CN1389547A - Oil-based coal slurry fuel and preparation process thereof - Google Patents
Oil-based coal slurry fuel and preparation process thereof Download PDFInfo
- Publication number
- CN1389547A CN1389547A CN 01113675 CN01113675A CN1389547A CN 1389547 A CN1389547 A CN 1389547A CN 01113675 CN01113675 CN 01113675 CN 01113675 A CN01113675 A CN 01113675A CN 1389547 A CN1389547 A CN 1389547A
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- oil
- coal
- fuel
- agent
- water
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- 239000000446 fuel Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims description 10
- 239000003250 coal slurry Substances 0.000 title abstract description 3
- 239000003245 coal Substances 0.000 claims abstract description 39
- 239000003921 oil Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 18
- 239000002002 slurry Substances 0.000 claims abstract description 14
- 239000000295 fuel oil Substances 0.000 claims abstract description 10
- 238000009775 high-speed stirring Methods 0.000 claims abstract description 10
- 230000001804 emulsifying effect Effects 0.000 claims abstract description 4
- 238000001914 filtration Methods 0.000 claims abstract description 4
- 238000001238 wet grinding Methods 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 239000006185 dispersion Substances 0.000 claims description 17
- 239000012530 fluid Substances 0.000 claims description 16
- 238000005516 engineering process Methods 0.000 claims description 12
- 239000004094 surface-active agent Substances 0.000 claims description 9
- 238000004945 emulsification Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 238000004537 pulping Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 3
- 239000005642 Oleic acid Substances 0.000 claims description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical class CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 3
- 239000010779 crude oil Substances 0.000 claims description 3
- 239000002283 diesel fuel Substances 0.000 claims description 3
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 claims description 3
- 238000013467 fragmentation Methods 0.000 claims description 3
- 238000006062 fragmentation reaction Methods 0.000 claims description 3
- 239000003502 gasoline Substances 0.000 claims description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 3
- 229960002969 oleic acid Drugs 0.000 claims description 3
- 235000021313 oleic acid Nutrition 0.000 claims description 3
- -1 polyoxyethylene Polymers 0.000 claims description 3
- 150000003871 sulfonates Chemical group 0.000 claims description 3
- 239000002569 water oil cream Substances 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 239000002817 coal dust Substances 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000010742 number 1 fuel oil Substances 0.000 description 2
- 239000002802 bituminous coal Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
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- Liquid Carbonaceous Fuels (AREA)
Abstract
An oil-base coal slurry fuel is prepared from oil (10-40 wt.%), water (10-30), coal (40-60) and emulsifier and disperser (0.5-3) through breaking raw coal, wet grinding, superfine processing, filtering, adding it to oil-water emulsifying system, and high-speed stirring. The slurry fuel has good fluidity and stability, can save a large amount of fuel oil, has low ash content and high heat value of 5000-8000 kcal/kg, and can be widely used for replacing combustion oil for low-load operation of industrial boilers, industrial kilns and power plants.
Description
The present invention relates to oil-base coal fluid fuel and preparation technology, i.e. oil base ternary fuel slurry and the preparation technology who forms with oil, water, coal.
Two big hot issue-energy and environmental protection of current society, with regard to China, quite be difficult to change in period based on the energy general layout of coal, the future source of energy environmental problem is outstanding, developing clean coal technology is the selection of reality, and the coal slurry technology is an important content in the clean coal technology.In in the past more than 20 year, what coal oil mixture and coal water slurry fuel were used for oil-firing boiler has caused people's common concern for oil fuel, because they are a kind of coal-based generation flow of oil fuel, can be used on Industrial Boiler, station boiler, industrial furnace cellar for storing things previous generation's oil or for gas firing, and also play a part certain reducing environmental pollution.But because the coal oil mixture fuel-economizing is few, and viscosity height, price are expensive, thereby replaced very soon by coal water slurry, coal water slurry has very big superiority in fuel-economizing aspect transporting safely, solved large-scale production process at home and abroad, but coal water slurry is being had relatively high expectations aspect the selection of slurrying coal, its burning-point is higher, calorific value is lower, be only applicable to the high bituminous coal of high volatile, coal water slurry is also higher to the requirement of pipeline and nozzle in addition, the improvement expenses costliness.
The purpose of this invention is to provide that a kind of burning-point is lower, calorific value is higher, fuel-economizing, improvement expenses is lower, is used to replace the oil-base coal fluid fuel and the preparation technology of Industrial Boiler, Industrial Stoves and power station underrun.
Oil-base coal fluid fuel of the present invention, but with fuel oil, water, coal add emulsifying agent in proportion, dispersion agent is uniformly mixed into slurry, its content is respectively: oil accounts for 10～40%, and water accounts for 10～30%, coal accounts for 40%～60%, and emulsifying agent and dispersion agent respectively account for 0.5～3% (weight percent).Used emulsifying agent adopts Span-85, Span80 series nonionic surface active agent, and dispersion agent is Sulfonates, alkylphenol polyoxyethylene class and oleic-acid, and dispersion agent is the mixture of nonionic surface active agent and aniorfic surfactant; But fuel oil can be gasoline, diesel oil, heavy oil, residual oil or crude oil.
The preparation technology of oil-base coal fluid fuel of the present invention: with the raw coal fragmentation, through wet-milling super-fine processing, filtration, join then (that is: oil and dispersion agent stir, and add the system of emulsifying agent and water stirring and emulsifying again) in the oil-water emulsion system, through high-speed stirring emulsification pulping.
Oil-base coal fluid fuel of the present invention and preparation technology, the oil base ternary fuel slurry and the preparation technology that adopt oil, water, coal to form, this fuel slurry flowability and good stability can be saved a large amount of oil fuel, and its point of ignition is lower than coal water slurry; This fuel slurry fine size, ash content is low, thereby the unit volume calorific value is higher: 5000～8000kcal/kg can be widely used in the burning oil when replacing Industrial Boiler, Industrial Stoves and power station underrun, its economic benefit and obvious social benefit have practicality widely.
Below in conjunction with embodiment the present invention is further described:
Oil-base coal fluid fuel of the present invention, but by fuel oil, water, coal add emulsifying agent in proportion, dispersion agent is uniformly mixed into slurry, wherein emulsifying agent adopts Span-85, Span80 series nonionic surface active agent, and dispersion agent is Sulfonates, alkylphenol polyoxyethylene class and oleic-acid.Dispersion agent is the mixture of nonionic surface active agent and aniorfic surfactant, but fuel oil can be gasoline, diesel oil, heavy oil, residual oil or crude oil.
Its preparation technology:,, join then (that is: oil and dispersion agent stir, and add the system of emulsifying agent and water stirring and emulsifying again) in the oil-water emulsion system, through high-speed stirring emulsification pulping through wet-milling super-fine processing, filtration with the raw coal fragmentation.
Embodiment 1: with oil 300 grams (30%), add emulsifying agent 16.1 grams, add water 180 grams (18%), high-speed stirring emulsification adds dispersion agent 3.9 grams (emulsifying agent and dispersant dosage 2%) again, coal dust after the super-fine processing (granularity＜20 μ m) 500g (50%), fully mix, high-speed stirring emulsification pulping is 10 minutes again, promptly makes stable oil-base coal fluid fuel, when shear velocity was 100 seconds, viscosity was 960mPa..S.
Embodiment 2: with oil 200 grams (20%), add emulsifying agent 8 grams, add water 290 grams (29%), high-speed stirring emulsification adds dispersion agent 2 grams (emulsifying agent and dispersant dosage 1%) again, coal dust after the super-fine processing (granularity＜20 μ m) 500g (50%), fully mix, high-speed stirring emulsification pulping is 10 minutes again, promptly makes stable oil-base coal fluid fuel, when shear velocity was 100 seconds, viscosity was 780mPa..S.
Embodiment 3: be heated to 70-80 ℃ with oil 350 grams (35%), add emulsifying agent 17 grams, add water 130 grams (13%), high-speed stirring is even, adds dispersion agent 3 grams (emulsifying agent and dispersant dosage 2%) again, adding is through coal dust (granularity＜20 μ m) 500 grams (50%) of super-fine processing, fully mix, high-speed stirring emulsification pulping is 8 minutes again, promptly makes oil-base coal fluid fuel, when shear velocity was 100 seconds, viscosity was 1000mPa..S.
Claims (6)
1. oil-base coal fluid fuel, it is characterized in that: but with fuel oil, water, coal add emulsifying agent in proportion, dispersion agent is uniformly mixed into slurry, its content is respectively: oil accounts for 10～40%, and water accounts for 10～30%, coal accounts for 40%～60%, and emulsifying agent and dispersion agent respectively account for 0.5～3% (weight percent).
2. oil-base coal fluid fuel according to claim 1 is characterized in that: described emulsifying agent adopts Span-g5, Span80 series nonionic surface active agent.
3. oil-base coal fluid fuel according to claim 1 is characterized in that: described dispersion agent is Sulfonates, alkylphenol polyoxyethylene class and oleic-acid.
4. according to claim 1,2 or 3 described oil-base coal fluid fuels, it is characterized in that: described dispersion agent is the mixture of nonionic surface active agent and aniorfic surfactant.
5. oil-base coal fluid fuel according to claim 1 is characterized in that: but described fuel oil can be gasoline, diesel oil, heavy oil, residual oil or crude oil.
6. the preparation technology of oil-base coal fluid fuel, it is characterized in that:,, join then in the oil-water emulsion system that (that is: oil and dispersion agent stir through wet-milling super-fine processing, filtration the raw coal fragmentation, the system that adds emulsifying agent and water stirring and emulsifying again), through high-speed stirring emulsification pulping.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01113675 CN1389547A (en) | 2001-06-05 | 2001-06-05 | Oil-based coal slurry fuel and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01113675 CN1389547A (en) | 2001-06-05 | 2001-06-05 | Oil-based coal slurry fuel and preparation process thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1389547A true CN1389547A (en) | 2003-01-08 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01113675 Pending CN1389547A (en) | 2001-06-05 | 2001-06-05 | Oil-based coal slurry fuel and preparation process thereof |
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| CN (1) | CN1389547A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101597526A (en) * | 2008-06-02 | 2009-12-09 | 金军 | Method, product and the purposes of the liquid fuel in a kind of coal oil-gas reservoir of gathering |
| CN101270311B (en) * | 2007-03-23 | 2012-09-05 | 北京国成环网机电设备有限公司 | Grinding burning-rate accelerator for coal, preparation method and application thereof |
| CN103627458A (en) * | 2013-12-25 | 2014-03-12 | 济南开发区星火科学技术研究院 | Heavy oil and coal water slurry blended fuel and preparation method thereof |
| CN105018159A (en) * | 2015-06-19 | 2015-11-04 | 四川华益隆环保科技有限公司 | Oil gas engineering oil-containing solid waste resource modification treatment method |
| CN105925327A (en) * | 2016-04-26 | 2016-09-07 | 太原理工大学 | Coal-based three phase hybrid fuel prepared from waste engine oil |
| CN107227183A (en) * | 2017-07-13 | 2017-10-03 | 斯养武 | A kind of high heating value water-coal-slurry |
| US10287522B2 (en) | 2013-01-31 | 2019-05-14 | General Electric Company | System and method for preparing coal water slurry |
-
2001
- 2001-06-05 CN CN 01113675 patent/CN1389547A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101270311B (en) * | 2007-03-23 | 2012-09-05 | 北京国成环网机电设备有限公司 | Grinding burning-rate accelerator for coal, preparation method and application thereof |
| CN101597526A (en) * | 2008-06-02 | 2009-12-09 | 金军 | Method, product and the purposes of the liquid fuel in a kind of coal oil-gas reservoir of gathering |
| CN101597526B (en) * | 2008-06-02 | 2013-03-27 | 金军 | Method for collecting liquid fuel in coal oil-gas reservoir, product and application thereof |
| US10287522B2 (en) | 2013-01-31 | 2019-05-14 | General Electric Company | System and method for preparing coal water slurry |
| CN103627458A (en) * | 2013-12-25 | 2014-03-12 | 济南开发区星火科学技术研究院 | Heavy oil and coal water slurry blended fuel and preparation method thereof |
| CN103627458B (en) * | 2013-12-25 | 2016-06-08 | 济南开发区星火科学技术研究院 | A kind of heavy oil water-coal-slurry fuel combination and preparation method thereof |
| CN105018159A (en) * | 2015-06-19 | 2015-11-04 | 四川华益隆环保科技有限公司 | Oil gas engineering oil-containing solid waste resource modification treatment method |
| CN105925327A (en) * | 2016-04-26 | 2016-09-07 | 太原理工大学 | Coal-based three phase hybrid fuel prepared from waste engine oil |
| CN107227183A (en) * | 2017-07-13 | 2017-10-03 | 斯养武 | A kind of high heating value water-coal-slurry |
| CN107227183B (en) * | 2017-07-13 | 2019-07-09 | 斯养武 | A kind of high heating value water-coal-slurry |
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| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |