CN1401680A - Hard polyurethane casting material - Google Patents
Hard polyurethane casting material Download PDFInfo
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- CN1401680A CN1401680A CN 02135510 CN02135510A CN1401680A CN 1401680 A CN1401680 A CN 1401680A CN 02135510 CN02135510 CN 02135510 CN 02135510 A CN02135510 A CN 02135510A CN 1401680 A CN1401680 A CN 1401680A
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Abstract
A hard polyurethane as pouring material contains components A, R and F. The component A is a semi-prepolymer of polyisocyanate and polyether polyol. The R is composed of chain extending agent, polyether polyol and assistant. The F is the reinforcing fibres. Its advantages are high antiwear, anticrossion, shock-damping and anti-impact performance and high size stability.
Description
Technical field
The present invention relates to the polyurethane-type macromolecular material, specifically is a kind of hard polyurethane casting material, and this material is suitable for the making of structure component, the instead of part metallic substance.
Background technology
Normally used polymer composite comprises Resins, epoxy, unsaturated polyester resin, resol, polyvinyl resin etc., but all there is different shortcomings in above-mentioned materials, as the Resins, epoxy poor toughness, the unsaturated polyester resin percent thermal shrinkage is big, and resol, polyvinyl resin curing action are poor, wear resisting property difference etc.Urethane is as a kind of novel macromolecular material, has higher mechanical strength, excellent fatigue strength, heat shock resistance, wear-resisting, anti tear etc., is very suitable for the making of structure component.
At United States Patent (USP) 5,234, has reported in 975 and used the fiber reinforcement hard polyurethane casting material, but the shortcoming of invention is to need cast about 40-60 ℃, and the pourable phase about 2-3 minute, be unfavorable for manual operations.At United States Patent (USP) 5,234, reported with the fiber reinforcement polyurethane material and made that hardness can not be used as structured material but this material hardness is too low at Shao A40-80 in 975 as the skin of football.
The cast polyurethane matrix material that the purpose of this invention is to provide a kind of hard, this viscosity of material is low, the pourable phase is long, normal temperature solidified, normal pressure cast, cured product has higher mechanical strength, excellent fatigue strength, heat shock resistance, wear-resisting, anti tear etc., can carry out car, mill, machining such as plane, mill, be suitable for making various components of machine as a kind of structured material.
Summary of the invention
Hard polyurethane casting material of the present invention comprises A, R, F three components;
Wherein the A component is that the free isocyanate group content in this semi-prepolymer is between 18～35% by the polyisocyanates of 65～90% (in the gross weights of A component) of functionality between 2～2.7 and molecular weight 10～35% polyether glycol synthetic semi-prepolymer at 400-10000;
R component (in the gross weight of R component) is to comprise 10～40% chainextenders, 30～60% polyether glycols, 1～5% auxiliary agent;
The F component is a fortifying fibre.
Wherein the preparation method of A component is: the polyisocyanates of accurate measurement is added in the reactor, at the uniform velocity stir, be heated to 50～80 ℃, in still, drip the polyol compound of accurate measurement, insulation while stirring progressively is warming up to 85 ± 2 ℃ and be incubated 3 hours after dropwising, after sampling is surveyed NCO content and reached theoretical value, cooling discharging promptly gets the excessive semi prepolymer of isocyanic ester.Free isocyanate group content in general this semi prepolymer is between 18～35%.
Free isocyanate group content in the above-mentioned semi prepolymer is preferably between 25%～35%.
Wherein the preparation method of R component is: it is even that polyether glycol, chainextender, the auxiliary agent of accurate measurement is added in the reactor thorough mixing, and be warming up to 100 ℃ of vacuum hydro-extractions about 2 hours, treats that water-content is lower than 0.05% and can discharging gets the R component.
In the semi prepolymer polyisocyanates preferred following one or more: 4 of carbodiimide-uretonimine-modified, 4 '-diphenylmethanediisocyanate (LMDI), polymethine polyphenyl polyisocyanate (PAPI), 4,4 '-diphenylmethanediisocyanate (MDI), 2,4 '-diphenylmethanediisocyanate (2,4-MDI), tolylene diisocyanate (TDI) etc.
Polyether glycol in polyether glycol in the above-mentioned semi prepolymer and the R component is propylene oxide or oxyethane polyethers with what adopt usually, and its functionality is between 2 to 4.Its molecular weight is between 400～10000, best between 500～5000, preferred following one or more: the multipolymer of polyglycol ether, polypropylene glycol ether, polyglycerol ether, polypentaerythritol ether, PTMG and said structure, the polyether glycol that also comprises low-unsaturation-degree, for example Acclaim3201 of Acro company etc.
Chainextender in the R component comprises amine chain extender and alcohols chainextender.
Wherein the functionality of amine chain extender is most typical is between 2～3.Preferred diethyl toluene diamine (DETDA), diformazan sulfenyl tolylene diamine (DADMT), N, N '-two sec-butyl methylenediphenyl diamines, 4,4 '-diaminodiphenyl-methane (MDA), 3,3 '-two chloro-4,4 '-diaminodiphenyl-methane (MOCA), aliphatic polyamine.
The alcohols chainextender is preferred 1,4-butyleneglycol (BDO), 1,3 butylene glycol, 1,5-pentanediol, 1,6-hexylene glycol, TriMethylolPropane(TMP) (TMP), glycerol, trolamine etc.
Auxiliary agent in the R component comprises: catalyzer, oxidation inhibitor, ultraviolet absorbers, antisettling agent.Wherein catalyzer comprises the organo-metallic class, for example organic tin, organic mercury class, organo-bismuth; Organic amine as: triethylenediamine, triethylamine, the best are selected the organo-metallic class for use, as T-12, the T-9 etc. of U.S.'s gas companies;
Oxidation inhibitor is the IRGANOX 1010 and 1076 of CIBA GEIGY company for example, the YOSHINOX BHT of YOSHITOMSEIYAKU company, BB, GSY-930; Ultraviolet absorbers is the TINUVIN P of CIBA GEIGY company for example, and 327,328; Antisettling agent is BYK-203, the BYK-401 of BYK company for example.
The F component be by short cut or sledge mill fibrous, mainly play enhancement, comprise glass fibre, charcoal fiber, graphite fibre, nylon fiber etc., the length of fiber is between 1.5～5mm, diameter is between 10～40 microns.Preferably pass through coupling agent treatment, handle as A-187, A-186, A-1230 with Witco company.The addition of fiber is controlled at and both can makes mixed solution that good mobility is arranged, and makes mixture have enough viscosity with the assurance fiber suspension again, thereby guarantees the homogeneity of cured product.The oil number of different fibers is different, and generally its add-on is 20～60% (weight) of A and R amount of the mixture.
The synthetic method of hard polyurethane casting material of the present invention is: after A, R two components were mixed by weight 1: 1, and add fortifying fibre, and mix once more, be poured in the mould.Curing, the demoulding in the short period of time, formation hardness height, the rigid structure material that toughness is strong.
This rigid structure members has shown excellent performance, as wear resistance, preservative property, shockproof, shock resistance, dimensional stability etc., can carry out car, mill, machining such as plane, mill, be suitable for making various components of machine such as gear, blade of wind-driven generator, pedestal etc. as a kind of structured material.
Embodiment
Below provide several representative instances, but the present invention is confined to not merely in the following example.Example 1:
The preparation of A component: with 600g polymethine polyphenyl polyisocyanate (PAPI), 4 of 200g carbodiimide-uretonimine-modified, 4 '-diphenylmethanediisocyanate (LMDI) adds in the reactor, at the uniform velocity stir, be heated to 50～80 ℃, (molecular weight is 1000 to drip 200g poly(propylene oxide) dibasic alcohol in still, functionality is 2), insulation while stirring, progressively be warming up to 85 ± 2 ℃ and be incubated 3 hours after dropwising, after sampling survey NCO content reached theoretical value, cooling discharging promptly got the excessive semi prepolymer of isocyanic ester.Testing the free isocyanate content of A component with the Di-n-Butyl Amine method is 23.5%.
The preparation of R component: with 174g 330N (polyether glycol, molecular weight is 4950, functionality is 3, the big chemical industry group in east, Shandong), 500g 210 (polyether glycols, molecular weight is 1000, functionality is 2, the big chemical industry group in east, Shandong), 100g TriMethylolPropane(TMP) TMP and 200g diformazan sulfenyl tolylene diamine (Albemarle Corporation, the U.S.), 10g oxidation inhibitor (CIBA GEIGY, Irganox1076) and 10g ultraviolet absorbers (CIBA GEIGY, Tinuvin 328), 1g catalyzer (U.S.'s gas companies, T-12), the 5g anti-sedimentation agent (BYK company, it is even BYK-203) to join in the reactor thorough mixing, is heated to 100 ℃ and dewatered 2 hours, the sampling and testing moisture content is 0.03%, and discharging promptly gets the R component.
With 100g A and 100g R thorough mixing, add 80g glass fibre (length 3mm, 20 microns of diameters) and also stir once more, above-mentioned material is poured in the mould, get final product depanning after 40 minutes.Carry out performance test after cured product at room temperature placed a week, the result is as follows:
(25 ℃, cps) A 250 for viscosity
R 800
A, R, F mixture 500
The duration of pouring/minutes 15
Demould time/minutes 40
Hardness (Shao D) 60
Shrinking percentage (%) 0.0022
Elongation (%) 6%
Modulus in flexure/psi 236000
Flexural strength/psi 8500 examples 2:
The preparation of A component: with 275g polymethine polyphenyl polyisocyanate (PAPI), 600g4,4 '-diphenylmethanediisocyanate (MDI) add in the reactor, at the uniform velocity stir, be heated to 50～80 ℃, in still, drip 125g poly(propylene oxide) dibasic alcohol (molecular weight is 2000, and functionality is 2), while stirring insulation, progressively be warming up to 85 ± 2 ℃ and be incubated 3 hours after dropwising, after sampling survey NCO content reached theoretical value, cooling discharging promptly got the excessive semi prepolymer of isocyanic ester.Testing the free isocyanate content of A component with the Di-n-Butyl Amine method is 29%.
The preparation of R component: with 224g 330N (polyether glycol, molecular weight is 4950, functionality is 3, the big chemical industry group in east, Shandong), 500g 210 (polyether glycols, molecular weight is 1000, functionality is 2, the big chemical industry group in east, Shandong), 100g TriMethylolPropane(TMP) TMP and 150g1,4 butyleneglycols (BDO), 10g oxidation inhibitor (CIBA GEIGY, Irganox 1076) and 10g ultraviolet absorbers (CIBA GEIGY, Tinuvin 328), 1g catalyzer (U.S.'s gas companies, T-12), the 5g anti-sedimentation agent (BYK company, it is even BYK-203) to join in the reactor thorough mixing, is heated to 100 ℃ and dewatered 2 hours, the sampling and testing moisture content is 0.03%, and discharging promptly gets the R component.
With 100g A and 100g R thorough mixing, add 100g charcoal fiber (length 4mm, 20 microns of diameters) and also stir once more, above-mentioned material is poured in the mould, get final product depanning after 40 minutes.Carry out performance test after cured product at room temperature placed a week, the result is as follows:
(25 ℃, cps) A 200 for viscosity
R 850
A, R, F mixes
Compound 500
The duration of pouring/minutes 10
Demould time/minutes 40
Hardness (Shao D) 70
Shrinking percentage (%) 0.0025
Elongation (%) 6%
Modulus in flexure/psi 215000
Flexural strength/psi 9500
Example 3:
The preparation of A component: with 950g 2, (2,4 '-MDI) adds in the reactor 4 '-diphenylmethanediisocyanate, at the uniform velocity stirs, be heated to 50～80 ℃, Dropwise 5 0g poly(propylene oxide) dibasic alcohol in still (molecular weight is 2000, and functionality is 2), insulation while stirring, progressively be warming up to 85 ± 2 ℃ and be incubated 3 hours after dropwising, after sampling survey NCO content reached theoretical value, cooling discharging promptly got the excessive semi prepolymer of isocyanic ester.Testing the free isocyanate content of A component with the Di-n-Butyl Amine method is 32%.
The preparation of R component: with 224g 330N (polyether glycol, molecular weight is 4950, functionality is 3, the big chemical industry group in east, Shandong), 400g 210 (polyether glycols, molecular weight is 1000, functionality is 2, the big chemical industry group in east, Shandong), (polyether glycol, molecular weight are 300 to 50g 403, and functionality is 4, Nanjing, Nanjing petrochemical industry), 150g TriMethylolPropane(TMP) TMP and 150g 1,4 butyleneglycol (BDO), 10g oxidation inhibitor (CIBA GEIGY, Irganox 1076) and 10g ultraviolet absorbers (CIBA GEIGY, Tinuvin 328), 1g catalyzer (U.S.'s gas companies, T-12), the 5g anti-sedimentation agent (BYK company, it is even BYK-203) to join in the reactor thorough mixing, is heated to 100 ℃ and dewatered 2 hours, the sampling and testing moisture content is 0.03%, and discharging promptly gets the R component.
With 100g A and 100g R thorough mixing, add 100g nylon fiber (length 3mm, 30 microns of diameters) and also stir once more, above-mentioned material is poured in the mould, get final product depanning after 40 minutes.Carry out performance test after cured product at room temperature placed a week, the result is as follows:
Viscosity A 100
(25℃，cps)
R 810
A, R, F mixes
Compound 700
The duration of pouring/minutes 15
Demould time/minutes 50
Hardness (Shao D) 80
Shrinking percentage 0.002
Elongation (%) 6%
Modulus in flexure/psi 217000
Flexural strength/psi 9500
Claims (10)
1. a hard polyurethane casting material is characterized in that, comprises A, R, F three components;
Wherein the A component is that the free isocyanate group content in this semi-prepolymer is between 18～35% by the polyisocyanates of 65～90% (in the gross weights of A component) of functionality between 2～2.7 and molecular weight 10～35% polyether glycol synthetic semi-prepolymer at 400-10000;
R component (in the gross weight of R component) is to comprise 10～40% chainextenders, 30～60% polyether glycols, 1～5% auxiliary agent;
The F component is a fortifying fibre.
2. according to the hard polyurethane casting material of claim 1, it is characterized in that, the preparation method of described A component is: the polyisocyanates of accurate measurement is added in the reactor, at the uniform velocity stir, be heated to 50～80 ℃, in still, drip the polyol compound of accurate measurement, insulation while stirring progressively is warming up to 85 ± 2 ℃ and be incubated 3 hours after dropwising, after sampling is surveyed NCO content and reached theoretical value, cooling discharging promptly gets the excessive semi-prepolymer of isocyanic ester.
3. according to the hard polyurethane casting material of claim 1, it is characterized in that, the preparation method of described R component is: it is even that polyether glycol, chainextender, the auxiliary agent of accurate measurement is added in the reactor thorough mixing, and be warming up to 100 ℃ of vacuum hydro-extractions about 2 hours, treat that water-content is lower than 0.05% and can discharging gets the R component.
4. according to the hard polyurethane casting material of claim 1, it is characterized in that, in the described semi-prepolymer polyisocyanates preferred following one or more: 4 of carbodiimide-uretonimine-modified, 4 '-diphenylmethanediisocyanate (LMDI), polymethine polyphenyl polyisocyanate (PAPI), 4,4 '-diphenylmethanediisocyanate (MDI), 2, and 4 '-diphenylmethanediisocyanate (2,4-MDI), tolylene diisocyanate (TDI) etc.
5. according to the hard polyurethane casting material of claim 1, it is characterized in that, polyether glycol in polyether glycol in the above-mentioned semi-prepolymer and the R component is propylene oxide or oxyethane polyethers with what adopt usually, and its functionality is between 2 to 4, and its molecular weight is between 400～10000.
6. according to the hard polyurethane casting material of claim 5, it is characterized in that, described polyether glycol preferred following one or more: the multipolymer of polyglycol ether, polypropylene glycol ether, polyglycerol ether, polypentaerythritol ether, PTMG and said structure, the polyether glycol of low-unsaturation-degree.
7. according to the hard polyurethane casting material of claim 1, it is characterized in that the chainextender in the described R component comprises amine chain extender and alcohols chainextender.
8. according to the hard polyurethane casting material of claim 7, it is characterized in that the functionality of described amine chain extender is most typical to be between 2～3.Preferred diethyl toluene diamine (DETDA), diformazan sulfenyl tolylene diamine (DADMT), N, N '-two sec-butyl methylenediphenyl diamines, 4,4 '-diaminodiphenyl-methane (MDA), 3,3 '-two chloro-4,4 '-diaminodiphenyl-methane (MOCA), aliphatic polyamine.
9. according to the hard polyurethane casting material of claim 1, it is characterized in that, the length of described F component fortifying fibre is between 1.5～5mm, diameter is between 10～40 microns, comprise: glass fibre, charcoal fiber, graphite fibre, nylon fiber, its add-on are 20～60% (weight) of A and R amount of the mixture.
10. the synthetic method of hard polyurethane casting material of the present invention is: after A, R two components were mixed by weight 1: 1, and add fortifying fibre, mix once more, be poured in the mould curing, the demoulding under the room temperature.
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| CN 02135510 CN1189498C (en) | 2002-08-31 | 2002-08-31 | Hard polyurethane casting material |
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| CN 02135510 CN1189498C (en) | 2002-08-31 | 2002-08-31 | Hard polyurethane casting material |
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| CN1995105B (en) * | 2005-12-19 | 2011-05-04 | 积水化学工业株式会社 | A resin molded article for constructing a rail and a method for manufacturing the same |
| CN102850774A (en) * | 2011-07-01 | 2013-01-02 | 重庆信合塑胶有限公司 | Method for preparing polyurethane with high property |
| CN103113818A (en) * | 2013-02-19 | 2013-05-22 | 海洋化工研究院有限公司 | Preparation and application of solvent-free spraying polyurethane pipeline mending coating |
| CN103540122A (en) * | 2012-07-13 | 2014-01-29 | 深圳市科中大交通建材有限公司 | Carbon-fiber-enhanced polyurethane road mending material and preparation method thereof |
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| CN105038192A (en) * | 2015-06-25 | 2015-11-11 | 浙江方氏眼镜制造有限公司 | High-strength wear-resistant polyurethane spectacle frame and preparation method thereof |
| CN105237713A (en) * | 2015-11-13 | 2016-01-13 | 淄博正大聚氨酯有限公司 | Glass fiber compound polyurethane for telegraph pole and preparation method thereof |
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| CN109863216A (en) * | 2016-09-30 | 2019-06-07 | 艾仕得涂料系统胡思韦特英国有限公司 | Composition |
| CN112194771A (en) * | 2020-08-26 | 2021-01-08 | 广东铭泽脚轮工业有限公司 | High-resilience casting type polyurethane elastomer |
| CN113831822A (en) * | 2021-07-09 | 2021-12-24 | 成都上泰科技有限公司 | Method for manufacturing high-performance polyurea composite material |
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| CN100485001C (en) * | 2007-02-12 | 2009-05-06 | 江苏双良复合材料有限公司 | Section material product of continuous glass-fiber reinforced hard polyurethane microfoam and coextrusion forming process |
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| CN1995105B (en) * | 2005-12-19 | 2011-05-04 | 积水化学工业株式会社 | A resin molded article for constructing a rail and a method for manufacturing the same |
| CN102850774A (en) * | 2011-07-01 | 2013-01-02 | 重庆信合塑胶有限公司 | Method for preparing polyurethane with high property |
| CN102850774B (en) * | 2011-07-01 | 2014-07-02 | 重庆信合塑胶有限公司 | Method for preparing polyurethane with high property |
| CN103540122A (en) * | 2012-07-13 | 2014-01-29 | 深圳市科中大交通建材有限公司 | Carbon-fiber-enhanced polyurethane road mending material and preparation method thereof |
| CN103113818A (en) * | 2013-02-19 | 2013-05-22 | 海洋化工研究院有限公司 | Preparation and application of solvent-free spraying polyurethane pipeline mending coating |
| CN103113818B (en) * | 2013-02-19 | 2015-04-15 | 海洋化工研究院有限公司 | Preparation and application of solvent-free spraying polyurethane pipeline mending coating |
| CN103723379A (en) * | 2014-01-11 | 2014-04-16 | 苏州安特实业有限公司 | Heat insulation cold closet for medical supplies |
| CN103723379B (en) * | 2014-01-11 | 2015-12-30 | 苏州安特实业有限公司 | Medicines insulation refrigeration case |
| CN104647227A (en) * | 2015-02-10 | 2015-05-27 | 台山市远鹏研磨科技有限公司 | Material of polyurethane wet type polishing wheel |
| CN105038192A (en) * | 2015-06-25 | 2015-11-11 | 浙江方氏眼镜制造有限公司 | High-strength wear-resistant polyurethane spectacle frame and preparation method thereof |
| CN105237713A (en) * | 2015-11-13 | 2016-01-13 | 淄博正大聚氨酯有限公司 | Glass fiber compound polyurethane for telegraph pole and preparation method thereof |
| CN105237713B (en) * | 2015-11-13 | 2018-01-30 | 淄博正大聚氨酯有限公司 | Electric pole glass composite polyurethane and preparation method thereof |
| CN109863216A (en) * | 2016-09-30 | 2019-06-07 | 艾仕得涂料系统胡思韦特英国有限公司 | Composition |
| CN107725601A (en) * | 2017-07-10 | 2018-02-23 | 北华大学 | A kind of preparation method of double-decker polyurethane composite bearing |
| CN107725601B (en) * | 2017-07-10 | 2019-07-09 | 北华大学 | A kind of preparation method of double-layer structure polyurethane composite bearing |
| CN112194771A (en) * | 2020-08-26 | 2021-01-08 | 广东铭泽脚轮工业有限公司 | High-resilience casting type polyurethane elastomer |
| CN112194771B (en) * | 2020-08-26 | 2023-11-28 | 广东铭泽脚轮工业有限公司 | High-resilience casting polyurethane elastomer |
| CN113831822A (en) * | 2021-07-09 | 2021-12-24 | 成都上泰科技有限公司 | Method for manufacturing high-performance polyurea composite material |
| CN115678256A (en) * | 2022-08-29 | 2023-02-03 | 湘潭大学 | High-speed impact resistant polyurethane elastomer composite material and preparation method thereof |
| CN117486632A (en) * | 2023-11-01 | 2024-02-02 | 西南科技大学 | Polyurea foam concrete and preparation method thereof |
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