CN1320096C - Brewing equipment for preparing lightweight alkane from heavy hydrocarbon and process thereof - Google Patents

Brewing equipment for preparing lightweight alkane from heavy hydrocarbon and process thereof Download PDF

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CN1320096C
CN1320096C CNB2004100839431A CN200410083943A CN1320096C CN 1320096 C CN1320096 C CN 1320096C CN B2004100839431 A CNB2004100839431 A CN B2004100839431A CN 200410083943 A CN200410083943 A CN 200410083943A CN 1320096 C CN1320096 C CN 1320096C
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hydrocarbon
tank body
heavy hydrocarbon
fluidised form
renormalization
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CN1635105A (en
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姜国文
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Abstract

The present invention relates to a brewing appliance for preparing light alkane from heavy hydrocarbon and a technology thereof, and the brewing appliance for preparing light alkane from heavy hydrocarbon is used for preparing alkyl group hydrocarbon C8-C24 by mixing and brewing fermented herb grain hydrocarbon and the heavy hydrocarbon. The brewing appliance for preparing light alkane from heavy hydrocarbon is characterized in that the brewing appliance for preparing light alkane from heavy hydrocarbon is composed of a tank body, a double hydrogen factor transforming reflux filling post, a cross flow state reaction pipe, a catalytic reaction pipe, a hydrocarbon gas flow state reforming generator, a foam breaking net, a differential frequency local oscillator post, a differential frequency reflux pipe, a surplus heat stress ring-shaped space pipe and a heat absorption wing guide plate. The brewing appliance for preparing light alkane from heavy hydrocarbon is the production appliance having the advantages of simple structure, reasonable design, low energy consumption, low cost and low danger, and the production appliance can save steel and machining energy source. The present invention can convert heavy oil, residual oil, thickened oil, waste and old rubber tires, coal tar, coal and waste and old engineering plastic which can not be refined by the traditional oil refining technology into light hydrocarbon oil, and the present invention is an energy source development project and a resource development and utilization project. The present invention is also an environmental protection project having the advantages of little investment and obvious effect.

Description

A kind of heavy hydrocarbon prepares the brewing equipment and the technology thereof of light paraffins
Technical field
The present invention relates to a kind of utilization fermentation straw hydrocarbon and heavy hydrocarbon mixing and brewage preparation alkyl hydrocarbon C 8-C 24Heavy hydrocarbon prepare the brewing equipment and the technology thereof of light paraffins.
Background technology
Present oil shortage, energy shortage has become the major issue that influences Economic development, industry, agricultural, life, there is not one can leave the energy, but tellurian resource is not nexhaustible, and resources such as oil, coal have all been sent warning to people, at present, human recover petroleum resource has reached the limit.7,000 ten thousand tons of China's petroleum resource gaps in 2003, agricultural traffic material fuel oil, the consumption of ocean exploitation boats and ships heavy gas oil go up day by day.Investigate in by the end of October, 2003 according to: 2300 yuan/ton of fuel oil market valencys, 3100 yuan/ton of solar oil prices, existing market diesel oil retail price has broken through 4100 yuan/ton.Be the Energy resources approach exhaustions on one side, the other side is that Energy resources can not be regenerated, and seeks the new energy, produces cheap fuel, becomes urgent task of world energy sources science.For traffic in the world in future, industrial energy fuel, radical solving method is to seek the fuel that can substitute oil.Some countries of Europe, the U.S., Japan all give great attention to biofuel, and the respective standard of biofuel has been formulated in Europe, and this biofuel derives from soybean, rapeseed oil.Calendar year 2001, the yield of biodiesel of European Union broke through 1,000,000 tons, wherein France and Germany are maximum factory states, biofuel can be used on existing diesel engine, need not repacking, benz, BMW, the Volkswagen of Germany, various types of diesel engine of production all allow to use biofuel, and the U.S. begins the production biofuel in early 1990s, in addition, Canada, Brazil, Japan, new southwest and some other country are also in development biodiesel technology and industry.But because this biofuel is that soybean, vegetable seed are raw material, its cost is very high, brings certain difficulty for the popularization of biofuel.
The physicist thinks: plant that carbohydrate dry powder and photosynthesis are grown up down and crop, withered grass, academicly be called biomass resource, if be processed into particle, with oil, the mixed fermentation of hydro carbons microorganism, they are sublimate into to a certain degree, as long as alkylation a little, add strong oxidizer, just can synthesize primary explosive.Blast is the embodiment that material releases energy.At present, carbohydrate such as plant leaf, stalk, withered grass, except that a small part was used as agricultural byproducts or handicraft materials consumption, the overwhelming majority abandoned the field and burns in vain.Through measuring: routine is lighted or the mode of nature consumes stalk, only utilized the 12-13% of their energy, China abounds with 4600 kinds of gramineae plants, and wherein crop materials such as farm crop paddy rice, wheat, corn, jowar are produced 3.7 hundred million tons per year, 1.2 hundred million tons of wild withered grass, production and utilization that can be year after year, nexhaustible, inexhaustible, at present, countries in the world all are not used as industrial important source material to it, abandon or burn, had a strong impact on natural ecological environment.
Our oil Refining Technologies also can't be eaten the crude oil of exploiting out fully to do and be pressed only at present, the part oil field, industrial waste remains quite a few deposition heavy hydrocarbon resource, as, 1,700 ten thousand tons of the high viscous crudes that refining of petroleum can't achieve the goal, high 9,000,000 tons of the oil that coagulate, refine 3,000 ten thousand tons in residual oil etc., also have some depleted doughnuts, depleted engineering macromolecular material, discarded pitch, the coal tar of coking etc. can be found everywhere, not only cause the waste of resource, and cause environmental pollution, if these materials are all used raw material as the energy and twice-laid stuff, problem of environmental pollution not only can be solved, and problems such as the energy and regeneration novel material can be solved.
Our oil refining process still is a high energy consumption at present, expensive, the production technique of high-risk, with regard to the atmospheric and vacuum distillation unit of lifting refinery is example, when crude oil is heated to 360 ℃ in process furnace, part crude oil is vaporized, gasoline wherein, kerosene, the component that boiling points such as diesel oil are lower is preferentially vaporized, become gas, and heavy oil, the higher component of boiling points such as residual oil still is a liquid, enter atmospheric fractional tower, gas-liquid two-phase is able to initial gross separation, contains gasoline, kerosene, the mixed gas of diesel oil, through multiple condensation, heat exchange, mass exchange, at the lower boiling gasoline that arrives of cat head, obtain kerosene at last at the middle part, diesel oil, the bottom obtains heavy oil, because of the heavy oil boiling point very high, vaporization need be heated to 500 ℃, and under this temperature, oil product can decompose, therefore to carry out vacuum fractionation to heavy oil, at the vacuum fractionation tower, part heavy oil is vaporized at 400 ℃, improves the yield of oil product with this.167 of the total sized devices of atmospheric and vacuum distillation unit, be divided into five big classes, separation column is with regard to five, and the highest reaches 35 meters, 40 layers of column plates, three in process furnace, the highest reaches 17 meters, interchanger, water cooler, pump, container etc., do not comprise pipeline, the equipment rolled steel dosage reaches 5400 tons, so many equipment and pipeline is heated to 360 ℃ of temperature and maintain between 360-400 ℃ throughout the year, and energy consumption is well imagined.
Summary of the invention
The objective of the invention is to utilize the little engineering transition intersection of biological peptide transfer factor technology, design a kind of brewing equipment, with each kind of plant, crop material, withered grass, after attrition process and the mixed fermentation of biological peptide heavy hydrocarbon resolvase, mix with the part heavy hydrocarbons, the middle two hydrogen transfer factor prozymes of biology that switch are brewageed lightweight alkyl hydrocarbon C 8-C 24Oil fuel.
Technical scheme of the present invention is:
This equipment is by tank body, two hydrogen transfer factor backflow filled columns, intersection fluidised form reaction tubes, catalytic reaction tube, hydrocarbon gas fluidised form renormalization generator, foam breaking mesh, difference frequency local oscillator post, the difference frequency return line, be full of thermal stresses annular space pipe, heat absorption flyer lead plate constitutes, tank body is a horizontal cylindrical housings, four right cylinder hydrocarbon gas fluidised form renormalization generators are installed in the outer both sides, two ends, top of tank body respectively, and be communicated with tank body, two intersection fluidised form reaction tubess will be communicated with the hydrocarbon gas fluidised form renormalization generator of surveying two ends respectively, two hydrogen transfer factor backflow filled columns are contained in the top of tank body, the bottom is communicated with tank body, difference frequency return line one end is communicated with tank body, one end is communicated with the top of backflow filled column, catalytic reaction tube is connected two and intersects between the fluidised form reaction tubes, and with distillate the pipe be communicated with, foam breaking mesh is flat horizontal below the junction of hydrocarbon gas fluidised form renormalization generator and tank body, gas phase liquid phase two portions will be divided in the jar, difference frequency local oscillator post vertically is contained in center under the foam breaking mesh, two are full of the part of thermal stresses annular space pipe as tank shell, be installed in the two bottom sides of tank shell, heat absorption flyer lead plate is installed in outside the jar lower housing.
To mix with the 20-80% heavy hydrocarbon through proteinization, the alkylating biological peptide heavy hydrocarbon resolvase double hydrogen transfer factor modified cellulose 20-80% of modification (be called for short straw hydrocarbon, this preparation method has applied for Chinese patent) and add this equipment as raw material and brewage lighter hydrocarbons C 8-C 24, its design lifting force is a 4-6 rice, when material is heated when subliming up into hydrocarbon gas fluidised form renormalization generator, backflow filled column, by the hydro carbons gas molecule in space behind the biological enzyme target location, fails C by the lifting force reorganization at heat space 8-C 24, or greater than C 8-C 24The hydrocarbon molecules group reflux through foam breaking mesh feedback, most of along difference frequency local oscillator post recurrence liquid phase, because the temperature and the liquid phase temperature difference of the hydrocarbons that feedback refluxes are bigger, so cause a jar interior liquid phase fluid material generation local oscillator, quicken enzymatic reaction, press the C of lifting force reorganization at heat space 8-C 24The hydrocarbon molecules group enters the finished product jar through hydrocarbon gas fluidised form renormalization generator, intersection fluidised form reaction tubes, catalytic reaction tube, outlet pipe.
Filler in this technology hydrocarbon gas fluidised form renormalization generator is a zirconium white, and the filler in the catalytic reaction tube is an aluminium sesquioxide, with intersecting the fluidised form reaction tubes, carries out biological target, rectifying C 8-C 24
Filler in two hydrogen transfer factor backflow filled columns is the niobium molybdenum alloy, when material is subjected to heat sublimation to produce " hydro carbons fermentation gas (non-biogas) ", owing to hot-fluid attitude gas upwards enters, and by being back to liquid phase in the tank body repeatedly, with difference frequency local oscillator post, quicken enzymatic reaction.
Be full of and scribble niobium zirconium metallic coating in the hollow of thermal stresses annular space pipe, play save energy.
Vaporization temperature is 84-284 ℃.
It is simple in structure that the heavy hydrocarbon of the present invention design prepares the brewing equipment of light paraffins; reasonable in design; it is a less energy-consumption; low-cost; low dangerous production unit; only with one or several such brewing jars; just can finish traditional oil refining process and need several tall and big distillation towers; process furnace; just the production process that can finish realized no tower oil refining, and a brewing jar is used 175 kilograms of steel at most; can save more than 5200 ton of steel; oil outlet temperature only needs 140-280 ℃, has saved a large amount of manufactured energies, the heavy oil that traditional oil refining process can not be refined; residual oil; viscous crude; waste and used rubber tyre; coal tar; coal and waste and old engineering plastics are converted into light hydrocarbons oil; it is an energy development project; be again a resources development and utilization project, or an environmental protection project, less investment; instant effect is at one stroke several.
Description of drawings
Fig. 1 heavy hydrocarbon prepares light paraffins brewing jar internal structure synoptic diagram.
Fig. 2 heavy hydrocarbon prepares light paraffins brewing jar external structure synoptic diagram.
Wherein:
1, intersect fluidised form reaction tubes 2, catalytic reaction tube 3, distillate pipe 4, hydrocarbon gas fluidised form renormalization generator 5, two hydrogen transfer factor backflow filled column 6, gas-phase space 7, liquid phase space 8, scum pipe 9, be full of thermal stresses annular space pipe 10, heat absorption flyer lead plate 11, difference frequency local oscillator post 12, foam breaking mesh 13, housing 14, difference frequency return line
Embodiment
Embodiment 1
With reference to the accompanying drawings heavy hydrocarbon of the present invention is prepared light paraffins brewing jar structure below and carry out detailed stating.
Tank body is made horizontal cylindrical housings (13) and (is seen Fig. 1, Fig. 2), four right cylinder hydrocarbon gas fluidised form renormalization generators (4) are installed in the outer both sides, two ends, top of tank body respectively, and be communicated with tank body, two intersection fluidised form reaction tubess (1) will be communicated with the hydrocarbon gas fluidised form renormalization generator (4) of surveying two ends respectively, two hydrogen transfer factor backflow filled columns (5) are contained in the top of tank body, the bottom is communicated with tank body, difference frequency return line (14) one ends are communicated with tank body, one end is communicated with the top of backflow filled column, catalytic reaction tube (2) is connected two and intersects between the fluidised form reaction tubes (1), and with distillate pipe (3) and be communicated with, foam breaking mesh (12) is flat horizontal in the junction below of hydrocarbon gas fluidised form renormalization generator (4) with tank body, gas-phase space (6) and liquid phase space (7) two portions will be divided in the jar, difference frequency local oscillator post (11) vertically is contained in center under the foam breaking mesh (12), two are full of the part of thermal stresses annular space pipe (9) as tank shell, be installed in the two bottom sides of tank shell, heat absorption flyer lead plate (10) is installed in outside the jar lower housing, and scum pipe (8) is contained in the bottom of jar.Be full of and scribble niobium zirconium metallic coating in the hollow of thermal stresses annular space pipe, play save energy.
Embodiment 2
Filling material zirconia filler in the gas flow pattern renormalization generator in the equipment of embodiment 1 is loaded aluminium sesquioxide in the catalytic reaction tube, filling niobium molybdenum alloy in two hydrogen transfer factor backflow filled columns.Straw hydrocarbon with 30% mixes with 70% heavy oil, puts into aforesaid device and brewages alkane C 8-C 24Vaporization when temperature reaches 84-284 ℃ is failed C by lifting force reorganization at heat space 8-C 24, or greater than C 8-C 24The hydrocarbon molecules group, a part is kept off back by the gas flow pattern renormalization generator, reflux through the foam breaking mesh feedback, another part refluxes through the foam breaking mesh feedback by two hydrogen transfer factor backflow filled columns, and major part returns liquid phase along difference frequency local oscillator post, because the temperature and the liquid phase temperature difference of the hydrocarbons that feedback refluxes are bigger, so cause a jar interior liquid phase fluid material generation local oscillator, quicken enzymatic reaction, press the C of lifting force reorganization at heat space 8-C 24The hydrocarbon molecules group, the gas flow pattern renormalization generator through being filled with zirconia filler, intersect the fluidised form reaction tubes, be filled with the catalytic reaction tube of aluminium sesquioxide, produce refining alkane C 8-C 24The carbon dust of yield 60%, 40%.
Embodiment 3
With the equipment of embodiment 1, the technology of embodiment 2,20% straw hydrocarbon, 80% waste asphalt mixes to brewage produces refining alkane C 8-C 24, vaporization when temperature reaches 84-284 ℃ is failed C by lifting force reorganization at heat space 8-C 24, or greater than C 8-C 24The hydrocarbon molecules group, a part is kept off back by the gas flow pattern renormalization generator, reflux through the foam breaking mesh feedback, another part refluxes through the foam breaking mesh feedback by two hydrogen transfer factor backflow filled columns, and major part returns liquid phase along difference frequency local oscillator post, because the temperature and the liquid phase temperature difference of the hydrocarbons that feedback refluxes are bigger, so cause a jar interior liquid phase fluid material generation local oscillator, quicken enzymatic reaction, press the C of lifting force reorganization at heat space 8-C 24The hydrocarbon molecules group, the gas flow pattern renormalization generator through being filled with zirconia filler, intersect the fluidised form reaction tubes, be filled with the catalytic reaction tube of aluminium sesquioxide, produce refining alkane C 8-C 24
The Graphite Powder 99 of yield 60%, 40%.
Embodiment 4
With the equipment of embodiment 1, the technology of embodiment 2,40% straw hydrocarbon, 60% junked tire mixes to brewage produces refining alkane C 8-C 24, vaporization when temperature reaches 84-284 ℃ is failed C by lifting force reorganization at heat space 8-C 24, or greater than C 8-C 24The hydrocarbon molecules group, a part is kept off back by the gas flow pattern renormalization generator, reflux through the foam breaking mesh feedback, another part refluxes through the foam breaking mesh feedback by two hydrogen transfer factor backflow filled columns, and major part returns liquid phase along difference frequency local oscillator post, because the temperature and the liquid phase temperature difference of the hydrocarbons that feedback refluxes are bigger, so cause a jar interior liquid phase fluid material generation local oscillator, quicken enzymatic reaction, press the C of lifting force reorganization at heat space 8-C 24The hydrocarbon molecules group, the gas flow pattern renormalization generator through being filled with zirconia filler, intersect the fluidised form reaction tubes, be filled with the catalytic reaction tube of aluminium sesquioxide, produce refining alkane C 8-C 24
The calcium carbide powder of yield 60%, 40%.
Embodiment 5
With the equipment of embodiment 1, the technology of embodiment 2,50% straw hydrocarbon, 50% coal mixes to brewage produces refining alkane C 8-C 24, vaporization when temperature reaches 84-284 ℃ is failed C by lifting force reorganization at heat space 8-C 24, or greater than C 8-C 24The hydrocarbon molecules group, a part is kept off back by the gas flow pattern renormalization generator, reflux through the foam breaking mesh feedback, another part refluxes through the foam breaking mesh feedback by two hydrogen transfer factor backflow filled columns, and major part returns liquid phase along difference frequency local oscillator post, because the temperature and the liquid phase temperature difference of the hydrocarbons that feedback refluxes are bigger, so cause a jar interior liquid phase fluid material generation local oscillator, quicken enzymatic reaction, press the C of lifting force reorganization at heat space 8-C 24The hydrocarbon molecules group, the gas flow pattern renormalization generator through being filled with zirconia filler, intersect the fluidised form reaction tubes, be filled with the catalytic reaction tube of aluminium sesquioxide, produce refining alkane C 8-C 24The calcium carbide powder of yield 60%, 40%.
Embodiment 6
With the equipment of embodiment 1, the technology of embodiment 2,60% straw hydrocarbon, 40% waste and old engineering plastics mix to brewage produces refining alkane C 8-C 24, vaporization when temperature reaches 84-284 ℃ is failed C by lifting force reorganization at heat space 8-C 24, or greater than C 8-C 24The hydrocarbon molecules group, a part is kept off back by the gas flow pattern renormalization generator, reflux through the foam breaking mesh feedback, another part refluxes through the foam breaking mesh feedback by two hydrogen transfer factor backflow filled columns, and major part returns liquid phase along difference frequency local oscillator post, because the temperature and the liquid phase temperature difference of the hydrocarbons that feedback refluxes are bigger, so cause a jar interior liquid phase fluid material generation local oscillator, quicken enzymatic reaction, press the C of lifting force reorganization at heat space 8-C 24The hydrocarbon molecules group, the gas flow pattern renormalization generator through being filled with zirconia filler, intersect the fluidised form reaction tubes, be filled with the catalytic reaction tube of aluminium sesquioxide, produce refining alkane C 8-C 24
The calcium carbide powder of yield 60%, 40%.

Claims (2)

1. a heavy hydrocarbon prepares the brewing equipment of light paraffins, it is characterized in that: it is by tank body, two hydrogen transfer factor backflow filled columns, intersection fluidised form reaction tubes, catalytic reaction tube, hydrocarbon gas fluidised form renormalization generator, foam breaking mesh, difference frequency local oscillator post, the difference frequency return line, be full of thermal stresses annular space pipe, heat absorption flyer lead plate constitutes, tank body is a horizontal cylindrical housings, four right cylinder hydrocarbon gas fluidised form renormalization generators are installed in the outer both sides, two ends, top of tank body respectively, and be communicated with tank body, two intersection fluidised form reaction tubess will be communicated with the hydrocarbon gas fluidised form renormalization generator of surveying two ends respectively, two hydrogen transfer factor backflow filled columns are contained in the top of tank body, the bottom is communicated with tank body, two hydrogen transfer factor backflow filled column fillers are zirconium white or niobium molybdenum alloy, difference frequency return line one end is communicated with tank body, one end is communicated with the top of backflow filled column, catalytic reaction tube is connected two and intersects between the fluidised form reaction tubes, and with distillate the pipe be communicated with, the catalyzed reaction tube packing is an aluminium sesquioxide, foam breaking mesh is flat horizontal below the junction of hydrocarbon gas fluidised form renormalization generator and tank body, gas phase and liquid phase two portions will be divided in the jar, difference frequency local oscillator post vertically is contained in center under the foam breaking mesh, two are full of the part of thermal stresses annular space pipe as tank shell, be installed in the two bottom sides of tank shell, be full of and scribble niobium zirconium metallic coating in the hollow of thermal stresses annular space pipe, heat absorption flyer lead plate is installed in outside the jar lower housing.
2. a heavy hydrocarbon prepares the making method of light paraffins, it is characterized in that: it is that application rights requires 1 equipment, to mix with the 20-80% heavy hydrocarbon through proteinization, the alkylating biological peptide heavy hydrocarbon resolvase double hydrogen transfer factor modified cellulose 20-80% of modification and brewage, its design lifting force is a 4-6 rice, vaporization when temperature reaches 84-284 ℃ is failed C by lifting force reorganization at heat space 8-C 24, or greater than C 8-C 24The hydrocarbon molecules group, a part is kept off back by the gas flow pattern renormalization generator, reflux through the foam breaking mesh feedback, another part refluxes through the foam breaking mesh feedback by two hydrogen transfer factor backflow filled columns, and major part returns liquid phase along difference frequency local oscillator post, by because the temperature difference, liquid phase fluid material generation local oscillator in the jar that causes promotes enzymatic reaction, presses the C of lifting force reorganization at heat space 8-C 24The hydrocarbon molecules group through gas flow pattern renormalization generator, intersection fluidised form reaction tubes, catalytic reaction tube, distillates.
CNB2004100839431A 2004-10-13 2004-10-13 Brewing equipment for preparing lightweight alkane from heavy hydrocarbon and process thereof Expired - Fee Related CN1320096C (en)

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CN106929413B (en) * 2017-03-01 2023-03-17 姜国文 Brewing equipment and process for preparing alkane from chicken manure terpenized grass hydrocarbon

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86108918A (en) * 1986-12-30 1987-11-11 郑州工学院 The fermentor tank that has novel hybrid element
CN1082592A (en) * 1993-05-29 1994-02-23 何巨堂 C in the hydrotreatment process overhead gas 3, C 4The recovery method of hydrocarbon
CN2285679Y (en) * 1996-06-11 1998-07-08 中国石化洛阳石油化工工程公司 Two-stage combined selective cracking lift pipe reactor
CN1414067A (en) * 2002-09-17 2003-04-30 大庆油田有限责任公司 Recovery method of light hydrocarbon in natural gas

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86108918A (en) * 1986-12-30 1987-11-11 郑州工学院 The fermentor tank that has novel hybrid element
CN1082592A (en) * 1993-05-29 1994-02-23 何巨堂 C in the hydrotreatment process overhead gas 3, C 4The recovery method of hydrocarbon
CN2285679Y (en) * 1996-06-11 1998-07-08 中国石化洛阳石油化工工程公司 Two-stage combined selective cracking lift pipe reactor
CN1414067A (en) * 2002-09-17 2003-04-30 大庆油田有限责任公司 Recovery method of light hydrocarbon in natural gas

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