CN1350983A - Process and reactor for quickly purifying water - Google Patents

Process and reactor for quickly purifying water Download PDF

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Publication number
CN1350983A
CN1350983A CN 00130321 CN00130321A CN1350983A CN 1350983 A CN1350983 A CN 1350983A CN 00130321 CN00130321 CN 00130321 CN 00130321 A CN00130321 A CN 00130321A CN 1350983 A CN1350983 A CN 1350983A
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China
Prior art keywords
water
reaction unit
stage
ozone
reactor
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CN 00130321
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Chinese (zh)
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CN1140470C (en
Inventor
曲久辉
雷鹏举
刘会娟
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Research Center for Eco Environmental Sciences of CAS
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Research Center for Eco Environmental Sciences of CAS
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Priority to CNB00130321XA priority Critical patent/CN1140470C/en
Publication of CN1350983A publication Critical patent/CN1350983A/en
Application granted granted Critical
Publication of CN1140470C publication Critical patent/CN1140470C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Physical Water Treatments (AREA)

Abstract

A process for fast purifying water includes such steps as preparing ozone by using (180-200)-nm ultraviolet lamp to radiate air, pumping the mixture of ozone and air into water, and using (232-238)-nm ultraviolet ray to radiate water for removing bacteria and trace organic substances from water. Its reactor is also disclosed. Its advantage is high effect.

Description

Quickly cleaning water method and the reactor that is used for this method
The present invention relates to a kind of method and reactor of quickly cleaning water, specifically be to utilize the uviolizing of air and secondary different wave length to produce ozone continuously, and ozone and UV-light combined action are purified waste water, increase the method and apparatus of oxygen in water.
At present, the device that utilizes ultraviolet-sterilization mainly is the ultraviolet irradiation by single wavelength, can not produce ozone in the process, can't realize the synergy function of ultraviolet and ozone, relatively poor to the treatment effects such as organic pollutant in the water, more can not will effectively increase the treating water dissolved oxygen.Development recently and the UV/O that uses 3The Synergistic biocidal device mainly is to utilize the method for one-level ultraviolet and air pump aerating to produce a part of ozone, and has realized UV/O 3Synergy.But this method and apparatus is because of having only the one-level uv irradiating, can not take into account that best ozone takes place and the making full use of of UV-light, and makes the not high or UV of the productive rate of ozone utilize effect bad as sterilizing function.
The objective of the invention is: by the ultraviolet source irradiation of different wave length, in the continuous ozoniferous while, improve UV-light and with the symphyogenetic purifying water effect of ozone.
Method of the present invention is: purification of water quality process branch two-stage is carried out, the first step produces ozone based on the UV irradiation, air produces ozone under the UV-irradiation of 180nm-200nm wavelength, and will mix in its suction water by water sprayer, the water that contains ozone carries out oxidation disinfection under the UV irradiation handles, and water carries out second stage 232-238nm then, preferred 235nm, the UV-irradiation of wavelength makes UV/O 3Combined action reaches the purpose of purifying waste water and increasing oxygen in water.This method does not need extra making-up air device.
The structure such as the accompanying drawing of reactor of the present invention show.Quartz socket tube 2 is housed in first step reaction unit 1, and ultraviolet lamp tube 3, emptying gas-filled valve 4 and the ozone suction tube 5 of a 180nm-200nm is housed in the quartz socket tube: ultraviolet lamp tube 4 is connected in power supply 7 by lead 6; Be furnished with water-in 8 at first step reaction unit, and make it to be connected with water-jet case 9, water sprayer 10, inlet valve 11 and water inlet pipe 12; A side that is preferably in reactor is installed water discharging valve 13 and 14, to arrange the water in the discharger on request; The top of reaction is provided with water outlet 15, links to each other with outlet regulated valve 16 is installed; By pipeline 17 first step reaction unit is connected to second stage reaction unit 18, is provided with water-in 19 in the bottom of second stage reactor; Quartz socket tube 20 is housed in the reaction unit of the second stage, the ultraviolet lamp tube 21 of a 235nm wavelength is housed in the quartz socket tube, and be connected with power supply 7 by lead 22; Final outflow water mouth and water outlet regulated valve 23,24 are housed on the top of second stage reaction unit.
Reactor assembly operating process of the present invention is as follows:
After opening first step flowing water Valve 16 and second stage flowing water Valve 24, open inlet valve 11 again, pending water enters the first order reaction device through water inlet pipe 11, water sprayer 10 and one-level water-in 8, this is after one-level water outlet and flowing water Valve 16 enter the second order reaction device, after treating that water flows out water outlet 23, power-on 7 is started working ultraviolet lamp 3 and 21.At this moment, under the effect of water sprayer, the ozone that the one-level uv irradiating is produced is by mixing in the extraction pipe 5 suction water and with it, this water that contains ozone and air gas mixture carries out purifying treatment through the secondary uv irradiating, constantly mend air, the treatment capacity of regulating water inlet and flowing water Valve may command water by gas-filled valve 4.
Characteristics of the present invention are as follows:
1, adopt the ultraviolet source irradiation of secondary different wave length, the first step is to produce ozone, and the second stage is to purify waste water;
2, adopting water sprayer to make replenish air and processed water enter reactor carries out simultaneously, does not need extra making-up air device;
3, utilize the combined action of ozone oxidation and purple light irradiation, can remove pollutents such as trace organic matter, bacterium in the water, increased the dissolved oxygen of water simultaneously;
4, the water noresidue ozone after handling etc. does not produce new pollutent, has kept trace element, and is safe and reliable.
Brief Description Of Drawings: Fig. 1 is the synoptic diagram of reactor of the present invention
Embodiment:
Embodiment 1 utilizes the tap water preparation to contain the pending water of bacterium and soil ulmin, wherein contains 34800/mL of total bacterial count, 22000/100mL of intestinal bacteria, fulvic acid 8mg/L, carry out germicidal treatment under the following conditions:
One-level ultraviolet lamp tube: power 20W, wavelength 200nm;
Secondary ultraviolet lamp tube: power 20W, wavelength 235nm;
Air flow quantity: 70L/h;
Processed water flow: 600L/h;
Ozone generation amount: 130.18mg/m 3
It is as shown in table 1 to handle back water quality.
Water quality after table 1 embodiment 1 handles
Detect index Before the processing After the processing Remove (increase) rate %
Total bacterium (individual/mL) ????34800 ????4 ????99.99
Intestinal bacteria (individual/100mL) ????22000 ????0 ????100
Dissolved oxygen (mg/L) ????4.3 ????5.2 ????20.9
Soil ulmin (mg/L) ????8 ????2 ????75.0
Embodiment 2 utilizes the tap water preparation to contain the pending water of bacterium and soil ulmin, wherein contains 39700/mL of total bacterial count, 25000/100mL of intestinal bacteria, fulvic acid 8mg/L, carry out germicidal treatment under the following conditions:
One-level ultraviolet tube: power 20W, wavelength 200nm;
Secondary ultraviolet tube: power 30W, wavelength 235nm;
Air flow quantity: 120L/h;
Processed water flow: 700L/h;
Ozone generation amount: 141.12mg/m 3
It is as shown in table 2 to handle back water quality.
Water quality after table 2 embodiment 2 handles
Detect index Before the processing After the processing Remove (increase) rate %
Total bacterium (individual/mL) ?????39700 ?????2 ?????99.99
Intestinal bacteria (individual/100mL) ?????25000 ?????0 ?????100
Dissolved oxygen (mg/L) ?????4.3 ?????5.5 ?????28
Fulvic acid (mg/L) ?????8 ?????1.6 ?????80.0
Embodiment 3 utilizes the tap water preparation to contain the pending water of bacterium and soil ulmin, wherein contains 43900/mL of total bacterial count, 28000/100mL of intestinal bacteria, fulvic acid 8mg/L, carry out germicidal treatment under the following conditions:
One-level ultraviolet tube: power 30W, wavelength 200nm;
Secondary ultraviolet tube: power 30W, wavelength 235nm;
Air flow quantity: 150L/h;
Processed water flow: 900L/h;
Ozone generation amount: 177.48mg/m 3
It is as shown in table 3 to handle back water quality.
Water quality after table 3 embodiment 3 handles
Detect index Before the processing After the processing Remove (increase) rate %
Total bacterium (individual/mL) ????43900 ????2 ????99.99
Intestinal bacteria (individual/100mL) ????28000 ????0 ????100
Dissolved oxygen (mg/L) ????4.1 ????5.4 ????31.7
Fulvic acid (mg/L) ????8 ????0.92 ????88.8

Claims (5)

1. the method for a quickly cleaning water, this method comprises, ultra violet lamp air with 180~200nm wavelength produces ozone earlier, and with in ozone and the air gas mixture suction water, after ozone and one-level UV combined action are purified water, use the second stage UV-irradiation of 232-238nm wavelength again, make ozone and UV-light continue combined action, remove bacterium, micro-content organism in the water.
2. in accordance with the method for claim 1, wherein, second stage ultraviolet light wavelength is 235nm.
3. reactor that is used for quickly cleaning water, it is characterized in that, it comprises first step reaction unit (1) and the second stage reaction unit (18) that order links to each other, quartz socket tube (2) is housed in first step reaction unit (1), ultraviolet lamp tube (3), emptying gas-filled valve (4) and the ozone suction tube (5) of a 180nm-200nm is housed in the quartz socket tube; Ultraviolet lamp tube (4) is connected in power supply (7) by lead (6); Be furnished with water-in (8) at first step reaction unit, and make it to be connected with water-jet case (9), water sprayer (10), inlet valve (11) and water inlet pipe (12); The top of reaction is provided with water outlet (15), links to each other with outlet regulated valve (16) is installed; By pipeline (17) first step reaction unit is connected to second stage reaction unit (18), is provided with water-in (19) in the bottom of second stage reactor; Quartz socket tube (20) is housed in the reaction unit of the second stage, the ultraviolet lamp tube (21) of a 232-238nm wavelength is housed in the quartz socket tube, and be connected with power supply (7) by lead (22); Final outflow water mouth and water outlet regulated valve (23,24) are housed on the top of second stage reaction unit.
4. according to the described reactor of claim 3, it is characterized in that the ultraviolet light wavelength that the ultraviolet lamp tube that is equipped with in the quartz socket tube in the reaction unit of the second stage (21) is sent is 235nm.
5. according to the described reactor of claim 4, it is characterized in that, water discharging valve 13 and 14 also are installed, be used for the water in the discharger in a side of reactor.
CNB00130321XA 2000-10-31 2000-10-31 Process and reactor for quickly purifying water Expired - Fee Related CN1140470C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB00130321XA CN1140470C (en) 2000-10-31 2000-10-31 Process and reactor for quickly purifying water

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Application Number Priority Date Filing Date Title
CNB00130321XA CN1140470C (en) 2000-10-31 2000-10-31 Process and reactor for quickly purifying water

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CN1350983A true CN1350983A (en) 2002-05-29
CN1140470C CN1140470C (en) 2004-03-03

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101962213A (en) * 2010-10-21 2011-02-02 东南大学 Energy-saving multitube photochemical excitation/oxidation water advanced treatment device
CN102923813A (en) * 2012-10-31 2013-02-13 章燕 Method for sewage disposal and devices for sewage disposal
CN105293626A (en) * 2015-11-20 2016-02-03 江苏合一水业有限公司 Ultraviolet sewage processor
CN105621586A (en) * 2016-01-01 2016-06-01 深圳市利源水务设计咨询有限公司 Raw water treatment process and system based on ultraviolet light technology
US9933503B2 (en) 2012-09-11 2018-04-03 Koninklijke Philips N.V. Measurement of magnetic resonance rheology transducer vibrations using navigators

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101962213A (en) * 2010-10-21 2011-02-02 东南大学 Energy-saving multitube photochemical excitation/oxidation water advanced treatment device
US9933503B2 (en) 2012-09-11 2018-04-03 Koninklijke Philips N.V. Measurement of magnetic resonance rheology transducer vibrations using navigators
CN102923813A (en) * 2012-10-31 2013-02-13 章燕 Method for sewage disposal and devices for sewage disposal
CN105293626A (en) * 2015-11-20 2016-02-03 江苏合一水业有限公司 Ultraviolet sewage processor
CN105621586A (en) * 2016-01-01 2016-06-01 深圳市利源水务设计咨询有限公司 Raw water treatment process and system based on ultraviolet light technology
CN105621586B (en) * 2016-01-01 2018-07-06 深圳市利源水务设计咨询有限公司 A kind of original sub-block technique and system based on ultraviolet Technology

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Publication number Publication date
CN1140470C (en) 2004-03-03

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Granted publication date: 20040303

Termination date: 20161031