CN1319737A - Nanometer high-property resin composite material pipeline and making method thereof - Google Patents
Nanometer high-property resin composite material pipeline and making method thereof Download PDFInfo
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- CN1319737A CN1319737A CN 01102743 CN01102743A CN1319737A CN 1319737 A CN1319737 A CN 1319737A CN 01102743 CN01102743 CN 01102743 CN 01102743 A CN01102743 A CN 01102743A CN 1319737 A CN1319737 A CN 1319737A
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- resin
- pipeline
- nanometer
- composite material
- silvalin
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Abstract
The present invention relates to a nanometer high-performance resin composite material pipe and its production method. The hardening resin glue contains the following components; resin 100 portions, nanometer SiO2 0.5-10 portions and hardening agent 1-3 portions. Its production method incldues the following steps: enviloping nanometer SiO2 with 0.1-0.5 portions of organo-siloxane, then using ultrasonic equipment or high-performance crushing machine to break nanometer SiO2 agglomeration body, making them uniformly disperse into unsaturated resin or epoxy resin, adding other material, uniforrly stirring, dipping fibre fabric, winding, hardening, cutting, grinding and finishing so as to obtain the invented product with wear-resistance, resistance to impact, high tensile strength, high bending strength and high heat-resistance.
Description
The present invention relates to the application and the pipe technology field of resin material.
Glass fibre reinforced plastics (composite material) pipeline of using on the present market, though have preferably lightweight, characteristics such as high-strength, corrosion-resistant, hardness own is low, wear resistance is undesirable, deficiencies such as impact strength difference, tensile strength, flexural strength and resistance to heat await improving.In order to reach desirable intensity, must increase its thickness, so also with regard to the corresponding cost that increased, thereby influenced the popularization of this series products.
The purpose of this invention is to provide a kind of nanometer high-property resin composite material pipeline and manufacture method thereof, easy, reasonable, the easy row of its method, cost are low, its pipeline has characteristics such as good wear resistance, heat resistance, impact strength, tensile strength, flexural strength, and is of many uses.
One of the present invention is achieved in that a kind of nanometer high-property resin composite material pipeline, is made up of silvalin and cured resin glue, it is characterized in that cured resin glue made by the material of following parts by weight proportioning component:
100 parts of unsaturated resin or epoxy resin
Nanometer SiO
20.5-10 part
Curing agent 0.5-3 part
Promoter 0.2-6 part
Silvalin material useable glass fiber or carbon fiber.
This two manufacture method that is achieved in that a kind of above-mentioned nanometer high-property resin composite material pipeline of the present invention is characterized in that:
A, carry out glue preparation: add preparation by described parts by weight proportioning component, earlier with nanometer SiO
2Organosilicon oxidation alkane dispersing agent parcel with 0.1-0.5 part is handled, and uses ultrasonic equipment or high-performance shredder with nanometer SiO then
2Aggregate is pulverized, and it is distributed in unsaturated resin or the epoxy resin equably;
B, add curing agent and promoter in resin, puddle is even;
C, silvalin is carried out impregnation handle;
D, utilize mould that the silvalin of impregnation is twined, make desired pipeline;
E, with the pipeline finishing pipeline that gets product that cuts, polishes.
Particularly of the present invention: method is simple, rationally, easy row, cost is low, and its pipeline has good wear resistance, heat resistance, impact strength, tensile strength, characteristics that flexural strength is high.Can be widely used in industries such as urban construction, petrochemical industry, electric power, building, agricultural, application prospect is very wide.
Be described further below in conjunction with embodiment, but not as a limitation of the invention.
Embodiment:
1, liquid glue preparation:
Annotate: (1) resin is with epoxy resin or unsaturated resin, as 191 or 196 etc.;
| Material | Embodiment kg | ||||
| ????1 | ????2 | ????3 | ????4 | ????5 | |
| Unsaturated resin or epoxide resin | ????100 | ????100 | ????100 | ????100 | ????100 |
| Nanometer SiO 2 | ????0.5 | ????2 | ????5 | ????8 | ????10 |
| Curing agent | ????1 | ????1.5 | ????2 | ????2.5 | ????3 |
| Promoter | ????2 | ????3 | ????4 | ????5 | ????6 |
(2) curing agent can be routine techniques with methyl-ethyl ketone peroxide etc.;
(3) promoter can be routine techniques with cobalt naphthenate etc.
2, technology: method is with above-mentioned (summary).Bore φ 1000mm, wall thickness 16mm, long 12000mm.
3, the Performance Detection data following (with or not SiO
2Relatively):
Wear resistance: improve 1-2 doubly;
Impact strength: improve 50-70%;
Tensile strength: improve 10-30;
Flexural strength: improve 8-16%;
Martin's temperature: improve the 2-3 degree;
Overall cost: reduce 15-40%.
Claims (3)
1, a kind of nanometer high-property resin composite material pipeline is made up of silvalin and cured resin glue, it is characterized in that cured resin glue made by the material of following parts by weight proportioning component:
100 parts of unsaturated resin or epoxy resin
Nanometer SiO
20.5-10 part
Curing agent 0.5-3 part
Promoter 0.2-6 part
2, pipeline according to claim 1 is characterized in that the silvalin material is with glass fibre or carbon fiber.
3, the manufacture method of the described nanometer high-property resin composite material pipeline of arbitrary claim in a kind of claim 1 or 2 is characterized in that:
A, carry out glue preparation: add preparation by described parts by weight proportioning component, earlier with nanometer SiO
2Organosilicon oxidation alkane dispersing agent parcel with 0.1-0.5 part is handled, and uses ultrasonic equipment or high-performance shredder with nanometer SiO then
2Aggregate is pulverized, and it is distributed in unsaturated resin or the epoxy resin equably;
B, add curing agent and promoter in resin, puddle is even;
C, silvalin is carried out impregnation handle;
D, utilize mould that the silvalin of impregnation is twined, make desired pipeline;
E, with the pipeline finishing pipeline that gets product that cuts, polishes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011027436A CN1141505C (en) | 2001-01-04 | 2001-01-04 | Nanometer high-property resin composite material pipeline and making method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011027436A CN1141505C (en) | 2001-01-04 | 2001-01-04 | Nanometer high-property resin composite material pipeline and making method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1319737A true CN1319737A (en) | 2001-10-31 |
| CN1141505C CN1141505C (en) | 2004-03-10 |
Family
ID=4652957
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011027436A Expired - Fee Related CN1141505C (en) | 2001-01-04 | 2001-01-04 | Nanometer high-property resin composite material pipeline and making method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1141505C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103396656A (en) * | 2013-08-27 | 2013-11-20 | 连云港神鹰碳纤维自行车有限责任公司 | Preparation method of epoxy resin system for nanometer modified carbon fiber prepreg |
| CN105452374A (en) * | 2013-08-13 | 2016-03-30 | 3M创新有限公司 | Nanocomposites containing nonspherical silica nanoparticles, composites, articles, and methods of making same |
| CN106433033A (en) * | 2016-09-09 | 2017-02-22 | 天津工业大学 | Preparation technology for material for promoting frictional wear performance of epoxy resin under synergic effect of inorganic particles and carbon fibers |
-
2001
- 2001-01-04 CN CNB011027436A patent/CN1141505C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105452374A (en) * | 2013-08-13 | 2016-03-30 | 3M创新有限公司 | Nanocomposites containing nonspherical silica nanoparticles, composites, articles, and methods of making same |
| US10023725B2 (en) | 2013-08-13 | 2018-07-17 | 3M Innovative Properties Company | Nanocomposites containing nonspherical silica nanoparticles, composites, articles, and methods of making same |
| US10023724B2 (en) | 2013-08-13 | 2018-07-17 | 3M Innovative Properties Company | Nanocomposites containing spherical pyrogenic silica nanoparticles and composites, articles, and methods of making same |
| US10442914B2 (en) | 2013-08-13 | 2019-10-15 | 3M Innovative Properties Company | Nanocomposites containing silica nanoparticles and dispersant, composites, articles, and methods of making same |
| US10450444B2 (en) | 2013-08-13 | 2019-10-22 | 3M Innovative Properties Company | Nanocomposites containing spherical pyrogenic silica nanoparticles and composites, articles, and methods of making same |
| CN103396656A (en) * | 2013-08-27 | 2013-11-20 | 连云港神鹰碳纤维自行车有限责任公司 | Preparation method of epoxy resin system for nanometer modified carbon fiber prepreg |
| CN106433033A (en) * | 2016-09-09 | 2017-02-22 | 天津工业大学 | Preparation technology for material for promoting frictional wear performance of epoxy resin under synergic effect of inorganic particles and carbon fibers |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1141505C (en) | 2004-03-10 |
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