CN1324783A - Antibacterial ceramic glaze liquid and application thereof - Google Patents
Antibacterial ceramic glaze liquid and application thereof Download PDFInfo
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- CN1324783A CN1324783A CN 00107543 CN00107543A CN1324783A CN 1324783 A CN1324783 A CN 1324783A CN 00107543 CN00107543 CN 00107543 CN 00107543 A CN00107543 A CN 00107543A CN 1324783 A CN1324783 A CN 1324783A
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- antibacterial
- glaze liquid
- ceramic glaze
- liquid according
- antibacterial ceramic
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 38
- 239000000919 ceramic Substances 0.000 title claims abstract description 37
- 239000007788 liquid Substances 0.000 title claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 239000002270 dispersing agent Substances 0.000 claims abstract description 4
- 238000007598 dipping method Methods 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 238000005245 sintering Methods 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 230000008021 deposition Effects 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical group CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 6
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims description 6
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 6
- 229910021536 Zeolite Inorganic materials 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 229920000084 Gum arabic Polymers 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 3
- 241000978776 Senegalia senegal Species 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000205 acacia gum Substances 0.000 claims description 3
- 235000010489 acacia gum Nutrition 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 229920000609 methyl cellulose Polymers 0.000 claims description 3
- 239000001923 methylcellulose Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 3
- 239000011800 void material Substances 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 239000006004 Quartz sand Substances 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 2
- 210000003298 dental enamel Anatomy 0.000 abstract description 10
- 239000000047 product Substances 0.000 abstract description 8
- 230000001680 brushing effect Effects 0.000 abstract description 2
- 239000003242 anti bacterial agent Substances 0.000 abstract 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 239000011265 semifinished product Substances 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 7
- 241000894006 Bacteria Species 0.000 description 6
- 230000003115 biocidal effect Effects 0.000 description 6
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 239000000741 silica gel Substances 0.000 description 5
- 229910002027 silica gel Inorganic materials 0.000 description 5
- 229960001866 silicon dioxide Drugs 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000006067 antibiotic powder Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000022972 amelogenesis Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000000968 intestinal effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a glaze liquid which can make the surface of ceramic or enamel articles have antibacterial function and the application thereof. The antibacterial glaze liquid comprises 1-7 parts of low-temperature antibacterial agent or high-temperature antibacterial agent, 0.2-4 parts of adhesive, 0.1-0.5 part of dispersing agent, 0.1-1 part of defoaming agent, 7-10 parts of solvent and 90-100 parts of water. The antibacterial paint can be used on blanks, semi-finished products and finished products of various ceramic or enamel articles, and can make the ceramic articles have good and durable antibacterial function by spraying, brushing, dipping and evaporating materials.
Description
The present invention relates to a kind of pottery or enamel article surface of making and have glaze liquid of antibacterial and uses thereof.
Pottery or enamel article are widely used, and in fields such as food and drink, building decoration, machinofacture, medical chemical industry application are arranged all.Pottery or enamel articles for use smooth surface, quality is hard, be easy to clean; Common people think that bacterium is difficult to adhere to existence, but show pottery or the easier absorbing pathogenic bacteria of enamel article after tested.Above-mentioned article are communicate illness important in, bathroom simultaneously especially, and the lavatory waits sanitary equipment and ceramic building material in the building to be more conducive to bacterial reproduction, generation peculiar smell, communicate illness between food car.Various countries take to the pottery of antibacterial or enamel development in the early 1990s for this reason.In glaze liquid, add raw materials such as titanium dioxide as present employing, touch technology with light and produce antibacterial ceramic products, but this requirement has the ceramic of above-mentioned raw materials enough illumination must be arranged, and this goods precipitate in sintering process gradually, cause the antibiotic composition of product surface few, the anti-microbial property extreme difference.
The purpose of this invention is to provide a kind of antibacterial ceramic glaze liquid and uses thereof, require it to have and make ceramic-type enamel article surface have good antibacterial, and preparation technology is simple and practical, cost is low, and antibacterial is long-acting lasting.Easy row of many uses.
For achieving the above object, the present invention takes following design;
It contains antiseptic-germicide and water a kind of antibacterial ceramic glaze liquid.Its component is (weight)
Low temperature antiseptic-germicide or high temperature antiseptic-germicide 1-7 part
Tackiness agent 0.2-4 part
Dispersion agent 0.1-0.5 part
Defoamer 0.1-1 part
Solvent 7-10 part
Water 90-100 part
Described tackiness agent is from methylcellulose gum, tripoly phosphate sodium STPP, and water-soluble acrylic acid resin, polyvinyl alcohol is chosen any one kind of them in the gum arabic or several composition.
Described dispersion agent is the vinylcarbinol monomer dispersant, or SP-17 colorant dispersion agent.
Described defoamer is octanol or organic silicon emulsion.
Described solvent is model 9813 homemade solvents.
Described low temperature antiseptic-germicide is the antiseptic-germicide of putting down in writing in China Patent No. 96106369.6 open source literatures, its preparation method is the silica gel efflorescence with median size 0.1-10 micron, 180 ℃ of oven dry activation in 2 hours, in normal-temperature water, add antibacterial metal salts, make the reaction solution that concentration is 0.008-2M, this reaction solution pH value is 9-9.5.In reaction solution, add the activatory silica-gel powder.Stirred 2-4 hour, carry out ion-exchange after, it is standby that the antibiotic powder of silica gel is dried into 80 ℃ in the back of anhydrating.With zeolite, titanium dioxide or aluminum oxide grind averageparticle 0.1-10 micron again, 160 ℃-300 ℃, oven dry in 3-4 hour activates into carrier, makes its water content be lower than 1%, and the antibacterial metal salts of interpolation 0.008-3M and calcium chloride or the lime carbonate of 0.008M-1.5M are made reaction solution in normal-temperature water, its pH value is 5-8, add the activatory carrier, stirring at normal temperature 7-12 hour, carry out ion-exchange, remove upper clear liquid, anhydrate to dry with clear water cleaning free metal ion and make antibiotic powder.With antibiotic powder and the antibiotic powder of the silica gel mixed by 9: 1 to 4: 6 (weight), be ground into the 0.1-10 micron again, 100 ℃ of-300 ℃ of oven dry are anhydrated and are made the mixing antiseptic-germicide, and this mixing antiseptic-germicide is the low temperature antiseptic-germicide.
Described high temperature antiseptic-germicide is the antiseptic-germicide of putting down in writing in Chinese patent 98100064.9 open source literatures, its preparation method is from zinc nitrate, choose any one kind of them in zinc chloride, cupric nitrate, the magnesium nitrate or several, add the ammonium nitrate of 0.1-3M, add water in the 30-50L/kg ratio and make slurries.After in calcium hydroxide, potassium hydroxide, sodium hydroxide, selecting one or more silica gel that add 5% 0.5-5 micron again, add water in the 10-15L/kg ratio and make solution, slurries and the solution mixed by 2: 8 is stirred, solid solution 30 minutes-3 hours, cleaning, drying is made antiseptic-germicide.Be the high temperature antiseptic-germicide.
The also Silver Nitrate of available 0.001-0.1M or 0.1-1M cupric nitrate, add the zinc oxide of total amount 5% again at the zinc nitrate of 0.1-2M, add the permutite of oven dry, with the lime carbonate that accounts for permutite total amount 25-50%, exchange after 3-10 hour, clean, the high temperature antiseptic-germicide is made in oven dry.
The low temperature antiseptic-germicide is used for the enamel below 800 ℃, and among the ceramic preparation technology, the high temperature antiseptic-germicide is used for enamel and the ceramic preparation technology more than 800 ℃ or 800 ℃.
Glaze liquid of the present invention can be used as and makes ceramic articles for use surface have the antibacterial glaze liquid of antibacterial.Also can be used on the base of ceramic articles, or on the work in-process, or the extension of the spray on the finished surface, or brushing or dipping or Coating Materials.Also can be used on the deposition material that is mixed and made into carrier in the sintering oven of sintered ceramic article.
In the purposes, described carrier aluminum oxide, silicon carbide, quartz sand, or diatomite, zeolite, one or more sintering of SeaShell are made aperture 5-6 micron, and the material of void content 〉=60-80% is made.
The invention will be further described below in conjunction with embodiment.
Embodiment 1
Prepare the glaze liquid of the present invention of 800 ℃ of following temperature agglomerating pottery articles for use, component (weight) is as follows:
2 parts of low temperature antiseptic-germicides
2 parts of methylcellulose gum
1 part of polyvinyl alcohol
0.5 part of gum arabic
0.3 part of organic silicon emulsion
0.2 part of vinylcarbinol monomer dispersant
0.7 part of 9813 solvent
90 parts in water
Above-mentioned raw materials fully is mixed.
Be used in and hang up properly common glaze liquid, on drying, the work in-process to be sintered, on the blank, on ceramic product, can adopt spray to hang the product of the present invention of 0.5 mm thick.Or brush, the impregnating method makes above-mentioned article outside surface adhere to the product of the present invention of 0.1-0.7 mm thick, after the seasoning, makes its water ratio reach at 1% o'clock and goes into the klining knot, and 800 ℃ below the temperature.
Embodiment 2
The glaze fluid component weight of the present invention of preparation temperature agglomerating pottery articles for use more than 800 ℃ is as follows:
7 parts of high temperature antiseptic-germicides
0.5 part of water-soluble acrylic
0.8 part of tripoly phosphate sodium STPP
0.9 part of octanol
0.2 part of SP-17 construction materials contract dispersion agent
9 parts of solvents
100 parts in water
Above-mentioned raw materials is mixed.
Be used on the embodiment 1 described product, more than 800 ℃, high temperature sintering.
Embodiment 3
With following component (weight):
10 parts in diatomite
10 parts in zeolite
15 parts of SeaShells
20 parts in aluminum oxide
160 ℃ of-300 ℃ of sintering, 3-4 hour, oven dry was pulverized and is made aperture 5-6 micron.Void content is greater than the carrier of 60-68%, with carrier add implement 1 or the prepared ceramic antibacterial glaze liquid of embodiment 2 in, stirred 7-12 hour, carry out ion-exchange, wash upper clear liquid off, anhydrating to dry is made into piece or bar-shaped deposition material.
Deposition material is put in sintering oven, or put at the sintering zone afterbody, apart from ceramic articles for use top or the about 2-20cm of adjacent side place, place a deposition material every a segment distance, be used in ceramic articles for use finished product, on the work in-process, in the sintering process, the antibiotic ion in the steaming liquid material evaporates because of high temperature oxidation and surveys and drop on the ceramic articles surface, after its cooling, oxide compound with antibacterial just is securely fixed in the ceramic articles surface, plays sterilization functions.
Obviously deposition material can use repeatedly, when the antibiotic ion that evaporates is not enough, supports antibiotic ion again as stated above and gets final product.
Embodiment 4
Cooperate embodiment 1 or embodiment 2 to use jointly the deposition material and the using method of embodiment 3 preparations, the antibacterial effect of ceramic articles for use is better.Be not repeated.
The present invention can make ceramic articles or enamel article, realizes antibacterial simultaneously at sintering, and antibacterial length is put lastingly, the safety non-toxic of antiseptic-germicide own, and fringe cost is low.Simultaneous test of the present invention is as follows.
Experimental technique is got three antibiotic service plates of the present invention, gets the same material that does not add antibacterial glaze liquid of the present invention simultaneously and does controlled trial with 3 of the identical service plates of quadrat method manufacturing.
Get 5 * 10 by " disinfection technology regulation "
6-5 * 10
7Bacterium liquid 0.5ml, drip respectively on antibiotic service plate and common service plate, after acting on following different time, dip in disinfecting cotton swab and to get sterilization PBS, and the bacterium liquid that will coil washes respectively, put into the 10ml PBS that sterilizes, do different dilutions, get 1ml, after cultivating 48 hours under 37 ℃, be viable bacteria test (three service plates equal to do three samples) result:
| The viable bacteria contrast | 7 hours antibacterial numbers | 24 hours antibacterial numbers | |
| Intestinal bacteria | 6.2×10 6 | 80.21％ | 99.93％ |
| Streptococcus aureus | 6.2×10 6 | 77.20％ | 99.81％ |
Common service plate viable bacteria contrast still was 6.2 * 10 in 7-24 hour
6In addition, the anti-bacteria ceramic that uses the same method and make has good sterilizing function equally.
Claims (10)
1, a kind of antibacterial ceramic glaze liquid is characterized in that: it contains antiseptic-germicide and water.
2, antibacterial ceramic glaze liquid according to claim 1 is characterized in that: component is (weight):
Low temperature antiseptic-germicide, or high temperature antiseptic-germicide 1-7 part
Tackiness agent 0.2-4 part
Dispersion agent 0.1-0.5 part
Defoamer 0.1-1 part
Solvent 7-10 part
Water 90-100 part.
3, antibacterial ceramic glaze liquid according to claim 1 is characterized in that: described tackiness agent is from methylcellulose gum, tripoly phosphate sodium STPP, and water-soluble acrylic acid resin, polyvinyl alcohol is chosen any one kind of them in the gum arabic or several composition.
4, antibacterial ceramic glaze liquid according to claim 1 is characterized in that: described dispersion agent is the vinylcarbinol monomer dispersant, or SP-17 colorant dispersion agent.
5, antibacterial ceramic glaze liquid according to claim 1 is characterized in that: described defoamer is octanol or organic silicon emulsion.
6, antibacterial ceramic glaze liquid according to claim 1 is characterized in that: described solvent is model 9813 homemade solvents.
7, the purposes of antibacterial ceramic glaze liquid according to claim 1 is characterized in that: can be used as and make ceramic articles for use surface have the antibacterial glaze liquid of antibacterial.
8, the purposes of antibacterial ceramic glaze liquid according to claim 1 is characterized in that: can be used on the base of ceramic articles, or on the work in-process, or the extension of the spray on the finished surface, or brush or dipping, or Coating Materials.
9, the purposes of antibacterial ceramic glaze liquid according to claim 1 is characterized in that: can be used on the deposition material that is mixed and made into carrier in the sintering oven of sintered ceramic article.
10, the purposes of antibacterial ceramic glaze liquid according to claim 9, it is characterized in that: described carrier can be used aluminum oxide, silicon carbide, quartz sand or diatomite, zeolite, one or more sintering of SeaShell are made aperture 5-6 micron, and the material of void content 〉=60-68% is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00107543 CN1240643C (en) | 2000-05-18 | 2000-05-18 | Antibacterial ceramic glaze liquid and its use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00107543 CN1240643C (en) | 2000-05-18 | 2000-05-18 | Antibacterial ceramic glaze liquid and its use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1324783A true CN1324783A (en) | 2001-12-05 |
| CN1240643C CN1240643C (en) | 2006-02-08 |
Family
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|---|---|---|---|
| CN 00107543 Expired - Fee Related CN1240643C (en) | 2000-05-18 | 2000-05-18 | Antibacterial ceramic glaze liquid and its use |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101880177A (en) * | 2010-08-10 | 2010-11-10 | 唐山梦牌瓷业有限公司 | Self-cleaning antibacterial glaze used for sanitary ceramic ware |
| CN103145448A (en) * | 2013-04-01 | 2013-06-12 | 漳州师范学院 | Technology for preparing antibacterial ceramic at low temperature |
| CN103717545A (en) * | 2011-08-01 | 2014-04-09 | 蓝宝迪有限公司 | Additives for ceramic glazes |
| CN105036804A (en) * | 2015-06-16 | 2015-11-11 | 德化均能手造陶瓷有限公司 | Health-preserving antimicrobial ceramic glaze |
| CN106746668A (en) * | 2016-12-14 | 2017-05-31 | 顾马飞 | A kind of antibacterial ceramic glaze liquid and preparation method thereof |
| CN109761647A (en) * | 2019-03-19 | 2019-05-17 | 重庆唯美陶瓷有限公司 | A kind of titanium system cladding fancy glaze Ceramic Tiles and preparation method thereof |
| CN111704481A (en) * | 2020-07-07 | 2020-09-25 | 佛山市三水普朗克新型材料有限公司 | Production process of antibacterial polished brick, preparation method of antibacterial agent and antibacterial polished brick |
| CN112279517A (en) * | 2020-10-26 | 2021-01-29 | 同曦集团有限公司 | Antibacterial and antiviral glaze, antibacterial and antiviral ceramic and preparation method thereof |
-
2000
- 2000-05-18 CN CN 00107543 patent/CN1240643C/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101880177A (en) * | 2010-08-10 | 2010-11-10 | 唐山梦牌瓷业有限公司 | Self-cleaning antibacterial glaze used for sanitary ceramic ware |
| CN103717545B (en) * | 2011-08-01 | 2016-10-19 | 蓝宝迪有限公司 | The additive of ceramic glaze |
| CN103717545A (en) * | 2011-08-01 | 2014-04-09 | 蓝宝迪有限公司 | Additives for ceramic glazes |
| CN103145448A (en) * | 2013-04-01 | 2013-06-12 | 漳州师范学院 | Technology for preparing antibacterial ceramic at low temperature |
| CN103145448B (en) * | 2013-04-01 | 2014-08-13 | 漳州师范学院 | Technology for preparing antibacterial ceramic at low temperature |
| CN105036804B (en) * | 2015-06-16 | 2017-01-04 | 德化均能手造陶瓷有限公司 | Health preserving antibacterial ceramic glaze |
| CN105036804A (en) * | 2015-06-16 | 2015-11-11 | 德化均能手造陶瓷有限公司 | Health-preserving antimicrobial ceramic glaze |
| CN106746668A (en) * | 2016-12-14 | 2017-05-31 | 顾马飞 | A kind of antibacterial ceramic glaze liquid and preparation method thereof |
| CN106746668B (en) * | 2016-12-14 | 2019-05-14 | 江西精隆陶瓷有限公司 | A kind of antibacterial ceramic glaze liquid and preparation method thereof |
| CN109761647A (en) * | 2019-03-19 | 2019-05-17 | 重庆唯美陶瓷有限公司 | A kind of titanium system cladding fancy glaze Ceramic Tiles and preparation method thereof |
| CN111704481A (en) * | 2020-07-07 | 2020-09-25 | 佛山市三水普朗克新型材料有限公司 | Production process of antibacterial polished brick, preparation method of antibacterial agent and antibacterial polished brick |
| CN112279517A (en) * | 2020-10-26 | 2021-01-29 | 同曦集团有限公司 | Antibacterial and antiviral glaze, antibacterial and antiviral ceramic and preparation method thereof |
| CN112279517B (en) * | 2020-10-26 | 2023-02-21 | 同曦集团有限公司 | Antibacterial and antiviral glaze, antibacterial and antiviral ceramic and preparation method thereof |
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