydrochloric acid (chemical pure, the Beijing Chemical Plant produces) adjustment slurries is 3.5; The mixture that adds the auxiliary agent hydroxide of above-mentioned preparation; Under agitation continue to add 110.68 gram boehmites (specification is with example 1) and 18.94 gram aluminium colloidal sols (alumina content is 22 heavy %, and the Shandong catalyst plant is produced), continue to stir, make slurries be uniform colloid shape.50 ℃ aging 1.5 hours, 130 ℃ of oven dry, 850 ℃ of roasting temperatures 6 hours make reference composite alumina B1.Table 1 has provided specific surface and the pore volume of B1.Table 2 has provided the composition of B1
Example 2
The preparation method of this example explanation composite alumina.
Method by example 1 prepares composite alumina, different is when first kind of slurries of preparation, the temperature of making beating is 40 ℃, and taking out first kind of slurries is 40 ℃ also with the temperature that hydrochloric acid adjusting slurry pH value and first kind of slurries mix with second kind of slurries, obtains composite alumina A1a.Table 1 has provided specific surface and the pore volume of composite alumina A1a.Table 2 has provided the composition of A1a.
Example 3
The preparation method of this example explanation composite alumina.
Method by example 1 prepares composite alumina, different is when first kind of slurries of preparation, the temperature of making beating is 60 ℃, and taking out first kind of slurries is 60 ℃ also with the temperature that hydrochloric acid adjusting slurry pH value and first kind of slurries mix with second kind of slurries, obtains composite alumina A1b.Table 1 has provided specific surface and the pore volume of composite alumina A1b.Table 2 has provided the composition of A1b
Example 4
The preparation method of this example explanation composite alumina.
Method by example 1 prepares composite alumina, and the temperature of last roasting that different is is 750 ℃, obtains composite alumina A1c.Table 1 has provided specific surface and the pore volume of composite alumina A1c.Table 2 has provided the composition of A1c
Example 5
The preparation method of this example explanation composite alumina.
Method by example 1 prepares composite alumina, and the consumption of different is lanthanum concentrate rare earth chloride is 25.256 grams, and the boehmite consumption is 218.75 grams.Alumina content is 44.1 heavy % in the first kind of slurries that obtains, the auxiliary agent oxide content is 20.9 heavy %, 50% of first kind of slurries gross weight that taking-up obtains, the pH value that adds nitric acid adjusting slurries in room temperature with under stirring is 3.0, obtain second kind of slurries, the weight ratio of first kind of slurries and second kind of slurries is 1.Obtain composite alumina A2.Table 1 has provided specific surface and the pore volume of A2.Table 2 has provided the composition of A2
Comparative Examples 2
The preparation method of this Comparative Examples explanation prior art composite alumina.
In 1000 milliliters of three-necked bottles, add 400 ml deionized water, stir the 23.55 gram zirconium oxychlorides (specification is with example 1) of adding down, 25.256 gram lanthanum concentrate rare earth chlorides (specification is with example 1) and 31.86 gram ammonium ceric nitrate [(NH
4)
2Ce (NO
3)
6, be equivalent to cerium oxide 10 grams, chemical pure, the Beijing Chemical Plant produces], make it to dissolve fully.Add ammoniacal liquor under the room temperature, adjust the pH=11 of slurries, treat that precipitation fully after, be warming up to 80 ℃, aging slurries are 6 hours under this temperature, filter, washing gained filter cake is not to there being acid group, the mixture of auxiliary agent hydroxide is stand-by.
Get 103.30 gram boehmites (specification is with example 1) and add deionized water, stirred 30 minutes, being made into solid content is the slurries of 19 heavy %, and adding 1: 1 hydrochloric acid (chemical pure, the Beijing Chemical Plant produces) adjustment pH value is 3.5; The mixture that adds the auxiliary agent hydroxide of above-mentioned preparation; Under agitation continue to add 103.30 gram boehmites (specification is with example 1) and 17.68 gram aluminium colloidal sols (specification is with Comparative Examples 1), continue to stir, make slurries be uniform colloid shape.50 ℃ aging 1.5 hours, 130 ℃ of oven dry, 850 ℃ of roasting temperatures 6 hours make reference composite alumina B2.Table 1 has provided specific surface and the pore volume of B2.Table 2 has provided the composition of B2
Example 6
The preparation method of this example explanation composite alumina.
Method by example 1 prepares composite alumina, the consumption of different is lanthanum concentrate rare earth chloride is that 31.57 grams, cerous chlorate consumption are that 32.48 grams, zirconium oxychloride consumption are that 39.25 grams, boehmite consumption are 562.5 grams, alumina content is 51.1 heavy % in the first kind of slurries that obtains, the auxiliary agent oxide content is 13.9 heavy %, 75% of first kind of slurries gross weight that taking-up obtains, the hydrochloric acid that under room temperature and stirring, adds 20 heavy %, the pH value of regulating slurries is 2.5, obtain second kind of slurries, the weight ratio of first kind of slurries and second kind of slurries is 0.33.Obtain composite alumina A3.Table 1 has provided specific surface and the pore volume of A3.Table 2 has provided the composition of A3
Comparative Examples 3
The preparation method of this Comparative Examples explanation prior art composite alumina.
In 1000 milliliters of three-necked bottles, add and add 31.57 gram lanthanum concentrate rare earth chlorides (specification is with example 1), 32.48 gram cerous chlorates (specification is with example 1) and 39.25 gram zirconium oxychlorides (specification is with example 1) under 400 ml deionized water, the stirring, make it to dissolve fully.Add ammoniacal liquor under the room temperature, adjust its pH=11, treat that precipitation fully after, be warming up to 80 ℃, aging slurries are 6 hours under this temperature, filter, washing gained filter cake is not to there being acid group, the mixture of auxiliary agent hydroxide is stand-by.
Get 265.625 gram boehmites (specification is with example 1) and add deionized water, stirred 30 minutes, being made into solid content is the slurries of 19 heavy %, and the pH value that adds 1: 1 hydrochloric acid (chemical pure, the Beijing Chemical Plant produces) adjustment slurries is 3.5; The mixture that adds the auxiliary agent hydroxide of above-mentioned preparation; Under agitation continue to add 265.625 gram boehmites (specification is with example 1) and 45.45 gram aluminium colloidal sols (specification is with Comparative Examples 1), continue to stir, make slurries be uniform colloid shape.50 ℃ aging 1.5 hours, 130 ℃ of oven dry, 850 ℃ of roasting temperatures 6 hours make reference composite alumina B3.Table 1 has provided specific surface and the pore volume of B3.Table 2 has provided the composition of B3
Example 7
The preparation method of this example explanation composite alumina.
Method by example 1 prepares composite alumina, different is not add lanthanum concentrate rare earth chloride and zirconium oxychloride, the cerous chlorate consumption is 38.97 grams, the boehmite consumption is 256.25 grams, alumina content is 53.3 heavy % in the first kind of slurries that obtains, the auxiliary agent oxide content is 11.7 heavy %, obtains composite alumina A4.Table 1 has provided specific surface and the pore volume of A4.Table 2 has provided the composition of A4
Example 8
The preparation method of this example explanation composite alumina.
Method by example 1 prepares composite alumina, different is not add lanthanum concentrate rare earth chloride, the cerous chlorate consumption is that 34.64 grams, zirconium oxychloride consumption are that 31.40 grams, boehmite consumption are 212.5 grams, alumina content is 44.2 heavy % in the first kind of slurries that obtains, the auxiliary agent oxide content is 20.8 heavy %,, obtain composite alumina A5.Table 1 has provided specific surface and the pore volume of A5.Table 2 has provided the composition of A5
Table 1
| Example number | Composite alumina | Specific surface, rice 2/ gram | Pore volume, milliliter/gram |
| ??1 | ????A1 | ????135 | ????0.35 |
| Comparative Examples 1 | ????B1 | ????124 | ????0.28 |
| ??2 | ????A1a | ????137 | ????0.36 |
| ??3 | ????A1b | ????138 | ????0.34 |
| ??4 | ????A1c | ????142 | ????0.37 |
| ??5 | ????A2 | ????141 | ????0.37 |
| Comparative Examples 2 | ????B2 | ????130 | ????0.29 |
| ??6 | ????A3 | ????146 | ????0.38 |
| Comparative Examples 3 | ????B3 | ????136 | ????0.31 |
| ??7 | ????A4 | ????148 | ????0.39 |
| ??8 | ????A5 | ????139 | ????0.34 |
The result of table 1 shows, the present invention adopts very simple method, but can prepare to have the more composite alumina of Large ratio surface and pore volume.
Table 2
| Example number | Composite alumina | Alumina content, heavy % | Auxiliary agent kind and content, heavy % (in oxide) |
| ??1 | ????A1 | ????74.1 | La.3.0; Ce10.0; Zr8.9; Y3.0; Other rare earth oxides 1.0 |
| Comparative Examples 1 | ????B1 | ????74.1 | La.3.0; Ce10.0; Zr8.9; Y3.0; Other rare earths 1.0 |
| ??2 | ????A1a | ????74.1 | La.3.0; Ce10.0; Zr8.9; Y3.0; Other rare earths 1.0 |
| ??3 | ????A1b | ????74.1 | La.3.0; Ce10.0; Zr8.9; Y3.0; Other rare earths 1.0 |
| ??4 | ????A1c | ????74.1 | La.3.0; Ce10.0; Zr8.9; Y3.0; Other rare earths 1.0 |
| ??5 | ????A2 | ????67.9 | La.7.8; Ce9.9; Zr8.7; Y2.9; Other rare earths 2.8 |
| Comparative Examples 2 | ????B2 | ????67.9 | La.7.8; Ce9.9; Zr8.7; Y2.9; Other rare earths 2.8 |
| ??6 | ????A3 | ????78.6 | La.4.4; Ce6.7; Zr6.6; Y2.2; Other rare earths 1.5 |
| Comparative Examples 3 | ????B3 | ????78.6 | La.4.4; Ce6.7; Zr6.6; Y2.2; Other rare earths 1.5 |
| ??7 | ????A4 | ????82.0 | Ce18.0 |
| ??8 | ????A5 | ????68.0 | Ce16.0；Zr12.0；Y4.0 |
Example 9
This example illustrates the preparation method of exhaust gas purifying catalyst provided by the invention.
With the composite alumina A1 of the 13.5 milliliters of platinum acid chloride solutions dipping that contains Pt 0.02082 grams per milliliter 30 gram examples, 1 preparation, under 120 ℃ of temperature dry 2 hours then, and, make base coating material X1 600 ℃ of roasting temperatures 2 hours.The composition of X1 is listed in the table 3.
Place ball mill to make the slurries that solid content is 30.2 heavy % in 4 hours the X1 that all makes with 70 gram deionized water mixing wet-millings.With external diameter is that 20 millimeters, length are 33 millimeters, the sectional area cordierite honeycomb carrier that contains 0.65 millimeter of 400 airflow hole, wall thickness immerses in these slurries per square inch, from slurries, take out again, after blowing away slurries unnecessary in the hole with compressed air, 120 ℃ of dryings 4 hours, 850 ℃ of roastings 6 hours.Make catalyst C1.Contain 117 gram composite aluminas and 1.0 gram platinum among every liter of catalyst C1.
Comparative Examples 4
The preparation method of this Comparative Examples explanation reference exhaust gas purifying catalyst.
Method by example 9 prepares base coating material and exhaust gas purifying catalyst, and different is to replace A1 with the reference composite alumina B1 that Comparative Examples 1 prepares, and makes reference base coating material XB1 and reference catalyst CB1.The composition of XB1 is listed in the table 3.Contain 117 gram composite aluminas and 1.0 gram platinum among every liter of catalyst CB1.
Example 10-11
Following example illustrates the preparation method of exhaust gas purifying catalyst provided by the invention.
Method by example 9 prepares base coating material X2-X3 and catalyst C2-C3.Different is that the composite alumina A1a and the A1b that prepare with example 2 and example 3 respectively replace composite alumina A1.The composition of base coating material X2-X3 is listed in the table 3.All contain 117 gram composite aluminas and 1.0 gram platinum among every liter of catalyst C2 and the C3.
Example 12
This example illustrates the preparation method of exhaust gas purifying catalyst provided by the invention.
Method by example 9 prepares base coating material and catalyst, and different is to substitute 13.5 milliliters of platinum acid chloride solutions that contain Pt 0.02082 grams per milliliter with 13.5 milliliters of palladium chloride solutions that contain the Pd0.04089 grams per milliliter, and the consumption of composite alumina A1 is 32 grams.Obtain base coating material X4 and catalyst C4.The composition of base coating material X4 is listed in the table 2.Wherein, the solid content that contains the slurries of base coating material is 31.8 heavy %.Every liter contains 117 gram composite aluminas among the catalyst C4,2.0 gram palladiums.
Example 13
This example illustrates the preparation method of exhaust gas purifying catalyst provided by the invention.
With 13.5 milliliters of composite alumina A1 that contain palladium chloride solution dipping 32 gram examples 1 preparation of Pd 0.04089 grams per milliliter, under 120 ℃ of temperature dry 2 hours then, and 600 ℃ of roasting temperatures 2 hours, again with 13.5 milliliters of rhodium chloride solution dippings that contain Rh 0.0041 grams per milliliter, under 120 ℃ of temperature dry 2 hours then, and, obtain base coating material X5 600 ℃ of roasting temperatures 2 hours.The composition of base coating material X5 is listed in the table 3.
Place ball mill to mix with 70 gram deionized waters the X5 that all makes, wet-milling made the slurries that solid content is 31.8 heavy % in 4 hours.With external diameter is that 20 millimeters, length are 33 millimeters, and sectional area contains 400 airflow holes per square inch, and the cordierite honeycomb carrier that wall thickness is 0.65 millimeter immerses in these slurries.From slurries, take out again, blow away slurries unnecessary in the hole with compressed air after, 120 ℃ of dryings 4 hours, 850 ℃ of roastings 6 hours.Make catalyst C5.Contain 117 gram composite aluminas among every liter of catalyst C5,2.0 gram palladiums and 0.2 gram rhodium.
Example 14
This example illustrates the preparation method of exhaust gas purifying catalyst provided by the invention.
With 13.5 milliliters of composite alumina A1 that contain chloroplatinic acid aqueous solution dipping 30 gram examples 1 preparation of Pt 0.02074 grams per milliliter, under 120 ℃ of temperature dry 2 hours then, and 600 ℃ of roasting temperatures 2 hours, again with 13.5 milliliters of rhodium chloride solution dippings that contain Rh 0.0021 grams per milliliter, under 120 ℃ of temperature dry 2 hours then, and 600 ℃ of roasting temperatures 2 hours, base coating material X6.The composition of base coating material X6 is listed in the table 3.
Place ball mill to mix (predetermined amounts) wet-milling the X6 that all makes and made the slurries that solid content is 30.2 heavy % in 4 hours with 70 gram deionized waters.With external diameter is that 20 millimeters, length are 33 millimeters, and sectional area contains 400 airflow holes per square inch, and the cordierite honeycomb carrier that wall thickness is 0.65 millimeter immerses in these slurries.From slurries, take out again, blow away slurries unnecessary in the hole with compressed air after, 120 ℃ of dryings 4 hours, 850 ℃ of roastings 6 hours.Make catalyst C6.Contain 117 gram modified aluminas and 1.0 gram platinum and 0.1 gram rhodium among every liter of catalyst C6.
Example 15-16
Following example illustrates the preparation method of exhaust gas purifying catalyst provided by the invention.
Method by example 9 prepares base coating material and exhaust gas purifying catalyst, and different is that the composite alumina A2 and the A3 that prepare with example 5 and example 6 respectively replace A1, makes base coating material X7 and X8 and catalyst C7 and C8.The composition of X7 and X8 is listed in the table 3.Contain 117 gram composite aluminas and 1.0 gram platinum among every liter of catalyst C7.Contain 117 gram composite aluminas and 1.0 gram platinum among every liter of catalyst C8.
Comparative Examples 5-6
The preparation method of following Comparative Examples explanation reference exhaust gas purifying catalyst.
Method by example 15-16 prepares base coating material and exhaust gas purifying catalyst, different is that the reference composite alumina B2 and the B3 that prepare with Comparative Examples 2 and Comparative Examples 3 respectively replace A2 and A3, makes reference base coating material XB2 and XB3 and reference catalyst CB2 and CB3.The composition of XB2 and XB3 is listed in the table 3.Contain 117 gram composite aluminas and 1.0 gram platinum among every liter of reference catalyst CB2.Contain 117 gram composite aluminas and 1.0 gram platinum among every liter of reference catalyst CB3.
Example 17-18
Following example illustrates the preparation method of exhaust gas purifying catalyst provided by the invention.
Method by example 9 prepares base coating material and exhaust gas purifying catalyst, and different is that the composite alumina A4 and the A5 that prepare with example 7 and example 8 respectively replace A1, makes base coating material X9 and X10 and catalyst C9 and C10.The composition of X9 and X10 is listed in the table 3.Contain 117 gram composite aluminas and 1.0 gram platinum among every liter of catalyst C9.Contain 117 gram composite aluminas and 1.0 gram platinum among every liter of catalyst C10.
Table 3
| Example number | The base coating material numbering | The composite alumina kind | Composite alumina content, heavy % | Platinum content, heavy % | Palladium content, heavy % | Rhodium content, heavy % |
| 9 | ????X1 | ????A1 | ?????99.06 | ????0.94 | ???- | ?????- |
| Comparative Examples 4 | ????XB1 | ????B1 | ?????99.06 | ????0.94 | ???- | ?????- |
| 10 | ????X2 | ????A1a | ?????99.06 | ????0.94 | ???- | ?????- |
| 11 | ????X3 | ????A1b | ?????99.06 | ????0.94 | ???- | ?????- |
| 12 | ????X4 | ????A1 | ?????98.27 | ????- | ???1.73 | ?????- |
| 13 | ????X5 | ????A1 | ?????98.10 | ????- | ???1.73 | ?????0.17 |
| 14 | ????X6 | ????A1 | ?????98.97 | ????0.93 | ???- | ?????0.10 |
| 15 | ????X7 | ????A2 | ?????99.06 | ????0.94 | ???- | ?????- |
| Comparative Examples 5 | ????XB2 | ????B2 | ?????99.06 | ????0.94 | ???- | ?????- |
| 16 | ????X8 | ????A3 | ?????99.06 | ????0.94 | ???- | ?????- |
| Comparative Examples 6 | ????XB3 | ????B3 | ?????99.06 | ????0.94 | ???- | ?????- |
| 17 | ????X9 | ????A4 | ?????99.06 | ????0.94 | ???- | ?????- |
| 18 | ????X10 | ????A5 | ?????99.06 | ????0.94 | ???- | ?????- |
Example 19-28
Following example illustrates the catalytic performance of the exhaust gas purifying catalyst of method preparation provided by the invention.
With the catalyst C1-C10 of example 9-18 preparation respectively the monoblock internal diameter of packing into be in 30 millimeters the quartz tube reactor, with the slit between expansion block sealed silica envelope reactor and the catalyst, CO, HC, NO in the vehicle exhaust during analog theory air-fuel ratio
xConcentration, preparation contains CO 9000ppm, H
22000ppm, HC600ppm, CO
210800ppm, NO
x900ppm, O
2The mist of 16000ppm and surplus nitrogen is the exhaust-gas purifying performance of reaction raw materials evaluate catalysts with this mist.This mist was with 12000 hours
-1Volume space velocity by quartz tube reactor, from room temperature temperature programming to 500 ℃, 20 ℃ of assaying reaction devices of every intensification exit generates CO, HC and the NO in the gas to quartz tube reactor with 11 ℃/minute speed
xThe change in concentration value, then, calculate the purifying rate of pernicious gas according to following formula.
With the function construction of purifying rate as purification temperature, the purification temperature T when trying to achieve purifying rate 50%
50Value, this value can be used as the standard of evaluation catalyst to exhaust-gas purifying performance.The T of the catalyst C1-C10 of the present invention that according to said method records
50And CO, HC, NO during temperature programming to 350 ℃
xPurifying rate list in the table 4.
Material concentration is by following Instrument measuring in the generation gas of reactor exit:
Carbon monoxide (CO): QGS-08B type CO infrared spectrum analyser, Sino-German co-partnership company of Beijing Analytical Instrument Factory;
Carbon dioxide (CO
2): QGS-08B type CO
2Infrared spectrum analyser, Sino-German co-partnership company of Beijing Analytical Instrument Factory;
Oxygen: (O
2) GXH-500 type O
2Analyzer, Sino-German co-partnership company of Beijing Analytical Instrument Factory;
Hydrocarbon (HC) 3110 RES type exhaust-gas analyzers, Japan produces;
Nitrogen oxide (NO
x) Mode1-10 type chemiluminescence NO
xAnalyzer, U.S. Thermo Electron Corp..
Comparative Examples 7-9
The catalytic performance of following Comparative Examples explanation reference catalyst.
Press the activity of the method evaluate catalysts of example 19-28, the results are shown in Table 4 for the reference catalyst CB1-CB3 of Comparative Examples 4-6 preparation for different just catalyst system therefors.
Table 4
| Example number | The catalyst numbering | Initial activity | |||||
| ???????????T 50，℃ | 350 ℃ purifying rate, heavy % | ||||||
| ??CO | ????HC | ????NO x | ????CO | ????HC | ????NO x | ||
| 19 | ????C1 | ??170 | ????189 | ????190 | ????99 | ????98 | ????98 |
| Comparative Examples 7 | ????CB1 | ??227 | ????257 | ????240 | ????92 | ????88 | ????73 |
| 20 | ????C2 | ??172 | ????189 | ????192 | ????100 | ????100 | ????100 |
| 21 | ????C3 | ??169 | ????190 | ????191 | ????100 | ????99 | ????99 |
| 22 | ????C4 | ??170 | ????190 | ????189 | ????100 | ????99 | ????100 |
| 23 | ????C5 | ??165 | ????189 | ????167 | ????100 | ????100 | ????100 |
| 24 | ????C6 | ??170 | ????191 | ????172 | ????100 | ????100 | ????100 |
| 25 | ????C7 | ??169 | ????189 | ????190 | ????100 | ????100 | ????100 |
| Comparative Examples 8 | ????CB2 | ??221 | ????250 | ????238 | ????95 | ????96 | ????93 |
| 26 | ????C8 | ??178 | ????194 | ????195 | ????100 | ????100 | ????99 |
| Comparative Examples 9 | ????CB3 | ??224 | ????258 | ????248 | ????85 | ????87 | ????80 |
| 27 | ????C9 | ??180 | ????195 | ????196 | ????98 | ????97 | ????98 |
| 28 | ????C10 | ??178 | ????192 | ????197 | ????100 | ????98 | ????98 |
The result of table 4 shows that exhaust gas purifying catalyst provided by the invention has higher exhaust-gas purifying performance, illustrates that the exhaust gas purifying catalyst of method preparation provided by the invention has more high catalytic activity.
Claims (24)
1. preparation method who contains the exhaust gas purifying catalyst of noble metal, this method comprises with a kind of composite alumina of solution impregnation that contains noble metal, dry also roasting, obtain a kind of base coating material, the slurries that will contain described base coating material are coated on a kind of carrier, dry also roasting, it is characterized in that, the preparation method of described composite alumina comprises the aqueous solution making beating of the salt of boehmite and auxiliary agent even, obtaining alumina content is the heavy % of 10-60, and the auxiliary agent oxide content is first kind of slurries of the heavy % of 5-40; With the aqueous solution making beating of the salt of boehmite and auxiliary agent evenly, add pH value that acid regulates slurries to 0.5-5.5, obtaining alumina content is the heavy % of 10-60, and the auxiliary agent oxide content is second kind of slurries of the heavy % of 5-40; First kind of slurries and the second kind of slurries weight ratio by 0.1-10 is mixed dry and slurries that roasting obtains; Described auxiliary agent is selected from one or more in rare earth element, zirconium, yttrium, magnesium, chromium, manganese, iron, cobalt, the nickel.
2. method according to claim 1 is characterized in that described auxiliary agent is selected from one or more in rare earth element, zirconium, the yttrium.
3. method according to claim 1 is characterized in that, the salt of described auxiliary agent is selected from the nitrate of rare earth element, zirconium, yttrium, magnesium, chromium, manganese, iron, cobalt, nickel and in the chloride one or more.
4. method according to claim 3 is characterized in that the salt of described auxiliary agent is selected from the chloride of nitrate of rare earth element, rare earth element, one or more in the nitrate of zirconium oxychloride, zirconyl nitrate, yttrium and the chloride of yttrium.
5. according to any described method among the claim 1-4, it is characterized in that described rare earth element is selected from the mixture of lanthanum, cerium or rare earth element.
6. method according to claim 1 is characterized in that, the alumina content in first kind of slurries and the second kind of slurries is the heavy % of 30-60; The auxiliary agent oxide content is the heavy % of 5-35.
7. method according to claim 1 is characterized in that, the used acid of adjusting pH value is one or more in hydrochloric acid, nitric acid, the citric acid.
8. method according to claim 1 is characterized in that the pH value of second kind of slurries is 2-5.
9. method according to claim 1 is characterized in that, the weight ratio of first kind of slurries and second kind of slurries is 0.2-4.
10. method according to claim 1 is characterized in that with the aqueous solution making beating of the salt of boehmite and auxiliary agent and the temperature that adds acid for adjusting pH value be room temperature to 90 ℃.
11. method according to claim 10 is characterized in that with the aqueous solution making beating of the salt of boehmite and auxiliary agent and the temperature that adds acid for adjusting pH value be room temperature to 70 ℃.
12. method according to claim 1 is characterized in that temperature that first kind of slurries mixes with second kind of slurries is a room temperature to 90 ℃.
13. method according to claim 12 is characterized in that temperature that first kind of slurries mixes with second kind of slurries is a room temperature to 70 ℃.
14. preparation method who contains the exhaust gas purifying catalyst of noble metal, this method comprises with a kind of composite alumina of solution impregnation that contains noble metal, dry also roasting, obtain a kind of base coating material, the slurries that will contain described base coating material are coated on a kind of carrier, dry also roasting, it is characterized in that, the preparation method of described composite alumina comprises the aqueous solution making beating of the salt of boehmite and auxiliary agent even, obtaining alumina content is the heavy % of 10-60, and the auxiliary agent oxide content is first kind of slurries of the heavy % of 5-40; Take out first kind of slurries that part obtains, add pH value that acid regulates slurries, obtain second kind of slurries, first kind of slurry and the weight ratio of second kind of slurries by 0.1-10 are mixed the slurries that dry also roasting obtains to 0.5-5; Described auxiliary agent is selected from one or more in rare earth element, zirconium, yttrium, magnesium, chromium, manganese, iron, cobalt, the nickel.
15., it is characterized in that the temperature of the drying of dipping behind the noble metal is a room temperature to 300 ℃ according to claim 1 or 14 described methods, be more than 0.5 hour drying time, sintering temperature is that 400-700 ℃ of roasting time is more than 0.5 hour.
16. method according to claim 15 is characterized in that, the temperature of the drying behind the dipping noble metal is 100-200 ℃, and be 1-10 hour drying time, and sintering temperature is 450-650 ℃, and roasting time is 1-10 hour.
17., it is characterized in that according to claim 1 or 14 described methods, be benchmark with the total amount of base coating material, in precious metal simple substance, it is the heavy % of 0.1-30 that the described solution usage that contains noble metal makes the content of the noble metal in the base coating material.
18. method according to claim 17 is characterized in that, it is the heavy % of 0.1-15 that the described solution usage that contains noble metal makes the content of the noble metal in the base coating material.
19. method according to claim 18 is characterized in that, it is the heavy % of 0.1-5 that the described solution usage that contains noble metal makes the content of the noble metal in the base coating material.
20., it is characterized in that described noble metal is selected from one or more in platinum, palladium, rhodium, osmium, iridium, the ruthenium according to claim 1 or 14 described methods.
21. method according to claim 20 is characterized in that, described noble metal is selected from one or more in platinum, palladium, the rhodium.
22., it is characterized in that the described solid content that contains the slurries of base coating material is the heavy % of 10-50 according to claim 1 or 14 described methods.
23. method according to claim 22 is characterized in that, the described solid content that contains the slurries of base coating material is the heavy % of 20-40.
24., it is characterized in that after the slurries that will contain base coating material were coated on the carrier, baking temperature was 100-300 ℃ according to claim 1 or 14 described methods, be 1-10 hour drying time; Sintering temperature is 300-900 ℃, and roasting time is 1-10 hour.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102861594A (en) * | 2011-07-07 | 2013-01-09 | 中国石油化工股份有限公司 | Coating slurry, preparation method and application thereof |
| CN113649079A (en) * | 2020-05-12 | 2021-11-16 | 中国石油化工股份有限公司 | Titanium oxide-aluminum oxide composite carrier and preparation method and application thereof |
| CN114849697A (en) * | 2022-05-23 | 2022-08-05 | 东风汽车集团股份有限公司 | Catalyst based on three-way catalyst ceramic carrier and preparation method thereof |
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|---|---|---|---|---|
| CN102000599B (en) * | 2010-11-09 | 2012-07-04 | 中国海洋石油总公司 | Preparation method of catalyst for deeply desorbing trace olefins in aromatic hydrocarbon |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102861594A (en) * | 2011-07-07 | 2013-01-09 | 中国石油化工股份有限公司 | Coating slurry, preparation method and application thereof |
| CN102861594B (en) * | 2011-07-07 | 2014-12-31 | 中国石油化工股份有限公司 | Coating slurry, preparation method and application thereof |
| CN113649079A (en) * | 2020-05-12 | 2021-11-16 | 中国石油化工股份有限公司 | Titanium oxide-aluminum oxide composite carrier and preparation method and application thereof |
| CN113649079B (en) * | 2020-05-12 | 2023-10-10 | 中国石油化工股份有限公司 | Titanium oxide-aluminum oxide composite carrier and preparation method and application thereof |
| CN114849697A (en) * | 2022-05-23 | 2022-08-05 | 东风汽车集团股份有限公司 | Catalyst based on three-way catalyst ceramic carrier and preparation method thereof |
| CN114849697B (en) * | 2022-05-23 | 2023-10-27 | 东风汽车集团股份有限公司 | Catalyst based on three-way catalyst ceramic carrier and preparation method thereof |
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