CN1313559C - Ternary mixed working medium for intermediate-high-temperature heat pump - Google Patents
Ternary mixed working medium for intermediate-high-temperature heat pump Download PDFInfo
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- CN1313559C CN1313559C CNB2005101222594A CN200510122259A CN1313559C CN 1313559 C CN1313559 C CN 1313559C CN B2005101222594 A CNB2005101222594 A CN B2005101222594A CN 200510122259 A CN200510122259 A CN 200510122259A CN 1313559 C CN1313559 C CN 1313559C
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Abstract
The present invention relates to ternary mixed working medium used for a middle-high temperature heat pump. The ternary mixed working medium is respectively composed of HCFC-22, HFC-125, HCFA-142b, HFC-152a, and HFC-245 fa, various components are physically mixed under normal temperature according to the designated compounding ratio, and the present invention can be used as refrigerant of a middle-high temperature heat pump system with a condensing temperature of 70 DEG C to 100 DEG C. The damage of the working medium of the present invention to the ozonosphere nears or equals zero, the greenhouse effect is lower, which accords with environmental requirements, and the thermal parameters and the cycle performance are good. An HCFC-22 air conditioning compressor is used for the optimization design of a middle-high temperature heat pump system, and the working medium of the present invention can be directly filled in the existing HCFC-22 air conditioning unit which is changed into a middle-high temperature heat pump unit of the new working medium.
Description
Technical field
The invention belongs to the refrigeration agent in heat pump or refrigeration, the air-conditioning system, especially being suitable as condensing temperature is the refrigeration working medium of 70～100 ℃ moderate and high temperature heat system.
Background technology
For produce and life in a large amount of that exist, to heat energy grade requirement relatively low (temperature is 65-100 ℃) with can link, adopt the heat pump heat supply technology that the total energy utilising efficiency higher than conventional energy-provision way not only arranged, minimizing CO
2Discharging, thereby reduction Greenhouse effect, can also effectively utilize the low-grade energy that contains in industrial exhaust heat, Geothermal energy, sun power and the environment (air, soil, surface water or the layer underground water of diving), reduce the thermal pollution that the waste heat discharging causes, current, the direction of high temperature in the heat pump techniques forward (condensing temperature is 80-100 ℃), high temperature (condensing temperature is higher than 100 ℃) develops, and as for one of key of its development, is exactly to lack the cycle fluid that is fit to.The material that in the past once was used as the working medium of high temperature heat pump system has CFC11, CFC113, CFC114 etc., their ozone layer destroying gesture (ODP) and global warming potential (GWP) are all very big, developed country forbids in 1996 that developing country also will be in forbidding in 2010.What application was more at present is the air-conditioning-heat pump of working medium with HCFC-22 or its surrogate R407C, R410A etc., the hot water top temperature that can provide is 50-55 ℃, and (high more not only cycle performance worsens, also will cause the accident because of the pressure of breaking through system and the warm upper limit of row), the heat energy of higher temperature level can't be provided.Development environment close friend, the good novel working medium of thermal performance are most important to the development of moderate and high temperature heat technology.
Summary of the invention
The purpose of this invention is to provide one group of ternary mix working medium that is suitable for the moderate and high temperature heat unit, make its environmental characteristics and cycle performance all good.Be particularly useful for condensing temperature and be 70-100 ℃ moderate and high temperature heat system, also can be used as centrifugal refrigerating, air conditioning unit working medium.
Content introduction of the present invention and embodiment: be used for the ternary mix working medium of moderate and high temperature heat, described ternary mix working medium is made up of HFC-125/HFC-152a/HFC-245fa, and mass percent is: 5-40/10-40/20-85%.Each constituent element material mass percentage ratio sum of mixing medium is 100%.The basic parameter of each constituent element material is as shown in table 1.
Preparation method of the present invention is that each constituent element material is carried out physical mixed at normal temperatures by its specified quality proportioning.
The present invention has following some beneficial effect:
(1) compliance with environmental protection requirements: ODP approaches zero, and GWP is also very low.(2) thermal parameter is suitable: under the moderate and high temperature heat design conditions, and very close under the standard air conditioning condition of stress level and HCFC-22, the warm row's temperature limit that is lower than the HCFC-22 compressor of row.Therefore, can adopt the compressor of air conditioner of HCFC-22 in the moderate and high temperature heat system, need not to be working medium of the present invention specialized designs compressor separately.(3) cycle performance is good: the heat supply COP of the present invention under the moderate and high temperature heat design conditions is greater than 5, and the unit volume heating capacity is substantially at 4200kJ/m
3More than.It is close with the HCFC-22 air-conditioning system that interchanger meets, and it is air conditioning unit working medium of the present invention directly can be poured into existing HCFC-22, is translated into the moderate and high temperature heat unit of new working medium, and efficiency and unit main hardware matching degree can guarantee to circulate.
The basic parameter of contained constituent element in the table 1 moderate and high temperature heat mixing medium
T
b: normal boiling point, T
c: critical temperature, P
c: emergent pressure
| Constituent element | Title | Molecular formula | Molecular weight | T b ℃ | T c ℃ | P c MPa | ODP | GWP |
| HFC152a | 1, the 1-C2H4F2 C2H4F2 | CHF 2CH 3 | 66.05 | -24.0 | 113.0 | 4.52 | 0 | 140 |
| HFC125 | 1,1,1,2, the 2-pentafluoride ethane | CHF 2CF 3 | 120.02 | -48.1 | 66.3 | 3.63 | 0 | 3200 |
| HFC245fa | 1,1,1,3, the 3-pentafluoropropane | CHF 2CF 2CF 3 | 134.05 | 15.3 | 157.6 | 3.64 | 0 | 950 |
Embodiment
Each constituent element component of mixing medium all refers to mass percent in following examples.
Embodiment: get 12%HFC-125,34%HFC-152a, 54%HFC-245fa, mix the back at normal temperatures as refrigeration agent.
The average operating mode of heat pump is taken as: average vaporization temperature is 45 ℃, and average condensing temperature is 85 ℃, and suction superheat is 5 ℃, condensate depression is 5 ℃, it is 0.85 that compression process is decided entropic efficiency, and according to cycle calculations, above-mentioned three embodiment have related parameter and cycle performance index as shown in table 2.
Table 2 embodiment cycle performance
| Parameter is in performance | Embodiment |
| Evaporating pressure MPa | 0.6 |
| Condensing pressure MPa | 1.9 |
| Pressure ratio | 3.17 |
| Exhaust temperature ℃ | 99.7 |
| COP | 5.63 |
| Heat supplied kJ/kg | 182.9 |
| Unit volume heating capacity kJ/m 3 | 4554 |
| ODP | 0 |
| GWP | 944.6 |
Claims (1)
1. the ternary mix working medium that is used for moderate and high temperature heat, it is characterized in that described mixing medium is made up of HFC-125, HFC-152a and HFC-245fa, mass percent is: 5-40/10-40/20-85%, each constituent element material mass percentage ratio sum of mixing medium is 100%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101222594A CN1313559C (en) | 2005-12-09 | 2005-12-09 | Ternary mixed working medium for intermediate-high-temperature heat pump |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101222594A CN1313559C (en) | 2005-12-09 | 2005-12-09 | Ternary mixed working medium for intermediate-high-temperature heat pump |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006101490662A Division CN100434492C (en) | 2005-12-09 | 2005-12-09 | Triple mixed working medium 2 for immediate-high temperature |
| CNA2006101490677A Division CN101173162A (en) | 2005-12-09 | 2005-12-09 | Ternary mix working medium for middle/high-temperature heat pump |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1775890A CN1775890A (en) | 2006-05-24 |
| CN1313559C true CN1313559C (en) | 2007-05-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005101222594A Expired - Fee Related CN1313559C (en) | 2005-12-09 | 2005-12-09 | Ternary mixed working medium for intermediate-high-temperature heat pump |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106566476A (en) * | 2016-10-28 | 2017-04-19 | 佛山市大芝热泵制冷设备有限公司 | Environment-friendly ternary non-azeotropic high-condensing-temperature refrigerant and filling method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63305185A (en) * | 1987-06-05 | 1988-12-13 | Asahi Glass Co Ltd | Working medium mixture |
| JPH01153786A (en) * | 1987-12-11 | 1989-06-15 | Asahi Glass Co Ltd | Working medium mixture |
| US4957652A (en) * | 1987-10-19 | 1990-09-18 | Daikin Industries, Ltd. | Refrigerants |
| CN1162616A (en) * | 1996-06-19 | 1997-10-22 | 清华大学 | Pollutionless refrigerant |
| CN1236801A (en) * | 1998-05-22 | 1999-12-01 | 中山威力集团公司 | Safety-type refrigerant of ozone |
| CN1364846A (en) * | 2001-01-19 | 2002-08-21 | 范志平 | Green refrigerant |
-
2005
- 2005-12-09 CN CNB2005101222594A patent/CN1313559C/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63305185A (en) * | 1987-06-05 | 1988-12-13 | Asahi Glass Co Ltd | Working medium mixture |
| US4957652A (en) * | 1987-10-19 | 1990-09-18 | Daikin Industries, Ltd. | Refrigerants |
| JPH01153786A (en) * | 1987-12-11 | 1989-06-15 | Asahi Glass Co Ltd | Working medium mixture |
| CN1162616A (en) * | 1996-06-19 | 1997-10-22 | 清华大学 | Pollutionless refrigerant |
| CN1236801A (en) * | 1998-05-22 | 1999-12-01 | 中山威力集团公司 | Safety-type refrigerant of ozone |
| CN1364846A (en) * | 2001-01-19 | 2002-08-21 | 范志平 | Green refrigerant |
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|---|---|
| CN1775890A (en) | 2006-05-24 |
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| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Tianjin Century Tianyuan Geothermal Environmental Protection Engineering Co.,Ltd. Assignor: Tianjin University Contract record no.: 2011120000173 Denomination of invention: Triple mixed working medium 2 for immediate-high temperature Granted publication date: 20070502 License type: Exclusive License Open date: 20060524 Record date: 20110901 |
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Addressee: Zhu Zeming Document name: Notification of Passing Examination on Formalities |
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