CN1412366A - Preparation method of composite fibre formed from glass fibre and polypropylene fibre - Google Patents
Preparation method of composite fibre formed from glass fibre and polypropylene fibre Download PDFInfo
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- CN1412366A CN1412366A CN 01127551 CN01127551A CN1412366A CN 1412366 A CN1412366 A CN 1412366A CN 01127551 CN01127551 CN 01127551 CN 01127551 A CN01127551 A CN 01127551A CN 1412366 A CN1412366 A CN 1412366A
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Abstract
The present invention relates to a production method of composite fibre formed from glass fibre and polypropylene fibre. Said method adopts high-temp. heat-setting process of stretched polypropylene fibre so as to greatly reduce shrinkability of polypropylene fibre. The adoption of modified polypropylene raw material can make glass fibre and polypropylene fibre interface obtain effective combination. In the composition fibre produced by said invented method additive quantity of glass fibre is large, its distribution is uniform and strength is high.
Description
One, technical field
The present invention relates to the galss fiber reinforced resin field of compound material, further relate to the manufacture method of the composite fibre that glass fibre and thermoplastic resin fibre be combined into.
Two, background technology
Because strengthening composite that various resin matrixes make, glass fibre has characteristics such as light weight, intensity height, electric insulation, corrosion-resistant, fire-retardant, long service life, worldwide be subjected at present paying attention to widely, particularly glass fibre strengthens thermoplastic resin such as polypropylene, polyethylene etc., because of its economy and impact flexibility thereof good, easy-formation, easily repair, easily regeneration waits premium properties, has occupied the leading position of polymer matrix composites in the quite a while.This composite is general to adopt glass chopped particle to mix with thermoplastic resin particle; extrude form by screw extruder then and make, the shortcoming of this method is: the glass fibre addition is not high, and intensity is low; the glass fibre skewness can not be controlled the orientation of glass fibre etc.US Patent specification US-5454846 discloses a kind of composite fibre manufacturing technique.In this technology, glass fibre flows out from mould and moves along a passage with certain speed, and thermoplastic fibre flows out from wire drawing machine and move along two passages with another speed, and two kinds of fibers become composite fibre after through the buncher boundlings.Owing to behind the thermoplastic fibre drawn shrinkage is arranged, make composite fibre have ripple, when being wound in coil, causing the winding difficulty because of fiber is bulk, and mix unequal a lot of adverse effect in addition.In order to address this problem, US Patent specification US-5454846 has adopted and has made the method for thermoplastic fibre translational speed greater than the glass fibre translational speed, makes thermoplastic fibre contraction back length with glass fibre in composite fibre consistent.Can make two kinds of mixed with fibers even on this technology theory, the effectively orientation of controlling fiber, the addition of raising glass fibre is enhanced product performance.Therefore but said method is wayward in actual production, fails to realize suitability for industrialized production all the time.In addition, polypropylene is a kind of non-polar polyolefinic, and is relatively poor with the compatibility of glass fibre, and it is difficult to form effective interface with glass fibre and combines.In order to give full play to the humidification of glass fibre, the glass fiber reinforced polypropylene composite material that obtained performance is good must manage to improve glass fibre and polyacrylic interface binding intensity.Because fiberglass surfacing contains a large amount of silanol bases, generally adopts sizing agent that glass fibre is directly soaked into, and mainly is the polypropylene film forming agent except that containing coupling agent in the sizing agent.This method strengthens the polar thermoplastic resin to glass fibre, because of coupling agent can to form chemical bond very effective with resin, but for glass fiber reinforced polypropylene, because of polypropylene is that non-polar resin can only make its interface binding intensity slightly improve.
Three, summary of the invention
In order to solve the fluffy problem of bringing because of the polypropylene fibre contraction of composite fibre and more effectively to improve glass fibre and polyacrylic interface binding intensity, the composite fibre that obtained performance is good, the present invention makes it reduce shrinkage by polypropylene fibre being carried out secondary hot-stretch and elevated temperature heat typing processing.Polypropylene fibre behind the drawn, great changes have taken place in aggregated structure, usually be in non-equilibrium state, but its structure and character time to time change, it is carried out the elevated temperature heat typing handle, can eliminate the internal stress and the de novo fault of construction that produce when stretching, make the final structure of fiber basicly stable, the character basic fixed, thus shrinkage factor is reduced greatly.Heat treatment temperature is 100-120 ℃, and preferred 110 ℃, the processing time is 5-10 second, preferred 6 seconds.The present invention is by using the method for polypropylene and modified polypropene mixed material, thereby make in the polypropylene fibre polar group with soak into after fiberglass surfacing generation chemical bond combine raising glass fibre and polyacrylic interface binding intensity, preferred maleic anhydride modified polypropylene, modified polypropene content is 3-8%, preferred 5%.
Four, the description of drawings and the specific embodiment
Technological process of the present invention and beneficial effect will be done with the specific embodiment in conjunction with the accompanying drawings and specify.
Accompanying drawing is a process flow diagram of the present invention.
The present invention adopts glass fibre formation system and polypropylene fibre formation system to be arranged in juxtaposition, and becomes silk respectively, planar stretch, Planar Compound, the method for collection silk bunchy.Specify as follows: the glass metal after the clarification flows out from bushing (1) and forms glass fibre (2), glass fibre cools off fast by spray cooling, apply sizing agent through a graphite roller baster (3) then, contain silane coupler and light trigger in the sizing agent.Bushing adopts rectangular design, to improve the diffusion area of fiber.The path that a glass metal is arranged on bushing makes glass metal keep uniform temperature by electrical heating.Drain board material is a platinum-rhodium alloy.Maintain a certain distance between the nozzle, make glass fibre become planar stretch.The polypropylene granules that contains maleic anhydride modified polypropylene 5% joins in the screw extruder from funnel, add antioxidant, light stabilizer simultaneously, also can add functionalization auxiliary agent such as fire retardant etc. as required, make it become molten condition by heating, flow out formation polypropylene fibre (5) from spinnerets (4) then, spinnerets also becomes rectangle.Polypropylene fibre is planar stretch, with certain speed through one the blowing cooling duct after, be drawn to three pairs of draw rolls (7,8), (9,10), (11 by guide roller (6), 12) on, for improving the intensity of polypropylene fibre, reduce percentage elongation, change molecularly oriented, the controlling fiber diameter must stretch through above-mentioned three pairs of draw rolls.First pair of draw roll (7,8) is controlled at more than the polyacrylic vitrification point, below the softening point temperature by resistor heats.The rotating speed of the 3rd pair of draw roll (11,12) is greater than second pair and identical with the linear velocity of wire drawing machine (18), and the rotating speed of second pair of draw roll (9,10) is greater than first pair, and three pairs of draw rolls all adopt variable frequency control.Like this, polypropylene fibre has just obtained twice stretching after through three pairs of draw rolls.Polypropylene fibre after the stretching is drawn on a pair of warm-up mill (13,14) again, and warm-up mill adopts electrical heating, and temperature is controlled at about 120 ℃, and through the heat treatment in 6 seconds, the shrinkage of polypropylene fibre reduces greatly.Make it rapidly cooling to about 70 ℃ by cooling damping roller (15) again.At this moment the polypropylene fibre that has possessed composite demand is located alternate co-extrusion with glass fibre at pressure roller (16) and is become composite fibre.Composite fibre is integrated a branch of by buncher (17) at last, is rolled into yarn volume, i.e. finished product composite fibre by wire drawing machine (18).When using this composite fibre to make composite, must be heated more than the polyacrylic fusing point, at this moment polypropylene fibre serves as matrix material, flows around glass fibre, glass fibre is applied dipping preferably and produces interface combination preferably, make its moulding rapidly under low pressure.
The composite fibre that adopts above-mentioned process to make mixes, and the content of glass fiber in the composite fibre can reach 50-70%, and glass fiber diameter is between 13-17 μ m, and the polypropylene fibre diameter is between 20-30 μ m.The composite that uses this composite fibre to make, Fiber Distribution is even, the intensity height, effectively controlling fiber orientation makes product have good performance.
Claims (5)
1. the manufacture method of a composite fibre of forming by glass fibre and polypropylene fibre, glass fibre (2) flows out from a rectangle platinum-rhodium alloy bushing (1), apply sizing agent through water spray cooling back at baster (3), polypropylene fibre (5) flows out from a rectangle spinnerets (4), be drawn to draw roll (7 by lateral blowing cooling back by a guide roller (6), 8), (9,10), (11,12) on, at this polypropylene fibre is added hot-stretch, make it meet the requirements of diameter, locate alternate co-extrusion at pressure roller (16) then and become composite fibre with glass fibre, it is characterized in that: polypropylene fibre is drawn to warm-up mill (13 again after three pairs of draw roll places are through the secondary hot-stretch, 14) carry out high-temperature shaping on, use chill roll (15) cooling again, make the structure of polypropylene fibre and character basicly stable, contain polypropylene and modified polypropene in the raw material of polypropylene fibre.
2. method according to claim 1, the elevated temperature heat setting temperature of glass fibre is 110-125 ℃.
3. method according to claim 1 and 2, preferred 120 ℃ of the elevated temperature heat setting temperature of glass fibre.
4. method according to claim 1, the preferred maleic anhydride modified polypropylene of modified polypropene, its content is 3-8%.
5. method according to claim 4, maleic anhydride modified polyacrylic content preferred 5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01127551 CN1215209C (en) | 2001-10-16 | 2001-10-16 | Preparation method of composite fibre formed from glass fibre and polypropylene fibre |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01127551 CN1215209C (en) | 2001-10-16 | 2001-10-16 | Preparation method of composite fibre formed from glass fibre and polypropylene fibre |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1412366A true CN1412366A (en) | 2003-04-23 |
| CN1215209C CN1215209C (en) | 2005-08-17 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01127551 Expired - Fee Related CN1215209C (en) | 2001-10-16 | 2001-10-16 | Preparation method of composite fibre formed from glass fibre and polypropylene fibre |
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| CN (1) | CN1215209C (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1314524C (en) * | 2003-06-25 | 2007-05-09 | 东华大学 | Composite yarn, its preparation and application |
| CN100357089C (en) * | 2004-05-21 | 2007-12-26 | 山东伟佳玻璃钢制品有限公司 | Method of making plastic section bar for door and window by glass fiber reinforced thermoplastic composite material |
| CN102212205A (en) * | 2011-04-01 | 2011-10-12 | 江苏金发科技新材料有限公司 | Fiberglass composite reinforced material and preparation method thereof |
| CN102432947A (en) * | 2011-10-20 | 2012-05-02 | 金发科技股份有限公司 | Composite fiber reinforcement polypropylene material and preparation method thereof |
| CN102713036A (en) * | 2009-11-17 | 2012-10-03 | 仓敷纺绩株式会社 | Spun yarn and intermediate for fiber-reinforced resin, and molded article of fiber-reinforced resin using same |
| CN103173913A (en) * | 2013-04-01 | 2013-06-26 | 浙江联洋复合材料有限公司 | Composite fiber fabric and manufacturing method thereof |
| CN104278379A (en) * | 2014-04-22 | 2015-01-14 | 浙江永能化纤有限公司 | Glass fiber reinforced polyester composite filament and preparation method thereof |
| CN104747826A (en) * | 2013-12-30 | 2015-07-01 | 漯河君叁材料高科有限公司 | Manufacturing method of fiber-reinforced thermoplastic composite pipe |
| CN104911789A (en) * | 2015-07-14 | 2015-09-16 | 爱谱诗（苏州）服装有限公司 | Manufacturing method of uvioresistant medium-alkali glass fiber cloth |
-
2001
- 2001-10-16 CN CN 01127551 patent/CN1215209C/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1314524C (en) * | 2003-06-25 | 2007-05-09 | 东华大学 | Composite yarn, its preparation and application |
| CN100357089C (en) * | 2004-05-21 | 2007-12-26 | 山东伟佳玻璃钢制品有限公司 | Method of making plastic section bar for door and window by glass fiber reinforced thermoplastic composite material |
| CN102713036A (en) * | 2009-11-17 | 2012-10-03 | 仓敷纺绩株式会社 | Spun yarn and intermediate for fiber-reinforced resin, and molded article of fiber-reinforced resin using same |
| CN102212205B (en) * | 2011-04-01 | 2013-07-24 | 江苏金发科技新材料有限公司 | Fiberglass composite reinforced material and preparation method thereof |
| CN102212205A (en) * | 2011-04-01 | 2011-10-12 | 江苏金发科技新材料有限公司 | Fiberglass composite reinforced material and preparation method thereof |
| CN102432947A (en) * | 2011-10-20 | 2012-05-02 | 金发科技股份有限公司 | Composite fiber reinforcement polypropylene material and preparation method thereof |
| CN102432947B (en) * | 2011-10-20 | 2013-11-06 | 金发科技股份有限公司 | Composite fiber reinforcement polypropylene material and preparation method thereof |
| CN103173913A (en) * | 2013-04-01 | 2013-06-26 | 浙江联洋复合材料有限公司 | Composite fiber fabric and manufacturing method thereof |
| CN103173913B (en) * | 2013-04-01 | 2014-12-24 | 浙江联洋新材料股份有限公司 | Composite fiber fabric and manufacturing method thereof |
| CN104747826A (en) * | 2013-12-30 | 2015-07-01 | 漯河君叁材料高科有限公司 | Manufacturing method of fiber-reinforced thermoplastic composite pipe |
| CN104278379A (en) * | 2014-04-22 | 2015-01-14 | 浙江永能化纤有限公司 | Glass fiber reinforced polyester composite filament and preparation method thereof |
| CN104278379B (en) * | 2014-04-22 | 2017-06-13 | 浙江昊能科技有限公司 | A kind of glass fiber reinforcement polyester composite filament and preparation method thereof |
| CN104911789A (en) * | 2015-07-14 | 2015-09-16 | 爱谱诗（苏州）服装有限公司 | Manufacturing method of uvioresistant medium-alkali glass fiber cloth |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1215209C (en) | 2005-08-17 |
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Owner name: TAISHAN FIBREGLASS CO., LTD. Free format text: FORMER OWNER: TAI AN TAISHAN COMPOSITE MATERIAL CO. LTD. Effective date: 20050415 |
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Effective date of registration: 20050415 Address after: 271000 Taishan Shandong Glass Fiber Co., Ltd. Tai'an Southwest Industrial Zone Applicant after: Taishan Fiberglass Inc. Address before: 271000 Taishan Shandong Glass Fiber Co., Ltd. Tai'an Southwest Industrial Zone Applicant before: Tai'an Taishan Composite Material Co. Ltd. |
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Owner name: TAISHAN FIBREGLASS CO., LTD.; EAST CHINA UNIVERSIT Free format text: FORMER NAME OR ADDRESS: TAISHAN FIBREGLASS CO., LTD. |
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Address after: 271000 Taishan Shandong Glass Fiber Co., Ltd. Tai'an Southwest Industrial Zone Co-patentee after: East China University of Science and Technology Patentee after: Taishan Fiberglass Inc. Address before: 271000 Taishan Shandong Glass Fiber Co., Ltd. Tai'an Southwest Industrial Zone Patentee before: Taishan Fiberglass Inc. |
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| C56 | Change in the name or address of the patentee |
Owner name: TAISHAN GLASS FIBER LTD.; EAST CHINA UNIVERSITY OF Free format text: FORMER NAME OR ADDRESS: TAISHAN FIBREGLASS CO., LTD.; EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY |
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| CP01 | Change in the name or title of a patent holder |
Address after: Shandong Tai'an Southwest Industrial Zone Taishan Glass Fiber Co., Ltd. zip code: 271000 Co-patentee after: East China University of Science and Technology Patentee after: Taishan Glass Fiber Co., Ltd. Address before: Shandong Tai'an Southwest Industrial Zone Taishan Glass Fiber Co., Ltd. zip code: 271000 Co-patentee before: East China University of Science and Technology Patentee before: Taishan glass fiber Limited by Share Ltd |
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Granted publication date: 20050817 Termination date: 20111016 |