CN1325378C - Modified molecular sieve and its prepn process - Google Patents
Modified molecular sieve and its prepn process Download PDFInfo
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- CN1325378C CN1325378C CNB2003101049036A CN200310104903A CN1325378C CN 1325378 C CN1325378 C CN 1325378C CN B2003101049036 A CNB2003101049036 A CN B2003101049036A CN 200310104903 A CN200310104903 A CN 200310104903A CN 1325378 C CN1325378 C CN 1325378C
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical class [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims abstract description 89
- 238000000034 method Methods 0.000 title claims abstract description 29
- 239000002808 molecular sieve Substances 0.000 claims abstract description 81
- 239000002253 acid Substances 0.000 claims abstract description 37
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 17
- 239000010703 silicon Substances 0.000 claims abstract description 17
- 238000005342 ion exchange Methods 0.000 claims abstract description 9
- 238000002360 preparation method Methods 0.000 claims description 20
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 9
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- 229910017604 nitric acid Inorganic materials 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 7
- 239000011707 mineral Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 5
- 150000007524 organic acids Chemical class 0.000 claims description 5
- 229940095064 tartrate Drugs 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- 229940070337 ammonium silicofluoride Drugs 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 238000010992 reflux Methods 0.000 claims description 2
- 238000002425 crystallisation Methods 0.000 abstract description 35
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
- 229930195733 hydrocarbon Natural products 0.000 abstract description 7
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 7
- 239000000843 powder Substances 0.000 abstract description 5
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 230000008025 crystallization Effects 0.000 description 33
- 239000000243 solution Substances 0.000 description 32
- 238000001035 drying Methods 0.000 description 19
- 206010013786 Dry skin Diseases 0.000 description 18
- 238000001914 filtration Methods 0.000 description 17
- 238000013019 agitation Methods 0.000 description 16
- 238000005406 washing Methods 0.000 description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- 239000000499 gel Substances 0.000 description 9
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- -1 diamine compounds Chemical class 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 159000000013 aluminium salts Chemical class 0.000 description 3
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 210000002421 cell wall Anatomy 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000011218 segmentation Effects 0.000 description 3
- 239000000741 silica gel Substances 0.000 description 3
- 229910002027 silica gel Inorganic materials 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229960001866 silicon dioxide Drugs 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000004645 aluminates Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 150000008040 ionic compounds Chemical class 0.000 description 2
- 238000006317 isomerization reaction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000010189 synthetic method Methods 0.000 description 2
- QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical compound Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 description 1
- 241000269350 Anura Species 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
- 229910002796 Si–Al Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000000295 emission spectrum Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009415 formwork Methods 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
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- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
The present invention relates to a modified molecular sieve and a preparing method thereof. The molecular sieve initial powder which comprises an organic mould plate agent is firstly processed, the organic mould plate agent is completely eliminated, and the modified molecular sieve is prepared by ion exchanging, dealuminizing, silicon complementing, etc. The modified molecular sieve provided by the method of the present invention has the characteristics of high crystallisation degree, high surface phase / volume phase of Si/Al ratio, etc. Besides, the modified molecular sieve obviously lowers the acid size, and remains the fundamental invariant of L acid. The modified molecular sieve of the present invention has higher activity and selectivity when the modified molecular sieve is used for processing hydrocarbon.
Description
Technical field
The present invention relates to a kind of modified molecular screen and preparation method thereof, in particular, provide the preparation method of a kind of TON of having type constitutional features modified molecular screen and this molecular sieve.
Background technology
Molecular sieve is the important member in the crystalline material, has the crystalline structure (can characterize with XRD) of regular pore structure.A variety of molecular sieves have been had been found that at present, zeolite A for example, ZSM series, β, X, Y, mesoporous molecular sieve such as micro porous molecular sieve such as SAPO series and MCM-41.
The shape and size in the absorption of molecular sieve and catalytic performance and its duct and hole have substantial connection, and the molecular sieve of Different Pore Structures generally has different purposes.For example the ZSM-5 molecular sieve is mainly used in the reaction process such as shape slective cracking, alkylation, small molecules isomerization, toluene disproportionation, catalytic dewaxing and etherificate of hydro carbons, Y molecular sieve is applied to processes such as the cracking, aromatic hydrogenation of hydro carbons, and SAPO-11 is applied to the isomerization reaction of paraffinic hydrocarbon etc.
In the 1980s, the high silicon Si-Al zeolite molecular sieve that a class is new is found, and its XRD result has table 1 feature, and its code name is the TON structure molecular screen, for example THA-1, Nu-10, KZ-2, ISI-1 and ZSM-22 etc.This molecular sieve analog is to belong to rhombic system, has 10 Yuans annular distance mouths (5.5 * 4.5 ) and one dimension ellipse duct.Compare with other molecular sieve, for example ZSM-5 has the pore canal system (53 * 5.6 and 5.1 * 5.5 ) of two intersections or the hole that ZSM-35 has one 6 ～7 diameters, in the pour point depression reaction of the particularly high condensation point distillate of distillate, have unique heterogeneous activity and good anti-coking performance.
The XRD result of table 1TON structure molecular screen
| d hkl(nm) | I/I 0 |
| 1.090±0.02 | N-W |
| 0.870±0.016 0.694±0.010 0.458±0.007 0.436±0.007 0.368±0.005 0.362±0.005 0.347±0.004 0.252±0.002 | VW VW VW VS VS S M W-VW |
The represented relative intensity of symbol is worth as follows in the form: VS, 80%-100%; S, 60%-80%; M, 40%-60%; W, 20%-4%0; VW,＜20%.
Having of relevant TON structure molecular screen: USP4481177 discloses the method that a kind of low whipping speed is synthetic ZSM-22 under the 400RPM condition; EP-A-65400 discloses a kind of synthetic method of called after NU-10 molecular sieve, needs to stir in crystallization process; EP-A-87017 discloses the molecular sieve of a kind of called after ISI-1, and crystallization process is to finish under agitation condition; EP-A77624 discloses a kind of synthetic method of called after NU-10 molecular sieve; EP-A-57049 discloses the molecular sieve preparation method of a kind of called after THETA-1, and this process is finished in the rotation voltage-resistant reactor.
The molecular sieve surface generally has B acid site and L acid site, and the B acid site is acid strong, and the cracking function is strong, the L acid site a little less than, the isomery function is strong, therefore for different reaction types, the acid sites that needs is different.And the common B of existing molecular sieve acid site is more, and the L acid site is less, molecular sieve after treatment, and reduce simultaneously in B acid site and L acid site, and this is disadvantageous to being applied to need the reaction process of isomery function.
Summary of the invention
At the deficiencies in the prior art, the invention provides a kind of modified molecular screen and preparation method thereof, modified molecular screen of the present invention has the TON constitutional features, degree of crystallinity height, surperficial SiO
2/ Al
2O
3Mol ratio is greater than body phase SiO
2/ Al
2O
3Mol ratio, sour the measuring significantly of the B of molecular sieve reduced, and characteristics such as reduction remains unchanged are substantially measured in L acid.
Modified molecular screen of the present invention has following character, has TON type constitutional features, molecular sieve epiphase SiO
2/ Al
2O
3Mol ratio is 50～200, is preferably 80～120, epiphase SiO
2/ Al
2O
3Mol ratio is than body phase SiO
2/ Al
2O
3Mol ratio is high by 5～50, be preferably 15～35, B acid amount is 0.1mmol/g～0.5mmol/g, be preferably 0.1mmol/g～03mmol/g, L acid amount is 0.05mmol/g～0.3mmol/g, be preferably 0.1mmol/g～0.2mmol/g, the degree of crystallinity of molecular sieve is 85%～100%, is preferably 92%～98%.
The preparation method of modified molecular screen of the present invention is: gets the molecular sieve that synthetic has TON type structure, at first template all removed, and then through processes such as ion-exchange, dealuminzation, benefit silicon.Processes such as said here ion-exchange, dealuminzation, benefit silicon can proceed step by step, also can merge in order and carry out, and most preferably merges and carries out.
The molecular sieve of TON structure has long-pending more less than table, characteristics such as cell walls is thicker, modified molecular screen of the present invention utilizes this characteristics, adjust sial distribution situation in cell walls surface and the cell walls structure, make molecular sieve have outstanding characteristics, as the epiphase sial be higher than body phase sial, the B acid site is few, the L acid site is many, degree of crystallinity is high.Compare with direct synthetic molecular sieve, reduced B acid site number in a large number, and farthest kept the L acid site, can reduce by 20%～60%, generally can reduce about 50%, and L acid amount only reduces by 0～30%, generally only reduces about 5% as B acid amount.When modified molecular screen of the present invention is used for the hydrocarbons hydrogenation processing, have higher activity and selectivity.
Description of drawings
Fig. 1. be the XRD figure of embodiment 1 sample E-1M.
Fig. 2. be the SEM figure of embodiment 1 sample E-1M.
Fig. 3. be the XRD figure of comparative example 1 sample C-1M.
Fig. 4. be the XRD figure of embodiment 2 sample E-2M.
Fig. 5. be the XRD figure of embodiment 3 sample E-3M.
Fig. 6. be the XRD figure of comparative example 4 sample E-4M.
Fig. 7. be the XRD figure of embodiment 5 sample E-5M.
Fig. 8. be the XRD figure of embodiment 6 sample E-6M.
Fig. 9. be the XRD figure of embodiment 7 sample E-7M.
Embodiment
The TON type molecular sieve that the present invention relates to can be the molecular sieve of ordinary method synthetic the type, but building-up process below preferred.
(a) preparation is a kind of is selected from III in the periodic table of elements by at least a
A, IV
AThe even gel that element compound, mineral alkali, organic formwork agent and water are formed preferably also contains auxiliary agent in the gel.Wherein template is preferably double template, and the master module agent is a diamine compounds, and the auxiliary template agent is generally nitrogen-containing heterocycle compound, and auxiliary agent is one or more alkane.
(b) gel of heating steps (a) preparation under the condition of crystallization, makes the gel crystallization complete, through aftertreatment, obtains molecular sieve of the present invention, and crystallization preferably adopts the segmentation crystallization method.
Usually the said template of step (a) is a double template, promptly is made up of two kinds of template, and wherein the master module agent is a diamine compounds, can be C
2-C
10Diamines, be preferably C
5-C
8Diamines, hexanediamine more preferably; The auxiliary template agent is generally nitrogen-containing heterocycle compound, is preferably pyrrole derivative, more preferably tetramethyleneimine.Said auxiliary agent can be C
5-C
10Alkane, be preferably C
5-C
8Normal paraffin or naphthenic hydrocarbon, C more preferably
5-C
7Naphthenic hydrocarbon.IV in the said periodic table of elements
AElement compound, can be selected from the compound of silicon or germanium one or more, be preferably the compound of silicon, can be all silicon-containing compounds that can be used in other molecular sieve of preparation, for example, silica-gel powder, active silica, silicate, vaporific silicon, white carbon black, silicon sol and siliceous organism etc. are preferably silicate, silicon sol and silica-gel powder, more preferably silica-gel powder.Said III
AElement can be boron, aluminium, gallium, indium etc., is preferably aluminium.The aluminium source can be to be selected from activated alumina and precursor, aluminum soluble salt and the organic aluminum contained compound one or more, for example clay, hydrated aluminum oxide, aluminium colloidal sol, aluminate, aluminium salt and aluminiferous organism, be preferably aluminate and aluminium salt, more preferably aluminium salt, for example AlCl
3, Al
2(SO
4)
3, Al (NO
3)
3Deng.Said mineral alkali can be all alkaline matters, and the oxyhydroxide of for example alkali-metal oxyhydroxide, carbonate, alkaline-earth metal and ammoniacal liquor etc. are preferably alkali-metal oxyhydroxide, more preferably potassium hydroxide.A) preparation method of said gel carries out thorough mixing with required material, obtains the homogeneous phase colloidal mixture.
Said crystallization is to carry out in the high-pressure reactor of autogenous pressure in the step (b), and crystallization can be that the single hop crystallization also can be the segmentation crystallization.During the single hop crystallization, general crystallization temperature is 120 ℃～180 ℃, is preferably 130 ℃～170 ℃, and crystallization time is 8～96h, and being preferably is 24～60h.During for the segmentation crystallization, for two sections crystallization, first section crystallization temperature is 80 ℃～100 ℃, and preferred 85 ℃～95 ℃, crystallization time is 4h～48h, is preferably 8h～36h.Second section crystallization temperature is 120 ℃～180 ℃, and preferred 130 ℃～170 ℃, crystallization time is 8h～48h, is preferably 12～24h.For three sections crystallization, first section crystallization temperature is 80 ℃～100 ℃, and preferred 85 ℃～95 ℃, crystallization time is 4h～36h, is preferably 8h～24h.Second section crystallization temperature is 100 ℃～140 ℃, and preferred 110 ℃～130 ℃, crystallization time is 4h～24h, is preferably 12～24h.The 3rd section crystallization temperature is 140 ℃～180 ℃, and preferred 150 ℃～170 ℃, crystallization time is 12h～96h, is preferably 24h～48h.Said aftertreatment refers to through processing such as collection, washing and dryings, can adopt method commonly used at present to carry out, and for example collects and uses method of pumping filtration, uses deionized water wash, makes the sample thorough drying at 100 ℃～250 ℃ then.It is fast that above-mentioned sieve synthesis procedure has crystallization velocity, degree of crystallinity height, characteristics such as molecular sieve performance is outstanding.
The synthetic molecular sieve obtains final zeolite product through processes such as removed template method, ion-exchange, dealuminzation, benefit silicon, and detailed process is as follows.Removing of template can be adopted existing any method, for example processes such as high-temperature roasting or organic solvent extraction under air atmosphere.The ion-exchange process, solutions employed is introduced cationic compound solution for containing needs, is preferably H
+Or/and NH
4 +The solution of ionic compound more preferably contains NH
4 +The solution of ionic compound, for example NH
4NO
3, (NH
4)
2SO
4And NH
4Cl solution etc.NH in the solution
4 +Volumetric molar concentration is 0.05mol/L～10mol/L, is preferably 0.2mol/L～5mol/L.Temperature is normal temperature～200 ℃, is preferably 30 ℃～150 ℃, more preferably 50 ℃～100 ℃.Pressure is the pressure of liquid phase for keeping solution, is preferably normal pressure.Time is 1h～24h, is preferably 1h～12h, more preferably 2h～8h.Gu the liquid/mass ratio of solution and molecular sieve is 5～20, is preferably 5～10.
The dealumination process of the inventive method, used solution is acidic solution, wherein contain at least a be selected from mineral acid and at least a middle organic acid such as oxalic acid, acetate, citric acid that is selected from nitric acid, hydrochloric acid and the sulfuric acid etc., be preferably nitric acid and citric acid mixing solutions, the ratio of the molar weight of nitric acid and citric acid is 10: 1～1: 1, is preferably 10: 1～2: 1.H in the solution
+Volumetric molar concentration is 0.05mol/L～10mol/L, is preferably 0.05mol/L～5mol/L.Temperature is normal temperature～300 ℃, is preferably 50 ℃～200 ℃, more preferably 70 ℃～100 ℃.Pressure is normal pressure～5MPa, is preferably the autogenous pressure of encloses container, more preferably normal pressure.Time is 0.5h～8h, is preferably 1h～6h, more preferably 2h～4h.The mass ratio of solution and molecular sieve is 5～10.
The benefit silicon process of the inventive method, used solution is preferably ammonium fluosilicate solution for containing the soluble silicon compound solution.Strength of solution is 1wt%～10wt%, is preferably 2wt%～5wt%.Temperature is normal temperature～200 ℃, is preferably 50 ℃～100 ℃, more preferably 70 ℃～80 ℃.Pressure is normal pressure～5MPa, is preferably the autogenous pressure of encloses container, more preferably normal pressure.Time is 0.5h～12h, is preferably 1h～8h, more preferably 2h～4h.The mass ratio of solution and molecular sieve is 5～10.
Above-mentioned treatment step can carry out respectively, also can be in order in conjunction with carrying out, most preferably be ion-exchange, dealuminzation and same step of benefit silicon process to finish, contain NH in the used solution
4 +, H
+And silicon, the same step-by-step processing of condition is preferably NH
4 +Volumetric molar concentration is 0.2mol/L～5mol/L, H
+Volumetric molar concentration is 0.05mol/L～5mol/L, and the ratio of mineral acid and organic acid molar weight is 10: 1～2: 1, and ammonium silicofluoride concentration is 1wt%～10wt%, normal temperature～solution reflux temperature, pressure is normal pressure, and the time is 0.5h～12h, and the mass ratio of solution and molecular sieve is 5～10.
Below by embodiment the solution of the present invention is further detailed.
A kind of preparation process of the TON of having structure molecular screen is:
(a) preparation process of gel is: with the KOH of 17.8 grams 82%, and 35.4 grams 1,6-hexanediamine, 4 gram AlCl
3, 200 gram SiO
2Content is 30% silicon sol, and 8.4 gram hexanaphthenes, 3.5 gram tetramethyleneimine and 540 gram water mix according to a definite sequence, through 20 minutes vigorous stirring, obtain homogeneous gel shape mixture, and the mole that obtains gel consists of:
1.3K
2O/3.00R/0.15Al
2O
3/10SiO
2/1.0CH/0.5PY/300 H
2O
R=1,6-hexanediamine, CH=hexanaphthene, PY=tetramethyleneimine.
(b) crystallization process: the gel that step (a) obtains is transferred in the stainless steel autogenous pressure reactor, carried out three sections crystallization, first section crystallization condition is 70 ℃ of constant temperature 24h; Second section crystallization condition is 100 ℃ of constant temperature 12h; The 3rd section crystallization condition is 150 ℃ of constant temperature 24h.After finishing, crystallization stops heating, the reactor naturally cooling.
(c) aftertreatment: open reactor, can see that upper solution clarification, crystallisate all accumulate in the still bottom, through suction filtration, deionized water wash 3 times, 110 ℃ of dryings 4 hours obtain the former powder of crystalline molecular sieve, are numbered E-1S.
(d) template removal: the E-1S molecular sieve, in nitrogen atmosphere, with heat-up rate to the 550 ℃ constant temperature of 2.5 ℃/min 2 hours, constant temperature 4 hours in air atmosphere then obtained removing the molecular sieve of organic lamina membranacea agent, is numbered E-1C from room temperature.
(e) get E-1C molecular sieve 20 grams and place 500 ml beakers, add 200 milliliters of massfractions and be 10% ammonium nitrate solution, under agitation, be warmed up to 80 ℃, constant temperature 4 hours, product through filtration, washing, 110 ℃ of dryings 4 hours, repeat top operation then 2 times, obtain ammonium type molecular sieve, through 550 ℃ of roastings 4 hours, obtain the modified molecular screen product, be numbered E-1M.
(e) characterize: the SiO of E-1M
2/ Al
2O
3Be 62, XRD sees Fig. 1, and SEM sees Fig. 2.As seen from Figure 1, product has TON type structure molecular screen feature; The E-1M crystallization is needle-like as seen from Figure 2, and length is about 0.8 micron, and its physico-chemical property sees Table 2.
Comparative example 1
A kind of preparation process of modified molecular screen is:
(1) gets E-1C molecular sieve 20 grams and place 500 ml beakers, add 200 milliliters of massfractions and be 10% ammonium nitrate solution, under agitation, be warmed up to 80 ℃, constant temperature 4 hours, product through filtration, washing, 110 ℃ of dryings 4 hours, repeat top operation then 2 times, obtain ammonium type molecular sieve, be numbered C-1N.
(1) get the processing 2 hours under 550 ℃ and 100% water vapor conditions of C-1N molecular sieve 10 gram, product obtains the dealuminzation molecular sieve through 110 ℃ of dryings 4 hours, is numbered C-1H.
(2) get C-1H molecular sieve 8 grams and place 250 milliliters of three-necked bottles, add (the NH that 100 ml concns are 3w%
4)
2SiF
6The aqueous solution under agitation, is warmed up to 85 ℃, constant temperature 4 hours, product through filtration, washing, 110 ℃ of dryings 2 hours and 450 ℃ of roastings 2 hours, obtain the modified molecular screen product, be numbered C-1M, its XRD sees Fig. 3, the character of product sees Table 2.
A kind of preparation process of modified molecular screen is:
(1) gets E-1C molecular sieve 20 grams and place 500 ml beakers, add 200 milliliters of massfractions and be 10% ammonium nitrate solution, under agitation, be warmed up to 80 ℃, constant temperature 4 hours, product through filtration, washing, 110 ℃ of dryings 4 hours, repeat top operation then 2 times, obtain ammonium type molecular sieve, be numbered E-2N.
(1) gets E-2N molecular sieve 10 grams and place 250 ml beakers, adding 100 milliliters of nitric acid volumetric molar concentrations is that 0.5mol/L and tartrate volumetric molar concentration are the mixed acid solution of 0.2mol/L, under agitation, be warmed up to 90 ℃, constant temperature 4 hours, product through filtration, washing, 110 ℃ of dryings 4 hours, obtain the dealuminzation molecular sieve, be numbered E-2H.
(2) get E-2H molecular sieve 8 grams and place 250 milliliters of three-necked bottles, add (the NH that 100 ml concns are 3w%
4)
2SiF
6The aqueous solution under agitation, is warmed up to 85 ℃, constant temperature 4 hours, product through filtration, washing, 110 ℃ of dryings 2 hours and 450 ℃ of roastings 2 hours, obtain the modified molecular screen product, be numbered E-2M, its XRD sees Fig. 4, the character of product sees Table 2.
A kind of preparation process of modified molecular screen is:
(1) gets E-1C molecular sieve 20 grams and place 500 ml beakers, add 200 milliliters of massfractions and be 2% ammonium nitrate solution, under agitation, be warmed up to 90 ℃, constant temperature 4 hours, product through filtration, washing, 110 ℃ of dryings 4 hours, repeat top operation then 4 times, obtain ammonium type molecular sieve, be numbered E-3N.
(2) get E-3N molecular sieve 10 grams and place 250 ml beakers, adding 50 milliliters of nitric acid volumetric molar concentrations is that 3.0mol/L and tartrate volumetric molar concentration are the mixed acid solution of 0.5mol/L, under agitation, be warmed up to 90 ℃, constant temperature 4 hours, product through filtration, washing, 110 ℃ of dryings 4 hours, obtain the dealuminzation molecular sieve, be numbered E-3H.
(3) get E-3H molecular sieve 8 grams and place 250 milliliters of three-necked bottles, add (the NH that 200 ml concns are 3w%
4)
2SiF
6The aqueous solution under agitation, is warmed up to 40 ℃, constant temperature 8 hours, product through filtration, washing, 110 ℃ of dryings 2 hours and 550 ℃ of roastings 2 hours, obtain the modified molecular screen product, be numbered E-3M, its XRD sees Fig. 5, the character of product sees Table 2.
Embodiment 4
A kind of preparation process of modified molecular screen is:
(1) gets E-1C molecular sieve 20 grams and place 500 ml beakers, add 200 milliliters of ammonium nitrate, 0.6mol/L nitric acid and 0.2mol/L tartrate mixing solutionss that contain 2w%, under agitation, be warmed up to 70 ℃, constant temperature 8 hours, product through filtration, washing, 110 ℃ of dryings 4 hours, repeat top operation then 1 time, obtain the dealuminzation molecular sieve, be numbered E-4H.
(2) get E-4H molecular sieve 10 grams and place 250 milliliters of three-necked bottles, add (the NH that 150 ml concns are 0.2w%
4)
2SiF
6The aqueous solution under agitation, is warmed up to 90 ℃, constant temperature 2 hours, product through filtration, washing, 150 ℃ of dryings 4 hours and 650 ℃ of roastings 1 hour, obtain the modified molecular screen product, be numbered E-4M, its XRD sees Fig. 6, the character of product sees Table 2.
A kind of preparation process of modified molecular screen is:
(1) gets E-1C molecular sieve 20 grams and place 500 ml beakers, add 400 milliliters of massfractions and be 15% ammonium nitrate solution, under agitation, be warmed up to 60 ℃, constant temperature 12 hours, product through filtration, washing, 110 ℃ of dryings 6 hours, repeat top operation then 2 times, obtain ammonium type molecular sieve, be numbered E-5N.
(2) get E-5N molecular sieve 10 grams and place 250 milliliters of three-necked bottles, add 250 milliliters of (NH that contain 0.2w%
4)
2SiF
6, 1.0mol/L nitric acid and 0.1mol/L tartrate mixing solutions, under agitation, be warmed up to 75 ℃, constant temperature 3 hours, product through filtration, washing, 120 ℃ of dryings 4 hours and 550 ℃ of roastings 4 hours, obtain the modified molecular screen product, be numbered E-5M, its XRD sees Fig. 7, and the character of product sees Table 2.
Embodiment 6
A kind of preparation process of modified molecular screen is:
Get E-1C molecular sieve 20 grams and place 500 ml beakers, add 300 milliliters and contain the ammonium nitrate of the 6w%, (NH of 0.4w%
4)
2SiF
6, 0.5mol/L nitric acid and the tartaric mixing solutions of 0.1mol/L, under agitation, be warmed up to 55 ℃, constant temperature 6 hours, product through filtration, washing, 110 ℃ of dryings 6 hours, repeat top operation then 2 times, obtain the modified molecular screen product, be numbered E-6M, its XRD sees Fig. 8, and the character of product sees Table 2.
A kind of preparation process of modified molecular screen is:
Get E-1C molecular sieve 20 grams and place 500 ml beakers, add 300 milliliters and contain the ammonium nitrate of the 10w%, (NH of 0.2w%
4)
2SiF
6, 3.0mol/L hydrochloric acid and 0.5mol/L oxalic acid mixing solutions, under agitation, be warmed up to 70 ℃, constant temperature 4 hours, product through filtration, washing, 110 ℃ of dryings 6 hours, repeat top operation then 3 times, obtain the modified molecular screen product, be numbered E-7M, its XRD sees Fig. 9, and the character of product sees Table 2.
The character of table 2 embodiment modified molecular screen
| Sample number into spectrum | Pore volume, ml/g | Specific surface area, m 2/g | Degree of crystallinity, % | SiO 2/Al 2O 3 | The acid amount, mmol/g | ||
| Epiphase (1) | The body phase (2) | B (reduces, %) | L (reduces, %) | ||||
| E-1M C-1M E-2M E-3M E-4M E-5M E-6M E-7M | 0.20 0.18 0.20 0.19 0.20 0.20 0.20 0.19 | 274 236 268 253 262 259 266 257 | 100 82 98 87 95 94 97 92 | 62 88 96 124 104 108 105 112 | 62 86 76 93 80 82 78 90 | 0.320(-) 0.178(44.4) 0.212(33.8) 0.136(57.5) 0.184(42.5) 0.162(49.4) 0.203(36.6) 0.138(56.9) | 0.141(-) 0.08(43.3) 0.141(0) 0.129(8.5) 0.137(2.8) 0.140(0.7) 0.138(2.1) 0.133(5.7) |
(1) record by XPS: (2) record by ICP.
Wherein degree of crystallinity is 100% with the degree of crystallinity of E-1C molecular sieve.XRD result adopts D/MAX-RA type x-ray diffractometer of science, and source of radiation is the copper target, the filtering of graphite monocrystalline, operation tube voltage 35KV, tube current 30～50mA, sweep velocity (20) be 4 degree/minute, sweep limit is 4～35 degree.The acid amount of molecular sieve and strength of acid are to obtain with temperature programmed desorption of ammonia (TPD), and molecular sieve at first is heated to 500 ℃, hold 2 hours in the continuation of insurance of helium relaying then, then cool to room temperature.Ammonia is as sorbent material, and sample is warmed up to 100 ℃ with helium displacement 1 hour, and purpose is to remove the material of physical adsorption, makes temperature be warmed up to 500 ℃ from 100 ℃ with 10 ℃/minute heat-up rate then, detects the signal of TPD.X-ray photoelectron spectroscopy (XPS) is to adopt Perkin-Elmer PHI581 spectrometer, and data are by the method collection of standard, and the epiphase silica alumina ratio calculates by the area at relative photo electronics peak.Body phase silica alumina ratio records by plasma emission spectrum (ICP).The amount in B acid and L acid site is that pyridine-TPD is at 1700cm by in fourier-transform infrared (FT-IR) spectrum
-1-1350cm
-1Peak area obtains.
Claims (6)
1, a kind of modified molecular screen has TON type constitutional features, it is characterized in that molecular sieve epiphase SiO
2/ Al
2O
3Mol ratio is 50～200, epiphase SiO
2/ Al
2O
3Mol ratio is than body phase SiO
2/ Al
2O
3Mol ratio is high by 5～50.
2,, it is characterized in that described epiphase SiO according to the described molecular sieve of claim 1
2/ Al
2O
3Mol ratio is 80～120.
3, according to claim 1 or 2 described molecular sieves, it is characterized in that described epiphase SiO
2/ Al
2O
3Mol ratio is than body phase SiO
2/ Al
2O
3Mol ratio is high by 15～35.
4, according to claim 1 or 2 described molecular sieves, it is characterized in that the B acid amount of molecular sieve is 0.1mmol/g～0.5mmol/g, L acid amount is 0.05mmol/g～0.3mmol/g, the degree of crystallinity of molecular sieve is 85%～100%.
5, according to claim 1 or 2 described molecular sieves, it is characterized in that the B acid amount of molecular sieve is 0.1mmol/g～0.3mmol/g, L acid amount is 0.1mmol/g～0.2mmol/g, the degree of crystallinity of molecular sieve is 92%～98%.
6, a kind of preparation method of claim 1 modified molecular screen: get the molecular sieve that synthetic has TON type structure, at first template is all removed, and then through ion-exchange, dealuminzation, the processing of benefit silicon process, wherein ion-exchange, dealuminzation, benefit silicon process be proceed step by step in order, or merges into a step and carry out;
The condition of described proceed step by step in order is: (1) ion-exchange: with containing NH
4 +Volumetric molar concentration is the solution-treated of 0.05mol/L～10mol/L, and temperature is normal temperature～200 ℃, and the time is 1h～24h, Gu the liquid/mass ratio of solution and molecular sieve is 5～20; (2) dealuminzation: with containing at least a mineral acid and at least a organic acid solution, H in the solution
+Volumetric molar concentration is 0.05～10mol/L, treatment temp is normal temperature～300 ℃, and the treatment time is 0.5h～8h, and the mass ratio of solution and molecular sieve is 5～10, described mineral acid is selected from nitric acid, hydrochloric acid and sulfuric acid, and described organic acid is selected from oxalic acid, acetate, citric acid and tartrate; (3) mend silicon: used solution is that concentration is the ammonium fluosilicate solution of 1wt%～10wt%, and treatment temp is normal temperature～200 ℃, and the time is 0.5h～12h, and the mass ratio of solution and molecular sieve is 5～10;
The described step condition of carrying out of merging into is: with the NH that contains 0.2mol/L～5mol/L
4 +, 0.05mol/L～5mol/L H
+And the mixing solutions of the ammonium silicofluoride of 1wt%～10wt% handles 0.5h～12h under normal temperature～solution reflux temperature, and wherein the ratio of mineral acid and organic acid molar weight is 10: 1～2: 1, and the mass ratio of solution and molecular sieve is 5～10.
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| CN100594179C (en) * | 2005-06-03 | 2010-03-17 | 中国科学院大连化学物理研究所 | Micropore crystalline aluminium silicate and its preparation process |
| CN101618347B (en) * | 2008-07-04 | 2010-12-22 | 中国石油化工股份有限公司 | Y-type molecular sieve-containing hydrocracking catalyst carrier and preparation method thereof |
| CN102464327A (en) * | 2010-11-04 | 2012-05-23 | 中国石油化工股份有限公司 | Method for modifying molecular sieve |
| CN103058214B (en) * | 2011-10-21 | 2016-03-23 | 中国石油化工股份有限公司 | Si-Al molecular sieve of a kind of TON crystalline structure and preparation method thereof |
| CN103880035A (en) * | 2014-04-02 | 2014-06-25 | 中国石油大学(华东) | Compound modification method for USY molecular sieve |
| CN105536854B (en) * | 2014-11-03 | 2018-04-10 | 中国石油化工股份有限公司 | A kind of method for preparing the hydrocracking catalyst containing Y molecular sieve |
| CN105536855B (en) * | 2014-11-03 | 2018-04-10 | 中国石油化工股份有限公司 | A kind of preparation method of the hydrocracking catalyst containing Y molecular sieve |
| CN107303496B (en) * | 2016-04-22 | 2019-11-15 | 中国石油化工股份有限公司 | A kind of hydrocracking catalyst and its preparation method and application |
| CN107303495B (en) * | 2016-04-22 | 2019-09-10 | 中国石油化工股份有限公司 | A kind of preparation method and application and Catalyst For Single-stage Hydrocracking of modified Y molecular sieve |
| CN107973308B (en) * | 2016-10-21 | 2019-12-27 | 中国石油化工股份有限公司 | Phosphorus-containing MFI structure molecular sieve and preparation method thereof |
| CN107970969B (en) * | 2016-10-21 | 2020-05-19 | 中国石油化工股份有限公司 | Rare earth-containing Y molecular sieve and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4556477A (en) * | 1984-03-07 | 1985-12-03 | Mobil Oil Corporation | Highly siliceous porous crystalline material ZSM-22 and its use in catalytic dewaxing of petroleum stocks |
| US5080878A (en) * | 1989-07-11 | 1992-01-14 | Mobil Oil Corp. | Modified crystalline aluminosilicate zeolite catalyst and its use in the production of lubes of high viscosity index |
| CN1046437C (en) * | 1996-03-21 | 1999-11-17 | 中国石油化工总公司 | Aluminium-eliminating and silicon-replenishing method for zeolite |
| CN1046641C (en) * | 1990-12-05 | 1999-11-24 | 中国科学院大连化学物理研究所 | Modified zeolite catalyst for light hydrocardon aromatization reaction |
-
2003
- 2003-10-24 CN CNB2003101049036A patent/CN1325378C/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4556477A (en) * | 1984-03-07 | 1985-12-03 | Mobil Oil Corporation | Highly siliceous porous crystalline material ZSM-22 and its use in catalytic dewaxing of petroleum stocks |
| US5080878A (en) * | 1989-07-11 | 1992-01-14 | Mobil Oil Corp. | Modified crystalline aluminosilicate zeolite catalyst and its use in the production of lubes of high viscosity index |
| CN1046641C (en) * | 1990-12-05 | 1999-11-24 | 中国科学院大连化学物理研究所 | Modified zeolite catalyst for light hydrocardon aromatization reaction |
| CN1046437C (en) * | 1996-03-21 | 1999-11-17 | 中国石油化工总公司 | Aluminium-eliminating and silicon-replenishing method for zeolite |
Non-Patent Citations (3)
| Title |
|---|
| 沸石的改性技术 高繁华，张永明，高雄厚，工业催化，第2期 1998 * |
| 沸石的改性技术 高繁华，张永明，高雄厚，工业催化，第2期 1998;高硅分子筛ZSM-22的动态合成及表征 许宁，齐润国，张文祥，吴通好，孙家锺，催化学报，第23卷第4期 2002 * |
| 高硅分子筛ZSM-22的动态合成及表征 许宁，齐润国，张文祥，吴通好，孙家锺，催化学报，第23卷第4期 2002 * |
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