CN1391439A - Synergistic herbicidal active substance combinations - Google Patents

Synergistic herbicidal active substance combinations Download PDF

Info

Publication number
CN1391439A
CN1391439A CN00815932.7A CN00815932A CN1391439A CN 1391439 A CN1391439 A CN 1391439A CN 00815932 A CN00815932 A CN 00815932A CN 1391439 A CN1391439 A CN 1391439A
Authority
CN
China
Prior art keywords
methyl
chloro
ethyl
phenyl
fluoro
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN00815932.7A
Other languages
Chinese (zh)
Inventor
M·克雷默
D·费伊希特
A·维尔曼
P·达门
B·克劳斯科普夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19960918A external-priority patent/DE19960918A1/en
Application filed by Bayer AG filed Critical Bayer AG
Publication of CN1391439A publication Critical patent/CN1391439A/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof

Abstract

The invention relates to novel herbicidal synergistic active substance combinations which comprise tritosulfuron and conventional herbicidally effective compounds and, optionally, compounds that improve the compatibility of cultivated plants. The inventive synergistic herbicidal active substance combinations can be used with particularly good success in selectively killing weeds in different useful plant crops, especially in crops consisting of cereals and corn.

Description

Synergistic herbicidal active substance combinations
The present invention relates to new Synergistic herbicidal active substance combinations, wherein comprise Tritosulfuron and known weeding active compound and optionally can promote the compound of crop compatibility, this mixture can be used for optionally preventing and kill off the weeds in the various useful crops and has extraordinary herbicidal effect.
As weed killer herbicide with broad spectrum of activity, Tritosulfuron (N-[[[4-methoxyl group-6-(trifluoromethyl)-1,3,5-triazine-2-yl] amino] carbonyl]-2-trifluoromethyl-benzsulfamide) be that theme in a large amount of patent applications is (referring to DE-A4038430, WO-A97/10714).Yet this reactive compound also has weak point aspect active.
Surprisingly, found at present when Tritosulfuron mixes use with the known weeding active compound that is selected from different types of structure, aspect activity of weeding, show significant synergistic effect, and this broad spectrum of activity mixture can be particularly conducive to as selectivity and prevent and kill off weeds in the useful crop, these crops such as wheat and corn.
Surprisingly, the compound (safener/antipoison) of also finding co-administered following promoted crop compatibility in the mixture that uses Tritosulfuron and other known weeding active compound can obtain other more favourable action effects.
The invention provides a kind of composition, it is characterized in that they comprise the active substance combinations of synergy effective dose, this mixture comprises
(a)Tritosulfuron
With
(b) be selected from one or more compounds in the one group of weed killer herbicide that contains following reactive compound:
(5-Trifluoromethyl-1; 3; 4-thiadiazoles-2-base-oxygen base)-N-isopropyl-N-(4-fluoro-phenyl) acetamide (Flufenacet; DE-A-3821600); 2-(2-methoxycarbonyl benzenesulfonyl amino carbonyl)-4-methyl-5-positive propoxy-2; 4-dihydro-3H-1; 2; the sodium salt of 4-triazole-3-ketone or this compound (Propoxycarbazone (sodium salt); EP-A-507171); 2-(2-trifluoromethoxy-benzenesulfonyl-amino carbonyl)-4-methyl-5-methoxyl group-2; 4-dihydro-3H-1; 2; the sodium salt of 4-triazole-3-ketone or this compound (Flucarbazone (sodium salt); EP-A-507171); N-(3; the 4-dichlorophenyl) propionamide (Stam F-34; DE-A-1039779); N-2-benzothiazolyl-N; N '-dimethyl urea (methabenzthiazuron; GB-A-1085430); 4-amino-6-(1, the 1-dimethyl ethyl)-3-(methyl mercapto)-1,2; 4-triazine-5 (4H)-ketone (piperazine humulone; DE-A-1795784), 4-(2-chlorphenyl)-N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo-1H-tetrazolium-1-formamide (Fentrazamide; EP-A-612735); 4-amino-3-methyl-6-phenyl-1,2,4-triazine-5 (4H)-ketone (metamitron; DE-A-2138031); 2-(2-[4-morpholinodithio base oxygen base)-N-methyl-phenyl acetanilide,Phenacetylaniline (mefenacet, DE-A-2822155), 4-amino-6-(1; the 1-dimethyl ethyl)-3-(ethylmercapto group)-1; 2, and 4-triazine-5 (4H)-ketone (ethiozin, DE-A-1542873); 5-[4-bromo-1-methyl-5-(trifluoromethyl)-1H-pyrazole-3-yl]-2-chloro-4-fluobenzoic acid 1-methyl ethyl ester (Fluazolate, WO-A-9206962)
(" the 1st group of reactive compound ")
And it is optional
(c) be selected from one or more compounds in the second group of weed killer herbicide that contains following reactive compound:
2 - Chloro-N-(ethoxymethyl)-N-(2 - ethyl-6 - methyl - phenyl) - acetamide (dimethachlor Amine), 5 - (2 - chloro -4 - (trifluoromethyl) - phenoxy) -2 - nitro - acid salt (of trifluoromethyl carboxymethyl Ether), 2 - chloro-6 - nitro-3 - phenoxy - aniline (aclonifen), 2 - chloro-N-(methoxymethyl) - N-(2,6 - diethyl - phenyl) - acetamide (alachlor), N-ethyl-N'-isopropyl-6 - (methylthio) -1,3,5 - Triazine-2 ,4 - diamine (ametryn), 4 - amino-N-(1,1 - dimethyl - ethyl) - 4,5 - dihydro-3 - (1 - methyl - ethyl) -5 - oxo-1H-1, 2,4 - triazol-1 - carboxamide (Amicarbazone), N-(4,6 - dimethoxy - pyrimidin-2 - yl)-N'-(N-methyl-N-methyl- - Sulfonyl - sulfamoyl) - urea (acid-ethyl), 1H-1, 2,4 - triazol-3 - amine (amitrole), 6 - Chloro-4 - ethyl-2 - isopropyl-1 ,3,5 - triazine (atrazine), 2 - [2,4 - dichloro - 5 - (2 - propynyloxy) - phenyl] -5,6,7,8 - tetrahydro-1 ,2,4 - triazolo - [4,3-a] - pyridine -3 (2H) - one (propargyl piperidine grass yl), N-(4,6 - dimethoxy - pyrimidin-2 - yl)-N'-[1 - methyl - 4 - (2 - methyl-2H-tetrazol-5 - yl)-1H-pyrazol-5 - yl - sulfonyl] - urea (ethyl tetrazole Long), N-benzyl-2 - (4 - fluoro-3 - (trifluoromethyl) - phenoxy) butyramide (Beflubutamid), 4 - chloro-2 - oxo -3 (2H) - benzo-thiazole acetic acid (benazolin), N-D Yl-N-ethyl-2 ,6 - dinitro-4 - (trifluoromethyl) - aniline (B D F Ling), N-(4,6 - dimethoxyphenyl Oxy - pyrimidin-2 - yl)-N'-(2 - methoxycarbonyl - phenyl methyl sulfonyl) - urea (bensulfuron yellow Long), 2 - [2 - [4 - (3,6 - dihydro-3 - methyl-2 ,6 - dioxo-4 - (trifluoromethyl) -1 (2H) - pyrimidin Piperidinyl) phenoxy] methyl]-5 - ethyl - phenoxy - propionate (Benzfendizone), 3 - (2 - chloro-4 - methylsulphonyl - benzoyl) -4 - phenylthio - bicyclo - [3.2.1] - oct-3 - ene - 2 - one (Benzobicyclon), N-benzoyl-N-(3,4 - dichloro - phenyl)-DL-alanine Ethyl (new Yan spirit) 3 - isopropyl-1H-2, 1,3 - benzothiadiazin -4 (3H) - one (herbicides Pine), 5 - (2,4 - dichloro - phenoxy) -2 - nitro - benzoate (carboxymethyl nitrofen), 2,6 - Bis - (4,6 - dimethoxy - pyrimidin-2 - yl - oxy) - benzoate (bispyribac-sodium), 2 - bromo-3 ,3 - Dimethyl-N-(1 - methyl-1 - phenyl - ethyl) - butyramide (bromo butyryl alachlor), 3,5 - dibromo - 4 - hydroxy - benzaldehyde O-(2,4 - dinitro - phenyl)-oxime (oxime bromophenol), 3,5 - dibromo - 4 - hydroxy - Benzonitrile (bromoxynil), N-butoxy - methyl - 2 - chloro-N-(2,6 - diethyl - phenyl) - acetamide (Butachlor), [1,1 - dimethyl-2 - oxo-2 - (2 - propenyl oxy)] - ethyl 2 - chloro -5 - (3,6 - dihydro-3 - methyl-2 ,6 - dioxo-4 - (trifluoromethyl) -1 (2H) - pyrimidinyl) - benzoic acid Ester (Butafenacil-allyl), 2 - (1 - ethoxyimino - propyl) -3 - hydroxy-5 - [2,4,6 - trimethyl-3 - (1 - oxo - butyl) - phenyl]-2 - cyclohexen-1 - one (butoxy-ring Ketone), S-ethyl bis - (2 - methyl - propyl) - thio carbamate (Gerbera enemy), N, N-diethyl -3 - (2,4,6 - trimethyl - phenylsulfonyl)-1H-1, 2,4 - triazol-1 - carboxamide (phenone Yl), 2 - [1 - [(3 - chloro-2 - propenyl) - oxy - imino] - propyl] -3 - hydroxy-5 - (tetrahydro- -2H-pyran-4 - yl) - 2 - cyclohexen-1 - one (quinone oxime grass), 2 - (4 - chloro-2 - fluoro-5 - (2 - chloro - 2 - ethoxycarbonyl - ethyl) - phenyl) -4 - (difluoromethyl) -5 - methyl -2,4 - dihydro-3H- 1,2,4 - triazol-3 - one (fluoromethyl ketone yl grass), 2,4 - dichloro-1 - (3 - methoxy - 4 - nitro - phenoxy Yl) - benzene (methoxy nitrofen) 3 - amino -2,5 - dichloro - benzoic acid (grass off fear), N-(4 - chloro - 6 - methoxy - pyrimidin-2 - yl)-N'-(2 - ethoxycarbonyl - phenylsulfonyl) - urea (chloro-ethyl Long), 1,3,5 - trichloro-2 - (4 - nitro - phenoxy) - benzene (CNP), N-(4 - methoxy-6 - Methyl-1 ,3,5 - triazin-2 - yl)-N'-(2 - chloro - phenylsulfonyl) - urea (chlorsulfuron), N'- (3 - chloro-4 - methyl - phenyl)-N, N-dimethylurea (chlorotoluron), 2 - chloro -3 - [2 - chloro -5 - (1,3,4,5,6,7 - hexahydro-1 ,3 - dioxo-2H-isoindol-2 - yl) - phenyl] -2 - acetic acid Ester (Cinidon-ethyl), N-(4,6 - dimethoxy-1 ,3,5 - triazin-2 - yl)-N'-(2 - (2 - methoxy - ethoxy) - phenylsulfonyl) - urea (ethyl ether) 2 - [1 - [2 - (4 - chloro - phenoxy Yl) - propoxy] butyl] -5 - (tetrahydro -2 H-thiopyran-3 - yl) - 1,3-cyclohexanedione (Clefoxydim), (E, E) - (+) -2 - [1 - [[(3 - chloro-2 - propenyl) - oxy] - imino Yl] - propyl] -3 - hydroxy-2 - cyclohexen-1 - one (clethodim), 2 - propynyl (R) -2 - [4 - (5 - chloro-3 - fluoro - pyridin-2 - yl - oxy) - phenoxy] - propionate (grass propargyl ester), 3,6 - dichloro - Pyridine-2 - carboxylic acid (clopyralid) 3 - chloro-2 - [(5 - ethoxy-7 - fluoro-[1,2,4] triazolo [1,5-c] pyrimidine-2 - yl - sulfonyl) - amino] - benzoate (yl ethyl sulfonamide salt), 2 - chloro -4 - Ethylamino-6 - (1 - cyano-1 - methyl - ethyl-amino) -1,3,5 - triazine (cyanazine), N-(4,6 - two Methoxy - pyrimidin-2 - yl)-N'-(2 - cyclopropylcarbonyl - phenyl - sulfonyl) - urea (ethyl cyclopropane Long), 2 - (1 - ethoxy-imino)-3 - hydroxy-5 - (tetrahydro-2H-thiopyran-3 - yl) -2 - ring Hexene-1 - one (metribuzin thiophene), (R) -2 - [4 - (4 - cyano-2 - fluoro - phenoxy) - phenoxy] - C Butyl (Cyhalofop), 2,4 - dichloro - acetic acid (2,4-D), 3,6 - dichloro-2 - methoxy- - Benzoic acid (dicamba), (R) -2 - (2,4 - dichloro - phenoxy) - propionic acid (fine 2,4 - C Acid), 2 - [4 - (2,4 - dichloro - phenoxy) - phenoxy] - propionic acid methyl ester (diclofop), N-(2,6 - Dichloro - phenyl)-5 - ethoxy-7 - fluoro - [1,2,4] - triazolo - [1,5-c] - pyrimidine-2 - sulfonamide Amine (ethyl sulfonamides yl), 1,2 - dimethyl-3 ,5 - diphenyl-1H-pyrazole methosulfate (wild Yan Dry), N-(2,4 - difluoro - phenyl) -2 - (3 - (trifluoromethyl) - phenoxy) - pyridine-3 - carboxamide (Fluazifop acid alachlor), 2 - [1 - [(3,5 - difluoro - phenyl) - amino - carbonyl - hydrazono] - ethyl] - Pyridine-3 - carboxylic acid (difluoromethyl topiramate long), S-(1 - methyl-1 - phenyl - ethyl)-1 - piperidine - thio acid Ester (Caodan piperazine), (S-) 2 - chloro-N-(2,4 - dimethyl-3 - thienyl)-N-(2 - methoxy-1 - Methyl - ethyl) - acetamide ((S-) dimethyl thiophene alachlor), 2 - amino -4 - (1 - fluoro-1 - methyl - ethyl Yl) -6 - (1 - methyl - 2 - (3,5 - dimethyl - phenoxy) - ethylamino) -1,3,5 - triazine (Dimexyflam), N3, N3-diethyl-2 ,4 - dinitro-6 - (trifluoromethyl) -1,3 - diamino - Benzene (enemy music amines), 6,7 - dihydro - bipyridine and [1,2-a: 2 ', 1'-c] pyrazine two bromide (Diquat Fast), S, S-dimethyl-2 - 2-fluoro-4 - iso-butyl-6 - (trifluoromethyl) pyridine-3, 5 - dithio Methyl ester (dithiopyr), N'-(3,4 - dichloro - phenyl)-N, N-dimethyl - urea (Diuron Long), 2 - [2 - (3 - chloro - phenyl) - oxirane-ylmethyl] -2 - ethyl-1H-indene -1,3 (2H) - Dione (Epropodan), S-ethyl dipropylthiocarbamate (Yin grass enemy), S-(phenyl- Methyl) N-ethyl-N-(1,2 - dimethyl - propyl) - thio carbamate (e Caodan), N-ethyl Yl-N-(2 - methyl-2 - propenyl) -2,6 - dinitro-4 - (trifluoromethyl) - aniline (fluoro-ethyl butylene Spirit), 2 - ethoxy-1 - methyl - 2 - oxo - ethyl (S) -2 - chloro-5 - (2 - chloro -4 - (trifluoromethyl) - Phenoxy) benzoate (Ethoxyfen), N-(4,6 - dimethoxy - pyrimidin-2 - yl)-N'- (2 - ethoxy - phenoxysulfonyl) - urea (ethoxy-ethyl), (R) -2 - [4 - (6 - chloro - benzoxazin Oxazol-2 - yl - oxy) - phenoxy] - propionic acid ethyl ester (fenoxaprop) 4 - (2 - chloro - phenyl) - N-cyclohexyl-N-ethyl-4 ,5 - dihydro-5 - oxo-1H-tetrazol-1 - carboxamide (Fentrazamide), N-benzoyl-N-(3 - chloro-4 - fluoro - phenyl)-DL-alanine iso Esters (isopropyl fluoride straw), N-benzoyl-N-(3 - chloro-4 - fluoro - phenyl)-L-alanine iso- Ester (straw fluoro isopropyl-L), N-benzoyl-N-(3 - chloro-4 - fluoro - phenoxy)-DL-alanine Methyl (methyl fluoride straw), N-(2,6 - difluoro - phenyl) -8 - fluoro-5 - methoxy - [1,2,4] - Triazolo - [1,5-c] - pyrimidine-2 - sulfonamide (Florasulam), (R) -2 - [4 - (5 - trifluoromethyl Base - pyridin-2 - yl - oxy) - phenoxy] - propionic acid butyl (fluazifop-butyl, fine fluazifop Wo Grass Ling butyl), 5 - (4 - bromo-1 - methyl-5 - (trifluoromethyl)-1H-pyrazol-3 - yl) -2 - chloro-4 - fluoro- - Benzoic acid isopropyl ester (Fluazolate), 4,5 - dihydro-3 - methoxy-4 - methyl-5 - oxo - N-[(2 - trifluoromethoxy-phenyl) - sulfonyl]-1H-1, 2,4 - triazol-1 - carboxamide sodium salt (Flucarbazone-sodium salt), N-(4 - fluoro - phenyl)-N-isopropyl-2 - (5 - (trifluoromethyl) - 1,3,4 - thiadiazol-2 - yl - oxy) - acetamide (Flufenacet), N-(2,6 - difluoro - benzene Yl) -5 - methyl-1 ,2,4 - triazolo [1,5-a] - pyrimidine-2 - sulfonamide (yl-ethyl grass Amine), [2 - chloro-4 - fluoro-5 - (1,3,4,5,6,7 - hexahydro-1 ,3 - dioxo-2H-isoindol-2 - Yl) - phenoxy] - acetate, amyl acetate (amyl acid allyl fluoride), 2 - [7 - fluoro-3 ,4 - dihydro-3 - oxo - 4 - (2 - propynyl)-2H-1, 4 - benzoxazin-6 - yl] -4,5,6,7 - tetrahydro-1H-isoindol - 1,3 - dione (flumioxazin amine), 2 - [4 - chloro-2 - fluoro-5 - [(1 - methyl - 2 - propynyl) - O Yl] - phenyl] -4,5,6,7 - tetrahydro-1H-isoindole--1,3 (2H) - dione (Flumipropyn), 3 - chloro-4 - (chloromethyl) -1 - (3 - (trifluoromethyl) - phenyl) -2 - pyrrolidine One (F 1,10 metribuzin), ethoxycarbonylmethyl 5 - (2 - chloro -4 - (trifluoromethyl) - phenoxy) -2 - nitro Base - benzoate (Fluoroglycofen ether), 1 - (4 - chloro -3 - (2,2,3,3,3 - five fluoro - propoxy A Yl) - phenyl) - phenyl-1H-1, 2,4 - triazole-3 - carboxamide (amine fluoride grass yl), 1 - isopropyl - 2 - chloro -5 - (3,6 - dihydro-3 - methyl-2 ,6 - dioxo-4 - (trifluoromethyl) -1 (2H) - pyrimidine Yl) - benzoate (Flupropacil), N-(4,6 - dimethoxy - pyrimidin-2 - yl)-N'-(3 - Methoxycarbonyl-6 - (trifluoromethyl) - pyridin-2 - yl - sulfonyl) - urea sodium salt (yellow fluazinam Long), 9 - hydroxy-9H-fluorene-9 - carboxylic acid (butyl fluorenyl), (4 - amino-3 ,5 - dichloro-6 - fluoro - pyridine - 2 - group - oxy) - acetic acid (2 - butoxy-1 - methyl - ethyl ester, 1 - methyl - heptyl ester) (lambda Topiramate peracetic acid, - butoxy propyl, - iso-heptyl), 5 - methyl-2 - phenyl-4 - (3 - (trifluoromethyl) - Phenyl) -3 (2H) - furanone (furosemide metribuzin), [(2 - chloro-4 - fluoro-5 - (tetrahydro-3 - oxo - 1H, 3H-[1,3,4] - thiadiazole and - [3,4-a] - pyridazin-1 - ylidene) - amino) - phenyl] - sulfur Generation acetate (up grass fluoro), 5 - (2 - chloro -4 - (trifluoromethyl) - propoxy)-N-methyl-sulfonyl-- 2 - nitro - benzamide (fomesafen), 2 - [[[[(4,6 - dimethoxy-2 - pyrimidinyl) - Amino] - carbonyl] - amino] - sulfonyl] -4 - formylamino-N, N-dimethyl - benzamide (Foramsulfuron), 2 - amino-4 - (hydroxymethyl-phosphinyl) - butyric acid (ammonium salt) (glufosinate-ammonium (Ammonium)), N-phosphonomethylglycine (isopropyl ammonium salt) (glyphosate, glyphosate isopropyl ammonium Salt), (R) -2 - [4 - (3 - chloro-5 - (trifluoromethyl) - pyridin-2 - yl - oxy) - phenoxy] - propionic acid (Methyl 2 - ethoxy - ethyl, butyl) (topiramate Wo Ling fluoride, fluorine topiramate A Wo Ling, fine fluoropyrazole A Wo Ling, Wo Ling fluoropyrazole ethoxyethyl, fluoro pyridine Wo Ling butyl) 3 - cyclohexyl-6 - dimethylamino-1 - A -1,3,5 - Triazine -2,4 (1H, 3H) - dione (hexazinone), 2 - (4,5 - dihydro-4 - methyl - 4 - Isopropyl-5 - oxo-1H-imidazol-2 - yl) -4 - methyl - benzoic acid methyl ester (methyl oxalate Mi Ester), 2 - (4,5 - dihydro-4 - methyl - 4 - isopropyl-5 - oxo-1H-imidazol-2 - yl) -5 - methyl- - Pyridine-3 - carboxylic acid (Imazamethapyr), 2 - (4,5 - dihydro-4 - methyl - 4 - isopropyl-5 - -Oxo-1H-imidazol-2 - yl) -5 - methoxymethyl - pyridine-3 - carboxylic acid (imazamox), 2 - (4,5 - dihydro-4 - methyl - 4 - isopropyl-5 - oxo-1H-imidazol-2 - yl) - quinoline-3 - carboxylic acid (Imidazol-quinolinic acid), 2 - (4,5 - dihydro-4 - methyl - 4 - isopropyl-5 - oxo-1H-imidazol-2 - Yl) -5 - ethyl - pyridine - 3 - carboxylic acid (imazethapyr), N-(4,6 - dimethoxy - pyrimidin-2 - Yl)-N'-(2 - chloro - imidazo [1,2-a] - pyridin-3 - yl - sulfonyl) - urea (ethyl zolpidem yellow Long), N-(4 - methoxy-6 - methyl-1 ,3,5 - triazin-2 - yl)-N'-(5 - iodo-2 - methoxycarbonyl Yl - phenylsulfonyl) - urea sodium salt (Iodosulfuron-methyl-sodium), 4 - hydroxy - 3,5 - diiodo - benzonitrile (ioxynil), N, N-dimethyl-N'-(4 - isopropyl - phenyl) - urea (isopropyl Long), N-(3 - (1 - ethyl-1 - methyl - propyl) - isoxazol-5 - yl) -2,6 - dimethoxy - phenyl Formamide (Clomazone amine), (4 - chloro-2 - methyl sulfonyl - phenyl) - (5 - cyclopropyl - isoxazole - 4 - yl) - methanone (Isoxachlortole), (5 - cyclopropyl - isoxazol-4 - yl) - (2 - methyl-sulfonamide Acyl -4 - (trifluoromethyl) - phenyl) - methanone (iso evil fluoride grass) 2 - [2 - [4 - [(3,5 - dichloro-2 - Pyridinyl) - oxy] - phenoxy]-1 - oxo - propyl] - isoxazolidine (Clomazone ether), (2 - ethoxyethyl -1 - methyl - 2 - oxo - ethyl) 5 - (2 - chloro -4 - (trifluoromethyl) - phenoxy) -2 - nitro - phenyl Methyl ester (Lactofen), N'-(3,4 - dichloro - phenyl)-N-methoxy-N-methyl - urea (Lee Gu Long), (4 - chloro-2 - methyl - phenoxy) acetic acid (MCPA) 2 - (4 - chloro-2 - methyl - phenoxy Yl) - propionic acid (2 mecoprop), 2 - (2 - benzothiazolyl yloxy)-N-methyl-N-phenyl - ethyl Amide (alachlor tiaprofenic acid), 2 - (4 - methylsulfonyl-2 - nitro - benzoyl) -1,3 - cyclohexyl Dione (Mesotrione), 4 - amino-3 - methyl-6 - phenyl-1 ,2,4 - triazin -5 (4H) - one (Metamitron), 2 - chloro-N-(2,6 - dimethyl - phenyl)-N-(1H-pyrazol-1 - yl - methyl Yl) - acetamide (pyrazol-metolachlor), N'-(4 - (3,4 - dihydro-2 - methoxy-2 ,4,4 - trimethyl - 2H-1-benzopyran-7 - yl - oxy) - phenyl)-N-methoxy-N-methyl - urea (pyran Long), N'-(4 - bromophenyl)-N-methoxy-N-methyl urea (Takayuki bromide), (S) -2 - chloro-N-(2 - Ethyl-6 - methyl - phenyl)-N-(2 - methoxy-1 - methyl - ethyl) - acetamide (metolachlor Amine, S-metolachlor), N-(2,6 - dichloro-3 - methyl - phenyl) -5,7 - dimethoxy - 1,2,4 - triazolo [1,5-a] pyrimidine-2 - sulfonamide (sulfonamide grass acetazolamide), N'-(3 - chloro-4 - methoxy- Yl - phenyl)-N, N-dimethyl - urea (methoxy Long), 4 - amino-6 - tert-butyl-3 - (methylthio) - 1,2,4 - triazine -5 (4H) - one (metribuzin), N-(4 - methoxy-6 - methyl-1, 3,5 - triazine - 2 - group)-N'-(2 - methoxycarbonyl - phenylsulfonyl) - urea (metsulfuron-methyl), S-ethyl - hexahydro - 1H-azepine 1 - carbothioate (Molinate), 2 - (2 - naphthyloxy)-N-phenyl - propanamide (naphthalene Propylamine), N-butyl-N'-(3,4 - dichloro - phenyl)-N-methyl - urea (grass is not long), N-(4,6 - two Methoxy - pyrimidin-2 - yl)-N'-(3 - dimethyl-carbamoyl - pyridin-2 - yl - sulfonyl) - Urea (nicosulfuron), S-(2 - chloro - benzyl)-N, N-diethyl - dithiocarbamate (Ping grass Dan), 4 - dipropyl-3 ,5 - dinitro - benzenesulfonamide (sulfamoyl pendimethalin), 3 - [2,4 - dichloro - 5 - (2 - propynyloxy) - phenyl] -5 - (tert-butyl) -1,3,4 - oxadiazol -2 (3H) - one (evil propargyl Yl grass), 3 - [2,4 - dichloro-5 - (1 - methyl - ethoxy) - phenyl] -5 - (tert-butyl) -1,3,4 - Oxadiazol -2 (3H) - one (oxadiazon), N-(4,6 - dimethyl - pyrimidin-2 - yl)-N'-(2 - oxa- Cyclobutan-3 - yl - butoxycarbonyl - phenylsulfonyl) - urea (Cinosulfuron cyclopropoxyimino), 3 - [1 - (3,5 - Dichlorophenyl) -1 - isopropyl-yl] -2,3 - dihydro-6 - methyl-5 - phenyl-4H-1, 3 - oxazin-4 - one (Chloro-oxazine grass), 2 - chloro-1 - (3 - ethoxy-4 - nitro - phenoxy) -4 - (trifluoromethyl) phenyl (ethyl Ether oxygen fluroxypyr), 1,1 '- dimethyl-4, 4'- bipyridinium salts (paraquat), 1 - amino-N-(1 - Ethyl - propyl) -3,4 - dimethyl-2 ,6 - dinitro - benzene (pendimethalin), 4 - (tert-butyl)-N- (1 - ethyl - propyl) -2,6 - dinitro - aniline (Pendralin), 4 - amino-3 ,5,6 - trichloro - Pyridine-2 - carboxylic acid (amino acid chloropyridine), 2 - chloro-N-(2,6 - diethyl - phenyl)-N-(2 - propoxy Yl - ethyl) - acetamide (metolachlor), N-(4,6 - bis difluoromethoxy - pyrimidin-2 - yl)-N'- (2 - methoxycarbonyl - phenylsulfonyl) - urea (Primisulfuron), 1 - chloro-N-[2 - chloro-4 - fluoro-5 - [(6S, 7aR) -6 - fluoro - tetrahydro-1 ,3 - dioxo-1H-pyrrolo [1,2-c] imidazol -2 (3H) - Yl] - phenyl] - methanesulfonamide (Profluazol), 2 - chloro-N-isopropyl-N-phenyl - acetyl Amine (propachlor), N-(3,4 - dichloro - phenyl) - propionamide (propanil), (R) - [2 - [[(1 - methyl - Ethylidene) - amino] - oxy] - ethyl] -2 - [4 - (6 - chloro-2 - quinoxalinyloxy) - phenoxy] - Propionate (Oh grass ester), 2 - chloro-N-(2 - ethyl-6 - methyl - phenyl)-N-[(1 - methyl - ethoxyethyl Yl) - methyl] - acetamide (iso-metolachlor), 2 - [[[(4,5 - dihydro-4 - methyl-5 - oxo - Propoxy-1H-1, 2,4 - triazol-1 - yl) - carbonyl] - amino] - sulfonyl] - Sodium benzoate Salt (Propoxycarbazone-sodium salt), S-phenylmethyl N, N-dipropyl - dithiocarbamate Esters (prosulfocarb), N-(4 - methoxy-6 - methyl-1 ,3,5 - triazin-2 - yl)-N'-(2 - (3,3,3 - trifluoro - propyl) - phenylsulfonyl) - urea (fluoro yellow Long), [2 - chloro-5 - (4 - chloro-5 - two Fluoro-methoxy-1 - methyl-1H-pyrazol-3 - yl) -4 - fluoro - phenoxy] - acetate (fluoro azole grass Ester), 1 - (3 - chloro-4 ,5,6,7 - tetrahydro - pyrazolo [1,5-a] pyridin-2 - yl) -5 - (methyl-2 - Amino-propynyl)-1H-pyrazol-4 - carbonitrile (Pyrazogyl), 4 - (2,4 - dichloro - benzoyl) - 1,3 - dimethyl-5 - (4 - methyl - phenyl sulfonyl group) - pyrazole (pyrazolate), 4 - (2,4 - Chloro - benzoyl) -1,3 - dimethyl-5 - (phenylcarbonyl - methoxy) - pyrazole (benzyl grass yl), N- (4,6 - dimethoxy - pyrimidin-2 - yl)-N'-(4 - ethoxy - carbonyl-1 - methyl - pyrazol-5 - yl - Sulfonyl) - urea (pyridin-ethyl), diphenyl ketone O-[2,6 - bis - (4,6 - dimethoxy - ethyl -2 - yl - oxy) - benzoyl] oxime (pyrimidin benzene grass oxime), 6 - chloro-3 - phenyl-4 - pyridazin-ol (Pyridafol), O-(6 - chloro-3 - phenyl - pyridazin-4 - yl) S-octyl thiocarbonate (pyridate Tex), 6 - chloro-3 - phenyl-pyridazin-4 - ol (Pyridatol), 7 - [(4,6 - dimethoxy-2 - pyrimidinyl Yl) - thio] -3 - methyl -1 (3H) - isobenzofuranone (Pyriftalid), 2 - (4,6 - dimethoxyphenyl Oxy - pyrimidin-2 - yl - oxy) - benzoic acid methyl ester (piperidine oxime grass), 2 - chloro-6 - (4,6 - dimethoxyphenyl Yl - pyrimidin-2 - ylthio) - benzoic acid sodium salt (ethyl sulfide grass), 3,7 - dichloro - quinolin-8 - carboxylic acid (Quinchlorac), 7 - chloro-3 - methyl - quinolin-8 - carboxylic acid (chloromethyl quinoline acid), 2 - [4 - (6 - Chloro-2 - quinoxalinyl yloxy) - phenoxy] - propionic acid (ethyl ester, tetrahydro-2 - furanyl - methyl) (quinoline Wo Ling, quizalofop - ethyl Quizalofop ethyl Quizalofop furfuryl acetate), N-(4,6 - dimethoxy - Pyrimidin-2 - yl)-N'-(3 - ethylsulfonyl - pyridin-2 - yl - sulfonyl) - urea (ethyl sulfone Long), 2 - (1 - ethoxy-imino-butyl) -5 - (2 - ethylthio-propyl) -3 - hydroxy-2 - cyclohexene - 1 - one (Sethoxydim piperidine), 6 - chloro-2 ,4 - bis - ethyl-1 ,3,5 - triazine (simazine), 2 - (2 - chloro - 4 - methylsulfonyl - benzoyl) - cyclohexane-1,3 - dione (sulcotrione), 2 - (2,4 - dichloro - 5 - methyl - sulfonyl-amino - phenyl) -4 - (difluoromethyl) -5 - methyl -2,4 - dihydro-3H- 1,2,4 - triazol-3 - one (methanesulfonamide alachlor), N-phosphono-methyl - Gly - trimethylsulfonium (grass sulfur Phosphine), N-(4,6 - dimethoxy - pyrimidin-2 - yl)-N'-(2 - ethyl-sulfonyl - imidazo [1,2 - a] pyridin-3 - yl) sulfonamide (b Huanghuang Long), 6 - chloro-4 - B-2 - tert-butylamino - 1,3,5 - triazine (terbuthylazine), 2 - tert-butyl-4 - ethyl-6 - methylthio-1 ,3,5 - Three Triazine (terbutryn), 2 - chloro-N-(2,6 - dimethyl - phenyl)-N-(3 - methoxy-2 - thienyl - A Yl) - acetamide (alachlor thienyl), 2 - (difluoromethyl) -5 - (4,5 - dihydro - thiazol-2 - yl) -4 - (2 - methyl - propyl) -6 - (trifluoromethyl) - pyridine-3 - carboxylate (thiazol-nicotinic acid), 6 - (6,7 - Dihydro-6 ,6 - dimethyl-3H, 5H-pyrrolo [2,1-c] -1,2,4 - thiadiazol - ylideneamino Yl) -7 - fluoro-4 - (2 - propynyl)-2H-1, 4 - benzoxazin -3 (4H) - one (Thidiazimin), N-(4 - methoxy-6 - methyl-1, 3,5 - triazin-2 - yl)-N'-(2 - methyl Oxy - carbonyl - thiophene-3 - yl - sulfonyl) - urea (thifensulfuron) 2 - (ethoxyimino - C Yl) -3 - hydroxy-5 - (2,4,6 - trimethyl - phenyl) -2 - cyclohexen-1 - one (grass trimethylbenzene Ketone), S-(2,3,3 - trichloro-2-propenyl) - diisopropyl thiocarbamate (wild wheat Fear), N-(4 - methoxy-6 - methyl-1, 3,5 - triazin-2 - yl)-N'-[2 - (2 - chloro - ethoxyethyl Yl) - phenylsulfonyl] - urea (triasulfuron), N-methyl-N-(4 - methoxy-6 - methyl - 1,3,5 - triazin-2 - yl)-N'-(2 - methoxycarbonyl - phenylsulfonyl) - urea (benzenesulfonic Long), (3,5,6 - trichloro) - pyridin-2 - yl - oxy - acetic acid (Triclopyr) 2 - (3,5 - Dichloro - phenyl) -2 - (2,2,2 - trichloro - ethyl) - ethylene oxide (herbicides ring), N-[[(4,6 - two Methoxy-2 - pyrimidinyl) - amino] - carbonyl] -3 - (2,2,2 - trifluoro-ethoxy) -2 - pyridinesulfonamide Sodium salt (Trifloxysulfuron), 1 - amino-2 ,6 - dinitro-N, N-dipropyl-4 - (Trifluoromethyl) - benzene (trifluralin), N-[4 - dimethylamino-6 - (2,2,2 - trifluoro - ethoxy) - 1,3,5 - triazin-2 - yl]-N'-(2 - methoxycarbonyl - phenylsulfonyl) - urea (methyl amine fluoride Long), N-[[(4,6 - dimethoxy-2 - pyrimidinyl) amino] carbonyl] -3 - (N-methyl-N-methyl- Sulfonylamino) -2 - pyridinesulfonamide (see WO-A-92/10660), 2 - [[[[(4,6 - dimethoxyphenyl -2 - pyrimidinyl) amino] carbonyl] amino] - sulfonyl] -4 - [[(methylsulfonyl) amino] methyl Yl] - benzoic acid methyl ester (see DE-A-4335297), 4 - [4,5 - dihydro-4 - methyl-5 - oxo- - (3 - trifluoromethyl)-1H-1, 2,4 - triazol-1 - yl] -2 - [(ethylsulfonyl) amino] -5 - fluoro- - Phenylthio-carboxamide (see WO-A-95/30661) ...
(" the 2nd group of reactive compound ")
And/or it is optional
(d) be selected from down the compound of organizing the promoted crop compatibility in the compound:
4-dichloro-acetyl-1-oxa--4-azepine-spiral shell [4.5]-decane (AD-67); 1-dichloro-acetyl-six hydrogen-3; 3; 8a-trimethyl pyrrolo-[1; 2-a]-pyrimidine-6 (2H)-ketone (BAS-145138); 4-dichloro-acetyl-3; 4-dihydro-3-methyl-2H-1; 4-benzoxazine (benoxacor); 5-chloro-quinoxaline-8-oxygen base-acetate 1-methyl-hexyl ester (cloquintocet-isocyanate); α-(cyano group-methoxyimino)-benzene acetonitrile (cyometrinil); 2; 4-dichlorophenoxyacetic acid (2; 4-D); 2; 2-two chloro-N-(2-oxo-2-(2-acrylic amino)-ethyl)-N-(2-acrylic)-acetamide (DKA_24); 2; 2-two chloro-N; N-two-2-acrylic-acetamide (dichlormide); N-(4-methyl-phenyl)-N '-(1-methyl isophthalic acid-phenyl-ethyl)-urea (daimuron); 4; 6-two chloro-2-phenyl-pyrimidines (fenclorim); 1-(2; 4-two chloro-phenyl)-5-trichloromethyl-1H-1; 2; 4-triazole-3-Ethyl formate (fenchlorazole ethyl ester); 2-chloro-4-trifluoromethyl-thiazole-5-carboxylic acid benzene methyl (flurazole); 4-chloro-N-(1; 3-dioxolanes-2-base-methoxyl group)-α-three fluoro-acetophenone oxime (fluxofenim); 3-dichloro-acetyl-5-(2-furyl)-2; 2-dimethyl-oxazolidine (Xie Cao oxazoles; MON-13900); 4; 5-dihydro-5; 5-diphenyl-3-isoxazole carboxylic acid ethyl ester (Isoxadifen-ethyl); (4-chloro-2-methyl-phenoxy group)-acetate (MCPA); (+-)-2-(4-chloro-2-methylphenoxy) propionic acid (Vi par); 1-(2,4 dichloro benzene base)-4,5-dihydro-5-methyl isophthalic acid H-pyrazoles-3; 5-dicarboxylate (pyrroles's two diethyl phthalates); 2-dichloromethyl-2-methyl isophthalic acid, 3-dioxolanes (MG191), 1; the 8-naphthalic anhydride; α-(1,3-dioxolanes-2-base-methoxyimino)-benzene acetonitrile (oxabetrinil), 2; 2-two chloro-N-(1; 3-dioxolanes-2-base-methyl)-and N-(2-acrylic)-acetamide (PPG-1292) and 3-dichloro-acetyl-2,2,5-trimethyl-oxazolidines (R-29148).
(" the 3rd group of reactive compound ")
Particularly preferred the 2nd group of reactive compound blending ingredients is:
2 - Chloro-N-(ethoxymethyl)-N-(2 - ethyl-6 - methyl - phenyl) - acetamide (dimethachlor Amine), 2 - chloro-N-(methoxymethyl)-N-(2,6 - diethyl - phenyl) - acetamide (a grass Amine), 4 - amino-N-(1,1 - dimethyl - ethyl) -4,5 - dihydro-3 - (1 - methyl - ethyl) -5 - -Oxo-1H-1, 2,4 - triazol-1 - carboxamide (Amicarbazone), N-(4,6 - dimethoxy - Pyrimidin-2 - yl)-N'-(N-methyl-N-methyl - sulfonyl - sulfamoyl) - urea (acid-ethyl), 6 - Chloro-4 - ethyl-2 - isopropyl-1 ,3,5 - triazine (atrazine), N-benzyl-2 - (4 - Fluoro-3 - (trifluoromethyl) - phenoxy) butyramide (Beflubutamid), 3 - isopropyl-1H- 2,1,3 - benzothiadiazin -4 (3H) - one (bentazone), 5 - (2,4 - dichloro - phenoxy) -2 - nitro Base - benzoic acid methyl ester (A carboxylase nitrofen), 2,6 - double - (4,6 - dimethoxy - pyrimidine-2 - yl - Oxygen Yl) - sodium benzoate (Bispyribac), 3,5 - dibromo-4 - hydroxy - benzonitrile (bromoxynil), [1,1 - dimethyl -2 - oxo-2 - (2 - propenyl oxy)] - ethyl 2 - chloro -5 - (3,6 - dihydro-3 - methyl-2 ,6 - Dioxo-4 - (trifluoromethyl) -1 (2H) - pyrimidinyl) - benzoate (Butafenacil- allyl), 2 - (4 - chloro-2 - fluoro-5 - (2 - chloro-2 - ethoxycarbonyl - ethyl) - phenyl) -4 - difluoro -5 - Methyl -2,4 - dihydro-3H-1, 2,4 - triazol-3 - one (fluoromethyl ketone yl grass), N-(4 - methoxy- -6 - methyl-1, 3,5 - triazin-2 - yl)-N'-(2 - chloro - phenylsulfonyl) - urea (chlorosulfonyl Long), N'-(3 - chloro-4 - methyl - phenyl)-N, N-dimethylurea (chlorotoluron), 2 - chloro -3 - [2 - chloro- -5 - (1,3,4,5,6,7 - hexahydro-1 ,3 - dioxo-2H-isoindol-2 - yl) - phenyl] -2 - C Ethyl (Cinidon-ethyl), 2 - propynyl (R) -2 - [4 - (5 - chloro-3 - fluoro - pyridin-2 - Yl - oxy) - phenoxy] - propionate (grass propargyl ester), 3,6 - dichloro - pyridine-2 - carboxylic acid (dichloropyrazolo Pyridine acid), 2 - chloro-4 - ethylamino-6 - (1 - cyano-1 - methyl - ethyl-amino) -1,3,5 - triazine (cyanuric Kusatsu), N-(4,6 - dimethoxy - pyrimidin-2 - yl)-N'-(2 - cyclopropylcarbonyl - phenyl - sulphonyl Yl) - urea (Cyclosulfamuron), 2,4 - dichloro - acetic acid (2,4-D), 3,6 - dichloro-2 - methoxy- Yl - benzoic acid (dicamba), (R) -2 - (2,4 - dichloro - phenoxy) - propionic acid (fine 2,4 - C Acid), 2 - [4 - (2,4 - dichloro - phenoxy) - phenoxy] - propionic acid methyl ester (diclofop), 1,2 - Methyl-3 ,5 - diphenyl-1H-pyrazole methosulfate (Yan Ye dry), N-(2,4 - difluoro - benzene Yl) -2 - (3 - (trifluoromethyl) - phenoxy) - pyridine-3 - carboxamide (fluazifop acid alachlor), 2 - [1 - [(3,5 - difluoro - phenyl) - amino - carbonyl - hydrazono] - ethyl] - pyridine-3 - carboxylic acid (difluoromethyl pyridine Long), (S-) 2 - chloro-N-(2,4 - dimethyl-3 - thienyl)-N-(2 - methoxy-1 - methyl - ethyl Yl) - acetamide ((S-) metolachlor dimethyl thiophene), S-ethyl dipropylthiocarbamate (Yin grass Enemy), (S) - (2 - ethoxy-1 - methyl - 2 - oxo-ethyl) -2 - chloro-5 - (2 - chloro-4 - trifluoromethyl Yl - phenoxy) benzoate (Ethoxyfen), N-(4,6 - dimethoxy - pyrimidin-2 - yl) - N'-(2 - ethoxy - phenoxysulfonyl) - urea (ethoxy-ethyl), (R) -2 - [4 - (6 - chloro - benzene And oxazol-2 - yl - oxy) - phenoxy] - propionic acid ethyl ester (fenoxaprop), N-benzoyl - N-(3 - chloro-4 - fluoro - phenyl)-DL-alanine isopropyl ester (isopropyl fluoride straw), N-benzoyl- -N-(3 - chloro-4 - fluoro - phenyl)-L-alanine isopropyl ester (straw fluoro isopropyl-L), N-benzoyl Yl-N-(3 - chloro-4 - fluoro - phenoxy)-DL-alanine methyl ester (methyl fluoride straw), N-(2,6 - two Fluoro - phenyl) -8 - fluoro-5 - methoxy - [1,2,4] - triazolo - [1,5-c] - pyrimidine-2 - sulfonamide (Florasulam), 5 - (4 - bromo-1 - methyl-5 - (trifluoromethyl)-1H-pyrazol-3 - yl) -2 - chloro - 4 - fluoro - benzoate (Fluazolate), 4,5 - dihydro-3 - methoxy - 4 - methyl-5 - O Generation-N-[(2 - trifluoromethoxy-phenyl) - sulfonyl]-1H-1, 2,4 - triazol-1 - carboxamide sodium salt (Flucarbazone-sodium salt), N-(4 - fluoro - phenyl)-N-isopropyl-2 - (5 - (trifluoromethyl) - 1,3,4 - thiadiazol-2 - yl - oxy) - acetamide (Flufenacet), N-(2,6 - difluoro - benzene Yl) -5 - methyl-1 ,2,4 - triazolo [1,5-a] - pyrimidine-2 - sulfonamide (alachlor yl-ethyl), ethyl Butoxycarbonyl methyl 5 - (2 - chloro -4 - (trifluoromethyl) - phenoxy) -2 - nitro - benzoate (ethyl carboxy Fluroxypyr ether), 1 - (4 - chloro -3 - (2,2,3,3,3 - pentafluoro - methyl-propoxy) - phenyl)-5 - phenyl - 1H-1, 2,4 - triazole-3 - carboxamide (amine fluoride grass yl), N-(4,6 - dimethoxy - pyrimidin-2 - Yl)-N'-(3 - methoxycarbonyl-6 - (trifluoromethyl) - pyridin-2 - yl - sulfonyl) - urea sodium salt (Fluazinam Cinosulfuron), 9 - hydroxy-9H-fluorene-9 - carboxylic acid (butyl fluorenyl), (4 - amino-3 ,5 - dichloro-6 - Fluoro - pyridin-2 - yl - oxy) - acetic acid (2 - butoxy-1 - methyl - ethyl ester, 1 - methyl - heptyl Ester) (fluroxypyr, - butoxy ester, - iso-heptyl) and 5 - methyl-amino-2 - phenyl-4 - (3 - Trifluoromethyl - phenyl) -3 (2H) - furanone (furosemide metribuzin), [(2 - chloro-4 - fluoro-5 - (tetrahydro-3 - Oxo-1H, 3H-[1,3,4] - thiadiazole and - [3,4-a] - pyridazin-1 - ylidene) - amino) - phenyl Yl] - thio acetate (up grass fluorine), 2 - [[[[(4,6 - dimethoxy-2 - pyrimidinyl) - amino Yl] - carbonyl] - amino] - sulfonyl] -4 - formylamino-N, N-dimethyl - benzamide (Foramsulfuron), 2 - amino-4 - (hydroxymethyl-phosphinyl) - butyric acid (ammonium salt) (glufosinate-ammonium (Ammonium)), N-phosphonomethylglycine (isopropyl ammonium salt) (glyphosate, glyphosate isopropyl ammonium Salt), 2 - (4,5 - dihydro-4 - methyl - 4 - isopropyl-5 - oxo-1H-imidazol-2 - yl) -4 - methyl- - Benzoic acid methyl ester (methyl imazethapyr), 2 - (4,5 - dihydro-4 - methyl - 4 - isopropyl-5 - oxo - 1H-imidazol-2 - yl) -5 - methyl - pyridine - 3 - carboxylic acid (Imazamethapyr), 2 - (4,5 - dihydro- -4 - Methyl-4 - isopropyl-5 - oxo-1H-imidazol-2 - yl) -5 - methoxymethyl - pyridin - Carboxylic acid (imazamox), 2 - (4,5 - dihydro-4 - methyl - 4 - isopropyl-5 - oxo-1H-imidazol - 2 - group) - quinoline-3 - carboxylic acid (imidazol-quinoline acid), 2 - (4,5 - dihydro-4 - methyl - 4 - isopropyl - 5 - oxo-1H-imidazol-2 - yl) -5 - ethyl - pyridine - 3 - carboxylic acid (imazethapyr), N-(4 - A -6 - methyl-1, 3,5 - triazin-2 - yl)-N'-(5 - iodo-2 - methoxycarbonyl - phenylsulfonyl Yl) - urea sodium salt (Iodosulfuron-methyl-sodium), 4 - hydroxy-3 ,5 - diiodo - Benzonitrile (ioxynil), N, N-dimethyl-N'-(4 - isopropyl - phenyl) - urea (isoproturon), N-(3 - (1 - ethyl-1 - methyl - propyl) - isoxazol-5 - yl) -2,6 - dimethoxy - benzamide (isoxazol Alachlor), (4 - chloro-2 - methyl sulfonyl - phenyl) - (5 - cyclopropyl - isoxazol-4 - yl) - methanone (Isoxachlortole), (5 - cyclopropyl - isoxazol-4 - yl) - (2 - methylsulphonyl-4 - Three Fluoro methyl - phenyl) - methanone (iso evil fluoride grass), (4 - chloro-2 - methyl - phenoxy) acetic acid (2 A 4 Chlorine) 2 - (4 - chloro-2 - methyl - phenoxy) - propionic acid (MCPA acid) 2 - (4 - methyl sulfonyl -2 - nitro - benzoyl) -1,3 - cyclohexanedione (Mesotrione), 2 - chloro-N-(2,6 - Dimethyl - phenyl)-N-(1H-pyrazol-1 - yl - methyl) - acetamide (pyrazol-metolachlor), (S) -2 - Chloro-N-(2 - ethyl-6 - methyl - phenyl)-N-(2 - methoxy-1 - methyl - ethyl) - acetamide (Metolachlor, S-metolachlor), N-(2,6 - dichloro-3 - methyl - phenyl) -5,7 - dimethyl Dioxo-1 ,2,4 - triazolo [1,5-a] - pyrimidine-2 - sulfonamide (sulfonamide grass acetazolamide), 4 - amino-6 - Butyl-3 - methylthio-1 ,2,4 - triazin -5 (4H) - one (metribuzin), N-(4 - methoxy-6 - Methyl-1 ,3,5 - triazin-2 - yl)-N'-(2 - methoxycarbonyl - phenylsulfonyl) - urea (methanesulfonyl Long), N-(4,6 - dimethoxy - pyrimidin-2 - yl)-N'-(3 - dimethyl-carbamoyl - pyridine - 2 - group - sulfonyl) - urea (nicosulfuron), 1 - amino-N-(1 - ethyl - propyl) -3,4 - dimethyl- 2,6 - dinitro - benzene (pendimethalin), N-(4,6 - bis difluoromethoxy - pyrimidin-2 - yl)-N'- (2 - methoxycarbonyl - phenylsulfonyl) - urea (Primisulfuron), 2 - chloro-N-isopropyl-N-phenyl - Acetamide (propachlor), N-(3,4 - dichloro - phenyl) - propionamide (propanil), 2 - [[[(4,5 - Hydrogen -4 - methyl-5 - oxo-3 - propoxy-1H-1, 2,4 - triazol-1 - yl) - carbonyl] - amino] - Sulfonyl] - benzoic acid methyl ester sodium salt (Propoxycarbazone-sodium salt), S-phenylmethyl- N, N-dipropyl - thiocarbamate (prosulfocarb), N-(4 - methoxy-6 - methyl-1, 3,5 - Triazin-2 - yl)-N'-(2 - (3,3,3 - trifluoro - propyl) - phenylsulfonyl) - urea (fluoro yellow Long), [2 - chloro-5 - (4 - chloro-5 - difluoro-methoxy-1 - methyl-1H-pyrazol-3 - yl) -4 - fluoro - phenyl Oxy] - acetate (fluoro grass yl ester), O-(6 - chloro-3 - phenyl - pyridazin-4 - yl) S-octyl sulfide Generation carbonate (pyridate), 7 - chloro-3 - methyl - quinolin-8 - carboxylic acid (chloromethyl quinoline acid), N- (4,6 - dimethoxy - pyrimidin-2 - yl)-N'-(3 - ethylsulfonyl - pyridin-2 - yl - sulfonyl Yl) - urea (ethyl sulfone), 2 - (1 - ethoxy-imino-butyl) -5 - (2 - ethylthio-propyl) -3 - hydroxy- -2 - cyclohexen-1 - one (Sethoxydim piperidine), 6 - chloro-2 ,4 - bis - ethyl-1 ,3,5 - triazine (SIMA Jin), 2 - (2 - chloro-4 - methylsulphonyl - benzoyl) - cyclohexane-1,3 - dione (methyl grass Ketone), N-phosphono-methyl - Gly - trimethylsulfonium (grass phosphinothioyl), N-(4,6 - dimethoxy - ethyl -2 - yl)-N'-(2 - ethyl-sulfonyl - imidazo [1,2-a] pyridin-3 - yl) sulfonamide (B Huanghuang Long), 6 - chloro-4 - B-2 - tert-butyl-1 ,3,5 - triazine (terbuthylazine), 2 - t- Butyl-4 - ethyl-6 - methylthio-1 ,3,5 - triazine (terbutryn), N-(4 - methoxy - 6 - methyl-1 ,3,5 - triazin-2 - yl)-N'-(2 - methoxy - carbonyl - thiophene-3 - yl - sulfonyl Yl) - urea (thifensulfuron-methyl), 2 - (ethoxy-imino - propyl) -3 - hydroxy-5 - (2,4,6 - trimethyl- - Phenyl) -2 - cyclohexen-1 - one (tralkoxydim), S-(2,3,3 - trichloro-2-propenyl) - two Isopropyl carbamate (triallate), N-(4 - methoxy-6 - methyl-1, 3,5 - triazine - 2 - group)-N'-[2 - (2 - chloro - ethoxy) - phenyl sulfonyl] - urea (triasulfuron), N-methyl - N-(4 - methoxy-6 - methyl-1, 3,5 - triazin-2 - yl)-N'-(2 - methoxycarbonyl - phenyl sulfonamide Acyl) - urea (tribenuron) 2 - (3,5 - dichloro - phenyl) -2 - (2,2,2 - trichloro - ethyl) - Epoxy Ethane (herbicides ring), N-[[(4,6 - dimethoxy-2 - pyrimidinyl) - amino] - carbonyl] -3 - (2,2,2 - trifluoro-ethoxy) -2 - pyridine sulfonamide sodium salt (Trifloxysulfuron), 1 - ammonia -2 ,6 - dinitro-N, N-dipropyl-4 - (trifluoromethyl) - benzene (trifluralin). ...
Particularly preferred the 3rd group of reactive compound blending ingredients is:
5-chloro-quinoxaline-8-oxygen base-acetate 1-methyl-hexyl ester (cloquintocet-isocyanate), 1-(2,4-two chloro-phenyl)-5-trichloromethyl-1H-1,2,4-triazole-3-Ethyl formate (fenchlorazole ethyl ester), 4,5-dihydro-5,5-diphenyl-3-isoxazole carboxylic acid ethyl ester (Isoxadifen-ethyl), 1-(2,4 dichloro benzene base)-4,5-dihydro-5-methyl isophthalic acid H-pyrazoles-3,5-dicarboxylate (pyrroles's two diethyl phthalates) and 2,4 dichlorophenoxyacetic acid (2,4-D) and derivative.
Compound 1-(2, the 4-dichlorophenyl)-4,5-dihydro-5-methyl isophthalic acid H-pyrazoles-3,5-diethyl dicarboxylate (pyrroles's two diethyl phthalates), 1-methyl hexyl [(5-chloro-8-quinolyl) oxygen base] acetic acid esters (cloquintocet isocyanate) and 1-(2,4 dichloro benzene base)-5-(trichloromethyl)-1H-1,2,4-triazole-3-carboxylic acid, ethyl ester (fenchlorazole ethyl ester) is disclosed in the following patent application: DE-A-3939503, EP-A-191736 and DE-A-3525205.2,4-D is known weed killer herbicide.
Astoundingly, have now found that the active substance combinations of above-mentioned Tritosulfuron and above-mentioned the 1st group of reactive compound, and choose wantonly and mix with the 2nd group of reactive compound and/or the 3rd group of reactive compound, particularly when having very high activity of weeding, have good crop tolerance and can be applicable to various crops, wheat particularly, but also can be in corn and barley selective weed control.
Wonderful, be significantly higher than the effect summation of single reactive compound by the activity of weeding of Tritosulfuron and above-mentioned the 1st group of active substance combinations of the present invention that compound forms.
Therefore, this shows not only have complementation but also have unexpected synergistic activity.Various crop has good tolerance to this new active substance combinations, and this new active substance combinations also can be prevented and kill off the weeds that those alternate manners are difficult to prevent and kill off effectively here.Therefore, in present selective herbicide, increased a kind of valuable new active substance combinations.
And, be surprisingly found out that the above-mentioned active substance combinations that forms by Tritosulfuron and safener/antipoison (" the 3rd group of reactive compound "), and mix with one or more above-mentioned the 1st group of reactive compounds, particularly when having very high activity of weeding, have good crop tolerance and can be applicable to various crops, cereal crop particularly, especially wheat, but also can be in soybean, potato, corn and paddy rice selective weed control.
Wonderful, also find the herbicidal active compounds 2,4 dichlorophenoxyacetic acid (2,4-D) and derivative also can play the effect of above-mentioned safener.
And surprisingly, but in of a large amount of known safe agent or antipoison of antagonism weed killer herbicide to the Toxicity in Crops effect, the mixture that the 3rd group of particularly above-mentioned reactive compound can almost completely be offset Tritosulfuron and one or more above-mentioned the 1st group of reactive compounds is to the Toxicity in Crops effect, and the activity of weeding to weeds does not have adverse effect simultaneously.
The present invention preferably especially to grouting cereal crop, as paddy rice, wheat, particularly advantageous those particularly preferred the 3rd group of blending ingredients of barley and rye.
More preferred Tritosulfuron and Propoxycarbazone (sodium salt) and the mixture that mixes with one or more following reactive compounds:
N-(4; 6-dimethoxy-pyrimidine-2-base)-N '-(N-methyl-N-methyl-sulfonyl-sulfonamides)-urea (amidosulfuron); 2; 6-two-(4; 6-dimethoxy-pyrimidine-2-base-oxygen base)-Sodium Benzoate (two careless ether); 2-(4-chloro-2-fluoro-5-(2-chloro-2-ethoxy carbonyl-ethyl)-phenyl)-4-difluoromethyl-5-methyl-2; 4-dihydro-3H-1; 2; 4-triazole-3-ketone (fluorine ketazolam grass); 2-chloro-3-[2-chloro-5-(1; 3; 4; 5; 6; 7-six hydrogen-1; 3-dioxo-2H-iso-indoles-2-yl)-phenyl]-2-ethyl propionate (Cinidon-ethyl); 2; 4-two chloro-phenoxy acetic acids (2; 4-D); (R)-2-(2; 4-two chloro-phenoxy groups)-propionic acid (smart 2; 4-drips propionic acid); N-(2; 4-two fluoro-phenyl)-2-(3-trifluoromethyl-phenoxy group)-pyridine-3-carboxamide (diflufenican); N-(4-fluoro-phenyl)-N-isopropyl-2-(5-Trifluoromethyl-1; 3; 4-thiadiazoles-2-base-oxygen base)-acetamide (Flufenacet); N-(4; 6-dimethoxy-pyrimidine-2-base)-sodium salt of N '-(3-methoxycarbonyl-6-trifluoromethyl-pyridine-2-base-sulfonyl)-urea (the fluorine pyridine is yellow grand); (4-amino-3; 5-two chloro-6-fluoro-pyridine-2-base-oxygen bases)-acetate (2-butoxy-1-methyl-ethyl ester; 1-methyl-heptyl ester) (fluroxypyr;-Ding oxygen propyl ester;-isocyanate); N-(4-methoxyl group-6-methyl isophthalic acid; 3; 5-triazine-2-yl)-sodium salt (Iodosulfuron-methyl-sodium) of N '-(5-iodo-2-methoxycarbonyl-phenyl sulfonyl)-urea; N; N-dimethyl-N '-(4-isopropyl-phenyl)-urea (isoproturon); 2-(4-chloro-2-methyl-phenoxy group)-propionic acid (Vi par); 4-amino-6-the tert-butyl group-3-methyl mercapto-1,2,4-triazine-5 (4H)-ketone (piperazine humulone); N-[[(4; 6-dimethoxy-2-pyrimidine radicals)-amino]-carbonyl]-3-(2,2, the 2-trifluoro ethoxy)-2-pyridine sulfonamide sodium salt (Trifloxysulfuron).
And, more preferred Tritosulfuron and Flucarbazone (sodium salt) and the mixture that mixes with one or more following reactive compounds:
2; 6-two-(4; 6-dimethoxy-pyrimidine-2-base-oxygen base)-Sodium Benzoate (two careless ether); 3; 5-two bromo-4-hydroxyl-benzonitriles (Brominal); 2-(4-chloro-2-fluoro-5-(2-chloro-2-ethoxy carbonyl-ethyl)-phenyl)-4-difluoromethyl-5-methyl-2; 4-dihydro-3H-1; 2; 4-triazole-3-ketone (fluorine ketazolam grass); 2-chloro-3-[2-chloro-5-(1; 3; 4; 5; 6; 7-six hydrogen-1; 3-dioxo-2H-iso-indoles-2-yl)-phenyl]-2-ethyl propionate (Cinidon-ethyl); 2-propynyl (R)-2-[4-(5-chloro-3-fluoro-pyridine-2-base-oxygen base)-phenoxy group]-propionic ester (alkynes grass ester); 3; 6-two chloro-pyridine-2-carboxylic acids (clopyralid); 2; 4-two chloro-phenoxy acetic acids (2; 4-D); 3; 6-two chloro-2-methoxyl group-benzoic acid (dicamba); (R)-2-[4-(6-chloro-benzoxazole-2-base-oxygen base)-phenoxy group]-ethyl propionate (fenoxapropPethyl); N-(2; 6-two fluoro-phenyl)-8-fluoro-5-methoxyl group-[1,2,4]-triazol-[1; 5-c]-pyrimidine-2-sulfonamide (Florasulam); N-(4-fluoro-phenyl)-N-isopropyl-2-(5-Trifluoromethyl-1,3,4-thiadiazoles-2-base-oxygen base)-acetamide (Flufenacet); N-(4; 6-dimethoxy-pyrimidine-2-base)-and the sodium salt of N '-(3-methoxycarbonyl-6-trifluoromethyl-pyridine-2-base-sulfonyl)-urea (the fluorine pyridine is yellow grand), (4-amino-3,5-two chloro-6-fluoro-pyridine-2-base-oxygen bases)-acetate (2-butoxy-1-methyl-ethyl ester; 1-methyl-heptyl ester) (fluroxypyr;-Ding oxygen propyl ester ,-isocyanate), 2-(4; 5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazoles-2-yl)-4-methyl-methyl benzoate (miaow methyl oxalate); 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazoles-2-yl)-5-methoxy-pyridine-3-carboxylic acid (imazamox), N-(4-methoxyl group-6-methyl isophthalic acid; 3; 5-triazine-2-yl)-and the sodium salt (Iodosulfuron-methyl-sodium) of N '-(5-iodo-2-methoxycarbonyl-phenyl sulfonyl)-urea, N, N-dimethyl-N '-(4-isopropyl-phenyl)-urea (isoproturon); (4-chloro-2-methyl-phenoxy group) acetate (2 first, 4 chlorine); 2-(4-chloro-2-methyl-phenoxy group)-propionic acid (Vi par), the 4-amino-6-tert-butyl group-3-methyl mercapto-1,2; 4-triazine-5 (4H)-ketone (piperazine humulone); 2-[[[(4,5-dihydro-4-methyl-5-oxo-3-propoxyl group-1H-1,2; the 4-triazol-1-yl)-carbonyl]-amino]-sulfonyl]-methyl benzoate sodium salt (Propoxycarbazone-sodium salt); [2-chloro-5-(4-chloro-5-difluoro-methoxy-1-methyl isophthalic acid H-pyrazole-3-yl)-4-fluoro-phenoxy group]-ethyl acetate (fluorine carfentrazone), N-(4,6-dimethoxy-pyrimidine-2-base)-N '-(2-ethylsulfonyl-imidazo [1; 2-a] pyridin-3-yl) sulfonamide (lead ethyl xanthate is yellow grand); N-(4-methoxyl group-6-methyl isophthalic acid, 3,5-triazine-2-yl)-N '-(2-methoxyl group-carbonyl-thiene-3-yl--sulfonyl)-urea (thifensulfuronmethyl); 2-(ethoxy imino-propyl group)-3-hydroxyl-5-(2; 4,6-trimethyl-phenyl)-2-cyclohexene-1-ketone (tralkoxydim), S-(2; 3; 3-three chloro-2-acrylic) diisopropyl thiocarbamate (triallate), N-[[(4,6-dimethoxy-2-pyrimidine radicals)-amino]-carbonyl]-3-(2; 2, the 2-trifluoro ethoxy)-2-pyridine sulfonamide sodium salt (Trifloxysulfuron).
Active substance combinations of the present invention for example can be applicable to following plant:
Broadleaf weed belongs to:The Europe sinapsis alba belongs to, separate row Vegetable spp, Bedstraw, Stellaria, Matricaria, Anthemis, ox achyranthes chrysanthemum spp, Chenopodium, Urtica, Senecio, Amaranthus, Portulaca, Xanthium, japanese bearbind belongs to, Ipomoea, Polygonum, Daubentonia, Ambrosia, Cirsium, bristlethistle, sonchus, Solanum, Lepidium, joint joint Lepidium, Vandellia, lamium, Veronica, abutilon, thorn Rumex, Datura, Viola, the weasel hemp nettle belongs to, papaver, bachelor's-button, Clover, Ranunculus and Dandelion.
Dicotyledonous crops belongs to:Gossypium, Glycine, Beta, Daucus, Phaseolus, Pisum, Solanum, linum, Ipomoea, Vetch, Nicotiana, tomato belongs to, Arachis, Brassicas, Lactuca, Cucumis and Cucurbita.
Monocotyledon weed belongs to:Echinochloa, setaria, Panicum, knotgrass, ladder forage spp, annual bluegrass belongs to, Festuca, and yard grass belongs to, Brachiaria, Lolium, Brome, Avena, Cyperus, sorghum, Agropyron, Cynodon, Monochoria, genus fimbristylis, arrowhead belongs to, Eleocharis, grass belongs to, Paspalum, ischaemum, cusp Pittosporum, talon eria, Jian's thigh Ying belongs to, and amur foxtail belongs to, and Apera and grass belong to.
Monocot crops belongs to:Oryza, Zea, Triticum, Hordeum, Avena, Secale, sorghum, Panicum, saccharum, Ananas, Asparagus and allium.
But the application of active substance combinations of the present invention is not restricted in the above-mentioned genus, but can expand to other plant in the same manner.
According to the present invention, can handle all plants and plant each several part.Plant can be understood as all plants and plant community herein, as needs and unwanted wild plant or crop (comprising the crop that nature grows).Crop can be by conventional breeding and optimization method or by biotechnology and genetic engineering method or said method in conjunction with the plant that obtains, comprise genetically modified plants and comprise the plant variety that obtains or do not obtain the protection of plant variety power.The each several part of plant can be regarded as all ground and under ground portion and plant tissues, and as stem, leaf, Hua Hegen, the example that can mention is blade, needle, branch, trunk, flower, fruit body, fruit and seed and root, stem tuber and root-like stock.The plant each several part also comprises asexual and sexual propagation material, for example seedling, stem tuber, root-like stock, cutting and seed.
The processing of using reactive compound of the present invention to carry out plant and plant each several part is to handle by them were directly used or acted on to conventional treatment method environment, habitat or storage area, for example floods, sprays, fumigates, atomizing, broadcasts sowing, brushes and particularly can also carry out one or more layers dressing under the situation of seed at propagating materials.
Active substance combinations of the present invention synergistic effect under certain concentration ratio is obvious especially.Yet the weight ratio of each reactive compound can change in the scope of broad in active substance combinations.Usually, the Tritosulfuron of every weight portion uses the 0.01-1000 weight portion, a kind of the 1st group of compound of preferred 0.05-500 weight portion and preferred especially 0.1-100 weight portion.
The crop compatibility of same active substance combinations of the present invention shows obviously especially in the finite concentration proportion.Yet the weight ratio of each reactive compound can change in the scope of broad in active substance combinations.Usually, every weight portion Tritosulfuron or with the 1st group of reactive compound, and optional mixture with the 2nd group of reactive compound uses the 0.001-1000 weight portion, preferred 0.01-100 weight portion and especially preferred the 3rd group of reactive compound of 0.1-10 weight portion.
Active substance combinations of the present invention can be converted to the preparation into routine, as liquor, and emulsion, wetting powder, suspending agent, pulvis, pulvis subtilis, paste, solvable pulvis, granule, dense suspended emulsion, with the natural and synthetic material of reactive compound dipping, and the microcapsules in the polymer.
These preparations are produced with known method, and for example with reactive compound and filler, promptly liquid flux and/or solid carrier mix and prepare, and can selectively use surfactant in the preparation arbitrarily, i.e. emulsifier and/or dispersant and/or blowing agent.
Under the situation that makes water as filler, for example, also can be with an organic solvent as cosolvent.Suitable liquid flux mainly contains: arene, and as dimethylbenzene, toluene or Fluhyzon, chlorinated aromatic hydrocarbons class and chloro fat hydro carbons, as chlorobenzene, dichloroethane or carrene, fat hydrocarbon is as cyclohexane or alkane, for example petroleum cuts, mineral oil and vegetable oil, alcohols is as butanols or ethylene glycol and ether and ester class, ketone, as acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK) or cyclohexanone, intensive polar solvent is as dimethyl formamide and dimethyl sulfoxide (DMSO) and water.
Suitable solid carrier has:
For example, ammonium salt and natural minerals powder, as kaolin, clay, talcum, chalk, quartz, Attagel, imvite or diatomite and synthetic mineral powder, as high dispersive silica, aluminium oxide and silicate; The solid carrier that is fit to granule has: for example, the natural rock of pulverizing and classification, as calcite, marble, float stone, sepiolite and dolomite, and the synthetic particle of inorganic and organic dust and the particle of organic material, as sawdust, shuck, corn ears and stems and tobacco stem; Suitable emulsifier and/or blowing agent have: for example nonionic and anion emulsifier, and as polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, alkaryl polyglycol ether for example, alkylsulfonate, alkyl sulfate, arylsulphonate and protein hydrolysate; The dispersant that is fit to has: for example lignin sulfite waste liquor and methylcellulose.
In preparation, also can use sticker, as carboxymethyl cellulose and powder, particle or the natural or synthetic polymer of latex shape, as gum Arabic, polyvinyl alcohol and polyvinyl acetate, and natural phospholipid, as cephalin and lecithin, and synthetic phospholipid.Other additive can be mineral oil and vegetable oil.
Colouring agent that may use such as inorganic pigment, iron oxide for example, titanium oxide and Prussia orchid, and organic dyestuff, as alizarin dyes, azo dyes and metal phthalocyanine dyestuff and trace nutrients are as the salt of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
Usually contain 0.1-95% by weight in the preparation, the reactive compound of preferred 0.5-90% is comprising safener.
Usually, active substance combinations of the present invention now uses with form with existing mixing.Yet the reactive compound that comprises in the active substance combinations is preparation and mixing in use separately, promptly uses with the bucket form of mixing.
New active substance combinations can itself or its dosage form use, and can also further mix with other known weed killer herbicide, wherein can also with existing mix existing with or jar mixed form use.They can also with other known activity compound, as kill true mattress agent, insecticide, miticide, nematocide, bird repellent, growth regulator, plant nutrient agent and soil structure conditioner mix.According to specific application purpose, particularly when postemergence application, also can preferably in preparation, add mineral or vegetable oil (for example commercially available prod " Rako Binol ") or the ammonium salt that plant can tolerate, as ammonium sulfate or ammonium thiocyanate as other additive.
The new active substance combinations of the present invention can itself, and the application form of its dosage form or further dilution preparation uses, as now using solution, suspension, emulsion, pulvis, paste and granule.Can use above-mentioned preparation in a usual manner, for example irrigate, spraying, atomizing dusts or broadcasts sowing.
Can plant emerge preceding and after, promptly before the seedling and postemergence application active substance combinations of the present invention.Also can prior to seeding active substance combinations be sneaked into soil.
When exceeding each reactive compound when using separately active, the activity of weeding of active substance combinations then has the synergistic effect of weed killer herbicide.
Calculate the expection activity (with reference to COLBY, S.R.: " synergy of Herbicidal compositions and the calculating of antagonism ", Weeds 15, the 20-22 pages or leaves, 1967) of the mixture of two kinds of given weed killer herbicides according to following formula:
The infringement % of weed killer herbicide A when if the X=amount of application is p kg/ha
The infringement % of weed killer herbicide B when being q kg/ha with the Y=amount of application
And the infringement % of E=amount of application weed killer herbicide A and B expection when being p and q kg/ha,
E=X+Y-(X*Y/100) then.
If actual infringement is greater than the desired value of calculating, so the activity of mixture just greater than add with, promptly have synergistic activity.
For three component Herbicidal compositions, formula is:
E＝X+Y+Z-((X*Y+X*Z+Y*Z)/100)+(X*Y*Z/10000)，
Wherein
The infringement % of weed killer herbicide C when the Z=amount of application is r kg/ha
Application Example:
Use the conventional formulation of above-mentioned reactive compound.The Propoxycarbazone-sodium salt uses 70WG and Tritosulfuron to use the 71.4WG preparation.The reactive compound aqueous spray solutions of 0.1%Renex-36 is added in preparation. Embodiment ABehind the seedling/greenhouse test
Test plants is planted in the greenhouse of controllable environment condition (temperature and illumination condition).When plant grows to 5-15cm when high, spray with test solution.Select spray liquid concentration so that under the various situation required a certain amount of reactive compound use with 500 premium on currency/hectares.
After spraying is handled, container for plants is remained in the constant greenhouse of illumination and temperature condition.
After about three weeks, compare the extent of injury of estimating crop with the developmental state of untreated control, with % injury expression.
Following numeral:
0%=is injury (being similar to untreated control) not
100%=all kills/injures
Reactive compound, amount of application, test plants and the results are shown in the following table, wherein following implication is represented in the abbreviation of using in the table:
A.i.=active component=reactive compound
Table A-1
Amount of application gai/ha Black bromegrass observation Black bromegrass calculated value *
The Propoxycarbazone-sodium salt ????30 ????95
Tritosulfuron ????15 ????8 ????0 ????0
Propoxycarbazone-sodium salt+Tritosulfuron ????30+15 ????30+8 ????100 ????100 ????95 ????95
Table A-2
Amount of application gai/ha The piemarker observation The piemarker calculated value *
The Propoxycarbazone-sodium salt ????30 ????15 ????20 ????0
Tritosulfuron ????30 ????15 ????40 ????0
Propoxycarbazone-sodium salt+Tritosulfuron ????30+30 ????15+30 ????30+15 ????15+15 ????80 ????80 ????70 ????70 ????52 ????40 ????20 ????0
Table A-3
Amount of application gai/ha The lamb's-quarters observation The lamb's-quarters calculated value *
The Propoxycarbazone-sodium salt ????30 ????60
Tritosulfuron ????8 ????40
Propoxycarbazone-sodium salt+Tritosulfuron ????30+8 ????100 ????76
Table A-4
Amount of application gai/ha Polco conudvulus observation Polco conudvulus calculated value *
The Propoxycarbazone-sodium salt ????30 ????0
Tritosulfuron ????30 ????8 ????50 ????0
Propoxycarbazone-sodium salt+Tritosulfuron ????30+30 ????30+8 ????80 ????40 ????50 ????0
Table A-5
Amount of application gai/ha The black nightshade observation The black nightshade calculated value *
The Propoxycarbazone-sodium salt ????30 ????15 ????50 ????50
Tritosulfuron ????30 ????15 ????8 ????70 ????70 ????30
Propoxycarbazone-sodium salt+Tritosulfuron ????30+30 ????15+30 ????30+15 ????15+15 ????30+8 ????100 ????98 ????98 ????95 ????98 ????85 ????85 ????85 ????85 ????65
Table A-6
Amount of application gai/ha The chickweed observation The chickweed calculated value *
The Propoxycarbazone-sodium salt ????30 ????20
Tritosulfuron ????8 ????50
Propoxycarbazone-sodium salt+Tritosulfuron ????30+8 ????100 ????60
Table A-7
Amount of application gai/ha Arabic Veronica observation Arabic Veronica calculated value *
The Propoxycarbazone-sodium salt ????30 ????20
Tritosulfuron ????30 ????40
Propoxycarbazone-sodium salt+Tritosulfuron ????30+30 ????90 ????52
Table A-8
Amount of application gai/ha The field viola observation The field viola calculated value *
The Propoxycarbazone-sodium salt ????30 ????15 ????60 ????30
Tritosulfuron ????15 ????0
Propoxycarbazone-sodium salt+Tritosulfuron ????30+15 ????15+15 ????95 ????70 ????60 ????30
*Value according to the calculating of Colby method

Claims (5)

1. a Herbicidal combinations is characterized in that they comprise the active substance combinations of synergy effective dose, and this mixture comprises
(a)Tritosulfuron
With
(b) be selected from one or more compounds in the one group of weed killer herbicide that contains following reactive compound:
(5-Trifluoromethyl-1; 3; 4-thiadiazoles-2-base-oxygen base)-N-isopropyl-N-(4-fluoro-phenyl) acetamide (Flufenacet); 2-(2-methoxycarbonyl benzenesulfonyl amino carbonyl)-4-methyl-5-positive propoxy-2; 4-dihydro-3H-1; 2; the sodium salt of 4-triazole-3-ketone or this compound (Propoxycarbazone (sodium salt)); 2-(2-trifluoromethoxy-benzenesulfonyl-amino carbonyl)-4-methyl-5-methoxyl group-2; 4-dihydro-3H-1; 2; the sodium salt of 4-triazole-3-ketone or this compound (Flucarbazone (sodium salt)); N-(3; the 4-dichlorophenyl) propionamide (Stam F-34); N-2-benzothiazolyl-N; N '-dimethyl urea (methabenzthiazuron); 4-amino-6-(1; the 1-dimethyl ethyl)-3-(methyl mercapto)-1; 2; 4-triazine-5 (4H)-ketone (piperazine humulone); 4-(2-chlorphenyl)-N-cyclohexyl-N-ethyl-4; 5-dihydro-5-oxo-1H-tetrazolium-1-formamide (Fentrazamide); 4-amino-3-methyl-6-phenyl-1; 2; 4-triazine-5 (4H)-ketone (metamitron), 2-(2-[4-morpholinodithio base oxygen base)-N-methyl-phenyl acetanilide,Phenacetylaniline (mefenacet), 4-amino-6-(1; the 1-dimethyl ethyl)-3-(ethylmercapto group)-1; 2,4-triazine-5 (4H)-ketone (ethiozin), 5-[4-bromo-1-methyl-5-(trifluoromethyl)-1H-pyrazole-3-yl]-2-chloro-4-fluobenzoic acid 1-methyl ethyl ester (Fluazolate)
(" the 1st group of reactive compound ")
And it is optional
(c) be selected from one or more compounds in the second group of weed killer herbicide that contains following reactive compound:
2 - Chloro-N-(ethoxymethyl)-N-(2 - ethyl-6 - methyl - phenyl) - acetamide (dimethachlor Amine), 5 - (2 - chloro -4 - (trifluoromethyl) - phenoxy) -2 - nitro - acid salt (of trifluoromethyl carboxymethyl Ether), 2 - chloro-6 - nitro-3 - phenoxy - aniline (aclonifen), 2 - chloro-N-(methoxymethyl) - N-(2,6 - diethyl - phenyl) - acetamide (alachlor), N-ethyl-N'-isopropyl-6 - (methylthio) -1,3,5 - Triazine-2 ,4 - diamine (ametryn), 4 - amino-N-(1,1 - dimethyl - ethyl) - 4,5 - dihydro-3 - (1 - methyl - ethyl) -5 - oxo-1H-1, 2,4 - triazol-1 - carboxamide (Amicarbazone), N-(4,6 - dimethoxy - pyrimidin-2 - yl)-N'-(N-methyl-N-methyl- - Sulfonyl - sulfamoyl) - urea (acid-ethyl), 1H-1, 2,4 - triazol-3 - amine (amitrole), 6 - Chloro-4 - ethyl-2 - isopropyl-1 ,3,5 - triazine (atrazine), 2 - [2,4 - dichloro - 5 - (2 - propynyloxy) - phenyl] -5,6,7,8 - tetrahydro-1 ,2,4 - triazolo - [4,3-a] - pyridine -3 (2H) - one (propargyl piperidine grass yl), N-(4,6 - dimethoxy - pyrimidin-2 - yl)-N'-[1 - methyl - 4 - (2 - methyl-2H-tetrazol-5 - yl)-1H-pyrazol-5 - yl - sulfonyl] - urea (ethyl tetrazole Long), N-benzyl-2 - (4 - fluoro-3 - (trifluoromethyl) - phenoxy) butyramide (Beflubutamid), 4 - chloro-2 - oxo -3 (2H) - benzo-thiazole acetic acid (benazolin), N-D Yl-N-ethyl-2 ,6 - dinitro-4 - (trifluoromethyl) - aniline (B D F Ling), N-(4,6 - dimethoxyphenyl Oxy - pyrimidin-2 - yl)-N'-(2 - methoxycarbonyl - phenyl methyl sulfonyl) - urea (bensulfuron yellow Long), 2 - [2 - [4 - (3,6 - dihydro-3 - methyl-2 ,6 - dioxo-4 - (trifluoromethyl) -1 (2H) - pyrimidin Piperidinyl) phenoxy] methyl]-5 - ethyl - phenoxy - propionate (Benzfendizone), 3 - (2 - chloro-4 - methylsulphonyl - benzoyl) -4 - phenylthio - bicyclo - [3.2.1] - oct-3 - ene - 2 - one (Benzobicyclon), N-benzoyl-N-(3,4 - dichloro - phenyl)-DL-alanine Ethyl (new Yan spirit) 3 - isopropyl-1H-2, 1,3 - benzothiadiazin -4 (3H) - one (herbicides Pine), 5 - (2,4 - dichloro - phenoxy) -2 - nitro - benzoate (carboxymethyl nitrofen), 2,6 - Bis - (4,6 - dimethoxy - pyrimidin-2 - yl - oxy) - benzoate (bispyribac-sodium), 2 - bromo-3 ,3 - Dimethyl-N-(1 - methyl-1 - phenyl - ethyl) - butyramide (bromo butyryl alachlor), 3,5 - dibromo - 4 - hydroxy - benzaldehyde O-(2,4 - dinitro - phenyl)-oxime (oxime bromophenol), 3,5 - dibromo - 4 - hydroxy - Benzonitrile (bromoxynil), N-butoxy - methyl - 2 - chloro-N-(2,6 - diethyl - phenyl) - acetamide (Butachlor), [1,1 - dimethyl-2 - oxo-2 - (2 - propenyl oxy)] - ethyl 2 - chloro -5 - (3,6 - dihydro-3 - methyl-2 ,6 - dioxo-4 - (trifluoromethyl) -1 (2H) - pyrimidinyl) - benzoic acid Ester (Butafenacil-allyl), 2 - (1 - ethoxyimino - propyl) -3 - hydroxy-5 - [2,4,6 - trimethyl-3 - (1 - oxo - butyl) - phenyl]-2 - cyclohexen-1 - one (butoxy-ring Ketone), S-ethyl bis - (2 - methyl - propyl) - thio carbamate (Gerbera enemy), N, N-diethyl -3 - (2,4,6 - trimethyl - phenylsulfonyl)-1H-1, 2,4 - triazol-1 - carboxamide (phenone Yl), 2 - [1 - [(3 - chloro-2 - propenyl) - oxy - imino] - propyl] -3 - hydroxy-5 - (tetrahydro- -2H-pyran-4 - yl) - 2 - cyclohexen-1 - one (quinone oxime grass), 2 - (4 - chloro-2 - fluoro-5 - (2 - chloro - 2 - ethoxycarbonyl - ethyl) - phenyl) -4 - (difluoromethyl) -5 - methyl -2,4 - dihydro-3H- 1,2,4 - triazol-3 - one (fluoromethyl ketone yl grass), 2,4 - dichloro-1 - (3 - methoxy - 4 - nitro - phenoxy Yl) - benzene (methoxy nitrofen) 3 - amino -2,5 - dichloro - benzoic acid (grass off fear), N-(4 - chloro - 6 - methoxy - pyrimidin-2 - yl)-N'-(2 - ethoxycarbonyl - phenylsulfonyl) - urea (chloro-ethyl Long), 1,3,5 - trichloro-2 - (4 - nitro - phenoxy) - benzene (CNP), N-(4 - methoxy-6 - Methyl-1 ,3,5 - triazin-2 - yl)-N'-(2 - chloro - phenylsulfonyl) - urea (chlorsulfuron), N'- (3 - chloro-4 - methyl - phenyl)-N, N-dimethylurea (chlorotoluron), 2 - chloro -3 - [2 - chloro -5 - (1,3,4,5,6,7 - hexahydro-1 ,3 - dioxo-2H-isoindol-2 - yl) - phenyl] -2 - acetic acid Ester (Cinidon-ethyl), N-(4,6 - dimethoxy-1 ,3,5 - triazin-2 - yl)-N'-(2 - (2 - methoxy - ethoxy) - phenylsulfonyl) - urea (ethyl ether) 2 - [1 - [2 - (4 - chloro - phenoxy Yl) - propoxy] butyl] -5 - (tetrahydro-2H-thiopyran-3 - yl) - 1,3-cyclohexanedione (Clefoxydim), (E, E) - (+) -2 - [1 - [[(3 - chloro-2 - propenyl) - oxy] - imino Yl] - propyl] -3 - hydroxy-2 - cyclohexen-1 - one (clethodim), 2 - propynyl (R) -2 - [4 - (5 - chloro-3 - fluoro - pyridin-2 - yl - oxy) - phenoxy] - propionate (grass propargyl ester), 3,6 - dichloro - Pyridine-2 - carboxylic acid (clopyralid) 3 - chloro-2 - [(5 - ethoxy-7 - fluoro-[1,2,4] triazolo [1,5-c] pyrimidine-2 - yl - sulfonyl) - amino] - benzoate (yl ethyl sulfonamide salt), 2 - chloro - 4 - ethyl-6 - (1 - cyano-1 - methyl - ethyl-amino) -1,3,5 - triazine (cyanazine), N- (4,6 - dimethoxy - pyrimidin-2 - yl)-N'-(2 - cyclopropylcarbonyl - phenyl - sulfonyl) - urea (Cyclosulfamuron), 2 - (1 - ethoxy-imino)-3 - hydroxy-5 - (tetrahydro-2H-thiopyran-3 - Yl) -2 - cyclohexen-1 - one (metribuzin thiophene), (R) -2 - [4 - (4 - cyano-2 - fluoro - phenoxy) - benzene Oxy] - propionic acid butyl ester (Cyhalofop), 2,4 - dichloro - acetic acid (2,4-D), 3,6 - dichloro - 2 - methoxy - benzoic acid (dicamba), (R) -2 - (2,4 - dichloro - phenoxy) - propionic acid (2,4-fine - Dichlorprop), 2 - [4 - (2,4 - dichloro - phenoxy) - phenoxy] - propionate (diclofop-methyl), N- (2,6 - dichloro - phenyl)-5 - ethoxy-7 - fluoro - [1,2,4] - triazolo - [1,5-c] - pyrimidine - 2 - sulfonamide (sulfa yl-ethyl), 1,2 - dimethyl-3 ,5 - diphenyl-1H-pyrazole methosulfate (Yan Ye dry), N-(2,4 - difluoro - phenyl) -2 - (3 - (trifluoromethyl) - phenoxy) - pyridin-3 - methyl Amide (fluazifop acid alachlor), 2 - [1 - [(3,5 - difluoro - phenyl) - amino - carbonyl - hydrazono] - acetic Yl] - pyridine-3 - carboxylic acid (difluoromethyl topiramate long), S-(1 - methyl-1 - phenyl - ethyl)-1 - piperidine - thio Methyl ester (Caodan piperazine), (S-) 2 - chloro-N-(2,4 - dimethyl-3 - thienyl)-N-(2 - methoxy- -1 - Methyl - ethyl) - acetamide ((S-) dimethyl thiophene alachlor), 2 - amino -4 - (1 - fluoro-1 - methyl - Ethyl) -6 - (1 - methyl - 2 - (3,5 - dimethyl - phenoxy) - ethylamino) -1,3,5 - triazine (Dimexyflam), N3, N3-diethyl-2 ,4 - dinitro-6 - (trifluoromethyl) -1,3 - diamino - Benzene (enemy music amines), 6,7 - dihydro - bipyridine and [1,2-a: 2 ', 1'-c] pyrazine two bromide (Diquat Fast), S, S-dimethyl-2 - 2-fluoro-4 - iso-butyl-6 - (trifluoromethyl) pyridine-3, 5 - dithio Methyl ester (dithiopyr), N'-(3,4 - dichloro - phenyl)-N, N-dimethyl - urea (Diuron Long), 2 - [2 - (3 - chloro - phenyl) - oxirane-ylmethyl] -2 - ethyl-1H-indene -1,3 (2H) - Dione (Epropodan), S-ethyl dipropylthiocarbamate (Yin grass enemy), S-(phenyl- Methyl) N-ethyl-N-(1,2 - dimethyl - propyl) - thio carbamate (e Caodan), N-ethyl Yl-N-(2 - methyl-2 - propenyl) -2,6 - dinitro-4 - (trifluoromethyl) - aniline (fluoro-ethyl butylene Spirit), 2 - ethoxy-1 - methyl - 2 - oxo - ethyl (S) -2 - chloro-5 - (2 - chloro -4 - (trifluoromethyl) - Phenoxy) benzoate (Ethoxyfen), N-(4,6 - dimethoxy - pyrimidin-2 - yl)-N'- (2 - ethoxy - phenoxysulfonyl) - urea (ethoxy-ethyl), (R) -2 - [4 - (6 - chloro - benzoxazin Oxazol-2 - yl - oxy) - phenoxy] - propionic acid ethyl ester (fenoxaprop) 4 - (2 - chloro - phenyl) - N-cyclohexyl-N-ethyl-4 ,5 - dihydro-5 - oxo-1H-tetrazol-1 - carboxamide (Fentrazamide), N-benzoyl-N-(3 - chloro-4 - fluoro - phenyl)-DL-alanine iso Esters (isopropyl fluoride straw), N-benzoyl-N-(3 - chloro-4 - fluoro - phenyl)-L-alanine iso- Ester (straw fluoro isopropyl-L), N-benzoyl-N-(3 - chloro-4 - fluoro - phenoxy)-DL-alanine Methyl (methyl fluoride straw), N-(2,6 - difluoro - phenyl) -8 - fluoro-5 - methoxy - [1,2,4] - Triazolo - [1,5-c] - pyrimidine-2 - sulfonamide (Florasulam), (R) -2 - [4 - (5 - trifluoromethyl Base - pyridin-2 - yl - oxy) - phenoxy] - propionic acid butyl (fluazifop-butyl, fine fluazifop Wo Grass Ling butyl), 5 - (4 - bromo-1 - methyl-5 - (trifluoromethyl)-1H-pyrazol-3 - yl) -2 - chloro-4 - fluoro- - Benzoic acid isopropyl ester (Fluazolate), 4,5 - dihydro-3 - methoxy-4 - methyl-5 - oxo - N-[(2 - trifluoromethoxy-phenyl) - sulfonyl]-1H-1, 2,4 - triazol-1 - carboxamide sodium salt (Flucarbazone-sodium salt), N-(4 - fluoro - phenyl)-N-isopropyl-2 - (5 - (trifluoromethyl) - 1,3,4 - thiadiazol-2 - yl - oxy) - acetamide (Flufenacet), N-(2,6 - difluoro - benzene Yl) -5 - methyl-1 ,2,4 - triazolo [1,5-a] - pyrimidine-2 - sulfonamide (yl-ethyl grass Amine), [2 - chloro-4 - fluoro-5 - (1,3,4,5,6,7 - hexahydro-1 ,3 - dioxo-2H-isoindol-2 - Yl) - phenoxy] - acetate, amyl acetate (amyl acid allyl fluoride), 2 - [7 - fluoro-3 ,4 - dihydro-3 - oxo - 4 - (2 - propynyl)-2H-1, 4 - benzoxazin-6 - yl] -4,5,6,7 - tetrahydro-1H-isoindol - 1,3 - dione (flumioxazin amine), 2 - [4 - chloro-2 - fluoro-5 - [(1 - methyl - 2 - propynyl) - O Yl] - phenyl] -4,5,6,7 - tetrahydro-1H-isoindole--1,3 (2H) - dione (Flumipropyn), 3 - chloro-4 - (chloromethyl) -1 - (3 - (trifluoromethyl) - phenyl) -2 - pyrrolidine One (F 1,10 metribuzin), ethoxycarbonylmethyl 5 - (2 - chloro -4 - (trifluoromethyl) - phenoxy) -2 - nitro Base - benzoate (Fluoroglycofen ether), 1 - (4 - chloro -3 - (2,2,3,3,3 - five fluoro - propoxy A Yl) - phenyl) - phenyl-1H-1, 2,4 - triazole-3 - carboxamide (amine fluoride grass yl), 1 - isopropyl - 2 - chloro -5 - (3,6 - dihydro-3 - methyl-2 ,6 - dioxo-4 - (trifluoromethyl) -1 (2H) - pyrimidine Yl) - benzoate (Flupropacil), N-(4,6 - dimethoxy - pyrimidin-2 - yl)-N'-(3 - Methoxycarbonyl-6 - (trifluoromethyl) - pyridin-2 - yl - sulfonyl) - urea sodium salt (yellow fluazinam Long), 9 - hydroxy-9H-fluorene-9 - carboxylic acid (butyl fluorenyl), (4 - amino-3 ,5 - dichloro-6 - fluoro - pyridine - 2 - group - oxy) - acetic acid (2 - butoxy-1 - methyl - ethyl ester, 1 - methyl - heptyl ester) (lambda Topiramate peracetic acid, - butoxy propyl, - iso-heptyl), 5 - methyl-2 - phenyl-4 - (3 - (trifluoromethyl) - Phenyl) -3 (2H) - furanone (furosemide metribuzin), [(2 - chloro-4 - fluoro-5 - (tetrahydro-3 - oxo - 1H, 3H-[1,3,4] - thiadiazole and - [3,4-a] - pyridazin-1 - ylidene) - amino) - phenyl] - sulfur Generation acetate (up grass fluoro), 5 - (2 - chloro -4 - (trifluoromethyl) - propoxy)-N-methyl-sulfonyl-- 2 - nitro - benzamide (fomesafen), 2 - [[[[(4,6 - dimethoxy-2 - pyrimidinyl) - Amino] - carbonyl] - amino] - sulfonyl] -4 - formylamino-N, N-dimethyl - benzamide (Foramsulfuron), 2 - amino-4 - (hydroxymethyl-phosphinyl) - butyric acid (ammonium salt) (glufosinate-ammonium (Ammonium)), N-phosphonomethylglycine (isopropyl ammonium salt) (glyphosate, glyphosate isopropyl ammonium Salt), (R) -2 - [4 - (3 - chloro-5 - (trifluoromethyl) - pyridin-2 - yl - oxy) - phenoxy] - propionic acid (Methyl 2 - ethoxy - ethyl, butyl) (topiramate Wo Ling fluoride, fluorine topiramate A Wo Ling, fine fluoropyrazole A Wo Ling, Wo Ling fluoropyrazole ethoxyethyl, fluoro pyridine Wo Ling butyl) 3 - cyclohexyl-6 - dimethylamino-1 - A -1,3,5 - Triazine -2,4 (1H, 3H) - dione (hexazinone), 2 - (4,5 - dihydro-4 - methyl - 4 - Isopropyl-5 - oxo-1H-imidazol-2 - yl) -4 - methyl - benzoic acid methyl ester (methyl oxalate Mi Ester), 2 - (4,5 - dihydro-4 - methyl - 4 - isopropyl-5 - oxo-1H-imidazol-2 - yl) -5 - methyl- - Pyridine-3 - carboxylic acid (Imazamethapyr), 2 - (4,5 - dihydro-4 - methyl - 4 - isopropyl-5 - -Oxo-1H-imidazol-2 - yl) -5 - methoxymethyl - pyridine-3 - carboxylic acid (imazamox), 2 - (4,5 - dihydro-4 - methyl - 4 - isopropyl-5 - oxo-1H-imidazol-2 - yl) - quinoline-3 - carboxylic acid (Imidazol-quinolinic acid), 2 - (4,5 - dihydro-4 - methyl - 4 - isopropyl-5 - oxo-1H-imidazol-2 - Yl) -5 - ethyl - pyridine - 3 - carboxylic acid (imazethapyr), N-(4,6 - dimethoxy - pyrimidin-2 - Yl)-N'-(2 - chloro - imidazo [1,2-a] - pyridin-3 - yl - sulfonyl) - urea (ethyl zolpidem yellow Long), N-(4 - methoxy-6 - methyl-1 ,3,5 - triazin-2 - yl)-N'-(5 - iodo-2 - methoxycarbonyl Yl - phenylsulfonyl) - urea sodium salt (Iodosulfuron-methyl-sodium), 4 - hydroxy - 3,5 - diiodo - benzonitrile (ioxynil), N, N-dimethyl-N'-(4 - isopropyl - phenyl) - urea (isopropyl Long), N-(3 - (1 - ethyl-1 - methyl - propyl) - isoxazol-5 - yl) -2,6 - dimethoxy - phenyl Formamide (Clomazone amine), (4 - chloro-2 - methyl sulfonyl - phenyl) - (5 - cyclopropyl - isoxazole - 4 - yl) - methanone (Isoxachlortole), (5 - cyclopropyl - isoxazol-4 - yl) - (2 - methyl-sulfonamide Acyl -4 - (trifluoromethyl) - phenyl) - methanone (iso evil fluoride grass) 2 - [2 - [4 - [(3,5 - dichloro-2 - Pyridinyl) - oxy] - phenoxy]-1 - oxo - propyl] - isoxazolidine (Clomazone ether), (2 - ethoxyethyl -1 - methyl - 2 - oxo - ethyl) 5 - (2 - chloro -4 - (trifluoromethyl) - phenoxy) -2 - nitro - phenyl Methyl ester (Lactofen), N'-(3,4 - dichloro - phenyl)-N-methoxy-N-methyl - urea (Lee Gu Long), (4 - chloro-2 - methyl - phenoxy) acetic acid (MCPA) 2 - (4 - chloro-2 - methyl - phenoxy Yl) - propionic acid (2 mecoprop), 2 - (2 - benzothiazolyl yloxy)-N-methyl-N-phenyl - ethyl Amide (alachlor tiaprofenic acid), 2 - (4 - methylsulfonyl-2 - nitro - benzoyl) -1,3 - cyclohexyl Dione (Mesotrione), 4 - amino-3 - methyl-6 - phenyl-1 ,2,4 - triazin -5 (4H) - one (Metamitron), 2 - chloro-N-(2,6 - dimethyl - phenyl)-N-(1 H-pyrazol-1 - yl - methyl Yl) - acetamide (pyrazol-metolachlor), N'-(4 - (3,4 - dihydro-2 - methoxy-2 ,4,4 - trimethyl - 2H-1-benzopyran-7 - yl - oxy) - phenyl)-N-methoxy-N-methyl - urea (pyran Long), N'-(4 - bromophenyl)-N-methoxy-N-methyl urea (Takayuki bromide), (S) -2 - chloro-N-(2 - Ethyl-6 - methyl - phenyl)-N-(2 - methoxy-1 - methyl - ethyl) - acetamide (metolachlor Amine, S-metolachlor), N-(2,6 - dichloro-3 - methyl - phenyl) -5,7 - dimethoxy - 1,2,4 - triazolo [1,5-a] - pyrimidine-2 - sulfonamide (sulfonamide grass acetazolamide), N'-(3 - chloro-4 - methoxy- Yl - phenyl)-N, N-dimethyl - urea (methoxy Long), 4 - amino-6 - tert-butyl-3 - (methylthio) - 1,2,4 - triazine -5 (4H) - one (metribuzin), N-(4 - methoxy-6 - methyl-1, 3,5 - triazine - 2 - group)-N'-(2 - methoxycarbonyl - phenylsulfonyl) - urea (metsulfuron-methyl), S-ethyl - hexahydro - 1H-azepine 1 - carbothioate (Molinate), 2 - (2 - naphthyloxy)-N-phenyl - propanamide (naphthalene Propylamine), N-butyl-N'-(3,4 - dichloro - phenyl)-N-methyl - urea (grass is not long), N-(4,6 - two Methoxy - pyrimidin-2 - yl)-N'-(3 - dimethyl-carbamoyl - pyridin-2 - yl - sulfonyl) - Urea (nicosulfuron), S-(2 - chloro - benzyl)-N, N-diethyl - dithiocarbamate (Ping grass Dan), 4 - dipropyl-3 ,5 - dinitro - benzenesulfonamide (sulfamoyl pendimethalin), 3 - [2,4 - dichloro - 5 - (2 - propynyloxy) - phenyl] -5 - (tert-butyl) -1,3,4 - oxadiazol -2 (3H) - one (evil propargyl Yl grass), 3 - [2,4 - dichloro-5 - (1 - methyl - ethoxy) - phenyl] -5 - (tert-butyl) -1,3,4 - Oxadiazol -2 (3H) - one (oxadiazon), N-(4,6 - dimethyl - pyrimidin-2 - yl)-N'-(2 - oxa- Cyclobutan-3 - yl - butoxycarbonyl - phenylsulfonyl) - urea (Cinosulfuron cyclopropoxyimino), 3 - [1 - (3,5 - Dichlorophenyl) -1 - isopropyl-yl] -2,3 - dihydro-6 - methyl-5 - phenyl-4H-1, 3 - oxazin-4 - one (Chloro-oxazine grass), 2 - chloro-1 - (3 - ethoxy-4 - nitro - phenoxy) -4 - (trifluoromethyl) phenyl (ethyl Ether oxygen fluroxypyr), 1,1 '- dimethyl-4, 4'- bipyridinium salts (paraquat), 1 - amino-N-(1 - Ethyl - propyl) -3,4 - dimethyl-2 ,6 - dinitro - benzene (pendimethalin), 4 - (tert-butyl)-N- (1 - ethyl - propyl) -2,6 - dinitro - aniline (Pendralin), 4 - amino-3 ,5,6 - trichloro - Pyridine-2 - carboxylic acid (amino acid chloropyridine), 2 - chloro-N-(2,6 - diethyl - phenyl)-N-(2 - propoxy Yl - ethyl) - acetamide (metolachlor), N-(4,6 - bis difluoromethoxy - pyrimidin-2 - yl)-N'- (2 - methoxycarbonyl - phenylsulfonyl) - urea (Primisulfuron), 1 - chloro-N-[2 - chloro-4 - fluoro-5 - [(6S, 7aR) -6 - fluoro - tetrahydro-1 ,3 - dioxo-1H-pyrrolo [1,2-c] imidazol -2 (3H) - Yl] - phenyl] - sulfonamide (Profluazol), 2 - chloro-N-isopropyl-N-phenyl - acetyl Amine (propachlor), N-(3,4 - dichloro - phenyl) - propionamide (propanil), (R) - [2 - [[(1 - methyl - Ethylidene) - amino] - oxy] - ethyl] -2 - [4 - (6 - chloro-2 - quinoxalinyloxy) - phenoxy]] - Propionate (Oh grass ester), 2 - chloro-N-(2 - ethyl-6 - methyl - phenyl)-N-[(1 - methyl - ethoxyethyl Yl) - methyl] - acetamide (iso-metolachlor), 2 - [[[(4,5 - dihydro-4 - methyl-5 - oxo - Propoxy-1H-1, 2,4 - triazol-1 - yl) - carbonyl] - amino] - sulfonyl] - Sodium benzoate Salt (Propoxycarbazone-sodium salt), S-phenylmethyl N, N-dipropyl - dithiocarbamate Esters (prosulfocarb), N-(4 - methoxy-6 - methyl-1 ,3,5 - triazin-2 - yl)-N'-(2 - (3,3,3 - trifluoro - propyl) - phenylsulfonyl) - urea (fluoro yellow Long), [2 - chloro-5 - (4 - chloro-5 - two Fluoro-methoxy-1 - methyl-1H-pyrazol-3 - yl) -4 - fluoro - phenoxy] - acetate (fluoro azole grass Ester), 1 - (3 - chloro-4 ,5,6,7 - tetrahydro - pyrazolo [1,5-a] pyridin-2 - yl) -5 - (methyl-2 - Amino-propynyl)-1H-pyrazol-4 - carbonitrile (Pyrazogyl), 4 - (2,4 - dichloro - benzoyl) - 1,3 - dimethyl-5 - (4 - methyl - phenyl sulfonyl group) - pyrazole (pyrazolate), 4 - (2,4 - Chloro - benzoyl) -1,3 - dimethyl-5 - (phenylcarbonyl - methoxy) - pyrazole (benzyl grass yl), N- (4,6 - dimethoxy - pyrimidin-2 - yl)-N'-(4 - ethoxy - carbonyl-1 - methyl - pyrazol-5 - yl - Sulfonyl) - urea (pyridin-ethyl), diphenyl ketone O-[2,6 - bis - (4,6 - dimethoxy - ethyl -2 - yl - oxy) - benzoyl] oxime (pyrimidin benzene grass oxime), 6 - chloro-3 - phenyl-4 - pyridazin-ol (Pyridafol), O-(6 - chloro-3 - phenyl - pyridazin-4 - yl) S-octyl thiocarbonate (pyridate Tex), 6 - chloro-3 - phenyl-pyridazin-4 - ol (Pyridatol), 7 - [(4,6 - dimethoxy-2 - pyrimidinyl Yl) - thio] -3 - methyl -1 (3H) - isobenzofuranone (Pyriftalid), 2 - (4,6 - dimethoxyphenyl Oxy - pyrimidin-2 - yl - oxy) - benzoic acid methyl ester (piperidine oxime grass), 2 - chloro-6 - (4,6 - dimethoxyphenyl Yl - pyrimidin-2 - ylthio) - benzoic acid sodium salt (ethyl sulfide grass), 3,7 - dichloro - quinolin-8 - carboxylic acid (Quinchlorac), 7 - chloro-3 - methyl - quinolin-8 - carboxylic acid (chloromethyl quinoline acid), 2 - [4 - (6 - Chloro-2 - quinoxalinyl yloxy) - phenoxy] - propionic acid (ethyl ester, tetrahydro-2 - furanyl - methyl) (quinoline Wo Ling, quizalofop - ethyl Quizalofop ethyl Quizalofop furfuryl acetate), N-(4,6 - dimethoxy - Pyrimidin-2 - yl)-N'-(3 - ethylsulfonyl - pyridin-2 - yl - sulfonyl) - urea (ethyl sulfone Long), 2 - (1 - ethoxy-imino-butyl) -5 - (2 - ethylthio-propyl) -3 - hydroxy-2 - cyclohexene - 1 - one (Sethoxydim piperidine), 6 - chloro-2 ,4 - bis - ethyl-1 ,3,5 - triazine (simazine), 2 - (2 - chloro - 4 - methylsulfonyl - benzoyl) - cyclohexane-1,3 - dione (sulcotrione), 2 - (2,4 - dichloro - 5 - methyl - sulfonyl-amino - phenyl) -4 - (difluoromethyl) -5 - methyl -2,4 - dihydro-3H- 1,2,4 - triazol-3 - one (methanesulfonamide alachlor), N-phosphono-methyl - Gly - trimethylsulfonium (grass sulfur Phosphine), N-(4,6 - dimethoxy - pyrimidin-2 - yl)-N'-(2 - ethyl-sulfonyl - imidazo [1,2 - a] pyridin-3 - yl) sulfonamide (b Huanghuang Long), 6 - chloro-4 - B-2 - tert-butylamino - 1,3,5 - triazine (terbuthylazine), 2 - tert-butyl-4 - ethyl-6 - methylthio-1 ,3,5 - Three Triazine (terbutryn), 2 - chloro-N-(2,6 - dimethyl - phenyl)-N-(3 - methoxy-2 - thienyl - A Yl) - acetamide (alachlor thienyl), 2 - (difluoromethyl) -5 - (4,5 - dihydro - thiazol-2 - yl) -4 - (2 - methyl - propyl) -6 - (trifluoromethyl) - pyridine-3 - carboxylate (thiazol-nicotinic acid), 6 - (6,7 - Dihydro-6 ,6 - dimethyl-3H, 5 H-pyrrolo [2,1-c] -1,2,4 - thiadiazol - ylideneamino Yl) -7 - fluoro-4 - (2 - propynyl)-2H-1, 4 - benzoxazin -3 (4H) - one (Thidiazimin), N-(4 - methoxy-6 - methyl-1, 3,5 - triazin-2 - yl)-N'-(2 - methyl Oxy - carbonyl - thiophene-3 - yl - sulfonyl) - urea (thifensulfuron) 2 - (ethoxyimino - C Yl) -3 - hydroxy-5 - (2,4,6 - trimethyl - phenyl) -2 - cyclohexen-1 - one (grass trimethylbenzene Ketone), S-(2,3,3 - trichloro-2-propenyl) - diisopropyl thiocarbamate (wild wheat Fear), N-(4 - methoxy-6 - methyl-1, 3,5 - triazin-2 - yl)-N'-[2 - (2 - chloro - ethoxyethyl Yl) - phenylsulfonyl] - urea (triasulfuron), N-methyl-N-(4 - methoxy-6 - methyl - 1,3,5 - triazin-2 - yl)-N'-(2 - methoxycarbonyl - phenylsulfonyl) - urea (benzenesulfonic Long), (3,5,6 - trichloro) - pyridin-2 - yl - oxy - acetic acid (Triclopyr) 2 - (3,5 - Dichloro - phenyl) -2 - (2,2,2 - trichloro - ethyl) - ethylene oxide (herbicides ring), N-[[(4,6 - two Methoxy-2 - pyrimidinyl) - amino] - carbonyl] -3 - (2,2,2 - trifluoro-ethoxy) -2 - pyridinesulfonamide Sodium salt (Trifloxysulfuron), 1 - amino-2 ,6 - dinitro-N, N-dipropyl-4 - (Trifluoromethyl) - benzene (trifluralin), N-[4 - dimethylamino-6 - (2,2,2 - trifluoro - ethoxy) - 1,3,5 - triazin-2 - yl]-N'-(2 - methoxycarbonyl - phenylsulfonyl) - urea (methyl amine fluoride Long), N-[[(4,6 - dimethoxy-2 - pyrimidinyl) amino] carbonyl] -3 - (N-methyl-N-methyl- Sulfonylamino) -2 - pyridinesulfonamide (see WO-A-92/10660), 2 - [[[[(4,6 - dimethoxyphenyl -2 - pyrimidinyl) amino] carbonyl] amino] - sulfonyl] -4 - [[(methylsulfonyl) amino] methyl Yl] - benzoic acid methyl ester (see DE-A-4335297), 4 - [4,5 - dihydro-4 - methyl-5 - oxo- - (3 - trifluoromethyl)-1H-1, 2,4 - triazol-1 - yl] -2 - [(ethylsulfonyl) amino] -5 - fluoro- - Phenylthio-carboxamide (see WO-A-95/30661) ...
(" the 2nd group of reactive compound ")
And/or it is optional
(d) be selected from down the compound of organizing the promoted crop compatibility in the compound:
4-dichloro-acetyl-1-oxa--4-azepine-spiral shell [4.5]-decane (AD-67); 1-dichloro-acetyl-six hydrogen-3; 3; 8a-trimethyl pyrrolo-[1; 2-a]-pyrimidine-6 (2H)-ketone (BAS-145138); 4-dichloro-acetyl-3; 4-dihydro-3-methyl-2H-1; 4-benzoxazine (benoxacor); 5-chloro-quinoxaline-8-oxygen base-acetate 1-methyl-hexyl ester (cloquintocet-isocyanate); α-(cyano group-methoxyimino)-benzene acetonitrile (cyometrinil); 2; 4-dichlorophenoxyacetic acid (2; 4-D); 2; 2-two chloro-N-(2-oxo-2-(2-acrylic amino)-ethyl)-N-(2-acrylic)-acetamide (DKA_24); 2; 2-two chloro-N; N-two-2-acrylic-acetamide (dichlormide); N-(4-methyl-phenyl)-N '-(1-methyl isophthalic acid-phenyl-ethyl)-urea (daimuron); 4; 6-two chloro-2-phenyl-pyrimidines (fenclorim); 1-(2; 4-two chloro-phenyl)-5-trichloromethyl-1H-1; 2; 4-triazole-3-Ethyl formate (fenchlorazole ethyl ester); 2-chloro-4-trifluoromethyl-thiazole-5-carboxylic acid benzene methyl (flurazole); 4-chloro-N-(1; 3-dioxolanes-2-base-methoxyl group)-α-three fluoro-acetophenone oxime (fluxofenim); 3-dichloro-acetyl-5-(2-furyl)-2; 2-dimethyl-oxazolidine (Xie Cao oxazoles; MON-13900); 4; 5-dihydro-5; 5-diphenyl-3-isoxazole carboxylic acid ethyl ester (Isoxadifen-ethyl); (4-chloro-2-methyl-phenoxy group)-acetate (MCPA); (+-)-2-(4-chloro-2-methylphenoxy) propionic acid (Vi par); 1-(2,4 dichloro benzene base)-4,5-dihydro-5-methyl isophthalic acid H-pyrroles-3; 5-dicarboxylate (pyrroles's two diethyl phthalates); 2-dichloromethyl-2-methyl isophthalic acid, 3-dioxolanes (MG191), 1; the 8-naphthalic anhydride; α-(1,3-dioxolanes-2-base-methoxyimino)-benzene acetonitrile (oxabetrinil), 2; 2-two chloro-N-(1; 3-dioxolanes-2-base-methyl)-and N-(2-acrylic)-acetamide (PPG-1292) and 3-dichloro-acetyl-2,2,5-trimethyl-oxazolidines (R-29148)
(" the 3rd group of reactive compound ").
2. the Herbicidal combinations of claim 1 is characterized in that, they comprise at least a compound of promoting the crop compatibility as the 3rd group of reactive compound, and this compound that can promote the crop compatibility is selected from following one group of compound:
5-chloro-quinoxaline-8-oxygen base-acetate 1-methyl-hexyl ester (cloquintocet-isocyanate), 1-(2,4-two chloro-phenyl)-5-trichloromethyl-1H-1,2,4-triazole-3-Ethyl formate (fenchlorazole ethyl ester), 4,5-dihydro-5,5-diphenyl-3-isoxazole carboxylic acid ethyl ester (Isoxadifen-ethyl), 1-(2,4 dichloro benzene base)-4,5-dihydro-5-methyl isophthalic acid H-pyrazoles-3,5-dicarboxylate (pyrroles's two diethyl phthalates) and 2,4 dichlorophenoxyacetic acid (2,4-D) and derivative.
3. claim 1 or 2 composition are prevented and kill off the application that does not need plant.
4. prevent and kill off the method that does not need plant, it is characterized in that the composition of claim 1 or 2 is applied to unwanted plant and/or their vitellarium.
5. the preparation method of Herbicidal combinations is characterized in that the composition of claim 1 or 2 is mixed with surfactant and/or filler.
CN00815932.7A 1999-11-18 2000-11-08 Synergistic herbicidal active substance combinations Pending CN1391439A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE19955407.2 1999-11-18
DE19955407 1999-11-18
DE19960918.7 1999-12-17
DE19960918A DE19960918A1 (en) 1999-11-18 1999-12-17 Synergistic herbicidal combinations of active ingredients

Publications (1)

Publication Number Publication Date
CN1391439A true CN1391439A (en) 2003-01-15

Family

ID=26055567

Family Applications (1)

Application Number Title Priority Date Filing Date
CN00815932.7A Pending CN1391439A (en) 1999-11-18 2000-11-08 Synergistic herbicidal active substance combinations

Country Status (12)

Country Link
EP (1) EP1233672A2 (en)
CN (1) CN1391439A (en)
AR (1) AR026521A1 (en)
AU (1) AU1029401A (en)
BR (1) BR0015701A (en)
CA (1) CA2390570A1 (en)
CZ (1) CZ20021728A3 (en)
HU (1) HUP0203400A3 (en)
MX (1) MXPA02004904A (en)
PL (1) PL355974A1 (en)
RU (1) RU2002116229A (en)
WO (1) WO2001035741A2 (en)

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102265869A (en) * 2010-06-07 2011-12-07 南京华洲药业有限公司 Herbicidal composition containing bentazone, dicamba and sulcotrione and application thereof
CN102265855A (en) * 2010-06-04 2011-12-07 南京华洲药业有限公司 Mixed herbicide containing bentazone and fenoxaprop-p-ethyl, and application thereof
CN102265871A (en) * 2010-06-07 2011-12-07 南京华洲药业有限公司 Weeding composition containing bentazone and 2,4-dichlorophenoxyacetic acid and application thereof
CN102283220A (en) * 2011-07-04 2011-12-21 永农生物科学有限公司 Composition of fluroxypyr or ester thereof and flumetsulam and preparation method of composition
CN102326563A (en) * 2011-07-12 2012-01-25 陕西美邦农药有限公司 Weeding composition containing diflufenican and flumetsulam
CN102405916A (en) * 2011-11-20 2012-04-11 广东中迅农科股份有限公司 Herbicidal composition containing fenoxaprop-P-ethyl and bentazone
CN103300014A (en) * 2013-06-20 2013-09-18 安徽丰乐农化有限责任公司 Weeding water suspension agent
CN103598195A (en) * 2013-11-19 2014-02-26 江苏钟山化工有限公司 Mixed herbicide containing clodinafop-propargyl and procarbazone sodium
CN103609581A (en) * 2013-11-13 2014-03-05 山东滨农科技有限公司 Herbicide composition containing pyrazosulfuron-ethyl, pyribenzoxim and S-metolachlor
CN103704236A (en) * 2013-12-30 2014-04-09 孙蒙蒙 Herbicide for rice field
CN104365612A (en) * 2014-11-06 2015-02-25 江苏省农用激素工程技术研究中心有限公司 Weeding composition for preventing and controlling weeds in peanut field
CN104642365A (en) * 2013-11-15 2015-05-27 南京华洲药业有限公司 Mixing herbicide containing aminopyralid and trifloxysulfuron sodium
CN105230638A (en) * 2015-05-29 2016-01-13 山东中新科农生物科技有限公司 Herbicidal composition comprising diquat and clethodim
WO2017107580A1 (en) * 2015-12-23 2017-06-29 Rotam Agrochem International Company Limited Herbicidal composition and use thereof
CN107279144A (en) * 2017-06-23 2017-10-24 北京科发伟业农药技术中心 A kind of Herbicidal combinations containing fluorochloridone
CN107410321A (en) * 2017-06-23 2017-12-01 北京科发伟业农药技术中心 A kind of Herbicidal combinations containing fluorochloridone and pyrithiobac-sodium
CN110200023A (en) * 2019-06-05 2019-09-06 广西天浩农业发展有限公司 A kind of sugar-cane herbicide
CN113057163A (en) * 2020-01-02 2021-07-02 山东省农业科学院植物保护研究所 Herbicide composition containing sethoxydim and sulfentrazone and applied to soybean and peanut fields

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002017719A2 (en) * 2000-08-31 2002-03-07 Basf Aktiengesellschaft Herbicide mixtures
AR036047A1 (en) * 2001-06-13 2004-08-04 Syngenta Participations Ag SELECTIVE HERBICIDE COMPOSITION AND METHOD TO SELECTLY CONTROL WEEDS AND PASTES IN USEFUL PLANTS CROPS
DE10129856A1 (en) * 2001-06-21 2003-01-02 Bayer Ag Selective herbicides based on pyrimidine derivatives
DE10135641A1 (en) * 2001-07-21 2003-02-06 Bayer Cropscience Gmbh Herbicide combinations with special sulfonylureas
AR036546A1 (en) * 2001-09-20 2004-09-15 Syngenta Participations Ag HERBICIDE COMPOSITION
DE10209430A1 (en) 2002-03-05 2003-09-18 Bayer Cropscience Gmbh Herbicide combination with acylated aminophenylsulfonylureas
DE10209478A1 (en) * 2002-03-05 2003-09-18 Bayer Cropscience Gmbh Herbicide combinations with special sulfonylureas
AU2003253395B2 (en) * 2002-08-08 2008-05-22 Syngenta Participations Ag Herbicidal composition
EA012521B1 (en) 2003-11-03 2009-10-30 Байер Кропсайенс Аг Liquid preparation, use thereof, process for preparing thereof and method for controlling harmful plants
CA2543972C (en) * 2005-04-26 2013-09-24 Sumitomo Chemical Company, Limited A combination comprising flumioxazin and imazosulfuron to control weeds
ES2407657T3 (en) * 2006-03-28 2013-06-13 Riceco, Llc Synergistic effects of ALS inhibitor herbicides when combined with propanil
JP2013511294A (en) * 2009-11-23 2013-04-04 バイエル・クロップサイエンス・エヌ・ヴェー Herbicide-tolerant plants and methods for identifying them
CN102265844B (en) * 2010-06-04 2013-09-18 南京华洲药业有限公司 Herbicidal composition containing bentazone, acifluorfen-sodium and clethodim, and its application
CN102265846B (en) * 2010-06-04 2013-09-18 南京华洲药业有限公司 Weeding composition containing bentazone, acifluorfen-sodium and fluazifop-p-butyl, and application thereof
CN102265843B (en) * 2010-06-04 2013-09-18 南京华洲药业有限公司 Herbicidal composition containing bentazone, acifluorfen-sodium and sethoxydim and application thereof
CN102265845B (en) * 2010-06-04 2013-09-18 南京华洲药业有限公司 Weeding composition containing bentazone, acifluorfen-sodium and quizalofo-P-ethyl, and application thereof
CN102265847B (en) * 2010-06-04 2013-09-18 南京华洲药业有限公司 Herbicidal composition containing bentazone, acifluorfen-sodium and fenoxaprop-p-ethyl, and its application
CN102265848B (en) * 2010-06-04 2013-09-18 南京华洲药业有限公司 Weeding composition containing bentazone, acifluorfen-sodium and haloxyfop-r-methyl, and application thereof
JP5364936B2 (en) * 2010-11-09 2013-12-11 ダウ グローバル テクノロジーズ エルエルシー Synergistic combination of flumeturum or diclosram with diiodomethyl-p-tolylsulfone
CN102326573B (en) * 2011-06-23 2014-04-02 陕西韦尔奇作物保护有限公司 Weeding composition containing rimsulfuron
CN106472552A (en) * 2015-08-25 2017-03-08 陕西省蒲城美尔果农化有限责任公司 A kind of insecticides for preventing and treating vegetable thrips and its production method
CN106719764A (en) * 2016-11-09 2017-05-31 徐州得铸生物科技有限公司 Herbicidal combinations containing amicarbazone
CN106818782A (en) * 2016-12-14 2017-06-13 安徽扬子化工有限公司 A kind of seedbed herbicide
CN106689155A (en) * 2016-12-22 2017-05-24 云南省林业科学院 Mikania micrantha eliminating pesticide and method for eliminating mikania micrantha by using mikania micrantha eliminating pesticide

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19534910A1 (en) * 1995-09-20 1997-03-27 Basf Ag Herbicidal mixtures with a synergistic effect

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102265855A (en) * 2010-06-04 2011-12-07 南京华洲药业有限公司 Mixed herbicide containing bentazone and fenoxaprop-p-ethyl, and application thereof
CN102265869A (en) * 2010-06-07 2011-12-07 南京华洲药业有限公司 Herbicidal composition containing bentazone, dicamba and sulcotrione and application thereof
CN102265871A (en) * 2010-06-07 2011-12-07 南京华洲药业有限公司 Weeding composition containing bentazone and 2,4-dichlorophenoxyacetic acid and application thereof
CN102265869B (en) * 2010-06-07 2013-03-20 南京华洲药业有限公司 Herbicidal composition containing bentazone, dicamba and sulcotrione and application thereof
CN102283220A (en) * 2011-07-04 2011-12-21 永农生物科学有限公司 Composition of fluroxypyr or ester thereof and flumetsulam and preparation method of composition
CN102326563A (en) * 2011-07-12 2012-01-25 陕西美邦农药有限公司 Weeding composition containing diflufenican and flumetsulam
CN102326563B (en) * 2011-07-12 2013-10-09 陕西美邦农药有限公司 Weeding composition containing diflufenican and flumetsulam
CN102405916A (en) * 2011-11-20 2012-04-11 广东中迅农科股份有限公司 Herbicidal composition containing fenoxaprop-P-ethyl and bentazone
CN103300014A (en) * 2013-06-20 2013-09-18 安徽丰乐农化有限责任公司 Weeding water suspension agent
CN103300014B (en) * 2013-06-20 2015-03-25 安徽丰乐农化有限责任公司 Weeding water suspension agent
CN103609581A (en) * 2013-11-13 2014-03-05 山东滨农科技有限公司 Herbicide composition containing pyrazosulfuron-ethyl, pyribenzoxim and S-metolachlor
CN104642365A (en) * 2013-11-15 2015-05-27 南京华洲药业有限公司 Mixing herbicide containing aminopyralid and trifloxysulfuron sodium
CN103598195A (en) * 2013-11-19 2014-02-26 江苏钟山化工有限公司 Mixed herbicide containing clodinafop-propargyl and procarbazone sodium
CN103598195B (en) * 2013-11-19 2015-05-13 江苏钟山化工有限公司 Mixed herbicide containing clodinafop-propargyl and procarbazone sodium
CN103704236A (en) * 2013-12-30 2014-04-09 孙蒙蒙 Herbicide for rice field
CN104365612A (en) * 2014-11-06 2015-02-25 江苏省农用激素工程技术研究中心有限公司 Weeding composition for preventing and controlling weeds in peanut field
CN104365612B (en) * 2014-11-06 2016-03-30 江苏省农用激素工程技术研究中心有限公司 For preventing and treating the Herbicidal combinations of Weed in peanut field
CN105230638A (en) * 2015-05-29 2016-01-13 山东中新科农生物科技有限公司 Herbicidal composition comprising diquat and clethodim
WO2017107580A1 (en) * 2015-12-23 2017-06-29 Rotam Agrochem International Company Limited Herbicidal composition and use thereof
CN107279144A (en) * 2017-06-23 2017-10-24 北京科发伟业农药技术中心 A kind of Herbicidal combinations containing fluorochloridone
CN107410321A (en) * 2017-06-23 2017-12-01 北京科发伟业农药技术中心 A kind of Herbicidal combinations containing fluorochloridone and pyrithiobac-sodium
CN110200023A (en) * 2019-06-05 2019-09-06 广西天浩农业发展有限公司 A kind of sugar-cane herbicide
CN113057163A (en) * 2020-01-02 2021-07-02 山东省农业科学院植物保护研究所 Herbicide composition containing sethoxydim and sulfentrazone and applied to soybean and peanut fields

Also Published As

Publication number Publication date
AU1029401A (en) 2001-05-30
CZ20021728A3 (en) 2002-10-16
WO2001035741A3 (en) 2001-12-27
RU2002116229A (en) 2004-01-20
BR0015701A (en) 2002-07-23
WO2001035741A2 (en) 2001-05-25
AR026521A1 (en) 2003-02-12
PL355974A1 (en) 2004-05-31
HUP0203400A2 (en) 2003-03-28
MXPA02004904A (en) 2003-01-28
CA2390570A1 (en) 2001-05-25
EP1233672A2 (en) 2002-08-28
HUP0203400A3 (en) 2005-03-29

Similar Documents

Publication Publication Date Title
CN1391439A (en) Synergistic herbicidal active substance combinations
CN1278607C (en) Selective herbicides based upon 2,6-disubstituted pyridine derivatives
CN1273020C (en) Carbamoyl triazolinone-based herbicides
CN1589101B (en) Herbicides containing substituted thien-3-yl-sulfonylamino(thio)carbonyl-triazolin(thi)one compound
ES2711895T3 (en) A herbicidal composition comprising a uracil compound as active ingredient
CN1407854A (en) N-aryi-uracile-based herbicides
CN1378424A (en) Selective herbicides on basis of n-aryl-trizoline (thio) ones
DE19947918A1 (en) Selective herbicides based on pyrimidine derivatives
CN1277472C (en) Selective herbicide comprising a tetrazolinone derivative
WO2003000058A1 (en) Selective herbicides based on pyrimidine derivatives
JP4348186B2 (en) Synergistic herbicides containing herbicides from the group of benzoylpyrazoles
KR20060015292A (en) New safeners and their application
EP3876736B1 (en) Stable formulation comprising herbicides
CN1768582A (en) Selective herbicides based on 2,6-disubstituted pyridine derivatives
DE19960918A1 (en) Synergistic herbicidal combinations of active ingredients
KR20020035601A (en) Selective herbicides on the basis of N-aryl-triazoline(thi)ones
MXPA06010985A (en) Use of sulfonylureas

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication