CN1331977C - Antirust non-freezing solution from polyaniline - Google Patents
Antirust non-freezing solution from polyaniline Download PDFInfo
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- CN1331977C CN1331977C CNB2004100112658A CN200410011265A CN1331977C CN 1331977 C CN1331977 C CN 1331977C CN B2004100112658 A CNB2004100112658 A CN B2004100112658A CN 200410011265 A CN200410011265 A CN 200410011265A CN 1331977 C CN1331977 C CN 1331977C
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- polyaniline
- freezing solution
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- ethylene glycol
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Abstract
The present invention relates to an antirust non-freezing solution from polyaniline, which belongs to the field of a non-freezing solution for water tanks. The present invention is prepared from the following ingredients (wt%): 1 to 3% of polyaniline water preservative agent and 97 to 99% of an ethanediol non-freezing solution. The present invention has the advantages of the polyaniline water preservative agent used as an additive agent of an ethanediol non-freezing solution to effectively prevent the acidification of the original ethanediol and organic corrosion inhibitors. The present invention solves the problem of poor antirust property for the non-freezing solutions of the existing vehicles. Simultaneously, antiscaling agents and antifoaming agents do not need to be added, and the technical requirements for scale resistance and no foam generation are reached. The present invention is an ideal non-freezing solution of a novel vehicle water box with good corrosion resistance effect.
Description
Technical field
The invention belongs to radiator and use the non-freezing solution field, in order to improve the Corrosion Protection of product.
Background technology
At present, the automobile non-freezing solution on the China market, great majority are that to dose the organic anti-corrosive agent with ethylene glycol be major product.The shortcoming that exists is: organic anti-corrosive agent and ethylene glycol is very easily acidifying under 80 ℃ temperature, and causes the corrosion to radiator recycle pump and engine cylinder-body.Generally speaking, our non-freezing solution bought from the market meets national standard after testing.But, in radiator, to use after three months and detect again, considerable change has taken place in product performance aspect antiseptic property.After using three months, still continue the non-freezing solution difficult quality guarantee of use in other words.
Summary of the invention
The invention provides the antirust non-freezing solution of a kind of polyaniline, to solve the problem of present deicing fluid rustless property difference.The technical scheme that the present invention takes is: the component of following weight percent is formed:
Polyaniline aqueous sanitas 1～3%
Ethylene glycol non-freezing solution 97～99%.
The wherein preparation of anticorrosive polyaniline agent prepares the anticorrosive polyaniline agent by the following method:
With 10 gram polyaniline in eigenstate, 1 gram Sulfuric acid disilver salt, join in 100 grams, 23% the sulfuric acid, under 90 ℃ temperature, stirred 2 hours, filtration washing to be cooled repeatedly three times to neutral, obtain about 50 gram black pastes; Get this slurry 4 grams, add deionized water 10 grams, add caustic soda 0.2 gram, pH value is transferred to 8-9, and then add 1 gram borax, stirred 1.5 hours with 1700 rev/mins, make it dissolving with high speed dispersor; Add zinc sulfate 0.004 gram again, Sodium Nitrite 0.35 restrains, Sodium Benzoate 0.4 gram, and ethanol 0.02 gram continues with high speed dispersor with the extremely dissolving of 1700 rev/mins of high speed dispersion.
Important embodiment of the present invention is:
Component by following weight percent is formed:
Polyaniline aqueous sanitas 1%
Ethylene glycol non-freezing solution 99%.
The ethylene glycol non-freezing solution is made up of the component of following weight percent among the present invention:
Ethylene glycol 35～60%
Distilled water 40～65%.
The invention has the advantages that: with the compound of polyaniline aqueous sanitas, effectively prevented the acidifying of original ethylene glycol and organic anti-corrosive agent, solved the bad problem of present automobile non-freezing solution rustless property as the ethylene glycol non-freezing solution.Simultaneously, scale inhibitor and defoamer be needn't dose again, antiscale, non-foaming technical requirements also can be reached.It is the splendid new automobile water tank non-freezing solution of a kind of ideal, preservative effect.
Technical indicator: freezing point :-20 ℃-45 ℃, boiling point: 108 ℃, the automobile organic coating is influenced: do not have, pH value 8-9, the foam tendency: foams and＜80ml lather collapse time＜3s.
The glassware corrosion experiment:
Test piece test piece value amount changing value: mg/ sheet
Red copper-0.8
Brass-1.2
Steel-2.1
Cast iron+1.6
Scolding tin-2.3
Cast aluminium+4.2
Embodiment
Embodiment 1:
The preparation of anticorrosive polyaniline agent: prepare the anticorrosive polyaniline agent by the following method.
With 10 gram polyaniline in eigenstate, 1 gram Sulfuric acid disilver salt, join in 100 grams, 23% the sulfuric acid, under 90 ℃ temperature, stirred 2 hours, filtration washing to be cooled repeatedly three times to neutral, obtain about 50 gram black pastes; Get this slurry 4 grams, add deionized water 10 grams, add caustic soda 0.2 gram, pH value is transferred to 8-9, and then add 1 gram borax, stirred 1.5 hours with 1700 rev/mins, make it dissolving with high speed dispersor; Add zinc sulfate 0.004 gram again, Sodium Nitrite 0.35 restrains, Sodium Benzoate 0.4 gram, and ethanol 0.02 gram continues with high speed dispersor with the extremely dissolving of 1700 rev/mins of high speed dispersion.
Obtain polyaniline aqueous sanitas 15.9 grams.Its outward appearance is the black aqueous solution, free from extraneous odour, and density is (20 ℃) kg/m
3: 1050-1080, pH value are 9-10.
1 kilogram of polyaniline aqueous sanitas, 55 kg ethylene glycol, 44 kilograms of distilled water are mixed in the material barrel, stirred 20 minutes with the high speed dispersion stirrer, filtration can obtain the double centner black liquor, free from extraneous odour, density (20 ℃): kg/m:1080.
Embodiment 2
The preparation of anticorrosive polyaniline agent is with embodiment 1.
2 kilograms of polyaniline aqueous sanitass, 36 kg ethylene glycol, 62 kilograms of distilled water are mixed in the material barrel, stirred 20 minutes with the high speed dispersion stirrer, filtration can obtain the double centner black liquor.
Embodiment 3
The preparation of anticorrosive polyaniline agent is with embodiment 1.
3 kilograms of polyaniline aqueous sanitass, 48 kg ethylene glycol, 49 kilograms of distilled water are mixed in the material barrel, stirred 20 minutes with the high speed dispersion stirrer, filtration can obtain the double centner black liquor.
Claims (3)
1, the antirust non-freezing solution of a kind of polyaniline is characterized in that being made up of the component of following weight percent:
Polyaniline aqueous sanitas 1～3%
Ethylene glycol non-freezing solution 97～99%,
Wherein the preparation method of anticorrosive polyaniline agent is as follows:
With 10 gram polyaniline in eigenstate, 1 gram Sulfuric acid disilver salt, join in 100 grams, 23% the sulfuric acid, under 90 ℃ temperature, stirred 2 hours, filtration washing to be cooled repeatedly three times to neutral, obtain about 50 gram black pastes; Get this slurry 4 grams, add deionized water 10 grams, add caustic soda 0.2 gram, pH value is transferred to 8-9, and then add 1 gram borax, stirred 1.5 hours with 1700 rev/mins, make it dissolving with high speed dispersor; Add zinc sulfate 0.004 gram again, Sodium Nitrite 0.35 restrains, Sodium Benzoate 0.4 gram, and ethanol 0.02 gram continues with high speed dispersor with the extremely dissolving of 1700 rev/mins of high speed dispersion.
2, the antirust non-freezing solution of a kind of polyaniline according to claim 1 is characterized in that being made up of the component of following weight percent:
Polyaniline aqueous sanitas 1%
Ethylene glycol non-freezing solution 99%.
3, the antirust non-freezing solution of a kind of polyaniline according to claim 1 and 2 is characterized in that the ethylene glycol non-freezing solution is made up of the component of following weight percent:
Ethylene glycol 35～60%
Distilled water 40～65%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100112658A CN1331977C (en) | 2004-11-26 | 2004-11-26 | Antirust non-freezing solution from polyaniline |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100112658A CN1331977C (en) | 2004-11-26 | 2004-11-26 | Antirust non-freezing solution from polyaniline |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1778861A CN1778861A (en) | 2006-05-31 |
| CN1331977C true CN1331977C (en) | 2007-08-15 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100112658A Expired - Fee Related CN1331977C (en) | 2004-11-26 | 2004-11-26 | Antirust non-freezing solution from polyaniline |
Country Status (1)
| Country | Link |
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| CN (1) | CN1331977C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113105951B (en) * | 2021-04-12 | 2022-10-18 | 重庆多次元新材料科技有限公司 | Formula and preparation method of high-corrosion-resistance automobile glass water |
| CN115613019B (en) * | 2022-09-29 | 2024-08-09 | 南京科润工业介质股份有限公司 | Waste heat blackening liquid suitable for workpiece split charging of full-automatic weighing and packaging machine |
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| CN1174186A (en) * | 1997-09-02 | 1998-02-25 | 齐齐哈尔铁路机务工贸总公司信德化工厂 | Boiling-preventing and antifreezing coolant for diesel locomotive |
| CN1202510A (en) * | 1997-06-12 | 1998-12-23 | 宋清晖 | Multi-effect antifreezing solution |
| US6096236A (en) * | 1997-03-11 | 2000-08-01 | Cci Co., Ltd. | Antifreeze/coolant composition |
| US6126851A (en) * | 1996-09-04 | 2000-10-03 | Cci Co., Ltd. | Antifreeze/coolant composition containing p-toluate and a molybdate |
| WO2001070900A1 (en) * | 2000-03-21 | 2001-09-27 | Shishiai-Kabushikigaisha | Antifreeze/coolant composition |
| CN1396232A (en) * | 2002-07-16 | 2003-02-12 | 中国石油化工股份有限公司茂名分公司研究院 | Antifreezing liquid resisting corrosion, deposit and boiling for car |
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| WO2004065516A1 (en) * | 2003-01-21 | 2004-08-05 | Basf Aktiengesellschaft | Thermal liquids providing glass corrosion protection especially for solar systems |
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2004
- 2004-11-26 CN CNB2004100112658A patent/CN1331977C/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6126851A (en) * | 1996-09-04 | 2000-10-03 | Cci Co., Ltd. | Antifreeze/coolant composition containing p-toluate and a molybdate |
| US6096236A (en) * | 1997-03-11 | 2000-08-01 | Cci Co., Ltd. | Antifreeze/coolant composition |
| CN1202510A (en) * | 1997-06-12 | 1998-12-23 | 宋清晖 | Multi-effect antifreezing solution |
| CN1174186A (en) * | 1997-09-02 | 1998-02-25 | 齐齐哈尔铁路机务工贸总公司信德化工厂 | Boiling-preventing and antifreezing coolant for diesel locomotive |
| WO2001070900A1 (en) * | 2000-03-21 | 2001-09-27 | Shishiai-Kabushikigaisha | Antifreeze/coolant composition |
| CN1396232A (en) * | 2002-07-16 | 2003-02-12 | 中国石油化工股份有限公司茂名分公司研究院 | Antifreezing liquid resisting corrosion, deposit and boiling for car |
| CN1498938A (en) * | 2002-11-11 | 2004-05-26 | 浙江万丰奥特集团有限公司 | Compsn. of impregnating and antifreezing fluid and preparation method |
| WO2004065516A1 (en) * | 2003-01-21 | 2004-08-05 | Basf Aktiengesellschaft | Thermal liquids providing glass corrosion protection especially for solar systems |
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| Title |
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| 中国腐蚀与防护学报 井新利 等，301.305，本征态聚苯胺的防腐性能 2004 * |
| 功能高分子学报 张金勇 等，350.354，聚苯胺在防腐领域中的应用 1999 * |
| 材料保护 李娟，25，汽车防冻液的配制 2001 * |
| 材料保护 李娟，25，汽车防冻液的配制 2001;材料保护 汽车防冻液的配制，25，李娟 2001;功能高分子学报 张金勇 等，350.354，聚苯胺在防腐领域中的应用 1999;精细石油化工 田玉竹 等，86.91，汽车防冻液中的缓蚀剂与稳定剂 1994;中国腐蚀与防护学报 井新利 等，301.305，本征态聚苯胺的防腐性能 2004 * |
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| CN1778861A (en) | 2006-05-31 |
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Owner name: JILIN ZHENGJI SCIENCE + TECHNOLOGY DEVELOPMENT CO. Free format text: FORMER NAME: ZHENGJI SCIENCE AND TECHNOLOGY DEVELOPMENT CO., LTD., JILIN |
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