CN1318603A - Air purifying paint - Google Patents

Air purifying paint Download PDF

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Publication number
CN1318603A
CN1318603A CN 00115413 CN00115413A CN1318603A CN 1318603 A CN1318603 A CN 1318603A CN 00115413 CN00115413 CN 00115413 CN 00115413 A CN00115413 A CN 00115413A CN 1318603 A CN1318603 A CN 1318603A
Authority
CN
China
Prior art keywords
solvent
coating
titanium dioxide
silicone resin
gel adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 00115413
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Chinese (zh)
Other versions
CN1142230C (en
Inventor
马成夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANGHAI MINTAO INDUSTRY DEVELOPMENT Co Ltd
Original Assignee
SHANGHAI MINTAO INDUSTRY DEVELOPMENT Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANGHAI MINTAO INDUSTRY DEVELOPMENT Co Ltd filed Critical SHANGHAI MINTAO INDUSTRY DEVELOPMENT Co Ltd
Priority to CNB001154133A priority Critical patent/CN1142230C/en
Publication of CN1318603A publication Critical patent/CN1318603A/en
Application granted granted Critical
Publication of CN1142230C publication Critical patent/CN1142230C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

Air purifying paint consists of organic silicon resin or solvent-gel adhesive 20-35 wt%, titania 50-60 wt%, and solvent 10-30 wt%. When the paint is applied to building, overpass and road side, its titania can absorb nitrogen oxide by the catalysis of sunlight and this can solve problem of nitrogen oxide pollution effectively.

Description

A kind ofly purify atmospheric coating
The present invention relates to the technical field of fine chemical product, specifically a kind ofly purify atmospheric coating.
Increasing along with vehicle, from the particulate matter of pollution especially severe, the especially NOx of vehicle exhaust, it is a kind of fatal carcinogenic substance, and is very big to people's health harm, at present the coating that also can effectively not handle the pollution of Nox of China.
The object of the present invention is to provide a kind of atmospheric coating that purifies, it can absorb the oxynitride in the atmosphere.
Technical scheme of the present invention is achieved in that a kind of atmospheric coating that purifies, it is characterized in that: it is by silicone resin or solvent-gel adhesive, titanium dioxide and solvent composition, the weight percent of described coating is silicone resin or solvent-gel adhesive 20-35%, titanium dioxide 50-60%, solvent 10-30%.
A kind ofly purify atmospheric coating, it is characterized in that: it is by silicone resin or solvent-gel adhesive, titanium dioxide and solvent composition, the weight percent of described coating is silicone resin or solvent-gel adhesive 20-35%, titanium dioxide 50-60%, solvent 10-20%, gac 3-5%.
Titanium dioxide among the present invention (TIO2) is a kind of metal oxide, its energy gap very big (being 3ev more), it is a kind of n N-type semiconductorN material, when titanium dioxide is subjected to ultraviolet radiation, can decomposite the electronegative electronics (e-) that moves freely and the hole (n+) of positively charged voluntarily, form hole-electron pair, the oxygen trapped electron that absorption is dissolved in titanium dioxide surface forms O2, OH and H2O that the hole then will be adsorbed on titanium dioxide surface are oxidized to HO, the atomic oxygen and the hydroxyl free radical that generate have very strong chemically reactive, can generate NO2 with the Nox reaction in the atmosphere, NO2 generates the buildings that HNO3 is coated in this product in the city with the H2O reaction on surface, viaduct, the both sides of road, utilize the catalysis of sunlight, but titanium dioxide absorbing NOx wherein, through test, the employing thickness is that this coating of 15um is put into flow-through reactor, with UV-lamp irradiation 24 hours, feeding concentration in reactor is the NO of 10ppm, flow is 1.5v/mim, the average decreasing ratio of NO can solve the pollution problem of oxynitride effectively more than 80%.
Below the invention will be further described and provide embodiment.
The present invention is a kind of atmospheric coating that purifies, it is characterized in that: it is by silicone resin or solvent-gel adhesive, titanium dioxide and solvent composition, the weight percent of described coating is silicone resin or solvent-gel adhesive 20-35%, titanium dioxide 50-60%, solvent 10-30%; Silicone resin or solvent-gel adhesive are film forming matter,-as silicone resin all can, described titanium dioxide is the ultrafine powder of 10-30 nanometer, as catalyzer, solvent among the present invention is ethanol, propyl alcohol, butanols, amylalcohol, ethyl acetate, butylacetate, acetone, cyclohexanone, toluene, dimethylbenzene, also can increase the auxiliary agent of 3-5% in the specific implementation, this auxiliary agent adopts gac or pigment, makes this coating have the versicolor coating of ventilation property, water tolerance and weathering resistance.
Embodiment 1
Solvent-gel adhesive 20%
The titania powder 60% of 1O nanometer
Ethanol 20%
In flow-through reactor, this coating to be made film and adopted oxynitride to filter, specific absorption is 88%.
Embodiment 2
Sol-gel tackiness agent 30%
The titania powder 50% of 10 nanometers
Butanols 20%
In flow-through reactor, this coating to be made film and adopted oxynitride to filter, specific absorption is 83%.
Embodiment 3
Silicone glass resin 20%
The titania powder 60% of 10 nanometers
Ethyl acetate 17%
Gac 3%
In flow-through reactor, this coating to be made film and adopted oxynitride to filter, specific absorption is 85%.
Embodiment 4
Silicone resin 30%
The titania powder 50% of 30 nanometers
Dimethylbenzene 15%
Gac 5%
In flow-through reactor, this coating to be made film and adopted oxynitride to filter, specific absorption is 82%.
Embodiment 5
Silicone resin 35%
The titania powder 50% of 30 nanometers
Ethanol 10%
Pigment (golden red) 5%
In flow-through reactor, this coating to be made film and adopted oxynitride to filter, specific absorption is 82%.
Embodiment 6
Silicone glass resin 35%
The titania powder 50% of 25 nanometers
Acetone 10%
Gac 5%
In flow-through reactor, this coating to be made film and adopted oxynitride to filter, specific absorption is 81%.
Embodiment 7
Silicone glass resin 35%
The titania powder 50% of 30 nanometers
Toluene 10%
Pigment (golden yellow) 5%
In flow-through reactor, this coating to be made film and adopted oxynitride to filter, specific absorption is 83%.

Claims (4)

1, a kind ofly purifies atmospheric coating, it is characterized in that: it is by silicone resin or solvent-gel adhesive, titanium dioxide and solvent composition, the weight percent of described coating is silicone resin or solvent-gel adhesive 20-35%, titanium dioxide 50-60%, solvent 10-30%.
2, by the described a kind of atmospheric coating that purifies of claim 1, it is characterized in that: titanium dioxide is the ultrafine powder of 10-30 nanometer.
3, by the described a kind of atmospheric coating that purifies of claim 1, it is characterized in that: solvent is ethanol, propyl alcohol, butanols, amylalcohol, ethyl acetate, butylacetate, acetone, pimelinketone, toluene, dimethylbenzene.
4, a kind ofly purify atmospheric coating, it is characterized in that: it is by silicone resin or solvent-gel adhesive, titanium dioxide and solvent composition, the weight percent of described coating is silicone resin or solvent-gel adhesive 20-35%, titanium dioxide 50-60%, solvent 10-20%, gac 3-5%.
CNB001154133A 2000-04-20 2000-04-20 Air purifying paint Expired - Fee Related CN1142230C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB001154133A CN1142230C (en) 2000-04-20 2000-04-20 Air purifying paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB001154133A CN1142230C (en) 2000-04-20 2000-04-20 Air purifying paint

Publications (2)

Publication Number Publication Date
CN1318603A true CN1318603A (en) 2001-10-24
CN1142230C CN1142230C (en) 2004-03-17

Family

ID=4584861

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB001154133A Expired - Fee Related CN1142230C (en) 2000-04-20 2000-04-20 Air purifying paint

Country Status (1)

Country Link
CN (1) CN1142230C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101768410A (en) * 2010-01-29 2010-07-07 海洋王照明科技股份有限公司 Diffuse reflection coating and reflector with the same
CN102247755A (en) * 2011-04-26 2011-11-23 同济大学 Method for decomposing automobile tail gas
CN101760133B (en) * 2009-11-30 2014-04-09 中昊北方涂料工业研究设计院有限公司 Mn-Ni-SBA-15 coating material for removing ozone

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101760133B (en) * 2009-11-30 2014-04-09 中昊北方涂料工业研究设计院有限公司 Mn-Ni-SBA-15 coating material for removing ozone
CN101768410A (en) * 2010-01-29 2010-07-07 海洋王照明科技股份有限公司 Diffuse reflection coating and reflector with the same
CN101768410B (en) * 2010-01-29 2013-06-12 海洋王照明科技股份有限公司 Diffuse reflection coating and reflector with the same
CN102247755A (en) * 2011-04-26 2011-11-23 同济大学 Method for decomposing automobile tail gas

Also Published As

Publication number Publication date
CN1142230C (en) 2004-03-17

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Granted publication date: 20040317