CN1315465A - Glass-fibre reinforced warp-resistant polypropylene with low shrinkage ratio - Google Patents

Glass-fibre reinforced warp-resistant polypropylene with low shrinkage ratio Download PDF

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Publication number
CN1315465A
CN1315465A CN 00115313 CN00115313A CN1315465A CN 1315465 A CN1315465 A CN 1315465A CN 00115313 CN00115313 CN 00115313 CN 00115313 A CN00115313 A CN 00115313A CN 1315465 A CN1315465 A CN 1315465A
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China
Prior art keywords
fiber reinforced
glass fiber
reinforced polypropylene
novel glass
polypropylene according
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CN 00115313
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Chinese (zh)
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CN1126784C (en
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陈媛
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Liaoning Liaojie Science & Technology Co ltd
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Shanghai Genius Advanced Materials Group Co Ltd
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Abstract

A glass fibre reinforced polypropylene contains copolypropylene (200-700 Wt. portions), styrene resin (100-300), compatibilizer (50-200), glass fibre (1-300), coupling agent (1-10), cross-linking agent (1-10), antioxidizing agent (1-3), molecular weight regulator (1-10), assistant (0-3) and inorganic filler (1-300). Its advantages include low shrinkage ratio, uniform longitudinal and transverse shrinkage retios, and no surface buckle.

Description

A kind of glass-fibre reinforced warp-resistant polypropylene with low shrinkage ratio
The present invention relates to organic polymer material, relate in particular to a kind of glass-fibre reinforced warp-resistant polypropylene with low shrinkage ratio.
Glass fibre enhanced polypropylene (PP) material has advantages such as high rigidity, thermotolerance, resistance to chemical attack, weathering resistance and dimensional stabilizing, jumped out the original range of application of polypropylene, entered the engineering plastics field, Alloy instead of Copper, steel, timber, nylon, polyoxymethylene, polycarbonate etc. now have been widely used in fields such as automobile, electrical equipment, motor, machinery, household electrical appliances within the specific limits.Because the length-to-diameter ratio of glass fibre is far longer than 1 (staple length and fiber cross section diameter ratio) in the PP resin, therefore when product molding shrinks, horizontal vertical shrinking percentage difference, the result causes goods warpage to occur, if in the goods endoporus is arranged, the not round phenomenon in aperture can occur, make it to be applied to the precision size parts, thereby limited the range of application of this material greatly.
Purpose of the present invention is exactly to provide a kind of horizontal vertical shrinking percentage uniform glass-fibre reinforced warp-resistant polypropylene with low shrinkage ratio for the defective that overcomes above-mentioned prior art existence.
Purpose of the present invention can realize in the following manner: a kind of glass-fibre reinforced warp-resistant polypropylene with low shrinkage ratio is characterized in that: it comprises following component and content (weight part):
Co-polypropylene 200～700
Styrene resin 100～300
Compatilizer 50～200
Glass fibre 1～300
Coupling agent 1～10
Linking agent 1～10
Oxidation inhibitor 1～3
Molecular weight regulator 1～10
Other auxiliary agent 0～3
Mineral filler 1～300
Described Co-polypropylene melting index is 15.0～25.0g/10min, tensile strength 〉=20MPa.
Described styrene resin adopts vinyl cyanide, vinylbenzene polymeric resin, or styrene homopolymers or the noncrystalline resin of copolymer analog.
Described compatilizer employing polypropylene and unsaturated acid, Anhydride-grafted polymers.
Described glass fibre is an alkali free glass fibre, and its metric system number is 1000～2500 tex, and diameter is 10～16 microns.
Described coupling agent is the silicane homologue, can be KH550.
Described linking agent adopts bismaleimides.
Described oxidation inhibitor is Hinered phenols antioxidant, can be antioxidant CA, antioxidant 1010.
Described mineral filler is mica, talcum powder, lime carbonate class inorganic materials.
Described molecular weight regulator is the butanone or the ethyl acetate solution of dicumyl peroxide, dibenzoyl peroxide class.
Described other auxiliary agent can be thermo-stabilizer or releasing agent, for example, and calcium stearate, molybdenumdisulphide.
Compared with prior art, the present invention adopts Co-polypropylene as matrix resin, strengthen with glass fibre, in order to prevent the finished product warpage, in compound system, add the noncrystalline resin of styrenic, the stable contraction rate that can make material is in that (molding shrinkage of virgin pp is 1.5% below 0.5%, the molding shrinkage of general glass fibre enhanced polypropylene is 0.5～0.7%), and the difference within ± 0.02% scope (general glass fibre enhanced polypropylene material 〉=0.1%) of shrinking percentage in length and breadth.The present invention adds mineral filler in system, further reduced molding shrinkage.
Adopt the resulting a series of glass fiber reinforced polypropylene materials of above technique means, mechanical propertys such as its stretching, shock strength and thermotolerance are similar with general glass fiber reinforced polypropylene material, but shrinking percentage is lower than general glass fiber reinforced polypropylene material, and shrink evenly the no warpage in surface in length and breadth.Be suitable for making precise part.
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment 1:
With the Co-polypropylene is base mateiral, styrene resin adopts maleic anhydride graft styrol copolymer (AS-g-MAH), with maleic anhydride inoculated polypropylene (PP-g-MAH) is compatilizer, and alkali free glass fibre is as strengthening material, and the content of other blend component (weight) is as follows:
Unit: kilogram
Co-polypropylene 300
AS-g-MAH??????150
PP-g-MAH??????150
Glass fibre 100
KH550????????????5
Bismaleimides 10
Antioxidant 1010 1
Other auxiliary agent 1
Mica 250
Above-mentioned component except that glass fibre was placed high-speed mixer and mixing 2～3 minutes, and extruding pelletization adds glass fibre in extrusion then, is injection molded into the standard batten after the drying, and for performance test, performance is as follows:
Melt flow rate (MFR) (230 ℃, 2.16kG) g/10min ????6.4
Tensile strength MPa ????46
Charpy shock strength KJ/m 2 ????15.0
Charpy notched Izod impact strength KJ/m 2(25℃) ????8.4
Flexural strength MPa ????84
Modulus in flexure MPa ????6440
Shrinking percentage % Horizontal ????0.30
Vertical ????0.30
Embodiment 2～6
With the Co-polypropylene is base mateiral, styrene resin adopts maleic anhydride graft styrol copolymer (AS-g-MAH) and vinylbenzene superpolymer (AS), with maleic anhydride inoculated polypropylene (PP-g-MAH) is compatilizer, alkali free glass fibre is as strengthening material, and the content of other blend component (weight) is as follows:
Unit: kilogram
2??????3??????4??????5??????6
Co-polypropylene 200 280 300 300 580
AS-g-MAH???????-?????170????100????100????120
AS????????????300?????-?????100????150?????-
PP-g-MAH???????50????150????200????100????150
Glass fibre 150 100 200 100 50
KH550???????????8?????5???7?????5?????5
Bismaleimides 5 10 8 10 10
Antioxidant 1010 21111
Calcium stearate 1 1-1 1
Molybdenumdisulphide 1----
Dicumyl peroxide 2-4-7
Ethyl acetate solution-2-5-
Mica 300 250 100 250-
Talcum powder----100
Above-mentioned component except that glass fibre was placed high-speed mixer and mixing 2～3 minutes, and extruding pelletization adds glass fibre in extrusion then, is injection molded into the standard batten after the drying, and for performance test, performance is as follows:
???2 ??3 ??4 ??5 ??6
Melt flow rate (MFR) (230 ℃, 2.16kG) g/10min ?5.53 ?6.2 ?4.93 ?8.9 ?9.5
Tensile strength MPa ?47.0 ?45.3 ?52.0 ?43.0 ?41.5
Charpy shock strength KJ/m 2 ?14.2 ?16.3 ?16.9 ?17.6 ?18.4
Charpy notched Izod impact strength KJ/m 2(25℃) ?7.9 ?8.7 ?9.4 ?9.6 ?7.6
Flexural strength MPa ?84.9 ?81.9 ?100 ?74.0 ?69.1
Modulus in flexure MPa ?6613.6 ?7003.6 ?5996.3 ?5996.3 ?5697.4
Shrinking percentage % Horizontal ?0.25 ?0.28 ?0.28 ?0.26 ?0.38
Vertical ?0.25 ?0.27 ?0.26 ?0.26 ?0.38

Claims (10)

1. novel glass fiber Reinforced Polypropylene, it is characterized in that: it comprises following component and content (weight part):
Co-polypropylene 200～700
Styrene resin 100～300
Compatilizer 50～200
Glass fibre 1～300
Coupling agent 1～10
Linking agent 1～10
Oxidation inhibitor 1～3
Molecular weight regulator 1-10
Other auxiliary agent 0～3
Mineral filler 1～300
2. a kind of novel glass fiber Reinforced Polypropylene according to claim 1 is characterized in that: described Co-polypropylene melting index is 15.0～25.0g/10min, tensile strength 〉=20MPa.
3. a kind of novel glass fiber Reinforced Polypropylene according to claim 1 is characterized in that: described styrene resin adopts vinyl cyanide, vinylbenzene polymeric resin, or styrene homopolymers or the noncrystalline resin of copolymer analog.
4. a kind of novel glass fiber Reinforced Polypropylene according to claim 1 is characterized in that: described compatilizer employing polypropylene and unsaturated acid, Anhydride-grafted polymers.
5. a kind of novel glass fiber Reinforced Polypropylene according to claim 1 is characterized in that: described glass fibre is an alkali free glass fibre, and its metric system number is 1000～2500 tex, and diameter is 10～16 microns.
6. a kind of novel glass fiber Reinforced Polypropylene according to claim 1 is characterized in that: described coupling agent is the silicane homologue, can be KH550.
7. a kind of novel glass fiber Reinforced Polypropylene according to claim 1 is characterized in that: described linking agent adopts bismaleimides.
8. a kind of novel glass fiber Reinforced Polypropylene according to claim 1 is characterized in that: described oxidation inhibitor is Hinered phenols antioxidant, can be antioxidant CA, antioxidant 1010.
9. a kind of novel glass fiber Reinforced Polypropylene according to claim 1 is characterized in that: described mineral filler is mica, talcum powder, lime carbonate class inorganic materials.
10. a kind of novel glass fiber Reinforced Polypropylene according to claim 1 is characterized in that: described molecular weight regulator is the butanone or the ethyl acetate solution of dicumyl peroxide, dibenzoyl peroxide class.
CN 00115313 2000-03-30 2000-03-30 Glass-fibre reinforced warp-resistant polypropylene with low shrinkage ratio Expired - Lifetime CN1126784C (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1295274C (en) * 2004-12-29 2007-01-17 刘明春 Recovery and shaping process of polypropylene composite waste material
CN102181100A (en) * 2011-03-18 2011-09-14 四川长虹电器股份有限公司 Glass fiber reinforced co-polypropylene composite material and preparation method of the Glass fiber reinforced co-polypropylene composite material
CN102329454A (en) * 2011-10-18 2012-01-25 深圳市科聚新材料有限公司 Polypropylene composite material as well as preparation method and application thereof
CN102382370A (en) * 2011-10-18 2012-03-21 深圳市科聚新材料有限公司 Polypropylene engineering plastic as well as preparation method and application thereof
CN102807710A (en) * 2012-08-15 2012-12-05 科沃斯机器人科技(苏州)有限公司 Glass fiber reinforced polypropylene compound material and preparation method thereof
CN102816384A (en) * 2012-08-08 2012-12-12 金发科技股份有限公司 Glass fiber-reinforced polypropylene material with shallow shrinkage mark and low warpage as well as preparation method and application thereof
CN101715386B (en) * 2007-06-11 2013-01-30 道达尔石油化学产品研究弗吕公司 Method for minimising shrinkage and warpage in rotomoulding applications
CN102911437A (en) * 2012-11-12 2013-02-06 上海清远管业科技有限公司 Skin-core structured glass fiber reinforced resin composite material and fabricating method thereof
CN103012968A (en) * 2012-11-21 2013-04-03 合肥杰事杰新材料股份有限公司 Weather-resistant glass fiber reinforced polypropylene composite and preparation method thereof
CN103160030A (en) * 2011-12-16 2013-06-19 上海铂砾耐材料科技有限公司 Thermoplastic composite material for hollow building templates and manufacture method thereof and application thereof
CN103254614A (en) * 2012-02-16 2013-08-21 合肥杰事杰新材料股份有限公司 Bismaleimide modified thermoplastics and preparation method thereof
CN103589060A (en) * 2013-10-29 2014-02-19 天津金发新材料有限公司 Glass fiber reinforced polypropylene/polystyrene alloy composite material and its preparation and application thereof
CN107163426A (en) * 2017-06-05 2017-09-15 中山大学惠州研究院 A kind of 3D printing low warpage ABS material and preparation method thereof
CN108929485A (en) * 2017-05-25 2018-12-04 合肥杰事杰新材料股份有限公司 A kind of creep-resistant polypropylene composite material

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1295274C (en) * 2004-12-29 2007-01-17 刘明春 Recovery and shaping process of polypropylene composite waste material
CN101715386B (en) * 2007-06-11 2013-01-30 道达尔石油化学产品研究弗吕公司 Method for minimising shrinkage and warpage in rotomoulding applications
CN102181100A (en) * 2011-03-18 2011-09-14 四川长虹电器股份有限公司 Glass fiber reinforced co-polypropylene composite material and preparation method of the Glass fiber reinforced co-polypropylene composite material
CN102181100B (en) * 2011-03-18 2012-12-19 四川长虹电器股份有限公司 Glass fiber reinforced co-polypropylene composite material and preparation method of the Glass fiber reinforced co-polypropylene composite material
CN102329454B (en) * 2011-10-18 2013-10-16 深圳市科聚新材料有限公司 Polypropylene composite material as well as preparation method and application thereof
CN102329454A (en) * 2011-10-18 2012-01-25 深圳市科聚新材料有限公司 Polypropylene composite material as well as preparation method and application thereof
CN102382370A (en) * 2011-10-18 2012-03-21 深圳市科聚新材料有限公司 Polypropylene engineering plastic as well as preparation method and application thereof
CN102382370B (en) * 2011-10-18 2015-01-21 深圳市科聚新材料有限公司 Polypropylene engineering plastic as well as preparation method and application thereof
CN103160030A (en) * 2011-12-16 2013-06-19 上海铂砾耐材料科技有限公司 Thermoplastic composite material for hollow building templates and manufacture method thereof and application thereof
CN103254614A (en) * 2012-02-16 2013-08-21 合肥杰事杰新材料股份有限公司 Bismaleimide modified thermoplastics and preparation method thereof
CN102816384A (en) * 2012-08-08 2012-12-12 金发科技股份有限公司 Glass fiber-reinforced polypropylene material with shallow shrinkage mark and low warpage as well as preparation method and application thereof
CN102816384B (en) * 2012-08-08 2014-09-10 金发科技股份有限公司 Glass fiber-reinforced polypropylene material with shallow shrinkage mark and low warpage as well as preparation method and application thereof
CN102807710A (en) * 2012-08-15 2012-12-05 科沃斯机器人科技(苏州)有限公司 Glass fiber reinforced polypropylene compound material and preparation method thereof
CN102911437A (en) * 2012-11-12 2013-02-06 上海清远管业科技有限公司 Skin-core structured glass fiber reinforced resin composite material and fabricating method thereof
CN103012968A (en) * 2012-11-21 2013-04-03 合肥杰事杰新材料股份有限公司 Weather-resistant glass fiber reinforced polypropylene composite and preparation method thereof
CN103589060A (en) * 2013-10-29 2014-02-19 天津金发新材料有限公司 Glass fiber reinforced polypropylene/polystyrene alloy composite material and its preparation and application thereof
CN103589060B (en) * 2013-10-29 2016-02-10 天津金发新材料有限公司 Fiber glass reinforced polypropylene/polystyrene alloy matrix material and preparation and application thereof
CN108929485A (en) * 2017-05-25 2018-12-04 合肥杰事杰新材料股份有限公司 A kind of creep-resistant polypropylene composite material
CN107163426A (en) * 2017-06-05 2017-09-15 中山大学惠州研究院 A kind of 3D printing low warpage ABS material and preparation method thereof

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