CN1323209C - Fiber treatment agent composition - Google Patents
Fiber treatment agent composition Download PDFInfo
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- CN1323209C CN1323209C CNB028263235A CN02826323A CN1323209C CN 1323209 C CN1323209 C CN 1323209C CN B028263235 A CNB028263235 A CN B028263235A CN 02826323 A CN02826323 A CN 02826323A CN 1323209 C CN1323209 C CN 1323209C
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- Prior art keywords
- fiber
- amphipathic lipids
- finish composition
- fibre finish
- agent
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/419—Amides having nitrogen atoms of amide groups substituted by hydroxyalkyl or by etherified or esterified hydroxyalkyl groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/08—Processes in which the treating agent is applied in powder or granular form
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
A fiber treatment agent composition comprising an amphipathic lipid having one or more hydroxyl group(s) and one or more amide group(s) in the molecule thereof, the lipid being solid particles having an average particle size of 1 to 100 mum. The fiber treated with the fiber treatment agent composition of the invention provides excellent feeling to the resultant textile and pleasant feel to the skin. When a consumer wears the fiber product produced from the thus-treated fiber, remarkable effects are attained, including pleasant feel to the skin with which the fiber product is brought into contact, skin protective effect, effect of enabling the people having sensitive skin to wear at ease, moisturizing effect, and effect of improving skin disease such as rough skin.
Description
Technical field
The present invention relates to pay the fibre finish composition of the excellent sensation of fiber, and the fiber that excellent sense of touch and good sensation are provided when the consumer dresses the final products of being made by this fiber.More specifically, the present invention relates to comprise the fibre finish composition of the amphipathic lipids of solid particulate form, the amphipathic lipids of described solid particulate form has the specific average grain diameter that is of value to fiber treatment; Relate to the fiber that carries described amphipathic lipids from the teeth outwards; Also relate to the method for handling described fiber.
Background technology
In the last few years, those textiless that the processing fiber application in textiles, particularly consumer that produce the effect that is similar to skin protection cosmetics dressed had in daily life been found to be designed for.Japanese Patent Application Publication (kokai) has disclosed the skin care fiber product that is attached with the protein that contains serine thereon 8-60547 number.Japanese Patent Application Publication (kokai) discloses a kind of finish composition that is used for fabric 2001-146680 number, and it comprises non-ionic amphiphilic materials.More specifically, described non-ionic amphiphilic materials is a ceramide, and preferably has ceramide with other compositions in composition, is the form that particle diameter is no more than the emulsion particle of 1000nm simultaneously.Because these features, composition disclosed herein it is said have excellent through the time stability of emulsion, prevent the precipitation of ceramide, and ceramide and pending fiber bonding and adhesive attraction with excellence.Equally, treated textiles can promote the moisture-retaining capacity of skin when the consumer dresses.Therefore, disclosed ceramide type material does not exist with solid form in the document.
But these technology still can not be very satisfactory, because the amount that the ceramide type material is retained on the fiber still can not provide enough effects, washing endurance is low, and can not improve the sensation of fiber under the situation of not sacrificing other features.
The purpose of this invention is to provide a kind of fibre finish, it can make the amphipathic lipids with skin care effect stably be retained on the fiber, pay the sensation of fiber excellence, and when the consumer dresses the final products of being made by this fiber, skin is produced wetting action, and when skin contacts with fiber product, pay the sensation of skin happiness.
Summary of the invention
The invention provides a kind of fibre finish composition, it is included in the amphipathic lipids that has one or more hydroxyls and one or more amide groups in the molecule, and described lipid is that average grain diameter is the solid particle of 1-100 μ m.
The present invention also provides a kind of fibre finish composition, and it also comprises the material that one or more are selected from surfactant and water-bearing media except that above-mentioned fibre finish component.
The present invention also provides a kind of treated fiber, and it is following making: above-mentioned fibre finish composition is contacted with fiber, make on the continuous or discontinuous surface that is present in described fiber of above-mentioned amphipathic lipids.
The present invention also provides a kind of fiber that is fixed with above-mentioned amphipathic lipids on it.
The present invention also provides a kind of method of handling fiber, and it comprises makes above-mentioned fibre finish composition contact with fiber.
The specific embodiment
(hereinafter referred to as component (a)) is defined as the lipid that has one or more hydroxyls and one or more amide groups in the molecule at lipid at this used term " amphipathic lipids that has one or more hydroxyls and one or more amide groups in molecule "; By the lipid in natural ceramide type material, synthetic ceramide type material and the scope for example formed by the synthetic analog (false manifestation of vitality is through amide substance) that makes; And be down the lipid of solid in room temperature (25 ℃).The example of amphipathic lipids comprises ceramide H03 (Sederma), ceramide II (Sederma), QuesamideH (Quest), ceramide TIC-001 (Takasago International Corporation) and SOFCARECERAMIDE SL-E (Kao Corp).The stability of the lipid from be incorporated in the fibre finish composition, described lipid preferably have and are not less than 30 ℃, more preferably are not less than 40 ℃ fusing point.In the synthetic similar thing of ceramide, particularly preferably be amide derivatives (comprising above-mentioned SOFCARECERAMIDE SL-E) with following formula (1) expression:
Wherein: R
1And R
2Be identical or different, and represent straight or branched independently respectively, saturated or undersaturated C
7-39Alkyl, this alkyl can be replaced by one or more hydroxyl; And R
3And R
4Be identical or different, and represent hydrogen atom independently respectively, phosphate residue, sulfate residue or saccharide residue; Condition is: comprise one or more hydroxyl in a molecule of this derivative.
In formula (1), R
1Preferably straight or branched, saturated or undersaturated C
9-25Alkyl; R
2Preferably straight or branched, saturated or undersaturated C
10-26Alkyl; And R
3And R
4Difference is hydrogen atom preferably.
The method for preparing above-mentioned amide derivatives (1) for example is described in detail in Japanese Patent Application Publication (kokai) 62-228048 and 63-216852 number.
Described amphipathic lipids be average grain diameter be 1-100 μ m, be preferably 2-100 μ m, more preferably 5-100 μ m, also more preferably 5-80 μ m, most preferably be the solid particle of 7-50 μ m.Preferably, this solid particle is to exist with crystal state.
Above-mentioned amphipathic lipids can use separately or two or more are used in combination, its use amount in fibre finish composition of the present invention is 0.005-40 weight %, be preferably 0.05-40 weight %, more preferably 5-40 weight % most preferably is 10-30 weight %.When the fibre finish composition is concentrated solution, the amount of described amphipathic lipids in the fibre finish composition is preferably 1-40 weight %, 5-40 weight % more preferably, most preferably be 10-30 weight %, and when described composition is weak solution, their amounts in the fibre finish composition are preferably 0.005-1 weight %, and more preferably 0.01-0.9 weight % most preferably is 0.02-0.6 weight %.
Surfactant (hereinafter referred to as component (b)) for the fibre finish composition that can be used for preparing the present invention does not have concrete restriction, and one or more surfactants can suitably be selected from non-ionic surface active agent, anion surfactant, amphoteric surfactant and cationic surfactant.
If described amphipathic lipids is at first carried out crystallization, is incorporated in the fibre finish composition then with component (b), then preferably one or more are selected from normally used surfactant in the cosmetics to component (b); For example be selected from non-ionic surface active agent, anion surfactant and amphoteric surfactant.
The example of non-ionic surface active agent comprises alkylpolyglycosides, polyoxyalkylene alkyl or alkenyl ether, polyoxyalkylene fatty acid esters of sorbitan, fatty acid esters of sorbitan, polyoxyalkylene Span, polyoxyalkylene fatty acid glyceride, polyglyceryl fatty acid ester, fatty acid monoglyceride, cithrol and Marlamid.
Examples of anionic surfactants comprises polyoxyalkylene alkyl acetate or its salt, N-acyl amino hydrochlorate, polyoxyalkylene alkyl sulfate, polyoxyalkylene alkyl phosphate, alkylphosphonic, N-acyl methyl taurine salt, alkyl sulfo succinate, polyoxyalkylene alkyl sulfo succinate and soap.
The example of amphoteric surfactant comprises p dialkylaminobenzoic acid betaine, alkyl amine oxide, alkylamide propyl-betaine, alkyl hydroxy sulfobetaines and amide groups amino acid (imidazoline type betaine).
Preferred surfactants is non-ionic surface active agent and polyethylene oxide alkyl ethers acetate or its salt.Preferred nonionic is alkylpolyglycosides, polyoxyalkylene alkyl or alkenyl ether, polyoxyalkylene fatty acid esters of sorbitan and fatty acid esters of sorbitan.
Most preferred nonionic surfactant comprises alkylpolyglycosides (for example wherein alkyl has 8-14 carbon atom and sugared condensation degree is 1-2 person), polyoxyalkylene alkyl or alkenyl ether (for example wherein alkyl or alkenyl have 8-18 carbon atom and also add oxidation ethene average mol be 4-25, be preferably 4-15 person), the polyoxyalkylene fatty acid esters of sorbitan (for example wherein aliphatic acid have 8-20 carbon atom and also add oxidation ethene average mol be 5-25 person), and fatty acid esters of sorbitan (monoesters that for example has the aliphatic acid of 8-20 carbon atom).
The example of polyoxyalkylene alkyl acetate or its salt comprise itself have 8-20 carbon atom and also add oxidation ethene average mol be these acid of 3-15; And alkali metal salt.That is to say, but polyoxyalkylene alkyl acetate former state (not being neutralized) is used or is used after neutralization.
When further interpolation cationic surfactant, can strengthen the absorption of described amphipathic lipids on fiber.The example of described cationic surfactant comprises list (chain alkyl) ammonium salt, two (chain alkyl) ammonium salt, benzene bundle ammonium salt, benzyl rope ammonium salt and pyridiniujm.
Above-mentioned surfactant all can use separately or two or more are used in combination.The incorporation of surfactant in the fibre finish composition is 2-55 weight %, is preferably 5-40 weight %.When carrying out crystallisation step, it is particularly preferred meeting these scopes.
The weight ratio of amphipathic lipids and surfactant promptly, (a)/(b), is preferably 90/10-25/75, and more preferably 80/20-30/70 most preferably is 70/30-40/60.When carrying out crystallisation step, it is particularly preferred meeting these scopes.
The water-bearing media for preparing the present invention's fibre finish composition in this used can being used for is the polar organic solvent of water and/or water soluble.The example of water-soluble polar organic solvent comprises alcohol, as methyl alcohol, ethanol and propyl alcohol; Glycols is as ethylene glycol, propylene glycol, diethylene glycol (DEG) and polyethylene glycol; And acetone.
The preferred example of water-bearing media comprises water, ethanol and glycols, and wherein water is most preferred.
When handling fiber, but fibre finish composition former state of the present invention is used or use after water and/or the dilution of water-soluble polar organic solvent, perhaps dilutes with surfactant and water-bearing media.When fibre finish composition of the present invention was concentrated solution, composition preferably diluted before use.
Fibre finish composition of the present invention can for example prepare by the following method: under agitation heat the mixture of amphipathic lipids (component (a)), surfactant (component (b)) and water to the temperature of the fusing point that is not less than amphipathic lipids (from fusing point to the temperature that is approximately higher than 10 ℃ of fusing points), make the mixture fusion thus, and after melt becomes homogeneous state, under agitation cool off melt, so that component (a) crystallization.
In the method, the particle diameter of component (a) can be regulated by type and amount, cooldown rate and the mixing speed etc. of control surface activating agent.Preferably, the average grain diameter of component (a) is 1-100 μ m, 2-100 μ m more preferably, and 5-100 μ m more preferably also, even 5-80 μ m more preferably most preferably are 7-50 μ m, and this average grain diameter is measured by method described below.In this used average grain diameter arithmetic mean value that is following mensuration: under light microscope, particle is being taken a picture under the transmitted light, selecting any 30 particles on the photo, then in 30 particles each is all being measured the main shaft of particle.
Fibre finish composition of the present invention also can comprise pH regulator agent, preservative agent, softening agent, curing agent, antistatic additive, sterilization/deodorant, wetting agent etc.
The example of wetting agent comprises plant extracts, Sodium Hyaluronate, collagen, animal oil, vegetable oil, paraffin, atoleine, vaseline, ceresine, saualane etc.
Plant extracts is the extract that is obtained by any plant, and the example of described plant comprises aloe, aloe vera, ginkgo, fennel, marine alga, the root of kudzu vine, yellow chamomile, Kiwi fruit, cucumber, sponge gourd, cape jasmine, rice bran, peach, citron, Job's tears, common wormwood artemisia, St. john's wort, tealeaves etc.
The example of vegetable oil comprises olive oil, camellia oil, macadamia oil, castor oil, Brazil wax, candelila wax, jojoba oil, safflower oil, soya-bean oil, galam butter, sunflower oil, cupu oil, coconut oil, palm kernel oil, pond flower seed oil, rice germ oil, orange oil etc.
The example of animal oil comprises ermine oil, beeswax, lanolin etc.
The example of used fiber comprises natural fabric among the present invention, as cotton, silk, fiber crops and wool; Regenerated fiber, as a chain for binding criminals entangle, bemsilk and day the silk (tensel); Semisynthetic fibre is as acetate fibre, diacetate fibre and triacetate; And synthetic fiber, as polyester fiber, nylon, acrylic fibre, vinylon, polypropylene fibre and polyurethane fibre.Form for fiber does not have special restriction, and the example of fiber comprises various fibrous materials such as staple fibre and yarn; Half product such as nonwoven fabric, braided fabric and textiles; And end product such as clothes and bedding.
The preferred example of the fiber product of being made by above-mentioned fiber is those products that directly contact use with skin or hair; Underwear particularly is as pantyhose, tights, lingerie, petticoat, camisole, pants, undershirt, sport pants and briefs; Substrate is as waistband, brassiere and bodysuit; Nightwear is used nightwear, nightwear and bathing gown as women and children; Clothes is as leotard, socks, waistband, gloves, scarf, mouth mask, towel and cap; And bedding, as pillowcase and sheet.
A method that is used to handle fiber according to the present invention is that fiber is contacted with fibre finish composition of the present invention.
This step that fiber is contacted with the fibre finish composition can comprise fiber is immersed in the fibre finish composition, and is dry then; And the fibre finish composition is sprayed on the fiber, dry then.These processing can produce in a continuous manner or discontinuous mode is carried the fiber of amphipathic lipids on the surface of fiber.Drying can or apply heat by nature and implement.By using for example flatiron or boiling hot trousers device, can carry out pressurized heat and handle.
The example of concrete processing method comprises rolling-the baking method of use ironer and drier; Use the dip dyeing method of winch dyeing mahcine, yarn package dyeing machine or jet dyeing machine; Spray-on process; Cladding process; Decal; And be applicable to that a chain for binding criminals is entangled or acrylic fibre add mixed method.
When relating to textile product, fibre finish composition of the present invention can use in the arbitrary steps during doing washing, for example in washing step, drip washing step, softening agent-arrangement step or starching step.Perhaps, fibre finish composition of the present invention can be applied directly on clothes or the bedding by methods such as sprayings.
In fiber-treating method of the present invention, amphipathic lipids is 0.001-5 weight % with respect to the use amount of fibre weight, and more preferably 0.05-1 weight % most preferably is 0.1-0.8 weight %.
When handling fiber, can choose the use adhesive wantonly.Consider that from washing persistent angle it is preferred using adhesive.The example of adhesive comprises silicones, acrylic resin, carbamate resins, vinyl acetate resin etc.(when promptly, carrying out fiber treatment) in the case, except that adhesive, also can use following reagent according to purpose: softening agent, curing agent, sewing make things convenient for agent (sewing facilitating agents), fire retardant, antistatic additive, refuse dirty agent, sterilization/deodorant, raising agent, antilubricant, wetting agent, water repellent, water absorbing agent, fluorescent dye, anti-piping compound such as glyoxal, fixative etc.
Consider that from good washing persistence and fiber treatment effect aspect with respect to the weight of amphipathic lipids, the use amount of adhesive is preferably 10-500 weight %, 50-300 weight % more preferably is based on wherein that the solid constituent of adhesive calculates.
It is believed that with the amphipathic lipids of dissolving or emulsification form and compare that because specific forms (promptly, average grain diameter be the particle of 1-100 μ m), amphipathic lipids of the present invention can not be incorporated into the inside of processed fiber, but can be fixed on effectively on the surface of fiber.In addition, when fiber-treating method comprised washing step or drip washing step, the amphipathic lipids of dissolving or emulsification form was washed off easily.But according to the present invention, because amphipathic lipids is the solid particle with suitable dimension, it is difficult for being washed off, and lipid can be retained on the fiber better thus.Owing to these reasons, the fiber of handling with fibre finish composition of the present invention is believed to make the fabric of gained to have excellent sensation, and skin is had pleasant sensation.
Embodiment
Embodiment 1-3 and Comparative Examples 1
Preparation fibre finish composition
Amphipathic lipids, surfactant and the water on embodiment 1-3 hurdle in the table 1 are heated to 80-90 ℃.Under agitation cool off the mixture of each gained subsequently, make the amphipathic lipids crystallization thus.Proceed to stir, and mixture is cooled to room temperature, produce the fibre finish composition thus.Find that the amphipathic lipids that comprises in the resulting composition is needle-like or flat crystal particle, average grain diameter is 11.8 μ m (embodiment 1), 8.9 μ m (embodiment 2) or 16.3 μ m (embodiment 3).Crystal state confirms with X-ray diffraction.
In Comparative Examples 1, repeat the method for embodiment 1, but the MYDOL10 of 32.0 weight portions obtains a kind of composition thus with the RHEODOL TW-S120 replacement of 23.0 weight portions, wherein amphipathic lipids crystallization not yet, but have (confirming) with X-ray diffraction with the form of emulsion particle.
Table 1
(weight portion)
| Embodiment | Comparative Examples | ||||
| 1 | 2 | 3 | 1 | ||
| (a) amphipathic lipids | Formula (1) R 1＝C 15H 31 R 2＝C 16H 33 R 3＝H R 4=H (fusing point: 74-76 ℃) | 20.0 | 23.0 | 15.0 | 20.0 |
| Formula (1) R 1＝C 17H 35 R 2＝C 14H 29 R 3＝H R 4=H (fusing point: 78-80 ℃) | 3.0 | ||||
| (b) surfactant | MYDOL 10 *1 | 32.0 | 25.0 | ||
| EMULGEN 106 *2 | 15.5 | ||||
| KAO AKYPO RLM-100 *3 | 2.0 | ||||
| RHEODOL TW-S120 *4 | 23.0 | ||||
| Water | Aequum | Aequum | Aequum | Aequum | |
| Average grain diameter | 11.8 | 8.9 | 16.3 | 1 or littler | |
| Particle form | Solid particle | Solid particle | Solid particle | Liquid particles | |
*1: the flower king, decyl gather glycosides (condensation degree: 1-1.35), active ingredient: 40 weight %
*2: flower king, polyoxyethylene (5) lauryl ether
*3: flower king, polyoxyethylene (10) lauryl ether acetate, active ingredient: 89 weight %
*4: flower king, polyoxyethylene (20) Arlacel-60
Test case 1 and contrast test example 1 and 2
The fibre finish composition that 1g is obtained by embodiment 1 is dispersed in the water of 2.0L, then will be soaks wherein with the pantyhose of commercially available detergent washing 5 times.Subsequently, with a pair of pantyhose dehydration of 25g once, drip washing in isopyknic water, and then dehydration, air dry obtains the present invention's treated fiber product thus.According to identical mode, prepare 3 pairs of pantyhose, and offer the panelist.5 have Dry and often complain that when dressing pantyhose the women panelist of itch carried out the pantyhose wearing test 3 days in the winter time.
For comparing, the composition that use is obtained by Comparative Examples 1, promptly, wherein amphipathic lipids is not crystalline state but the composition of emulsion particle form, handle severally in a comparable manner, and carry out wearing test (contrast test example 1) by 5 panelists identical with test case 1 to pantyhose.Carry out several wearing tests to pantyhose (contrast test example 2) equally, these pantyhose are similarly handled, but without the processing of fibre finish composition.
The results are shown in the table 2.Evaluation item and evaluation criteria are as follows.Result shown in the table is 5 panelists' a average mark.
The sensation of fabric (sense of touch)
4: very good
3: good
2: slightly poor
1: poor
The easiness (smooth property) of dressing
4: very good
3: good
2: slightly poor
1: poor
The sensation that skin feel arrives during wearing changes
4: become very good
3: improve
2: no change
1: variation
Wetting action during wearing
4: very effective
3: effectively
2: effective slightly
1: invalid
Pruitus behind the wearing
4: eliminate itch
3: itch is eliminated on a little degree ground
2: no change
1: itch increases the weight of
Table 2
| Test case 1 | Contrast test example 1 | Contrast test example 2 | |
| The sensation of fabric | 3.6 | 1.8 | 1.6 |
| The easiness of dressing | 4.0 | 2.2 | 2.0 |
| The sensation that skin feel arrives changes | 3.8 | 2.2 | 1.8 |
| Wetting action | 3.4 | 1.2 | 1.0 |
| Pruitus | 3.4 | 2.2 | 1.8 |
Can obviously find out from table 2, paid the sensation of the fiber product excellence of gained with the fiber of fibre finish compositions-treated of the present invention, when dressing this fiber product, show the smooth property of fiber product, improved sense of touch to skin, strengthen wetting action, and alleviated the itch of skin.
Test case 2-4
The fibre finish composition (respectively corresponding to test case 2,3 and 4) that 5g is obtained from embodiment 1,2 and 3 respectively is dispersed in the water of 10.0L.In the dispersion liquid of gained, soak the cotton fiber (COTTON FABRIC) of 1.0Kg.Afterwards, push COTTON FABRIC with ironer, drying is 30 minutes under 55 ℃, forms the present invention's treated fiber thus.
The panelist who is made up of 5 male sex and 5 women touches treated fiber and through similar processing but do not use the fiber of fibre finish composition of the present invention, they are compared aspect the sensation by the Blind Test method.Evaluation criteria is as follows.Score value in the table 3 is the mean value of 10 marks that the panelist gives.
Sensation
5: product of the present invention is better widely
4: product of the present invention is better
3: quite
2: untreated product is better
1: untreated product is better widely
Table 3
| Test case 2 | Test case 3 | Test case 4 | |
| Sensation | 4.4 | 4.1 | 3.8 |
Can find out obviously from table 3, compare that those fiber products with fibre finish compositions-treated of the present invention have excellent sensation when touching with hand with untreated fiber product.
Embodiment 4
Fibre finish composition of the present invention can be incorporated in the softener composition, and can be used for making fiber product to have flexibility.
Fibre finish composition (embodiment 1) 10.0%
QUARTAMIN D86P
*1) 3.0
EMULGEN 123P
*2) 0.5％
Ethylene glycol 1.5%
Level is weighed
Amount to 100.0%
*1) distearyl acyl group alkyl dimethyl ammonium chloride (product of Kao Corp, active ingredient 75%)
*2) polyoxyethylene (23) lauryl ether (product of Kao Corp)
Embodiment 5
Fibre finish composition (embodiment 2) 2.5%
Spices q.s.
Level is weighed
Amount to 100.0%
The composition of gained is placed in the automiser spray, then fully shakes, and be sprayed on the fiber product equably.
Industrial applicability
The fiber of processing with fiber treatment agent composition of the present invention can make the fabric of gained have excellent sensation, and skin is provided the sensation of pleasant. When the consumer dresses the fiber product of being made by the process fiber of processing like this; can obtain obvious effect; the sensation that comprises the pleasant of the skin that fiber product is contacted with it; the skin sparing effect; the effect that makes people with allergic skin be easy to dress; wetting action, and the effect that improves disease of skin such as coarse skin.
Claims (11)
1, the application of amphipathic lipids in the fibre finish composition, this amphipathic lipids have one or more hydroxyls and one or more amide groups in molecule, and are that average grain diameter is the solid particle of 1-100 μ m.
2, the application of amphipathic lipids as claimed in claim 1 in the fibre finish composition, wherein said amphipathic lipids is following obtaining: amphipathic lipids, surfactant and water-bearing media are heated to the temperature of the fusing point that is not less than this amphipathic lipids, carry out crystallization then.
3, the application of amphipathic lipids as claimed in claim 1 or 2 in the fibre finish composition, wherein said amphipathic lipids are the derivatives in order to following formula (1) expression:
Wherein: R
1And R
2Be identical or different, and represent straight or branched independently respectively, saturated or undersaturated C
7-39Alkyl, this alkyl is replaced by one or more hydroxyl or is not substituted; And R
3And R
4Be identical or different, and represent hydrogen atom independently respectively, phosphate residue, sulfate residue or saccharide residue; Condition is: comprise one or more hydroxyl in a molecule of this derivative.
4, as the application of the described amphipathic lipids of one of claim 1-3 in the fibre finish composition, the content of wherein said amphipathic lipids in the fibre finish composition is 0.005-40 weight %.
5, as the application of the described amphipathic lipids of one of claim 1-4 in the fibre finish composition, described fibre finish composition comprises that also one or more are selected from the material in following group: surfactant and water-bearing media.
6, a kind of treated fiber, it is by the fibre finish composition is contacted with fiber so that make on the continuous or discontinuous surface that is present in described fiber of described amphipathic lipids, wherein said fibre finish composition is included in the amphipathic lipids that has one or more hydroxyls and one or more amide groups in the molecule, and described lipid is that average grain diameter is the solid particle of 1-100 μ m.
7, a kind of fiber that is fixed with amphipathic lipids, wherein said amphipathic lipids has one or more hydroxyls and one or more amide groups in molecule, and is the solid particle of 1-100 μ m for average grain diameter.
8, a kind of method of handling fiber, it comprises makes the fibre finish composition contact with fiber, wherein said fibre finish composition is included in the amphipathic lipids that has one or more hydroxyls and one or more amide groups in the molecule, and described lipid is that average grain diameter is the solid particle of 1-100 μ m.
9, the method for processing fiber as claimed in claim 8, wherein said fiber is handled by being immersed in described fibre finish composition.
10, the method for processing fiber as claimed in claim 8, wherein said fiber is by handling described fibre finish composition spray on described fiber.
11, as the method for the described processing fiber of one of claim 8-10, wherein said fiber contacts with described fibre finish composition, and uses at least a material that is selected from following group jointly: adhesive, softening agent, curing agent, sewing make things convenient for agent, fire retardant, antistatic additive, refuse dirty agent, sterilization/deodorant, raising agent, antilubricant, wetting agent, water repellent, water absorbing agent, fluorescent dye, anti-piping compound and fixative.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP400934/2001 | 2001-12-28 | ||
| JP2001400934 | 2001-12-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1639410A CN1639410A (en) | 2005-07-13 |
| CN1323209C true CN1323209C (en) | 2007-06-27 |
Family
ID=19189701
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB028263235A Expired - Fee Related CN1323209C (en) | 2001-12-28 | 2002-12-20 | Fiber treatment agent composition |
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| Country | Link |
|---|---|
| US (1) | US20050086741A1 (en) |
| EP (1) | EP1521881B1 (en) |
| KR (1) | KR100950879B1 (en) |
| CN (1) | CN1323209C (en) |
| AU (1) | AU2002349788A1 (en) |
| ES (1) | ES2380428T3 (en) |
| WO (1) | WO2003057976A2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITTO20050788A1 (en) * | 2005-11-09 | 2007-05-10 | Sagitta Srl | PROCEDURE FOR THE TREATMENT OF FABRICS AND CLOTHING GARMENTS |
| CN105421052A (en) * | 2015-12-24 | 2016-03-23 | 常熟市馨格家纺有限公司 | Plush fabric |
| CN110172819B (en) * | 2019-05-17 | 2021-06-01 | 天津工业大学 | Amphiphilic carbon fiber and preparation method thereof |
| CN110453492B (en) * | 2019-08-12 | 2021-09-24 | 南通大学 | Long-acting washable antibacterial fabric finishing method |
| CN111992470B (en) * | 2020-08-24 | 2021-11-02 | 上海大学 | Fluorine-free super-hydrophobic surface and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1258492A (en) * | 1998-12-25 | 2000-07-05 | 花王株式会社 | Amphoteric lipids dispersion body |
| JP2001146680A (en) * | 1999-11-19 | 2001-05-29 | Bayer Ltd | Finishing agent composition for fiber |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1423201A (en) * | 1973-07-09 | 1976-02-04 | Ibis Engineers Ltd | Machines for washing garments |
| AU688737B2 (en) * | 1992-10-07 | 1998-03-19 | Quest International B.V. | Hydroxy alkyl amides of dicarboxylic acids and their use in cosmetic compositions |
| FR2702653B1 (en) * | 1993-03-16 | 1995-05-24 | Oreal | Use in cosmetics or in topical application of an aqueous dispersion based on non-volatile organopolysiloxanes and a crosslinked polymer of methacryloyloxyethyl trimethylammonium chloride. |
| FR2747567B1 (en) * | 1996-04-22 | 1998-05-22 | Oreal | USE OF CERAMIDE FOR THE TREATMENT OF NAILS |
| DE69732796T2 (en) * | 1996-10-08 | 2006-05-04 | Kao Corp. | ANTI WRINKLE AGENT |
| DE60140838D1 (en) * | 2000-05-12 | 2010-02-04 | Kao Corp | Absorbent object |
| JP3574059B2 (en) * | 2000-09-14 | 2004-10-06 | 花王株式会社 | Polymer particles |
-
2002
- 2002-12-20 KR KR1020047010016A patent/KR100950879B1/en not_active IP Right Cessation
- 2002-12-20 ES ES02786165T patent/ES2380428T3/en not_active Expired - Lifetime
- 2002-12-20 WO PCT/JP2002/013355 patent/WO2003057976A2/en active Application Filing
- 2002-12-20 AU AU2002349788A patent/AU2002349788A1/en not_active Abandoned
- 2002-12-20 US US10/498,820 patent/US20050086741A1/en not_active Abandoned
- 2002-12-20 EP EP02786165A patent/EP1521881B1/en not_active Expired - Fee Related
- 2002-12-20 CN CNB028263235A patent/CN1323209C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1258492A (en) * | 1998-12-25 | 2000-07-05 | 花王株式会社 | Amphoteric lipids dispersion body |
| JP2001146680A (en) * | 1999-11-19 | 2001-05-29 | Bayer Ltd | Finishing agent composition for fiber |
Also Published As
| Publication number | Publication date |
|---|---|
| KR100950879B1 (en) | 2010-04-06 |
| AU2002349788A8 (en) | 2003-07-24 |
| US20050086741A1 (en) | 2005-04-28 |
| EP1521881A2 (en) | 2005-04-13 |
| KR20040070273A (en) | 2004-08-06 |
| WO2003057976A2 (en) | 2003-07-17 |
| EP1521881B1 (en) | 2012-01-18 |
| AU2002349788A1 (en) | 2003-07-24 |
| CN1639410A (en) | 2005-07-13 |
| ES2380428T3 (en) | 2012-05-11 |
| WO2003057976A3 (en) | 2005-02-10 |
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