CN1356280A - permanently self-cleaning nano ceramic enamel - Google Patents
permanently self-cleaning nano ceramic enamel Download PDFInfo
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- CN1356280A CN1356280A CN 02115404 CN02115404A CN1356280A CN 1356280 A CN1356280 A CN 1356280A CN 02115404 CN02115404 CN 02115404 CN 02115404 A CN02115404 A CN 02115404A CN 1356280 A CN1356280 A CN 1356280A
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- dioxide
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- sesquioxide
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Abstract
A permanently self-cleaning nano ceramic glase is prepared by adding more kinds of nano oxide to ordinary ceramic glase. Its advantages include permanently self-clearing and hydrophoblic functions, simple preparing process, wide temp range, and high resistance to acid and alkali.
Description
Technical field
The present invention relates to industry, civilian ceramic glaze material, particularly permanently self-cleaning nano ceramic enamel material.
Background technology
The conventional ceramic glaze, hydrophobic and in particular for electric power porcelain vase, porcelain rod, building and family and ceramic glaze surface from clean poor performance, easily pollute.Still find at present the report and the introduction of preparation permanently self-cleaning nanometer high-tension porcelain insulator, also do not find any relevant permanently self-cleaning nano ceramic enamel and at the report and the practical application product of the application on ceramic product surface.Self-cleaning nano ceramic enamel and self-cleaning ceramics series products are thirsted for having by ceramic product production and application producer.
Summary of the invention
The purpose of this invention is to provide a kind of permanently self-cleaning nano ceramic enamel,, make it have permanent hydrophobic, clean certainly performance by the structure on nanotechnology change ceramic glaze surface.
The permanently self-cleaning nano ceramic enamel of realizing the object of the invention is to add a zinc oxide (ZnO), bismuthous oxide bismuth trioxide (Bi in the conventional ceramic glaze
2O
3), antimonous oxide (Sb
2O
3), Manganse Dioxide (MnO
2), cobalt sesquioxide (Co
2O
3), chromium sesquioxide (Cr
2O
3), nickel protoxide (NiO), silicon-dioxide (SiO
2), boron trioxide (B
2O
3), nine water aluminum nitrate (Al (NO
3)
39H
2O) inorganic nano material, wherein the weight proportion of each material is: 200 parts in conventional ceramic glaze, 0～10 part in a zinc oxide, 0.7～1.0 part of bismuthous oxide bismuth trioxide, 1.5～1.8 parts of antimonous oxides, 0.7～1.0 part of Manganse Dioxide, 1.5～1.8 parts of cobalt sesquioxides, 0.7～1.0 part of chromium sesquioxide, 1.5～1.8 parts of nickel protoxides, 2～2.8 parts of silicon-dioxide, 0.15～0.2 part of boron trioxide, 0～0.2 part of nine water aluminum nitrate.
The compound method of described permanently self-cleaning nano ceramic enamel the steps include:
(1) with nano level bismuthous oxide bismuth trioxide, antimonous oxide, Manganse Dioxide, cobalt sesquioxide, chromium sesquioxide, nickel protoxide, silicon-dioxide, boron trioxide, nine water aluminum nitrates by 1: 0.5: 1: 0.5: 1: 0.5: 1: 1.5: 0.1: 0～0.1 weight ratio mixed;
(2) 1 mixture is mixed by 2: 0～5 weight ratios with zinc oxide;
(3) (2) mixture is mixed promptly by 8～20 grams and 200 milliliters of conventional ceramic glaze.
The permanently self-cleaning nano ceramic enamel product that is mixed and made into by the present invention, be coated in ceramic sun-dried mud brick surface, the ceramic surface of preparing through the traditional ceramics sintering technology has nanostructure, forms one deck air film between the enamel surface and the globule, makes it that permanent hydrophobic, clean certainly performance be arranged.
The present invention has compared following advantage and positively effect with existing correlation technique: permanent hydrophobic, from clean performance; Preparation technology is simple; Cost is low; Do not change the conventional sintering technology of ceramic product; Temperature resistant range is big; Resistance to acids and bases is good.
Embodiment
Embodiment 1
Add nano level bismuthous oxide bismuth trioxide (Bi in the conventional ceramic glaze
2O
3), antimonous oxide (Sb
2O
3), Manganse Dioxide (MnO
2), cobalt sesquioxide (Co
2O
3), chromium sesquioxide (Cr
2O
3), nickel protoxide (NiO), silicon-dioxide (SiO
2), boron trioxide (B
2O
3) oxide compound, concrete ratio is 0.5: 1: 0.5: 1: 0.5: 1: 1.5: 0.1.After these nano materials were mixed, the ratio of itself and common enamel was 10 gram nano material and 200 milliliters of common enamel.Common enamel that uses in the example and china clay base are the common enamel and the product of china clay base.Sintering process reached 300 degree for beginning from room temperature through 1 and a half hours at the uniform velocity heat, 300 degree insulations 1 and a half hours; On the bases of 300 degree, again through 1 and a half hours at the uniform velocity heat, reach 600 degree, 600 degree insulations 1 hour; On 600 long bases,, reach 900 degree, 900 degree insulations 1 and a half hours through 1 and a half hours at the uniform velocity heat; On 900 degree bases, through insulation in 1 and a half hours, reach 1100 degree, 1100 degree insulations 1 hour; On 1100 degree bases, through 1 and a half hours at the uniform velocity heat, reach 1280 degree, 1280 degree insulations 2 hours; Turn off power supply at last, make it naturally cool to room temperature, obtain permanent hydrophobic, clean certainly nanometer enamel surface, hydrophobic angle reaches 120 degree.
Embodiment 2
Add nano level bismuthous oxide bismuth trioxide (Bi in the conventional ceramic glaze
2O
3), antimonous oxide (Sb
2O
3), Manganse Dioxide (MnO
2), cobalt sesquioxide (Co
2O
3), chromium sesquioxide (Cr
2O
3), nickel protoxide (NiO), silicon-dioxide (SiO
2), boron trioxide (B
2O
3) oxide compound and nine water aluminum nitrate (Al (NO
3)
39H
2O), concrete ratio is 0.5: 1: 0.5: 1: 0.5: 1: 1.5: 0.1: 0.1.After these nano materials are mixed,, be that 10 gram nano materials are joined 200 milliliters of common enamel with the ratio of mixture and common enamel again with the mixed of zinc oxide according to 2: 5.Common enamel that this example is used and china clay base and sintering process obtain permanent hydrophobic, clean certainly nanometer enamel surface with embodiment 1, and hydrophobic angle reaches 125 degree.
Claims (2)
1, a kind of self-cleaning nano ceramic enamel comprises the conventional ceramic glaze, it is characterized in that also comprising a zinc oxide (ZnO), bismuthous oxide bismuth trioxide (Bi
2O
3), antimonous oxide (Sb
2O
3), Manganse Dioxide (MnO
2), cobalt sesquioxide (Co
2O
3), chromium sesquioxide (Cr
2O
3), nickel protoxide (NiO), silicon-dioxide (SiO
2), boron trioxide (B
2O
3), nine water aluminum nitrate (Al (NO
3)
39H
2O) inorganic nano material, the weight proportion of each material is: 200 parts of conventional ceramic glaze add 0～10 part in a zinc oxide, 0.7～1.0 part of bismuthous oxide bismuth trioxide, 1.5～1.8 parts of antimonous oxides, 0.7～1.0 part of Manganse Dioxide, 1.5～1.8 parts of cobalt sesquioxides, 0.7～1.0 part of chromium sesquioxide, 1.5～1.8 parts of nickel protoxides, 2～2.8 parts of silicon-dioxide, 0.15～0.2 part of boron trioxide, 0～0.2 part of nine water aluminum nitrate.
2, the compound method of the described nano ceramic enamel of claim 1 the steps include:
(1) with nano level bismuthous oxide bismuth trioxide, antimonous oxide, Manganse Dioxide, cobalt sesquioxide, chromium sesquioxide, nickel protoxide, silicon-dioxide, boron trioxide, nine water aluminum nitrates by 1: 0.5: 1: 0.5: 1: 0.5: 1: 1.5: 0.1: 0～0.1 weight ratio mixed;
(2) 1 mixture is mixed by 2: 0～5 weight ratios with zinc oxide;
(3) (2) mixture is mixed promptly by 8～20 grams and 200 milliliters of conventional ceramic glaze.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB02115404XA CN1164515C (en) | 2002-01-04 | 2002-01-04 | permanently self-cleaning nano ceramic enamel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB02115404XA CN1164515C (en) | 2002-01-04 | 2002-01-04 | permanently self-cleaning nano ceramic enamel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1356280A true CN1356280A (en) | 2002-07-03 |
| CN1164515C CN1164515C (en) | 2004-09-01 |
Family
ID=4743624
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB02115404XA Expired - Fee Related CN1164515C (en) | 2002-01-04 | 2002-01-04 | permanently self-cleaning nano ceramic enamel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1164515C (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101274858B (en) * | 2008-05-16 | 2011-03-23 | 景德镇陶瓷学院 | Hydrophobic self-cleaning sanitary ware glaze and preparation thereof |
| CN102503571A (en) * | 2011-10-20 | 2012-06-20 | 景德镇陶瓷学院 | Ceramic glaze modifying additive and preparation method and application thereof |
| CN102718557A (en) * | 2012-05-31 | 2012-10-10 | 潮州宏业陶瓷制作厂有限公司 | High-grade stripe iron red crystallization transmutation ceramic glaze for daily use |
| WO2013139257A1 (en) * | 2012-03-19 | 2013-09-26 | 东莞市海格瑞化工有限公司 | Burn-free colored glaze material |
| CN105924231A (en) * | 2016-05-03 | 2016-09-07 | 武汉工程大学 | Wear-resistant electric porcelain glaze and preparation method thereof |
| CN106243789A (en) * | 2016-08-09 | 2016-12-21 | 广东皮阿诺科学艺术家居股份有限公司 | A kind of nano microcrystalline glaze slip and baking vanish goods |
| CN106517793A (en) * | 2016-11-16 | 2017-03-22 | 合众（佛山）化工有限公司 | Novel ultra fine self cleaning glaze material and preparation process thereof |
| CN108249961A (en) * | 2018-01-19 | 2018-07-06 | 段艳玲 | A kind of method based on 3D printing and the surface coating super-hydrophobic high-strength ceramic glaze thin layer of micrometer/nanometer particle preparation |
| CN108585500A (en) * | 2018-08-10 | 2018-09-28 | 张家港市六福新材料科技有限公司 | A kind of preparation method of hydrophobic type composite ceramic enamel |
| CN116986922A (en) * | 2023-08-03 | 2023-11-03 | 潮州市德科陶瓷有限公司 | Nano self-cleaning ceramic glaze and preparation method thereof |
-
2002
- 2002-01-04 CN CNB02115404XA patent/CN1164515C/en not_active Expired - Fee Related
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101274858B (en) * | 2008-05-16 | 2011-03-23 | 景德镇陶瓷学院 | Hydrophobic self-cleaning sanitary ware glaze and preparation thereof |
| CN102503571A (en) * | 2011-10-20 | 2012-06-20 | 景德镇陶瓷学院 | Ceramic glaze modifying additive and preparation method and application thereof |
| CN102503571B (en) * | 2011-10-20 | 2014-02-12 | 景德镇陶瓷学院 | Ceramic glaze modifying additive and preparation method and application thereof |
| WO2013139257A1 (en) * | 2012-03-19 | 2013-09-26 | 东莞市海格瑞化工有限公司 | Burn-free colored glaze material |
| CN102718557A (en) * | 2012-05-31 | 2012-10-10 | 潮州宏业陶瓷制作厂有限公司 | High-grade stripe iron red crystallization transmutation ceramic glaze for daily use |
| CN102718557B (en) * | 2012-05-31 | 2014-04-09 | 潮州宏业陶瓷制作厂有限公司 | High-grade stripe iron red crystallization transmutation ceramic glaze for daily use |
| CN105924231A (en) * | 2016-05-03 | 2016-09-07 | 武汉工程大学 | Wear-resistant electric porcelain glaze and preparation method thereof |
| CN105924231B (en) * | 2016-05-03 | 2018-12-14 | 武汉工程大学 | A kind of wear-resisting glaze for electric porcelain and preparation method thereof |
| CN106243789A (en) * | 2016-08-09 | 2016-12-21 | 广东皮阿诺科学艺术家居股份有限公司 | A kind of nano microcrystalline glaze slip and baking vanish goods |
| CN106517793A (en) * | 2016-11-16 | 2017-03-22 | 合众（佛山）化工有限公司 | Novel ultra fine self cleaning glaze material and preparation process thereof |
| CN106517793B (en) * | 2016-11-16 | 2020-09-01 | 合众（佛山）化工有限公司 | Superfine self-cleaning glaze and preparation process thereof |
| CN108249961A (en) * | 2018-01-19 | 2018-07-06 | 段艳玲 | A kind of method based on 3D printing and the surface coating super-hydrophobic high-strength ceramic glaze thin layer of micrometer/nanometer particle preparation |
| CN108585500A (en) * | 2018-08-10 | 2018-09-28 | 张家港市六福新材料科技有限公司 | A kind of preparation method of hydrophobic type composite ceramic enamel |
| CN116986922A (en) * | 2023-08-03 | 2023-11-03 | 潮州市德科陶瓷有限公司 | Nano self-cleaning ceramic glaze and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1164515C (en) | 2004-09-01 |
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