CN1312259C - High-effective energy-saving fuel oil cleaning agent and its production method - Google Patents

High-effective energy-saving fuel oil cleaning agent and its production method Download PDF

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Publication number
CN1312259C
CN1312259C CNB031139191A CN03113919A CN1312259C CN 1312259 C CN1312259 C CN 1312259C CN B031139191 A CNB031139191 A CN B031139191A CN 03113919 A CN03113919 A CN 03113919A CN 1312259 C CN1312259 C CN 1312259C
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oil
lubricant
effective energy
wind
saving fuel
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CN1515656A (en
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李瑞波
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Shenzhen Jimmy Chemical Technology Co ltd
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JINHAITIAN TRADE CO Ltd SHENZHEN CITY
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Abstract

The present invention relates to a fuel oil cleaning agent and a production method thereof. The cleaning agent is compounded from 5 to 70 wt% of oil soluble surfactant: Span 80, Span 60, T151 or T152, 10 to 70 wt% of lubricant salad oil, vegetable oil acid ester, castor oil, epoxy grease or fanning colza oil, and cosolvent kerosene or gasoline as the rest. The production method of the cleaning agent comprises the following steps: (a) uniformly mixing solvent oil and a combustion supporting agent, (b) orderly adding and uniformly stirring required lubricant, oil soluble surfactant and plasticizers, (c) adding required polar materials to regulate the transparence of the mixed liquid, and (d) filtering and filling the liquid after sedimentation. The cleaning agent of the present invention has the advantages of high degree of atomization for fuel oil, oil consumption reduction, abrasion reduction for parts of machines and sealing performance enhancement for parts, and the cleaning agent can be widely used for fuel oil additives.

Description

Energy-efficient Burning Oil Clarifying Agent And Production Mode
Technical field
The present invention relates to a kind of purification agent and production method, more particularly, relate to a kind of Energy-efficient Burning Oil Clarifying Agent And Production Mode.
Background technology
Fuel oil cleaning agent generally adopts solvent oil to add the amine dispersion agent and generates, the peace and quiet effect of this prescription is low, and for the effect that white gasoline and low-sulfur diesel-oil are not reduced friction, cause easily parts such as nozzle, ram pump wearing and tearing, make it poorly sealed, and the fuel spray effect is relatively poor.
Summary of the invention
Technical problem to be solved by this invention is the defective that overcomes above-mentioned prior art purification agent, a kind of new high-effective energy-saving fuel oil purification agent is provided, thereby effectively improves the fuel spray degree, reduces oil consumption, reduces the machine part wearing and tearing, the reinforcing member sealing property.
Another technical problem to be solved by this invention provides the production method of above-mentioned high-effective energy-saving fuel oil purification agent.
Technical scheme of the present invention is, a kind of high-effective energy-saving fuel oil purification agent, and component that it comprises and content are:
Oil soluble surfactant Span80, Span60, T151 or T152 5%~70%
Lubricant salad oil, vegetables oil acid esters, Viscotrol C, epoxy grease or wind rape oil 10%~70%
Solubility promoter kerosene or gasoline surplus
All percentage ratios are weight percentage.
Oil soluble surfactant Span80, Span60, T151 or T152 have peace and quiet effect, and preferred amounts is 10%~25%, and the best is 22%; Lubricant salad oil, vegetables oil acid esters, Viscotrol C, epoxy grease and wind rape oil have lubrication, and preferred amounts is 40%~50%, and the best is 45%; In order to obtain better effect, the component of described lubricant and content are: Viscotrol C is 3%~25%, and the best is 20%, and wind rape oil is 5%~30%, and the best is 20%, salad oil or vegetables oil acid esters 2%~15%, and the best is 10%; Solubility promoter kerosene and gasoline have the hydrotropy effect.
In order to obtain better effect, can in above-mentioned purification agent, add to have to soak and dissolve and auxiliary cleanup action softening agent Octyl adipate, dioctyl sebacate or dioctyl phthalate (DOP) 5%~20%, preferred amounts is 11%; Have the outward appearance of improvement and auxiliary cleaning function polar material gylcol ether, methyl alcohol, ethanol, Tween80 or water 0.5%~10%, preferred amounts is 1.8%; Have ignition dope dicumyl peroxide, tert-butyl peroxide ether or the n-octyl nitrate 1%~10% of combustion-supporting effect, preferred amounts is 5%.
The above each component all is the product that can buy from market.
The present invention also provides the production method of above-mentioned high-effective energy-saving fuel oil purification agent, may further comprise the steps:
A, required solvent oil is dropped in the reactor, add ignition dope as required and be stirred to fully and mix;
B, in step a gained mixed solution, add required lubricant, oil soluble surfactant and softening agent successively, be stirred to evenly;
C, in step b gained mixed solution, add required polar material and regulate the mixed solution transparency;
D, with the sedimentation of step c gained mixed solution, refilter can.
In order to obtain better effect, the mixing among above-mentioned steps a, b, c and the d is placed in the static mixer to be carried out, and is volatilization and the decomposition that prevents ignition dope and solubility promoter, and the temperature condition of described each step is for being no more than 35 ℃, and the open exposure time is 12 to surpass hour.
Embodiment
Embodiment one
A kind of high-effective energy-saving fuel oil is peace and quiet, and its component and content are:
Oil soluble surfactant Span80 18%
Lubricant wind rape oil 45%
Solubility promoter kerosene 37%
All percentage ratios are weight percentage.
Embodiment two
A kind of high-effective energy-saving fuel oil is peace and quiet, and its component and content are:
Oil soluble surfactant Span60 18%
Lubricant vegetables oil acid esters 45%
Solubility promoter gasoline 37%
All percentage ratios are weight percentage.
Embodiment three
A kind of high-effective energy-saving fuel oil is peace and quiet, and its component and content are:
Oil soluble surfactant SpanT151 25%
Oil soluble surfactant T152 23%
Lubricant vegetables oil acid esters 12%
Lubricant Viscotrol C 27%
Solubility promoter kerosene 13%
All percentage ratios are weight percentage.
Embodiment four
A kind of high-effective energy-saving fuel oil purification agent, its component and content are:
Oil soluble surfactant T152 22%
Lubricant salad oil 10%
Lubricant Viscotrol C 11%
Lubricant wind rape oil 29%
Softening agent Octyl adipate 11%
Polar material Tween80 1.8%
Ignition dope dicumyl peroxide 5%
Solubility promoter kerosene 10.2%
All percentage ratios are weight percentage.
Embodiment five
A kind of high-effective energy-saving fuel oil purification agent, its component and content are:
Oil soluble surfactant T151 11%
Lubricant salad oil 10%
Lubricant Viscotrol C 20%
Lubricant wind rape oil 20%
Softening agent dioctyl sebacate 15%
Polar material ethanol 1.8%
Ignition dope tert-butyl peroxide ether 2%
Solubility promoter kerosene or gasoline 20.2%
All percentage ratios are weight percentage.
Embodiment six
A kind of high-effective energy-saving fuel oil purification agent, its component and content are:
Oil soluble surfactant Span60 11%
Lubricant vegetables oil acid esters 11%
Lubricant Viscotrol C 24%
Lubricant wind rape oil 13%
Plasticizer phthalic acid dioctyl ester 18%
Polar material water 1.5%
Ignition dope n-octyl nitrate 1.5%
Solubility promoter gasoline 20%
All percentage ratios are weight percentage.
Embodiment seven
A kind of high-effective energy-saving fuel oil purification agent, its component and content are:
Oil soluble surfactant T152 22%
Lubricant wind rape oil 50%
Plasticizer phthalic acid dioctyl ester 11%
Polar material methyl alcohol 1.8%
Solubility promoter gasoline 15.2%
All percentage ratios are weight percentage
Embodiment eight
A kind of high-effective energy-saving fuel oil purification agent, its component and content are:
Oil soluble surfactant Span80 42%
Lubricant wind rape oil 35%
Softening agent Octyl adipate 11%
Polar material Tween80 1.8%
Ignition dope dicumyl peroxide 5%
Solubility promoter kerosene 5.2%
All percentage ratios are weight percentage.
Embodiment nine
A kind of high-effective energy-saving fuel oil purification agent, its component and content are:
Oil soluble surfactant T152 22%
Lubricant epoxy soybean oil 10%
Lubricant peanut oil 11%
Lubricant Viscotrol C 29%
Softening agent Octyl adipate 11%
Polar material Tween80 1.8%
Ignition dope dicumyl peroxide 5%
Solubility promoter kerosene 10.2%
Embodiment ten
A kind of production method of high-effective energy-saving fuel oil purification agent may further comprise the steps:
A, 102 kilograms of solvent kerosene are dropped in the reactors, add 50 kilograms of ignition dope dicumyl peroxides, be stirred to fully and mix;
B, in step a gained mixed solution, add lubricant salad oil double centner successively, 110 kilograms of Viscotrol C, 290 kilograms of wind rape oils, 220 kilograms of oil soluble surfactant T152 add 110 kilograms of softening agent Octyl adipates again, are stirred to evenly;
C, in step b gained mixed solution, add 18 kilograms of polar material Tween80 and regulate the mixed solution transparencies;
D, with step c gained mixed solution sedimentation 4 hours, filter can.
High efficiency fuel purification agent of the present invention strengthens its sealing property in the wearing and tearing that reduce machine part, improves aspects such as fuel spray and minimizing oil consumption and has unusual effect, describes in detail below in conjunction with comparative example.
Comparative example one
The carbon deposit simulation test, measure by Institute of Analysis of Lanzhou Branch of the Chinese Academy of Sciences, use nozzle burner and carbonizing of engine simulation test instrument, carbon trumpet simulation test condition is that 60 hours 200 gram fuel oils carry out under the blowing air condition, and certain commercially available purification agent and purification agent of the present invention add in the fuel oil with 1/1000 amount; Carbonizing of engine simulation test condition is that 100 milliliters of fuel oils carry out under 190 ℃, and purification agent of the present invention adds in the fuel oil with 1/1000 amount, and testing used fuel oil is commercially available blue refining 90# white gasoline.Test-results is shown in table 2, and high efficiency fuel purification agent of the present invention can make carbon trumpet reduce 73.0%, and carbonizing of engine reduces 58.6%, compares with commercially available certain purification agent, has better peace and quiet effect.
Comparative example two
Train oil consumption and injector wearing test, test section (comes and goes) to Zhangye at the Jiayu Pass, and the adding proportion of purification agent of the present invention is 1/1000, the oil consumption situation is shown in table 1, use the up rate of economizing gasoline 3.1% of purification agent train of the present invention, descending rate of economizing gasoline 3.6%, it is remarkable to reduce the oil consumption effect; When train is supplementally taken, use the locomotive of purification agent of the present invention, the fraction defective of fuel injector nozzle reduces.
Table 1
The sample title The carbon trumpet simulation test The carbonizing of engine simulation test
Deposition on the 45# steel disc (mg) Deposition decrement (%) Deposition on the aluminium flake (mg) Deposition decrement (%)
No purification agent fuel oil 21.0 26.8
Add certain commercially available purification agent fuel oil 6.0 71.4 18.0 32.8
Add embodiment five purification agent fuel oils 5.6 73.0 11.1 58.6
Table 2
Train The sample title Section Gross ton kilometers (ten thousand freight tonne kilometres) With oil mass (kg) Unit consumption (kg/ ten thousand freight tonne kilometres) Unit consumption relatively Rate of economizing gasoline %
3556 No purification agent Good-as to open 806.02 9448 11.72
Purification agent is arranged 408.93 4674 11.43 -0.29 2.5
No purification agent Open-Jia 356.70 8509 23.85
Purification agent is arranged 295.66 6853 23.18 -0.67 2.8
3667 No purification agent Good-as to open 611.07 7298 11.94
Purification agent is arranged 745.65 8610 11.55 -0.39 3.3
No purification agent Open-Jia 353.74 8450 23.89
Purification agent is arranged 352.02 8115 23.05 -0.84 3.5
3939 No purification agent Good-as to open 610.76 7298 11.95
Purification agent is arranged 746.30 8525 11.43 -0.52 4.4
No purification agent Open-Jia 527.36 12670 24.03
Purification agent is arranged 290.60 6757 23.25 -0.78 3.2
6206 No purification agent Good-as to open 606.93 7455 12.28
Purification agent is arranged 812.20 9632 11.86 -0.42 3.4
No purification agent Open-Jia 236.66 5683 24.01
Purification agent is arranged 413.55 9660 23.12 -0.89 3.7
6207 No purification agent Good-as to open 671.04 8159 12.16
Purification agent is arranged 610.74 7216 11.82 -0.34 2.8
No purification agent Open-Jia 349.84 8429 24.09
Purification agent is arranged 413.55 9509 22.99 -1.10 4.6
On average No purification agent Good-as to open 12.00
Purification agent is arranged 11.63 -0.37 3.1
No purification agent Open-Jia 23.98
Purification agent is arranged 23.11 -0.87 3.6

Claims (9)

1, a kind of high-effective energy-saving fuel oil purification agent is characterized in that, comprising: oil soluble surfactant Span80, the Span60, T151 or the T152 that account for weight percent 5%~70%; Account for lubricant salad oil, vegetables oil acid esters, Viscotrol C, epoxy grease or the wind rape oil of weight percent 10%~70%, and solubility promoter kerosene or gasoline are as surplus.
2, peace and quiet according to the described high-effective energy-saving fuel oil of claim 1, it is characterized in that its component concentration is:
Oil soluble surfactant Span80, Span60, T151 or T152 10%~25%
Lubricant salad oil, vegetables oil acid esters, Viscotrol C, epoxy grease or wind rape oil 40%~50%
Solubility promoter kerosene or gasoline surplus
All percentage ratios are weight percentage.
3, peace and quiet according to the described high-effective energy-saving fuel oil of claim 1, it is characterized in that described component that comprises and content are:
Oil soluble surfactant Span80, Span60, T151 or T152 18%
Lubricant salad oil, vegetables oil acid esters, Viscotrol C, epoxy grease or wind rape oil 45%
Solubility promoter kerosene or gasoline surplus
All percentage ratios are weight percentage.
4, peace and quiet according to the described high-effective energy-saving fuel oil of claim 1, it is characterized in that described component that comprises and content are:
Oil soluble surfactant Span80, Span60, T151 or T152 5%~25%
Lubricant salad oil, vegetables oil acid esters, Viscotrol C, epoxy grease or wind rape oil 10%~70%
Softening agent Octyl adipate, dioctyl sebacate or dioctyl phthalate (DOP) 5%~20%
Polar material gylcol ether, methyl alcohol, ethanol, water or Tween80 0.5%~10%
Ignition dope dicumyl peroxide, tert-butyl peroxide ether or n-octyl nitrate 1%~10%
Solubility promoter kerosene or gasoline surplus
All percentage ratios are weight percentage.
5, peace and quiet according to the described high-effective energy-saving fuel oil of claim 1, it is characterized in that the component of described lubricant and weight percent content are:
Salad oil, vegetables oil acid esters or epoxy grease 20%~22.9%
Viscotrol C 22%~50%
Wind rape oil 27.1%~58%.
According to the described high-effective energy-saving fuel oil purification agent of claim 1, it is characterized in that 6, described component that comprises and content are:
Oil soluble surfactant Span80, Span60, T151 or T152 22%
Lubricant salad oil, vegetables oil acid esters or epoxy grease 10%
Lubricant Viscotrol C 11%
Lubricant wind rape oil 29%
Softening agent Octyl adipate, dioctyl sebacate or dioctyl phthalate (DOP) 11%
Polar material gylcol ether, methyl alcohol, ethanol, water or Tween80 1.8%
Ignition dope dicumyl peroxide, tert-butyl peroxide ether or n-octyl nitrate 5%
Solubility promoter kerosene or gasoline surplus
All percentage ratios are weight percentage.
According to the described high-effective energy-saving fuel oil purification agent of claim 1, it is characterized in that 7, described component that comprises and content are:
Oil soluble surfactant Span80, Span60, T151 or T152 11%
Lubricant salad oil, vegetables oil acid esters or epoxy grease 10%
Lubricant Viscotrol C 20%
Lubricant wind rape oil 20%
Softening agent Octyl adipate, dioctyl sebacate or dioctyl phthalate (DOP) 15%
Polar material gylcol ether, methyl alcohol, ethanol, water or Tween80 1.8%
Ignition dope dicumyl peroxide, tert-butyl peroxide ether or n-octyl nitrate 2%
Solubility promoter kerosene or gasoline surplus
All percentage ratios are weight percentage.
According to the described high-effective energy-saving fuel oil purification agent of claim 1, it is characterized in that 8, described component that comprises and content are:
Oil soluble surfactant Span80, Span60, T151 or T152 11%
Lubricant salad oil, vegetables oil acid esters or epoxy grease 11%
Lubricant Viscotrol C 24%
Lubricant wind rape oil 13%
Softening agent Octyl adipate, dioctyl sebacate or dioctyl phthalate (DOP) 18%
Polar material gylcol ether, methyl alcohol, ethanol, water or Tween80 1.5%
Ignition dope dicumyl peroxide, tert-butyl peroxide ether or n-octyl nitrate 1.5%
Solubility promoter kerosene or gasoline surplus
All percentage ratios are weight percentage.
9, peace and quiet according to the described high-effective energy-saving fuel oil of claim 1, it is characterized in that described lubricant is vegetables oil acid esters or wind rape oil.
CNB031139191A 2003-03-11 2003-03-11 High-effective energy-saving fuel oil cleaning agent and its production method Expired - Lifetime CN1312259C (en)

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CN1312259C true CN1312259C (en) 2007-04-25

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1329490C (en) * 2004-09-08 2007-08-01 阎威凭 Tail gas dust-laying agent of vehicle
CN103351892B (en) * 2013-08-06 2015-09-30 杨宝伟 A kind of Environmentally-friebiofuel biofuel for boiler and preparation method thereof
CN110129103A (en) * 2019-01-31 2019-08-16 中实投石化科技有限公司 A kind of low-sulfur ordinary diesel oil
CN109749796B (en) * 2019-03-18 2021-05-11 德泰易驰(天津)环保科技有限公司 Detergent suitable for liquid fuel

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1104245A (en) * 1994-04-30 1995-06-28 虞展州 Cleaning additive for running of engine

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1104245A (en) * 1994-04-30 1995-06-28 虞展州 Cleaning additive for running of engine

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