CN1427710A

CN1427710A - Composition for colouring and conditioning hair

Info

Publication number: CN1427710A
Application number: CN 01808994
Authority: CN
Inventors: 尼古拉斯·W·吉尔里; 迪特尔·H·J·兰希; 西蒙·P·戈弗雷
Original assignee: Procter and Gamble Ltd
Current assignee: Procter and Gamble Ltd; Procter and Gamble Co
Priority date: 2000-04-07
Filing date: 2001-03-30
Publication date: 2003-07-02
Also published as: WO2001076545A1; EP1267809A1; JP2003530334A; AU2001249729A1

Abstract

A hair colouring and conditioning composition comprising: (a) a hair colouring agent; and (b) a hair conditioning agent; wherein the composition provides an Average Combing Index Value of greater than 1.2 asmeasured by the Combing Technical Test Method. The products can provide excellent hair colouring together with excellent conditioning, reduced hair damage, brittleness and dryness, and is convenient and easy to use.

Description

Hair dyeing and care composition

Technical field

The present invention relates to composition for hair dying and hair colouring methods, more specifically relate to provide by a kind of product simultaneously the composition for hair dying of hair dyeing and conditioning hair effect.

Background of invention

The need of change human hair color just occurred if it were not for the modern times.From Roman Empire period, the color relation of human hair often changes to adapt to the variation of fashion and style.Yet, obtain accurate priming color and be a target that is difficult to realize always its time that keeps the desired length of people.Exploitation can bring the difficult part of the composition for hair dying of the accurate color that keeps lastingly to be because the inherent structure of hair itself partly is because the required condition of effective hair dyeing process.The FAQs of conventional composition for hair dying comprise fade, wash fade, irregular dyestuff absorbs, hair injury and fragility, skin irritation, abnormal smells from the patient and skin dye.

People have carried out the effort of several years and have eliminated the many problems relevant with the dyeing of human hair.At present, develop multiple hair dyeing method, comprised direct effect dyestuff, natural dye, metal dye and oxidative dyestuff.

But, still there are a kind of like this needs, wish to obtain obtaining significantly improved product at many critical aspects.Especially, be desirable to provide to hair and bring outstanding color, still reduced the composition for hair dying of relevant with hair dyes, particularly oxidative hair dyestuff usually injury effect simultaneously.The injury effect comprises that entanglement, fragility, drying and hair are easily broken.In addition, be desirable to provide the composition for hair dying of the part of convenient to use and the routine cleaning that can in bathing and shower, use as consumer and coordinating program.Many present composition for hair dying that can access for example based on the oxidative dyestuff technology those, are faced with in order these compositionss need to be stayed the quite a long time on the hair average about 30 minutes shortcoming in colour developing on the hair.In addition, many such compositionss are used inconvenient.For example, under the situation of the conventional composition for hair dying that uses the oxidative dyestuff technology, with the mixture process hair of oxidative hair dyeing agent and oxidant.Hydrogen peroxide is the oxidant of normal use.Usually, this product is sold with the form of the hair dyeing suit of the hair dyes component that comprises packing separately and oxidation component.Consumer mixed these two kinds of components before using on the head according to explanation.This is consuming time and loaded down with trivial details for consumers.

Now be surprisingly found out that the composition for hair dying that comprises hair colourant and hair conditioner of the present invention, wherein said composition has certain opsonic action, overcome problem based on the conventional composition for hair dying of oxidative dyestuff technology, outstanding opsonic action particularly is provided, reduce hair injury, entanglement, fragility, drying and scrambling, and increased convenience and the easiness used.In fact, the composition for hair dying that the purpose of this invention is to provide the part of the routine cleaning that can in bathing and shower, use as consumer and coordinating program.

Unless otherwise indicated, all percentage ratios all are based on the weight of final composition of the present invention that will type of service.

Summary of the invention

Theme of the present invention is coloring hairs and the care composition that is suitable for handling the mankind or animal hair.

According to an aspect of the present invention, provide coloring hairs and care composition, having comprised: (a) at least a conditioner; And (b) at least a hair colourant; Wherein the average combing exponential quantity of compositions (Average Combing Index Value) is greater than 1.2, and this is to measure by carding technology method of testing (Combing Technical Test Method) hereinafter described.

Should be understood that present composition percentages of ingredients represents with total composition, and refer to will type of service compositions, promptly will use the final composition on the hair.

According to a further aspect of the invention, the method that is used for coloring hairs and conditioning is provided, wherein coloring hairs and care composition are applied directly on the hair, rinse then, wherein coloring hairs and care composition comprise: (a) at least a conditioner; (b) at least a hair colourant; Wherein the average combing exponential quantity of compositions is greater than 1.2, and this is the carding technology test determines by hereinafter described.

According to a further aspect of the invention, the coloring hairs and the conditioning suit that comprise at least two kinds of components are provided: first component and second component that contains hair colourant that contain oxidant, condition is that at least a component comprises conditioner, wherein immediately two kinds of components is mixed before being applied to coloring hairs and care composition on the hair.

In some embodiments, can also be included in the initial colouring compositions that uses the compositions that changes hair color to be suitable for providing before initial hair color in the suit to hair.Consumer uses initial colouring compositions to begin to have used color, and by using the compositions that changes hair color to keep color in ensuing several weeks.Usually, initial colouring compositions has identical tone (shade) basically with the compositions that changes hair color.

Detailed Description Of The Invention

Coloring hairs of the present invention and care composition comprise at least a conditioner and at least a hair colourant.In addition, the average combing exponential quantity of coloring hairs and care composition is greater than 1.2, and this is the carding technology test determines by hereinafter described.

" hair " that will handle of Shi Yonging can be " work " in the present invention, promptly on the health that lives, perhaps can be " non-work ", promptly at the aggregation of wig, artificial brow (hairpiece) or other non-living body fiber, those as in textile and fabric, using.Preferred mammal, preferred human hair.But Pilus Caprae seu Ovis, fur and other comprise the substrate that melanic fiber also is suitable as the present composition.

The term that uses in the present invention " coloring hairs and care composition " is broader sense, be used for comprising the compositions that contains at least a conditioner and at least a hair colourant, wherein the average combing exponential quantity of compositions is greater than 1.2, and this is the carding technology test determines by hereinafter described.And this term also plans to be used for comprising complicated compositions, and wherein containing can be other composition of activity or non-active ingredient.Therefore, term " coloring hairs and care composition " is used to refer to except that the mixture of at least a conditioner and at least a hair colourant, also comprise this class material, for example, but be not limited to the compositions that oxidant, oxidation promoter, chelating agen (sequestrants), stabilizing agent, thickening agent, buffer agent, carrier, surfactant, solvent, antioxidant, polymer, ultraviolet filter agent and additional conditioner.

Conditioner

Conditioner among the present invention can be any conditioner that is applicable to conditioning hair, and condition is that coloring hairs and care composition provide the average combing exponential quantity greater than 1.2, and this is the carding technology test determines by hereinafter described.

Coloring hairs among the present invention and care composition comprise one or more conditioners, preferable amount is about 0.1% to about 25% based on the weight of coloring hairs and care composition, preferred about 1% to about 20%, and more preferably from about 5% to about 20%, about in particular 5% to about 15%.

Suitable conditioner used in this invention includes, but are not limited to: cationic surfactant, cationic polymer, insoluble polysiloxanes, non-volatile hydrocarbon, saturated C ₁₄-C ₂₂Straight-chain fatty alcohol, non-volatile hydrocarbon ester and their mixture.Other suitable conditioner is disclosed among the WO 95/20939, introduces among the present invention as a reference.

Preferred conditioner used in this invention comprises cationic polymer, non-volatile polysiloxanes and saturated C ₁₄-C ₂₂Straight-chain fatty alcohol and their mixture.The cationic polymer that particularly preferably is used in this invention, non-volatile polysiloxanes and C ₁₄-C ₂₂The mixture of straight-chain fatty alcohol.

When using, the amount of non-volatile polysiloxanes be composition weight about 0.1 to 10%, preferred about 0.1% to about 5%, more preferably from about 1% to about 3%.

When using, the amount of cationic polymer be composition weight about 0.1 to 10%, preferred about 0.1% to about 5%, more preferably from about 1% to about 3%.

When using, the amount of aliphatic alcohol be composition weight about 0.1% to about 20%, preferred about 1% to about 15%, more preferably from about 3% to about 10%.

Hair colourant

Hair colourant of the present invention can be any hair colourant that is useful in the hair dyeing.

Suitable hair colourant includes, but are not limited to: oxidative dyestuff, dyes for silver halide photography (photographic dyes), acid stain (acid dyes), neutral dye, the dye of positive ion, reactive dye, VAT dyestuff and their mixture.Be particularly preferred among the present invention is oxidative dyestuff.

Composition for hair dying of the present invention preferably comprises oxidisability or non-oxidizable hair colourant.This class hair colourant and conditioner are used in combination permanent (permanent), inferior permanent (demi-permanent) or semipermanent (semi-permanent) hair dye composition that has outstanding hair-conditioning performance with preparation.

Ding Yi permanent hair dye composition is such compositions in the present invention, after in a single day they be applied on the hair, and washable basically going.Time permanent hair dye composition of definition in the present invention is such compositions, and they are after maximum 24 washings, basically by eccysis.Ding Yi semipermanent hair dye composition is such compositions in the present invention, after in a single day they be applied on the hair, after maximum 10 washings, basically by eccysis.Ding Yi provisional hair dye composition is such compositions in the present invention, after in a single day they be applied on the hair, after maximum 2 washings, basically by eccysis.These dissimilar composition for hair dying can be prepared in the concrete combination of different amounts and ratio by oxidant and/or dyestuff.Ding Yi eccysis in the present invention is the method for passing eccysis from the hair by normal hair cleaning scheme in time.Ding Yi fastness to washing refers to the anti-eccysis of the hair after the dyeing in the present invention.

The oxidative hair dyeing agent

The preferred hair colourant of the present invention is the oxidative hair dyeing agent.The concentration of every kind of oxidative hair dyeing agent in the colouring compositions of the present invention is preferably about 0.001% to about 3% weight, and more preferably from about 0.01% to about 2% weight.

Amount after total merging of the oxidative hair dyeing agent in the present composition is about 0.001% to about 5%, and preferred about 0.01% to about 4%, and more preferably from about 0.1% to about 3%, and most preferably from about 0.1% to about 1% weight.

In compositions of the present invention, can use oxidative hair dyeing agent arbitrarily.Usually, but do not plan to limit therefrom, the oxidative hair dyeing agent is made up of at least two kinds of components basically, and these two kinds of components are referred to as the intermediate (precursor) that forms dyestuff.The intermediate that forms dyestuff can react in the presence of suitable oxidant and form colored molecule.

The intermediate that is used for the formation dyestuff of oxidizing hair coloring agents (colorants) comprises: aromatic diamine, amino-phenol, various heterocycle, phenol, naphthols and their various derivants.These intermediate that form dyestuffs can be from broadly being divided into: main intermediate (primary intermediates) and less important intermediate (secondary intermediates).Main intermediate is to be activated through oxidation, then can react each other and/or forms the chemical compound of coloured dye ligand compound with coupling agent reaction, and they are also referred to as the oxidative dyestuff precursor.The molecule that less important intermediate is normally colourless, they can form color in the presence of the precursor/main intermediate after the activation, can be used from the specific color effects of generation or make colour stable with other intermediate one, less important intermediate be also referred to as color adaptation agent or coupling agent.

Be applicable to that the main intermediate in the compositions and methods of the invention comprises: the derivant of aromatic diamine, polyhydroxy phenol, amino-phenol and these aromatic compounds (as, the N-substitutive derivative of amine and the ether of phenol).This class main intermediate normally colourless molecule before oxidation.

Not bound by theory, it is considered herein that the method that forms color by these main intermediate and less important coupling compound comprises sequence of steps, according to this order, main intermediate can be activated in (by oxidation), combine the conjugation coloring matter that obtains dimerization then with coupling agent, " be activated " main intermediate with another afterwards and combine the trimeric conjugation coloured molecule of generation.

The oxidative dyestuff precursor

Generally speaking, the oxidative dyestuff main intermediate comprises those monomeric substances that form oligomer or polymer through peroxidating, has the conjugated electrons system of expansion in the molecular structure of described oligomer or polymer.Because new electronic structure, the electronic spectrum of gained oligomer and polymer shows to the displacement of visible-range and produces color.For example, the oxidisability main intermediate that can form colored polymeric comprises those materials such as aniline, and it only has a functional group and forms a series of conjugated imines and quinoid dimer, trimers etc. from green to the black scope through peroxidating.Chemical compound such as p-phenylenediamine (PPD) with two functional groups, energy oxidation polymerization obtains the coloring matter of the conjugated electrons system with expansion of higher molecular weight.Oxidative dyestuff known in the art can be used for compositions of the present invention.Be applicable to that representational main intermediate of the present invention and less important coupling agent are recorded in Sagarin, " Cosmetic Science andTechnology " (Interscience, Special Ed.Vol.2,308-310 page or leaf).Should be appreciated that the main intermediate that describes in detail below only is to be described by way of example, but not specially limit the compositions and methods of the invention.

Above-mentioned representational aromatic diamine, polyhydroxy phenol, amino phenols and derivant thereof as main intermediate can have other substituent group on aromatic ring, for example halogen, aldehyde, carboxylic acid, nitro, sulfonic acid and replacement and unsubstituted alkyl, and on the oxygen atom of amino nitrogen atom and phenolic hydroxyl group, also can have other substituent group, for example replace with unsubstituted alkyl and aryl.

The example of suitable aromatic diamine, amino phenols, polyhydroxy phenol and their derivant is respectively following general formula (I), (II) and chemical compound (III):

Or

Wherein Y be hydrogen, halogen (for example fluorine, chlorine, bromine or iodine), nitro, amino, hydroxyl, -COOM or-SO ₃M (wherein M is the ammonium of hydrogen, alkali metal, alkaline-earth metal, ammonium or replacement, and the one or more hydrogen in the ammonium of replacement on the ammonium ion are by the alkyl of 1-3 carbon atom or hydroxy alkyl displacement), wherein R ₁, R ₂, R ₃And R ₄Be same to each other or different to each other, they are selected from hydrogen, C ₁To C ₄Alkyl or alkenyl and C ₆To C ₉Aryl, alkaryl or aralkyl, and R ₅Be hydrogen, C ₁To C ₄Unsubstituted or replace alkyl or alkenyl, substituent group wherein be selected among the top Y specified those; Perhaps R ₅Be selected from C ₆To C ₉Unsubstituted or replace aryl, alkaryl or aralkyl, substituent group wherein is selected from those that define among the top Y.Because the precursor of formula (I) is an amine, thus they can with shown in the form with the salt of peroxide compatible be used for the present invention, wherein X represents above to describe in detail type and anion peroxide compatible.The salt of general formula shown in should be appreciated that comprise have one, two or three anionic those salt.

The instantiation of formula (I) chemical compound is: o-phenylenediamine, m-diaminobenzene., p-phenylenediamine (PPD), 2-chloro-p-phenylenediamine (PPD), 2-iodo-p-phenylenediamine (PPD), 4-nitro-o-phenylenediamine, 2-nitro-p-phenylenediamine (PPD), 1,3, the 5-triaminobenzene, 2-hydroxyl-p-phenylenediamine (PPD), 2, the 4-diaminobenzoic acid, 2,4-diaminobenzoic acid sodium, two-2,4-diaminobenzoic acid calcium, 2,4-diaminobenzoic acid ammonium, 2,4-diaminobenzoic acid trimethyl ammonium, 2,4-diaminobenzoic acid three-(2-ethoxy) ammonium, 2,4-diaminobenzene formaldehyde carbonate, 2, the 4-diamino benzene sulfonic acid, 2,4-diamino benzene sulfonic acid potassium, N, N-diisopropyl-p-phenylenediamine (PPD) bicarbonate, N, N-dimethyl-p-phenylenediamine (PPD), N-ethyl-N '-(2-acrylic)-p-phenylenediamine (PPD), N-phenyl-p-phenylenediamine (PPD), N-phenyl-N-benzyl-p-phenylenediamine (PPD), N-ethyl-N '-(3-ethylphenyl)-p-phenylenediamine (PPD), 2, the 4-toluenediamine, 2-ethyl-p-phenylenediamine (PPD), 2-(2-bromoethyl)-p-phenylenediamine (PPD), 2-phenyl-p-phenylenediamine (PPD) laruate, 4-(2, the 5-diamino-phenyl) benzaldehyde, 2-benzyl-p-phenylenediamine (PPD) acetate, 2-(4-nitrobenzyl)-p-phenylenediamine (PPD), 2-(4-aminomethyl phenyl)-p-phenylenediamine (PPD), 2-(2, the 5-diamino-phenyl)-the 5-ar-Toluic acid, the methoxyl group p-phenylenediamine (PPD), dimethyl-p-phenylenediamine (PPD), 2, the 5-dimethyl-p-phenylenediamine, 2-methyl-5-methoxyl group-p-phenylenediamine (PPD), 2,6-dimethyl-5-methoxyl group-p-phenylenediamine (PPD), 3-methyl-4-amino-N, the N-diethylaniline, N, two (the beta-hydroxyethyl)-p-phenylenediamine (PPD) of N-, 3-methyl-4-amino-N, two (beta-hydroxyethyl) aniline of N-, 3-chloro-4-amino-N, two (beta-hydroxyethyl) aniline of N-, 4-amino-N-ethyl-N-(carbonyl methyl (carbamethyl)) aniline, 3-methyl-4-amino-N-ethyl-N-(carbonyl methyl) aniline, 4-amino-N-ethyl-(β-piperidines ethyl) aniline, 3-methyl-4-amino-N-ethyl-(β-piperidines (piperidono) ethyl) aniline, 4-amino-N-ethyl-N-(β-morpholino ethyl) aniline, 3-methyl-4-amino-N-ethyl-N-(β-morpholino ethyl) aniline, 4-amino-N-ethyl-N-(β-acetylamino ethyl) aniline, 4-amino-N-('beta '-methoxy ethyl) aniline, 3-methyl-4-amino-N-ethyl-N-(β-acetylamino ethyl) aniline, 4-amino-N-ethyl-N-(β-methanesulfonamido ethyl) aniline, 3-methyl-4-amino-N-ethyl-N-(β-methanesulfonamido ethyl) aniline, 4-amino-N-ethyl-N-(β-sulfo group ethyl) aniline, 3-methyl-4-amino-N-ethyl-N-(β-sulfo group ethyl) aniline, N-(4-aminophenyl) morpholine, N-(4-aminophenyl) piperidines, 2,3-dimethyl-p-phenylenediamine (PPD), isopropyl-p-phenylenediamine (PPD), N, N-pair-(2-ethoxy)-p-phenylenediamine sulfate.

The chemical compound of general formula (II) is as follows:

Or

Wherein identical in X and Y and the formula (I), R ₁And R ₂Can be same to each other or different to each other and with formula (I) in identical, R ₅With identical and R in the formula (I) ₆Be hydrogen or C ₁-C ₄That replace or unsubstituted alkyl or alkenyl, substituent group wherein is selected from those that are defined as Y in the formula (I).

The instantiation of formula (II) chemical compound is: o-aminophenol, m-aminophenol, para-aminophenol, 2-iodo-para-aminophenol, 2-nitro-para-aminophenol, 3,4-dihydroxy aniline, 3, the 4-diaminophenol, chloracetate, 2-hydroxyl-4-amino benzoic Acid, 2-hydroxyl-4-aminobenzaldehyde, 3-amino-4-hydroxy benzenesulfonic acid, N, N-diisopropyl-para-aminophenol, N-methyl-N-(1-acrylic)-para-aminophenol, N-phenyl-N-benzyl-p-aminophenol sulfate, N-methyl-N-(3-ethylphenyl)-para-aminophenol, 2-nitro-5-ethyl-para-aminophenol, 2-nitro-5-(2-bromoethyl)-para-aminophenol, (2-hydroxyl-5-aminophenyl) acetaldehyde, 2-methyl-para-aminophenol, (2-hydroxyl-5-aminophenyl) acetic acid, 3-(2-hydroxyl-5-aminophenyl)-1-propylene, 3-(2-hydroxyl-5-aminophenyl)-2-chloro-1-propylene, 2-phenyl-para-aminophenol palmitate, 2-(4-nitrobenzophenone)-para-aminophenol, 2-benzyl-para-aminophenol, 2-(4-benzyl chloride base-para-aminophenol) perchlorate, 2-(4-aminomethyl phenyl)-para-aminophenol, 2-(2-amino-4-aminomethyl phenyl)-para-aminophenol, P-nethoxyaniline, 2-bromoethyl-4-aminophenyl ether phosphate, 2-nitro-ethyl-4-aminophenyl ether bromide, 2-amino-ethyl-4-aminophenyl ether, 2-hydroxyethyl-4-aminophenyl ether, (4-amino-benzene oxygen) acetaldehyde, (4-amino-benzene oxygen) acetic acid, (4-amino-benzene oxygen) methanesulfonic acid, 1-acrylic-4-aminophenyl ether isobutyrate, (2-chlorine)-1-acrylic-4-aminophenyl ether, (2-nitro)-1-acrylic-4-aminophenyl ether, (2-amino)-acrylic-4-aminophenyl ether, (2-hydroxyl)-1-acrylic-4-aminophenyl ether, N-methyl-para-aminophenol, 3-methyl-4-amino-phenol, 2-chloro-4-amino-phenol, 3-chloro-4-amino-phenol, 2,6-dimethyl-4-amino-phenol, 3,5-dimethyl-4-amino-phenol, 2,3-dimethyl-4-amino-phenol, 2,5-dimethyl-4-amino-phenol, 2-hydroxymethyl-4-amino-phenol, 3-hydroxymethyl-4-amino-phenol, 2,6-two chloro-4-amino-phenols, 2,6-two bromo-4-amino-phenols and 2-bromo-4-amino-phenol.

The instantiation of formula (III) chemical compound is: o-hydroxy phenol (catechol), between hydroxyl phenol (resorcinol), para hydroxybenzene phenol (hydroquinone), the 4-methoxyphenol, the 2-methoxyphenol, 4-(2-chloro ethyoxyl) phenol, 4-(2-propenyloxy group) phenol, 4-(3-chloro-2-propenyloxy group) phenol, 2-chloro-4-hydroxyl phenol (2-chlorohydroquinone), 2-nitro-4-hydroxyl phenol (2-nitro hydroquinone), 2-amino-4-hydroxy phenol, 1,2,3-trihydroxy benzene (1,2,3,-thrihydroxy-benzene), 2, the 4-4-dihydroxy benzaldehyde, 3, the 4-resorcylic acid, 2, the 4-dihydroxy benzenes sulfonic acid, 3-ethyl-4-hydroxyl phenol, 3-(2-nitro-ethyl)-4-hydroxyl phenol, 3-(2-acrylic)-4-hydroxyl phenol, 3-(3-chloro-2-acrylic)-4-hydroxyl phenol, 2-phenyl-4-hydroxyl phenol, 2-(4-chlorphenyl)-4-hydroxyl phenol, 2-benzyl-4-hydroxyl phenol, 2-(2-nitrobenzophenone)-4-hydroxyl phenol, 2-(2-aminomethyl phenyl)-4-hydroxyl phenol, 2-(2-methyl-4-chlorphenyl)-4-hydroxyl phenol, 3-methoxyl group-4-hydroxyl-benzaldehyde, 2-methoxyl group-4-(1-acrylic) phenol, 4-hydroxyl-3-methoxy cinnamic acid, 2, the 5-dimethoxyaniline, the 2-methylresorcinol, alpha-Naphthol and salt thereof.

The less important coupling compound that is suitable for being included in the invention described above composition for hair dying and the method comprises some aromatic amine and phenol and derivant thereof, they self do not produce color, but can change the intensity by color, color and luster and the color of first oxidation dye intermediate colour developing.Some aromatic amines and phenolic compound and their derivant comprise following formula (I), (Ia), (Ib), (II) and (III) some aromatic diamine and the polyhydroxy benzenes phenolic compound of described type, but well known in the art those should not be suitable to coupling agent of the present invention as those chemical compounds of main intermediate.The polyhydroxy alcohols is also suitable to coupling agent of the present invention.

Above-mentioned aromatic amine and phenol derivmives blend biology as coupling agent also can have other substituent group on aromatic ring; replace and unsubstituted group as halogen, aldehyde, carboxylic acid, nitro, sulfonyl and by alkyl; and also can have other substituent group on the oxygen atom of amino nitrogen atom or phenolic hydroxyl group, as replace or unsubstituted alkyl and aryl.Moreover their salt with peroxide compatible also is applicable to the present invention.

The example of aromatic amine, phenol compound and derivant thereof is following general formula (IV) and chemical compound (V):

Or

Wherein Z is hydrogen, C ₁To C ₃Alkyl, halogen (as, fluorine, chlorine, bromine, iodine), nitro, -COOM or SO ₃M, (wherein M is the ammonium of hydrogen, alkali metal, alkaline-earth metal, ammonium or replacement, and the one or more hydrogen in the ammonium of replacement on the ammonium ion are by the alkyl of 1-3 carbon atom or hydroxy alkyl displacement), wherein R ₁And R ₂Be same to each other or different to each other, they are selected from hydrogen, C ₁To C ₄Alkyl or alkenyl and C ₆To C ₉Aryl, alkaryl or aralkyl, and R ₇Be hydrogen, C ₁To C ₄Unsubstituted or replace alkyl or alkenyl are defined as those of Z above substituent group wherein is selected from; Perhaps R ₇Be selected from C ₆To C ₉Unsubstituted or replace aryl, alkaryl or aralkyl, be defined as above substituent group wherein is selected from Z those and wherein X suc as formula defining in (I).

The instantiation of formula (IV) chemical compound is: aniline, parachloroanilinum, para-fluoroaniline, paranitroanilinum, para aminotenzaldehyde, para-amino benzoic acid, para aminobenzoic acid sodium salt, the para-amino benzoic acid lithium, two-para-amino benzoic acid calcium, the para-amino benzoic acid ammonium, the para-amino benzoic acid trimethyl ammonium, three (2-hydroxyethyl)-para-aminobenzoates, p-anilinesulfonic acid., p-anilinesulfonic acid. potassium, methylphenylamine, N-propyl group-N-phenylaniline, N-methyl-N-2-acrylic aniline, Phenhenzamine, N-(2-ethylphenyl) aniline, the 4-monomethylaniline., 4-(2-bromoethyl) aniline, 2-(2-nitro-ethyl) aniline, (4-aminophenyl) acetaldehyde, (4-aminophenyl) acetic acid, 4-(2-acrylic) phenylglycine salt, 4-(3-bromo-2-acrylic) aniline, 4-phenylaniline chloracetate, 4-(3-chlorphenyl) aniline, the 4-benzylaniline, 4-(4-iodine benzyl) aniline, 4-(3-ethylphenyl) aniline, 4-(2-chloro-4-ethylphenyl) aniline.

Wherein Z and R ₇Suc as formula defining and R in (IV) ₈Be hydrogen or C ₁-C ₄That replace or unsubstituted alkyl or alkenyl, substituent group wherein is selected from those that are defined as Z in the formula (IV).

The instantiation of formula V chemical compound is: phenol, parachlorophenol, paranitrophenol, hydroxy benzaldehyde, P-hydroxybenzoic acid, p-hydroxybenzenyl sulfonate, ethylphenyl ether, 2-chloroethyl phenyl ether, 2-nitro-ethyl phenyl ether, phenoxy acetaldehyde, phenoxyacetic acid, 3-phenoxy group-1-propylene, 3-phenoxy group-2-nitro-1-propylene, 3-phenoxy group-2-bromo-1-propylene, the 4-propylphenol, 4-(3-bromopropyl) phenol, 2-(2-nitro-ethyl) phenol, (4-hydroxy phenyl) acetaldehyde, (4-hydroxy phenyl) acetic acid, 4-(2-acrylic) phenol, the 4-phenylphenol, the 4-benzylphenol, 4-(3-fluoro-2-acrylic) phenol, 4-(4-benzyl chloride base) phenol, 4-(3-ethylphenyl) phenol, 4-(2-chloro-3-ethylphenyl) phenol, 2, the 5-xylenols, 2, the 5-diamino-pyridine, 2-hydroxyl-5-aminopyridine, 2-amino-3-pyridone, tetraminopyrimidine, 1,2, the 4-trihydroxy benzene, 1,2,4-trihydroxy-5-(C ₁-C ₆-alkyl) benzene, 1,2,3-trihydroxy benzene, 4-aminoresorcinol, 1,2-dihydroxy benzenes, 2-amino-1,4-dihydroxy benzenes, 2-amino-4-methoxyl group-phenol, 2,4-diaminophenol, 3-methoxyl group-1,2-dihydroxy-benzene, 1,4-dihydroxy-2-(N, the N-diethylamino) benzene, 2,5-diaminourea-4-methoxyl group-1-hydroxy benzenes, 4,6-dimethoxy-3-amino-1-hydroxy benzenes, 2,6-dimethyl-4-[N-(p-hydroxybenzene) amino]-1-hydroxy benzenes, 1,5-diaminourea-2-methyl-4-[N-(p-hydroxybenzene) amino] benzene and salt thereof.

Be applicable to that other main intermediate of the present invention comprises pyrocatechol, catechol " DOPA " class especially, they comprise homologue, analog and the derivant of DOPA itself and DOPA.The example of suitable pyrocatechol comprises that cysteinyl dopa, alkyl have 1-4, and alpha-alkyl DOPA, epinephrine and the alkyl of preferred 1-2 carbon atom has 1-6, the DOPA Arrcostab of preferred 1-2 carbon atom.

Usually, the pyrocatechol of Shi Heing is represented by following formula (VI):

R wherein ₁, R ₂And R ₃Can be identical or different, they can be to be selected from following electron donor or receptor substituent group: H, rudimentary (C ₁-C ₆) alkyl, OH, OR, COOR, NHCOR, CN, COOH, halogen, NO ₂, CF ₃, SO ₃H or NR ₄R ₅, condition is R ₁, R ₂Or R ₃In have only one may be CN, COOH, halogen, NO ₂, CF ₃Or SO ₃H; R ₄And R ₅Can be identical or different, be H, rudimentary (C ₁-C ₆) rudimentary (C of alkyl or replacement ₁-C ₆) alkyl, substituent group wherein can be OH, OR, NHCOR ₆, NHCONH ₂, NHCO ₂R ₆, NHCSNH ₂, CN, COOH, SO ₃H, SO ₂NR ₆, SO ₂R ₆Or CO ₂R ₆R ₆Be the rudimentary (C that links to each other with nitrogen-atoms by alkylidene chain ₁-C ₆) alkyl, rudimentary (C ₁-C ₆) the hydroxy alkyl phenyl, phenyl or be defined as R ₁The phenyl that replaces of substituent group, and R is C ₁-C ₆Alkyl or C ₁-C ₆Hydroxy alkyl.

The present invention also comprises the oxidative hair dyeing agent of following formula:

Wherein: R ₁=replace or unsubstituted phenyl ring, the tert-butyl group etc.; R=group that replace or unsubstituted phenyl ring and following formula:

Wherein R=aminoalkyl, amidoalkyl, aminobenzene (replace or unsubstituted), acylamino-benzene (replacement or unsubstituted), alkyl, replacement or unsubstituted phenyl ring; R ₁=replace or unsubstituted phenyl ring.

Main intermediate can be used for the present invention separately or can be used in combination with other main intermediate, and one or more main intermediate also can be used in combination with one or more coupling agents.The intensity that the selection of main intermediate and coupling agent is depended on required color, color and luster and color.Can be used for have 19 kinds of preferred main intermediate and coupling agent of the present invention, the dyestuff that has from the ash gold to the various color and lusters of black to provide can separately or be provided for they; They are: 1,2,3,-thrihydroxy-benzene, resorcinol, to toluenediamine, p-phenylenediamine (PPD), o-phenylenediamine, m-diaminobenzene., o-aminophenol, para-aminophenol, 4-amino-2-nitrophenol, nitro-p-phenylenediamine (PPD), N-phenyl-p-phenylenediamine (PPD), m-aminophenol, 2-amino-3-pyridone, 1-naphthols, N, two (2-hydroxyethyl) p-phenylenediamine (PPD) of N-, 4-amino-2-hydroxy-methylbenzene, 1,5-dihydroxy naphthlene, 2-methylresorcinol and 2, the 4-diamino anisole.As mentioned above, these can use with molecular forms or with the form of peroxide compatible salt.

For example, the low-intensity color, for example natural golden hair color to light brown chroma of hair comprises usually and accounts for about 0.001% to about 5% of colouring compositions weight, preferred about 0.1% to about 2%, total oxidative coloration agent of more preferably about 0.2% to about 1%, they can obtain by main intermediate is combined with coupling agent, described main intermediate is, for example 1, and 4-diaminourea-benzene, 2, the 5-diaminotoluene, 2,5-diaminourea-methyl phenyl ethers anisole, the 4-amino-phenol, 2,5-diaminourea-benzylalcohol and 2-(2 ', 5 '-diaminourea) phenyl-ethanol, described coupling agent is, for example resorcinol, 2-methylresorcinol or 4-chloro resorcinol.

The above-mentioned main intermediate of amount of total stain and the similar combination of coupling agent with about 0.5% to about 1%, as 5-amino-2-methyl phenol and 1,3-diaminourea-benzene derivative, for example 2,4-diaminourea-methyl phenyl ethers anisole can obtain the redness of moderate strength.High-intensity color such as blueness to hepatic hair tone can be by accounting for composition weight total dyeing dosage of about 1% to about 6% with above-mentioned main intermediate and coupling agent, as 1,3-diaminourea-benzene or derivatives thereof, for example 2,5-diaminourea-toluene makes up and obtains.The hair color of black can be by in conjunction with above-mentioned main intermediate and coupling agent, and for example 1,3-diaminobenzene or derivatives thereof obtains.

Non-oxidizable dyestuff and other dyestuff

Except the oxidative hair dyeing agent, hair colouring compositions of the present invention also can comprise non-oxidizable and other dye substance, perhaps replaces the oxidative hair dyeing agent with non-oxidizable and other dye substance.That optional non-oxidizable and other dyestuff that is applicable to composition for hair dying of the present invention and method comprises is semi-permanent, face effect with other dyestuff.Non-oxidizable dyestuff as the present invention's definition comprises so-called " directly acting on dyestuff ", metal dye, metal-chelator dyestuff, fibre-reactive dye and other synthetic or natural dye.All kinds of non-oxidizable dyestuffs are specified in: " Chemical and Physical Behaviour ofHuman Hair " 3rd Ed., Clarence Robbins (250-259 page or leaf); " The Chemistry andManufacture of Cosmetics ", Volume IV.2nd Ed.Maison G.De Navarre, the 45th chapter, G.S.Kass (841-920 page or leaf); " cosmetics:Science and Technology " 2nd Ed., Vol.II Balsam Sagarin, Chapter 23 by F.E.Wall (279-343 page or leaf); " The Science of HairCare " edited by C.Zviak, Chapter7 (pp 235-261) and " Hair Dyes ", J.C.Johnson, Noyes Data Corp., Park Ridge, U.S.A. (1973), (3-91 and 113-139 page or leaf).

The direct effect dyestuff that does not need Oxidation to develop the color is also referred to as hair coloring agents (hair tint), and they are that this area is just known a long time ago.They are applied to hair with the matrix form that comprises surfactant materials usually.Directly the effect dyestuff comprises nitro dye, as the derivant of nitro amino benzene or nitro amino phenol; Disperse dyes are as nitro arylamine, amino anthraquinones or azo dye; Anthraquinone dye, naphthoquinone dyestuff; Basic stain is as Acridine Orange C.I.46005.Under the situation of direct dyes, in compositions of the present invention, these direct dyess preferably together use with the oxidative hair dyeing agent, and do not use separately usually.

In dye composite, add the suitable aesthetic property that nitro dye is used preceding dye mixture with the color and the increase of enhancing stain.

Directly other example of effect dyestuff comprises Arianor dyestuff bismarck brown 17, C.I. (color index)-12,251; Alkalescence is red 76, C.I.-12,245; Bismarck brown 16, C.I.-12,250; Basic yellow 57, C.I.-12,719 and alkali blue 99, C.I.-56,059 and other direct effect dyestuff: Indian yellow 1, C.I.-10,316 (D﹠amp; Yellow No. 7 of C); Indian yellow 9, C.I.-13,015; The purple C.I.-45 of alkalescence, 170; Disperse yellow 3, C.I.-11,855; Basic yellow 57, C.I.-12,719; Disperse yellow 1, C.I.-10,345; Alkaline purple 1, C.I.-42,535, alkaline purple 3, C.I.-42,555; Turquoise, C.I.-42090 (FD﹠amp; Blue No. 1 of C); Yellowish red color, C.I.-14700 (FD﹠amp; Red No. 4 of C); Yellow, C.I.19140 (FD﹠amp; Yellow No. 5 of C); Yellowish orange, C.I.15985 (FD﹠amp; Yellow No. 6 of C); Aeruginous, C.I.42053 (FD﹠amp; Green No. 3 of C); Yellowish red color, C.I.16035 (FD﹠amp; Red No. 40 of C); Aeruginous, C.I.61570 (D﹠amp; Green No. 3 of C); Orange, C.I.45370 (D﹠amp; No. 5, C orange); Redness, C.I.15850 (D﹠amp; Red No. 6 of C); The bluish red color, C.I.15850 (D﹠amp; Red No. 7 of C); Little bluish red color, C.I.45380 (D﹠amp; Red No. 22 of C); The bluish red color, C.I.45410 (D﹠amp; Red No. 28 of C); The bluish red color, C.I.73360 (D﹠amp; Red No. 30 of C); Reddish purple, C.I.17200 (D﹠amp; Red No. 33 of C); The dark blue redness, C.I.15880 (D﹠amp; Red No. 34 of C); Bright orange redness, C.I.12085 (D﹠amp; Red No. 36 of C); Bright orange, C.I.15510 (D﹠amp; No. 4, C orange); Green-yellow, C.I.47005 (D﹠amp; Yellow No. 10 of C); Aeruginous, C.I.59040 (D﹠amp; Green No. 8 of C); Bluish violet, C.I.60730 (Ext.D﹠amp; Purple No. 2 of C); Green-yellow, C.I.10316 (Ext.D﹠amp; Yellow No. 7 of C).

Fibre-reactive dye comprises Procion (RTM), Drimarene (RTM), Cibacron (RTM), Levafix (RTM) and the Remazol (RTM) that derives from ICI, Sandoz, Ciba-Geigy, Bayer and Hoechst respectively.

The natural dye of the present invention definition and vegetable colour comprise Flos Impatientis (mignonettetree (Lawsonia alba)), Flos Matricariae chamomillae (moral Flos Chrysanthemi (Matricaria chamomila) or Anthemis nobilis), indigo, logwood and Endocarpium Juglandis extract.

Face and imitate hair dyes or the coloring hairs purificant generally includes such dye molecule, they too big so that can not diffuse to dry in and can only act on the outside of hair.They are generally used by disposable method, make dye solution in the hair surface drying in the method.Therefore, these dyestuffs not too can tolerate washing or the cleaning of using surface-active substance confrontation hair to be carried out usually, are easier to eccysis from the hair relatively.Any hair dyes that faces effect all is applicable to compositions of the present invention, describes below and preferably faces the example of imitating hair dyes.Facing under the situation of imitating dyestuff, these dyestuffs among the present invention preferably use with oxidative dyestuff and do not use separately.

The purple redness

Yellow indigo plant-purple

Semipermanent hair dyes is that molecule and effect are imitated the hair purificant less than facing usually, but generally greater than permanent (oxidation) hair dyes.Usually, semipermanent hair dyes to be to be similar to the mode effect of oxidative dyestuff, and promptly they have and diffuse to dry potentiality.But the molecule of semipermanent dyestuff is generally less than above-mentioned conjugated oxidative dyestuff molecule, so they have and be introduced into, then the tendency that diffuses out once more from the hair gradually.Simple hair washing and cleaning action will help this process, be washed off from hair largely usually through 5-8 the semipermanent dyestuff in washing back.Any semipermanent dye system all is applicable to the present composition.Be applicable to that the semipermanent dyestuff in the present composition is HCBlue2, HC Yellow4, HC Red 3, Disperse Violet 4, Disperse Black 9, HC Blue7, HC Yellow 2, Disperse Blue 3, Disperse violet 1 and composition thereof.Enumerate the example of semipermanent dyestuff below:

Blue

Yellow

Red

Typical semipermanent dye system is mixed with big and little coloured molecule simultaneously.Because root of hair is to the hair thickness inequality of sending out slightly, micromolecule will and be sent out and locate diffusion slightly at root of hair, but be difficult for remaining in send out slightly in, bigger molecule then only can diffuse to head slightly usually.Help to neutralize in conjunction with the dye molecules of different sizes and obtain from root of hair to the level dyeing of sending out slightly in the washing process subsequently in initial hair dyeing process.

Oxidant

The present composition preferably also comprises at least a oxidant, and this oxidant can be inorganic or organic oxidizing agent.The content of oxidant preferably account for composition weight about 0.01% to about 10%, preferred about 0.01% to about 6%, more preferably from about 1% to about 4%.

Inorganic oxidizer

Being used for preferred oxidant of the present invention is the inorganic peroxygen oxidising agent of crossing.The inorganic peroxy oxidant should be used in the composition for hair dying safely and effectively.Preferably, when compositions of the present invention is the form of liquid form or expection use, be applicable to that inorganic peroxy oxidant of the present invention will be dissolved in the compositions of the present invention.Preferably, be applicable to that peroxygen oxidising agent excessively of the present invention will be water miscible.The water-soluble oxidizers of the present invention's definition is meant at 25 ℃ the material (" Chemistry " C.E.Mortimer.5th Edn.p277) of the dissolubility in the 1000ml deionized water about about 10g.

Be used for the inorganic peroxide that inorganic peroxy oxidant of the present invention normally can produce peroxide at aqueous solution.The inorganic peroxy oxidant is known in the art, comprise hydrogen peroxide, inorganic base metal peroxide such as sodium metaperiodate, perbromic acid sodium and sodium peroxide, and inorganic perhydrate salts oxide such as perboric acid, percarbonic acid, peroxophosphoric acid, cross the alkali metal salt of silicic acid, persulfuric acid etc.These inorganic perhydrate salts can add with forms such as monohydrate, tetrahydrates.As required, can use the mixture of two or more these class inorganic peroxy oxidants.Though alkali metal bromate and iodate all are applicable to the present invention, bromate is preferred.Be particularly preferred in the present composition is hydrogen peroxide.

In preferred composition of the present invention, the content range of inorganic peroxy oxidant account for composition weight about 0.01% to less than 6%, preferred about 0.01% to about 4%, more preferably from about 1% to about 4%, more preferably from about 2% to about 3%.

Preformed organic peroxide acid

Except that the inorganic peroxy oxidant, compositions of the present invention can comprise one or more preformed organic peroxy acid oxidants, and perhaps available organic peroxy acid oxidant substitutes the inorganic peroxy oxidant.

The suitable organic peroxy acid oxidant that is used for composition for hair dying of the present invention has following formula:

R-C(O)OOH

Wherein R is selected from saturated or undersaturated, replacement or the alkyl with 1-14 carbon atom, aryl or alkaryl unsubstituted, straight or branched.

Be applicable to that the class organic peroxide acid among the present invention is the chemical compound with amide replacement of following general formula:

Or

R wherein ¹Be the alkyl or the alkaryl of the saturated or undersaturated 1-14 of having carbon atom, perhaps aryl; R ²Be the alkyl or the alkaryl of the saturated or undersaturated 1-14 of having carbon atom, perhaps aryl; R ⁵Be the alkyl or the alkaryl of the saturated or undersaturated 1-10 of having the carbon atom of H, perhaps aryl.EP-A-0 has described the organic peroxy acid compound that this class amide replaces in 170,386.

Other suitable organic peroxide acid oxidant comprises peracetic acid; cross n-nonanoic acid; nonyl-amido is crossed oxy hexanoic acid (NAPCA); benzylhydroperoxide; metachloroperbenzoic acid; the diperoxy M-phthalic acid; one peroxide phthalic acid; the peroxide lauric acid; hexane sulfonyl Perpropionic Acid; N; N-O-phthalic acylamino-peroxide caproic acid; one crosses succinic acid; the pelargonyl group oxybenzoic acid; dodecane diacyl one benzoyl hydroperoxide; the nonyl amide of peroxide adipic acid; diacyl and four acyl peroxides, especially diperoxy dodecanedioic acid; diperoxy tetracosandioic acid and diperoxy hexadecandioic acid (hexadecane diacid) and derivant thereof.One-and two cross Azelaic Acids ,-and two cross brassylic acids and N-O-phthalic acylamino-peroxide caproic acid and derivant thereof and also be applicable to the present invention.

Preformed organic peroxy acid oxidant should be used for the present composition safely and effectively.Preferably, when compositions of the present invention is liquid form and expection type of service, be applicable to that preformed organic peroxy acid oxidant of the present invention dissolves in the compositions of the present invention.Preferably, be applicable to that organic peroxy acid oxidant of the present invention is water miscible.The preformed organic peroxy acid oxidant of water solublity of the present invention's definition is meant at 25 ℃ the material (" Chemistry " C.E.Mortimer.5th Edn.p277) of the dissolubility in the 1000ml deionized water about about 10g.

Be applicable to that preferred peroxy acid material of the present invention is selected from peracetic acid and crosses n-nonanoic acid and their mixture.

When having preformed organic peroxy acid oxidant, its content preferably account for composition for hair dying weight about 0.01% to about 8%, more preferably from about 0.1% to about 6%, most preferably from about 0.2% to about 4%, especially preferred about 0.3% to about 3%.

When having inorganic peroxy oxidant and preformed organic peroxide acid in the compositions of the present invention, the weight ratio of inorganic peroxy oxidant and preformed organic peroxide acid is preferably about 0.0125: 1 to about 500: 1, more preferably from about 0.0125: 1 to about 50: 1.

Except being applicable to inorganic peroxy oxidant of the present invention and preformed organic peroxy acid oxidant, compositions of the present invention can randomly comprise other organic peroxide, as urea peroxide, tripolycyanamide peroxide and their mixture.When having organic peroxide, its content be account for composition weight about 0.01% to about 3%, preferred about 0.01% to about 2%, more preferably from about 0.1% to about 1.5%, most preferably from about 0.2% to about 1%.

Colouring compositions of the present invention can be mixed with has very wide pH scope, for example about 2 to about 13, but consider from the angle that the compositions that reduces infringement and reduce skin contamination is provided, compositions is preferably prepared when hanging down pH, preferred pH is about 2 to about 7, preferred about 2.5 to about 6, more preferably from about 3 to about 6, also more preferably from about 3.5 to about 5.5, and about in particular 4 to about 5.5.Compositions of the present invention can also be prepared under high pH, is generally about 8 to about 12, preferred about 9 to about 11.

Compositions can comprise one or more optional buffer agent and/or hair swellers (HSA).Can use several different pH regulator agent to regulate the pH value of final composition or its any component part.Yet preferred composition of the present invention is substantially free of additional buffer agent and hair sweller, and promptly they comprise and are less than approximately 1%, preferably are less than 0.5%, more preferably are less than this class material of about 0.1% (weight).

PH value can use the processing angle azelon, especially known acidulant in people's hair field, adjust as inorganic and organic acid, described acid is hydrochloric acid for example, tartaric acid, citric acid, succinic acid, phosphoric acid and carboxylic acid or sulfonic acid such as ascorbic acid, acetic acid, lactic acid, sulphuric acid, formic acid, ammonium sulfate and sodium dihydrogen phosphate/phosphoric acid, sodium hydrogen phosphate/phosphoric acid, potassium chloride/hydrochloric acid, phthalic acid potassium dihydrogen/hydrochloric acid, sodium citrate/hydrochloric acid, potassium citrate dihydrogen/hydrochloric acid, potassium citrate dihydrogen/citric acid, sodium citrate/citric acid, sodium tartrate/tartaric acid, sodium lactate/lactic acid, sodium acetate/acetic acid, sodium hydrogen phosphate/citric acid and sodium chloride/glycine/hydrochloric acid, succinic acid and their mixture.

The example of ealkaline buffer is an ammonium hydroxide, ethamine, di-n-propylamine, triethylamine and alkane diamine are as 1, the 3-diaminopropanes, anhydrous alkaline alkanolamine as one-or two-ethanolamine, the preferred amino for example dimethylaminoethanol of those amine of being replaced fully of going up, polyalkylenepolyamines such as diethylenetriamines or heterocyclic amine such as morpholine and alkali metal hydroxide such as sodium hydroxide and potassium hydroxide, alkaline earth metal hydroxide such as magnesium hydroxide and calcium, basic amino acid such as L-arginine, lysine, alanine, leucine, isoleucine, hydroxylysine and histidine and alkanolamine such as dimethylaminoethanol and aminoalkyl propylene glycol and their mixture.Can dissociate in water except that ammonium carbonate or aminoquinoxaline forms HCO ₃-chemical compound (hereinafter referred to as " ion formation chemical compound ") also be applicable to the present invention.It is Na that suitable ion forms examples for compounds ₂CO ₃, NaHCO ₃, K ₂CO ₃, NH ₄HCO ₃, CaCO ₃And Ca (HCO ₃) and their mixture.

Coloring hairs of the present invention and care composition can comprise the final composition that contains hair colourant blended together before being applied on the hair and conditioner or can comprise the one-component system as described hereinafter.Therefore, compositions of the present invention can comprise the dyeing suit with many independent components.

In oxidation that comprises part inorganic peroxy oxidant such as hydrogen peroxide and dyeing suit (this part can exist with solid or liquid form), can use buffer agent solution with stable peroxide hydrogen.Because hydrogen peroxide is at 2 to 4 times buffer agents stable, that therefore preferred use has this pH value scope of pH value.Diluted acid is the peroxide buffer agent that suits.

Diluted acid is suitable hydrogen peroxide buffer agent.

Catalyst

Composition for hair dying of the present invention randomly contains the catalyst that contains transition metal of the preformed peroxy acid oxidant that is useful on catalysis inorganic peroxy oxidant and chooses wantonly.The suitable catalyst that is used for the present invention is to be disclosed among the WO 98/27945 those, and the document is introduced the present invention as a reference.

Heavy metal ion chelating agent

Colouring compositions of the present invention can comprise the heavy metal ion chelating agent as optional components.Among the present invention, heavy metal ion chelating agent is meant the composition that acts on chelating agen (chelating or removing) heavy metal ion.These components also can have calcium and magnesium sequestering power, but preferably in conjunction with heavy metal ion, show selectivity as ferrum, manganese and copper.In composition for hair dying of the present invention, this class chelating agen helps the controlled oxidation effect and makes hair dyeing product have stability for storage.

The content of heavy metal ion chelating agent generally accounts for about 0.005% to about 20%, preferred about 0.01% to about 10%, more preferably about 0.05% to about 2% of composition weight.

Suitable chelating agen is disclosed among the WO 98/27945, and the document is introduced the present invention as a reference.

Thickening agent

It is about 0.05% to about 20% that colouring compositions of the present invention can comprise weight percentage in addition, and preferred about 0.1% to about thickening agent of 10%, more preferably about 0.5% to about 5%.Be applicable to that the thickening agent in the present composition is selected from oleic acid, spermol, oleyl alcohol, sodium chloride, spermaceti/stearyl alcohol, stearyl alcohol, synthetic thickening agent such as Carbopol, Aculyn and Acrosyl and composition thereof.Being used for preferred thickener of the present invention is Aculyn 22 (RTM), steareth-20 methacrylate copolymer; Aculyn 44 (RTM), polyurethane resin and Acusol 830 (RTM) can derive from Rohm and Haas, Philadelphia, PA, the acrylate copolymer of USA.Be applicable to that other thickening agent of the present invention comprises sodium alginate and arabic gum, perhaps cellulose derivative is as the sodium salt or the acrylate copolymer of methylcellulose or carboxymethyl cellulose.

Diluent

Water is the preferred diluent of the present composition.Yet the present composition also can comprise one or more solvents as additional diluent.The solvent that is applicable to colouring compositions of the present invention generally be selected from water miscible and to harmless those of skin.The solvent that is suitable for use as additional diluent of the present invention comprises C ₁-C ₂₀Monohydric alcohol or polyhydric alcohol and their ether, glycerol, wherein monohydric alcohol and dihydroxylic alcohols and ether thereof are preferred.In these chemical compounds, the pure residue that comprises 2-10 carbon atom is preferred.Therefore, preferred group comprises ethanol, isopropyl alcohol, normal propyl alcohol, butanols, propylene glycol, ethylene glycol monoethyl ether and composition thereof.Water is the preferred main diluent of the present composition.Define as the present invention, main diluent is meant that the content of water is higher than the total content of any other diluent.

The content of diluent preferably account for composition weight about 5% to about 99.98%, preferred about 15% to about 99.5%, more preferably at least about 30% to about 99%, especially preferred about 50% to about 98%.

Enzyme

The another kind of added substance that is used for colouring compositions of the present invention is one or more enzymes.Suitable enzyme comprises commercially available lipase, at (cutinases), amylase, neutrality and alkaline protease, esterase, cellulase, pectase, Lactose enzyme and the peroxidase that mixes usually in the cleaning compositions.US patent 3,519,570 and 3,533,139 and WO 98/27945 in suitable enzyme has been discussed, above-mentioned document is introduced the present invention as a reference.

Surfactant materials

Compositions of the present invention can comprise a kind of surfactant system in addition.The appropriate surfactant that is included in the present composition generally has the about 8 lipophilic chains to about 22 carbon atoms, and they are selected from anion, cation, nonionic, both sexes, zwitterionic surfactant and composition thereof.Be applicable to that surfactant of the present invention is to be disclosed among the WO 98/27945 those, the document is introduced the present invention as a reference.

Optional materials

Multiple additional optional, materials can be added in the composition for hair dying of the present invention, and their content separately accounts for about 0.001% to about 5%, preferred about 0.01% to about 3%, more preferably about 0.05% to about 2% of composition weight.This class material comprises protein and polypeptide and derivant thereof; But the antiseptic of water solublity or solubilising, for example methyl, ethyl, propyl group and the butyl ester of DMDM Hydantoin, Germall 115, hydroxy benzoic acid, EDTA, Euxyl (RTM) K400; Natural antiseptic agent, for example benzylalcohol, potassium sorbate and bisabolol, benzoic acid, sodium benzoate and 2-phenyl phenol; Antioxidant, for example sodium sulfite, hydroquinone, sodium sulfite, sodium metabisulfite and TGA, sodium dithionite, erythrobic acid and other sulfur alcohol; The pigment remover is as oxalic acid, Sulfation Oleum Ricini, salicylic acid and sodium thiosulfate; The H2O2 stabilizing agent, tin compound for example is as sodium stannate, stannic hydroxide and tin octoate; Monoacetylaniline; Phenacetin; Silica sol, as magnesium silicate, Hydroxyquinoline Sulfate, sodium phosphate and tetrasodium pyrophosphate; And ρ-hydroxy benzoic acid; Humidizer, as hyaluronic acid, chitin, and starch-grafted sodium polyacrylate, as available from Celanese Superabsorbent Materials, Portsmith, VA, USA and be recorded in US-A-4,076,663 Sanwet (RTM) IM-1000, IM-1500 and IM-2500 and methylcellulose, starch, high fatty alcohol, paraffin oil, fatty acid etc.; Solvent; Antibacterial is as Oxeco (phenoxy group isopropyl alcohol); The low temperature phase modifier, as ammonium ion source (as NH ₄Cl); Viscosity-control additive is as magnesium sulfate and other electrolyte; Quaternary ammonium compound, as distearyl-, dilauryl-, the dihydro Adeps Bovis seu Bubali-, alkyl dimethyl ammonium chloride, two cetyl diethyl ethyl sulfuric acid ammoniums, two Adeps Bovis seu Bubali dimethyl methyl ammonium sulfate, two Semen sojae atricolor alkyl-dimethyl ammonium chlorides and two coco dimethyl ammonium chloride; Hair conditioner, as polysiloxanes, higher alcohol, cationic polymer etc.; Enzyme stabilizers is as water-soluble calcium source or borate family; Coloring agent; TiO ₂And TiO ₂The Muscovitum of-coating; Spice and spice solubilizing agent; Zeolite, for example Valfour BV400 and derivant thereof and Ca ²⁺/ Mg ²⁺Chelating agen, as the multi-carboxylate, aminopolycanboxylic acid's salt, polyphosphate, amino polyphosphate etc., and water softener are as sodium citrate.

The carding technology method of testing

Mentioned as mentioned, coloring hairs of the present invention and care composition must be 1.2 or higher in the average combing exponential quantity (Average Combing Index Value) of 6 circulations (cycle) back on wet hair, preferred 1.5 or higher, more preferably 1.8 or higher, most preferably 2.0 or higher, this is to measure by carding technology method of testing (Combing Technical Test Method) hereinafter described.

Coloring hairs of the present invention and care composition also preferably in 1 circulation (cycle) back the combing exponential quantity on the wet hair greater than 1.1 and after 6 circulations the combing exponential quantity on wet hair greater than 1.1.

Bunch (the hair switches) that use in this method of testing is the maiden's of burnt umber hair (medium brown virgin hair), weighs 6 grams, long 10 inches.Handle 5 such send out bunch with coloring hairs of the present invention and care composition according to following process.

Bunch handle sending out with coloring hairs and care composition

Want tested coloring hairs and care composition just to make before use, (for example mix with the second kind of component that comprises hydrogen peroxide and prepare) by first kind of component that will comprise the oxidative hair dyeing agent.To send out a bunch top that is suspended on groove, and be get wet hair 30 seconds of the water of 8-15 grain (grain) with the pressure hardness of 100 and 1.5pgm, in this method of testing, 1 lattice are equivalent to calcium and/or the magnesium ion of 17.1ppm.(hardness of water is identical always in this experiment).Excessive water during extruding is set out bunch.The 1.2 gram colouring compositions that will test are applied to the top of sending out bunch and spread into the bottom equably downwards, it are rubbed to smear then and set out bunch, continue 30 seconds, and continue to stay and send out bunch last 4.5 minute (the application time was total up to 5 minutes).Send out bunches 30 seconds with 100 water rinse.Excessive water during extruding is set out bunch.

Above-mentioned processing constitutes a circulation.This circulation repeats up to 6 times, carries out combing after each circulation and measures.Employed in the present invention term " combing exponential quantity " be the regulation cycle-index after measured combing exponential quantity (CIV).Employed in the present invention " average combing exponential quantity " calculated in the following manner:

Average combing exponential quantity=(CIV after CIV+6 the circulation after CIV+5 the circulation after CIV+4 the circulation after CIV+3 the circulation after CIV+2 the circulation after 1 circulation)/6

Combing is measured:

Devices needed:

Instron 5543 tensions test justice with IBM compatible computer and Merlin Profiler software

The Instron load cell has the 5N maximum capacitor of crosshead adapter

Line (string) with Small clamp

Be used to carry out the special combing clamper that combing is measured

295 Hercules Saw Cut2 Combs, combing " wide tooth " is (4 teeth/centimetre, 9 centimeter length) and " narrow tooth " partly (10 teeth/centimetre, 8 centimeter length) partly

For each test, the each processing used 5 bunches, and each bunch carries out 5 and independently measure.Send out and bunch to handle with the above-mentioned colouring compositions that will test.As long as after finishing the single treatment circulation, just measure wet bunch.Load cell is assembled on the crosshead of Instron tester.Remove any load cell from the bottom of tester.The line that will have Small clamp is assembled on the load cell.With screw the combing clamper is fixed on the Instron tester bottom.Open the Instron tester, and make pick off balance (equilibrate).Open computer, download Merlin Profiler software.[Merlin Profiler software is available from Instron company].It is as follows to test relevant condition:

Extension speed: 15mm/ second

Development length: 240mm

Reading interval: 0.5sec

The crosshead of Instron tester is set to the starting position.This position should guarantee that be 20mm from comb to the distance of sending out bunch top.(rack) takes off each bunch from frame, once and with narrow stripping fork reason once (repeats combing as required, up to not tangling) with the canine tooth combing.New comb is put on the clamper, and purpose is that narrow toothed portion can be used in combing.Send out and bunch to be fixed on the clip balance load cell.Use the narrow toothed portion Hair Fixer bunch of comb then, and will send out by deflector (deflector) and bunch be fixed on correct position.Method of testing begins by activating mobile crosshead.

Must comprise a tester in the test, this tester is with water-wet 30 seconds untreated bunch (carrying out under the condition of using colouring compositions).

In case after having analyzed all bunch, use following equation to calculate the combing merit: (equation 1)

Wherein F be send out bunch with comb stretching x millimeter apart from the time load cell pressure load

The combing merit of average each bunch.Use 5 bunches the average reading (merit [processing]) of meansigma methods to produce each processing.The statistical method of use standard is analyzed the significant difference (significant differences) of these readings between each the processing.

The combing merit of reality is converted into the index reading, based on the result who obtains by the internal reference thing (equation 2).

(equation 2)

The result

Several coloring hairs of the present invention and conditioning products and several commercially available hair products are applied in the above-mentioned method of testing.The combing exponential quantity that obtains is as follows:

Treatment product	1 circulation	2 circulations	3 circulations	4 circulations	5 circulations	6 circulations	Average CIV
Treatment product	1 circulation	2 circulations	3 circulations	4 circulations	5 circulations	6 circulations	Average CIV	Embodiment A ¹	????1.6	????1.7	????2.0	????2.2	????2.1	????2.1	????1.95
Embodiment B ²	????1.1	????0.7	????0.8	????0.9	????0.8	????0.9	????0.87	Embodiment A ¹	????1.6	????1.7	????2.0	????2.2	????2.1	????2.1	????1.95
Embodiment B ²	????1.1	????0.7	????0.8	????0.9	????0.8	????0.9	????0.87	Embodiment C ³	????0.9	????1.1	????1.1	????0.9	????0.9	????0.8	????0.95
Embodiment D ⁴	????1.1	????1.1	????1.2	????0.9	????0.9	????0.7	????0.98	Embodiment C ³	????0.9	????1.1	????1.1	????0.9	????0.9	????0.8	????0.95
Embodiment D ⁴	????1.1	????1.1	????1.2	????0.9	????0.9	????0.7	????0.98	Embodiment E ⁵	????1.1	????0.8	????0.8	????0.8	????0.8	????0.7	????0.83
Embodiment F ⁶	????1.6	????1.7	????1.8	????2.1	????2.0	????1.9	????1.85	Embodiment E ⁵	????1.1	????0.8	????0.8	????0.8	????0.8	????0.7	????0.83
Embodiment F ⁶	????1.6	????1.7	????1.8	????2.1	????2.0	????1.9	????1.85	Embodiment G ⁷	????1.1	????1.1	????1.4	????1.2	????1.3	????1.1	????1.2

1. embodiment A is coloring hairs of the present invention and care composition, prepare by following method: mix the compositions of following embodiment XII and the Pantene Pro-V VitalizingConditioner that commercially available balance is used for common hair, wherein added hydrogenperoxide steam generator, thereby the amount of the hydrogen peroxide in the conditioner composition is 6% of a conditioner composition weight.The compositions of embodiment XII and the mixed of the care composition that comprises hydrogen peroxide with 1: 1

2. Embodiment B is the outer commercially available hair colouring compositions-L ' Oreal Castings Light BrownNo.33 of the scope of the invention (getting rid of the In-box conditioner)-Batch LU211

3. Embodiment C is the outer commercially available hair colouring compositions-Goldwell Colourance pH6.8 system No.5N-Batch D1458P of the scope of the invention

4. embodiment D is the outer commercially available hair colouring compositions-Kao Corp Lavenus NeoYellow Nuance-Batch 1799 of the scope of the invention

5. embodiment E is outer commercially available hair colouring compositions-L ' Oreal Excellence No.5 (not comprising the In-box the conditioner)-Batch PU344 of the scope of the invention

6. embodiment F is coloring hairs of the present invention and care composition, be by with the compositions of following embodiment XII and commercially available humidification be used for do or the Pantene Pro-V Vitalizing Conditioner of damaged hair, wherein added hydrogenperoxide steam generator, thereby the amount of the hydrogen peroxide in the conditioner composition is 6% of a conditioner composition weight.The compositions of embodiment XII and the mixed of the compositions that comprises hydrogen peroxide with 1: 1

7. embodiment G is the hair colouring compositions of the outer following embodiment XII of the scope of the invention

Estimate priming color and color change

The Δ E value that preferred coloring hairs of the present invention and care composition provide is greater than about 8, is preferably greater than approximately 10, and more preferably greater than about 12, most preferably greater than about 15, particularly greater than about 20, this is according to following test determines.

The staining technique analytical method

Evaluate color changes

Adopt Hunter LabScan spectrophotometer to measure priming color and change color with coloring hairs of the present invention and the painted substrate of care composition (hair/skin) as measuring device.Be used to represent that the value of change color degree on arbitrary concrete substrate is Δ E value (Δ E).As actual summation (factual sum) expression of the Δ E value of preceding definition by L, a and b value, thereby:

ΔE＝(ΔL ²+Δa ²+Δb ²) ^1/2

The CIELab color gamut (Space) that L, a, b representative are defined by Commission Internationale de L ' Eclairage (CIE).According to this definition, L is measuring of brightness and darkness, and wherein, L=100 is equivalent to white, and L=0 is equivalent to deceive.And then ' a ' is measure (shade of color (hue)) of red and green quotient (quotient), and red on the occasion of expression, negative value is represented green.' b ' is measure (shade of color) yellow and blue quotient, and yellow on the occasion of expression, negative value is represented indigo plant.

Hunter LabScan colorimetric is counted the full scan spectrophotometer, and wave-length coverage is 400-700nm, with " L ", " a " and " b " value record the test hair send out bunch color of (lock of hair).Instrument is set to: pattern-0/45; Port sizes-1/2 inch; Observe size-1/2 inch; Light-D65; Viewing area-10 °; UV lamp/light filter-nothing.Hair is placed in the sample holder that is designed for the clamping hair, and the hair orientation is consistent in measuring process.Can use suitable tintometer, but must guarantee that hair does not move during measuring.Must guarantee that hair spreads out to cover port in the color measuring process.On a bunch clamper, gauge point is set to instruct the location of port clamper.Be marked as linear array on gauge point and the port, read reading in each site.

Each bunch is carried out 8 times measure every side 4 times.

The standard hair is sent out bunch

The present composition can be used for dyeing coloured hair of all colours, type and condition.For illustrative purposes, use Lycoperdon polymorphum Vitt to send out bunch.Can measure these standard hair switches, with their roughly L, a, b value representation.

L?????????????a????????????b

Lycoperdon polymorphum Vitt sends out bunches 75 4 27

Hair is sent out a bunch colouring method-single administration

For having hair dyed, be that 4 about 8 inches grams are sent out and bunch hung on suitable container top with length, moistening continued to carry out 30 seconds.Setup test is with dyeing product (promptly mixing the component of each bottle when using) then, and products that will about 5.6 grams are applied directly in the test bunch.Product dyed thereby rubbed to be put on to send out bunch to go up continue, stay then to send out bunch to go up and continue about 20 minutes up to 1 minute.After about 2 minutes, use the hair after the hair drier drying dyes with mobile water rinse.Use the HunterLabScan spectrophotometer to dye then and color show value that exsiccant test is sent out bunch.

Hair is sent out a bunch colouring method-repeatedly use

For having hair dyed, be that 4 about 8 inches grams are sent out and bunch hung on suitable container top with length, moistening continued to carry out 30 seconds.Setup test is with dyeing product (promptly mixing the component of each bottle when using) then, and product that will about 0.4 gram is applied directly in the test bunch.Product dyed thereby rubbed to be put on to send out bunch to go up continue, stay then to send out bunch to go up and continue about 1 minute up to about 30 seconds.With mobile water rinse after about 2 minutes, use sending out bunch after the dry dyeing of hair drier.The color of using assessment dyeing of HunterLabScan spectrophotometer and exsiccant test to send out bunch then shows situation.Repeat said process again 13 times.Use Hunter LabScan spectrophotometer to estimate final color show value and the representative that exsiccant test sends out bunch and use dyeing and the care composition of using for 14 times.

The present invention is represented by following non-restrictive example.In these embodiments, unless otherwise indicated, all concentration all be based on 100% active substance and all be percentage by weight, abbreviation has a following implication.

Example I-XV

Example I-XV is the compositions that comprises the oxidative coloration agent.With any in these compositionss can both be with the compositions of embodiment XVI with 1: 1 mixed so that coloring hairs of the present invention and care composition to be provided. Composition I II III IV V VI VII VIIIDyestuff pre-composition: water 45.9 45.77 45.83 44.6 44.56 43.9 44.91 43.31 citric acids 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7EDTA four sodium 0.19 0.19 0.19 0.19 0.19 0.19 0.19 0.19 sodium sulfite 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2pPD that remove mineral matter¹0 0.1 0 0.24 0 0.4 0.332 1.498mPD sulfate ²0 0.001 00000 0pAP ³0 0.012 0 0.27 0.75 0.9 0.332 0.22A3HP ⁴000 0.6 0.6 0.6 0 0.6mAP ⁵0 0.012 000 0.1 00 resorcinols, 0000000 04A2HT ⁶0 0.006 0.04 0000 0o-AP ⁷00 0.04 000 0.332 032%NaOH, 00000000 ascorbic acid, 000 0.2 000 0.3 dyestuff washings: water 88888888 emulsion matrixes: water 29.77 29.77 29.77 29.77 29.77 29.77 29.77 29.77Ceteareth-25 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 cetanols 2.25 2.25 2.25 2.25 2.25 2.25 2.25 2.25 stearyl alcohols 2.25 2.25 2.25 2.25 2.25 2.25 2.25 2.25 Sodium Benzoates 0.09 0.09 0.09 0.09 0.09 0.09 0.09 0.09 phenoxetol 0.108 0.108 0.108 0.108 0.108 0.108 0.108 0.108EDTA four sodium 0.036 0.036 0.036 0.036 0.036 0.036 0.036 0.036pH conditioning agent: water to 100 to 100 to 100 to 100 to 100 to 100 to 100 to 10050% citric acids 0000000 032%NaOH 0 1.8 2 1.5 0.7 0.5 1.75 0.467Composition IX X XI XII XIII XIV XVDyestuff pre-composition: water 43.31 42.21 43.81 42.51 41.38 43.84 38.45 citric acids 1.7 1.7 1.7 1.7 1.7 1.7 1.7EDTA four sodium 0.19 0.19 0.19 0.19 0.19 0.19 0.19 sodium sulfite 0.2 0.2 0.2 0.2 0.2 0.2 0.2pPD that remove mineral matter¹0.8 0.6 0 0.8 1.9 0.95 2 mPD sulfate ²000000 0.4pAP ³0.6 1.498 1.498 1.498 0.54 0.27 02A3HP ⁴0000 0.44 0.22 0mAP ⁵0 0.6 0.6 0.5 0.048 0.024 0 resorcinols, 000000 0.454A2HT ⁶000000 0o-AP ⁷000000 032%NaOH, 000000 3.003 ascorbic acid, 0.6 10 0.6 1.6 0.6 1.6 dyestuff washings: water 8888888 emulsion matrixes: water 29.77 29.77 29.77 29.77 29.77 29.77 29.77Ceteareth-25 1.5 1.5 1.5 1.5 1.5 1.5 1.5 cetanols 2.25 2.25 2.25 2.25 2.25 2.25 2.25 stearyl alcohols 2.25 2.25 2.25 2.25 2.25 2.25 2.25 Sodium Benzoates 0.09 0.09 0.09 0.09 0.09 0.09 0.09 phenoxetol 0.108 0.108 0.108 0.108 0.108 0.108 0.108EDTA four sodium 0.036 0.036 0.036 0.036 0.036 0.036 0.036pH conditioning agent: water to 100 to 100 to 100 to 100 to 100 to 100 to 10050% citric acids 000000 032%NaOH 1.8 1.5 0.5 1.6 3.7 1.1 2

1. p-phenylenediamine (PPD) 2HCl

2. m-diaminobenzene. sulfate

3. para-aminophenol

4.2-amino-3-pyridone

5. m-aminophenol

6.4-amino-2-hydroxy-methylbenzene

7. o-aminophenol

In the above-described embodiments, water is as diluent.But, in the embodiment that changes, account for about 0.5% to about 50% water of water weight among the embodiment can be enough as lower alcohol for example ethylene glycol, ethylene glycol monomethyl ether, diethylene glycol, carbiphene, propylene glycol, 1, ammediol, ethanol, isopropyl alcohol, glycerol, butyl cellosolve, ethoxydiglycol, hexanediol, polyglyceryl-2-oleyl ether and their mixture partly replace.

The chemical compound of example I-XV is prepared as follows:

Prepare the dyestuff pre-composition by under agitation in container, adding deionized water, sodium sulfite, EDTA four sodium, ammonium acetate and dipropyl glycol.In this container, add dye substance then, mix, can heat as required until dissolving.After dissolving fully,, add ascorbic acid then with the solution cool to room temperature.

The pH pre-composition prepares by in container sodium hydroxide and deionized water being mixed.

Emulsion matrix is to prepare by adding deionized water and begin to stir when being heated to 80 ℃ in container.Add EDTA four sodium then, and then add sodium benzoate, dissolve these components.Next add ceteareth.Open homogenizer, add spermol and stearyl alcohol, keep temperature to be higher than 80 ℃.After the homogenize, when adding phenyl phenol, mixture is cooled to 60 ℃.At 40 ℃, close homogenizer and blender, with mixture thickened 60 minutes.

Final dyestuff substrate is prepared as follows: by add emulsion matrix in container, next add dyestuff pre-composition solution, the mixture that mixes gained is until evenly.Add ammonium hydroxide, next mix and add the pH pre-composition.Add entry up to 100%, mix up to evenly.

The product of above-mentioned any embodiment I-XV is mixed with care composition among following embodiment XVI or the embodiment XVII with 1: 1 ratio.

Embodiment XVI is the Pantene Pro-V VitalizingConditioner that commercially available balance is used for common hair, wherein added hydrogenperoxide steam generator, thereby embodiment XVI comprises the hydrogen peroxide of 6% weight.Embodiment XVII be commercially available humidification be used for do or the Pantene Pro-VVitalizing Conditioner of damaged hair, wherein added hydrogenperoxide steam generator, thereby embodiment XVII comprises the hydrogen peroxide of 6% weight.

By coloring hairs and the care composition that any compositions of example I-XV and embodiment XVI or embodiment XVII are obtained with 1: 1 mixed, complete color gamut is provided, promptly from the gold to black, provide outstanding hair-conditioning effect simultaneously.The compositions of embodiment also provides outstanding Lycoperdon polymorphum Vitt spreadability when using about 4 times as one week of hair care composition of routine, and outstanding root of hair spreadability.

Using method

Importantly colouring compositions is consumer easily and be convenient to the form for preparing and uses, can droplet not drop down from hair because oxidant must keep contact a period of time with hair, and this might cause eye or skin irritation.

For addressing the above problem, colouring compositions of the present invention can be the unitary package form, or for keeping the nested form of stability with the component independent packaging, and if desired, can mix immediately by user before being applied on the hair facing, perhaps mix the back and store, perhaps mix the back and use a part, store rest parts so that use in the future so that use in the future.

As indicated above, compositions of the present invention can be the unitary package form and be used by consumer.Such unitary package comprises the single compositions that contains hair colourant and hair conditioner.This compositions can directly be applied to hair and be need not any processing or mixing in advance by consumer, and a kind of simple, quick, the wieldy and hair dyeing and conditioning system of " chaotic " therefore is provided.Another advantage of this class one-component system is that it can be stored or reuse, and promptly unitary package can be included in the composition for hair dying that is enough in a period of time for the several use.In addition, compositions can also distribute from the packing that comprises two bag chambers, and wherein each bag chamber comprises a kind of component, wherein each independent component is mixed, perhaps in packing, carry out, perhaps outside packing, carry out, thereby form the uniform compositions that can be applied on the hair.

Therefore, the present invention provides the method with coloring hairs and conditioning on the other hand, wherein coloring hairs and care composition directly are applied on the wet hair, and next rinsing, wherein coloring hairs and care composition comprise:

(a) conditioner; With

(b) hair colourant;

Wherein the average combing exponential quantity of compositions is greater than 1.2, and this is by carding technology test determines mentioned above.

Dyeing of the present invention preferably is applied on the hair as conventional must the conditioning with the washing-off type compositions with care composition, and after the use from the hair flush away.Therefore, dyeing and care composition are easy to and are convenient to use under shower.Dyeing and care composition preferably are used on the hair and continue 0.5 minute to 5 minutes, and this depends on needed dye levels.The preferred time is 0.5-3 minute.Colouring compositions of the present invention preferably is used on the wet hair after washing hair with shampoo.

Suit

The present invention also provides the hair dyeing suit, and wherein this suit comprises and contains two or more independently component packages, and preferably also comprises the description how indication consumer uses this suit hair dyeing.In preferred embodiments, before being applied to hair, the component of mixing suit forms hair dyeing and care composition.In another embodiment, in a sequential manner each component is applied on the hair separately.

Preferred suit of the present invention comprises at least two kinds of components, and first component comprises the compositions of oxidisability and/or non-oxidizable hair colourant and conditioner, and second component comprises oxidant and conditioner.These components can be mixed immediately before being applied on the hair or can use separately facing by user.Also these components can be mixed, the compositions that reservoir gets is so that use or use the part of resulting composition in the future and store remaining composition so that use in the future.In one embodiment of the invention, the oxidisability component comprises the cream of the stabilisation that contains inorganic peroxy oxidant (normally hydrogen peroxide) and above-mentioned other material, makes that the ultimate density be used in the colouring compositions on the hair is about 0.05% to about 6% (weight).

In comprising the suit of two or more components, but these component independent packagings maybe can be packaged in the unitary package with a plurality of bags chamber, each the bag chamber comprise each independently component.

It is the packing with two bag chambers that the present invention preferably packs, and a bag chamber comprises first component that contains hair colourant, and another bag chamber comprises second component that contains oxidant.Any or two components can comprise conditioner in second component, and condition is that at least one component comprises conditioner.Two components or mix in packing are perhaps mixed outside packing.Importantly two components will fully be mixed to be provided for homogeneous coloring hairs and the care composition on the hair.Such packing provides the product that is easy to and is convenient to use under shower.

The example of suit of the present invention is the packing with two bag chambers, and the compositions of embodiment XVI or embodiment XVII is contained in a bag chamber, and another contains among example I-XV any one.This packing has the device of each in two kinds of components of hybrid limited amount in packing, and has the coloring hairs of distribution gained and the device of care composition.This suit also comprises the explanation of indicating consumer, indicates them using on the wet hair during in shower after the hair washing, replaces conventional care composition, preferred week 1-7 time, preferred week 2-4 time.

Claims

1. coloring hairs and care composition comprise:

(a) at least a conditioner; And

(b) at least a hair colourant;

Wherein the average combing exponential quantity of compositions on wet sending out is greater than 1.2, and this is by carding technology test determines as herein described.

2. according to the compositions of claim 1, wherein the average combing exponential quantity of said composition is greater than 1.5.

3. according to the compositions of claim 1 or 2, wherein the average combing exponential quantity of said composition is greater than 1.8.

4. according to each compositions among the claim 1-3, wherein conditioner is selected from cationic surfactant, cationic conditioning polymer, polysiloxanes conditioner, aliphatic alcohol, fatty acid and their mixture.

5. according to each compositions among the claim 1-4, wherein conditioner is selected from cationic surfactant, cationic conditioning polymer, insoluble polysiloxanes conditioner, fixed hydrocarbon ester, aliphatic alcohol and their mixture.

6. according to each compositions among the claim 1-5, wherein conditioner is the mixture of cationic conditioning polymer, polysiloxanes conditioner and aliphatic alcohol.

7. according to each compositions among the claim 1-6, comprise about 0.1% to about 25%, preferred about 1% to about 20%, more preferably from about 5% to about 20%, and particularly about 5% conditioner to about 15% weight.

8. according to each compositions among the claim 1-7, wherein hair colourant is the oxidative hair dyeing agent.

9. according to each compositions among the claim 1-8, also comprise account for composition weight about 0.01% to less than about 6%, preferred about 0.01% to about 4%, more preferably from about 1% to about 4%, also 2% to about 3% oxidant more preferably from about.

10. according to the compositions of claim 9, wherein oxidant is the inorganic peroxy oxidant.

11. according to the compositions of claim 9 or 10, wherein oxidant is a hydrogen peroxide.

12. according to each compositions among the claim 1-11, wherein the pH of compositions is about 2 to about 13, is preferably about 2 to about 7, more preferably about 9 to about 11.

13. according to each compositions among the claim 1-12, wherein the total amount of hair colourant is about 0.001% to about 5%, preferred about 0.01% to about 4%, more preferably from about 0.1% to about 3%, and most preferably from about 0.1% to about 1% weight.

14. according to each compositions among the claim 1-13, wherein the combing exponential quantity of compositions after circulation once is greater than 1.1, the combing value after 6 circulations is greater than 1.1.

15. be used for the compositions that simultaneously hair dyeed and nurses one's health, comprise:

(a) oxidative hair dyeing agent;

(b) oxidant;

(c) conditioning component;

Wherein conditioning component comprises about 0.1% to about 10% the insoluble polysiloxanes conditioner that accounts for composition weight, and/or about 0.1% cation opsonizing agent to about 10% weight, and/or about 0.1% straight-chain fatty alcohol to about 10% weight.

16. according to each compositions among the claim 1-15 with the purposes in dyeing of the mankind or animal hair and the conditioning.

17. the method to the mankind or animal hair dye and nurse one's health comprises each coloring hairs and care composition among the claim 1-15 is applied on the hair, rinses then.

18. coloring hairs and conditioning suit, comprise at least two kinds of components, first component comprises oxidant and optional conditioner, second component comprises oxidative hair dyeing agent and optional conditioner, condition is at least a conditioner that comprises in the described component, wherein before being applied on the hair, two kinds of components are mixed immediately each coloring hairs and care composition among the formation claim 1-15.

19. the coloring hairs and the conditioning products of packing, comprise the packing that contains at least two bag chambers, the first bag chamber comprises first component that contains the oxidative hair dyeing agent, the second bag chamber comprises second component that contains oxidant, wherein first component and second component were mixed in packing or outside the packing before being applied on the hair, so that coloring hairs and care composition to be provided, wherein coloring hairs and care composition comprise at least a conditioner and at least a hair colourant, and wherein the average combing exponential quantity that has of coloring hairs and conditioner is greater than 1.2, and this is by carding technology test determines as herein described.

20. according to the suit of claim 18, also comprise the initial colouring compositions that is suitable for providing priming color to hair, wherein the color that provides by hair color change compositions (a) has and the initial essentially identical tone of colouring compositions.