CN1366355A - Pressure transfer device for accumulator - Google Patents

Pressure transfer device for accumulator Download PDF

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Publication number
CN1366355A
CN1366355A CN01101943A CN01101943A CN1366355A CN 1366355 A CN1366355 A CN 1366355A CN 01101943 A CN01101943 A CN 01101943A CN 01101943 A CN01101943 A CN 01101943A CN 1366355 A CN1366355 A CN 1366355A
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CN
China
Prior art keywords
pressure
storage battery
outer container
transmission pipe
conductive sheet
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Pending
Application number
CN01101943A
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Chinese (zh)
Inventor
刘粤荣
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Individual
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Individual
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Priority to CN01101943A priority Critical patent/CN1366355A/en
Publication of CN1366355A publication Critical patent/CN1366355A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

The invention relates to an equipment for transmitting pressure of accumulator suitable for use in various pressure conditions. The equipment includes outer box of accumulator and pressure-transmission element that is fixed on supplement filling opening of outer box of accumulator or port of pressure reducing valve of accumulator. The bottom face of the pressure-transmission element touches electrolyte inside the accumulator. The invented equipment can keep kinetic balance of pressure between inside and outside of interface which is outer casing of the accumulator. Thus invented accumulator suits various pressure conditions, especially such as deep-sea environment.

Description

The pressure conduction device that a kind of storage battery is used
The present invention relates to a kind of structure of storage battery, particularly relate to the pressure conduction device that a kind of storage battery that adapts to use under the various pressure environments is used.
Up to now, the battery applications field overwhelming majority is to use in the air ambient on land, no matter external environment condition pressure is fine day or rainy being about 1 barometric millimeter of mercury, the outer container of the storage battery product of therefore, selling on the existing market is seldom considered the Application Design after external environment condition pressure sharply changes.In recent years, because land resources is poor day by day, each advanced industrial country is coincidentally the exploitation abundant more seabed resources that fixate, thereby proposed to adapt to the demand of the storage battery (as the battery that uses in the deep-sea) that various pressure environments use.
As everyone knows, the exploration of deep-sea resources and exploitation, the difficult problem that first is run into except that producing automated machine is an energy problem.For some fixed network operations, people still can resemble and lay special cable solution energy problem land.But when particularly needing mobile operation, can only rely on storage battery that the energy is provided for the deep-sea, require for this reason storage battery must adapt to tens in addition the external environment condition of a hundreds of barometric millimeter of mercury pressure in use.
In the battery design of existing deep-sea, generally be to use the shell of conventional storage battery instead high-strength material to make, perhaps adopt high-strength material to make special-purpose storage battery resistance to compression outer container, be used to resist external environment condition pressure, increase the storage battery cost thus greatly, be unfavorable for the inexpensive functional principle of civilian storage battery.On the other hand, even adopt the method for high strength resistance to compression outer container, for the requirement that thousands of meters abyssal environments use, the difficulty that realizes aspect material technology is very big, therefore only has several developed countries to obtain industry success, market price costliness at present in the world.So a kind of cheap practical method is sought in the research always of civilian storage battery industry, expect that the easy method of available industrial realization produces the deep-sea storage battery, to adapt to the 21 century demand that develops of ocean civilian industry.
The objective of the invention is to: overcome the shortcoming that existing civilian storage battery externally uses under the excessive situation of ambient pressure, or the very big and high shortcoming of cost of the storage battery manufacture difficulty that overcomes existing employing high strength resistance to compression outer container, thereby provide a kind of be applicable under the deep-sea use, all adopt conventional material manufacturing, the pressure conduction device that the simple storage battery of manufacture craft is used.
The object of the present invention is achieved like this:
The pressure conduction device that storage battery provided by the invention is used, comprise a common storage battery outer container, on the additional filling opening of storage battery outer container or the decompression valve port of storage battery (former pressure-reducing valve cap is removed), connect firmly a pressure conducting piece, and the bottom of pressure conducting piece contacts fully with the electrolyte of internal storage battery.
Described pressure conducting piece comprises pressure conductive sheet or pressure transmission pipe; Pressure conductive sheet or pressure transmission pipe can with rubber or other be as bigger, the acidproof and alkaline-resisting material of coefficient of elasticity such as plastics; , note adaptation requirement when selecting material to battery electrolyte acid (or alkali) degree.
Described pressure conductive sheet top exposes shape in the storage battery exterior portion and can be circle, ellipse, square, rectangle, trapezoidal, polygonal limit shape and other geometry, and its area is greater than 1mm 2, thickness is greater than 0.01mm.
Described pressure conductive sheet directly connects firmly on the additional filling opening of open type storage battery outer container, and the bottom surface of pressure conductive sheet touches the internal storage battery electrolyte; Perhaps the pressure conductive sheet connects firmly indirectly and replenishes on the filling opening, be that a hole is opened in the center of circle promptly with the center that replenishes the filling opening blind nut, the size in hole is similar to replenishes the filling opening diameter, the pressure conductive sheet is fixing within it, cover this hole, blind nut is fixed on and replenishes on the filling opening, and the bottom surface of pressure conductive sheet touches the internal storage battery electrolyte.Described hole can be the hole of geometries such as circular, square, ellipse.
The cross section of described pressure transmission pipe is greater than 1mm 2, its length is greater than 1mm, is shaped as circle, ellipse, square, rectangle, trapezoidal and other geometry.
Described storage battery outer container comprises open type or enclosed accumulator outer container; When a pressure transmission pipe connects firmly at enclosed accumulator outer container decompression valve port (former pressure-reducing valve cap is removed) when going up, the afterbody of pressure transmission pipe touches the internal storage battery electrolyte, and electrolyte is filled to pressure transmission pipe exposes in the pipe outside storage battery, the top of its pressure transmission pipe is lived with a seal sealing and fixing.Described seal is identical with the material of pressure transmission pipe.Described seal is that a diaphragm seal directly seals, but perhaps does seal with the piston of opening a supplier, and plug is in the decompression valve port, and interface is filled the pressure-resistant material of common waterproof gas-tight.The material of piston should be selected for use with the material of pressure transmission pipe identical, and as rubber or other elasticity acid resisting material preferably, sealing means can adopt the form that is connected that rotation is connected or other makes things convenient for secondary to use.
Fill with traditional storage battery electrolyte lean solution and general rich solution is filled and different is, must change abundant rich solution filling into after using this device instead.When adopting pressure conductive sheet producing device, the electrolyte of internal storage battery must be filled to the pressure conductive sheet and contact fully; When adopting the pressure transmission pipe producing device.
To the utilization of apparatus of the present invention, the type selecting of battery electrolyte is very important, does not have substantially when requiring electrolyte to discharge and recharge that any gas is separated out, the coefficient of expansion of charging and discharging state is minimum.To traditional lead acid accumulator, if the supporting unavoidable bubbing of charging method, the device that is connected of pressure transmission pipe or pressure conductive sheet and storage battery can be made into and can supply the secondary opening form.Like this, put pressure transmission pipe (sheet) in open state when charging, make it bubbing, storage battery is full of electricity back resealing pressure conduction device to be used.This method is owing to repeat the opening and the sealing of pressure conduction device during accumulator cell charging and discharging, and strength of discharge can only be limited in little current range, makes troubles to practical application.Therefore this device convenient and practical at lead acid accumulator need add in electrolyte sulfuric acid and adsorb additive by force or use colloidal electrolyte instead, to adapt to apparatus of the present invention to electrolytical above-mentioned requirements.
To the utilization of this device, also be a considerable problem as the pole plate compressive resistance of internal storage battery main structure body.In the manufacture craft of conventional chloride plate, the polar board surface active material after the pickling energising changes into is a kind of loose body, uses to be out of question under atmospheric pressure environment.But when using in conjunction with this device, because pressure transmission pipe (sheet) is passed to the internal storage battery structure with external pressure, when external pressure strengthens n times (n>1), the internal storage battery pole plate also will bear n multiplication of voltage power, active material solidifies bad pole plate might quicken to come off, thereby the capacity and the life-span of storage battery influenced to some extent.Therefore, must be when using this device to the active material state of cure requirement to some extent of accumulator plate, in principle, the compression resistance intensity of pole plate operate as normal will determine storage battery pressure environment life-span of using externally.
This device is not only applicable to use extraordinary sulfuric acid, chemical colloid to make electrolytical lead accumulator, its method principle be equally applicable to any use acidity, alkalescence, neutral electrolyte and use various material pole plates (or its distortion) once or secondary cell.
The advantage of apparatus of the present invention is:
Since principle that device of the present invention adopted be utilization liquid electrolyte volume can not compressed physical characteristic; by pressure conductive sheet or pressure transmission pipe external pressure transfer function with the liquid electrolyte that closely contacts; external pressure all is transferred to internal storage battery; thereby form the negative pressure identical with external pressure, that direction is opposite in internal storage battery; making storage battery is that the interface reaches external and internal pressure dynamic equilibrium with the shell, reaches storage battery and can adapt to the purpose that different pressures environment, particularly abyssal environment use significantly.Therefore, the resistance to compression principle is simple, and manufacture craft is easy, is fit to large-scale industrial production.
2. the cost of manufacture price is low.
3. withstand voltage big, the anti-pressure ability of this kind device only depends on the compression strength of storage battery outer container and pole plate on the principle.
4. this kind device is applicable to any use acidity, alkalescence, neutral electrolyte and uses the various material utmost points
Plate (or its distortion) once or secondary cell.
The present invention is described in detail below in conjunction with drawings and Examples:
Fig. 1 is the sealing structure of relief pressure valve schematic diagram on the common storage battery outer container
Fig. 2 a is an apparatus structure schematic diagram of the present invention
Fig. 2 b is the schematic diagram that has behind the storage battery filling electrolyte of Fig. 2 a structure
Fig. 3 a be on the common storage battery outer container additional filling opening blind nut structural representation
Fig. 3 b is the additional filling opening blind nut opening schematic diagram on the storage battery outer container
Fig. 4 a is a kind of structural representation of device of the present invention
Fig. 4 b is the another kind of structural representation of device of the present invention
Drawing is described as follows:
1-storage battery outer container; The additional filling opening of 2-storage battery outer container;
The decompression valve port of 3-storage battery; 4-pressure conductive sheet;
The 5-pressure transmission pipe; The 6-electrolyte;
The 7-top cover; The 8-circular hole;
The 9-nut; The 10-diaphragm seal;
11-coupling stud mouth;
Embodiment 1
A poly-pressure-reducing valve of moulding the sealed type lead acid battery 1 (add polymer water-absorbent and make it to discharge and recharge few gassing) of shell of the conventional high strength of use is transformed, and the form of conventional pressure-reducing valve is seen accompanying drawing 1.Remodeling method is: the bonnet that removes pressure-reducing valve becomes decompression valve port 3, select for use an internal diameter and bonnet is identical, length is 10cm lucite pipe as pressure transmission pipe 5 (requiring plastic tube transparent mainly is to be convenient to observe the electrolyte filling extent), one end of pressure transmission pipe 5 makes it firmly to link to each other with the valve rod that reduces pressure with epoxy resin, and its bore is inner to be communicated with fully with internal storage battery.By lucite pipe, the extraordinary electrolyte sulfuric acid to storage battery adds same prescription is filled to the level that plastic tube is full of substantially, and use vacuumizes and hot blast technique makes the other end of pressure transmission pipe 5 shut with a plastic seal sheet 10, as shown in Figure 2.
After using device repacking sealed lead accumulator of the present invention, close, can 1. expose pressure transmission pipe and use if pressure transmission pipe 5 occupy-places can not be adorned original seal cover; 2. can design the special supporting accurate seal cover of the box of falling the opening (for aesthetic reasons) in commercialization is produced, should design the water-permeable and air permeable aperture in the seal cover, purpose is in order effectively external environment condition pressure (air pressure, hydraulic pressure etc.) to be passed on the pressure transmission pipe.
Use the lead acid accumulator of plant modification of the present invention, when external environment condition pressure strengthens, the external pressure of storage battery will be by the pressure transmission pipe and the inner electrolyte that is full of of plastic production, be passed to the outer casing inner wall of storage battery, make it to produce pressure identical with the outer shell outer wall size, that direction is opposite, with the shell is that the interface reaches pressure dynamic equilibrium, thereby reaches the purpose of keeping operate as normal when externally ambient pressure strengthens.
Embodiment 2
Present embodiment as shown in Figure 3, the coupling nut formula capping that replenishes on the filling opening 2 with the storage battery outer container illustrates, use the poly-additional filling opening 2 of moulding the plumbous colloid storage battery of the open type outer container 1 of shell of conventional high strength to transform to one, replenish the common capping of filling opening 2 with the nut 9 of coupling is arranged, piston type and other form are also arranged.(both can install the device that is connected additional to other form capping, also can adopt other adhesive bonding method); Concentric circle holes 8 of excavation on nut 9 cappings, aperture 8 sizes are identical with the coupling stud internal diameter of former storage battery.The round rubber sheet of selecting external diameter identical with the coupling stud external diameter or big slightly (is principle not influence that nut rotatably compresses) for use is as pressure conductive sheet 4, and the elasticity of pressure conductive sheet 4 and intensity should be enough big.Then, with colloidal electrolyte internal storage battery is filled cmpletely, be filled to and replenish till filling opening 2 planes, the pressure conductive sheet 4 that above-mentioned sheet rubber is made is seated in the coupling stud mouth 11 that replenishes filling opening 2, bonding with the double-screw bolt circle wall, pressure conductive sheet 4 must contact fully with colloidal electrolyte.At last, it is fastening to add a cover nut, can add high-strength structureal adhesives at double-screw bolt and 9 on nut for the purpose of firmly, and the processing characteristic schematic diagram sees Fig. 3 for details.
Use the lead-colloid storage battery of this plant modification, aspect anti-compression property, can reach the effect identical with embodiment 1.
In the present embodiment, the hole of nut transformation excavation is not necessarily circular, also can be square, fusiformis, rectangle, other shape such as trapezoidal, but the most reasonable with circular design, effect that its size is identical with the double-screw bolt internal diameter is best.
Embodiment 3
Pressure transmission pipe device to embodiment 1, the jail of pressure transmission pipe and sealed cell relief valve seam connects form and changes coupling nut (post) into, pressure-reducing valve and double-screw bolt (cap), pressure transmission pipe and nut (post) and double-screw bolt and nut are all shut with epoxy resin or other adhesive, its bore inside is communicated with fully, and the mouth-sealing method of the liquid feeding requirement and the pressure transmission pipe other end is identical.Adopt this method also can reach the purpose of embodiment 1.
Embodiment 4
To the rubber pressure conductive sheet fastening method of embodiment 2, without the fastening form of double-screw bolt (cap), and sheet rubber and former double-screw bolt circle wall are connected with high-strength structureal adhesives, all the other methods are identical.Use this device and method also can reach the effect of embodiment 2.
Embodiment 5
To the plastic pressure conducting tube of embodiment 1 and embodiment 3, except that an end that is connected with the sealed cell pressure-reducing valve, but the upper end mouth-sealing method changes the piston that the supplier just opens into.The material of piston should be selected rubber or other elasticity acid resisting material preferably for use, and sealing means can adopt the form that is connected that rotation is connected or other makes things convenient for secondary to use, and interface is filled the pressure-resistant material of waterproof gas-tight.All the other methods are identical with embodiment 1 or embodiment 3.Use this device also can reach the effect of embodiment 1 or embodiment 3.
Above-described pressure conduction device both can be implemented through traditional opening, sealed type lead acid battery, the colloid storage battery of special processing at electrolyte, can be applied in also that alkaline battery and other be suitable for once or secondary cell, described example only is the preferred embodiment of the principle of the invention.Should be understood that; for the ordinary skill in the art; on the basis that does not break away from the principle of the invention; can by pressure transmission pipe or pressure conductive sheet material, shape and with the be connected change of technology of storage battery; or the utilization principle of the invention pressure conduction device special to battery designs; or on pressure transmission pipe that the present invention proposes and pressure conductive sheet principle basis, install the technology implementation that secondary, three grades of decompressors make some distortion additional and improve, this should be considered as belonging to protection scope of the present invention.

Claims (9)

1. pressure conduction device that storage battery is used, comprise a common storage battery outer container, it is characterized in that: on the decompression valve port of the additional filling opening of storage battery outer container or storage battery, connect firmly a pressure conducting piece, and pressure conducting piece bottom contacts fully with the electrolyte of internal storage battery.
2. the pressure conduction device of using by the described a kind of storage battery of claim 1, it is characterized in that: described storage battery outer container comprises the enclosed accumulator outer container; One pressure transmission pipe connects firmly on enclosed accumulator outer container decompression valve port, the bottom of pressure transmission pipe touches the internal storage battery electrolyte, and electrolyte is filled to pressure transmission pipe and exposes in the pipe outside storage battery, and the top of its pressure transmission pipe is lived with a seal sealing and fixing.
3. the pressure conduction device of using by the described a kind of storage battery of claim 2, it is characterized in that: described seal comprises diaphragm seal or sealing plug, its material therefor is identical with the material of pressure transmission pipe.
4. the pressure conduction device of using by the described a kind of storage battery of claim 3 is characterized in that: but described seal is the piston of opening a supplier, plug is in the decompression valve port, and interface is filled the pressure-resistant material of common waterproof gas-tight.
5. the pressure conduction device of using by the described a kind of storage battery of claim 1, it is characterized in that: the described pressure conducting piece that on the additional filling opening of storage battery outer container, connects firmly, comprise that a pressure conductive sheet directly connects firmly on the additional filling opening of storage battery outer container, the bottom surface of pressure conductive sheet touches the electrolyte in the storage battery.
6. the pressure conduction device of using by the described a kind of storage battery of claim 1, it is characterized in that: the described pressure conducting piece that on the decompression valve port of storage battery outer container, connects firmly, comprise that the pressure conductive sheet connects firmly indirectly on additional filling opening, at the center that replenishes the blind nut on the filling opening is that a circular hole is opened in the center of circle, the size of circular hole is similar to replenishes the filling opening diameter, in the pressure conductive sheet is fixed on, cover circular hole, blind nut is fixed on and replenishes on the filling opening, and the bottom surface of pressure conductive sheet touches the internal storage battery electrolyte.
7. the pressure conduction device of using by the described a kind of storage battery of claim 1, it is characterized in that: described pressure conducting piece comprises pressure conductive sheet, the pressure transmission pipe of bigger, the acidproof or alkaline-resisting material of coefficient of elasticity.
8. the pressure conduction device of using by claim 1 or 2 described a kind of storage batterys, it is characterized in that: the cross section of described pressure transmission pipe is greater than 1mm 2, its length is greater than 1mm, is shaped as circle, ellipse, square, rectangle, trapezoidal and other geometry.
9. the pressure conduction device of using by claim 1 or 5 described a kind of storage batterys, it is characterized in that: described pressure conductive sheet is exposed and be shaped as circle, ellipse, square, rectangle, trapezoidal, polygonal limit shape and other geometry outside storage battery, and its area is greater than 1mm 2, thickness is greater than 0.01mm.
CN01101943A 2001-01-18 2001-01-18 Pressure transfer device for accumulator Pending CN1366355A (en)

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Application Number Priority Date Filing Date Title
CN01101943A CN1366355A (en) 2001-01-18 2001-01-18 Pressure transfer device for accumulator

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Application Number Priority Date Filing Date Title
CN01101943A CN1366355A (en) 2001-01-18 2001-01-18 Pressure transfer device for accumulator

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CN1366355A true CN1366355A (en) 2002-08-28

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101804854A (en) * 2010-03-30 2010-08-18 中国船舶重工集团公司第七〇二研究所 Compensation-bag battery box for deep submergence vehicle
CN103119751A (en) * 2010-11-17 2013-05-22 宝马股份公司 Energy accumulator for a motor vehicle having a closure device for discharging condensate
CN108593010A (en) * 2018-06-28 2018-09-28 中国电子科技集团公司第二十二研究所 Cell Experimentation An tooling
CN109244372A (en) * 2018-08-09 2019-01-18 珠海吉达讯储能技术研究院有限公司 A kind of processing unit (plant) and method of battery pole piece

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101804854A (en) * 2010-03-30 2010-08-18 中国船舶重工集团公司第七〇二研究所 Compensation-bag battery box for deep submergence vehicle
CN103119751A (en) * 2010-11-17 2013-05-22 宝马股份公司 Energy accumulator for a motor vehicle having a closure device for discharging condensate
CN108593010A (en) * 2018-06-28 2018-09-28 中国电子科技集团公司第二十二研究所 Cell Experimentation An tooling
CN109244372A (en) * 2018-08-09 2019-01-18 珠海吉达讯储能技术研究院有限公司 A kind of processing unit (plant) and method of battery pole piece

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C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication