CN1392105A - Light catalytic reactor for contaminant degradation - Google Patents
Light catalytic reactor for contaminant degradation Download PDFInfo
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- CN1392105A CN1392105A CN 01113708 CN01113708A CN1392105A CN 1392105 A CN1392105 A CN 1392105A CN 01113708 CN01113708 CN 01113708 CN 01113708 A CN01113708 A CN 01113708A CN 1392105 A CN1392105 A CN 1392105A
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- optical fiber
- light
- catalytic reactor
- light catalytic
- contaminant degradation
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Abstract
The photocatalytic reactor for degrading contaminant in waste water and waste gas consists of cylinder, light conducting device and light distributing device. The cylinder has mouth, the light distributing device consists of light fiber and photocatalyst particles carried by the light fiber, and there is fiber coupler between the light conducing device and the light distributing device for connection. The use of the fiber coupler makes it possible to adopts different fiber in the light conducting device and to raise contaminant degrading capacity.
Description
The present invention relates to a kind of device that is used for waste water or waste gas Pollutant Treatment, refer in particular to light catalytic reactor for contaminant degradation.
The structure of existing photo catalysis reactor is that the lower end protective layer of optical fiber is peelled off; apply photocatalyst thereon; and be placed in the reactor shell; therefore; the part of every optical fiber in this photo catalysis reactor is to pass the light district; and another part is workspace, and optical fiber is thin more, and to pass optical efficiency high more passing the light district; yet; optical fiber is thin more, and is short more in the axial propagation distance of workspace light, causes the photochemical catalysis area to diminish; restricted ability to contaminant degradation; optical fibre set, then filling ratio is low, and light transmissioning efficiency is low.In addition, optical fiber catalysed partial in reactor is owing to lack the covering protection, and flexural strength is low, and anti-brittle failure ability is difficult to use on a large scale.
Goal of the invention of the present invention is to provide a kind of light catalytic reactor for contaminant degradation that helps improving pollutent ability in degrading waste water or the waste gas.
The present invention adopts following technical scheme to realize its goal of the invention:
The present invention is a kind of light catalytic reactor for contaminant degradation that is used for waste gas/wastewater treatment, form by reactor shell 1, biography optical device 2 and luminous intensity distribution device 3, on reactor shell 1, be provided with mouth 11, luminous intensity distribution device 3 is made up of optical fiber 31 and photocatalyst granular, photocatalyst granular loads on the optical fiber 31, between biography optical device 2 and luminous intensity distribution device 3, be provided with fiber coupler 4, pass optical device 2 and be connected with luminous intensity distribution device 3 by fiber coupler 4.
Compared with prior art, the present invention has following advantage:
1. in the present invention, passing optical device is to be connected with the luminous intensity distribution device by fiber coupler, this just makes and passes optical device and both can adopt identical optical fiber with optical fiber in the luminous intensity distribution device, also can adopt different classes of or different diameter fibers, make the available scope that passes the optical fiber in optical device, the luminous intensity distribution device very big, can select with light-catalysed different requirements according to passing light, distribute rationally, reach the best light effect that passes, and can steady in a long-termly move, thereby make the present invention can realize helping improving the purpose of degradation of contaminant ability.
2. because the existence of fiber coupler makes the present invention can select thicker longer photocatalyst optical fiber, thereby increased reaction area, improved the effect of mass transfer, reaction.
3. stranding biography optical device can improve the biography optical efficiency, linear optical fiber then can be grown apart from lateral emitting, and the present invention can make up it by fiber coupler, thereby, improve quantum yield and speed of reaction, more helped improving the ability of degradation of contaminant of the present invention.
4. the present invention places quartz socket tube with optical fiber, has improved the photochemical catalysis area of unit volume in the reactor, and casing buckling intensity height, and anti-brittle failure is good.
5. the bundle dividing orchestration can be divided into some bundles with the optical fiber that passes in the optical device, thereby has increased reaction area, has improved mass transfer effect and speed of reaction, has further improved the degradation capability of the present invention to pollutent.
6. can in reactor shell, blast air/oxygen by ventilating pit 12, further promote the carrying out of light-catalyzed reaction, gas and liquid mixing are got evenly, help waste water or off gas treatment.
Fig. 1 is the structural representation of the embodiment of the invention.
Fig. 2 is the A-A sectional view of the embodiment of the invention.
With reference to the accompanying drawings, embodiment of the present invention being done one describes in detail:
The present invention is a kind of light catalytic reactor for contaminant degradation that is used for waste water/off gas treatment, by reactor shell 1, pass optical device 2 and luminous intensity distribution device 3 compositions, on reactor shell 1, be provided with mouth 11, mouth 11 can supply advancing of waste water, go out and take a sample shared, also can set up import separately, outlet and thief hole, in the present embodiment, mouth 11 is as import, on reactor shell 1, be provided with thief hole 13 and outlet 14, luminous intensity distribution device 3 is made up of optical fiber 31 and photocatalyst granular, photocatalyst granular loads on the optical fiber 31, photocatalyst granular can be a ultra-fine grain, particularly nano level titanium, iron, tin, manganese, silicon, cobalt, nickel, copper, zinc, calcium, rhodium, palladium, silver, platinum, a kind of metal/metal compound or multiple metal/metal combination of compounds in gold or its metallic compound, between biography optical device 2 and luminous intensity distribution device 3, be provided with fiber coupler 4, passing optical device 2 is connected with luminous intensity distribution device 3 by fiber coupler 4, optical fiber 3 is linear optical fiber, also can be to inhale leakage property optical fiber or other axial emitting optical fibers, sheathed quartz socket tube 32 outside optical fiber 31, photocatalyst granular loads on the outside surface of quartz socket tube 32, in passing optical device 2, be provided with bundle dividing orchestration 6, be connected with luminous intensity distribution device 3 by fiber coupler by the biography light optical fiber 21 after 6 distribution of bundle dividing orchestration, be provided with shield cap 7 at bundle dividing orchestration 6 and by the outside of the biography light optical fiber 21 after 6 distribution of bundle dividing orchestration, bundle dividing orchestration 6 can be made of one with fiber coupler, passing optical device 2 is cable optical fiber, be provided with ventilating pit 12 in the bottom of reactor shell 1, on reactor shell 1, be provided with thief hole 13 and outlet 14.
Claims (8)
1. light catalytic reactor for contaminant degradation that is used for waste water/off gas treatment, form by reactor shell (1), biography optical device (2) and luminous intensity distribution device (3), on reactor shell (1), be provided with mouthful (11), luminous intensity distribution device (3) is made up of optical fiber (31) and photocatalyst granular, photocatalyst granular loads on the optical fiber (31), it is characterized in that between biography optical device (2) and luminous intensity distribution device (3), being provided with fiber coupler (4), pass optical device (2) and be connected with luminous intensity distribution device (3) by fiber coupler (4).
2. light catalytic reactor for contaminant degradation according to claim 1 is characterized in that optical fiber (31) is linear optical fiber.
3. light catalytic reactor for contaminant degradation according to claim 1 and 2 is characterized in that sheathed quartz socket tube (32) outside optical fiber (31), and photocatalyst granular loads on the outside surface of quartz socket tube (32).
4. light catalytic reactor for contaminant degradation according to claim 3 is characterized in that being provided with ventilating pit (12) in the bottom of reactor shell (1).
5. light catalytic reactor for contaminant degradation according to claim 4, it is characterized in that being provided with bundle dividing orchestration (6) in passing optical device (2), the biography light optical fiber (21) after being distributed by bundle dividing orchestration (6) is connected with luminous intensity distribution device (3) by fiber coupler.
6. light catalytic reactor for contaminant degradation according to claim 5 is characterized in that being provided with shield cap (7) at bundle dividing orchestration (6) and by the outside of the biography light optical fiber (21) after bundle dividing orchestration (6) distribution.
7. light catalytic reactor for contaminant degradation according to claim 1 is characterized in that being provided with thief hole (13) and outlet (14) on reactor shell (1).
8. according to claim 1 or 4 described light catalytic reactor for contaminant degradation, it is characterized in that passing optical device (2) is cable optical fiber.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 01113708 CN1128107C (en) | 2001-06-20 | 2001-06-20 | Light catalytic reactor for contaminant degradation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 01113708 CN1128107C (en) | 2001-06-20 | 2001-06-20 | Light catalytic reactor for contaminant degradation |
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Publication Number | Publication Date |
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CN1392105A true CN1392105A (en) | 2003-01-22 |
CN1128107C CN1128107C (en) | 2003-11-19 |
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CN 01113708 Expired - Fee Related CN1128107C (en) | 2001-06-20 | 2001-06-20 | Light catalytic reactor for contaminant degradation |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100348506C (en) * | 2005-10-18 | 2007-11-14 | 南京大学 | Efficient photocatalytic water-treating process and apparatus |
CN100376486C (en) * | 2006-03-03 | 2008-03-26 | 北京蓝景创新科技有限公司 | Use of solar energy in water treatment and solar energy collecting and conducting device |
CN101810876B (en) * | 2009-02-25 | 2013-06-26 | 中国科学院苏州纳米技术与纳米仿生研究所 | LED optical fiber photocatalyst device with large-area sterilization and dirty removal capacities |
CN105110410A (en) * | 2015-08-27 | 2015-12-02 | 东莞道汇环保科技有限公司 | Ultrahigh-strength ultraviolet irradiation device used for catalytic wet oxidation process |
CN107381781A (en) * | 2017-09-14 | 2017-11-24 | 重庆理工大学 | A kind of novel optical fiber photocatalysis and biodegradable direct-coupling reactor |
CN108283913A (en) * | 2017-01-09 | 2018-07-17 | 徐海澜 | The hollow light guide fiber photo catalysis reactor strengthened by three-dimensional electric field and graphene |
CN108911017A (en) * | 2018-06-07 | 2018-11-30 | 东南大学 | A kind of photocatalysis floating bed for water remediation |
-
2001
- 2001-06-20 CN CN 01113708 patent/CN1128107C/en not_active Expired - Fee Related
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100348506C (en) * | 2005-10-18 | 2007-11-14 | 南京大学 | Efficient photocatalytic water-treating process and apparatus |
CN100376486C (en) * | 2006-03-03 | 2008-03-26 | 北京蓝景创新科技有限公司 | Use of solar energy in water treatment and solar energy collecting and conducting device |
CN101810876B (en) * | 2009-02-25 | 2013-06-26 | 中国科学院苏州纳米技术与纳米仿生研究所 | LED optical fiber photocatalyst device with large-area sterilization and dirty removal capacities |
CN105110410A (en) * | 2015-08-27 | 2015-12-02 | 东莞道汇环保科技有限公司 | Ultrahigh-strength ultraviolet irradiation device used for catalytic wet oxidation process |
CN108283913A (en) * | 2017-01-09 | 2018-07-17 | 徐海澜 | The hollow light guide fiber photo catalysis reactor strengthened by three-dimensional electric field and graphene |
CN107381781A (en) * | 2017-09-14 | 2017-11-24 | 重庆理工大学 | A kind of novel optical fiber photocatalysis and biodegradable direct-coupling reactor |
CN108911017A (en) * | 2018-06-07 | 2018-11-30 | 东南大学 | A kind of photocatalysis floating bed for water remediation |
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CN1128107C (en) | 2003-11-19 |
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