CN1332789A - Bleach-containing detergent composition - Google Patents

Abstract

The invention relates to a detergent composition comprising a bleach-sensitive component and a hydrogen peroxide source, wherein the hydrogen peroxide source is present in a particulate component having an average particle size, by weight, of from 700 microns to 1100 microns, preferably from 750 microns to 1000 microns, whereby at least 80 % by weight of the particulate component comprising the hydrogen peroxide source has a particle size of between 70 % to 130 % of the average particle size. The compositions preferably comprise a bleach activator of a specified average particle size.

Description

The detergent composition that contains SYNTHETIC OPTICAL WHITNER

Invention field

The present invention relates to comprise the detergent composition of the hydrogen peroxide cource of the component of SYNTHETIC OPTICAL WHITNER sensitivity and specified particle size.

Background of invention

The detergent composition that contains SYNTHETIC OPTICAL WHITNER generally contains the SYNTHETIC OPTICAL WHITNER based on oxygen, discharges perborate or the percarbonate and the common bleach-activating agent or the precursor of hydrogen peroxide typically in washing water.In solid detergent composition, these compounds are general sneaks in the binder composition as independent particle.

Washing composition also contain the component of some SYNTHETIC OPTICAL WHITNER sensitivity and in producing or store or using can with the component of SYNTHETIC OPTICAL WHITNER reaction.Can lose their some performances when therefore, the component of these SYNTHETIC OPTICAL WHITNER sensitivities is in being present in the composition that contains SYNTHETIC OPTICAL WHITNER.For example, spices, enzyme, dyestuff and whitening agent can react with SYNTHETIC OPTICAL WHITNER, particularly percarbonate and perborate bleach, especially when they when spraying component or mixed composition and exist.The various technology of known usefulness are protected the component of SYNTHETIC OPTICAL WHITNER-sensitivity, for example apply these components.Yet, still need further to improve the stability of the component of SYNTHETIC OPTICAL WHITNER sensitivity.

The inventor now finds can reduce this problem when the specific hydrogen peroxide cource particle with having narrow size-grade distribution than volume particle size mixes in the solid detergent composition.Believe that this is due to the fact that, than the hydrogen peroxide cource per unit weight of volume particle size and thus each active oxygen maybe can get oxygen and have less surface-area.Per unit active oxygen SYNTHETIC OPTICAL WHITNER has less total surface area to contact with the component of SYNTHETIC OPTICAL WHITNER sensitivity in composition thus.Therefore, the component that has reduced the SYNTHETIC OPTICAL WHITNER sensitivity contacts with percarbonate or perborate and a possibility that reacts.

Particularly in the composition of component as the composite grain existence of SYNTHETIC OPTICAL WHITNER sensitivity, even in the component of SYNTHETIC OPTICAL WHITNER sensitivity is sprayed onto composition on the detergent particles that comprises percarbonate, it is of the present invention than volume particle size to find that hydrogen peroxide cource has, and this helps the stability of the responsive component of SYNTHETIC OPTICAL WHITNER.

Known general, the particulate granularity is big more, and particle dissolved in water is slow more.Therefore, this has expected that also the hydrogen peroxide cource particle dissolves slowly in water.Yet, the inventor finds the hydrogen peroxide cource of larger particles of the present invention surprisingly, percarbonate particularly has water-soluble similarly water-soluble with less hydrogen peroxide cource, for example has mean particle size and be about 600 or even 500 microns percarbonate.

In addition, the detergent composition that the inventor finds to mix hydrogen peroxide cource and bleach-activating agent surprisingly is after storage, and its bleachability is not always satisfactory, in addition when SYNTHETIC OPTICAL WHITNER be also like this when stablizing.In addition, they find that a collection of product and the bleachability of another batch product may be different.

They find that now this is because the hydrogen peroxide cource component in particulate product particularly, separate, causes the uneven distribution of hydrogen peroxide cource component and/or bleach-activating agent component in manufacturing processed or in the storage process.

The inventor finds that bleach-activating agent component or its part also have big mean particle size, and the granularity that preferred class is similar to the hydrogen peroxide cource component is favourable, to reduce the separation of these components in product.Preferably, the base-material particle of composition also has the hydrogen peroxide cource of being similar to component, the mean particle size of the granularity of preferred bleach-activating agent component.

Summary of the invention

The invention provides the component that comprises the SYNTHETIC OPTICAL WHITNER sensitivity and the solids composition of hydrogen peroxide cource, wherein hydrogen peroxide cource exists with the particle component, by weight, its mean particle size is 700 microns-1100 microns, preferred 700-1000 micron, wherein the granularity that has of the particle component that comprises hydrogen peroxide cource of at least 80% weight is the 60%-140% of mean particle size.

Preferably, said composition comprises one or more bleach-activating agents.The detailed Description Of The Invention hydrogen peroxide cource

Hydrogen peroxide cource of the present invention is present in the particle component of composition, preferably mixes with other detergent components, is preferably the independent particle component form of composition.It is 700 microns-1000 microns that the particle component that contains hydrogen peroxide cource preferably has mean particle size, more preferably 750 or even 800 microns-950 microns, or even 820-920 micron.

Thus, at least 80%, preferably at least 90%, or even at least 95% or even basically the 100% weight particle component that comprises hydrogen peroxide cource have 60%-140% for average particle size, preferred 70%-130%, or even the more preferably granularity of 80%-120%,

Preferably at least 70%, or even at least 80%, more preferably at least 90%, or even at least 95% component that comprises hydrogen peroxide cource have granularity 600 or even 710 microns to about 1180 microns, preferred 710 microns-1000 microns

Thus, preferably be less than 10% weight, or even less than 6%, or have granularity even less than the particle of 4% weight and be lower than 425 microns, or even 600 microns.Also preferably be less than 10% weight thus, or even less than 6% or have granularity greater than 1400 microns or even 1180 microns even less than the particle of 4% weight.

Preferably, the granularity that comprises the component of hydrogen peroxide cource is very narrow weight distribution, is approximately mean value or intermediate value.

For example preferably average particle size is 800 microns, thus by weight, 5% or be less than 5% particle and have granularity and be lower than 600 microns, be less than 2% particle and have granularity greater than 1180 microns.Also preferred average particle size is 800 microns, thus by weight, 3% or be less than 3% particle and have granularity and be lower than 425 microns, be less than 5% particle and have granularity greater than 1400 microns.

Mean particle size used herein is the average particle size that the granularity with the known any ordinary method analytic sample of prior art obtains, for example the sieve by a series of given size of mesh sieves this material, and measures the weight percent that is retained on the sieve and/or passes through the material of sieve.The known method of also available prior art is measured minimum and maximum particle size with the sieve screening material of given size of mesh.

Preferred hydrogen peroxide cource is the perhydrate SYNTHETIC OPTICAL WHITNER, metal peroxy one persulphate for example, more preferably metal perborate, most preferred metal percarbonate, particularly its sylvite or be more preferably its sodium salt.

Especially the percarbonate of the present invention's use can be coated.The coating agent that is fit to is that prior art is known, for example hydrophobic agents such as wax, inorganic salt such as magnesium salts, vitriol and carbonate and silicate or its mixture.

Hydrogen peroxide cource, the component that preferably contains it preferably has solvability in 10 ℃ of water, so that be less than 10 minutes, preferably be less than 8 minutes, or the theoretical maximum that discharges described component in 6 minutes can get 75% of oxygen (AvO).Thus, preferably be less than 5 minutes, preferably be less than in 4 minutes and discharge theoretical maximum and can get at least 50% of oxygen.

Can be by following mensuration solvability: 5.0 gram hydrogen peroxide cources or the component that comprises it are added in the Tergotometer ERWEKA plastic beaker of model DT6R, contain 1 liter of deionized water of 10 ℃ in the cup, wherein contain 50ml acetate, with oar shape rod mixing water-hydrogen peroxide cource mixture, speed is 150rpm, takes out the 15ml sample when the time that requires, by the got oxygen in the titration determination sample, for example use automatic Mettler DL25 titration apparatus, use thiosulphate 0.1N.The component of SYNTHETIC OPTICAL WHITNER sensitivity

The component of SYNTHETIC OPTICAL WHITNER sensitivity used herein can be the known any component that mixes in the detergent composition of prior art, in preparation, storage or the use of said composition, in with said composition washing or cleaning operation process, its can with hydrogen peroxide cource or hydroperoxidation.

For the object of the invention, the form that the component of SYNTHETIC OPTICAL WHITNER sensitivity or its part especially can be sprayed component exists, and it is sprayed on the solid detergent composition particle of the present invention.Yet the component of SYNTHETIC OPTICAL WHITNER sensitivity or its part can also other forms exist, and for example as composite grain, or the component of SYNTHETIC OPTICAL WHITNER sensitivity or its part can be included in the base-material particle.

The component of preferred SYNTHETIC OPTICAL WHITNER sensitivity of the present invention comprises spices, enzyme, whitening agent, dyestuff, optical white, dispersion agent, dirt release agent, especially comprise can be oxidized functional group's any of these component of thiazolinyl, aldehyde radical or amido for example.The component that is used for the SYNTHETIC OPTICAL WHITNER sensitivity that is fit to of the present composition is described in hereinafter.Detergent composition

Detergent composition of the present invention is solid laundry, wash up or hard-surface cleaning composition preferably, most preferably laundry or dishwashing compositions.Said composition is particle form preferably, but the present invention also estimates to use sheet, bar and the pie form that is preferably prepared by the particle component.

Said composition preferably comprises particle, and wherein at least 60%, more preferably at least 80% weight has mean particle size, by weight, is 600 microns-1400 microns, and preferred 700 microns-1100 microns, or even 750-1000 micron.Preferred said composition comprises and is less than 20%, or even less than 10%, or has granularity even less than 5% weight and be lower than 300 microns, or even be lower than 425 microns or even be lower than 600 microns particle component; Also preferred said composition comprises, and by the weight of said composition, is less than 20% or even less than 10% or have granularity greater than 1700 microns even less than 5%, or even greater than 1400 microns or even greater than 1180 microns particle component.

Said composition can comprise agglomeration and/or spraying drying with the known any method preparation of prior art, as described hereinly thus mixes or sprays some component.The preparation of preferred said composition is by mixing all or part particle, comprises by those of agglomeration or spraying drying preparation, adds tackiness agent then and with particle with tackiness agent mixes or agglomeration forms preferred agglomerant detergent particles.They can have the granularity of requirement, or they can be sized the particle that obtains desired particle size.Thus, the mixed composition that preferably contains hydrogen peroxide cource is not mixed together agglomeration with other particles and tackiness agent.

Said composition is solid detergent preferably, and preferably its density is at least 350g/l, more preferably 500g/l at least, or even 580g/l at least.

Also can contain the aucillary detergent component according to composition of the present invention.The definite character of these auxiliary components and its incorporation will depend on the physical form of composition or component and the definite classification of its washing operation that is used for.

It is highly preferred that one or more bleach-activating agents as the auxiliary components existence as mentioned below.

In one embodiment of this invention, preferred detergent composition of the present invention contains one or more anion surfactants and silico-aluminate washing assistant, preferably having only minor amount of silicon aluminate washing assistant and anion surfactant thus is intimate mixture, be anion surfactant be less than total amount 50% or even less than 30%, silico-aluminate be less than total amount 50% or even less than 30%; Even preferably in intimate mixture, be substantially free of anion surfactant and silico-aluminate washing assistant.Thus, preferred said composition comprises at least two kinds of independent particles that comprise anion surfactant or silico-aluminate.For the object of the invention, " intimate mixture " meaning is that the component of two or more compositions is evenly dispersed in component or the particle basically.Promptly find to have improved thus the solvability and/or the dispersiveness of composition.

In another embodiment of the invention, preferred composition only comprises the silico-aluminate washing assistant of low amount, weight by composition, for example be lower than 10% or even be lower than 5%, preferred composition comprises the washing assistant of highly water-soluble thus, for example Trisodium Citrate or citric acid, carbonate and/or crystalline layered silicate.

Also preferred said composition comprises as builder system or its a part of agglomerate, it comprises 0.5%-80% weight crystal layered silicate, preferred NaSKS-6, with 10%-70% weight tensio-active agent, the preferred anionic tensio-active agent by the weight of agglomerate, preferably is less than 10% free-water thus, more preferably 30%-60% (weight) crystalline layered silicate, and 20%-50% (weight) anion surfactant.The foaming component

Highly preferred this detergent composition comprises the foaming component, preferably comprises when contact with water the acid source and the alkali source of the formation gas that can one reacts, and particularly reacts the carbon dioxide that forms by organic carboxyl acid and carbonate source.For the object of the invention, the composition of foaming component can exist in the intimate mixture with another kind of composition, and preferably particle form maybe can be present in the independent particle.

Preferred foaming component is the particle component, and by weight, its mean particle size is 700 microns-1400 microns, preferred 750 microns-1100 microns, preferably comprises acid source and alkali source.

Preferred foaming component is substantially free of water, preferably makes water closely not mix with foaming component or its part, or except raw material self moisture content, does not have water.Generally, the water-content in the intimate mixture that contains the foaming component is lower than 5% of total particle weight, preferably is lower than 3%, more preferably less than 1.5%, is preferably obtained by dry powder compacting or pressurization agglomeration.

These preferred dry effervescent granules produce carbonic acid gas very apace, have quickened the dispersion and the dissolution rate of particulate composition thus.Particulate composition within a short period of time of the present invention that comprises dry effervescent granules as described herein and under the lower situation of effervescent granules/material total amount, allowing particulate composition to disperse and being dissolved in the water and guaranteeing fast and more effectively to give in the washing provides detergent ingredients.

The suitable acid that the present invention uses comprises SOLID ORGANIC, mineral or mineral acid, its salt or derivatives thereof or its mixture.Preferred this acid is one, two or three protonic acids.This acid comprises list or poly carboxylic acid, optimization citric acid, adipic acid, pentanedioic acid, 3chetoglutaric acid, citromalic acid, tartrate, toxilic acid, fumaric acid, oxysuccinic acid, succsinic acid, propanedioic acid.Their sour form is preferably used in this acid, preferably uses their anhydrous form, or its mixture.Derivative also comprises the ester that this is sour.

Foaming component or its raw material preferred package carbonate containing source comprise carbonate, supercarbonate and percarbonate, especially supercarbonate and/or carbonate.The carbonate that is fit to that the present invention uses comprises salt of wormwood, lithium, sodium and saleratus, lithium, sodium etc., wherein preferred yellow soda ash and potassium.The supercarbonate that is fit to that the present invention uses comprises any alkali metal hydrocarbonate, and as lithium, sodium, potassium etc., wherein sodium bicarbonate and potassium are preferred.Supercarbonate can be preferable over carbonate, and is more effective because they are weight, and promptly the supercarbonate of similar weight has bigger CO2 " deposit " than carbonate.Yet the selection of carbonate in dry effervescent granules or supercarbonate or its mixture can be depending on the desired pH of water-bearing media of the dry effervescent granules of dissolving.For example in water-bearing media, require high relatively pH (for example being higher than pH9.5), the preferred mixture that uses carbonate separately or use carbonate and supercarbonate, wherein the content of carbonate is higher than the content of supercarbonate, the weight ratio of general carbonate and supercarbonate is 0.1-10, more preferably 1-5, most preferably 1-2.

This effervescent granules also can comprise tackiness agent, comprises tensio-active agent, for example negatively charged ion and nonionogenic tenside.

The preferred content of foaming component in the present composition is 0.5%-60% weight, preferred 2%-50%, more preferably 5%-45%, preferably make and the content of acid constituents, be 0.3%-40% by the weight of composition, more preferably 1.0%-35%, or even 2%-25%, or even to 15%.Bleach-activating agent

Said composition preferably comprises bleach-activating agent, and preferred package contains organic peroxyacid bleach precursor.Preferred said composition comprises at least two kinds of peroxyacid bleach precursors as defined herein, preferred at least a hydrophobic peroxyacid bleach precursor and at least a hydrophilic peroxyacid bleach precursor.This precursor and hydrogen peroxide cource situ reaction produce organic peroxide acid then.

Bleach-activating agent can be in addition, or comprise the ready-formed peroxyacid bleach in addition.

Preferred bleach-activating agent is present in the particle component of the present composition.Preferred its exists as independent composite grain.In addition, bleach-activating agent or its part can be present in the basic particle of washing composition.

Preferably, at least a bleach-activating agent, preferred peroxyacid bleach precursor exists with the particle component, and by weight, its mean particle size is 600 microns-1400 microns, preferred 700 microns-1100 microns.More preferably, all activators are present in one or more particle components of the average particle size with regulation.

Thus, preferably at least 80%, preferred at least 90% or even at least 95% or even basically 100% component that comprises bleach-activating agent have 300 microns-1700 microns of granularities, preferred 425 microns-1400 microns.

Hydrophobic peroxyacid bleach precursor preferably includes the compound with oxygen-Phenylsulfonic acid alkali as described herein, preferred NOBS, DOBS, LOBS and/or NACA-OBS.

Hydrophilic peroxyacid bleach precursor preferably comprises TAED as described herein.Peroxyacid bleach precursor

Peroxyacid bleach precursor is the compound that produces peroxy acid in crossing hydrolysis reaction with hydroperoxidation.Usually, peroxyacid bleach precursor is expressed from the next:

Wherein, L is a leavings group, and X is any functional group substantially, makes the peroxy acid structure that produces when crossing hydrolysis be:

For the object of the invention, hydrophobic peroxyacid bleach precursor produces the following formula peroxy acid, and wherein X is the group that comprises at least 6 carbon atoms, and hydrophilic peroxyacid bleach precursor produces the peroxyacid bleach of following formula, and wherein X is the group that comprises 1-5 carbon atom.

In detergent composition weight, O.5-20% the content of peroxyacid bleach precursor compound be preferably, more preferably 1-15%, most preferably 1.5-10%.Hydrophilic and hydrophobic bleach agent precursor are when existing, and its ratio is preferably 10: 1-1: 10, more preferably 5: 1-1: 5, or even 3: 1-1: 3.

Suitable peroxyacid bleach precursor compound comprises one or more N-or O-carboxyl groups usually, and this precursor can be selected from type widely.Suitable type comprises the acylated derivatives of acid anhydrides, ester, imide, lactan and imidazoles and oxime.The example of the useful matter in these classes is disclosed in GB-A-1586789.Suitable ester is disclosed in GB-A-836988,864798,1147871,2143231 and EP-A-0170386.Leavings group

Leavings group hereinafter referred to as the L group must have enough reactivities to the hydrolysis reaction of crossing that occurs in the Best Times section (for example cycles of washing).But if L is too active, this activator will be difficult to stably be used for bleaching composition.

Preferred L group is selected from following radicals or its mixture:

Wherein, R ¹Be alkyl, aryl or the alkaryl that comprises 1-14 carbon atom, R ³For comprising the alkyl chain of 1-8 carbon atom, R ⁴Be H or R ³, Y is H or solubilization radical.R ¹, R ³And R ⁴In appoint-kind can be replaced by any functional group basically, comprise for example alkyl, hydroxyl, alkoxyl group, halogen, amino, nitrosyl radical, amido and ammonium or alkyl ammonium group.

Preferred solubilization radical is-SO ₃ ^-M ⁺,-CO ₂ ^-M ⁺,-SO ₄ ^-M ⁺,-N ⁺(R ³) ₄X ^-With 0＜--N (R ³) ₃, most preferably-SO ₃ ^-M ⁺With-CO ₂ ^-M ⁺, wherein, R ³For comprising the alkyl of 1-4 carbon atom, M is for providing deliquescent positively charged ion to bleach-activating agent, and X is for providing deliquescent negatively charged ion to bleach-activating agent.Preferred M is the ammonium cation of basic metal, ammonium or replacement, most preferably sodium and potassium, and X is halogen, hydroxide radical, methylsulfate or acetic acid anion.Alkyl percarboxylic acids bleach precursor

Alkyl percarboxylic acids bleach precursor forms percarboxylic acids when crossing hydrolysis.Preferred such precursor provides peracetic acid when crossing hydrolysis.

Preferred imide-type alkyl peroxycarboxylic acid precursors compound comprises N, N, and N ', N '-tetra-acetylatedization Alkylenediamine, wherein, alkylidene group comprises 1-6 carbon atom, and particularly wherein alkylidene group comprises those compounds of 1,2 and 6 carbon atom.Preferred especially tetraacetyl ethylene diamine (TAED) is as hydrophilic peroxyacid bleach precursor.

Other preferred alkyl peroxycarboxylic acid precursors comprises 3,5,5-trimethyl acetyl oxygen base benzene sulfonic acid sodium salt (different-NOBS), acyloxy benzene sulfonic acid sodium salt in the ninth of the ten Heavenly Stems (NOBS), acetoxyl group benzene sulfonic acid sodium salt (ABS) and penta-acetyl glucose.The alkyl peroxy acids precursor that acid amides replaces

The alkyl peroxy acids precursor compound that acid amides replaces is applicable to the present invention, comprises the compound of following general formula:

R wherein ¹Be aryl or alkaryl with about 1-14 carbon atom, R ²Be alkylidene group, arylidene and the alkarylene that contains 1-14 the carbon atom of having an appointment, R ⁵Be H or alkyl, aryl or the alkaryl that contains 1-10 carbon atom, L can be any leavings group basically.R ¹Preferably contain 6-12 the carbon atom of having an appointment, R ²Preferably contain 4-8 the carbon atom of having an appointment.R ¹Can be the straight or branched alkyl, contain the aryl of side chain, substituting group or the two replacement or alkaryl and can obtain that described natural source comprises for example butter fat by synthetic source or natural source.R ²The similar structures variant also allow.R ²Can comprise alkyl, aryl, wherein said R ²Also can contain halogen, nitrogen, sulphur and other typical substituting group or organic compound.R ⁵Preferably H or methyl.R ¹And R ⁵Should not contain altogether and surpass 18 carbon atoms.The bleach activating immunomodulator compounds that such acid amides replaces is described among the EP-A-0170386.Preferred R ¹And R ⁵Form ring structure with nitrogen and carbon atom.

The preferred embodiment of this class bleach precursor comprises the peroxyacid precursor compound that acid amides replaces; be selected from (6-decoyl amino-caproyl) the oxygen base benzene sulfonate that is described among the EP-A-0170386; (6-caprinoyl amino-caproyl) oxygen base benzene sulfonate; with highly preferred (the amino caproyl of 6-nonanoyl) oxygen base benzene sulfonate and their mixture.Peroxybenzoic acid precursors

The peroxybenzoic acid precursors compound provides peroxybenzoic acid when crossing hydrolysis.Suitable O-acylations peroxybenzoic acid precursors compound comprises and replacing and not unsubstituted benzoyloxy benzene sulfonate; and Sorbitol Powder, glucose and all sugar are carried out benzoylated product with benzoylation reagent; those compounds of imide-type comprise the urea that N-benzoyl succinimide, four benzoyl quadrols and N-benzoyl replace.Suitable imidazole type peroxybenzoic acid precursors comprises N-benzoyl imidazoles and N-benzoyl benzo imidazoles.The peroxybenzoic acid precursors that contains the N-acyl group that other is useful comprises N-benzoyl pyrrolidone, dibenzoyl taurine and benzoyl Pyrrolidonecarboxylic acid.The positively charged ion peroxyacid precursor

Positively charged ion peroxyacid precursor compound produces the positively charged ion peroxy acid when crossing hydrolysis.

Usually, the positively charged ion peroxyacid precursor is by with positively charged functional group such as ammonium or alkyl ammonium group, and preferred ethyl or ammonium methyl group replace the peroxy acid part of suitable peroxyacid precursor compound and form.The positively charged ion peroxyacid precursor has suitable negatively charged ion such as halogen ionic salt is present in the solid detergent composition as a kind of usually.

The peroxyacid precursor compound that this positively charged ion replaces can be the derivative of peroxybenzoic acid or its replacement, precursor compound as the aforementioned.Perhaps, the peroxyacid precursor compound can be the alkyl peroxy acids precursor of alkyl peroxycarboxylic acid precursors compound as described below or acid amides replacement.

The positively charged ion peroxyacid precursor is stated in following document: US4,904,406; 4,751,015; 4,988,451; 4,397,757; 5,269,962; 5,127,852; 5,093,022; 5,106,528; U.K.1,382,594; EP475,512; 458,396 and 284,292; JP87-318,332.

The example of preferred cation peroxyacid precursor is stated in UK number of patent application 9407944.9 and US number of patent application 08/298903,08/298650,08/298904 and 08/298906.

Suitable positively charged ion peroxyacid precursor comprises alkyl that ammonium or alkylammonium replace or in the tetra-acetylated glucose benzoyl peroxide of benzoyloxy benzene sulfonate, N-acidylate hexanolactam and single benzoyl any.Preferred N-acylations hexanolactam cationoid peroxyacid precursor comprises trialkyl ammonium methylene-benzene formyl radical caprolactam and trialkyl ammonium methylene radical alkyl hexanolactam.Benzoxazine organic peroxy acid precursor

What also be suitable for is benzoxazine type precursor compound, EP-A-332 for example, in 294 and EP-A-482,807 disclosed those, particularly have the compound of following formula:

Wherein, R ₁Be H, alkyl, alkaryl, aryl or aralkyl.Prefabricated organic peroxide acid

Detergent composition of the present invention except that comprising organic peroxyacid bleach precursor compound or as an alternative also can comprise the ready-formed organic peroxide acid, and in the weight of the present composition, its content is generally 1-15%, more preferably 1-10%,

A preferred class organic peroxy acid compound is the compound with acid amides replacement of following general formula:

Wherein, R ¹Be alkyl, aryl or the alkaryl with 1-14 carbon atom, R ²Be alkylidene group, arylidene and the alkarylene with 1-14 carbon atom, R ⁵For H or have alkyl, aryl or the alkaryl of 1-10 carbon atom.The organic peroxy acid compound that such acid amides replaces is disclosed among the EP-A-0170386.

Other organic peroxide acid comprises diacyl and four acyl peroxides, particularly diperoxy dodecanedioic acid, diperoxy tetradecane diacid and diperoxy Thapsic acid.Single-as and two to cross nonane diacid, single-and two cross undecane dicarboxylic acid and the amino oxy hexanoic acid of crossing of N-phthaloyl also is suitable for the present invention.Dyestuff

The preferred component of the present composition is dyestuff and painted particle or spot grain, and it may be the SYNTHETIC OPTICAL WHITNER sensitivity.Dyestuff used herein can be the aqueous solution or the non-aqueous solution of tinting material or tinting material.Preferred coloring agent is the aqueous solution that comprises tinting material, and it can be any amount to reach the suitable dyeing of detergent particles or spot grain, as mentioned above, preferably makes the content of dye solution reach 2% weight of dyed particles, more preferably reaches 0.5% weight.Dyestuff also can mix with the nonaqueous carrier material, for example comprises the on-aqueous liquid material of nonionogenic tenside.

Randomly, dyestuff also comprises for example organic binder bond material of other components, and it can be non-water liquid.

Tinting material can be any suitable tinting material.The specific examples of the tinting material that is fit to comprises E104-food Huang 13 (quinoline yellow), E110-food Huang 3 (sunset yellow FCF), E131-food indigo plant 5 (patent blue V), ultramarine blue (trade(brand)name), E133-food indigo plant 2 (brilliant blue FCF), E140-natural green 3 (chlorophyll and CHLOROPHYLLINE), E141 and pigment Green 7 (chlorating CuPc).Preferred tinting material can be monastral blue BV lotion (trade(brand)name) and/or Pigmasol Green (trade(brand)name).

Painted detergent particles preferably includes up to 10% or be more preferably up to 2%, or even high to 1% weight dyed particles.Spices

The another kind of preferred component of the present composition is spices or flavor compositions.The present invention can use any flavor compositions, and spices also can be encapsulated.

Preferred spices contains at least a component with lower molecular weight volatile components, and for example molecular weight is 150-450, or preferred 350.

Preferably, the spices component comprises oxygen containing functional group.Preferred functional group is aldehyde, ketone, alcohol or ether functional group or its mixture.

The aliphatic ketone that is fit to for example is:

-2,7,8-trimethylammonium-1-ethanoyl-ring 12 carbon-2,5,7-triolefin

-7-ethanoyl-1,1,6,7-tetramethyl--1,2,3,4,5,6,7,8-octalin

-different the ketone that comes into leaves

-γ-irone

-a-vetivone

The aromatic ketone that is fit to for example is:

-4-(p-hydroxybenzene)-Ding-2-ketone

-1,1,2,4,4,7-hexamethyl-6-ethanoyl-1,2,3,4-tetralin

-benzophenone

-methyl naphthyl ketone

The aliphatic aldehyde that are fit to for example are:

-2-methyl the undecyl aldehyde

-hendecanal

-4 (4 '-methyl-4 '-hydroxyl amyl group)-hexamethylene-3-cyclohexene carboxaldehydes

-7-(formyl radical-5-sec.-propyl-2-methyl bicycle [2.2.2] oct-2-ene

-4-(three ring [5.2.1.0{2,6}] inferior decyls-8)-butyraldehyde

-4-(4 '-methylpent-3-thiazolinyl)-hexamethylene-3-cyclohexene carboxaldehyde

The aromatic aldehyde that is fit to for example is:

-α-basic phenylacrolein

-aubepine

-piperonylaldehyde

-2-phenylpropionaldehyde

-dihydro cinnamon aldehyde

-3-(to tert-butyl-phenyl)-2 methyl propanal

The condensation product that is fit to of aldehyde and amine for example is:

-N-(2,4-dimethyl-3-cyclohexenyl) methylene radical-methyl oaminobenzoate

-N-(3,7-dimethyl-7-hydroxyl-octylene)-methyl oaminobenzoate

-N-(4-(4 '-methyl-4 '-hydroxyl amyl group) hexamethylene-3-thiazolinyl) methylene radical methyl oaminobenzoate

The macrolide Moschus that is fit to for example is:

-dodecanedioic acid glycol ester

-11-oxa-n-Hexadecane lactide

-cyclopentadecane lactide

The preferred spices of the present invention can be High ImpactAccord (" HIA ") the spice oil particle of the starch encapsulate of modification.Preferred HIA spice oil comprises:

4-(2,2,6-3-methyl cyclohexanol-1-thiazolinyl)-2-alkene-4-ketone

(E, Z)-the stillingic acid ethyl ester

6-(with-8) isopropyl quinoline

Acetaldehyde styroyl propyl group acetal

(2-methyl butoxy) acetate 2-propenyl ester

(3-methyl butoxy) acetate 2-propenyl ester

2,6,10-trimethylammonium-9-undecenal

2-pentyloxy-oxyacetic acid allyl ester

Caproic acid 2-propenyl ester

1-octene-3-alcohol

Trans-anethole

(z)-2-methyl-2-butene acid isobutyl ester

Aubepine diethyl acetal 4-(1, the 1-dimethyl ethyl)-phenylpropyl aldehyde 2,6-nonadiene-1-alcohol 3-methyl-5-propyl group-tetrahydrobenzene-1-ketone (Z)-2-Methyl Butyric Acid 3-hexene ester [(3,7-dimethyl-6-octenyl) oxygen base] acetaldehyde lauronitrile 2,4-dimethyl-3-tetrahydrobenzene-1-formaldehyde 1-(2,6,6-trimethylammonium-1,3-cyclohexadiene-1-yl)-2-butylene-1-ketone (E)-1-(2,6,6-trimethylammonium-2-tetrahydrobenzene-1-yl)-and 2-butylene-1-ketone γ-decalactone is trans-4-decenal capraldehyde 1-amyl group cyclopentanone 1-(2,6,6-trimethylammonium 3 tetrahydrobenzene-1-yl)-2 butene-1s-ketone 2,6-dimethyl-g-2-alcohol 1,1 '-oxygen base biphenyl 1-(5,5-dimethyl-1-tetrahydrobenzene-1-yl)-4-amylene-1-ketone ethyl 2-methylbutyrate anthranilic acid ethyl ester 1,3,3-trimethylammonium-2-oxabicyclo [2.2.2] octane oxymethoxyallylbenzene 3-(3-isopropyl phenyl) butyraldehyde methyl 2-octynoate 4-(2,6,6-trimethylammonium-1-tetrahydrobenzene-1-base-3-butene-2-ketone 2-methoxyl group-3-(2-methyl-propyl) pyrazine 6-sec-butyl quinoline isoeugenol tetrahydrochysene-6-(3-pentenyl)-2H-pyran-2-one cis-3-hexenyl methyl carbonic phantol (E)-7,11-dimethyl-3-methylene radical-1,6,10-12 carbon triolefins 2,6-dimethyl-5-heptenal

Six hydrogen 4,7-methylene radical 1,2-indane 1-formaldehyde

2-methyl hendecanal

Methyl 2-octynoate

1,1-dimethoxy-2,2,5-trimethylammonium-4-hexene

The 2 hydroxybenzoic acid methyl esters

1-(5,5-dimethyl-1-tetrahydrobenzene-1-yl) 4-amylene-1-ketone

3,6-dihydro-4 methyl-2-(2-methyl isophthalic acid-propylene)-2H-pyrans

(Z)-3,7-dimethyl-2,6-octadiene nitrile

2, the 6-nonadienal

(Z)-the 6-nonenal

Aldehyde C-9

Octanal

The 2-nonenyl nitrile

Acetate 4-aminomethyl phenyl ester

The γ undecalactone

6, firpene-2-propionic aldehyde falls in 6-dimethyl-2-

4-lactide in the ninth of the ten Heavenly Stems

9-decen-1-ol

Tetrahydrochysene-4-methyl-2-(2-methyl isophthalic acid-propenyl)-2H-pyrans

5 methyl 3 heptanone oxime

3,7-dimethyl octanal

4-methyl-3-decene-5-alcohol

10-undecene-1-aldehyde

2-(1-ethyl propyl)-pyridine

Decahydro spiral shell [furans-2 (3H), 5 '-[4,7] methylene radical [5H] indenes

In addition, spices also can contain fragrance precursor.

In a single day fragrance precursor is exposed to wash conditions, can form the spices component with above-mentioned characteristic.Preferably, fragrance precursor forms the spices component through hydrolysis under aqueous conditions.

The preferred fragrance precursor of the present invention is nonionic or the anionic ester with vinyl carbinol spices of following formula:

Wherein n is 1 or greater than 1 integer; R is selected from C ₁-C ₃₀, preferred C ₁-C ₂₀Straight chain, side chain or cyclic alkyl, thiazolinyl, alkynyl, alkaryl or aryl, and expression is connected to the group on the carboxyl functional group of the carboxylic acid that is used to prepare flavorant ester." and each R is selected from hydrogen or C for each R ', R ₁-C ₂₀Straight chain, side chain or cyclic alkyl, thiazolinyl, alkynyl, alkaryl or aryl." select by this way with R , promptly the molecular weight of vinyl carbinol is 150-350 for R, R ' R.

In the most preferred embodiment, " be hydrogen, a R is hydrogen, methyl or ethyl, and other R are straight chain, side chain or ring-type C for R ' and R ₁-C ₁₀Alkyl or alkenyl.Cis/trans (also the being called Z/E) isomer at the two keys place shown in above in addition in the structure and the steric isomer of above structure also are possible.

Preferred spices component can be selected from Geraniol and/or flores aurantii alcohol ester.Geraniol and vernol are formula HO-CH ₂-CH=C (CH ₃)-CH ₂-CH ₂-CH=C (CH ₃) ₂The trans/cis constitutional isomer of molecule (at 2,3 position of double bond).Heavy metal ion chelating agent

The present composition preferably comprises the heavy metal ion chelating agent as optional ingredient.So-called heavy metal ion chelating agent has been meant the component of chelating heavy metal ion effect at this paper.These components also can have calcium and magnesium sequestering power, but preferably they demonstrate the selectivity in conjunction with heavy metal ion such as iron, manganese and copper.

The content of heavy metal ion chelating agent is generally the 0.005%-10% of present composition weight, preferred 0.1%-5%, more preferably 0.25%-7.5%, most preferably 0.3%-2%.

Be suitable for heavy metal ion chelating agent of the present invention and include organic phosphonates, as amino alkylidenyl many (alkylene phosphonic acids salt), basic metal ethane 1-hydroxyl diphosphonate and nitrilo trimethylene phosphonic salt.

Preferred diethylenetriamine five (methylene phosphonic acid salt), quadrol three (methylene phosphonic acid salt), hexamethylene-diamine four (methylene phosphonic acid salt) and hydroxyl-ethylidene 1 in the above-mentioned substance, 1-diphosphonate, 1,1-hydroxyl ethane di 2 ethylhexyl phosphonic acid and 1,1-hydroxyl ethane dimethylene phosphonic acids.

Other is applicable to that heavy metal ion chelating agent of the present invention comprises nitrilotriacetic acid(NTA) and polyamino carboxylic acid, as ethylenediamine tetraacetic acid (EDTA), ethylenediamine disuccinic acid, quadrol two pentanedioic acids, 2-hydroxyl propylene diamine disuccinic acid or its any salt.

Other is applicable to that heavy metal ion chelating agent of the present invention is an iminodiacetic acid derivatives, as 2-hydroxyethyl oxalic acid or glyceryl iminodiethanoic acid, and as EP-A-317,542 and EP-A-399, described in 133.The present invention also can adopt as EP-A-5126,102 described iminodiethanoic acid-N-2-hydroxypropyl sulfonic acid and aspartic acid N-carboxymethyl N-2-hydroxypropyl-3-sulfonic acid sequestrant.The present invention also can adopt EP-A-509,382 described Beta-alanine-N, N '-oxalic acid, aspartic acid-N, single acetate of N '-oxalic acid, aspartic acid-N-and imino-diacetic succsinic acid sequestrant.

EP-A-476,257 have described the suitable sequestrant based on amino.EP-A-510,311 have described the suitable sequestrant that is obtained by collagen, Keratin sulfate or casein.EP-A-528,859 have described a kind of suitable alkyl imino oxalic acid sequestrant.Pyridine dicarboxylic acid and 2-phosphinylidyne butane-1,2, the 4-tricarboxylic acid also is fit to.Glycine acid amides-N, N '-disuccinic acid (GADS), quadrol-N, N '-two pentanedioic acid (EDDG) and 2-hydroxyl propylene diamine-N, N '-disuccinic acid (HPDDS) also is fit to.

Particularly preferably be diethylene triaminepentaacetic acid(DTPA), quadrol-N, N '-disuccinic acid (EDDS) and 1, the ammonium salt of 1-hydroxyl ethane di 2 ethylhexyl phosphonic acid or its basic metal, alkaline-earth metal, ammonium or replacement, or its mixture.

The sequestrant that particularly comprises amino or amido may be the SYNTHETIC OPTICAL WHITNER sensitivity and be suitable in the present composition.Enzyme

The another kind of highly preferred component that is used for the present composition is one or more additional enzymes.

Preferred additional enzymes material comprises commercially available lipase, at, amylase, neutrality and Sumizyme MP, cellulase, interior living enzyme (endolase), esterase, polygalacturonase, Sumylact L and the peroxidase that is routinely added in the detergent composition.Suitable enzyme is discussed in United States Patent (USP) 3519570 and 3533139 to some extent.

Those proteolytic enzyme that preferred commercially available proteolytic enzyme comprises those proteolytic enzyme of being sold with trade(brand)name Alcalase, Savinase, Primase, Durazym and Esperase by Novo Industries A/S (Denmark), sold with trade(brand)name Maxatase, Maxacal and Maxapem by Gist-Brocades, those proteolytic enzyme of selling by Genencor International and those proteolytic enzyme of selling with trade(brand)name Opticlean and Optimase by Solvay Enzymes.Proteolytic enzyme is pressed the content that composition weight meter can the 0.0001%-4% organized enzyme and is added in the present composition.

Preferably amylase comprises, for example the α-Dian Fenmei that the special bacterial strain by bacillus licheniformis of detailed description obtains among the GB-1269839 (Novo).Preferred commercially available amylase comprises those amylase of for example being sold those amylase and sold with trade(brand)name Termamyl, Duramyl and BAN by Novo IndustriesA/S with trade(brand)name Rapidase by Gist-Brocades.Highly preferred amylase can be those that describe in PCT/US9703635 and WO95/26397 and WO96/23873.

By the weight of composition, amylase adds in the present composition with the content of 0.0001%-2% organized enzyme.

By the weight of composition, lipolytic enzyme can 0.0001%-2%, preferably 0.001%-1%, the most preferably active lipolytic enzyme content existence of 0.001%-0.5%.

Lipase can be obtained by fungi or bacterial origin, for example by the detritus enzyme belong to, the bacterial strain of the generation lipase of Thermomicrobium (Thermomyces) or Rhodopseudomonas obtains, described bacterial strain comprises pseudomonas pseudoalcaligenes or Pseudomonas fluorescens.Lipase chemical or that genetically altered mutation obtains by these bacterial strains also can be used among the present invention.Preferred lipase is obtained by pseudomonas pseudoalcaligenes, and it is described in the European patent EP-B-0218272 that authorizes.

The another kind of preferred lipase of the present invention is as described in European patent application EP-A-0258068, be the gene that obtains by fetal hair detritus bacterium by the clone and express the lipase that this gene obtains in as the host at aspergillus oryzae, it is from Novo Industri A/S Bagsvaerd, Denmark, Lipolase is purchased with trade(brand)name.This lipase also is described among the US4810414 of the Huge-Jensen of on March 7th, 1989 promulgation etc.White dyes

The present composition also preferably contains the hydrophilic white dyes as some above-mentioned type of 0.005% to 5% (weight) of having an appointment.

Can be used for hydrophilic white dyes of the present invention and have the following formula structure:

R wherein ₁Be selected from anilino, N-2-pair-hydroxyethyl and NH-2-hydroxyethyl; R ₂Be selected from N-2-pair-hydroxyethyl, N-2-hydroxyethyl-N-methylamino-, morpholino, chlorine and amino; With M be salt-forming cation such as sodium or potassium.

In following formula, R ₁Be anilino, R ₂Be N-2-two-when hydroxyethyl and M were positively charged ion such as sodium, whitening agent was 4,4 '-two [(4-anilino-6-(N-2-two-hydroxyethyl)-guanamine-yl) amino]-2,2 '-Stilbene disulfonic acid and disodium salt.Such special whitening agent can be bought from Ciba-Geigy company according to trade(brand)name Tinopal-UNPA-GX commercial.Tinopal-CBS-X and Tinopal-UNPA-GX are the preferred hydrophilic white dyess that can be used in the detergent composition of the present invention.

In following formula, R ₁Be anilino, R ₂Be N-2-hydroxyethyl-N-2-methylamino-and M when being positively charged ion such as sodium, whitening agent is 4,4 '-two [(4-anilino-6-(N-2-hydroxyethyl-N-methylamino-)-guanamine-yl) amino]-2,2 '-Stilbene disulfonic acid disodium salt.Such special whitening agent can be bought from Ciba-Geigy company according to trade(brand)name Tinopal 5BM-GX in commerce.

In following formula, R ₁Be anilino, R ₂Be morpholino and M when being positively charged ion such as sodium, whitening agent is 4,4 '-two [(4-anilino-6-morpholino-guanamine-yl) amino]-2,2 '-Stilbene disulfonic acid sodium salt.Such special whitening agent can be bought from Ciba-Geigy company is commercial according to trade(brand)name Tinopal-DMS-X and Tinopal AMS-GX.Optical white

Optical white is the preferred component of the present composition.The preferred optical white of the present invention comprises the compound with porphines or porphyrin structure.

In the literature, porphines and porphyrin are to use as different name, but porphines is represented the simplest without any substituent porphyrin routinely; Its mesoporphyrin is the subclass of porphines.In this application, the porphines of indication comprises porphyrin.

The porphines structure optimization comprises metallic element or positively charged ion, preferred Ca, Mg, P, Ti, Cr, Zr, In, Sn or Hf, more preferably Ge, Si or Ga, or more preferably Al, most preferably Zn.

Preferred light SYNTHETIC OPTICAL WHITNER compound or composition are selected from following substituting group and are replaced: alkyl such as methyl, ethyl, propyl group, the tertiary butyl and aromatic ring system such as pyridyl, pyridyl-N-oxide compound, phenyl, naphthyl and anthryl part.

Optical white compound or component can have as substituent solubilizing group.In addition, or in addition, optical white can comprise can solubilising photobleaching compound the polymerization component, for example PVP, PVNP, PVI or its multipolymer or its mixture.

Highly preferred photobleaching compound is the compound with phthalocyanine structure, and it preferably has above-mentioned metallic element or positively charged ion.

Metal phthalocyanine and their derivative have the structure shown in Fig. 1 and/or Fig. 2, and wherein the atom site of phthalocyanine structure is conventional numbering.

Phthalocyanine can be substituted, for example at 1-4, and 6,8-11,13,15-18,20,22-25,27 the substituted phthalocyanine structure in one or more atom sites place.Tensio-active agent

The present composition preferably contains one or more tensio-active agents, and these tensio-active agents are selected from anion surfactant, nonionogenic tenside, cats product, amphoterics, zwitterionics and its mixture.

Be issued to the US3 of Laughlin and Heuring on December 30th, 1975, provided the general catalogue of negatively charged ion, nonionic, both sexes and zwitterionics class and the kind of these tensio-active agents in 929,678.Other example is given in following document: " tensio-active agent and washing composition " (I volume and II volume, Schwartz, Perry and Berch).The catalogue of suitable cats product is given the US4 that is issued to Murphy on March 31st, 1981, in 259,217.

Both sexes and zwitterionics generally are to be used in combination with one or more negatively charged ion and/or nonionogenic tenside when existing.Anion surfactant

Preferably comprise additional anion surfactant according to composition of the present invention.Any basically anion surfactant that is used for the decontamination purpose all can be included in this detergent composition.These can comprise anion sulfate, sulfonate, carboxylate salt and sarcosinate surfactant (for example, comprise sodium, potassium, ammonium and substituted ammonium salt, as one, two and triethanolamine salt).Preferred anionic vitriol and sulfosalt surfactant.

Highly preferred surfactant system comprises sulfonate as described herein and sulfate surfactant, preferred straight or branched alkylbenzene sulfonate and alkyl ethoxy sulfate, the described cats product of preferred combination such as text.

Other anion surfactant comprises isethionate, as fatty acid amide, alkyl succinate and the alkyl sulfo succinate of acyl isethinate, N-ethanoyl taurate, methylamino esilate, monoesters (the particularly saturated and unsaturated C of sulfosuccinate ₁₂-C ₁₈Monoesters), the diester of sulfosuccinate (particularly saturated and unsaturated C ₆-C ₁₄Diester), N-acyl sarcosinate.Resinous acid and hydrogenated resin acid also suit, as rosin, staybelite, and the resinous acid and the hydrogenated resin acid that are present in butter or obtain by butter.The anion sulfate acid salt surfactant

Be applicable to that anion sulfate tensio-active agent of the present invention comprises straight chain and side chain primary and secondary alkyl-sulphate, alkyl ethoxy sulfate, fatty oil acylglycerol vitriol, alkylphenol oxygen Vinyl Ether vitriol, C ₅-C ₁₇Acyl group-N-(C ₁-C ₄Alkyl) and-N-(C ₁-C ₂Hydroxyalkyl) vitriol of glucosamine sulfate and alkyl polysaccharide is as the vitriol (compound of nonionic non-sulfuric acid salinization is described hereinafter) of alkyl polyglucoside.

Alkyl sulfate surfactant is preferably selected from straight chain and side chain uncle C ₁₀-C ₁₈Alkyl-sulphate, more preferably C ₁₁-C ₁₅Branched-chain alkyl vitriol and C ₁₂-C ₁₄Straight-chain alkyl sulfate.

Alkyl ethoxy sulfate surfactant is preferably selected from per molecule by the C of 0.5-20 moles of ethylene oxide ethoxylation ₁₀-C ₁₈Alkyl-sulphate.More preferably, alkyl ethoxy sulfate surfactant be per molecule by 0.5-7, the C of the oxyethane ethoxylation of preferred 1-5 mole ₁₁-C ₁₈, C most preferably ₁₁-C ₁₅Alkyl-sulphate.

The particularly preferred aspect of the present invention is to adopt the mixture of preferred alkyl-sulphate and/or sulfonate and alkyl ethoxy sulfate surfactant.This mixture is stated in following document: PCT number of patent application WO93/18124.The anion sulfoacid salt surfactant

Be applicable to that anionic sulphonate tensio-active agent of the present invention comprises C ₅-C ₂₀Linear alkylbenzene sulfonate, alkyl ester sulfonate, C ₆-C ₂₂Uncle or secondary paraffin sulfonate, C ₆-C ₂₄Alkene sulfonate, sulfonated poly carboxylic acid, alkyl glycerol sulfonate, fatty acyl group glycerol sulfonate, fatty oil acylglycerol sulfonate and its any mixture.The anionic carboxylic acid salt surfactant

Suitable anionic carboxylate tensio-active agent comprises alkyl ethoxy carboxylate, alkyl polyethoxye multi-carboxylate's tensio-active agent and soap (" alkyl carboxyl " soap), the secondary soap class of particularly as described herein some.

Suitable alkyl ethoxy carboxylate comprises having formula RO (CH ₂CH ₂O) _xCH ₂COO ^-M ⁺Those, wherein, R is C ₆-C ₁₈Alkyl, x are 0-10, and the distribution of ethoxylate is such, by weight, x be 0 amount of substance less than 20%, M is a positively charged ion.Suitable alkyl polyethoxye multi-carboxylate tensio-active agent comprises having formula RO-(CHR ₁-CHR ₂-O)-R ₃Those, wherein R is C ₆-C ₁₈Alkyl, x is 1-25, R ₁And R ₂Be selected from hydrogen, formyloxy, amber acidic group, hydroxy succinic acid base and its mixture, R ₃Be selected from hydrogen, have replacement or unsubstituted alkyl and its mixture of 1-8 carbon atom.

Suitable soap class tensio-active agent comprises secondary soap surfactant, and it comprises the carboxyl unit that links to each other with secondary carbon(atom).Being preferred for secondary soap surfactant of the present invention is to be selected from following water-soluble substances: the water-soluble salt that the water-soluble salt of the water-soluble salt of 2-methyl isophthalic acid-undecanoic acid, 2-ethyl-1-capric acid, the water-soluble salt of 2-propyl group-1-n-nonanoic acid, 2-butyl-1-are sad and the water-soluble salt of 2-amyl group-1-enanthic acid.

Some soap class also can be used as suds suppressor and adds.The basic metal sarcosinate surfactant

Other suitable anion surfactant is formula R-CON (R ¹) CH ₂The basic metal sarcosinate of COOM, wherein R is C ₅-C ₁₇-straight or branched alkyl or alkenyl, R ¹Be C ₁-C ₄Alkyl, M are alkalimetal ion.Preferred examples is the myristyl and the oleoyl methyl sarcosinate of its sodium-salt form.Alkoxy-based non-ionic surface active agent

Basically any alkoxy-based non-ionic surface active agent all is applicable to the present invention.Preferred ethoxylation and propoxylation nonionogenic tenside.

The preferred alkoxylated tensio-active agent can be selected from the alkylphenol condensation of non-ionic type, the ethoxylated alcohol of non-ionic type, the ethoxylated/propoxylated fatty alcohol of non-ionic type, ethoxylated/propoxylated condenses non-ionic type and propylene glycol, and ethoxylation condensation product non-ionic type and propylene oxide/ethylenediamine adduct.Nonionic alcohol alcoxylates tensio-active agent

The condensation product of Fatty Alcohol(C12-C14 and C12-C18) and 1-25 mole alkylene oxide, particularly oxyethane and/or propylene oxide is applicable to the present invention.The alkyl chain of Fatty Alcohol(C12-C14 and C12-C18) can be straight or branched, and uncle or secondary comprises 6-22 carbon atom usually.Particularly preferably be the every mol of alcohol of alkyl and the condensation product of 2-10 moles of ethylene oxide with 8-20 carbon atom.The nonionic polyhydroxy fatty acid amide surfactant

Be applicable to that polyhydroxy fatty acid amide of the present invention is to have those of following structural formula: R ²CONR ¹Z, wherein R ₁Be H, C ₁-C ₄Alkyl, 2-hydroxyethyl, 2-hydroxypropyl, oxyethyl group, propoxy-or its mixture, preferred C ₁-C ₄Alkyl, more preferably C ₁Or C ₂Alkyl, most preferably C ₁Alkyl (being methyl); R ₂Be C ₅-C ₃₁Alkyl, preferred straight chain C ₅-C ₁₉Alkyl or alkenyl, more preferably straight chain C ₉-C ₁₇Alkyl or alkenyl, most preferably straight chain C ₁₁-C ₁₇Alkyl or alkenyl, or its mixture; Z is the polyhydroxy alkyl with straight-chain alkyl chain of at least 3 hydroxyls that are directly connected on the chain, or its alkoxy derivative (preferred ethoxylation or propoxylation).Z preferably by reducing sugar in reductive amination process, derive to.More preferably Z is a glycosyl.The nonionic fatty acid amide surfactant

Suitable fatty acid amide surfactant comprises those with following formula: R ⁶CON (R ⁷) ₂, R wherein ⁶For comprising 7-21, the alkyl of preferred 9-17 carbon atom, each R ⁷Be selected from hydrogen, C ₁-C ₄Alkyl, C ₁-C ₄Hydroxyalkyl and-(C ₂H ₄O) _xH, wherein x is 1-3.The nonionic alkyl polysaccharide surfactant

Be applicable to that alkyl polysaccharide of the present invention is described among the US4565647 of the L1enado that authorized on January 21st, 1986, they have the hydrophobic grouping that contains 6-30 carbon atom, and the hydrophilic polysaccharide group that comprises 1.3-10 sugar unit, for example many glycosides.

Preferred alkyl polyglycoside has following formula:

R ²O (C _nH _2nO) _t(glycosyl) _xR wherein ²Be selected from alkyl, alkyl phenyl, hydroxyalkyl, hydroxyalkyl phenyl and its mixture, wherein alkyl contains 10-18 carbon atom; N is 2 or 3; T is 0-10; X is 1.3-8.This glycosyl is preferably obtained by glucose.Amphoterics

Be used for the amphoterics that the present invention is fit to and comprise amine oxide surfactant and alkyl both sexes carboxylic acid.

Suitable amine oxide comprises formula R ³(OR ⁴) _xN ⁰(R ⁵) ₂Those compounds, R wherein ³Be selected from the alkyl, hydroxyalkyl, acyl group amido propyl group and the alkyl phenyl that contain 8-26 carbon atom, or its mixture; R ⁴Be alkylidene group or the hydroxy alkylidene that contains 2-3 carbon atom, or its mixture; X is 0-5, preferred 0-3; Each R ⁵Be alkyl or the hydroxyalkyl that contains 1-3 carbon atom, perhaps contain the polyoxyethylene group of 1-3 oxyethylene group group.Preferred C ₁₀-C ₁₈Alkyl dimethyl amine oxide and C ₁₀-C ₁₈Acyl group amidoalkyl dimethyl oxidation amine.

The example of suitable alkyl both sexes dicarboxylic acid is Miranol (TM) C2M Conc., by Miranol, and Inc., Dayton, NJ produces.Zwitterionics

Zwitterionics also can add in the detergent composition of the present invention.These tensio-active agents can be described as the derivative of derivative, heterocyclic secondary and the tertiary amine of secondary amine and tertiary amine widely, or the derivative of quaternary ammonium, quaternary phosphine or uncle's sulfonium compound.Trimethyl-glycine and sultaine tensio-active agent are the examples that is used for zwitterionics of the present invention.

Suitable trimethyl-glycine is those compounds with following formula: R (R ') ₂N ⁺R ²COO ^-, wherein R is C ₆-C ₁₈Alkyl, each R ¹Be generally C ₁-C ₃Alkyl, R ²Be C ₁-C ₅Alkyl.Preferred trimethyl-glycine is C ₁₂-C ₁₈Dimethyl Ammonium hexanoate and C ₁₀-C ₁₈Acyl group amido propane (or ethane) dimethyl (or diethyl) trimethyl-glycine.The compound betaine tensio-active agent also is applicable to the present invention.Cats product

The cats product that is fit to that is used for washing composition of the present invention comprises quaternary ammonium surfactant.The preferably single C of quaternary ammonium surfactant ₆-C ₁₆, preferred C ₆-C ₁₀N-alkyl or alkenyl ammonium surfactant, wherein all the other positions of N are replaced by methyl, hydroxyethyl or hydroxypropyl.Preferred monoalkoxyization and bis-alkoxy amine tensio-active agent in addition.

The suitable cats product of another group that can be used for detergent composition of the present invention or its component is the cationic ester tensio-active agent.This cationic ester tensio-active agent is water dispersible preferably, is to comprise at least one ester bond (promptly-COO-) and the compound with surfactant properties of at least one positively charged ion charged group.

Suitable cationic ester tensio-active agent comprises the cholinesterase tensio-active agent, for example is disclosed among the US4228042,4239660 and 4260529.

In a kind of preferred situation, ester bond and positively charged ion charged group are spaced apart base and are separated from each other in surfactant molecule, described spacer is made up of a kind of chain, this chain comprises at least three atoms (i.e. three atom chain lengths), preferred 3-8 atom, more preferably 3-5 atom, most preferably 3 atoms.The atom that forms the spacer chain is selected from carbon, nitrogen and Sauerstoffatom and its any mixture, and condition is that any nitrogen-atoms in described chain or Sauerstoffatom only link to each other with carbon atom in the chain.Therefore, got rid of for example have-O-O-(being superoxide) ,-N-N-and-spacer of N-O-key, and comprise for example having-CH ₂-O-CH ₂-and-CH ₂-NH-CH ₂The spacer of-key.In preferred situation, the spacer chain only comprises carbon atom, and most preferably described chain is a hydrocarbyl chain.Cation mono alkoxylated amines tensio-active agent

This paper it is highly preferred that the cation mono alkoxylated amines tensio-active agent with general formula I:

R wherein ¹Be to contain 6-18 the carbon atom of having an appointment, preferred about 16 carbon atoms of 6-, the most preferably from about alkyl of 6-14 carbon atom or alkenyl; R ²And R ³Each is the alkyl that contains about 3 carbon atoms of 1-independently, preferable methyl, most preferably R ²And R ³It all is methyl; R ⁴Be selected from hydrogen (preferably), methyl and ethyl, X ^-Provide electroneutral negatively charged ion, for example chlorine, bromine, methylsulfate, sulfate radical etc.A is an alkoxyl group, particularly oxyethyl group, propoxy-or butoxy; P is that 0-is about 30, and preferred 2-is about 15, and most preferably 2-about 8.

ApR among the preferred formula I ⁴The p=1 of group and be hydroxyalkyl with no more than 6 carbon atoms, thus-the OH group separated with quaternary nitrogen atoms by no more than 3 carbon atoms.Particularly preferred ApR ⁴Group is-CH ₂CH ₂OH ,-CH ₂CH ₂CH ₂OH ,-CH ₂CH (CH ₃) OH and-CH (CH ₃) CH ₂OH ,-CH ₂CH ₂OH is particularly preferred.Preferred R ¹Group is a straight chained alkyl.Straight chain R with 8-14 carbon atom ¹Group is preferred.

Be used for the highly preferred cation mono alkoxylated amines of another kind of the present invention tensio-active agent and have following formula:

R wherein ¹Be C ₁₀-C ₁₈Alkyl and their mixture, particularly C ₁₀-C ₁₄Alkyl, preferred C ₁₀And C ₁₂Alkyl, X provide any suitable negatively charged ion of charge balance, preferred chlorine or bromine.

As described, the compound of the above-mentioned type comprises wherein oxyethyl group (CH ₂CH ₂O) unit (EO) is by butoxy, isopropoxy [CH (CH ₃) CH ₂O] and [CH ₂CH (CH ₃O] unit (i-Pr) or positive propoxy unit (Pr) or EO and/or Pr and/or the unitary mixture of i-Pr displaced those.

Be used for the content of the cation mono alkoxylated amines tensio-active agent of detergent composition of the present invention, the weight by composition is preferably 0.1%-20%, more preferably 0.2%-7%, most preferably 0.3%-3.0%.Positively charged ion dialkoxy amine tensio-active agent

Positively charged ion dialkoxy amine tensio-active agent preferably has general formula I I:

R wherein ¹Be to contain about 18 carbon atoms of the 8-that has an appointment, preferred about 16 carbon atoms of 10-, the most preferably from about alkyl of about 14 carbon atoms of 10-or alkenyl part; R ²Be the alkyl that contains 1-3 carbon atom, preferable methyl; R ³And R ⁴Can change independently, they are selected from hydrogen (preferably), methyl and ethyl; X-is enough to provide electroneutral negatively charged ion, for example chlorine, bromine, methylsulfate, sulfate radical etc.A and A ' can change independently, respectively are selected from C ₁-C ₄Alkoxyl group, particularly oxyethyl group (promptly-CH ₂CH ₂O-), propoxy-, butoxy and their mixture; P is that 1-is about 30, and preferred 1-is about 4, and q is that 1-is about 30, and preferred 1-is about 4, and most preferably p and q are 1.

Be used for the highly preferred positively charged ion dialkoxy of the present invention amine tensio-active agent and have following formula:

R wherein ¹Be C ₁₀-C ₁₈Alkyl and its mixture, preferred C ₁₀, C ₁₂, C ₁₄Alkyl and its mixture, X provides any suitable negatively charged ion of charge balance, preferred chlorine.About above-mentioned positively charged ion dialkoxy amine formula, because in preferred compound, R ¹Be by (cocounut oil) C ₁₂-C ₁₄Moieties lipid acid obtains, so R ²Be methyl, ApR ³And A ' qR ⁴All are monosubstituted ethoxies.

Be applicable to that other positively charged ion dialkoxy amine tensio-active agent of the present invention comprises the compound of following formula:

R wherein ¹Be C ₁₀-C ₁₈Alkyl, preferred C ₁₀-C ₁₄Alkyl, p are that 1-is about 3 independently, and q is that 1-is about 3, R ²Be C ₁-C ₃Alkyl, preferable methyl, X is a negatively charged ion, particularly chlorine or bromine.

Other compound of the above-mentioned type comprises wherein oxyethyl group (CH ₂CH ₂O) unit (EO) is by butoxy (Bu), isopropoxy [CH (CH ₃) CH ₂O] and [CH ₂CH (CH ₃O] unit (i-Pr) or positive propoxy unit (Pr) or EO and/or Pr and/or the unitary mixture of i-Pr displaced those.Bleaching catalyst

The present composition can contain a kind of bleaching catalyst that contains transition metal.

A kind of bleaching catalyst of suitable type is to comprise the active transition-metal cation of the bleach catalyst with definition such as copper, iron or manganese positively charged ion, have and seldom or not have the active assistant metal positively charged ion of bleach catalyst such as zinc or aluminium cations, with the catalyst system of the sequestrant with catalysis and the defined stability constant of assistant metal positively charged ion, described sequestrant is ethylenediamine tetraacetic acid (EDTA), ethylenediamine tetraacetic (methylene phosphonic acid) and its water-soluble salt particularly.This catalyzer is disclosed in US4, in 430,243.

The bleaching catalyst of other type comprises and is disclosed in US5, the manganese basigamy compound in 246,621 and US5,244,594.Other is described in the European patent application publication No. 549272.When being suitable for when of the present invention, the also bleaching catalyst that can select the present invention to be suitable for.For example, the bleaching catalyst that is fit to is referring to US4, and 246,612 and 5,227,084.Also referring to US5,194,416, it has lectured for example Mn (1,4,7-trimethylammonium-1,4,7-7-triazacyclononane)-(OCH of monokaryon manganese (IV) title complex ₃) ₃(PF ₆).

As the another kind of bleaching catalyst that is disclosed among the US5114606 is the water-soluble complexes of the polyol ligand of manganese (III) and/or the non-carboxylic acid that (IV) and at least has three continuous C-OH groups.Preferred ligand comprises Sorbitol Powder, iditol, galactitol, mannitol, Xylitol, arabitol, adonitol, meso-tetrahydroxybutane, meso-inositol, lactose and its mixture.

U.S. Pat 5114611 has been lectured bleaching catalyst, comprises the title complex of transition metal and non-(greatly) ring ligand, and described transition metal comprises Mn, Co, Fe or Cu.Described ligand has formula:

R wherein ¹, R ², R ³And R ⁴Each can be selected from the alkyl and the aryl of H, replacement, makes each R ¹-N=C-R ²And R ³-C=N-R ⁴Formation five or six-ring.Described ring also can be substituted.B is an abutment, is selected from O, S, CR ⁵R ⁶, NR ⁷And C=O, wherein R ⁵, R ⁶And R ⁷Each can be H, alkyl or aryl, comprises replacing or unsubstituted group.Preferred ligand comprises pyridine, pyridazine, pyrimidine, pyrazine, imidazoles, pyrazoles and triazole ring.Randomly, described ring can be substituted base for example alkyl, aryl, alkoxyl group, halogen and nitro replacement.Particularly preferably be ligand 2,2 '-two pyridine amine.Preferred bleaching catalyst comprise Co, Cu, the two pyridine methane of Mn, Fe-and-two pyridine amine complexes.Highly preferred catalyzer comprises Co (2,2 '-two pyridine amine) Cl ₂, two (different sulfo-cyanato-) two pyridine amine cobalts (II), three pairs of pyridine amine cobalts (II) perchlorate, Co (2,2 '-two pyridine amine) ₂O ₂ClO ₄, two (2,2 '-two pyridine amine) copper (II) perchlorate, three (two-2-pyridine amine) iron (II) perchlorate and its mixture.

Other example comprises the double-core Mn title complex that cooperates with four-N-dentate and two-N-dentate ligand, comprises N ₄Mn ^III(u-O) ₂Mn ^IVN ₄) ⁺[Bipy ₂Mn ^III(u-O) ₂Mn ^IVBipy ₂]-(ClO ₄) ₃

Other bleaching catalyst is described in the following document, for example European patent application publication No. 408,131 (cobalt complex catalyzer), European patent application publication No. 384,503 and 306,089 (metal-porphyrin catalyst), US4,728,455 (manganese/polygamy position polymerization of olefin using catalyst body catalyst), US4,711,748 and European patent application publication No. 224,952 (being adsorbed in the Mn catalyst on the silico-aluminate), US4,601,845 (being loaded with the silico-aluminate of manganese and zinc or magnesium salts), US4,626,373 (manganese/ligand catalyzer), US4,119,557 (iron complex catalyzer), DE2,054,019 (cobalt chelates catalyzer), CA866,191 (salt that contain transition metal), US4,430,243 (sequestrant) and US4 with manganese positively charged ion and on-catalytic metallic cation, 728,455 (gluconic acid Mn catalysts).

Bleaching catalyst generally is to be used for the present composition and method with catalytically effective amount." catalytically effective amount " meaning be this amount no matter under which type of contrast experiment's condition of use, all be enough to strengthen spot or some spots of being paid close attention on bleaching and the removal target substrates.This experiment condition will change according to washing plant type of using and user's custom.Some users select to use very hot water; Other user uses temperature or even cold water in washing operation.Certainly, the catalytic performance of bleaching catalyst will be subjected to the influence of these Considerations, can suitably be adjusted in the amount of the bleaching catalyst that uses in the washing composition of complete formula and the bleaching composition.In practical situation, not limited to, the present composition and method can be conditioned so that provide in wash water solution at least about per active bleaching catalyst of 1/10000000th, preferably provide about 1ppm to about 200ppm catalyzer in washing soln.In order to further specify this point, using under perborate and bleach precursor 40 ℃, the European condition of pH10, about 3 micromole's Mn catalysts are effective.Under U.S.'s condition,, may need concentration to increase 3-5 doubly in order to obtain equifinality.The water soluble detergency promoter compound

Present composition preferred package contains water-soluble washing-aid compound, and by the weight of composition, generally its content in cleaning composition is 1%-80%, preferred 10%-60%, more preferably 15%-40%.

Detergent composition of the present invention preferably comprises phosphatic washing assistant material.Preferred its content is 0.5%-60%, more preferably 5%-50%, more preferably 8%-40%.

Phosphatic washing assistant material preferably includes tetrasodium pyrophosphate or even more preferably anhydrous sodium tripolyphosphate.

Suitable water soluble detergency promoter compound comprises water-soluble monomer multi-carboxylate or its sour form, homopolymerization or copolymerization poly carboxylic acid or its salt, wherein poly carboxylic acid comprises each other the mixture that is no more than at least two carboxyls, borate and aforementioned any compound that two carbon atoms separate open.

Carboxylate salt or multi-carboxy acid salt washing agent can be monomer type or oligomer types, but because Cost And Performance, the multi-carboxylate of preferred monomers type usually.

The suitable carboxylate salt that contains a carboxyl comprises the water-soluble salt and the ether derivant thereof of lactic acid, oxyacetic acid.The multi-carboxylate of containing two carboxyls comprises the water-soluble salt of succsinic acid, propanedioic acid, (ethylidene dioxy base) oxalic acid, toxilic acid, Glyoxylic acid hydrate, tartrate, tartronic acid and fumaric acid and ether carboxylate and sulfinyl carboxylate salt.The multi-carboxylate or its acid that contain three carboxyls comprise particularly water-soluble citrate, aconitate and citraconate, and the succinate derivative, as English Patent 1,379,241 described carboxy methoxy-succinic acid salt, the newborn acyloxy succinate described in the English Patent 1389732, HOII P 7205873 described aminosuccinic acid salt, and English Patent 1,387,447 described oxygen multi-carboxylate material, for example 2-oxa-s-1,1,3-tricarballylic acid salt.The most preferred poly carboxylic acid that contains three carboxyls is a citric acid, and by the weight of composition, preferably its content is 0.1%-15%, more preferably 0.5%-8%.

The multi-carboxylate of containing four carboxyls comprises English Patent 1,261,829 described oxygen disuccinate, 1,1,2,2-ethane tetracarboxylic acid hydrochlorate, 1,1,3,3-propane tetracarboxylic acid salt and 1,1,2,3-propane tetracarboxylic acid salt.Comprise the substituent multi-carboxylate of sulfo group and comprise English Patent 1,398,421 and 1,398,422 and U.S. Pat 3,936,448 described sulfo-succinic acid salt derivatives, and English Patent 1,439,000 described sulfonation pyrolytic Citrate trianion.Preferred multi-carboxylate contain up to the hydroxycarboxylate of 3 carboxyls, Citrate trianion more specifically for per molecule.

The parent acid of monomer or oligomeric multi-carboxylate's sequestrant or can replenish as useful builder component with the mixture of its salt, for example, citric acid or Citrate trianion/citric acid mixture.

The borate washing assistant and can washing composition store or wash conditions under to produce the boratory washing assistant that forms borate substance that contains be the useful water soluble detergency promoter of the present invention.

The suitable example of water-soluble phosphate washing assistant is an alkali metal tripolyphosphates, trisodium phosphate, potassium and ammonium, and sodium orthophosphate and potassium, partially poly-/sodium phosphate, wherein the polymerization degree is about 6-21, and phytate.Be partly dissolved or insoluble washing-aid compound

The present composition can comprise part solubility or insoluble washing-aid compound, presses composition weight meter, and generally its content in cleaning composition is 0.5%-60%, preferred 5%-50%, most preferably 8%-40%.

The example of big water-insoluble washing assistant comprises sodium silicoaluminate.As mentioned above, in a kind of preferred embodiment of the present invention, only there is the small amount of aluminum silicate-like builder.

The aluminosilicate zeolite that is suitable for has unit structure cell formula Na _z[(AlO ₂) _z(SiO ₂) _y]-xH ₂O, wherein z and y are at least 6, and the mol ratio of z and y is 1.0-0.5, and x is at least 5, preferred 7.5-276, more preferably 10-264.Alumino-silicate materials can be hydrated form, and preferably xln contains 10%-28%, preferred 18%-22% combination water.

Aluminosilicate zeolite can be natural product, but preferably synthetic obtaining.Synthetic crystallization type aluminosilicate ion exchange material can be by zeolite A, zeolite B, zeolite P, the X zeolite of registration, and zeolite HS and composition thereof buys.Zeolite A has following formula:

Na ₁₂[(AlO ₂) ₁₂(SiO ₂) ₁₂] xH ₂O wherein x is 20-30, particularly 27.X zeolite has formula: Na ₈₆[(AlO ₂) ₈₆(SiO ₂) ₁₀₆] 276H ₂O.

Zeolite MAP builder is in addition preferred aluminosilicate zeolite.

With composition weight meter, the content of zeolite MAP is 1%-80%, more preferably 15%-40%.

Zeolite MAP is stated in EP384070A (Unilever).It is defined as the ratio with silicon and aluminium and is not more than 1.33, is preferably 0.9-1.33, more preferably the zeolite P type alkali metal aluminosilicate of 0.9-1.2.

Making us interested especially is silicon and the ratio of aluminium is not more than 1.15, is not more than 1.07 zeolite MAP more specifically.

In preferred situation, the granularity of zeolite MAP detergent builders is represented as d ₅₀, its value is 1.0-10.0 μ m, more preferably 2.0-7.0 μ m, most preferably 2.5-5.0 μ m.

d ₅₀Value is meant that 50 weight % particulate diameters are worth less than this.Granularity specifically can be measured or be measured with laser particle size analyzer as the microscope that adopts scanning electronic microscope to carry out by the routine analysis technical measurement.Other determines d ₅₀The method of value is stated in EP384070A.Organic polyhydroxyl compound

Organic polyhydroxyl compound is the preferred annexing ingredient of the present composition, and it preferably exists as the component of any grain fraction, and they play the effect that for example grain fraction is bonded together.So-called organic polyhydroxyl compound looks like here and is meant any basically polymerizable organic compound that is used as dispersion agent, anti redeposition agent or soil-suspending agent in detergent composition usually, be included in any high molecular organic polyhydroxyl compound that is stated as the clay flocculating agent herein, comprise that ethoxylation (gathering) amine of quaternary saltization of the present invention removes great soil group dirt agent/anti redeposition agent.

Press composition weight meter, the incorporation of organic polyhydroxyl compound in detergent composition of the present invention is generally 0.01%-30%, preferred 0.1%-15%, more preferably 0.5%-10%.

The example of organic polyhydroxyl compound comprises water-soluble organic homopolymerization or copolymerization poly carboxylic acid or its salt, and wherein poly carboxylic acid comprises at least two and is no more than the carboxyl that two carbon atoms separate are opened each other.The polymkeric substance of latter's type is disclosed in GB-A-1, in 596,756.The example of this salt be molecular weight 1000-5000 polyacrylate and with the multipolymer of maleic anhydride, this multipolymer has molecular weight 2000-100,000, particularly 40,000-80,000.

Polyamino compound can be used for the present invention, comprises those materials that obtained by aspartate-derived, for example EP-A-305282, EP-A-305283 and EP-A-351629 described those.

Comprising the ter-polymers, particularly molecular-weight average that are selected from toxilic acid, vinylformic acid, poly aspartic acid and vinyl alcohol monomeric unit is 5, and 000-10, those of 000 also are applicable to the present invention.

Other other organic polyhydroxyl compounds that are fit to add in the detergent composition of the present invention comprise derivatived cellulose, as methylcellulose gum, carboxymethyl cellulose, Vltra tears and Natvosol.

Other useful organic polyhydroxyl compound is that polyoxyethylene glycol, particularly molecular weight are 1000-10000, more preferably 2000-8000, most preferably from about those polyoxyethylene glycol of 4000.

The highly preferred polymeric component of the present invention is the U.S. Pat 5415807 according to the U.S. Pat 4968451 of Scheibel etc. and Gosselink etc., particularly according to the cotton and the non-cotton dirt release agent polymkeric substance of U.S. Patent application 60/051517.

Be used for another kind of organic compound of the present invention, it is the dirty dispersion agent/anti redeposition agent of a kind of preferred soil, and it can be ethoxylation positively charged ion monoamine and the diamines with following formula: Wherein X is a non-ionic group, is selected from H, C ₁-C ₄Alkyl or hydroxyalkyl acrylate or ether group and its mixture, a are 0-20, preferred 0-4 (as ethylidene, propylidene, hexa-methylene), and b is 1 or 0; For positively charged ion monoamine (b=0), n is at least 16, and general range is 20-35; For cationic diamine (b=1), n is at least about 12, and general range is about 12-about 42.

Be used for other dispersion agent/anti redeposition agent of the present invention and be described in EP-B-011965, US4659802 and US4664848.Press down foam system

When detergent composition of the present invention is mixed with the composition that is used to machine-wash, can comprise a kind of foam system that presses down, by the weight of composition, its content is 0.01%-15%, preferred 0.02%-10%, more preferably 0.05%-3%.

Being used for the suitable foam that presses down of the present invention is to comprise any basically known defoamer compound, comprises for example polysiloxane defoamers compound and 2-alkyl alkanol defoamer compound.

It is to detergent composition solution that defoamer compound is here looked like, the foaming that produces when particularly stirring this solution or for example inhibiting any compound of puff or its mixture.

Being used for the particularly preferred defoamer compound of the present invention is the polysiloxane defoamers compound, and it is defined as any defoamer compound that comprises the polysiloxane component at this paper.This polysiloxane defoamers compound generally also contains silica component.Used herein and also be that the term " polysiloxane " of industrial common employing comprises the various relative high molecular weight polymers that contain siloxane unit and all kinds alkyl.Preferred polysiloxane defoamers compound is a siloxanes, particularly has the unitary polydimethylsiloxane of trimethyl silyl end-blocking.

Other suitable defoamer compound comprises monobasic aliphatic carboxylic acid and its soluble salt.These substance descriptions are in the US2954347 of the Wayne St.John of mandate on September 27 nineteen sixty.Monobasic aliphatic carboxylic acid and salt thereof as suds suppressor generally have the 10-24 of containing carbon atom, the hydrocarbyl chain of preferred 12-18 carbon atom.The salt that is fit to comprises an alkali metal salt, sodium salt for example, sylvite, and lithium salts and ammonium salt and alkanol ammonium salts.

Other suitable defoamer compound comprises for example high-molecular weight fatty acid ester (as glycerine fatty acid three esters), monohydroxy-alcohol fatty acid ester, aliphatic C ₁₈-C ₄₀Ketone (as stearone), N-alkylation aminotriazine class, as three to six alkyl melamines or two to the tetraalkyl diammonium chloride for triazine, it is that cyanuryl chloride and 2 or 3 moles contain the uncle of 1-24 carbon atom or the reaction product of secondary amine, propylene oxide, distearyl acid amides and single stearyl di(2-ethylhexyl)phosphate basic metal (as sodium, potassium, lithium) salt and phosphoric acid ester.

The preferred foam system that presses down comprises: (a) defoamer compound, and preferred polysiloxane defoamers compound most preferably comprises the polysiloxane defoamers compound of following combination:

(i) polydimethylsiloxane, its content accounts for the 50%-99% of polysiloxane defoamers compound weight, preferred 75%-95%; With

(ii) silicon-dioxide, its content accounts for the 1%-50% of polysiloxane/silicon-dioxide defoamer compound weight, preferred 5%-25%; The incorporation of wherein said silicon-dioxide/polysiloxane defoamers compound is 5%-50%, preferred 10%-40% weight; (b) a kind of compound dispersing agent, most preferably comprise silicone glycol comb copolymer (rakecopolymer), its polyoxyalkylene content is 72%-78%, and the ratio of oxygen ethene and oxypropylene is 1: 0.9-1: 1.1, its content is 0.5%-10%, preferred 1%-10% weight; Particularly preferred the type silicone glycol comb copolymer is DC0544, is purchased with trade(brand)name DC0544 from DOW Corning company; (c) a kind of inertia carrying object compound, most preferably it comprises C ₁₆-C ₁₈Ethoxylated alcohol, its ethoxylation degree are 5-50, preferred 8-15, and its content is 5%-80%, preferred 10%-70% weight.

Particularly preferred granular suds suppressing system is disclosed among the EP-A-0210731, should pressing down foam system, to comprise a kind of polysiloxane defoaming compounds and a kind of fusing point be 50-85 ℃ organic carrier material, wherein the organic carrier material comprises the monoesters of glycerine and a kind of lipid acid, and described lipid acid has the carbochain that contains 12-20 carbon atom.EP-A-0210721 discloses other preferred granular suds suppressing system, and wherein the organic carrier material is lipid acid or the alcohol with the carbochain that contains 12-20 carbon atom, or its mixture, and its fusing point is 45-80 ℃.

Other is highly preferred to press down foam system and comprises polydimethylsiloxane or polysiloxane mixture for example polydimethylsiloxane, silico-aluminate and multi-carboxy acid copolymer, for example lactic acid (laic) and acrylic acid multipolymer.The polymeric dye transfer inhibitor

The present composition also can comprise 0.01%-10%, the polymeric dye transfer inhibitor of preferred 0.05%-0.5% weight.

The polymeric dye transfer inhibitor is preferably selected from multipolymer, polyvinylpyrrolidonepolymers polymers or its mixture of polyamine N-oxide pllymers, N-vinyl pyrrolidone and N-vinyl imidazole, so these polymkeric substance can be cross-linked polymers.The polymerization dirt release agent

The polymerization dirt release agent, hereinafter referred to as " SRA " can randomly be used for the present composition.If you are using, SRA ' s is generally 0.01% to 10.0% of composition weight, is typically 0.1% to 5%, and preferred 0.2% to 3.0%.

The hydrophobic part that preferred SRA ' s generally has the hydrophilic segment that makes hydrophobic fiber such as polyester and nylon surface hydrophilic and is deposited on the hydrophobic fiber and keeps being attached thereto in whole washing and rinse cycle, so it is as the fixture of hydrophilic segment.This can be so that spot easier being cleaned in washing process afterwards that produces subsequently of handling with SRA.

Preferred SRA ' s comprises oligomeric terephthalate, and it generally by comprising the method preparation of at least a transesterify/oligomerization, carries out under metal catalyst such as titanium alkoxide (IV) usually.This ester can use can by one, two, three, four or more position add other monomers preparations of ester structure, certainly, do not form fine and close full crosslinking structure.

SRA ' the s that is fit to comprises the sulfonated products of the ester oligomer that is straight chain basically; it contains oligomer ester skeleton and the oxyalkylene oxygen repeating unit and the allyl group deutero-sulfonation terminal portions covalently bound with skeleton of terephthaloyl, for example described in the U.S. Pat 4968451 of J.J.Scheibel that authorizes in November 6 nineteen ninety and E.P.Gosselink.This ester oligomer can prepare through the following steps: (a) ethoxylation allyl alcohol; (b) product and terephthalic acid dimethyl ester (" DMT ") and 1 that will (a) in two step transesterify/oligomerization process, 2-propylene glycol (" PG ") reacts; (C) in water with the product of (b) and sodium metabisulfite reaction.Other SRA ' s comprises the nonionic end capped 1 in the people's such as Gosselink that authorized on December 8th, 1987 the U.S. Pat 4711730,2-propylidene/polyoxyethylene terephthalic acid polyester, for example by poly-(ethylene glycol) methyl ether, DMT, the product of the transesterify of PG and poly-(ethylene glycol) (" PEG ")/oligomerization preparation.Other SRA ' s example comprises part and the whole end capped oligomer esters of negatively charged ion in the U.S. Pat 4721580 of the Gosselink that authorized on January 26th, 1988, as derive from ethylene glycol (" EG "), PG, DMT and 3, the oligopolymer of 6-two oxa-s-8-hydroxyl perfluorooctane sulfonate; Nonionic end-blocking block polyester oligomeric compound in the U.S. Pat 4702857 of the Gosselink that on October 27th, 1987 authorized, for example by DMT, methyl (Me)-end capped PEG and EG and/or PG preparation, perhaps by DMT, EG and/or PG, the product of the mixture preparation of end capped PEG of Me-and dimethyl-5-sulfoisophthalic acid sodium; With the Maldonado that authorized on October 31st, 1989; negatively charged ion in people's such as Gosselink the U.S. Pat 4877896; especially the end capped terephthalate of sulfo group aroyl; the latter is typical useful SRA ' s in laundry and fabric-conditioning product; one example be by-sulfosalicylic acid list sodium salt, the ester composition of PG and DMT preparation, but randomly preferably also contain the PEG of adding; for example, PEG3400.

SRA ' s also comprises: the simple copolymerization block thing of ethylene terephthalate or terephthalic acid propylene glycol ester and polyoxyethylene or polyoxypropylene terephthalate, referring to the U.S. Pat 3959230 of the Hays on May 25th, 1976 and the U.S. Pat 3893929 of the Basadur on July 8th, 1975; Derivatived cellulose such as the hydroxy ethers cellulose polymer compound bought from Dow by METHOCEL; C ₁-C ₄Alkylcellulose and C ₄Hydroxy alkyl cellulose is referring to the people's such as Nicol on December 28th, 1976 U.S. Pat 4000093; And methyl cellulose ether, it is about 1.6-2.3 that its each anhydroglucose unit has average substitution degree (methyl), and the soltion viscosities of measuring under 20 ℃ by 2% the aqueous solution are about 80-120 centipoise.This material can be buied by METOLOSESMi00 and METOLOSE SM200, and they are the trade(brand)names by the methyl cellulose ether of Shin-etsu Kagaku Kogyo KK production.

Another kind of SRA ' s comprises: (I) use vulcabond coupler and polyester construction banded nonionic terephthalate, referring to people's such as people's such as Violland U.S. Pat 4201824 and Lagasse U.S. Pat 4240918; (II) have the SRA ' s of carboxylicesters end group, it transforms terminal hydroxy group and becomes the trimellitate preparation by trimellitic acid 1,2-anhydride is added among known SRA ' s.By suitable selecting catalyst, trimellitic acid 1,2-anhydride forms the end group banded key with polymkeric substance, and this is to carry out by the isolated carboxylicesters of trimellitic acid 1,2-anhydride rather than by opening the acid anhydride key.Nonionic or negatively charged ion SRA ' s can be used as starting raw material, as long as have can esterified hydroxyl end groups for they, referring to people's such as Tung U.S. Pat 4525524.Other type comprises: (III) link the SRA ' s based on the negatively charged ion terephthalate of urethanes, referring to people's such as Violland U.S. Pat 4201824.Other optional ingredient

Other optional ingredient that is fit to be included in the present composition comprises colorant and filling salt, and sodium sulfate is preferred filling salt.

Highly preferred composition contains the 2%-10% weight organic acid of having an appointment, optimization citric acid.Can also preferably there be combined carbon hydrochlorate, a small amount of (for example being lower than about 20% weight) neutralizing agent, buffer reagent, phase modifier, hydrotropic agent, enzyme stabilizers, polyacid, foaming regulator, opalizer, antioxidant, sterilant and dyestuff, for example those (they quote for referencial use at this paper) of describing in the U.S. Pat 4285841 of the Barrat that authorizes on August 25th, 1981 etc.The form of composition

The present composition can pass through prepared in various methods, comprise all cpds that will comprise in the detergent component do mix, agglomeration, compacting or spraying drying, or the mixing of these technology.

The present composition can adopt various physical form, comprises liquid, but preferred solid form for example sheet, cake, lozenge and bar, the preferred particulates form.

The present composition also can be used for or is used in combination with compositions of additives that the bleaching compositions of additives for example comprises chlorine bleach.SYNTHETIC OPTICAL WHITNER based on chlorine

Detergent composition of the present invention can comprise the SYNTHETIC OPTICAL WHITNER based on chlorine as annexing ingredient.Yet because detergent composition of the present invention is a solid, great majority are not suitable in these detergent composition based on the liquid bleach of chlorine, and only particle or the powdery SYNTHETIC OPTICAL WHITNER based on chlorine is fit to.

In addition, detergent composition of the present invention can be mixed with make they be compatible based on the SYNTHETIC OPTICAL WHITNER of chlorine, guarantee that thus the user can add the SYNTHETIC OPTICAL WHITNER based on chlorine in the detergent composition in the beginning of washing stage or process.

Should in the aqueous solution, can form hypochlorite based on the SYNTHETIC OPTICAL WHITNER of chlorine.Hypochlorite ion is chemically by formula OCI ^-Expression.

Those SYNTHETIC OPTICAL WHITNER that produce hypochlorite in the aqueous solution comprise basic metal and alkaline-earth metal hypochlorite, hypochlorite affixture, chloramines, chlorimide, chloro-acid amide and chlorine imide.The specific examples of this compounds comprises clorox, potassium hypochlorite, monobasic Losantin, binary magnesium hypochlorite, Efficacious Disinfeitant dodecahydrate, potassium dichloroisocyanurate, Surchlor GR 60, Surchlor GR 60 dihydrate, trichlorocyanuric acid, 1,3-two chloro-5,5-T10, N-chloro sulphonamide, chloramine-T, dichloramine-T, chloramine B and dichloramine B.Being used for the preferred SYNTHETIC OPTICAL WHITNER of the present composition is clorox, potassium hypochlorite or its mixture.Preferably the SYNTHETIC OPTICAL WHITNER based on chlorine can be pure as jade pure (trade(brand)name).

Most of SYNTHETIC OPTICAL WHITNER of above-mentioned generation hypochlorite can solid or spissated form be purchased, and in preparation present composition process, be dissolvable in water water.Some above-mentioned materialss can be buied by the aqueous solution.Clothes washing method

The present invention's method of machine-washing generally comprises the machine-wash wash water solution of detergent composition of the present invention who is used in the washing machine dissolving or disperses significant quantity and handles soiled clothes.The detergent composition of the significant quantity meaning is meant at 5-65 and rises dissolving or dispersion 10g-300g product in the washing soln of volume that this is typical products consumption and the washing soln volume that is generally used in the conventional machine washing method.Preferred washing machine can be so-called low-washing machine of filling.

Aspect preferred use, said composition is formulated into and makes it be applicable to hard surface cleaning or hand washing.Another preferred aspect, detergent composition is to be used for pre-treatment or to soak dirty and pollute the pre-treatment of fabric or soak composition.That uses in granular detergent composition embodiment writes a Chinese character in simplified form

In detergent composition, the component symbol of writing a Chinese character in simplified form has following implication: LAS: straight chain C _11-13Sodium alkyl benzene sulfonate TAS: tallow alkyl sodium sulfate C _XyAS: C _1X-C _1YSodium alkyl sulfate C46SAS: C ₁₄-C ₁₆Secondary (2,3) sodium alkyl sulfate C _XyE _zS: with the C of Z moles of ethylene oxide condensation _1X-C _1YAlkylsurfuric acid

Sodium C _XyE _z: with the condensation of average z moles of ethylene oxide mainly be straight chain

C _1x-C _1yPrimary alconol QAS: R ₂N ⁺(CH ₃) ₂(C ₂H ₄OH), R ₂=C ₁₂-C ₁₄QAS1: R ₂N ⁺(CH ₃) ₂(C ₂H ₄OH), R ₂=C ₈-C ₁₁APA: C ₈-C ₁₀Amido propyl-dimethyl amine soap: straight-chain alkyl carboxylic acid's sodium, by butter and coco-nut oil fatty acid

80/20 mixture obtain STS: toluenesulfonic acid sodium salt CFAA: C ₁₂-C ₁₄(cocounut oil) alkyl N-methyl glucose amide TFAA: C ₁₆-C ₁₈Alkyl N-methyl glucose amide TPKFA: C ₁₂-C ₁₄Top full cut lipid acid STPP: anhydrous sodium tripolyphosphate TSPP: tetrasodium pyrophosphate zeolite A: formula Na ₁₂(AlO ₂SiO ₂) ₁₂27H ₂The hydration silicoaluminate of O

Sodium, primary particle size are that the 0.1-10 micron (is represented by moisture-free basis

Weight) NaSKS-6: formula δ-Na ₂Si ₂O ₅The crystalline layered silicate citric acid: Citric Acid, usp, Anhydrous Powder borate: Sodium Tetraborate carbonate: granularity is a 200-900 micron anhydrous sodium carbonate supercarbonate: size-grade distribution is at the anhydrous sodium bicarbonate silicate of 400-1200 micron: amorphous sodium silicate (SiO ₂: Na ₂O ratio=2.0: 1) vitriol: anhydrous sodium sulphate sal epsom: anhydrous magnesium sulfate Citrate trianion: citrate trisodium dihydrate, activity 86.4%, granularity

Be distributed in 425-850 micron MA/AA: 1: 4 toxilic acid/acrylic copolymer, molecular-weight average are approximately

70000MA/AA (1): 4: 6 toxilic acid/acrylic copolymer, molecular-weight average are approximately

10000AA: the polyacrylic acid sodium polymer CMC of molecular-weight average 4500: the plain ether of sodium carboxyme-thylcellulose fibre: the polymerization degree is 650 methyl cellulose ether, by Shin

Etsu Chemicals buys proteolytic enzyme: by Novo Industries A/S with trade(brand)name

The proteolytic ferment that Savinase sells has 3.3% weight

Amount organized enzyme proteolytic enzyme I: the proteolytic ferment of in WO95/10591, describing, tool

4% weight organized enzyme is arranged, by Genencor Int .Inc.

Sell the proteolysis that Alcalase is sold by Novo Industries A/S

Enzyme has 5.3% weight organized enzyme cellulase: by Novo Industries A/S with trade(brand)name

The cellulase that Carezyme sells has 0.23% weight

Amount organized enzyme amylase: by Novo Industries A/S with trade(brand)name

The amylase that Termamyl 120T sells has 1.6%

Weight organized enzyme lipase: by Novo Industries A/S with trade(brand)name

The lipolytic enzyme that Lipolase sells has 2.0% weight and lives

Property enzyme lipase (1): by Novo Industries A/S with trade(brand)name

The lipolytic enzyme that Lipolase Ultra sells has 2.0%

Weight organized enzyme Endolase: endoglucanase, by Novo Industries A/S

Sell, have 1.5% weight organized enzyme PB4: contain standard type NaBO ₂.3H ₂Sodium peroxoborate four hydrations of O

: the particle of thing, this particulate average particle size is 950 microns,

85% particle has granularity 850-950 micron PB1: contain standard type NaBO ₂.H ₂O ₂Anhydrous sodium perborate float

The particle of white agent, this particulate average particle size are 800 little

Rice, 85% particle has granularity 750-950 micron percarbonate: contain standard type 2Na ₂CO ₃3H ₂O ₂SPC-D

Grain, this particulate average particle size is 850 microns, 5% or few

Particle in 5% has granularity and is lower than 600 microns, 2% or

Be less than 2% particle and have granularity greater than 1180 microns NOBS: contain the particle of acyloxy benzene sulfonic acid sodium salt in the ninth of the ten Heavenly Stems, this particulate

Average particle size is 750-900 micron NAC-OBS: contain (6-nonanoyl caproyl) oxygen benzene sulfonate

Grain, this particulate average particle size is 825-875 micron TAED I: contain the particle of tetraacetyl ethylene diamine, this particulate weight average

Granularity is 700 microns-1000 microns TAED II: granularity is 150 microns-600 microns a tetrem acyl second two

Amine DTPA: diethylene triaminepentaacetic acid(DTPA) DTPMP: diethylenetriamine five (methylene phosphonic acid), by Meng Shandou

Sell photoactivated SYNTHETIC OPTICAL WHITNER with trade(brand)name Dequest2060: the photoactivated SYNTHETIC OPTICAL WHITNER of sulfonation phthalocyanine phthalocyanine zinc of in SYNTHETIC OPTICAL WHITNER (1), sealing (1): the aluminum phthalocyanine whitening agent 1: 4 of in SYNTHETIC OPTICAL WHITNER (2), sealing (2) with the dextrin soluble polymer with the dextrin soluble polymer, 4 '-two (2-sulfo group styryl) biphenyl disodium whitening agent 2: 4,4 '-two (4-phenylaminos-6-morpholino-1,3, the 5-triazine

-2-yl) Stilbene-2: 2 '-disulfonic acid disodium EDDS: quadrol-N amino), N '-disuccinic acid, its sodium-salt form

(S, S) isomer HEDP: hydroxyl ethane 1,1-di 2 ethylhexyl phosphonic acid PEGx: polyoxyethylene glycol, molecular weight is x (general 4000) PEO: polyoxyethylene, molecular-weight average 50000TEPAE: ethoxylation tetren PVI: polyvinyl imidazol, molecular-weight average 20000PVP: polyvinylpyrrolidonepolymers polymers, molecular-weight average

60000PVNO: polyvinylpyridine N-oxide polymer, mean molecule

Amount 50000PVPVI: the copolymerization of Polyvinylpyrolidone (PVP) and vinyl imidazole

Thing, molecular-weight average 20000QEA: two ((C ₂H ₅O)-(C ₂H ₄O) _n) (CH ₃)-N ⁺-C ₆H ₁₂-N ⁺-

(CH ₃) two ((C ₂H ₅O)-(C ₂H ₄O)) _n, n=20-wherein

30SRP1: the end capped polyester SRP2 of negatively charged ion: diethoxyization poly-(phthalic acid 1,2 inferior propyl ester) is short

Block polymer PEI: polyethylene imine based, molecular-weight average 1800, each nitrogen

The atom average degree of ethoxylation is 7 oxygen ethene residue polysiloxane defoamers: the polydimethylsiloxane foam control agent with as the silicon of dispersion agent

Oxygen alkane-oxyalkylene copolymers, described foam control agent and described branch

The ratio of powder is 10: 1-100: 1 opalizer: water base single styrene latex mixture, and by BASF

Aktiengesellschaft is with trade(brand)name Lytron

621 sell wax: paraffin

In following embodiment, all content are that the % by composition weight meter represents:

The following composition of Table I is according to composition of the present invention:

	A	B	C	D	E	?F	G	H	I
										The particle that spray is done
LAS	10.0	10.0	15.0	5.0	5.0	10.0	-	-	-
										TAS	-	1.0	-				-	-	-
MBAS	-	-		5.0	5.0		-	-	-
										C 45AS	-	-	1.0		2.0	2.0	-	-	-
C 45AE 3S	-	-		1.0			-	-	-

QAS			1.0	1.0			-	-	-
										DTPA, HEDP and/or EDDS	0.3	0.3	0.5	0.3			-	-	-
MgSO4	0.5	0.5	0.1	-			-	-	-
										Trisodium Citrate	-	-	-	3.0	5.0		-	-	-
Yellow soda ash	10.0	7.0	15.0			10.0	-	-	-
										Sodium sulfate	5.0	5.0	-	-	5.0	3.0	-	-	-
Water glass 1.6R	-	-	-	-	2.0		-	-	-
										Zeolite A	16.0	18.0	20.0	20.0	-	-	-	-	-
SKS-6	-	-	-	3.0	5.0	-	-	-	-
										MA/AA or AA	1.0	2.0	11.0	-	-	2.0	-	-	-
PEG4000	-	2.0	-	1.0	-	1.0	-	-	-
										QEA	1.0	-	-	-	1.0	-	-	-	-
Whitening agent	0.05	0.05	0.05	-	0.05	-	-	-	-
										Silicone oil	0.01	0.01	0.01	-	-	0.01	-	-	-
										Agglomerate
LAS			-	-	-	-	2.0	2.0	-
										MBAS			-	-	-	-	-	-	1.0
C45AS			-	-	-	-	2.0	-	-
										AE3			-	-	-	-	-	1.0	0.5
Carbonate			-	-	4.0	1.0	1.0	1.0	-
										Trisodium Citrate			-	-	-	-	-	-	5.0

CFAA					-	-	-	-	-
										Citric acid			-	-	-	4.0	-	1.0	1.0
QEA			-	-	-	2.0	2.0	1.0	-
										SRP			-	-	-	1.0	1.0	0.2	-
Zeolite A			-	-	-	15.0	26.0	15.0	16.0
										Water glass			-	-	-	-	-	-	-
PEG	-	-	-	-	-	-	4.0	-	-
Builder agglomerates
										SKS-6	6.0	-	-	-	6.0	3.0	-	7.0	10.0
LAS	4.0	5.0	-	-	5.0	3.0	-	10.0	12.0
Do the particle component that adds
										Toxilic acid/carbonate	8.0	10.0	10.0	4.0	-	8.0	2.0	2.0	4.0
(40∶20∶40)
										QEA	-	-	-	0.2	0.5	-	-	-	-
NACAOBS	3.0	-	-	4.5	-	-	-	2.5	-
										NOBS	1.0	3.0	3.0	-	-	-	-	-	5.0
TAEDI	2.5	-	-	1.5	2.5	6.5	-	1.5	-
										MBAS	-	-	-	8.0	-	-	8.0	-	4.0
LAS (thin slice)	10.0	10.0	-	-	-	-	-	8.0	-

										Spray
Whitening agent	0.2	0.2	0.3	0.1	0.2	0.1	-	0.6	0.3
										Dyestuff	-	-	-	0.3	0.05	0.1	-	-	-
AE7	-	-	-	-	-	0.5	-	0.7	-
										Spices	1.0	0.5	1.1	0.8	0.3	0.5	0.3	0.5	-
										Dried additive
Citrate trianion	-	-	20.0	4.0	-	5.0	15.0	-	5.0
										Percarbonate	15.0	3.0	6.0	10.0	-	-	24.0	18.0	5.0
Perborate	-	-	-	-	6.0	18.0	-	-	-
										Optical white	0.02	0.02	0.02	0.1	0.05	-	0.3	-	0.03
Enzyme (cellulase, amylase, proteolytic enzyme, lipase)	1.3	0.3	0.5	0.5	0.8	2.0	0.5	0.16	0.2
										Carbonate	0.0	10.0	-	-	-	5.0	8.0	10.0	5.0
Spices (sealing)	-	0.5	0.5	-	0.3	-	0.2	-	-
										Suds suppressor	1.0	0.6	0.3	-	0.10	0.5	1.0	0.3	1.2
Soap	0.5	0.2	0.3	3.0	0.5	-	-	0.3	-
										Citric acid	-	-	-	6.0	6.0	-	-	-	5.0
Painted carbonate (indigo plant, green)	0.5	0.5	1.0	2.0	-	0.5	0.5	0.5	1.0
										SKS-6	-	-	-	4.0	-	-	-	6.0	-
Filler adds to 100%

The following composition of Table II is according to composition of the present invention:

	A	B	C	D	E	?F	G	H	I
										The particle that spray is done
LAS	10.0	10.0	16.0	5?0	5.0	10.0	-	-	-
										TAS	-	1.0	-				-	-	-
MBAS	-	-	-	5.0	5.0		-	-	-
										C45AS	-	-	1.0		2.0	2.0	-	-	-
C 45AE 3S	-	-	-	1.0			-	-	-
										QAS	-	-	1.0	1.0			-	-	-
DTPA, HEDP and/or EDDS	0.3	0.3	?0.3	0.3			-	-	-
										MgSO4	0.5	0.4	0.1	-			-	-	-
Trisodium Citrate	10.0	12.0	17.0	3.0	5.0		-	-	-
										Yellow soda ash	15.0	8.0	15.0			10.0	-	-	-
Sodium sulfate	5.0	5.0	-	-	5.0	3.0	-	-	-
										Water glass	-	-	-	-	2.0	-	-	-	-
Zeolite A	-	-	-	2.0	-	-	-	-	-
										SKS-6	-	-	-	3.0	5.0	-	-	-	-
MA/AA or AA	1.0	2.0	10.0	-	-	2.0	-	-	-
										PEG4000	-	2.0	-	1.0	-	1.0	-	-	-

QEA	1.0	-	-	-	1.0	-	-	-	-
										Whitening agent	0.05	0.05	0.05	-	0.05	-	-	-	-
Silicone oil	0.01	0.01	0.01	-	-	0.01	-	-	-
Agglomerate
										LAS	-	-	-	-	-	-	2.0	2.0	-
MBAS	-	-	-	-	-	-	-	-	1.0
										C 45AS	-	-	-	-	-	-	2.0	-	-
AE 3	-	-	-	-	-	-	-	1.0	0.5
										Carbonate	-	-	-	-	4.0	1.0	1.0	1.0	-
Trisodium Citrate	-	-	-	-	-	-	-	-	5.0
										CFAA	-	-	-		-	-	-	-	-
Citric acid	-	-	-	-	-	4.0	-	1.0	1.0
										QEA	-	-	-	-	-	2.0	2.0	1.0	-
SRP	-	-	-	-	-	1.0	1.0	0.2	-
										Zeolite A	-	-	-	-	-	15.0	26.0	15.0	16.0
Water glass	-	-	-	-	-	-	-	-	-
										PEG	-	-	-	-	-	-	4.0	-	-
TAEDII							3.0		1.5
										Builder agglomerates
SKS-6	6.0	5.0	-	-	6.0	3.0	-	7.0	10.0
										LAS	4.0	5.0	-	-	5.0	3.0	-	10.0	12.0

Do the grain fraction of adding
										Toxilic acid/carbonate (40: 20: 40)	8.0	10.0	4.0	4.0	-	8.0	2.0	2.0	4.0
QEA	-	-	-	0.2	0.5	-	-	-	-
										NACAOBS	3.0	-	-	1.5	-	-	-	5.5	-
NOBS/LOBS/ DOBS	-	3.0	3.0	-	-	-	-	-	5.0
										TAEDI	2.5	-	-	1.5	2.5	6.5	-	1.5	-
MBAS	-	-	-	8.0		-	8.0	-	4.0
										LAS (thin slice)	-	-	-	-	-	-	-	8.0	-
										Spray
Whitening agent	0.2	0.2	0.3	0.1	0.2	0.1	-	0.6	-
										Dyestuff	-	-	-	0.3	0.05	0.1	-	-	-
AE7	-					0.5	-	0.7	-
										Spices	-	-	-	0.8		0.5	0.8	0.5	?1.0
										Dried additive
Citrate trianion	4.0	-	3.0	4.0	-	5.0	15.0	-	5.0
										Percarbonate	15.0	3.0	6.0	10.0	-	-	12.0	18.0	5.0
Perborate	-	-	-	-	6.0	18.0	-	-	+
										Optical white	0.02	0.02	0.02	0.1	0.05	-	0.3	-	0.03

Enzyme (cellulase, amylase, proteolytic enzyme, lipase)	1.5	0.3	0.5	0.5	0.8	2.0	0.5	0.16	0.2
										Carbonate	-	-	-	-	-	5.0	8.0	10.0	5.0
Spices (sealing)	0.6	0.5	0.5	-	0.3	0.5	0.2	0.1	0.6
										Suds suppressor	1.0	0.6	0.3	-	0.10	0.5	1.0	0.3	1.2
Soap	0.5	0.2	0.3	3.0	0.5	-	-	0.3	-
										Citric acid	-	-	-	6.0	6.0	-	-	-	5.0
Painted carbonate (indigo plant, green)	0.5	0.5	？	2.0	-	0.5	0.5	0.5	1.0
										SKS-6	-	-	-	4.0	-	-	-	6.0	-
Filler adds to 100%

Be according to high-density of the present invention and the detergent formulation that contains SYNTHETIC OPTICAL WHITNER below the Table III:

	????A	????B	????C
				The powder of blowing
Zeolite A	????-	????-	???15.0
				Sodium sulfate	???0.0	???5.0	???0.0
?????????LAS	???3.0	????-	???3.0

???????????????C45AS	????3.0	????2.0	????4.0
				?????????????????QAS	????-	????-	????1.5
???????????????DTPMP	????0.4	????0.4	????0.4
				?????????????????CMC	????0.4	????0.4	????0.4
???????????????MA/AA	????4.0	????2.0	????2.0
				??????????????TAEDII	????-	????-	????3.0
Agglomerate
				?????????????????QAS	????1.0	????-	????-
?????????????????LAS	????-	???11.0	????7.0
				?????????????????TAS	????2.0	????2.0	????1.0
Silicate	????3.0	????-	????4.0
				Zeolite A	????8.0	????8.0	????8.0
Carbonate	????8.0	????8.0	????4.0
				Agglomerate
NaSKS-6 (I) or (II)	???15.0	????12.0	????5.0
				?????????????????LAS	????8.0	????7.0	????4.0
??????????????????AS	????5.0	????-	????-
				Spray
Spices	????0.3	????0.3	????0.3
				???????????????C25E3	????2.0	????-	????2.0
Whitening agent	????0.1	????0.4
				Optical white	????0.03	????0.05	????-
Dried additive

?????????????????????????QEA	????1.0	????0.5	????0.5
				Citric acid/citrate	????5.0	?????-	????2.0
Supercarbonate	?????-	????3.0	?????-
				Carbonate	????8.0	????15.0	????10.0
??????????????????????NACOBS	????6.0	?????-	????5.0
				Mn catalyst	?????-	?????-	????0.3
???????????????????????TAEDI		????3.0	?????-
				????????????????????????NOBS	?????-	????2.0	?????-
Percarbonate	????14.0	????7.0	????10.0
				Polyethylene oxide MW5,000,000	?????-	?????-	????0.2
Wilkinite	?????-	?????-	????10.0
				Citric acid	?????-	?????-	????0.5
Proteolytic enzyme	????1.0	????1.0	????1.0
				Lipase	????0.4	????0.4	????0.4
Amylase	????0.6	????0.6	????0.6
				Cellulase	????0.6	????0.6	????0.6
Polysiloxane defoamers	????5.0	????5.0	????5.0
				Dried additive
Sodium sulfate	????0.0	????3.0	????0.0
				Equipoise (water and subsidiary)	????100.0	????100.0	????100.0
Density (g/ liter)	????850	????850	????850

Claims (10)

1. solid detergent composition, it comprises the component and the hydrogen peroxide cource of SYNTHETIC OPTICAL WHITNER sensitivity, wherein hydrogen peroxide cource exists with the particle component, by weight, its mean particle size is 700 microns-1100 microns, preferred 700-1000 micron, wherein the granularity that has of the particle component that comprises hydrogen peroxide cource of at least 80% weight is the 60%-140% of average particle size, is preferably the 70%-130% of average particle size.

2. according to the solid constituent of claim 1, wherein hydrogen peroxide cource comprises percarbonate.

3. according to the solid detergent composition of claim 2, wherein percarbonate is such, is being less than 10 minutes, preferably is less than the theoretical maximum that discharges percarbonate in 6 minutes and can gets 75% of oxygen (AvO).

4. according to the solid detergent composition of any aforesaid right requirement, wherein the mean particle size of hydrogen peroxide cource is 800 microns-950 microns.

5. the solids composition that requires according to any aforesaid right, it comprises one or more bleach-activating agents, and wherein preferred at least a bleach-activating agent is present in and has mean particle size 600-1400 micron by weight, in the particle component of preferred 700-1100 micron.

6. according to the solid detergent composition of claim 5, it comprises hydrophobic organic peroxide acid bleach precursor and hydrophilic organic peroxyacid bleach precursor, the hydrophilic organic peroxyacid bleach precursor preferably comprises TAED, hydrophobic precursor preferably comprises oxygen Phenylsulfonic acid alkali, preferably NACA-OBS or NOBS or its mixture.

7. the solid detergent composition that requires according to any aforesaid right, it is a particulate composition, at least 80% particle that wherein accounts for composition by weight, having mean particle size is 700 microns-1400 microns, preferred 750 microns-1000 microns.

8. according to the detergent composition of any aforesaid right requirement, wherein the component of SYNTHETIC OPTICAL WHITNER sensitivity comprises spices, dirt release agent polymkeric substance, dispersion agent, sequestrant, dyestuff, optical white or whitening agent or its mixture.

9. according to the detergent composition of any aforesaid right requirement, it comprises the sprinkling component that contains the responsive component of SYNTHETIC OPTICAL WHITNER.

10. according to the detergent composition of any aforesaid right requirement, it comprises the foaming component, preferably has 700 microns-1400 microns of mean particle sizes by weight, the particle foaming component of preferred 750-1100 micron.