CN1331578A - Skin cleansing compsn. providing enhanced perfumed deposition - Google Patents
Skin cleansing compsn. providing enhanced perfumed deposition Download PDFInfo
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- CN1331578A CN1331578A CN99809259.2A CN99809259A CN1331578A CN 1331578 A CN1331578 A CN 1331578A CN 99809259 A CN99809259 A CN 99809259A CN 1331578 A CN1331578 A CN 1331578A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q13/00—Formulations or additives for perfume preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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Abstract
A method for cleansing the skin and providing an increased fragrance benefit after rinsing the skin form the cleansing composition which comprises applying to the skin, a composition having: (a) one or more mixture of surfactants in sufficient quantity to cleanse the skin; (b) a fragrance in sufficient quantities to provide an aroma; (c) a silicone, a hydrocarbonaceous component or mixture thereof in sufficient quantities to bring about an increased fragrance benefit, and rinsing off said composition.
Description
Background of invention
Existing hundreds of years of the application of spice in skin care compositions and methods, these spice have a lot of purposes.For the user of compositions or be close to the people of user, these spice provide discernible fragrance.Spice can hide the abnormal smells from the patient that produces because of bacterial growth on the skin, and spice can be as the solubilizing agent of other organic substance in the compositions.Yet, at skin care compositions and methods, especially in " flush away " type, the effect of spice usually the persistent period very short.Even supposing them rests in short-and-medium time of contact on the skin not by flush away in the skin nursing process, they and skin bonding also very weak and/or their can the fast speed of ether break away from skin, so that just can not stay tangible abnormal smells from the patient after the short time after flushing.Therefore,, suitable spice binding capacity must be arranged on skin for suitable spice is provided for the space above the skin, just make it to be bonded on the skin and experience the suitable time limit after discharge from skin.This combination will provide a kind of " persistent " fragrance in for a long time.
Have now found that a kind of new compositions that these spice advantages are provided.Said composition is the improved washing-off type cleaning combination of a kind of spice benefit.
Summary of the invention
According to the present invention, provide a kind of cleaning skin and after skin flushing, the method that the spice in the cleaning combination is increased the benefit, this method comprise a kind of compositions are applied to skin that said composition contains:
A. clean a kind of surfactant of skin q.s or the mixture of kinds of surface activating agent;
B. q.s provides the spice of fragrance;
Q.s siloxanes or hydrocarbon component or its mixture that the spice benefit is improved;
Rinse out said composition then.
Detailed Description Of The Invention
Spice refers to provides any volatile aromatic reagent of fragrance can for the final composition that retains spice.The example of these materials is that boiling point is lower than about 500 ℃ those.About 250 ℃ or lower of high volatilization, the general boiling point of lower boiling perfume composition.Medium evaporable perfume composition be boiling point about 250 ℃ to about 300 ℃ those.Low volatilization, high boiling perfume composition be boiling point about 300 ℃ to about 500 ℃ those.Hereinafter many perfume compositions of Tao Luning and their abnormal smells from the patient and/or fragrance characteristic, with their physics and chemical property, as boiling point and molecular weight etc., provide in " spice and flavor chemistry product (aromachemicals) " (Perfume and Flavor Chemicals (Aroma Chemicals)) book of publishing in 1969 at SteffenArctander, the document is hereby incorporated by.The individual cleaning products of preferred this paper comprises spice, promptly at least about 5% perfume composition, more preferably at least about 25%, is 250 ℃ or more lower boiling high volatile volatile perfume composition at least about 50% perfume composition most preferably.
High volatile volatile, the example of lower boiling perfume composition is: isoesdragol, benzaldehyde, benzyl acetate, benzylalcohol, benzyl formate, isobornyl acetate, camphene, cis citral (neral), citronellal, citronellol, geraniol acetate, p-cymene, capraldehyde, dihydro linalool, dihydromyrcenol, dimethylphenyl carbinol, cineole, geranial, geraniol, geranyl acetate, geranonitrile, cis-3-hexenyl acetas, hydroxycitronellal, d-limonene, linalool, linalool oxide, linalyl acetate, linalyl propionate, methyl anthranilic acid ester, Alpha-Methyl ionone, methyl nonyl acetaldehyde, the aminomethyl phenyl methyl acetate, left-handed-the yl acetate, menthone, isomenthone, myrcene, lauryl acetate, myrcenol, nerol, neryl acetate, nonyl acetate, phenethanol, australene, nopinene, γ-Song Youxi, alpha-terpineol, β-terpineol, terpinenyl aceatae, and Vertenex (vertenex).Some natural oils also contains the high volatile volatile perfume composition of high percentage ratio.For example, the key component that lavandin oil comprises has: linalool, linalyl acetate, geraniol, and citronellol.Fructus Citri Limoniae oil and orange terpene all comprise about 95% d-limonene.
The example of medium volatile perfume composition is: amyl cinnamic aldehyde, isopentyl salicylate, β-caryophyllene, cedrene, cinnamyl alcohol, coumarin, the dimethyl benzyl methyl acetate, ethyl vanillin, acetaminol, isoeugenol, acetic acid fragrance of a flower ester, piperonal, 3-cis-hexenyl salicylate, 1-Hexyl salicylate, lilestralis (lilestralis), cetone gamma, nerolidol, patchouli alcohol, phenyl hexanol, β-selinene, trichloromethyl phenylacetic acid methyl ester, triethyl citrate, vanillin, and 3,4-dimethoxybenzenecarbonal.The Cupressus funebris Endl. terpene is mainly by ene, β-cedrene and other C
15H
24Sesquiterpene is formed.
The surfactant that can be used in the compositions comprises following all kinds of: anion, both sexes, nonionic and cationic surfactant are used alone or in combination.Soap, a kind of chain alkyl or thiazolinyl, side chain or normal chain carboxylate as its sodium salt, potassium salt, ammonium salt or substituted ammonium salt, can be present in the compositions.Typical chain alkyl or thiazolinyl are that about 22 carbon atoms of about 8-are long, specifically are that about 20 carbon atoms of about 10-are long, more preferably alkyl and most preferably normal chain, or the normal chain of minimum side chain is arranged.In the fragment that mainly is alkyl, can there be a small amount of ethylene linkage, if particularly the source of " alkyl " is by natural prodcuts, as Adeps Bovis seu Bubali, when the Cortex cocois radicis wet goods obtains.
The example of the anion surfactant except that soap includes, but is not limited to: alkyl sulfate; anionic acyl sarcosinates; methyl-acyl taurine salt, N-acyl glutamate, acyl isethinate; alkyl sulfo succinate; alkyl phosphate, ethoxylated alkyl phosphate ester, tridecyl ethoxy sulfate; the protein condensation substance, the mixture of ethoxylated alkyl sulfates etc.
The alkyl chain of these surfactants is C
8-C
22, preferred C
10-C
18, more preferably C
12-C
14The typical case who can be used as the non-soap surfactant of anion is the alkali metal organic sulfate on the contrary, has an alkyl that comprises about 8-22 carbon atom and sulfonic acid or sulfate group (so-called alkyl is the moieties of senior acyl group) in their molecular structure.Preferred sodium, ammonium, potassium or triethanolamine alkyl sulfate are especially by sulphation higher alcohol (C
8-C
18Individual carbon atom) those that obtain, fatty acid distribution of coconut oil monoglyceride sodium sulfate and fatty acid distribution of coconut oil coconut monoglyceride; The sodium salt or the potassium salt of the sulfuric ester of 1 mole of high fatty alcohol (as Adeps Bovis seu Bubali or cocoanut oil alcohol) and 1-12 moles of ethylene oxide product; Per molecule have 1-10 ethylene oxide unit and wherein alkyl comprise the sodium salt or the potassium salt of the alkyl phenol oxirane ether sulfuric ester of 8-12 carbon atom, alkyl glycerylether sodium sulfonate; Fatty acid with 10-22 carbon atom is also used the neutral product of sodium hydroxide with the isethionic acid esterification; The water soluble salt of fatty acid and sarcosine condensation product; And other material as known in the art.
The example that can be used as zwitterionic surfactant be extensively be called aliphatic quaternary ammonium, quaternary phosphine and season sulfonium compound derivant, wherein aliphatic group can be a straight or branched, and wherein one of aliphatic substituent group comprises about 8-18 carbon atom, and another comprises the anionic water-soluble group, as carboxyl, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.The general formula of these chemical compounds is:
R wherein
2The alkyl, alkenyl or the hydroxyalkyl that comprise about 8-18 carbon atom, 0-10 ethylene oxide moiety and 0-1 glyceryl part; Y is selected from nitrogen, p and s atom; R
3Be alkyl or the monohydroxy alkyl that comprises 1-3 carbon atom; X is 1 when Y is sulphur atom, and X is 2 when Y is nitrogen or phosphorus atoms; R
4Be the alkylidene or the hydroxyl alkylidene of 0-4 carbon atom, and Z is the group that is selected from carboxylate radical, sulfonate radical, sulfate radical, phosphonate radical and phosphate radical.
Example comprises: 4-[N, N-two (2-hydroxyethyl)-N-octadecyl ammonium]-butane-1-carboxylate; 5-[S-3-hydroxypropyl-S-cetyl sulfonium]-3-hydroxyl pentane-1-sulfate; 3-[P, P-P-diethyl-P 3,6,9 trioxa myristyls-Phosphonium]-2-hydroxy propane-1-phosphate; 3-[N, N-dipropyl-N-3-dodecyloxy-2-hydroxypropyl ammonium]-propane-1-phosphonate; 3-(N, N-dimethyl-N-cetyltrimethyl ammonium) propane-1-sulfonate; 3-(N, N-dimethyl-N-cetyltrimethyl ammonium)-2-hydroxy propane-1-sulfonate; 4-[N, N-two (2-ethoxy)-N-(2 hydroxyl dodecyl) ammonium]-butane-1-carboxylate; 3-[S-ethyl-S-(3-dodecyloxy-2-hydroxypropyl) sulfonium]-propane-1-phosphate; 3-(P, P-dimethyl-P-Shi Er Wan Ji Phosphonium)-propane-1-phosphonate; And 5-[N, N-two (3-hydroxypropyl)-N-cetyltrimethyl ammonium]-2-hydroxyl-pentane-1-sulfate.
The examples of amphoteric surfactants that can be used in the present composition is extensively to be called aliphatic secondary amine and tertiary amines derived thing, wherein aliphatic group can be a straight or branched, and wherein one of aliphatic substituent group comprises about 8-18 carbon atom, and another comprises the anionic water-soluble group, as carboxyl, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.The examples for compounds that drops in this range of definition is the 3-sodium dodecyl aminopropionitrile, 3-dodecyl amino propane sulfonic acid sodium, and the N-alkyltaurate is as according to the introduction of the US2658072 chemical compound by lauryl amine and hydroxyethyl sulfonate prepared in reaction; N-senior alkyl aspartic acid, as introduce according to US2438091 preparation those and sell and be described in product among the US2528378 with trade name " Miranol ".Other amphoteric surfactant also can be used in the present composition as betanin.
The example that is used for the betanin of this paper comprises the senior alkyl betanin, as Cortex cocois radicis dimethyl carboxymethyl betaine, the lauryl dimethyl carboxymethyl betaine, lauryl dimethyl α-carboxyethyl betanin, the hexadecyldimethyl benzyl ammonium carboxymethyl betaine, lauryl two-(2-ethoxy) carboxymethyl betaine, stearyl two-(2-hydroxypropyl) carboxymethyl betaine, oil base dimethyl γ-carboxylic CAB, lauryl two-(2-hydroxypropyl) α-carboxyethyl betanin etc.The representative of sulfobetaines is the Cortex cocois radicis dimethyl sulfopropyl betaine, stearyl dimethyl sulfopropyl betaine, amido betaines, acylamino-sulfobetaines etc.
Many cationic surfactants are well known in the art, and below mention as an example:
-stearyl dimethyl benzyl ammonium chloride;
-Dodecyl trimethyl ammonium chloride;
-nonyl benzyl ethyl dimethyl ammonium nitrate;
-myristyl pyridinium bromide;
-lauryl chloride pyridine;
-hexadecylpyridinium chloride;
-lauryl chloride pyridine;
-lauryl bromination isoquinolin;
-two Adeps Bovis seu Bubalis (hydrogenation) alkyl dimethyl ammonium chloride;
-dilauryl alkyl dimethyl ammonium chloride; With
-stearyl alkali (stearalkonium).
Other cationic surfactant is disclosed among the US4303543, and it is capable to walk to the 5th hurdle 1-42 referring to the 4th hurdle the 58th, and the document is hereby incorporated by.Various chain alkyl cationic surfactants are also referring to " CTFA cosmetic ingredient dictionary ", 4
ThEdition1991, p509-514, the document is hereby incorporated by.
Non-ionic surface active agent can extensively be defined as the chemical compound by organic hydrophobic compound condensation reaction preparation of alkylidene oxide (hydrophilic) and aliphatic series or alkyl aromatic character.The example of the non-ionic surface active agent of preferred type is:
1. the polyoxyethylene condensation substance of alkyl phenol, as contain about 6-12 carbon atom, the alkyl phenol of straight or branched configuration alkyl and the condensation product of oxirane, described oxirane amount is that every mole of alkyl phenol is equivalent to the 10-60 moles of ethylene oxide.Alkyl substituent in this chemical compound can be from for example polymeric propylene, diisobutylene, octane or nonane.
2. oxirane and the product that is generated by the reaction of expoxy propane and ethylenediamine product carry out that condensation produces, can be different according to its composition of balance between the required hydrophobic and hydrophilic component.For example, gratifying chemical compound is to comprise the about 80% weight polyoxyethylene of about 40%-, the about 5000-11000 of its molecular weight, by the chemical compound that Oxyranyle and the hydrophobic matrix reaction that is made of the product of ethylenediamine and excessive expoxy propane are generated, described hydrophobic matrix molecular weight ranges is 2500-3000.
3. have the aliphatic alcohol of 8-18 carbon atom, straight or branched configuration and the condensation product of oxirane, for example every mole of coco alcohol has the cocoanut oil alcohol ethylene oxide condensate of 10-30 moles of ethylene oxide, and described cocoanut oil alcohol partly has 10-14 carbon atom.Other oxirane condensation product is the ethoxylated fatty acid ester (as Tween 20-polyoxyethylene (20) sorbitan monolaurate) of polyhydric alcohol.
4. corresponding to the long chain tertiary amine oxide of following general formula:
R
1R
2R
3N → O is R wherein
1The alkyl, alkenyl or the monohydroxy alkyl that comprise about 8-18 carbon atom, about 10 ethylene oxide moieties of 0-and 0-1 glyceryl, and R
2And R
3Comprise about 3 carbon atoms of 1-and 0-1 hydroxyl, as methyl, ethyl, propyl group, ethoxy or hydroxypropyl.Arrow is the conventional expressing method of semi-polar bond in the formula.The example that is applicable to amine oxide of the present invention comprises the dimethyl dodecyl amine oxide, oil base-two (2-ethoxy) amine oxide, dimethyloctylamine oxide, dimethyldecylamine oxide, dimethyl-tetradecylamine oxide, 3,6,9-trioxa heptadecyl diethyl amine oxide, two (2-ethoxy)-myristyl amine oxides, 2-dodecane oxygen ethyl dimethyl oxidation amine, 3-dodecyloxy-2-hydroxypropyl two (3-hydroxypropyl) amine oxide, dimethyl cetyl amine oxide.
5. corresponding to the long chain tertiary phosphine oxide of following general formula:
RR’R”P→O
Wherein R comprises alkyl, alkenyl or the monohydroxy alkyl of 8-20 carbon atom chain length, about 10 ethylene oxide moieties of 0-and 0-1 glyceryl part, and R ' and R " alkyl or the monohydroxy alkyl of respectively doing for oneself and containing 1-3 carbon atom.Arrow is the conventional expressing method of semi-polar bond in the formula.The example of suitable phosphine oxide is: the dodecyl dimethyl phosphine oxide, tetra-decylmethylethylphosoxide oxide, 3,6,9-trioxa octadecyl dimethyl oxidation phosphine, the hexadecyldimethyl benzyl ammonium phosphine oxide, 3-dodecyloxy-2-hydroxypropyl two (2-ethoxy) phosphine oxide, stearyl dimethyl oxidation phosphine, cetyl ethyl propyl phosphine oxide, oil base diethyl phosphine oxide, dodecyl diethyl phosphine oxide, myristyl diethyl phosphine oxide, dodecyl dipropyl phosphine oxide, dodecyl two (methylol) phosphine oxide, dodecyl two (2-ethoxy) phosphine oxide, myristyl methyl-2-hydroxypropyl phosphine oxide, oil base dimethyl oxidation phosphine, 2-hydroxyl dodecyl dimethyl phosphine oxide.
6. comprise the short-chain alkyl of about 3 carbon atoms of 1-or the long-chain dialkyl sulphoxide of a hydroxyalkyl (normally methyl) and a long hydrophobic chain, this long hydrophobic chain comprises alkyl, alkenyl, hydroxyalkyl or contains the oxoalkyl group of about 8-20 carbon atom, a 0-10 ethylene oxide moiety and 0-1 glyceryl part.Example comprises: octadecyl methyl sulfoxide, 2-oxo tridecyl methyl sulfoxide, 3,6,9-trioxa octadecyl dihydroxy ethyl sulfoxide, dodecyl methyl sulfoxide, oil base 3-hydroxypropyl sulfoxide, tetradecyl methyl sulfoxide, 3-methoxytridecylmethysulfoxide sulfoxide, 3-hydroxyl tridecyl methyl sulfoxide, 3-hydroxyl-4-dodecane oxygen-butyl methyl sulfoxide.
7. many glycosides of alkylation, wherein alkyl is about 20 carbon atoms of about 8-, about 18 carbon atoms of preferably about 10-, the degree of polymerization of glucosides is about 3 for about 1-, preferably about 1.3-about 2.0.
Amount of component b (original text is e) can be general hydrocarbons, " full methyl " thing that the chain hydrocarbon of drawing money on credit that obtains as wax, vaseline, mineral oil, Cera Flava, by Permethyl Corporation company is formed.The general formula of full methyl thing is
Wherein n can change in about 4-200.Product is n=4,16,38,214, and respectively with Permethy102A, 104A, 106A and 1082A sell.
Other hydrocarbons comprises Adeps Bovis seu Bubali resin, cocos nucifera oil fat, and lanoline, the Pilus Caprae seu Ovis lipid material is as the long-chain ester of Pilus Caprae seu Ovis lipid and ether etc.
Being used for vaseline of the present invention can be arbitrary number of level other white or yellow vaseline that people that this area is approved, suitable is coated with usefulness.About 35 ℃ of preferred vaseline fusing point-Yue 70 ℃ of scopes, more preferably from about those of 50-60 ℃.Vaseline in the compositions can comprise the hydrocarbon mixture of using mineral oil and/or preparing in conjunction with the paraffin of various fusing points; Compare with vaseline and to be in a small amount.The vaseline that does not conform to other material is preferred.The example of wax, being particularly useful in the solid composite is microwax, is commonly referred to paraffin, Cera Flava and from those waxes of the native paraffin of plant.
The siloxanes that is used for this paper is siloxanes fluids preferably, and is different with siloxane glue.Siloxanes fluids is defined in and has about 600000 centistokes of the about 5-of range of viscosities, the more preferably from about siloxanes of about 100000 centistokes of 350-under 25 ℃ herein.Poly-alkylsiloxane is preferred as the polydimethylsiloxane that is commonly referred to " polydimethylsiloxane ".
It generally is nonvolatile being used for silicone material of the present invention, can be poly-alkylsiloxane, poly-aryl siloxanes, the polyoxyethylene alkyl aryl radical siloxane has the substituent polysiloxanes of amino-functional, the alkoxylate siloxanes, as ethyoxyl or propoxyl group siloxanes, and polyether siloxane copolymer.Be used for siloxanes of the present invention and can comprise for example end-blockings such as methyl, hydroxyl, oxirane, expoxy propane, amino, trialkyl silane (preferable methyl), carboxyl with the group of arbitrary number.The mixture of these materials also can use, and is preferred in some scheme.In addition, volatile siloxane can be used as the part of mixture of siloxanes, as long as final mixture is nonvolatile at least basically.
The poly-alkylsiloxane that can be used for this paper comprises, for example at the polydimethylsiloxane of 25 ℃ of about 600000 centistokes of the about 5-of following range of viscosities.These siloxanes can be buied with Viscasil series from for example GeneralElectric company, and can buy with DowCorning 200 from Dow Corning.The available Dow Corning of the measurement of the viscosity test method(s) CTM0004 of company, Jul.20, the glass capillary tube viscometer method that proposes in 1970.Preferred about 50 centistokes of range of viscosities-Yue 150000 centistokes, most preferably from about 350 centistokes-Yue 100000 centistokes.
Spendable polyoxyethylene alkyl aryl radical siloxane for example comprises the PSI of 25 ℃ of about 65 centistokes of the about 15-of following viscosity.These siloxanes can be buied with SF 1075 aminomethyl phenyl fluids from for example General E1ectric company, or buy with 556 cosmetics-stage fluids from Dow Corning.In addition, poly-(dimethyl siloxane) (diphenyl siloxane) copolymer of about 100000 centistokes of the about 10-of range of viscosities is also available.Spendable polyether siloxane copolymer is, the dimethyl polysiloxane of poly(propylene oxide) modification (as Dow Corning DC-1248) for example, but the mixture of oxirane or oxirane and expoxy propane also can use.
The list of references of disclosed suitable siloxanes comprises authorized the US2826551 of Green on March 11st, 1958; Authorized the US3964500 of Drakoff on June 22nd, 1967; Nineteen eighty-two, December authorized the US4364837 of Pader on the 21st; GB849433 with nineteen sixty JIUYUE disclosed Wooston on the 28th.All these patents are hereby incorporated by.That also be incorporated herein by reference is Petrarch Systems, Inc., " silicon compound " of 1984 distribution.This document provides comprehensively suitable silicone material catalogue.
Though cationic polymer is not main and can saves that it exists is preferred in compositions.
Cationic polymer includes, but is not limited to following kind:
(i) cationic polysaccharide;
(ii) the monomeric cation copolymer of polysaccharide and synthesizing cationic and
(iii) be selected from following synthetic polymer:
A. cation polyalkyleneimine
B. cationic ethoxy polyalkyleneimine
C. cation is gathered [N-[3-(Dimethyl Ammonium) propyl group] N ' [3-(ethylidene oxygen ethylene ammonium methyl) propyl group] dichloride urea]
D. the polymer that generally has quaternary ammonium or substituted ammonium ion.
Cationic polysaccharides comprises based on those polymer of 5 or 6 carbon sugar with by cationic moiety being grafted to the derivant that makes its cationization on the polysaccharide skeleton.They can be formed by a kind of sugar or more than a kind of sugar, promptly are made up of the copolymer of said derivative and cationic substance.Described monomer can be the straight or branched geometry arrangement.The cationic polysaccharide polymer comprises following material: cationic cellulose and hydroxyethyl-cellulose; Cationic starch and hydroxyalkyl starch; Based on the monomeric cationic polymer of arabinose, as derive from those of arabinose plant gum; Derive from the cationic polymer of the xylose polymer of finding in the materials such as trees, Caulis et Folium Oryzae, cotton seed hull and corn cob; Derive from the cationic polymer of finding in the Sargassum as the fucose polymer of cell wall constituent; Derive from the cationic polymer of the inuloid fructose polymers of finding in the certain plants such as (Inulin); Based on containing saccharic acid, as the cationic polymer of galacturonic acid and glucuronic acid; Based on amine sugar, as the cationic polymer of galactosamine and glycosamine; Cationic polymer based on 5 yuan or 6 yuan cyclopolyols; Based on the monomeric cationic polymer of the galactose in plant gum and the cement; Based on the monomeric cationic polymer of finding in plant, yeast and the red algae etc. of mannose; Based on the cationic polymer of galactomannan copolymer, i.e. the guar gum that obtains from the endosperm of Guar beans.
The instantiation of cationic polysaccharides comprises the cationic hydroxyethyl cellulose JR 400 by the preparation of Union Carbide company; By Staley, the cationic starch Stalok 100,200,300 and 400 of Inc. preparation; Based on the cationic galactomannan of guar gum, Henkel, Galactasol 800 series of company and the Jaguar series of Celanese company.
Be used for the monomeric cation copolymer of polysaccharide of the present invention and synthesizing cationic and comprise those that contain following polysaccharide: the polyhydric alcohol of glucose, galactose, mannose, arabinose, xylose, fucose, fructose, glycosamine, galactosamine, glucuronic acid, galacturonic acid and 5 yuan or 6 yuan rings.The methylol, ethoxy and the hydroxypropyl derivatives that also comprise above-mentioned sugar.When polysaccharide was bonded to each other in copolymer, they can be by any several arrangement mode combinations, as 1, and 4-α; 1,4-β; 1,3 α; 1,3; 1,3 β; With 1,6 bonding.The synthesizing cationic monomer that is used for these copolymers comprises dimethyl diallyl ammonium chloride, dimethyl amino ethyl methacrylate, diethyl diallyl ammonium chloride, N, N-diallyl, N-N-dialkyl group ammonium halide etc.The preferred cation polymer is the Polyquaternium7 by dimethyl dialkyl ammonium chloride and acrylamide monomer preparation.
The example of polysaccharide and the monomeric copolymer of synthesizing cationic comprises available from the Celquat by name of National Starch company, commodity, by cellulose derivative (as hydroxyethyl-cellulose) and N, N-diallyl, those that the N-N-dialkylammonium chloride is formed.
Being used for other cation synthesising copolymer of the present invention is the cation polyalkyleneimine, ethyoxyl polyalkyleneimine and CAS registration number are poly-[N-[3-(Dimethyl Ammonium) propyl group] N '-[3-(ethylidene oxygen ethylene ammonium methyl) propyl group] dichloride urea of 68555-336-2].Preferred cation polymerization skin conditioning agent of the present invention is that molecular weight is the cationic polysaccharide of the guar gum class of 1000-3000000.More preferably molecular weight is 2500-350000.The polysaccharide skeleton of these polymer comprises the galactomannan unit, and the cation substitution value is that each dehydrated glucose unit about 0.04 is to each dehydrated glucose unit about 0.80, the cation group of described replacement is 2, the adduct of 3-glycidyl-trimethyl ammonium chloride and natural polysaccharide skeleton.The JAGUAR C-14-S that example is sold for Celanese company, C-15 and C-17, this material viscosity of its trade literature report 1% is that 125cps is to about 3500 ± 500cps.
The example of other cationic polymer comprises the polymeric material as some quaternary ammonium salt, the copolymer of various materials, as hydroxyethyl-cellulose and dialkyl dimethyl ammonium chloride, acrylamide and β methylacryoyloxyethyl trimethyl sulphuric acid dimethylammonium, quaternary ammonium salt after methyl and stearyl dimethyl amino ethyl methacrylate and dimethyl sulfate are quaternized, by the QAS polymer that the copolymer reaction of dithyl sulfate and vinyl pyrrolidone and dimethyl amino ethyl methacrylate forms, quaternized guar gum and guar gum etc.The example that can be used to prepare the cationic polymer of compound of the present invention comprises, " CTFA international cosmetic ingredient dictionary " (the 4th edition, 1991, p461-464) disclosed: Polyquaternium-1,-2,-4 (copolymers of hydroxyethyl-cellulose and diallyldimethylammonium chloride),-5 (copolymers of acrylamide and β methylacryoyloxyethyl trimethyl sulphuric acid dimethylammonium),-6 (polymer of dimethyl diallyl ammonium chloride),-7 (the polymeric quaternary ammonium salts of acrylamide and dimethyldiallylammonchloride chloride monomer),-8 (methyl and stearyl dimethyl amino ethyl methacrylate are with the quaternised polymer quaternary ammonium salts of dimethyl sulfate),-9 (poly dimethyl amino-ethyl methacrylate is with the quaternised polymer quaternary ammonium salts of MB),-10 (the polymer quaternary ammonium salts of hydroxyethyl-cellulose and trimethyl substituted epoxy ammonium prepared in reaction),-11 (QAS polymer that the copolymer reaction of dithyl sulfate and vinyl pyrrolidone and dimethyl amino ethyl methacrylate forms),-12 (by the polymer quaternary ammonium salts of ethyl-methyl acrylate/abietyl methacrylate/diethylamino ethyl-methyl acrylate copolymer and dimethyl sulfate prepared in reaction),-13 (by the polymer quaternary ammonium salts of ethyl-methyl acrylate/oil base methacrylate/diethylamino ethyl-methyl acrylate copolymer and dimethyl sulfate prepared in reaction),-14,-15 (copolymers of acrylamide and β methylacryoyloxyethyl trimethyl ammonium chloride),-16 (the polymer quaternary ammonium salts that form by methyl ethylene imidazolitm chloride quinoline and vinyl pyrrolidone),-17,-18,-19 (by polyvinyl alcohol and 2, the polymer quaternary ammonium salt of 3 epoxy propylamine prepared in reaction),-20 (by polyvinyl octadecyl ether and 2, the polymer quaternary ammonium salt of 3 epoxy propylamine prepared in reaction),-22,-24 (the polymer quaternary ammonium salts of hydroxyethyl-cellulose and lauryl dimethyl substituted epoxy ammonium prepared in reaction),-27 (reacting the block copolymer that forms) by Polyquaternium-2 (q.v.) and Polyquaternium-17 (q.v.),-28,-29 (they being the Chitosan (q.v.) of expoxy propane and chloropropylene oxide quaterisation preparation), and-30.
Preferred surfactants is an anion surfactant, as soap, and the alkyl isethionate, as the coco group hydroxyethyl sulfonate, sulfonate, sulfate (optional ethoxylation) etc.Can use surfactant mixtures.Should exist enough surfactants to produce cleaning action.The described surfactant that is preferably anion or its mixture can different amounts be present in the compositions, described mixture comprises that one or more other type list surface-active agents (both sexes, nonionic etc.) are added with other anion surfactant, or is not added with other anion surfactant.For example, the minimum of described surfactant can be wide to 1,2,3,4,5,10,15 or 20% weight that accounts for compositions, particularly under the situation of liquid aqueous composition.For liquid state, Aquo-composition, anion surfactant accounts for about 25% weight of about 2%-of compositions, specifically is about 20% weight of about 5%-.Can there be other surfactant, as amphoteric surfactant, the many glycosides of particularly betanin, and non-ionic surface active agent, particularly alkylation.Their amount accounts for about 20% weight of about 1%-of compositions.The amount of total surfactant preferably at least about 5% weight, but is no more than about 30% weight at least about 3% or 4% weight usually in the liquids in general compositions, preferably is no more than about 25% weight, but can be low to moderate more than about 10,15 or 20%.For solid composite, total surfactant accounts for about 60-90% weight of compositions, preferably about 70-85% weight.The amount of soap is about 15-100% weight of total surfactant.Usually the soap that contains the 65-90% weight of having an appointment in " soap bar ", and other surfactant is lower than about 10% weight, preferably is lower than about 5% weight.Most preferably be wherein to have 0 or other surfactant of about 2% weight of 0-.In disclosed soap bar scope, contain than can contain gentle synthetic surfactant with moderate or high-load usually in the soap bar of small amounts of soap, as the coco group hydroxyethyl sulfonate.
If there is hydrocarbon component, its amount should be at least the about 0.1% of compositions, preferred about 0.5% weight.Though can use the described material of about 7% or 8% weight, preferably account for maximum about 5% weight of compositions, preferred about 4.5% weight.If there is siloxanes in the compositions, its minimum is about 0.01% weight of compositions, preferably at least about 0.1% weight.Its maximum can be different, but are no more than about 7% or 8% weight of compositions usually, preferred about 5% weight, more preferably from about 4.5% weight.
When using cationic polymer in the compositions, it is about 3.0% that the amount of polymer accounts for about 0.01%-of compositions, preferred minimum about 0.02% weight, more preferably minimum about 0.03% weight.Its maximum is no more than about 0.9% weight usually, or about 0.75% weight, though also can use lower maximum, 0.6% weight according to appointment.
The form of compositions can be liquid, solid or gel.Solid can be mixed with " bar ", and it can be the hands gel that is used to clean purpose.Liquid can be mixed with and can pour out from container, or the pump by hand motion and so on the viscosity of discharging.
The spice effect that is used for this description can comprise making the specific compound that fragrance is provided increase deposition on skin, prolongs the release of spice on skin, selective deposition etc. on skin.Described spice Ying Yineng provides the amount of fragrance to exist.Usually, compositions at least about 0.01% weight, be spice preferably at least about 0.1% weight.Maximum depends on the intensity and the amount of required fragrance usually.The general use is no more than about 2% weight of compositions, preferably is no more than the spice of about 1.5% weight.
Claims (8)
1. a cleaning skin and after the skin flushing can make the method that the spice benefit improves in the cleaning combination, and this method comprises a kind of compositions is applied to skin that said composition contains:
(a) clean a kind of surfactant of skin q.s or the mixture of kinds of surface activating agent,
(b) q.s provides the spice of fragrance,
(c) the q.s siloxanes that the spice benefit is improved, hydrocarbon component or its mixture rinse out said composition then.
2. also there is cationic polymer according to the process of claim 1 wherein in the compositions.
3. exist 0-to be less than the siloxanes of about 0.01% weight according to the process of claim 1 wherein in the compositions, and have hydrocarbon component.
4. exist 0-to be less than the hydrocarbon component of about 0.1% weight according to the process of claim 1 wherein in the compositions, and have silicone components.
5. the compositions that contains following compositions:
(a) a kind of surfactant or the kinds of surface active agent intermixture of cleaning skin q.s,
(b) q.s provides the spice of fragrance,
(c) the q.s siloxanes that the spice benefit is improved, hydrocarbon component or its mixture can improve the application aspect the skin-cleaning composition of spice benefit in preparation.
6. according to the application of claim 5, wherein said benefit is to increase the deposition of spice on skin.
7. according to the application of claim 5, wherein said benefit is to prolong the release of spice on skin.
8. (a) who comprises claim 1, (b) and (c) compositions of component.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8745898P | 1998-06-01 | 1998-06-01 | |
| US60/087,458 | 1998-06-01 | ||
| US30409999A | 1999-05-04 | 1999-05-04 | |
| US09/304,099 | 1999-05-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1331578A true CN1331578A (en) | 2002-01-16 |
Family
ID=26776992
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99809259.2A Pending CN1331578A (en) | 1998-06-01 | 1999-05-28 | Skin cleansing compsn. providing enhanced perfumed deposition |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP1082094A1 (en) |
| CN (1) | CN1331578A (en) |
| AR (1) | AR018618A1 (en) |
| AU (1) | AU4410599A (en) |
| BR (1) | BR9910844A (en) |
| CA (1) | CA2333906A1 (en) |
| GT (1) | GT199900076A (en) |
| HU (1) | HUP0102299A3 (en) |
| IL (1) | IL139803A0 (en) |
| NO (1) | NO20006081D0 (en) |
| TR (1) | TR200003550T2 (en) |
| WO (1) | WO1999062477A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6180577B1 (en) * | 1998-06-01 | 2001-01-30 | Colgate-Palmolive Company | Anti-germ attachment—composition |
| CN101299987B (en) | 2005-11-01 | 2014-05-07 | 宝洁公司 | Multi-phase personal care composition comprising a stabilizing perfume composition |
| US20070141001A1 (en) | 2005-12-15 | 2007-06-21 | The Procter & Gamble Company | Non-migrating colorants in multi-phase personal cleansing compositions |
| US8076280B2 (en) | 2006-12-20 | 2011-12-13 | Basf Se | Emulsions containing encapsulated fragrances and personal care compositions comprising said emulsions |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9200764D0 (en) * | 1992-01-15 | 1992-03-11 | Unilever Plc | Cosmetic composition |
| JPH05263097A (en) * | 1992-03-19 | 1993-10-12 | Mandamu:Kk | Fragrant composition |
| GB9511938D0 (en) * | 1995-06-13 | 1995-08-09 | Unilever Plc | Cosmetic composition |
| US6008173A (en) * | 1995-11-03 | 1999-12-28 | Colgate-Palmolive Co. | Bar composition comprising petrolatum |
| US5843875A (en) * | 1996-06-20 | 1998-12-01 | The Procter & Gamble Company | Perfume delivery systems in liquid personal cleansing |
| EP0908174A2 (en) * | 1997-09-18 | 1999-04-14 | INTERNATIONAL FLAVORS & FRAGRANCES INC. | Compositions for fragrancing at least one perfumable material and fragrance diffusion evaluation apparatus |
-
1999
- 1999-05-28 EP EP99927125A patent/EP1082094A1/en not_active Withdrawn
- 1999-05-28 HU HU0102299A patent/HUP0102299A3/en unknown
- 1999-05-28 TR TR2000/03550T patent/TR200003550T2/en unknown
- 1999-05-28 WO PCT/US1999/012102 patent/WO1999062477A1/en not_active Application Discontinuation
- 1999-05-28 CN CN99809259.2A patent/CN1331578A/en active Pending
- 1999-05-28 BR BR9910844-5A patent/BR9910844A/en not_active IP Right Cessation
- 1999-05-28 AU AU44105/99A patent/AU4410599A/en not_active Abandoned
- 1999-05-28 CA CA002333906A patent/CA2333906A1/en not_active Abandoned
- 1999-05-28 IL IL13980399A patent/IL139803A0/en unknown
- 1999-06-01 AR ARP990102591A patent/AR018618A1/en unknown
- 1999-06-01 GT GT199900076A patent/GT199900076A/en unknown
-
2000
- 2000-11-30 NO NO20006081A patent/NO20006081D0/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GT199900076A (en) | 2000-11-22 |
| AR018618A1 (en) | 2001-11-28 |
| HUP0102299A3 (en) | 2003-04-28 |
| TR200003550T2 (en) | 2001-04-20 |
| HUP0102299A2 (en) | 2001-11-28 |
| BR9910844A (en) | 2001-02-20 |
| IL139803A0 (en) | 2002-02-10 |
| NO20006081L (en) | 2000-11-30 |
| AU4410599A (en) | 1999-12-20 |
| EP1082094A1 (en) | 2001-03-14 |
| WO1999062477A1 (en) | 1999-12-09 |
| NO20006081D0 (en) | 2000-11-30 |
| CA2333906A1 (en) | 1999-12-09 |
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