CN1314503C - Electromagnetic wave absorbing material containing carbon covered metal or metal compound and its application - Google Patents
Electromagnetic wave absorbing material containing carbon covered metal or metal compound and its application Download PDFInfo
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- CN1314503C CN1314503C CNB021391173A CN02139117A CN1314503C CN 1314503 C CN1314503 C CN 1314503C CN B021391173 A CNB021391173 A CN B021391173A CN 02139117 A CN02139117 A CN 02139117A CN 1314503 C CN1314503 C CN 1314503C
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- electromagnetic wave
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- metal compound
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 48
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 29
- 239000002184 metal Substances 0.000 title claims abstract description 25
- 150000002736 metal compounds Chemical class 0.000 title claims abstract description 20
- 239000011358 absorbing material Substances 0.000 title claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 63
- 230000005855 radiation Effects 0.000 claims abstract description 7
- 238000004891 communication Methods 0.000 claims abstract description 3
- 230000002745 absorbent Effects 0.000 claims description 19
- 239000002250 absorbent Substances 0.000 claims description 19
- 239000003595 mist Substances 0.000 claims description 18
- 239000012188 paraffin wax Substances 0.000 claims description 8
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 239000002923 metal particle Substances 0.000 claims description 5
- 229910000765 intermetallic Inorganic materials 0.000 claims description 4
- 239000011817 metal compound particle Substances 0.000 claims description 4
- 229910010272 inorganic material Inorganic materials 0.000 claims description 3
- 239000011147 inorganic material Substances 0.000 claims description 3
- 239000011368 organic material Substances 0.000 claims description 3
- 229920000128 polypyrrole Polymers 0.000 claims description 3
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 claims description 2
- 229920005479 Lucite® Polymers 0.000 claims description 2
- 229910052779 Neodymium Inorganic materials 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- 239000000956 alloy Substances 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 150000001247 metal acetylides Chemical class 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 150000004767 nitrides Chemical class 0.000 claims description 2
- 239000011295 pitch Substances 0.000 claims description 2
- 229920000767 polyaniline Polymers 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims 2
- 229910052737 gold Inorganic materials 0.000 claims 2
- 230000035699 permeability Effects 0.000 abstract description 8
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 239000006229 carbon black Substances 0.000 description 3
- QMQXDJATSGGYDR-UHFFFAOYSA-N methylidyneiron Chemical compound [C].[Fe] QMQXDJATSGGYDR-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000000946 retinyl group Chemical group [H]C([*])([H])/C([H])=C(C([H])([H])[H])/C([H])=C([H])/C([H])=C(C([H])([H])[H])/C([H])=C([H])/C1=C(C([H])([H])[H])C([H])([H])C([H])([H])C([H])([H])C1(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Landscapes
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
- Hard Magnetic Materials (AREA)
Abstract
The present invention relates to an electromagnetic wave absorbing material in which carbon coated metal and carbon coated metal compounds are contained and the application of the electromagnetic wave absorbing material. The electromagnetic wave absorbing material is composed of carbon coated metal or carbon coated metal compounds and substrate materials, and has a good complex dielectric constant and complex permeability within a microwave and an infrared frequency ranges. The present invention is widely applied to the fields of electromagnetic wave radiation, radar wave signal attenuation, electromagnetic interference resistance, labor protection, etc. for example, the present invention can be used as a radar absorbing material, an infrared absorption material, an electromagnetic wave radiation resistance labor protection article, an electromagnetic wave shielding material or device for a computer and communication equipment, an electromagnetic wave radiation resistance material for mobile telephones, etc.
Description
Technical field
The present invention relates to a kind of electromagnetic wave absorbent material, more particularly it is a kind of carbon containing genus covered with gold leaf, carbon covered metal compound electromagnetic wave absorbent material.The invention still further relates to the application of this electromagnetic wave absorbent material.
Background technology
Usually, as a kind of electromagnetic wave absorbent material, in the wave frequency scope, material must have complex dielectric permittivity or complex permeability, and the imaginary part of the also imaginary part of complex dielectric permittivity or complex permeability wants enough big, if material has good complex dielectric permittivity and complex permeability simultaneously, this material just might be in very wide frequency range, absorb electromagnetic wave energy and convert it into other form of energy by dielectric loss and magnetic hystersis loss, thereby make the big high attenuation of electromagnetic wave signal by material.
At present, be widely used as the carbon black that has of electromagnetic wave dielectric loss material,,, improve the dielectric loss of material to increase the electric conductivity of material by in the nonconductive matrix material, adding carbon black.But this combined material is difficult to significantly improve the dielectric loss performance of material in actual applications, this is because the complex dielectric permittivity of material is difficult to significantly improve, and the carbon black in the composite can assemble, and causes the local display of material to go out the scrambling of conduction.1976, Japanese Atsushi Tomonaga and Tachikawa invented a kind of electromagnetic wave absorbent material (U.S Pat.No.3951904), and this material is to be composited by hollow carbon sphere and non-conducting material.In addition, (Sampe J.1991 for the retinyl Schiff's base salt that Stomier Roger A finds, 7/8:9), and conducting polymer composite such as polyacetylene, polypyrrole, polyaniline, polythiophene also can be used as the dielectric loss material, and the SiC ceramic material of Recent study has also demonstrated dielectric loss characteristics preferably.The dielectric loss material of more than enumerating has in various degree dielectric loss characteristics in the microwave high-frequency section, but most of material does not possess the magnetic hystersis loss characteristic.
The magnetic hystersis loss electromagnetic wave absorbent material, common have ferrite, metal powder, a nano-metal particle etc., these absorbents often have complex permeability preferably, but complex dielectric permittivity is unsatisfactory, and, metal material is than great, and anti-oxidant, poor corrosion resistance is restricted in actual applications.
Summary of the invention
Carbon covered metal or carbon metallization compound micro mist are a kind of novel nano-materials, but metal is when being transition metal or rare earth metal.Material has superior magnetism characteristic.Its architectural feature is that metal or metallic compound sodium rice particle are wrapped up by carbon and isolation mutually, and this new version makes it demonstrate good electricity, magnetic characteristic.The heat endurance of material and good corrosion resistance.Because the skin of micropowder material contains the C=C key, but material strong absorption infrared ray.
The purpose of this invention is to provide a kind of new electromagnetic wave absorbing material, this material is composited by carbon covered metal, carbon covered metal compound and host material, in microwave and infrared frequency range, have fine complex dielectric permittivity and complex permeability, can effectively absorb microwave and infrared energy.
Another object of the present invention provides the application of described electromagnetic wave absorbent material.
The objective of the invention is to realize by following measure:
The preparation of carbon covered metal, carbon covered metal compound micro mist can be adopted alternating current arc method (ZL 99 120144.2); Direct current arc method (Science, 1993,259,346; Jpn.J.Appl.Phys., 1994,33, L526) and other method (Chem.Phys.Letts, 1998,293,53; J.Mater.Chem., 2000,10,1971; J.Alloys and Compounds, 2002,333,308; J.Mater.Chem., 2000,10,715; J.Appl.Phys., 1998,11,6468; J.Appl.Phys., 1998,8,4409; Physics Letters A, 1999,254,65; Carbon, 2000,38,775; Materials research Bulletin, 1998,33[4], 663; ScriptaMaterialia, 2001,44,1583), wherein the alternating current arc method is one of effective method.By carbon covered metal, carbon covered metal compound micro mist that method for preparing goes out, its architectural feature is: metal or metal compound particles are wrapped up by outer carbon, and the size of micro mist is 50nm-10um, and metal or metal compound particles degree are 5nm-500nm.Micro mist has very high thermally-stabilised and chemical stability.
Carbon covered metal, carbon covered metal compound micro mist are distributed in the host material, are prepared into electromagnetic wave absorbent material.Host material can be selected organic material for use, as: paraffin, pitch, polystyrene, polyurethane, lucite, epoxy resin, polyphenyl ammonia, polypyrrole, various rubber and adhesive material also can be selected inorganic material for use, as: silicate, SiO
2
Metal in carbon covered metal, the carbon covered metal compound can be selected transition metal for use, as: Fe, Co, Ni, Mn, Ti also can select rare earth metal for use, as: Gd, Y, Nd, Sm.Metallic compound is metal carbides, nitride, oxide, sulfide.
Tenor is 5wt%-95wt% in synthetic carbon covered metal, metallic compound micro mist.
In the carbon covered metal electromagnetic wave absorbent material that is mixed with, carbon covered metal, the shared weight ratio of carbon covered metal compound micro mist are 5%-90%.
Carbon covered metal, carbon covered metal compound micro mist are distributed in the host material, make electromagnetic wave absorbent material of the present invention, its dielectric loss angle tangent tg δ
εCan reach 1.0, magnetic hystersis loss angle tangent tg δ
μCan reach 0.7, in the wave frequency scope, material surface reflection of electromagnetic wave rate reduces more than 90%.
The electromagnetic wave absorbent material that the present invention relates to has important application value; can be used as material obsorbing radar waves, infrared ray absorbing material, anti-electromagnetic radiation articles for labour protection; the electromagnetic shielding material of computer and communication equipment or device, mobile phone anti-electromagnetic radiation material.
The specific embodiment
In order to be illustrated more clearly in the present invention, enumerate the following example, but this there is not any restriction to the present invention.
Embodiment 1
Selecting iron content for use is the carbon iron clad micro mist of 70wt%, and host material is selected paraffin for use, micro mist/paraffin=1/1 (weight ratio), the complex dielectric permittivity of the microwave absorbing material that is mixed with and complex permeability are: 8.2GHz: ε '=14.44, and ε "=14.31; 10.0GHz: ε '=13.34, ε "=12.10, μ '=1.06, μ "=0.12; 12.0GHz: ε '=12.74, ε "=10.68.
Embodiment 2
Selecting iron content for use is the carbon iron clad micro mist of 80wt%, and host material is selected paraffin for use, micro mist/paraffin=4/1 (weight ratio), the complex dielectric permittivity of the microwave absorbing material that is mixed with and complex permeability are: 8.2GHz: ε '=28.5, and ε "=29.21; 10.0GHz: ε '=24.76, ε "=21.22, μ '=1.1, μ "=0.27; 12.0GHz: ε '=24.04, ε "=16.01; μ '=0.78, μ "=0.31; 15.0GHz: ε '=22.74, ε "=14.27, μ '=0.95, μ "=0.24; 18.0GHz: ε '=21.78, ε "=13.31; μ '=0.91, μ "=0.21.
Embodiment 3
Selecting iron content for use is the carbon iron clad micro mist of 70wt%, host material is selected paraffin for use, micro mist/paraffin=1/1 (weight ratio), the microwave absorbing material that is mixed with coats film forming on 300mm * 300mm aluminium sheet, the thickness of film is 1.3mm, and the flat reflective rate reduces 8-14dB in the 8Ghz-18GHz frequency range.
Need to prove that for one of ordinary skill in the art under the situation that does not change the principle of the invention, can also make some improvement or distortion to the present invention, this belongs to protection scope of the present invention equally.
Claims (5)
- A carbon containing covered with gold leafly belong to, carbon covered metal compound electromagnetic wave absorbent material, it is distributed in the host material by carbon covered metal or carbon covered metal compound micro mist and forms, it is characterized in that it is is that the carbon covered metal of 5wt%～95wt% or carbon covered metal compound are as electromagnetic consumable material with tenor, a kind of carbon containing that adds host material to and make genus covered with gold leaf, carbon covered metal compound electromagnetic wave absorbent material, the addition of described carbon covered metal or carbon covered metal compound is 5wt%～90wt%; Described metal is Fe, Co, and Ni, Mn, Ti, Gd, Y, Nd, the alloy of one or more among the Sm, metallic compound are metal carbides, nitride, oxide, sulfide; The size of described carbon covered metal or carbon covered metal compound micro mist is 50nm-10um, and metal or metal compound particles degree are 5nm-500nm.
- 2. a kind of electromagnetic wave absorbent material according to claim 1 is characterized in that described carbon covered metal or carbon covered metal compound micro mist are to be wrapped up by outer carbon by metal or metal compound particles.
- 3. a kind of electromagnetic wave absorbent material according to claim 1, it is characterized in that described host material is an organic material, described organic material is one or more in paraffin, pitch, polystyrene, polyurethane, lucite, epoxy resin, polyaniline, polypyrrole, organosilicon, the various rubber.
- 4. a kind of electromagnetic wave absorbent material according to claim 1 is characterized in that described host material is an inorganic material, and described inorganic material is silicate, SiO 2
- A carbon containing covered with gold leafly belong to, the application of carbon covered metal compound electromagnetic wave absorbent material, it is characterized in that its application in the electromagnetic shielding material of making material obsorbing radar waves, infrared ray absorbing material, anti-electromagnetic radiation articles for labour protection, computer and communication equipment or device, mobile phone anti-electromagnetic radiation material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021391173A CN1314503C (en) | 2002-09-29 | 2002-09-29 | Electromagnetic wave absorbing material containing carbon covered metal or metal compound and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021391173A CN1314503C (en) | 2002-09-29 | 2002-09-29 | Electromagnetic wave absorbing material containing carbon covered metal or metal compound and its application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1403406A CN1403406A (en) | 2003-03-19 |
| CN1314503C true CN1314503C (en) | 2007-05-09 |
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| CNB021391173A Expired - Fee Related CN1314503C (en) | 2002-09-29 | 2002-09-29 | Electromagnetic wave absorbing material containing carbon covered metal or metal compound and its application |
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Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100445342C (en) * | 2004-12-28 | 2008-12-24 | 同济大学 | Electromagnetic wave absorbing silicon-carbide material coated with barium ferrite film and its preparation process |
| CN102127391B (en) * | 2010-11-03 | 2014-12-10 | 北京航天万方科技有限公司 | Radiation-proof composite material and preparation method thereof |
| CN102108237B (en) * | 2010-12-29 | 2015-07-22 | 广东高鑫科技股份有限公司 | Preparation method and product of infrared stealth wave-absorbing composite protective paint |
| CN102604395A (en) * | 2012-01-09 | 2012-07-25 | 浙江师范大学 | Expandable graphite/polyaniline/cobalt ferrite wave-absorbing material and preparation technology thereof |
| CN104926964B (en) * | 2015-05-15 | 2018-01-12 | 西北大学 | A kind of cladding PS Gd2O3Particle preparation method and its composite |
| CN105778318A (en) * | 2016-03-22 | 2016-07-20 | 李晨露 | Plastic capable of resisting electromagnetic radiation and method for preparing plastic |
| CN108199150A (en) * | 2017-12-30 | 2018-06-22 | 吴迪 | A kind of preparation method of the carbon-based absorbing material of strong absorbent |
| CN117894542B (en) * | 2024-02-02 | 2024-09-10 | 南通华兴磁性材料有限公司 | Broadband high-conductivity manganese zinc ferrite material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62279934A (en) * | 1986-05-29 | 1987-12-04 | 旭化成株式会社 | Heat-resistant conductive film or sheet |
| CN1179875A (en) * | 1995-03-29 | 1998-04-22 | 美国3M公司 | Electromagnetic-power-absorbing composite |
-
2002
- 2002-09-29 CN CNB021391173A patent/CN1314503C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62279934A (en) * | 1986-05-29 | 1987-12-04 | 旭化成株式会社 | Heat-resistant conductive film or sheet |
| CN1179875A (en) * | 1995-03-29 | 1998-04-22 | 美国3M公司 | Electromagnetic-power-absorbing composite |
Non-Patent Citations (1)
| Title |
|---|
| 纳米材料及技术在电子领域中的应用 新材料产业，第8期 2001 * |
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| CN1403406A (en) | 2003-03-19 |
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