CN1328222C - Self straggle reaction connocting method of TiAl alloy and TiB2 metal ceramics - Google Patents
Self straggle reaction connocting method of TiAl alloy and TiB2 metal ceramics Download PDFInfo
- Publication number
- CN1328222C CN1328222C CNB200510010468XA CN200510010468A CN1328222C CN 1328222 C CN1328222 C CN 1328222C CN B200510010468X A CNB200510010468X A CN B200510010468XA CN 200510010468 A CN200510010468 A CN 200510010468A CN 1328222 C CN1328222 C CN 1328222C
- Authority
- CN
- China
- Prior art keywords
- tib
- tial alloy
- powder
- self
- ceramic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Ceramic Products (AREA)
- Powder Metallurgy (AREA)
Abstract
The present invention relates to a method for connecting TiAl alloy with TiB2 metal ceramic by a self-propagating reaction. The present invention relates to a welding method for TiAl alloy and TiB2 metal ceramic. The method is simple and overcomes the defects of complicated device and troublesome process existing in the prior art. The method comprises the following steps: TiAl alloy and TiB 2 metal ceramic are preheated by a high-frequency electromagnetic field; the axial pressure of 30MPa to 60MPa is applied to the alloy and the metal ceramic which are superposed when the high-frequency electromagnetic field is continuously applied, a powder pressed compact clamped between the alloy and the metal ceramic is ignited by the high-frequency electromagnetic field and generates a self-propagating reaction, the alloy is connected with the metal ceramic, wherein the powder pressed compact is prepared by pressing Ti powder and Mo powder which are uniformly mixed or is prepared by pressing Ti powder and Mo powder which are uniformly mixed. The method has the advantages of preheated parent material, one-time accomplishment of the self-propagating reaction of the ignited pressed compact by high-frequency induction heating, simplicity and low requirement to devices.
Description
Technical field
The present invention relates to TiAl alloy and TiB
2Ceramic-metallic welding process belongs to intermetallic compound jointing field.
Background technology
Along with the development of hard-core technologies such as advancing by leaps and bounds of modern science and technology, particularly space flight, aviation, nuclear power, more and more higher requirement has been proposed for the performance of material.At present, no matter be from economy or from the angle of practicality, single-material has been difficult to satisfy the demand of modern production technology to the material over-all properties, and therefore, the Materials science worker just is being devoted to research and develop the interconnection technique of novel material and foreign material both at home and abroad.Titanium aluminium base alloy has that density is little (to be about 3.8g/cm
3), advantage such as specific tenacity height, good rigidly, good high-temperature mechanical property and oxidation-resistance, be considered to a kind of ideal, be rich in Aeronautics and Astronautics, military affairs and the civilian new type high temperature structured material of development prospect.TiB
2Being connected to use in sintering metal and TiAl alloy of hot environment to(for) the TiAl alloy has very important significance.Because physics, the chemical property of these two kinds of materials differ greatly, and fusing point is than higher, and traditional fusion welding method is difficult to realize the connection of these two kinds of materials, and possible method of attachment relates generally to diffusion and connects and soldering.But TiAl alloy and TiB
2Fragility is mutually more in the ceramic-metallic diffusion jointing reaction product, and joint efficiency is very low, and unrelieved stress is very big at the interface, and joint quality is difficult to control, therefore is difficult to be applied.Although the effect of relieve stresses has been played in the fusing of solder in the brazing process; but brazed joint use at high temperature is restricted; and diffusion connects and soldering is very high to the requirement of equipment, the heating installation that general requirement is bigger and generally need vacuum or protective atmosphere.Publication number provides a kind of " pottery causes the self-propagating combustion connection method with metal field " for the patent of CN1475463A, the defective that this method exists is need with special ignition device to connect, the required equipment relative complex, and require the necessary nickel plating of ceramic surface, technology is more loaded down with trivial details.
Summary of the invention
The object of the present invention is to provide a kind of TiAl alloy and TiB
2Ceramic-metallic self-propagating reaction method of attachment should method is simple, overcome prior art equipment complexity, defective that technology is loaded down with trivial details.Present method comprises the steps: one, gives TiAl alloy and TiB with the higher frequency electromagnetic field
2The sintering metal preheating; Give stacked TiAl alloy and TiB when two, continuing to apply the higher frequency electromagnetic field
2Sintering metal applies the axle pressure of 30-60MPa, is clipped in TiAl alloy and TiB
2Powder compact between the sintering metal is realized TiAl alloy and TiB by the higher frequency electromagnetic field concurrent straggle reaction of being conigenous that ignites
2Ceramic-metallic connection, described powder compact by the powder mixes of Ti, Al, C, Ni and Mo evenly the back compacting form or by the powder mixes of Ti, Al, B, Ni and Mo evenly the back compacting form.The weight percent of being suppressed each component of powder compact that forms by Ti, Al, C, Ni and Mo is: Ti:27.5～45%, Al:15～25%, C:8～10%, Mo:3～5%, surplus are Ni; The weight percent of being suppressed each component of powder compact that forms by Ti, Al, B, Ni and Mo is: Ti:22.5～40%, Al:15～20%, B:10～15%, Mo:4～8%, surplus are Ni.The weight percent of being suppressed each component of powder compact that forms by Ti, Al, C, Ni and Mo is: Ti:27.5～45%, Al:15～25%, C:8～10%, Mo:3～5%, surplus are Ni; The weight percent of being suppressed each component of powder compact that forms by Ti, Al, B, Ni and Mo is: Ti:22.5～40%, Al:15～20%, B:10～15%, Mo:4～8%, surplus are Ni.
After adopting high-frequency induction heating that special composition Ti-Al-C-Ni-Mo or Ti-Al-B-Ni-Mo middle layer powder pressed compact are ignited among the present invention, utilize the self-propagating reaction liberated heat as connecting thermal source, simultaneously auxiliary TiAl alloy and the TiB of realizing down in the higher frequency electromagnetic field
2Sintering metal connects, and powder compact of the present invention is very big as its exothermic heat of reaction amount of middle layer reaction system, the temperature of igniting very low and also ignite after can realize self-propagating reaction.Mainly in order to reduce the ignition temperature of system, Ti-C or Ti-B are main heat release system in the adding of Al in the powder pressed compact of middle layer, and the adding of Mo can improve the wettability between Ni and the TiC.Ni in the powder pressed compact of middle layer can improve at the interface wetting situation and density on the one hand mainly as the thinner of entire reaction, can improve the mechanical behavior under high temperature and the use temperature of joint on the other hand.The radio-frequency induction coil that generates an electromagnetic field is both as giving TiAl alloy and TiB
2The device of sintering metal preheating has reduced the complexity of equipment again as the ignition device of self-propagating reaction; Do not need in the connection procedure to carry out Nickel Plating Treatment to any position.Present method has simple, the efficient and energy-saving advantages of step, has bigger promotional value.
Embodiment
Embodiment one: present method comprises the steps: one, gives TiAl alloy and TiB with the higher frequency electromagnetic field
2The sintering metal preheating.The frequency of higher frequency electromagnetic field is 20～30 hertz.Give stacked TiAl alloy and TiB when two, continuing to apply the higher frequency electromagnetic field
2Sintering metal applies the axle pressure of 30-60MPa, is clipped in TiAl alloy and TiB
2Powder compact between the sintering metal is realized TiAl alloy and TiB by the higher frequency electromagnetic field concurrent straggle reaction of being conigenous that ignites
2Ceramic-metallic connection, described powder compact by the powder mixes of Ti, Al, C, Ni and Mo evenly the back compacting form or by the powder mixes of Ti, Al, B, Ni and Mo evenly the back compacting form.The Ti-Al-C-Ni-Mo powder compact that adopts, the weight percent of its each component is: Ti:27.5～45%, Al:15～25%, C:8～10%, Mo:3～5%, surplus are Ni; The Ti-Al-B-Ni-Mo powder compact that adopts, the weight percent of its each component is: Ti:22.5～40%, Al:15～20%, B:10～15%, Mo:4～8%, surplus are Ni.The metal-powder of selecting for use in the starting powder of pressed powder pressed compact is nanometer powder; the granularity and the purity of starting powder are respectively: Ti (purity 〉=98.5%; granularity≤70nm); Al (purity 〉=99.9%, granularity≤35nm), C (purity 〉=99%; granularity≤1 μ m); Ni (purity 〉=99.5%, granularity≤50nm), Mo (purity 〉=99%; granularity≤90nm) and Ti (purity 〉=98.5%; granularity≤70nm), Al (purity 〉=99.9%, granularity≤35nm); B (purity 〉=99%; granularity≤2 μ m, amorphous), Ni (purity 〉=99.5%; granularity≤50nm); (purity 〉=99%, granularity≤90nm), starting powder adopts ball mill to do under argon shield and mixed 24 hours Mo.Powder compact is about 1mm being pressed into thickness under the pressure of 300～500MPa.Adopt the composition range of the TiAl alloy of the inventive method connection to be: Ti:31～78 (at%), Al:22～69 (at%), V:1.0～3.0 (at%), Cr:1.5～2.5 (at%), Nb:1.5～2.5 (at%).TiB
2The sintering metal composition range is: TiB
2: 42～68 (at%), Cu:32～58 (at%).
Embodiment two: the difference of present embodiment and embodiment one is that it also comprises the steps: three, gives stacked TiAl alloy and TiB when continuing to apply the higher frequency electromagnetic field
2Sintering metal applies the axle pressure of 10～40MPa, makes the TiAl alloy and the TiB that connect through preliminary
2Sintering metal is finished the diffusion and the homogenizing of jointing place elemental composition under the condition of high-frequency induction heating.Preliminary jointing after present embodiment is finished self-propagating reaction spreads with homogenizing and handles with high-frequency induction heating and pressurization, finally obtains the high quality jointing.Other step is identical with embodiment one.
Embodiment three: the difference of present embodiment two is: in step 3, high-frequency induction heating is to TiAl alloy and TiB
2The temperature at sintering metal jointing place is 1200～1300K, keeps 40～60min, stops heating then, TiAl alloy and TiB
2When being cooled to 373K, sintering metal removes pressure.Other step is identical with embodiment two.
Embodiment four: the difference of present embodiment and embodiment three is: the composition of TiAl alloy to be welded is: Ti-46.5Al-2.5V-1.0Cr (at%), TiB
2Ceramic-metallic composition is: TiB
2-40Cu (wt%).Soldered surface is with 400
#, 500
#, 600
#, 800
#, 1000
#Abrasive paper for metallograph polishes step by step, adopts ultrasonic washing instrument to clean in acetone soln then.According to Ti:27.5～45%, Al:15～25%, C:8～10%, Mo:3～5%, surplus is the powder that the ratio of Ni weighs each component, adopt ball mill under argon shield, to mix 24 hours in the powder of above component, the ratio of grinding media to material that ball mill adopts is 5～10: 1, adopts the axle pressure of 400～500MPa that starting powder is pressed into powder compact; Adopt the high-frequency induction heating mode to TiAl alloy and TiB
2The sintering metal joint is heated near the Al element fusing point, finishes the powder compact self-propagating reaction that ignites when workpiece partial preheating handles, and the self-propagating reaction by powder compact adds auxiliary TiAl alloy and the TiB of realizing down of electromagnetic field outside
2Ceramic-metallic preliminary connection, the weldment of finishing preliminary connection continue to adopt high-frequency induction heating to finish the processing of diffusion homogenizing, and treating processes finishes back weldment cooling, finishes.Other step is identical with embodiment three.
Embodiment five: the difference of present embodiment and embodiment four is: according to weight percent be Ti:22.5～40%, Al:15～20%, B:10～15%,, Mo:3～8%, surplus are the ratio preparation starting powder of Ni, adopt the pressure of 300～400MPa that well-mixed starting powder is pressed into powder compact.The axial connection pressure that keeps 40～60MPa in the self-propagating reaction connection procedure.
Claims (4)
1, TiAl alloy and TiB
2Ceramic-metallic self-propagating reaction method of attachment is characterized in that it comprises the steps: one, gives TiAl alloy and TiB with the higher frequency electromagnetic field
2The sintering metal preheating; Give stacked TiAl alloy and TiB when two, continuing to apply the higher frequency electromagnetic field
2Sintering metal applies the axle pressure of 30-60MPa, is clipped in TiAl alloy and TiB
2Powder compact between the sintering metal is realized TiAl alloy and TiB by the higher frequency electromagnetic field concurrent straggle reaction of being conigenous that ignites
2Ceramic-metallic connection, described powder compact by the powder mixes of Ti, Al, C, Ni and Mo evenly the back compacting form or by the powder mixes of Ti, Al, B, Ni and Mo evenly the back compacting form; The weight percent of being suppressed each component of powder compact that forms by Ti, Al, C, Ni and Mo is: Ti:27.5～45%, Al:15～25%, C:8～10%, Mo:3～5%, surplus are Ni; The weight percent of being suppressed each component of powder compact that forms by Ti, Al, B, Ni and Mo is: Ti:22.5～40%, Al:15～20%, B:10～15%, Mo:4～8%, surplus are Ni.
2, TiAl alloy according to claim 1 and TiB
2Ceramic-metallic self-propagating reaction method of attachment is characterized in that it also comprises the steps: three, gives stacked TiAl alloy and TiB when continuing to apply the higher frequency electromagnetic field
2Sintering metal applies the axle pressure of 10～40MPa.
3, TiAl alloy according to claim 2 and TiB
2Ceramic-metallic self-propagating reaction method of attachment is characterized in that in step 3 high-frequency induction heating is to TiAl alloy and TiB
2The temperature at sintering metal jointing place is 1200～1300K, keeps 40～60min, stops heating then, TiAl alloy and TiB
2When being cooled to 373K, sintering metal removes pressure.
4, TiAl alloy according to claim 3 and TiB
2Ceramic-metallic self-propagating reaction method of attachment is characterized in that the composition of TiAl alloy to be welded is: Ti-46.5Al-2.5V-1.0Cr (at%), TiB
2Ceramic-metallic composition is: TiB
2-40Cu (wt%), soldered surface uses 400 respectively
#, 500
#, 600
#, 800
#, 1000
#Abrasive paper for metallograph polishes step by step, adopt ultrasonic washing instrument in acetone soln, to clean then, according to Ti:27.5～45%, Al:15～25%, C:8～10%, Mo:3～5%, surplus is the powder that the ratio of Ni weighs each component, adopt ball mill under argon shield, to mix 24 hours in the powder of above component, the ratio of grinding media to material that ball mill adopts is 5～10: 1, and the axle pressure that adopts 400～500MPa is with above-mentioned powder compression powdered pressed compact; Adopt the high-frequency induction heating mode to TiAl alloy and TiB
2The sintering metal joint is heated near the Al element fusing point, finishes the powder compact self-propagating reaction that ignites when workpiece partial preheating handles, and the self-propagating reaction by powder compact adds auxiliary TiAl alloy and the TiB of realizing down of electromagnetic field outside
2Ceramic-metallic preliminary connection, the weldment of finishing preliminary connection continue to adopt high-frequency induction heating to finish the processing of diffusion homogenizing, and treating processes finishes back weldment cooling, finishes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200510010468XA CN1328222C (en) | 2005-10-25 | 2005-10-25 | Self straggle reaction connocting method of TiAl alloy and TiB2 metal ceramics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200510010468XA CN1328222C (en) | 2005-10-25 | 2005-10-25 | Self straggle reaction connocting method of TiAl alloy and TiB2 metal ceramics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1785913A CN1785913A (en) | 2006-06-14 |
| CN1328222C true CN1328222C (en) | 2007-07-25 |
Family
ID=36783533
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB200510010468XA Expired - Fee Related CN1328222C (en) | 2005-10-25 | 2005-10-25 | Self straggle reaction connocting method of TiAl alloy and TiB2 metal ceramics |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1328222C (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101333116B (en) * | 2008-07-30 | 2010-06-02 | 哈尔滨工业大学 | Method of Brazing ceramic and ceramic-based composite material with titan alloy |
| CN101786899B (en) * | 2010-01-26 | 2012-07-04 | 哈尔滨工业大学 | Solder for welding carbon/silicon carbide ceramic matrix composite material and titanium-aluminum-based alloy and soldering method |
| CN101880793A (en) * | 2010-07-09 | 2010-11-10 | 哈尔滨工业大学 | TiB2/TiAl composite panel and preparation method thereof |
| CN102489811B (en) * | 2011-12-09 | 2013-07-31 | 哈尔滨工业大学 | Method for carrying out self-propagating reaction assisted brazed connection on C/C (carbon/carbon) composites and TiAl |
| CN109778176A (en) * | 2019-01-11 | 2019-05-21 | 武汉科技大学 | A kind of preparation method of high-frequency induction auxiliary self-spreading TiAl series intermetallic compound coating |
| CN113929487B (en) * | 2020-06-29 | 2023-03-31 | 南京纳研企业管理合伙企业(有限合伙) | Piezoelectric ceramic composite material and preparation method and application thereof |
| CN111747769B (en) * | 2020-06-30 | 2022-12-09 | 哈尔滨工业大学（威海） | AlMgB 14 -TiB 2 Vacuum brazing method for composite ceramic and TiAl-based alloy |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0569159A (en) * | 1991-09-13 | 1993-03-23 | Nhk Spring Co Ltd | Method for joining composite material composed of, at least, one part of intermetallic compound |
| US5863670A (en) * | 1995-04-24 | 1999-01-26 | Nhk Spring Co., Ltd. | Joints of Ti-Al intermetallic compounds and a manufacturing method therefor |
| US6291086B1 (en) * | 1997-04-04 | 2001-09-18 | Xuan Nguyen-Dinh | Friction welding interlayer and method for joining gamma titanium aluminide to steel, and turbocharger components thereof |
| CN1475463A (en) * | 2003-06-05 | 2004-02-18 | 太原理工大学 | Ceramic and metal field self extending combustion connecting method |
-
2005
- 2005-10-25 CN CNB200510010468XA patent/CN1328222C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0569159A (en) * | 1991-09-13 | 1993-03-23 | Nhk Spring Co Ltd | Method for joining composite material composed of, at least, one part of intermetallic compound |
| US5863670A (en) * | 1995-04-24 | 1999-01-26 | Nhk Spring Co., Ltd. | Joints of Ti-Al intermetallic compounds and a manufacturing method therefor |
| US6291086B1 (en) * | 1997-04-04 | 2001-09-18 | Xuan Nguyen-Dinh | Friction welding interlayer and method for joining gamma titanium aluminide to steel, and turbocharger components thereof |
| CN1475463A (en) * | 2003-06-05 | 2004-02-18 | 太原理工大学 | Ceramic and metal field self extending combustion connecting method |
Non-Patent Citations (4)
| Title |
|---|
| Hardness measurement of (TiB2-TiAl)/TiAl symmetricallyFunction Gradient Material 梅炳初，武汉理工大学学报英文版，第17卷第3期 2002 * |
| TiB2金属陶瓷与TiAl的自蔓延高温合成连接 李卓然，焊接学报，第24卷第6期 2003 * |
| TiB2金属陶瓷与TiAl金属间化合物的扩散连接 李卓然，焊接学报，第24卷第2期 2003 * |
| 场助自蔓延高温连接TiAl合金的中间层选择 曹健，焊接学报，第25卷第5期 2004 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1785913A (en) | 2006-06-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1328222C (en) | Self straggle reaction connocting method of TiAl alloy and TiB2 metal ceramics | |
| CA1268322A (en) | Direct liquid phase bonding of ceramics to metals | |
| CN102489811B (en) | Method for carrying out self-propagating reaction assisted brazed connection on C/C (carbon/carbon) composites and TiAl | |
| US9299636B2 (en) | Heat sink for electronic device and process for production thereof | |
| CN102430829B (en) | Method for raising brazing strength for ZrB2-based material | |
| CN108546095A (en) | A kind of method that oxide ceramics is welded to connect with metal | |
| CN108558428A (en) | A kind of composite interlayer and its Joining Technology for spreading connection silicon carbide ceramics | |
| CN105643038B (en) | Brazed porous Si3N4The method of ceramics and Invar alloys | |
| Appendino et al. | Joining of C/C composites to copper | |
| CN101462890A (en) | Connecting method for Cf/SiC composite material and titanium alloy | |
| CN102689096A (en) | Method for laser-induced self-propagating connection between carbon fiber reinforced aluminum-based composite and metal | |
| CN108838504A (en) | It is a kind of for spread connection silicon carbide ceramics composite interlayer and its Joining Technology | |
| CN109454321B (en) | Hot isostatic pressing diffusion connection method for tungsten/steel cylinder structural member | |
| CN106588064B (en) | The solder and connection method of carbon/carbon compound material and nickel base superalloy | |
| CN103600169A (en) | Method for connecting Cf/Al composite with TiAl based on laser ignition and self-propagating reaction | |
| CN102219539A (en) | Reaction diffusion connection method of ceramic composite material and metal | |
| CN108947558A (en) | A kind of metal and Ti3SiC2The connection method of ceramics | |
| Feng et al. | Joining SiC ceramic and metal Mo with AuPdCoMnNi alloy and interfacial reactions | |
| CN106216879B (en) | A kind of Cu-TiH2- Ni+B composite solders and its preparation method and application | |
| CN108555476B (en) | Composite brazing filler metal for brazing quartz fiber reinforced composite ceramic and Invar alloy and preparation method and brazing method thereof | |
| CN109943755A (en) | A kind of preparation method of aluminum matrix composite used for electronic packaging | |
| CN116334435B (en) | Silicon carbide aluminum-based composite material and preparation method and application thereof | |
| CN106736030B (en) | A kind of application method of solder in welding C/SiC composite material and metal | |
| CN114406258A (en) | Thermite reduction reaction powder coated ZTA ceramic particles and preparation method and application thereof | |
| CN110026634B (en) | Method for brazing carbon fiber reinforced carbon-based composite material by using Si-Zr high-temperature brazing filler metal |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070725 Termination date: 20091125 |