CN1434071A - Total biodegraded thermoplastic starch resin - Google Patents
Total biodegraded thermoplastic starch resin Download PDFInfo
- Publication number
- CN1434071A CN1434071A CN 03117398 CN03117398A CN1434071A CN 1434071 A CN1434071 A CN 1434071A CN 03117398 CN03117398 CN 03117398 CN 03117398 A CN03117398 A CN 03117398A CN 1434071 A CN1434071 A CN 1434071A
- Authority
- CN
- China
- Prior art keywords
- starch
- resin
- thermoplastic starch
- complete biodegradable
- biodegradable thermoplastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The composition of total-biodegraded thermoplastic starch resin includes (by weight portion) starch 50.0-75.0, blend A 5.0-20.0, blend B 10.0-20.0 graft modifier 1.0-5.0, chemical initiator 0.1-1.0, plasticizer 2.0-10.0, covering agent 0.3-3.0 and antioxidant 0.1-2.0, in which the blend A is one kind of more than one kind of thermoplastic resin, and the blend B is one kind of more than one kind of cellulose, polyvinyl alcohol, polyglycolic acid and polyester, and its graft modifier is one or more than one kind of long-chain unsaturated carboxylic acid and its ester. It can be directly used for making various tableware, cup, disk, film and package products, etc.
Description
Technical field
The present invention relates to a kind of degradative resin, particularly relate to a kind of complete biodegradable thermoplastic starch resin.
Background technology
Plastics are one of most widely used materials, and a large amount of waste plastic products is made the face severe contamination to ecotope, and the development and application of degradative plastics is one of valid approach of this problem.What come into operation at present mainly is starch filled plastic and starch plastics, and starch content is low in these class degradative plasticss, is generally 10%～30%, and degradation property and poor mechanical property fundamentally do not solve " white pollution " problem.For overcoming above-mentioned deficiency, people begin starch plastics is carried out improved perfect, improve starch content and mechanical property in the goods.Chinese patent 1296988 discloses a kind of production method of biodegradable starch resin with high content of starch, its raw material comprises starch 65～75%, the attached thing of forming by polyvalent alcohol, polyprotonic acid and fatty cpd 25～35% of joining, ethylene-propylene copolymer 15～25%, and coupling agent, expanding material etc.Though this kind resin starch content is higher, but can not directly be used for making plastics, adding also needs to use with other processing characteristics, mixed with resin that mechanical property is good man-hour, could satisfy the processing characteristics and the mechanical property of plastics, so just greatly reduce contents of starch in the plastics, make that starch content only is about 35% in its plastics, only can partly degrade.Can not satisfy the effect requirement.
Summary of the invention
The object of the present invention is to provide a kind of starch content height, and good processability, the biodegradability excellence, and can directly be used for making the complete biodegradable thermoplastic starch resin of plastics.
The component of complete biodegradable thermoplastic starch resin of the present invention is by weight: starch 50.0～75.0, intermingling material A 5.0～20.0, intermingling material B 10.0～20.0, graft modification thing 1.0～5.0, chemical initiator 0.1～1.0, softening agent 2.0～10.0, coating 0.5～3.0, oxidation inhibitor 0.1～2.0.Wherein, intermingling material A is one or more in the thermoplastic resin, as polyethylene (PE), polypropylene (PP), polyethylene elastomer body (POE), α butene random copolymer (APA0) etc.Be mainly used in the thermoplasticity that improves material; Intermingling material B is one or more in cellulose family, polyvinyl alcohol (PVA), polyglycolic acid (PGA) class and polyester such as the polycaprolactone (PCL) etc.Be mainly used in the water resisting property and the biological degradability that improve material; The graft modification thing is one or more in long-chain unsaturated carboxylic acid and the ester class thereof, as hendecene base Succinic anhydried, dodecenylsuccinic acid ester, hendecene base Succinic anhydried, octadecenic acid etc.Be mainly used in the tensile strength that improves starch, elongation at break etc.; And fineness 〉=2000 orders of control starch, be generally 2000～3000 orders, can be W-Gum, wheat starch, pea starch, tapioca (flour) etc.; Chemical initiator is a kind of in the organo-peroxide, as dicumyl peroxide (DCP), benzoyl peroxide (BPO), ditertiary butyl peroxide ((DTBP) and lauroyl peroxide etc.Be used for causing the generation active centre; Softening agent is one or more in the polyol ester class.As adipic acid dibutylester, hexanodioic acid two (2-ethylhexyl) ester (DOA) dibutyl phthalate etc.; Coating is one or more in acid anhydrides or the organosilane ester.As maleic anhydride (MA), glycidyl methacrylate, titanic acid ester, phosphide ester etc., be used to eliminate the polarity and the crystallization of starch; Oxidation inhibitor is one or more in Hinered phenols or the hindered amines.As DI-tert-butylphenol compounds, 246,264, antioxidant A, antioxidant d, antioxidant A P, antioxidant H etc., prevent oxidation of starch in the processing.
The advantage of complete biodegradable thermoplastic starch resin of the present invention is the biological degradability excellence, and degraded has controllability, reduces environmental pollution, helps ecological environmental protection.Adopt combinatorial chemistry modification and crystalline region heat to melt processing, thoroughly eliminate the crystallization and the polarity of native starch, make its molecular structure realize randomization, improve starch thermoplastic resin performance and mechanical strength, and the technological process of production is brief, investment and production cost are low.Need not add other resin during use, improve contents of starch in the product, more help biological degradation, can be used for making all types of plastic goods, various tablewares, cup dish, film, packing bag, shopping bag etc.
Embodiment
Embodiment 1:
Component and consumption (by weight)
W-Gum 50.0
Polyethylene 15.0
Mierocrystalline cellulose 10.0
Hendecene base fourth diester acid anhydride 5.0
DCP??????????????????????????????????0.5
Polycizer W 260 10.0
Methacrylic ester glycidyl ester 0.5
DI-tert-butylphenol compounds 1.0
Earlier starch is carried out ultrafining treatment, making its fineness is that 2000 orders sieve, add methacrylic ester glycidyl ester simultaneously, so 100～150 ℃ of following heat are melted processing, enter then in the high-speed mixer, melt good and contain Polycizer W 260, DCP, polyethylene and cellulosic blend uniform mixing, reacted about 15 minutes with hot, it is mixing to join the second order forcing machine again, and extruding pelletization gets the present invention.Performance test results is as shown in table 1.
Embodiment 2:
Component and consumption (by weight)
Tapioca (flour) 60.0
POE??????????????????????????????????8.0
Poly-second lactone 30.0
Laurostearic acid alkenyl succinic acid ester 1.0
DTBP?????????????????????????????????0.1
Hexanodioic acid two (2-ethylhexyl) ester 6.0
Maleic anhydride 3.0
246??????????????????????????????????0.1
Its preparation method is with embodiment 1.Performance test results is as shown in table 1.
Embodiment 3:
Component and consumption (by weight)
Pea starch 70.0
Polypropylene 5.0
Polyvinyl alcohol 20.0
Octadecenic acid 3.0
BPO??????????????????????????????????0.8
Dibutyl phthalate 2.0
Titanic acid ester 1.5
Antioxidant H 2.0
Its preparation method is with embodiment 1.Performance test results is as shown in table 1.
Table 1: product performance detect as follows
| The goods starch content | ????≥10％ | ?????50％ | |
| Product tensile strength | ????≥10Mpa | ????≥12Mpa | |
| The goods elongation at break | ????≥100％ | ????≥300％ | |
| Degradation property | Mass loss rate | ????≥10％ | ????≥80％ |
| The loss of tensile strength rate | ????≥20％ | ????≥80％ | |
| The extension at break rate of loss | ????≥70％ | ????≥95％ | |
Claims (6)
1, a kind of complete biodegradable thermoplastic starch resin is characterized in that component is as follows by weight:
Starch 50.0～75.0
Intermingling material A 5.0～20.0
Intermingling material B 10.0～20.0
Graft modification thing 1.0～5.0
Chemical initiator 0.1～1.0
Softening agent 2.0～10.0
Coating 0.5～3.0
Oxidation inhibitor 0.1～2.0
Wherein, intermingling material A is one or more in the thermoplastic resin, intermingling material B is one or more in cellulose family, polyvinyl alcohol, polyglycolic acid class and the polyester, and the graft modification thing is one or more in long-chain unsaturated carboxylic acid and the ester class thereof.
2 complete biodegradable thermoplastic starch resins as claimed in claim 1 is characterized in that the fineness of starch is 〉=2000 orders.
3, complete biodegradable thermoplastic starch resin as claimed in claim 2 is characterized in that chemical initiator is a kind of in the organo-peroxide.
4, complete biodegradable thermoplastic starch resin as claimed in claim 2 is characterized in that softening agent is one or more in the polyol ester class.
5 complete biodegradable thermoplastic starch resins as claimed in claim 2 is characterized in that coating is one or more in acid anhydrides or the organosilane ester.
6, complete biodegradable thermoplastic starch resin as claimed in claim 2 is characterized in that oxidation inhibitor is one or more in Hinered phenols or the hindered amines.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031173985A CN1169870C (en) | 2003-03-04 | 2003-03-04 | Total biodegraded thermoplastic starch resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031173985A CN1169870C (en) | 2003-03-04 | 2003-03-04 | Total biodegraded thermoplastic starch resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1434071A true CN1434071A (en) | 2003-08-06 |
| CN1169870C CN1169870C (en) | 2004-10-06 |
Family
ID=27634348
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031173985A Expired - Fee Related CN1169870C (en) | 2003-03-04 | 2003-03-04 | Total biodegraded thermoplastic starch resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1169870C (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007033598A1 (en) * | 2005-09-21 | 2007-03-29 | Xiaolu Li | Water soluble biodegradable material |
| CN1326928C (en) * | 2004-12-20 | 2007-07-18 | 陈明忠 | Starchlike biological degradatable plastic mother material and its preparation method |
| CN101311208B (en) * | 2007-05-25 | 2011-09-07 | 江华 | Thermoplastic starch and method for preparing same |
| CN106565997A (en) * | 2016-10-21 | 2017-04-19 | 广西师范学院 | Naturally-degraded disposable tableware and manufacturing method thereof |
| CN112625341A (en) * | 2020-12-07 | 2021-04-09 | 上海大学 | Degradable and recyclable melt-blown material and preparation method thereof |
| CN112679923A (en) * | 2020-12-08 | 2021-04-20 | 上海浦景化工技术股份有限公司 | Degradable material suitable for hydrocarbon resource recovery and preparation method and application thereof |
-
2003
- 2003-03-04 CN CNB031173985A patent/CN1169870C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1326928C (en) * | 2004-12-20 | 2007-07-18 | 陈明忠 | Starchlike biological degradatable plastic mother material and its preparation method |
| WO2007033598A1 (en) * | 2005-09-21 | 2007-03-29 | Xiaolu Li | Water soluble biodegradable material |
| CN101311208B (en) * | 2007-05-25 | 2011-09-07 | 江华 | Thermoplastic starch and method for preparing same |
| CN106565997A (en) * | 2016-10-21 | 2017-04-19 | 广西师范学院 | Naturally-degraded disposable tableware and manufacturing method thereof |
| CN112625341A (en) * | 2020-12-07 | 2021-04-09 | 上海大学 | Degradable and recyclable melt-blown material and preparation method thereof |
| CN112679923A (en) * | 2020-12-08 | 2021-04-20 | 上海浦景化工技术股份有限公司 | Degradable material suitable for hydrocarbon resource recovery and preparation method and application thereof |
| CN112679923B (en) * | 2020-12-08 | 2022-03-25 | 上海浦景化工技术股份有限公司 | Degradable material suitable for hydrocarbon resource recovery and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1169870C (en) | 2004-10-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101197105B1 (en) | Resin composition, molding thereof and process for producing the same | |
| CN100338132C (en) | Full biological degradable composition and its preparing method and use | |
| CN101240086B (en) | Total-biodegradation plastic film and preparation method thereof | |
| CN103265798B (en) | Poly(lactic acid) (PLA) and ethylene-vinyl acetate copolymer (EVA) blend composition and moulded products thereof | |
| EP0567327B1 (en) | Gas barrier melt processable polymer blends | |
| CN111718566A (en) | PLA/PBAT biodegradable composite material and product thereof | |
| CN106317816B (en) | A kind of low cost toughness-increasing polylactic acid composite material and preparation method thereof | |
| JPWO2005123831A1 (en) | Polylactic acid-containing resin composition and molded product obtained therefrom | |
| JP2001123055A (en) | Polylactic acid resin composition | |
| CN100429263C (en) | Biological-degradable starch/polyester plastic completely and production thereof | |
| JP2002105298A (en) | Lactic acid resin composition | |
| CN102391631A (en) | Biodegradable anti-static macromolecule composite material and preparation method of the same | |
| JP7040074B2 (en) | Resin composition and laminate made of the resin composition | |
| CN110317406A (en) | A kind of biodegradable polypropene composition and preparation method thereof | |
| JP2009079124A (en) | Biodegradable polyester resin composition and molded body formed of it | |
| CN112358708A (en) | Biodegradable film blowing modified material with high starch content and preparation method thereof | |
| CN1169870C (en) | Total biodegraded thermoplastic starch resin | |
| JP2005307157A (en) | Novel compatibilizer and polar polymer composition using this compatibiliser | |
| CN1284820C (en) | Starch-based biodegradable film material and its production method | |
| JP2008001786A (en) | Resin composition and molded body obtained from the same | |
| KR102009819B1 (en) | Method of biodegradable resin composition, biodegradable resin composition and biodegradable sheet | |
| KR20220035142A (en) | Blends small-grained starch and starch-based materials with synthetic polymers for increased strength and other properties | |
| KR100468641B1 (en) | Composition for Polyolefin Elastomer Modified by Chemical | |
| CN1354197A (en) | Starch-based biodegradable material and production method of its disposable tableware | |
| CN1303154C (en) | Total-starch type biodegradable plastic |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20090206 Address after: Room 8-4, building B1, No. 58 Changjiang Road, Yuzhong, Chongqing Patentee after: Wang Zheng Address before: No. 168, Qing Jiang Dong Road, Sichuan, Chengdu Patentee before: Chengdu Xinkeli Chemical Sci-Tech Co., Ltd. |
|
| ASS | Succession or assignment of patent right |
Owner name: WANG ZHENG Free format text: FORMER OWNER: CHENGDU XINKELI CHEMICAL ENGINEERING SCIENCE CO., LTD. Effective date: 20090206 |
|
| ASS | Succession or assignment of patent right |
Owner name: CHONGQING YUAN INTELLIGENT LOCK SAFETY DOOR CO., L Free format text: FORMER OWNER: WANG ZHENG Effective date: 20110908 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 400014 YUZHONG, CHONGQING TO: 408200 FENGDU, CHONGQING |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20110908 Address after: 408200 No. 3, Fengdu water balance industrial park, Chongqing Patentee after: Chongqing far intelligent lock safety door Co., Ltd. Address before: 400014 room 8-4, building B1, No. 58 Changjiang Road, Yuzhong District, Chongqing, China Patentee before: Wang Zheng |
|
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20041006 Termination date: 20110304 |