CN1311655A

CN1311655A - Hair care product providing shine

Info

Publication number: CN1311655A
Application number: CN 99809094
Authority: CN
Inventors: 温迪·V·J·扬; 格雷厄姆·N·麦凯尔维; 钱特利·M·麦卡恩
Original assignee: Procter and Gamble Ltd
Current assignee: Procter and Gamble Ltd; Procter and Gamble Co
Priority date: 1998-07-30
Filing date: 1999-03-26
Publication date: 2001-09-05
Also published as: WO2000006107A1; AU8674598A; BR9912614A; EP1100442A1; WO2000006100A1; JP2003523924A; AU3359599A; CA2337163A1; CA2337163C

Abstract

Provided are hair care products, especially leave-on products, comprising a hair care compositions providing enhanced shine to the hair in combination with clean hair feel and refreshment to the hair and scalp without inducing excess drying-out of the scalp. The compositions comprise a combination of: (a) a hair shine agent consisting essentially of: (i) a high refractive index non-volatile polysiloxane fluid and (ii) a non-volatile spreading agent for the high refractive index polysiloxane fluid which is intermixed with the high refractive index polysiloxane fluid; (b) ethanol; and (c) water; wherein the ethanol level is from about 10% to about 50%, by weight, of the composition. In another aspect of the present invention, the composition hereof further comprises a scalp conditioning agent. The present invention also provides for methods of use of the hair care products.

Description

Glossy hair care product is provided

Technical field

The present invention relates to comprise a kind of hair care product of compositions, wherein, brought gloss to hair by using some polysiloxanes and ethanol, but also brought the hair sense of cleaning and make hair and the scalp sensation salubrious.The invention still further relates to above-mentioned such hair care product, they have described benefit, comprise ethanol and do not make scalp sensation dry.

Background of invention

Usually use in the numerous compositionss that contain detersive surfactant known in the art any one to have one's hair wash.But the result who cleans the comprehensive function of hair, environmental factors and a natural situation of human hair continually makes that hair is unhealthy, outward appearance lacks gloss.Address this problem one effective method is by using the Wo 2008069000 that can improve hair gloss to solve.Be to use the combination of high refractive index polysiloxane fluid and spreading agent at the more effective technology of this purpose, the polysiloxanes of described high refractive index polysiloxane fluid such as phenylating, spreading agent such as polyorganosiloxane resin, as (on April 28th, 1994 is open to be disclosed in WO 94/08557, people such as Brock, Procter ﹠amp; Gamble) those in.

And being desirable to provide hair-treatment composition, particularly non-washing type compositions, they give scalp clean feel or salubrious sense.This is a particular importance for the non-washing type hair care composition of polysiloxanes that comprises above-mentioned phenylating and spreading agent, apply sense because they can bring to hair, and this does not wish to exist for consumers especially.This problem is aggravated because of the non-washing type product.Although with respect to rinsing formula product, consider from bring excellent satin angle to hair, the non-washing type product is special needs, but they can stay the polysiloxanes/spreading agent of excessive phenylating on hair, and this brings deleterious effects can for the hair sense of cleaning.But sense object (sensates) can be used in the non-washing type product as menthol and Camphora, be used for increasing salubrious sense, but these can not overcome all salubrious problems fully, and it must comprise a kind of solution, solve the hair that the combination by the polysiloxanes/spreading agent of phenylating brings and apply sense.Having now found that in some cases, is ethanol for a kind of the most effective of this purpose and the composition of wishing most.But ethanol must use with high relatively amount, to reach salubrious to greatest extent and hair clean feel.Unfortunately, when using with this tittle, ethanol can make scalp become dry, causes skin to be itched or turns around skin.

The purpose of this invention is to provide hair care composition, non-washing type compositions particularly, it can bring excellent gloss, brings the salubrious sense of cleaning for simultaneously hair and scalp, but also minimizes or eliminated dry scalp.

Above-mentioned purpose can by use comprise the polysiloxane fluid of high refractive index and spreading agent combination polishing material and realize in conjunction with the ethanol of specified quantitative, and when it is used on the hair with certain product form, can realize above-mentioned purpose.Hereinafter will describe the present invention in detail.

Except as otherwise noted, all percent of the present invention all is based on the weight of the present composition.Except as otherwise noted, all ratio of the present invention all is weight ratio.Except as otherwise noted, all percent, ratio and the content of composition of the present invention all is based on the actual content of these compositions, therefore be not included in the commercially available prod may with the bonded solvent of these compositions, filler or other material.

The present invention comprises, by or any preferred or optional member described of the necessary component described by the present invention basically and the present invention form.

Summary of the invention

Having now found that to provide the hair care product that comprises compositions by the combination of following substances, it can make the gloss of hair strengthen, but also hair clean feel and salubrious sense have been brought, and do not make scalp too dry: (a) a kind of hair gloss agent, basic composition is: (ⅰ) the non-volatile polysiloxane fluid of high refractive index and (ⅱ) be used for the non-volatile spreading agent of high refractive index polysiloxane fluid, itself and the blending of high refractive index polysiloxane fluid; (b) ethanol; (c) water; Wherein alcoholic acid content is about 10% to about 50% of composition weight.

In another aspect of this invention, compositions of the present invention also comprises the scalp conditioner.

Suitable spreading agent includes, but not limited to silicone resin (particularly MQ silicone resin), surfactant such as polyether siloxane copolymer and do not contain the organic surface active agent of siloxanes.

The invention still further relates to by use makes hair have glossy method.Compositions of the present invention is the non-washing type compositions preferably, and therefore preferred using method allows compositions dry on hair, rather than is rinsed earlier.

The compositions and methods of the invention advantageously can with various hair care product couplings, particularly non-washing type compositions, as hair emulsion, flood (tonics), gel, cream and some hair spray.Can comprise aerosol and non-aerosol, for example the particle diameter of the spray droplets that is characterized as at least 40% volume of the spray products of hair spray, mousse etc. is at least 100 microns.The percent by volume of herein using is meant based on the fluidic percentage ratio of the particle diameter that whole fluid volume sprayed that is sprayed in above-mentioned reference quantity scope.

Another benefit of the present invention is the salubrious sense that compositions of the present invention can make cleaning, hair and the scalp of scalp sensation cleaning, salubrious and hair, and hair gloss.The feature of compositions of the present invention makes adhesion, oily degree low when also being to provide excellent gloss and low scalp dry sensation.Compositions of the present invention also provides opsonic action by using polishing material and supplementary element described below to hair.

Hereinafter with more detailed description the present invention, wherein comprise the various nonrestrictive optional and embodiment preferred of the present invention.

Detailed Description Of The Invention

Solvent of the present invention and feature and various optional and preferred composition of the present invention and embodiment are described below.

Hair care product

The present invention relates to comprise the hair care product that is suitable for using the hair care composition on the hair.Hair care product of the present invention can also comprise the packing that is used to comprise described compositions.

Various suitable being packaged in are known in the art.Their feature has been generally dispensing orifice, and by these holes, the said goods can be toppled over, rocked, the pump spray, push or spray.

Product of the present invention is preferably the non-washing type product.The non-washing type product is meant to be applied to compositions on the hair and to allow it to stay on the hair and becomes dry, rather than beginning is just by flush away.The non-washing type product can be any kind that is suitable for and plans to be applied on the hair and use in disposable mode.Without limits, these comprise conditioning and/or make the flooding of hair fixing, gel, cream, pastel and spray agent (aerosol, non-aerosol), comprise hair spray.

Non-washing type product of the present invention does not clean the clean surface activating agent of effective dose, and as anion surfactant and amphoteric surfactant, and they are present in the compositions as shampoo usually.In general non-washing type compositions, it is about 5% that the content of this class surfactant is no more than, and preferably is no more than approximately 3%, more preferably no more than about 1%, is most preferably not exceeding approximately 0.5%, and can be low to moderate 0%.

Non-washing type product of the present invention can also comprise and the consistent packing instruction of non-washing type product occupation mode, the content of partly describing in detail as using method hereinafter.

" spray agent " is meant a kind of product herein, and it distributes the compositions (the aerial dispersion of liquid) in the surrounding air of being dispersed in that is the drop form in use.Spray agent product of the present invention will comprise and be characterized as the compositions that is at least 100 microns at least about the particle diameter of the drop that sprays of 40% volume.The particle diameter of the drop of preferred at least 50%, more preferably at least 70%, most preferably at least 80% sprinkling is at least 100 microns.The particle diameter that sprays drop uses International Organization for Standardization standard method ISO/WD13320 to measure by laser diffraction (as Malvern Instruments2600C particle size analyzer or equivalent).Particle diameter is meant diameter.Do not plan to be bound by theory, believe that littler sprinkling microgranule is not enough to penetrate the whole thickness of hair, the result causes inadequate distribution, can not make compositions that the performance of required degree is provided.Be appreciated that spray products does not comprise mousse, although mousse can distribute by aerosol or non-aerosol packing, in fact they are not to be provided at dispersion of droplets in the surrounding air in the mode identical with the spray agent of routine.

Compositions can be to be suitable for being applied to solution, liquid/liquid dispersion, emulsion (emulsion), microemulsion, liquid crystal or any other form on hair and the scalp to remove hereinafter described those.

Be not limited to theory, believe mousse different be to be the form allocated product that is dispersed in the whole compositions with gas (for example propellant and/or air) wherein, that is, mousse is that the form with the dispersion of gas in liquid distributes.And, dispersion such as the mousse of gas in liquid can not provide above-mentioned benefit usually or realize purpose of the present invention, this is to be that they provide the effect of hair sense of cleaning poor, so mousse and other provide the hair care product of the dispersion of gas in liquid to be not included in the scope of the present invention in use.

The hair gloss agent

Compositions of the present invention comprises a kind of hair gloss agent, basic composition is high refractive index, non-volatile polysiloxane fluid and be used for the spreading agent of high refractive index polysiloxane fluid of this hair gloss agent.These two kinds of compositions with blending compositions identical mutually in.The amount of hair gloss agent be generally composition weight about 0.05% to about 10%, preferred about 0.1% to about 5%, more preferably from about 0.2% to about 2%." consist of basically " and be meant that the hair gloss agent must contain the neccessary composition of pointing out, but it also can comprise other and does not hinder the composition that compositions of the present invention works with its predetermined way.The total content of these two kinds of neccessary compositions is preferably in the above-mentioned same range as that agent provides to hair gloss.

The non-volatile polysiloxane fluid of high refractive index

Compositions of the present invention comprises the non-volatile polysiloxane fluid (polysiloxane fluid) as neccessary composition, and it is about 1.46 that its refraction index is at least, preferably at least about 1.48, more preferably at least about 1.52, most preferably at least about 1.55.Although not necessarily limit the present invention, the refraction index of polysiloxane fluid usually will be less than about 1.70, typically less than about 1.60.

Known in this field, refraction index refers to the direction of light when passing a kind of medium to another kind of medium and changes (, obviously deviation).Refraction index will refer to that light passes through in polysiloxane fluid or the polysiloxane fluid/spreading agent mixture from air in the present invention.The refraction index of polysiloxane fluid can use this area can obtain usually and known standard device is measured, as the Abbe refractometer.The technical description of measuring refraction index is at " chemical microscope handbook, the 1st volume-chemical method and inorganic quantitative analysis, Chemot and Mason etc., John Wiley ﹠amp; Sons, Inc., New York,, 311-334 page or leaf in 1958 ".

It is very low or do not have tangible vapour pressure that used herein term " non-volatile " refers to the vapour pressure of described material under environmental condition, and this is known in this field, understandable.Nonvolatile matter will have the vapour pressure that is no more than 0.2 millimetres of mercury usually under 25 ℃, one atmospheric pressure.Nonvolatile matter also has at least 275 ℃ usually under an atmospheric pressure, preferred at least 300 ℃ boiling point.

Be used for the viscosity of polysiloxane fluid of the present invention in the time of 25 ℃ and be generally at least about 10 centistokes, preferred about 20 to about 2000000 centistokes, and more preferably from about 30 to about 500000 centistokes.The non-volatile polysiloxane fluid of other viscosity also can require as long as they can satisfy as herein described other with in the present invention.Usually, wish that polysiloxane fluid can provide conditioning and hair gloss, the therefore preferred material that uses viscosity higher is about 50000 as being higher than, and preferably is higher than about 100000.Can be by means of measuring viscosity at the glass capillary tube viscometer described in the Dow Coming Corporate Test Method CTM0004 on July 20th, 1970.The polysiloxanes " fluid " that is used for the present invention comprises fluid and sizing material.It is about 1000000 centistokes or higher polysiloxanes that polysiloxanes " sizing material " refers to viscosity.

The polysiloxane fluid that is applicable to the object of the invention comprises those that represented by following logical formula I:

Wherein each R replaces or unsubstituted aliphatic series (for example alkyl or alkenyl), aryl, aryloxy group, alkaryl, alkoxyl, alkylamino (for example alkyl or alkenyl amino group), hydroxyl or hydrogen or their combination; X is the integer at least about 1, is typically about 1 to about 1000.The R substituent group also can comprise the combination of ether group, hydroxyl and amido and other functional group, the functional group that described other functional group such as halogen and halogen replace, for example aliphatic group and the aryl of halogen replacement.

Polysiloxane fluid can be ring-type or linearity.The example of linear polysiloxane such as above-mentioned formula I.Also can use side chain.Cyclic polysiloxanes comprises those of formula II representative down:

Wherein the definition of R as above, n is about 3 to about 7, preferred about 3 to about 5.

Substituent group on siloxane chain (R) can be an any structure, as long as the polysiloxanes of gained at room temperature remains fluid, is hydrophobic, non-stimulated in the time of on being applied to hair, avirulence or harmless, can be compatible with other composition in the compositions, chemical property is stable under the use of routine and condition of storage, can be deposited on the hair, and the polysiloxane fluid of gained has aforesaid refraction index.

Preferred alkyl and alkenyl substitutents are C ₁-C ₅Alkyl and alkenyl are more preferably C ₁-C ₄Alkyl and alkenyl most preferably are C ₁-C ₂Alkyl and alkenyl.Other aliphatic series part that contains the group (as alkoxyl, alkaryl and alkylamino) of alkyl, alkenyl or alkynyl can be a straight or branched, and preferably have 1 to 5 carbon atom, more preferably have 1 to 4 carbon atom, also more preferably have 1 to 3 carbon atom, most preferably have 1 to 2 carbon atom.As previously discussed, the R substituent group of this paper also can contain amido functional group, alkylamino for example, and it can be primary, secondary, tertiary amine or quaternary ammonium salt.That these substituent groups comprise is single-, two-and three-alkyl amino and alkoxy amino, wherein the chain length of aliphatic series part is preferably as indicated above.The R substituent group also can with other group such as halogen (as, chlorine, fluorine and bromine), halogenated aliphatic group or aryl and hydroxyl (aliphatic group that replaces as hydroxyl) replace.Suitable halogenated R base can comprise for example alkyl of three halos (preferred fluoro), as-R ¹-C (F) ₃, R wherein ¹Be C ₁-C ₃Alkyl.The example of this class polysiloxanes comprises poly-methyl-3,3, the 3-trifluoropropyl siloxane.

High refractive index polysiloxane fluid of the present invention comprises the R substituent group that contains aryl of q.s refraction index is increased to required level, and is as indicated above.

The substituent group that contains aryl comprises alicyclic and five Yuans or six Yuans aromatic rings of heterocycle family, and comprises and condense five or the substituent group of six membered ring.Aromatic ring itself can be replacement or unsubstituted.Substituent group comprises aliphatic substituent group, and can comprise alkoxy substituent, acyl substituent, ketone, halogen (for example chlorine and bromine), amine etc.The group that contains aryl that exemplifies comprises and replacing and unsubstituted aromatics, as phenyl and phenyl derivatives as having C ₁-C ₅The phenyl of alkyl or alkenyl substitutents, for example allyl phenyl, aminomethyl phenyl and ethylphenyl, ethenylphenyl such as styryl, and phenyl alkynyl (phenyl C for example ₂-C ₄Alkynyl).Heterocyclic aryl comprises the substituent group derived from furan, the azoles of rattling away, pyrroles, pyridine etc.Condensed aryl rings substituent group comprises for example naphthalene, coumarin and purine.

Usually, the amount that contains aryl substituent that polysiloxanes of the present invention has is at least about 15%, preferably at least about 20%, more preferably at least about 25%, also more preferably at least about 35%, most preferably at least about 50%.Be typically, although be not intended to necessarily limit the present invention, it is about 90% that the aryl substitution value will be less than, and more preferably less than about 85%, is preferably about 55% to about 80%.

The feature of polysiloxane fluid of the present invention also is to replace owing to their aryl usually, and has high relatively surface tension.Usually, polysiloxane fluid of the present invention will have at least about 24 dynes per centimeter ², be typically at least about 27 dynes per centimeter ²Surface tension.For the present invention, surface tension is according to the de Nouy ring strain instrumentation amount of on November 23rd, 1971 at Dow Corning Corporate Test Method CTM0461.Capillary variation can be measured according to above-mentioned method of testing or according to ASTM Method D1331.The preferred polysiloxane fluid of the present invention will have phenyl or have the phenyl derivatives substituent group of alkyl substituent (preferred phenyl), described alkyl substituent be preferably C1-C4 alkyl (most preferable) hydroxyl, alkylamino (particularly-R ¹NHR ²NH ₂, each R wherein ¹Be C independently ₁-C ₃Alkyl, alkenyl and/or alkoxyl).

The high refractive index polysiloxanes can from Dow Corning Corporation (Midland, Michigan, USA), Huls America (Piscataway, New Jersey, USA), (Waterford, New York USA) buys General Electric Silicones.

Spreading agent

Compositions of the present invention also will comprise the non-volatile spreading agent that is used for polysiloxane fluid.Spreading agent of the present invention must be compatible with polysiloxane fluid.

The definition of term " non-volatile " is as indicated above." compatible " refers to spreading agent and dissolves in, is dispersed in or miscible with polysiloxane fluid, thereby but these two kinds of component blending compositions same mutually in.Spreading agent and polysiloxane fluid carry out blending in compositions, form a kind of mixture, and spreading agent has reduced the surface tension of polysiloxane fluid thus.Capillary reduction can be according to above-described step measurements.Spreading agent of the present invention and polysiloxane fluid can be mutually in the present composition continuously or discontinuous phase.

The spreading agent that compositions of the present invention should preferably comprise q.s reduces at least about 5%, preferably at least about 10%, more preferably at least about 15%, also more preferably at least about 20%, most preferably at least about 25% with the surface tension with polysiloxane fluid.Polysiloxane fluid/capillary the reduction of spreading agent mixture has brought the enhancing of improved hair gloss.In the most preferred compositions of the present invention, surface tension will reduce about 20% to about 35%, more generally be about 25% to about 30%.

Also preferred spreading agent should reduce surface tension at least about 2 dynes per centimeter ², more preferably at least about 3 dynes per centimeter ², also more preferably at least about 4 dynes per centimeter ², most preferably at least about 5 dynes per centimeter ²

The surface tension of the polysiloxane fluid that exists with the ratio in final products and the mixture of spreading agent is preferably 30 dynes per centimeter ²Or lower, 28 dynes per centimeter more preferably from about ²Or lower, 25 dynes per centimeter most preferably from about ²Or it is lower.Be typically, capillary scope is about 15 to about 30, and more typical is about 18 to about 28, and the most common is about 20 to about 25 dynes per centimeter ²

Gloss (gloss) is a kind of physical attribute, and it helps gloss (shine) outward appearance of object.Gloss can be measured with direct reflection.Direct reflection refers in the angular deviation of regulation from the mark of the incident illumination of the surface reflectance of minute surface direction or percentage ratio (that is, catoptrical direction becomes 108 degree with light stream direction from the light source to the reflecting surface).Direct reflection is to measure a kind of useful method of hair gloss.Further background material about direct reflection and the application in the assessment hair gloss thereof can be at R F Stamm, ML Garcia and J J Fuchs " human hair's optical property-I.Fundamental Considerationand Goniophotometer Curves; and II .The Lustre of Human Hair Fibres ", J SocCosmet.Chem.28,571-599 and 601-609 (in JIUYUE, 1977) find, and all these introduces the present invention as a reference.

The direct reflection of being measured by present composition coating on the black porcelain plate that collagen protein applies is corresponding to the gloss on hair, and because the less suspection experimental bias of discordance between hair sample and the agent of deposition hair gloss.Therefore the direct reflection on the black porcelain plate that described collagen protein applies that determines the present invention and measured, step is called as gloss meter direct reflection (Glossmeter Spectular Reflectance) in this article shown in the following experiment.

Perhaps, the present invention can also be by comprising spreading agent and polysiloxane fluid the compositions of mixture describe, wherein said composition comprises the spreading agent of q.s to improve the gloss meter direct reflection of mixture, with respect to polysiloxane fluid, increase is at least about " Δ 1.0% " (Δ is represented the primary light intensity based on 100%, the variation of the percentage ratio of direct reflection).Preferably, the increase of gloss meter direct reflection is a Δ 2.0% at least, more preferably at least about Δ 5.0%, also more preferably at least about Δ 7.5%, most preferably at least about Δ 10.0%.

The gloss meter direct reflection is to measure according to the step of telling about in following experimental section.Usually, use with compositions in polysiloxane fluid 1.0% solution of the polysiloxane fluid in the used same solvent (if existence) in the homophase mutually.If the diluent that polysiloxane fluid need not be independent in compositions dilution should use annular dimethyl polysiloxane (cyclimethicone) to prepare 1.0% solution so.If desired, can use annular dimethyl polysiloxane ethanol (cyclomethocone ethanol) to be formed for 1.0% the polysiloxanes of this test purpose.In order to compare, do not introduce spreading agent.In addition, with the weight ratio identical with spreading agent spreading agent is incorporated in the solution with the polysiloxane fluid that in compositions, exists.Test solution is deposited on the black porcelain that collagen protein applies watt, makes its drying.The direct reflection gloss meter, a kind of be suitable for measuring from the spectrophotometer of the direct reflection of flat surfaces measure.Suitable gloss meter can be buied, and this is well known in the art, for example can be available from BYK-Gardner, and lnd, SilverSpring, MD, " micro-gloss " gloss meter of USA.

The weight ratio of polysiloxane fluid and spreading agent is generally about 1000: 1 to about 1: 10, and preferred about 100: 1 to about 1: 1, more preferably from about 50: 1 to about 2: 1, most preferably from about 25: 1 to about 2: 1.For hair rinse composition, preferred especially this ratio was at about 10: 1 to about 2: 1.When using fluoric surfactant, because the effect of these surfactants, so extra high polysiloxanes: the spreading agent ratio is effective.Therefore, can consider to use ratio apparently higher than 100: 1.

Be used for preferred spreading agent of the present invention and comprise polyorganosiloxane resin, and surfactant, it not only comprises polyether siloxane copolymer but also comprise the organic surface active agent that does not contain polysiloxanes.Particularly preferred spreading agent is a polyorganosiloxane resin.

Polyorganosiloxane resin

Silicone resin is highly cross-linked siloxane systems.Crosslinked is by in the silicone resin production process, trifunctional and four functional silanes are mixed among simple function or two functional units or simple function and two functional units and introduces.As understood in the art, can change according to the unitary variation of specific silane of mixing in the silicone resin for forming the required degree of cross linking of polyorganosiloxane resin.Usually, can consider to adopt trifunctional with abundant amount and four functional silicone monomeric units (thereby crosslinked fully) so that they are dried to the polysiloxanes material of rigidity or hard film as polyorganosiloxane resin.The ratio of oxygen atom and silicon atom shows the crosslinked level in concrete polysiloxanes material.It will be polyorganosiloxane resin of the present invention usually that the ratio of oxygen atom and silicon atom is at least about 1: 1 polysiloxanes material.The preferred oxygen atom was at least about 1.2: 1.0 with the ratio of silicon atom.The typical silane that is used to produce polyorganosiloxane resin comprises monomethyl, dimethyl, a phenyl, diphenyl, aminomethyl phenyl, a vinyl and methyl ethylene chlorosilane and tetrachloro silicane.Preferred resin is methyl substituted polyorganosiloxane resin, as by General Electric with those of GE SS4230 and SS4267 supply.Commercially available polyorganosiloxane resin is usually with the unhardened form supply in low viscosity volatility or preferred non-volatile polysiloxane fluid.Be used for polyorganosiloxane resin of the present invention and exist with unsclerotized form rather than with the form of hardening resin in compositions of the present invention, this is conspicuous for the ordinary skill in the art.

About comprising the part of the preparation method that polysiloxane fluid, sizing material and resin and polysiloxanes are discussed, the background knowledge of polysiloxanes can see Encyclopaedia of Polymer Science andEngineering (polymer science and engineering encyclopedia) (the 15th volume, second edition, the 204-308 page or leaf, John Wiley ﹠amp; Sons, Incorporated, 1989), and polysiloxanes chemistry and technology (Chemistryand Technology of Silicones), Walter Noll, Academic Press Inc., (Harcourt BruceJavanovich, Publishers, New York), 1968,282-287 and 409-426 page or leaf, this paper is introduced into as a reference.

Polysiloxanes material, particularly polyorganosiloxane resin can be easily according to well known to a person skilled in the art i.e. " MDTQ " nomenclature identification of shorthand nomenclature system.In this system, polysiloxanes is that the various siloxanyl monomers unit according to the existence that constitutes polysiloxanes is described.In brief, symbol M is represented simple function unit (CH ₃) ₃SiO _0.5D represents two functional unit (CH ₃) ₂SiO; T represents trifunctional units (CH ₃) SiO _1.5Q represents four functional unit SiO ₂Unit symbol apostrophe such as M ', D ', T ', the substituent group of Q ' representative except that methyl, all need concrete definition at every turn.Typical alternative substituent group comprises as groups such as vinyl, phenyl, amine, hydroxyls.In the MDTQ system, various unitary mol ratios are perhaps represented with the subscript that indicates the symbol of the unitary total number of every class (or its meansigma methods) in the siloxanes, perhaps show with concrete indicated ratio and binding molecule scale, can finish the description to silicone material.T, Q, T ' and/or Q ' represent the crosslinking degree height to the higher relative molecular weight of D, D ', M and/or M ' in polyorganosiloxane resin.But as previously discussed, whole crosslinked amount also can be represented the ratio of silicon atom with oxygen atom.

Be used for polyorganosiloxane resin of the present invention preferably MQ, MT, MTQ and MDTQ resin.Therefore, preferred polysiloxanes substituent group is a methyl.Particularly preferably be the MQ resin, particularly those wherein the mol ratio of M: Q be about 0.5: 1.0 to about 1.5: 1.0, the mean molecule quantity of this resin is about 500 to about 10000, is generally about 1000 to 10000.

Depend on concrete selection, can need or to wish to mix additional solvent compatible with each other to guarantee resin and polysiloxane fluid spreading agent (particularly polyorganosiloxane resin) and polysiloxane fluid.Therefore, if polyorganosiloxane resin is at required polysiloxane fluid: incompatible during the weight ratio of polyorganosiloxane resin with polysiloxane fluid, so usefully mix a kind of solvent to promote the increase of these components dissolved degree or dispersibility in mutually at polysiloxanes/spreading agent.If the refraction index of solvent is lower than about 1.46 or additionally be lower than the refraction index of polysiloxane fluid, then wish to use a kind of volatile solvent (under 25 ℃, one atmospheric pressure vapour pressure greater than 0.2 millimetres of mercury and boiling point usually less than about 275 ℃ material), thereby it does not remain on the hair, can not damage the gloss characteristics that obtains according to the present invention potentially.Suitable solvent comprises: annular dimethyl polysiloxane (cyclomethicone), other annular siloxane such as the present invention describe as carrier fluid those, linear polysiloxane polymer such as polydimethylsiloxane, and the low viscous analog of other polysiloxanes material of in formula I or II, describing, preferably the viscosity in the time of 25 ℃ is about 10 centistokes or lower, and this material has the substituent group that contains aryl of lower (or being zero) degree usually than polysiloxanes height arylation of the present invention, high refractive index; Volatile liquid hydrocarbon, as have about 4 side chain or straight-chain hydrocarbons (for example hexane, iso-butane, decane, dodecane, the tetradecane, tridecane) to about 16 carbon atoms; Lower alcohol (C for example ₂-C ₄Alcohol is as ethanol and isopropyl alcohol); Hydrocarbon ester, preferred the total number of carbon atoms are about 10 or lower (for example ethyl acetate); Halogenated hydrocarbons (for example freon); Volatility ketone (for example acetone); And their mixture.Particularly preferably be the ring-type methylsiloxane.But the present invention does not get rid of the non-volatile solvents of the polysiloxanes solvent that is used for resin/phenylating.

When using, for rinsing formula hair care product, aforesaid solvent, usually will use up to about 100: 1 amount the weight ratio of (the nonvolatile polysiloxanes of height arylation adds spreading agent) with (solvent), more typical is up to about 50: 1, for the hair rinse product, preferred about 2: 1 to about 10: 1.For the non-washing type product, can use high-load volatile solvent as carrier components, this will be described below.

Surfactant

Compatible with polysiloxane fluid of the present invention and be applicable to that the surfactant on the hair can be used as spreading agent.Surfactant can be anionic, cationic, non-ionic, amphoteric or zwitterionic.

Polyether siloxane copolymer

Polyether siloxane copolymer, perhaps sometimes the marquis to be called polysiloxanes " copolyol " be the surfactant that contains polysiloxanes, they can be as the spreading agent of polysiloxane fluid.The polysiloxanes copolyol is to be characterized as the surfactant with hydrophobicity polysiloxane chain and hydrophilic alkoxyl part.

Operable polysiloxanes copolyol comprises the polydimethylsiloxane of the following formula of polyoxyalkylene modification:

With

R '-Si--[-OSi (CH ₃) ₂] _x-(OC ₂H ₄) _a-(OC ₃H ₆) _B-3OR " wherein R be hydrogen, have 1 alkyl, have 1 alkoxyl or hydroxyl to about 6 carbon atoms to about 12 carbon atoms; R ' and R " be to have 1 alkyl to about 12 carbon atoms; X is 1 to 100 integer, preferred 20 to 30; Y is 1 to 20 integer, preferred 2 to 10; A and b are 0 to 50 integers, preferred 20 to 30.

Be applicable to that those polysiloxanes copolyols of the present invention also are disclosed in the following patent literature, all introducings the present invention as a reference: the United States Patent (USP) 4122029 of authorizing people such as Geen on October 24th, 1978; Authorized on May 5th, 1981 Keil United States Patent (USP) 4265878 and nineteen eighty-three December authorized people's such as Dixon United States Patent (USP) 4421769 on the 20th.This polysiloxanes copolyol material in hair composition also is disclosed in the UK Patent Application 2066659 (introducing the present invention as a reference) of disclosed Abe on the 15th July in 1981 and authorized on February 8th, 1966 in the Canadian Patent 727588 (introducing the present invention as a reference) of Kuehns.Can be used for the polysiloxanes copolyol of buying of the present invention and comprise Silwet surface active block copolymer (Union Carbide Corporation production); With Dow Corning polysiloxane surfactant (Dow Corning Corporation production).

The operable various suitable organic surface active agent that does not contain polysiloxanes is as mentioned below.

Anion surfactant

Be used for anion surfactant of the present invention and comprise alkyl and alkyl ether sulfate.These materials have general formula R OSO separately usually ₃M and RO (C ₂H ₄O) _xSO ₃M, wherein R has about 10 alkyl or alkenyls to about 20 carbon atoms, and x is 1-10, and M is water-soluble cationic such as ammonium, sodium, potassium and triethanolamine.

Another kind of suitable anion surfactant is the water soluble salt with organic sulfur acid reaction product of following general formula:

R ₁-SO ₃-M is R wherein ₁Be selected from and have about 8 to about 24 carbon atoms, preferred about 12 straight or brancheds, saturated aliphatic hydrocarbon residue to about 18 carbon atoms, M is a cation.Important example is the salt of the organic sulfur acid reaction product of methane series hydrocarbon, methane series hydrocarbon comprises having about 8 to about 24 carbon atoms, preferred about 12 to about 18 carbon atoms different-, new-or n-paraffin and sulfonated reagent for example sulfur trioxide, sulphuric acid, oleum, comprise according to known method of sulfonating and to bleach and hydrolysis obtains.Preferably sulfonated C ₁₂-C ₁₈The alkali metal of normal paraffin hydrocarbons and ammonium salt.

The additional example of the anion surfactant in this term scope of the present invention is a product of also using the neutral fatty acid of sodium hydroxide with the isethionic acid esterification, and wherein fatty acid derived is from Oleum Cocois; The sodium salt of the fatty acid amide of methyl taurate or potassium salt, wherein fatty acid is for example derived from Oleum Cocois.The anion surfactant of other of this class is told about in United States Patent (USP) 2486921,2486922 and 2396278.

The anion surfactant of other that also has comprises the classification that is called succinamate.This class comprises such surfactant such as N-octadecyl sulfosuccinamic acid disodium; N-(1,2-two carboxyethyls)-N-octadecyl sulfosuccinamic acid four sodium; The diamyl succinate sodium sulfonate; Dihexyl sodium sulfosuccinate; Dioctyl sodium sulfosuccinate.

Other can be used for suitable anion surfactant of the present invention is to have about 12 alkene sulfonates to about 24 carbon atoms.The term " alkene sulfonate " that is used for herein refers to the chemical compound that obtains by following reaction: alpha-olefin is SO 3 sulfonated with what do not cooperate, then and acidic reaction mixture, reaction condition is that any sultone of forming in reaction is hydrolyzed and provides corresponding hydroxyl-alkane sulfonate.The alpha-olefin that is used for obtaining alkene sulfonate is to have about 12 to about 24 carbon atoms, preferably has about 14 monoolefines to about 16 carbon atoms.Another kind of anion organic surface active agent is a b-alkoxy alkane sulfonate.

Non-ionic surface active agent

Non-ionic surface active agent can be broadly defined as the chemical compound that is obtained by oxyalkylene group (hydrophobicity) and hydrophobic compound (it can be aliphatic series or alkyl aromatic class) condensation.The example of indefiniteness is in the nonionic surfactants:

1. the condensation substance of the polyethylene glycol oxide of alkyl phenol, for example alkyl be side chain or straight chain configuration comprise about 6 to the alkyl phenol of about 20 carbon atoms and the condensation product of ethylene oxide, the amount of described ethylene oxide is that every mole of alkyl phenol about 10 is to about 60 mole ethylene oxides.

The product condensation of ethylene oxide and propylene oxide and reacting ethylenediamine gained obtain those.

3. have about 8 to about 18 carbon atoms, for side chain or the aliphatic alcohol of straight chain configuration and the condensation product of ethylene oxide, for example every mole of coco alcohol has the about 10 cocoanut oil alcohol ethylene oxide condensation substances to about 30 mole ethylene oxides, and cocoanut oil alcohol partly has about 10 to about 14 carbon atoms.

4. long chain tertiary amine, as corresponding to those of following general formula:

R ₁R ₂R ₃N → O is R wherein ₁Comprise have about 8 to the former alkyl that gives of about 18 carbon, alkenyl or monohydroxy alkyl, 0 to about 10 ethylene oxides part and 0 to about 1 glyceryl part, R ₂And R ₃Comprise about 1 to about 3 carbon atoms and 0 to about 1 hydroxyl, for example methyl, ethyl, propyl group, ethoxy or hydroxypropyl (arrow in the general formula is represented semi-polar bond).

5. long chain tertiary phosphorous oxide, as corresponding to those of following general formula:

RR ' R " P → O wherein R comprise chain length be about 8 alkyl, alkenyl or monohydroxy alkyl to about 18 carbon atoms, 0 to about 10 ethylene oxides part and 0 to about 1 glyceryl part, R ' and R " be to comprise about 1 alkyl or monohydroxy alkyl to about 3 carbon atoms.Arrow in the general formula is represented semi-polar bond.

6. long-chain dialkyl sulphoxide, comprise one have about 1 comprise to the short-chain alkyl of about 3 carbon atoms (normally methyl) or hydroxyalkyl and one have about 8 alkyl, alkenyl, hydroxy alkyl or ketone alkyl to about 20 carbon atoms, 0 to about 10 ethylene oxides part and 0 long-chain hydrophobic chain to about 1 glyceryl part.

7. polysorbate, for example sucrose ester of fatty acid.These materials are stated in United States Patent (USP) 3480616, for example coconut oil sucrose ester (mixture of coconut oil sucrose ester mainly is made of monoesters, by RITA with trade name GRILLOTENLSE 87K and the CRODESTA SL-40 that sold by Croda).

8. alkyl polysaccharide non-ionic surface active agent, be described in the United States Patent (USP) 4565647 of authorizing Llenado on January 21st, 1986, have and contain about 6, polysaccharide glycosides for example, hydrophilic group to about 30 carbon atoms, preferred about 10 hydrophobic group and polysaccharide to about 16 carbon atoms.Can use any reducing sugar that contains 5 or 6 carbon atoms, for example glucose, galactose, and the galactosyl part can replace with the grape glycosyl part.Randomly, the polyoxyalkylene chain that connects hydrophobic part and polysaccharide part can be arranged.Alkyl preferably comprises up to about 3 hydroxyls and/or polyoxyalkylene chain and can comprise up to about 10, preferably is less than 5 alkylene moiety.Suitable alkyl polysaccharide be octyl group, nonyl, decyl, undecyl, dodecyl, tridecyl, myristyl, pentadecyl, cetyl, heptadecyl and octadecyl, two-, three-, four-, five-and six glucosides, galactoside, lactoside, glucose, fructoside, fructose and/or galactose.

9. Polyethylene Glycol (PEG) glyceryl fatty ester is described as following formula RC (O) OCH ₂CH (OH) CH ₂(OCH ₂CH ₂) _nOH, wherein n is about 5 to about 200, preferred about 20 to about 100, more preferably from about 30 to about 85, RC (O)-be ester, wherein R comprises having about 7 to about 19 carbon atoms, preferred about 9 to about 17 carbon atoms, more preferably from about 11 to about 17 carbon atoms, most preferably from about 11 to about 14 carbon atoms aliphatic residue.Preferably n is about 20 to about 100, and C ₁₂-C ₁₈, preferred G ₁₂-C ₁₅The combination of fatty ester is to be minimized in the side effect of foaming aspect.

Cationic surfactant

The cationic surfactant that is used for the present composition particularly as the component in additional conditioner active substance or the gel carrier, comprises amino or quaternary ammonium hydrophilic segment, and it is positively charged in being dissolved in Aquo-composition of the present invention the time.Can be used for cationic surfactant of the present invention in these and be disclosed in the following document, described document all is incorporated herein by reference: M.C.Publishing Co., McCutcheon ' s Detergents ﹠amp; Emulsifiers. (North America version 1979); People such as Schwartz, surfactant, its chemistry and technology, New York: Interscience Publishers, 1949; Authorized the United States Patent (USP) 3155591 of Hilfer on November 3rd, 1964; Decembers in 1975 were authorized people's such as Laughlin United States Patent (USP) 3929678 on the 30th; Authorize people's such as Bailey United States Patent (USP) 3959461 on May 25th, 1976 and authorize Bolich June 7 nineteen eighty-three, the United States Patent (USP) 4387090 of Jr..

In containing the cationic surfactant of quaternary ammonium, can be used for of the present invention be following general formula represent those: R wherein ₁-R ₄Be to have about 1 aliphatic group independently, or have about 12 aromatics, alkoxyl, polyoxyalkylene, alkyl amido, hydroxy alkyl, aryl or alkylaryl to about 22 carbon atoms to about 22 carbon atoms; X is an anion, is selected from halogen, acetate, phosphate radical, nitrate anion and alkyl sulfate.Aliphatic group also comprises ehter bond or other group such as amino except that carbon atom and hydrogen atom.Long aliphatic chain, for example about 12 carbon are former to give or those higher aliphatic chains, can be saturated or undersaturated.

The primary, the salt of the second month in a season and uncle's fatty amine also is the suitable cationic surfactants material.The alkyl of this class amine preferably has about 12 to about 22 carbon atoms, can be that replace or unsubstituted.This class amine used herein comprises (having 5 moles of ethylene oxide) stearylamine, dihydroxy ethyl stearylamine and the arachidonic acyl group docosyl amine of the amino propyl-dimethyl amine of stearoyl, diethyllaminoethyl stearmide, dimethyl stearylamine, dimethyl Semen sojae atricolor amine, Semen sojae atricolor amine, Semen Myristicae amine, tridecyl amine, ethyl stearylamine, N-Adeps Bovis seu Bubali propane diamine, ethoxylation.Suitable amine salt comprises halogen, acetate, phosphate, nitrate, citrate, lactate and alkyl sulfate.This class salt comprises the amino propyl-dimethyl ammonium citrate of stearyl hydrochloric acid ammonium, Semen sojae atricolor ammonium chloride, stearyl ammonium formate, N-Adeps Bovis seu Bubali propane diamine dichloride and stearoyl.The cationic amine surfactant that is included in those cationic surfactants that are used for the present invention is disclosed in the United States Patent (USP) 4,275,055 of authorizing people such as Nachtigal on June 23rd, 1981, and this patent is introduced the present invention as a reference.

The quaternary ammonium cation conditioner that can be used for concrete class of the present invention is to be characterized as those of following formula:

[R _4-m-N ⁽⁺⁾-[(CH ₂) _n-Y-R ¹] _m] X ^(-)Wherein the R substituent group is short chain C ₁-C ₆Alkyl or hydroxy alkyl, benzyl or their mixture; Each m is 2 or 3; Each n is 1 to about 4; Each Y is-O-(O) C-or-C (O)-O-; Each R ¹Be the alkyl of alkyl or replacement, each R ¹The summation of middle carbon atom is worked as R ¹Add 1 when being-O (O) C-, be C ₁₂-C ₂₂R ¹The average iodine number of the maternal fatty acid of group is about 60 to about 140; And counter ion X wherein ^-It is any compatible counter ion.

Amphion and amphoteric surfactant

The example that can be used for the zwitterionic surfactant in shampoo and the conditioner is those of the derivant that can broadly be described as aliphatic quaternary ammonium, quaternary phosphine and sulfonium compound, wherein aliphatic residue can be a straight or branched, and one of them aliphatic substituent group comprises about 8 to about 18 carbon atoms, also have one and comprise the anionic water-soluble group, for example carboxylate radical, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.These general formula is:

R wherein ²Comprise have about 8 alkyl, alkenyl or monohydroxy alkyl to about 18 carbon atoms, 0 to about 10 ethylene oxides part and 0 to about 1 glyceryl part; Y is selected from nitrogen, p and s atom; R ³Be to comprise about 1 alkyl or monohydroxy alkyl to about 3 carbon atoms; When Y was sulphur atom, X was 1, and when Y was nitrogen, phosphorus atoms, X was 2; R ⁴Be to have about 1 alkylidene or hydroxy alkylidene to about 4 carbon atoms; Z is the group that is selected from carboxylate radical, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.

Other amphion such as betanin also can be used among the present invention.The example that can be used for the betanin among the present invention comprises high alkyl betaine, as coco dimethyl carboxymethyl betaine, lauryl dimethyl carboxymethyl betaine, lauryl dimethyl α-carboxyethyl betanin, cetyl dimethyl carboxymethyl betaine, two (2-ethoxy) carboxymethyl betaines of lauryl, two (2-hydroxypropyl) carboxymethyl betaines of stearyl, oil base dimethyl γ-carboxylic CAB and two (2-hydroxypropyl) α of lauryl-carboxyethyl betanin.The representative of sulfobetaines can be coco dimethyl sulfopropyl betaine, stearyl dimethyl sulfopropyl betaine, lauryl dimethyl sulfo group ethyl betanin, two (2-ethoxy) sulfopropyl betaine of lauryl etc., also can use amido betaines and acylamino-sulfobetaines, wherein RCONH (CH among the present invention ₂) ₃Group is connected on the nitrogen-atoms of betanin.

The examples of amphoteric surfactants that can be used for the present composition is to be those of derivant of aliphatic secondary and tertiary amine by generalized description, wherein aliphatic group can be straight or branched and one of them aliphatic substituent group comprise about 8 to about 18 carbon atoms, also have one and comprise the anionic water-soluble group, for example carboxylate radical, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.Examples for compounds in this range of definition is 3-sodium dodecyl aminopropionitrile, 3-dodecyl amino propane sulfonic acid sodium, N-alkyl taurine as the sort of, the N-senior alkyl aspartic acid of the method preparation that lauryl amine and hydroxyethyl sulfonate are told about according to United States Patent (USP) 2658072 as those of the method preparation told about according to United States Patent (USP) 2438091; Those products with selling down in trade name " Miranol " are described in the United States Patent (USP) 2528378, and the present invention introduces above-mentioned patent as a reference.

Other spendable surfactant comprises fluoro surfactants, or other halogenated surfactant, and they can be anion, nonionic, cation, both sexes or zwitterionic surfactant.

Fluoro surfactants comprises the chemical compound of perfluoro, as shown in the formula the representative those:

CF ₃-(CF ₂) _x-(CH ₂) _y-Z wherein Z is inorganic or the water soluble group of organic feature, x is generally 2 to 17 integer, and particularly 7 to 11, y is generally 0 to 4 integer, described chemical compound can be cation, anion, both sexes or amphion, and this depends on the character of the group that Z is included.The Z group can be maybe to comprise sulfate radical, sulfonate radical, carboxylate radical, amine salt, quaternary ammonium, phosphate radical, phosphonate radical and their combination.The chemical compound of perfluoro also is disclosed in the United States Patent (USP) 3993744 that the United States Patent (USP) of authorizing people such as Cella on November 27th, 1979 was authorized people's such as Cella United States Patent (USP) 3993745 November 23 in 4176176,1976 and authorized people such as Cella on November 23rd, 1976, and the present invention introduces these patents as a reference.

When using fluoro surfactants, its consumption amount than other spreading agent of great majority usually is low.They usually with polysiloxane fluid to the weight ratio of spreading agent about 10000: 1 to about 1: 1, used to about 10: 1 consumption in preferred about 1000: 1.

Ethanol

Compositions of the present invention will comprise about 10% ethanol to about 50% weight, and preferred about 15% to about 40%, and more preferably from about 18% to about 35%, most preferably from about 20% to about 30%.

Water

Compositions of the present invention will comprise water, usually its consumption be composition weight about 30% to about 89.9%, preferred about 30% to about 89.8%, more preferably from about 50% to about 85%, also more preferably from about 60% to about 80%, most preferably from about 65% to about 80%.

The scalp conditioner

Compositions is removed will preferably include the scalp conditioner, and it can also nurse one's health the skin of scalp except that as the hair gloss agent, therefore reduce or eliminated any desiccation of scalp.The amount of scalp conditioner be preferably composition weight about 0.1% to about 10%, more preferably from about 0.25% to about 5%, most preferably 0.5% to about 3%.

Scalp conditioner of the present invention can be any conditioning skin that is suitable for, and brings skin moistening, humidification or both to scalp, and is can introduce in the compositions of the present invention, and can not stop compositions to strengthen the material of hair gloss.Therefore, scalp conditioner of the present invention can comprise skin emollient and skin moisturizer and combination thereof.Emollient can comprise conventional lipoid (for example ester is as fat, oil, wax etc.), polarity lipoid (for example having carried out hydrophobic modified so that the lipoid that it is more water-soluble), polysiloxanes and hydro carbons.Scalp conditioner of the present invention will be normally nonvolatile.

Emollient

Suitable scalp conditioner comprise the non-volatile polysiloxane fluid (refraction index is lower than 1.46) of aliphatic alcohol, non-volatile hydro carbons, low refractive index comprise the formula of above-mentioned representative but be characterized as lower or zero aryl replaces those, particularly polydimethylsiloxane, and fatty ester and other lipoid ester.

Aliphatic alcohol comprises C ₁₂-C ₂₂Alcohol, preferred C ₁₆-C ₁₈Alcohol is as stearyl alcohol and spermol.

Non-volatile hydrocarbon oil comprises linear and the side chain hydro carbons, comprises saturated and unsaturated hydrocarbons.Hydrocarbon ils include but not limited to have 12-20 carbon atom straight-chain hydrocarbons, have 12 or the branched-chain hydrocarbons of more a plurality of carbon atoms, the polymer hydrocarbon of alkenyl monomer, as C ₂-C ₆Alkenyl monomer, it can be (common weight average molecular weight is not still got rid of higher amount up to about 500 yet) of straight or branched.The instantiation of hydrocarbons comprises paraffin oil, mineral oil, saturated or unsaturated dodecane, the tetradecane, pentadecane and hexadecane and polybutene.

Fatty ester comprise by aliphatic alcohol or fatty acid (as but be not limited to have C ₁₂-C ₂₂Those) ester that derives, as but be not limited to single-, two-, the tri-carboxylic acids ester.The hydrocarbyl residue of fatty ester and alcohol also can replace with other functional group, as amide and alkoxyl part (for example ethyoxyl or ehter bond).

The monocarboxylate comprises those of formula R ' OOR representative, and wherein R and R ' are alkyl or the alkenyls that does not replace or replace, and wherein the total number of carbon atoms among R and the R ' is at least 10, preferably is at least 20.Example comprises that fatty ester is as having C ₁₀-C ₂₂The alkyl of fatty acid and alkenyl ester and have the alkyl and the alkenyl aliphatic alcohol carboxylate of the pure deutero-chain of about 10-22 carbon atom.Preferably has C ₆-C ₂₂The C of R group ₁₀-C ₂₂Ester.Example comprises as the stearate with hexyl, isohesyl, decyl, isodecyl, cetyl, cetyl, lauryl, myristyl or oil base, isostearate, laurate, cetylate, oleate, adipate ester, lactate, myristinate, acetas and propionic ester.The example of the ester that other is suitable comprises diisopropyl adipate, adipic acid two dissident's ester and Dermol DIPSs.

Two of carboxylic acid-, trialkyl and alkenyl ester comprise, C for example ₄-C ₈Two or tricarboxylic C ₁-C ₂₂, preferred C ₁-C ₆Ester, described carboxylic acid such as succinic acid, 1,3-propanedicarboxylic acid, adipic acid, caproic acid, enanthic acid and sad, for example stearic different cetearyl alcohol acyl ester of described ester, diisopropyl adipate and tristearyl citrate.

Polyhydroxy alkyl ester comprises alkylidene diol fatty acid ester, glycol monomethyl-and di fatty acid ester for example, and diglycol monotertiary-and di fatty acid ester, polyethyleneglycol-and di fatty acid ester and propylene glycol list-and di fatty acid ester.Example comprises the propylene glycol monostearate, glyceryl list of polypropylene glycol monoleate and monostearate, ethoxylation-and glycerol monostearate, 1,3 butylene glycol distearate, polyoxyethylene polyols fatty acid ester, fatty acid esters of sorbitan and the polyoxyethylene sorbitan fatty acid ester of two-fatty acid ester, polyglycereol polyglycerol fatty acid ester, ethoxylation.Other suitable material is a glyceryl monostearate.

That glycerol comprises is single-, two-and triglyceride, comprise glycerol and long-chain carboxylic acid such as C ₁₀-C ₂₂This class of carboxylic acid is single-, two-and three esters.The material of these types can get from plant and animal fat and oil, as Oleum Ricini, safflower oil, lanoline etc.Artificial oil comprises oleic acid triglyceride, stearic acid triglyceride and Dilaurin.

The polyol carboxylate can be used for useful emollient of the present invention.These polyol carboxylates can or partly get by polyhydric alcohol residue or part and one or more carboxylic acid residues usually.In other words, these esters comprise part and the one or more part that derives from carboxylic acid that derives from polyhydric alcohol.These polyol carboxylates also can be described as polyol fatty acid ester, because term carboxylic acid and fatty acid are the terms that those of ordinary skills often exchange use.

The preferred polyhydric alcohols carboxylic acid polyester that is used for the present invention comprises some polyhydric alcohol, particularly sugar or sugar alcohol with at least four fatty acid group esterifications.Therefore, but the polyhydric alcohol initial substance must have the hydroxyl of at least four esterifications.The example of preferred polyhydric alcohols is a sugar, comprises monosaccharide and disaccharide, and sugar alcohol.The example that comprises the monosaccharide of four hydroxyls is xylose and arabinose and derived from the sugar alcohol of xylose, and it has 5 hydroxyls, i.e. xylitol.Monosaccharide is that erythrose is not suitable for being used for implementing the present invention, because it only comprises three hydroxyls, but is that erythritol comprises four hydroxyls derived from the sugar alcohol of erythrose, therefore can use.Suitable contain 5 hydroxyls monosaccharide be galactose, fructose and sorbose.Derived from the sugar alcohol that contains six hydroxyls of the hydrolysis prods of sucrose and glucose and sorbose, also be to be suitable for as sorbitol.Operable disaccharide examples of polyhydric alcohols comprises maltose, lactose and sucrose, and all these comprises eight hydroxyls.

The preferred polyhydric alcohols that preparation is used for polyester of the present invention is selected from erythritol, xylitol, Sorbitol, dextrose plus saccharose.Sucrose is particularly preferred.

Polyhydric alcohol initial substance usefulness at least four hydroxy position with at least four hydroxyls contains 8 fatty acid esterifications to about 22 carbon atoms of having an appointment.That the example of this fatty acid comprises is sad, capric acid, lauric acid, myristic acid, Semen Myristicae oleic acid, Palmic acid, palmitoleic acid, stearic acid, oleic acid, castor oil acid, linoleic acid, linolenic acid, eleostearic acid, arachidic acid, arachidonic acid, behenic acid and erucic acid.Fatty acid also can be derived from naturally occurring or synthetic fatty acid; They can be saturated or undersaturated, comprise position and geometric isomer.But, being preferred for liquid polyester of the present invention in order to provide, the fatty acid of introducing in the polyester molecule at least about 50% weight should be unsaturated.Preferred especially oleic acid and linoleic acid and their mixture.

Be used for polyol carboxylate of the present invention and should comprise at least four fatty acid ester group.The all hydroxyls that do not need polyhydric alcohol are all by fatty acid esterification, but preferred polyester comprises and is no more than 2 nonesterified hydroxyls.Most preferably, all hydroxyls basically of polyhydric alcohol are all by fatty acid esterification, and promptly polyol moiety is all esterified basically.Esterification can be identical or blended to the fatty acid of polyhydric alcohol molecule, still, should preferably exist a large amount of unsaturated acids ester groups to provide mobile.

Following is the non-limiting example that is applicable to the concrete polyol carboxylate who comprises at least 4 fatty acid ester group among the present invention; The glucose tetra-ester of glucose four oleates, soya fatty acid (unsaturated), mixing soya beans fatty acid oil mannose four esters, oleic galactose four esters, linoleic acid arabinose four esters, xylose four linoleates, galactose five oleates, sorbitol four oleates, unsaturated soya fatty acid sorbitol six esters, xylitol five oleates, sucrose four oleates, sucrose five oleates, sucrose six oleates, sucrose seven oleates, sucrose eight oleates and their mixture.

As mentioned above, particularly preferably being the polyol carboxylate is that wherein fatty acid comprises about 14 to those of about 18 carbon atoms.

Being used for preferred polyhydric alcohols carboxylate of the present invention is liquid, and fusing point is lower than about 30 ℃ fully, preferably is lower than about 27.5 ℃, more preferably less than about 25 ℃.Complete fusing point cited herein is measured by differential scanning calorimetry (DSC).

Be applicable to that polyol fatty acid polyesters of the present invention can prepare with various methods known to a person of ordinary skill in the art.These methods comprise uses various catalyst to carry out the ester exchange reaction of polyhydric alcohol with methyl, ethyl or the glyceride of fatty acid; Carry out the acidylate of polyhydric alcohol with fat acyl chloride; Carry out the acidylate of polyhydric alcohol with fatty acid anhydride; Carry out the acidylate of polyhydric alcohol with known fatty acid.Referring to United States Patent (USP) 2831854; Authorized the United States Patent (USP) 4005196 of Jandacek on January 25th, 1977.

Can be used for oxyalkylated alcohol of the present invention can be described by following general formula:

Wherein R is selected from alcohol, polyhydric alcohol, dihydroxylic alcohols and their mixture, and its chain length is about 2 to about 30 carbon atoms; N is about 3 to about 40 integer; X is selected from hydrogen, methyl, ethyl, propyl group and composition thereof.

Preferred R is selected from alcohol, polyhydric alcohol, dihydroxylic alcohols or their mixture, and its chain length is about 4 to about 20 carbon atoms; X is a methyl; N is about 6 to about 35 integer.More preferably, R is selected from alcohol, polyhydric alcohol, dihydroxylic alcohols and their mixture, and its chain length is about 4 to about 18 carbon atoms; X is a methyl; N is about 10 to about 20 integer.

The example that is used for the indefiniteness of oxyalkylated alcohol of the present invention comprises the propoxylation of pure and mild polyhydric alcohol and the ether of butoxyization.These chemical compounds can be described as PPG and PBG alkyl ether, and wherein PPG and PBG are respectively the general titles of polypropylene glycol and polytetramethylene glycol.The average of PPG or PBG group is usually by following the number designation in PPG or PBG group back to provide in these ethers.For example the PPG-14 butyl ether will be represented the polypropylene glycol ether of butanols, wherein on average have 14 propylene glycol unit in the molecule.

The example that is used for the indefiniteness of oxyalkylated alcohol of the present invention comprises the PPG-10 butyl ether, the PPG-11 butyl ether, the PPG-12 butyl ether, the PPG-13 butyl ether, the PPG-14 butyl ether, the PPG-15 butyl ether, the PPG-16 butyl ether, the PPG-17 butyl ether, the PPG-18 butyl ether, the PPG-19 butyl ether, the PPG-20 butyl ether, the PPG-22 butyl ether, the PPG-24 butyl ether, the PPG-30 butyl ether, the PPG-11 stearyl ether, the PPG-15 stearyl ether, the PPG-10 oleyl ether, the PPG-7 lauryl ether, the different cetyl ether of PPG-30, PPG-10 glyceryl ether, PPG-15 glyceryl ether, the PPG-10 butanediol ethere, the PPG-15 butanediol ethere, PPG-27 glyceryl ether, the PPG-30 cetyl ether, the PPG-28 cetyl ether, the PPG-10 cetyl ether, PPG-10 hexanediol ether, PPG-15 hexanediol ether, PPG-10 1,2,6-hexanetriol ether, PPG-15 1,2,6-hexanetriol ether and their mixture.

The example that is used for the indefiniteness of oxyalkylated polyhydric alcohol of the present invention comprises and is selected from following those: PPG-10 1,4-butanediol, PPG-12 1,4-butanediol, PPG-14 1,4-butanediol, PPG-2 butanediol, PPG-10 1,6-hexanediol, PPG-12 1,6-hexanediol, PPG-14 hexanediol, PPG-20 hexanediol and their mixture.Preferably be selected from following those: PPG-10 1,4-butanediol, PPG-12 1,4-butanediol, PPG-10 1,6-hexanediol, PPG-12 hexanediol and their mixture.

Polypropylene glycol also is to be used for suitable emollients of the present invention.They can be described to the common polymer that is formed by following material polymerization: propylene oxide, propylene glycol, propyl group chloropropylene oxide, propyl group epibromohydrin and other relevant material.Preferred polypropylene glycol is by those of following formula representative: Wherein n is about 10 to about 50 integer, and preferred about 15 to about 40, more preferably from about 20 to about 34.In said structure, even when having described isomer orientation for convenience, but this does not represent to get rid of other isomer structure.Polypropylene glycol is also represented with the PPG of the numerical value of following the repetitive average that indicates in the structure usually.For example, PPG-30 is with corresponding said structure, and wherein the meansigma methods of n is about 30.Based on this nomenclature, be used for polypropylene glycol of the present invention and comprise those of called after PPG-10 to PPG-50, more preferably those of called after PPG-15 to PPG-40, most preferably those of called after PPG-20 to PPG-34.

Wetting agent

Wetting agent also can have the moisturization that is used for scalp.Being used for examples of humectants of the present invention comprises as urea; Guanidine; Saturated or unsaturated alkyl 'alpha '-hydroxy acids such as glycolic and glycollate (for example ammonium salt and alkyl quaternary ammonium salts) and lactic acid and lactate (for example ammonium salt and alkyl quaternary ammonium salts); Various forms of Aloes (for example Aloe gel); Polyhydroxy-alcohol such as sorbitol, glycerol, low-molecular-weight polypropylene glycol (for example dipropyl glycol and 3 third glycol), hexanetriol, propylene glycol, butanediol, hexanediol etc.; Polyethylene Glycol; Sugar and starch; The derivant of sugar and starch (for example oxyalkylated glucose); Hyaluronic acid; Chitin; Starch-grafted sodium polyacrylate such as Sanwet (RTM) IM-1000, IM-1500 and IM-2500 (VA buys for CelaneseSuperabsorbent Materials, Portsmouth); Lactic acid amide monoethanolamine; The acetamide monoethanolamine; Propenoxylated glycerol (be described in the nineteen ninety December and authorized people's such as Orr United States Patent (USP) 4976953 on the 11st, the present invention introduces this full patent texts as a reference) and composition thereof.

The wetting agent that is used for the present composition comprises C ₃-C ₆Dihydroxylic alcohols and trihydroxylic alcohol, and propenoxylated glycerol.Example comprises propylene glycol, 1,3-dihydroxypropane, glycerol, butanediol, hexanediol, 1,4-dihydroxy-hexane, 1,2,6-hexanetriol, dipropyl glycol, 3 third glycol and composition thereof.Wetting agent can also comprise water miscible polyglyceryl methacrylate such as Lubrajels TM (GuardianChemical Corp., Hauppage, NY, USA).Lubrajels is hydrate or the cathrates that is formed by sodium glycerinate and methacrylate polymer.

Other composition

Compositions of the present invention can also comprise suitable other composition of making present composition carrier, and other active component except that the active component of above-mentioned necessity.

Select other suitable carrier components will depend on the employed concrete polysiloxane fluid and the type of the desired concrete compositions that obtains.Selecting and preparing such product is in the known scope of those of ordinary skills.

The non-limiting instance of supplementary element further describes hereinafter.

Be applicable to that the additional carrier fluid among the present invention comprises, but be not limited to, lower alcohol such as isopropyl alcohol, hydro carbons (as iso-butane, hexane, decene and acetone), halogenated hydro carbons such as freon, linalool, hydrocarbon ester (as ethyl acetate, dibutyl phthalate), the Y 7175 derivant, siloxanes particularly is as annular dimethyl polysiloxane and polydimethylsiloxane (viscosity is about 15 centistokes or lower 25 degrees centigrade the time for example) and composition thereof.

Compositions can also comprise the gel carrier material.Gel carrier can comprise two kinds of components: lipoid carrier mass and cationic surfactant vehicle materials.Cationic surfactant is above being described in detail.Preferred cationic surfactants is that quaternary ammonium compound is as two tallow alkyl dimethyl ammoniums.Another kind of preferred quaternary ammonium compound is three short-chain alkyls (C1-C3, preferred C1), single-long-chain alkyl (C10-C22, preferred C16-C18, particularly cetyl) ammonium salt.Preferred counter ion is sulfate radical and chloride, particularly chloride.Gel carrier is generally described in the following document, all all introduce the present invention as a reference: Barry, " the self-bodying effect of blended emulsifier sodium lauryl sulfate/spermol ", 28 J.ofColloid and Interface Science 82091 (1968), people such as Barry, " the self-bodying effect of blended emulsifying agent alkyl trimethyl ammonium bromide/cetostearyl alcohol; season chain length influence ", 35J.of Colloid and Interface Science, 689-708 (1971); With people such as Barry, " rheology that contains the system of Cetomacrogol 1000-cetostearyl mixture, the effect of I. self-bodying ", 38 J.of Colloid and Interface Science, 616-625 (1972).The lipoid carrier is water-fast basically, and comprise hydrophobic and hydrophilic segment, and comprise that chain length has about 12 to about 22 carbon atoms, preferred about 16 the natural or synthetic acid that obtains, acid derivative, alcohol, ester, ether, ketone and amide to about 18 carbon atoms.Such material also can be used as emollient, and wherein each kind is as indicated above.The pure and mild fatty ester of preferred fat.Special preferred fat alcohol.The example that is used to form the lipoid ester of gel carrier is cetin and glyceryl monostearate.

If use the gel carrier that is formed by cationic surfactant and lipoid carrier in compositions of the present invention, the amount of lipoid carrier mass is preferably about 0.1% to about 10.0% of compositions so; The amount of cationic surfactant vehicle materials is preferably about 0.2% to about 5.0% of compositions.

Other gellant also can be used for the present invention.Do not add any qualification, these comprise hydrophilic polymer as: acrylic acid/esters cross linked polymer as by B.F.Goodrich with trade name Carbopol ^TMThe carbomers that sells; Cellulose ether is as hydroxyethyl-cellulose, methylcellulose and hydroxypropyl cellulose; Polyvinylpyrrolidone; The polymer of polyvinyl alcohol, guar gum, hydroxypropyl guar gum, xanthan gum and other water solublity, water/ethanol solubility or colloidal state solubility.This gellant consumption in compositions usually is about 0.1% to about 5%, and preferred about 0.5% to about 2% weight.

Perhaps, can use other material to give the viscosity of composition gels shape, such material such as thickening agent (for example clay), viscosity modifier etc.Also can use the mixture of these materials.

Suspending agent also can (for example static-free be insoluble to the cationic surfactant in the compositions as the carrier component of suspension polysiloxane fluid/spreading agent hair gloss agent and/or other unmixing or graininess composition, antidandruff active substance such as 2-mercaptopyridine zinc oxide (ZPT), sulfur, selenium sulfide, coal tar, Octopirox ethanolamine (piroctone olamine), ketoconazole, Climbazole, salicylic acid etc.) suspending agent may be particular importance in dumpable liquid preparation.Preferred suspending agent is crystallization long acyl derivant such as glycol distearate, and it is described in United States Patent (USP) 4741855 (Grote, Russell, Procter ﹠amp with the glycol ester of other suitable fatty acid with 16-22 carbon atom; Gamble) in, the present invention introduces this patent as a reference.

Compositions of the present invention can also be used a kind of emulsifying agent.Emulsifying agent can be used for helping the agent of stable dispersion hair gloss, particularly low viscous compositions as flood (hair tonics) in.They also can be used for forming emulsive cream.Suitable emulsifying agent comprises nonionic, cation, anion surfactant or its mixture.The various examples that are suitable for the surfactant of making emulsifying agent are included in the surfactant of above-mentioned discussion particularly above-described nonionic and cationic surfactant.Emulsive cream like this can comprise those the combination described above of emulsifying agent and hydrocarbon, lipoid or lipoid carrier mass.If the use emulsifying agent, then preferred its amount is about 0.01% to about 7.5% of a compositions.

Compositions of the present invention can comprise additional hair conditioning composition, as, but be not limited to cationic surfactant, cationic polymer, as additional hair conditioning composition, and other hair conditioning composition such as pantothenylol, pantethine (panthetine), pantetheine (pantotheine), general benzyl ethyl ether and combination thereof.

Suitable cationic polymers comprises, the basic monomeric copolymer of vinyl monomer and water solublity interval that for example has cationic amine or quaternary ammonium functional group, basic monomer such as acrylamide, Methacrylamide, alkyl and dialkyl group acrylamide, alkyl and dialkyl methyl acrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone and vinyl pyrrolidone at interval.The monomer that alkyl and dialkyl group replace preferably has C ₁-C ₇Alkyl, more preferably C ₁-C ₃Alkyl.Other suitable interval base monomer comprises vinyl esters, vinyl alcohol (being obtained by the polyvinyl acetate hydrolysis), maleic anhydride, propylene glycol and ethylene glycol.Other cationic polymer comprises cation-modified polysaccharide, as the cellulose of ammonium cation modification.

Particularly preferably be the cationic saccharide base polymer (comprising copolymer) of sugar with following cationic charge density: greater than about 1.2meq/g, be preferably greater than about 1.5meq/g, more preferably greater than about 1.7meq/g even more preferably greater than about 1.8meq/g.The cationic charge density of cationic polymer usually less than about 5meq/g, preferably less than about 3.5meq/g, be more preferably less than about 2.5meq/g even be more preferably less than about 2.2meq/g.

" cationic charge density " of polymer refers to constitute the ratio of the molecular weight of positive charge number on the monomeric unit of polymer and described monomeric unit, that is:

Cationic charge density=positive charge number/monomeric unit molecular weight

The cationic charge density of the cationic polymer of this paper can use Kjeldahl method (American Pharmacopeia-test chemical＜461〉nitrogen determination-method II) to measure.At the pH value of the specific products that uses polymer, preferably satisfy under the condition of above-mentioned qualification to pH value, measure cationic charge density.

Such cationic saccharide base polymer comprises about 1% usually to about 10%, preferred about 2% to about 5%, more preferably from about 2.3% to about 3% even more preferably from about 2.5% cationic nitrogen to about 2.9% weight.

The mean molecule quantity normally about 5000 that is used for cation saccharide herein is to about 10,000,000, preferred about 100,000 to about 5,000,000, more preferably from about 500,000 to about 2,000,000 even more preferably from about 1,000,000 to about 1,500,000.

The cationic polysaccharide base polymer comprises the example of following indefiniteness: cationic cellulose and hydroxyethyl-cellulose, cationic starch and hetastarch.The example of the indefiniteness of suitable cationic polymers is can be from Amerchol Corp. (Edison, NJ, what USA) obtain is the salt of the epoxide reaction product of hydroxyethyl-cellulose and trimethyl ammonium replacement, and (CTFA) is called Polyquaternium 10 in industry.

Suitable cationic surfactants is described as above usually.

Compositions of the present invention can also comprise film forming polymer, i.e. sticky polymers.

The sticky polymers that exemplifies comprises polyvinylpyrrolidone (PVP), particularly poly N-vinyl pyrrolidone, the copolymer of the copolymer of PVP and methyl methacrylate, PVP and vinylacetate (VA) and polyvinyl alcohol (PVA).

The sticky polymers that exemplifies also comprises the copolymer of VA and .beta.-methylacrylic acid, methyl vinyl ether and maleic acid half ester are (for example, ethyl maleate and maleic acid butyl ester), hydroxypropyl cellulose, hydroxypropyl guar gum, poly styrene sulfonate, the polymer of acrylic acid polymer such as acrylic acid and methacrylic acid and copolymer, the ter-polymers of acrylic acid and/or methacrylic acid and acrylamide and/or vinylpyrrolidone copolymers and ter-polymers such as vinyl pyrrolidone/methyl methacrylate/methacrylic acid, the ter-polymers of vinyl pyrrolidone/ethyl methacrylate/methacrylic acid, the ter-polymers of tert-butyl group acrylamide/ethyl acrylate/acrylic acid ter-polymers and VA/ .beta.-methylacrylic acid/vinyl neodecanoate.

The example of other anion hair styling polymer is the vinyl acetate of the saturated mono carboxylic acid of aliphatic series of .beta.-methylacrylic acid and α-side chain such as the copolymer of vinyl neodecanoate and methyl vinyl ether and maleic anhydride (for example mol ratio is about 1: 1), and 50% usefulness comprises the radical of saturated aliphatic alcohol of 1-4 carbon atom as ethanol or esterified by butyl alcohol in wherein such copolymer; And comprise acrylic or methacrylic acid as the acrylic copolymer and the ter-polymers that contain the part of anion residue, as with the copolymer of butyl acrylate, ethyl methacrylate etc.

The polymer hair fixing copolymer also comprises amphiphilic polymers.An operable class amphiphilic polymers wherein is the acrylic resin that has cation and carboxyl.Example comprises the ter-polymers of octyl group acrylic amide/acrylic acid/butyl amino-ethyl methacrylate, the acrylic acid/copolymer of betanin methacrylate and the copolymer of octyl acrylamide/acrylate.

Also can use polysiloxane grafted adhesive copolymer, wherein be to contain silicone monomers and do not contain those of silicone monomers as already described, thereby the weight average molecular weight of described sticky agent comprises about 1 monomer that contains polysiloxanes to about 50% weight at least about 20000.

Suitable film forming polymer also comprises the sticky polymers that contains polysiloxanes.The preferred polymer of this class comprises organic main chain, particularly carbon backbone chain such as vinyl polymerization main chain, the polydimethylsiloxanemacromer macromer that also preferably will have following weight average molecular weight: at least about 500, preferred about 1000 to about 100000, more preferably from about 2000 to about 50000, most preferably from about 5000 to about 20000, is grafted on the main chain.Organic main chain of imagination comprises derived from those of polymerisable ethylenically unsaturated monomer.These comprise vinyl monomer, and other condensation monomer (for example, polymerization is to form those of polyamide and polyester) and open loop monomer (for example ethyl oxazoline and caprolactone).

The preferred polymerisable monomer (C monomer) that contains polysiloxanes can be exemplified by following general formula:

X (Y) _nSiR _3-mZ _mWherein X be can with the vinyl of A and B monomer copolymerization; Y is a divalent linker; R is hydrogen, hydroxyl, low alkyl group (for example C1-C4) aryl, alkaryl, alkoxyl or alkyl amino; Z is a number-average molecular weight at least about 500 monovalence siloxane polymerization part, under copolymerization conditions, do not react basically, and be above-mentioned vinyl polymerization main chain side group; N is 0 or 1; M is the integer of 1-3.

The example of spendable polymer and how to prepare them and be described in detail in JIUYUE in 1987 and authorized the United States Patent (USP) 4693935 of Mazurek on the 15th and authorized on March 1st, 1988 in people's such as Clemens the United States Patent (USP) 4728571, the present invention introduces above-mentioned two pieces of patents as a reference.

Suitable polymers also is disclosed in people's such as Hayama the EPO application 90307528.1 that is disclosed as EPO application 0408311A2 on January in 1991 11; Authorized people's such as Suzuki United States Patent (USP) 5061481 on October 29th, 1991, authorized people's such as Bolich United States Patent (USP) 5106609 on April 21st, 1992, authorized people's such as Bolich United States Patent (USP) 5100658 on March 31st, 1992, authorized people's such as Ansher-Jackson United States Patent (USP) 5100657 on March 31st, 1992, authorized people's such as Bolich United States Patent (USP) 5104646 and the U. S. application serial number of being submitted to by people such as Bolich on August 10th, 1,993 08/104232 on April 14th, 1992, all these the present invention are incorporated herein by reference.Preferably comprise tert-butyl acrylate and/or metering system tert-butyl acrylate and copolymer in these polymer with vinyl monomer of covalently bound polydimethylsiloxanemacromer macromer thereon.

Compositions of the present invention can comprise various other be suitable for make described compositions beauty treatment property or attractive in appearance more acceptable or make compositions have the optional components of additional use benefit.These conventional optional members are known to those of ordinary skills, for example opacifier such as polystyrene; Pearlescent additive such as diglycol stearate (it also is a kind of suspending agent, can be used for insoluble substance is suspended in the compositions), Muscovitum and Concha Margaritifera; Antiseptic such as benzylalcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate, imidazolidinyl urea; Thickening agent and viscosity modifier are as the diglycollic amide (for example PEG 3 lauric acid diethyl amides) of long-chain fatty acid, coconut monoethanol amide, starch and starch derivatives; Sodium chloride; Sodium sulfate; Polyvinyl alcohol; PH regulator agent such as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; Salt, generally for example potassium acetate and sodium chloride; Coloring agent such as FD﹠amp; C or D﹠amp; The C dyestuff; Hair oxidation (bleaching) agent is as hydrogen peroxide, perborate and persulfate; Hair Reducing agent such as thioglycolate salt; The hair dyestuff; Essence; Sequestering agent such as tetrasodium ethylenediamine tetraacetate; But sensory agent, as on being applied to hair the time with the chemical mode end that excites nerve, produce those materials of the change of hot and cold or other sensation, for example Camphora, menthol, the different pulegol of 1-, ethyl menthane formamide and trimethyl isopropyl butanamide, and other material, include but not limited to be disclosed in those of GB-B-1315626, GB-B-1404596 and GB-B-1411785 (the present invention introduces these as a reference); Antidandruff agent such as 2-mercaptopyridine zinc oxide (ZPT), Octopirox ethanolamine (piroctoneolamine), ketoconazole, Climbazole and salicylic acid; Antioxidant/UV filters agent such as octyl methoxycinnamate, benzophenone-3 and DL-alpha-tocopherol acetate and polymeric plasticizer such as glycerol, diisobutyl adipate, butyl stearate and propylene glycol.Usually these selectivity compositions use amount separately is about 0.01% to about 10.0%, preferred about 0.05% to about 5.0% of a composition weight.

The pH value of the present composition is usually between about 3 and about 9, preferably between about 4 and about 8.

For all compositionss, the present invention should not comprise those components of undue interference composition properties.

Hair care composition of the present invention can use common preparation and hybrid technology preparation.The example for preparing the method for various types of cosmetic compositions is described in greater detail among hereinafter the embodiment.

Can use the packing that is used for hair care composition of any routine, this discussed at preamble.The selection of spraying packing (comprising aerosol and non-aerosol) is in the known scope of hair spray field those of ordinary skill, and this hair spray packing will provide the required particle size distribution according to spray agent of the present invention.In addition, the aerosol hair spray agent can also be used a kind of propellant, and it can or split with compositions in packing with compositions blending of the present invention.The example of propellant includes, but not limited to trichlorine fluomethane, dichlorodifluoromethane, Difluoroethane, dimethyl ether, propane, normal butane or iso-butane.Can regulate the amount of propellant as required, but common consumption is about 5% to about 50% of an aerosol hair spray compositions weight.

Suitable spray container is being known in the art, and comprises conventional non-aerosol pump type sprayer, i.e. " aerosol apparatus ", have propellant aerosol container or jar, as indicated above, use the pump formula aerosol container of compressed air in addition as propellant.Pump formula aerosol container for example is disclosed in to be authorized in the United States Patent (USP) 4850577 of TerStege in United States Patent (USP) 4077441 and on July 25th, 1989 of authorizing Olofsson on March 7th, 1978, the present invention introduces two pieces of patents as a reference, and be disclosed in Gosselin on February 21st, 1992, Lund, in the U. S. application 07/839648 that Sojka and Lefebvre submit to, exercise question is " a consumer products packing of introducing the flusher that uses the major diameter bubble ".

Using method

Hair care composition of the present invention can conventional mode be administered on hair and the scalp, gloss of the present invention to be provided, to nurse one's health, have clean feel and salubrious benefit.This using method depends on the type of the compositions that is adopted, but be usually directed on hair or scalp, use the product of effective dose, with product on whole hair and the scalp or on its selected position, with hands or with being fit to use and/or the hair nursing apparatus of assign group compound, rub as comb, brush, nozzle, sponge or other device and touch.Preferably hair is arranged to user or hairdresser then and is wished the hair style or the form that obtain.In a preferred embodiment, compositions is a kind of disposable product, allow compositions to stay on the hair and become dry, and without flush away.But the usage that comprises the hair spray of viscosity hair fixing copolymer normally is sprayed onto compositions on the hair of being arranged to pre-hair fashioning, allows its exsiccation then, not rinsing." effective dose " is meant the amount that is enough to provide the hair gloss benefit.Compositions can be applied on dried or the wet hair.In the present invention, wet hair also comprises moist hair.Usually about 4 compositionss to about 20 grams are administered on hair and the scalp, but this tittle also can change the situation of selected purposes as only using at the specific part of hair and scalp according to the hobby of user or for selected purposes.

Experiment

The gloss meter direct reflection is measured through the following steps.

At 68 ℃, 10.0 gram gels (170 blooming) under agitation are dissolved in 83.0 gram DRO (two reverse osmosis) water preparation collagen solution.Next, 0.05 gram propyl p-hydroxybenzoate is dissolved in the gelatin solution.Then, adding the sodium hydroxide of 4.5 gram 1M, is the 3.0 gram Ceraphyl GA-D (mixture of the soybean oil of 10-15% soybean oil and the esterification of 85%-90% maleic acid then, can be from VanDyk Inc., Belleville, NJ, USA obtains), form a kind of emulsion of stable white.Next, in emulsion, stir adding 1.2 gram lactic acid, after this be called solution A.

In addition, separate packing, prepare the formalin in water of 3.0% weight, solution B with A solution.

Preparing on 7.3 centimetres of tops of about 7.3 cm x the average peak height (roughness) of black glaze is arranged is 5.0-7.0 micron (available Rodenstock RM600-2D/3-D measuring station (Rodenstock MeterologyMunich, W.Germany) porcelain tile mensuration) is coated with collagen albumen on their end face.The gloss meter direct reflection of the tile that collagen protein applies should be 8.0%-12.0%.

The direct reflection of the tile that collagen protein applies is to use gloss meter to measure measuring device such as BYK-Gardner " glimmering luster " gloss meter.Direct reflection is to measure under the situation of angle of incidence 60 degree according to ASTM method D 523.So the direct reflection of measuring is called as " gloss meter direct reflection " in the present invention.Being prepared as follows of tile.Syringe A is full of 3.0 milliliters solution A.Syringe B is full of 0.2 milliliter solution B.Material among the syringe B is turned on the top surface of tile.On the top surface of tile, the material among the syringe A is turned on the surface of B solution.With spatula solution is mixed 5 seconds kinds, uniform spreading on the surface of tile.Mix back 30 seconds kinds, the becket of 1.0 inches of internal diameters is placed on the top surface of tile.Allow dry 8 hours of collagen film.Remove becket.The roughness on the surface that the collagen protein of tile applies should be the 3.0-5.0 micron.

As mentioned above, in compatible diluent, prepare the mixture of polysiloxanes and spreading agent in 1.00% concentration, described polysiloxanes is corresponding with the amount of describing in compositions with the weight ratio of described spreading agent.On the tiled surface that collagen protein applies, use the mixture of 0.05 milliliter of syringe deposition, make its drying at ring area surrounded center.Measure the gloss meter direct reflection.

Embodiment

The following example further illustrates embodiment preferred in the scope of the invention.These embodiment provide just for illustrative purposes, are not to be used for limiting the present invention, under the situation that does not break away from aim of the present invention and scope, can carry out various changes to the present invention.

Pre-composition embodiment 1-6

Following is to can be used for various exemplary polysiloxane fluid of the present invention/spreading agent mixture.These mixture can be directly used in treatment of hair, perhaps, are more preferably as a kind of component and use in the hair care composition that comprises other beauty treatment or active constituents of medicine, carrier components or other composition.

Component (weight %)	Embodiment 1	Embodiment 2	Embodiment 3
Component (weight %)	Embodiment 1	Embodiment 2	Embodiment 3	Pentapheneyl trimethyl trisiloxanes (1)	57.00	?0.00	?50.00
Aminomethyl phenyl diphenyl siloxane copolymer (2)	38.00	?0.00	?0.00	Pentapheneyl trimethyl trisiloxanes (1)	57.00	?0.00	?50.00
Aminomethyl phenyl diphenyl siloxane copolymer (2)	38.00	?0.00	?0.00	Diphenyl dimethylsiloxane copolymer (3)	0.00	?45.00	?0.00
Polydimethylsiloxane (4)	0.00	?50.00	?0.00	Diphenyl dimethylsiloxane copolymer (3)	0.00	?45.00	?0.00
Polydimethylsiloxane (4)	0.00	?50.00	?0.00	MQ silicone resin/volatile cyclic polydimethylsiloxane (5)	5.00	?5.00	?0.00
Dimethicone copolyol (6)	0.00	?0.00	?50.00	MQ silicone resin/volatile cyclic polydimethylsiloxane (5)	5.00	?5.00	?0.00
Dimethicone copolyol (6)	0.00	?0.00	?50.00	Fluoro surfactants (7)	0.00	?1.00	?0.00
Annular dimethyl polysiloxane (8)	0.00	?0.00	?0.00	Fluoro surfactants (7)	0.00	?1.00	?0.00

Component (weight %)	Embodiment 4	Embodiment 5	Embodiment 6
Component (weight %)	Embodiment 4	Embodiment 5	Embodiment 6	Pentapheneyl trimethyl trisiloxanes (1)	99.00	?15.00	?27.00
Aminomethyl phenyl diphenyl siloxane copolymer (2)	0.00	?0.00	?12.00	Pentapheneyl trimethyl trisiloxanes (1)	99.00	?15.00	?27.00
Aminomethyl phenyl diphenyl siloxane copolymer (2)	0.00	?0.00	?12.00	Diphenyl dimethylsiloxane copolymer (3)	0.00	?0.00	?0.00
Polydimethylsiloxane (4)	0.00	?0.00	?0.00	Diphenyl dimethylsiloxane copolymer (3)	0.00	?0.00	?0.00
Polydimethylsiloxane (4)	0.00	?0.00	?0.00	MQ silicone resin/volatile cyclic polydimethylsiloxane (5)	0.00	?5.00	?5.00
Dimethicone copolyol (6)	0.00	?0.00	?0.00	MQ silicone resin/volatile cyclic polydimethylsiloxane (5)	0.00	?5.00	?5.00
Dimethicone copolyol (6)	0.00	?0.00	?0.00	Fluoro surfactants (7)	1.00	?0.00	?1.00
Annular dimethyl polysiloxane (8)	0.00	?80.00	?0.00	Fluoro surfactants (7)	1.00	?0.00	?1.00

1．Dow?Corning?705.Dow?Corning

2．PS162,Huls

3．SF1265,General?Electric

4．SE76,General?Electric

5.SS4320, General Electric (poly-trimethyl hydrogenation silicyl silicate/decamethylcyclopentaandoxane of 50%/50%)

6．Dow?Corning?190,Dow?Corning

7．FC-171?Fluorad,3M

8．Dow?Corning?344,Dow?Corning

Pre-composition is by preparing all the components blending half an hour approximately in room temperature with under stirring.

Following exemplary hair care composition can use any polysiloxane fluid/spreading agent pre-composition among the foregoing description 1-6 (hereinafter being called " silicone premix embodiment ") to be prepared.

Embodiment I-III

Following is the representative of non-washing type hair-treatment composition of the present invention.

Component	Embodiment 3 (weight %)
Component	Embodiment 3 (weight %)				????Ⅰ	????Ⅱ	????Ⅲ
Silicone premix	????4.5	????4.5	????4.5		????Ⅰ	????Ⅱ	????Ⅲ
Silicone premix	????4.5	????4.5	????4.5	Ethanol	????10.0	????50.0	????25.0
Diisobutyl adipate	????0.7	?????-	????-	Ethanol	????10.0	????50.0	????25.0
Diisobutyl adipate	????0.7	?????-	????-	Potassium hydroxide solution (45% concentration)	????1.0	????1.0	????1.0
Essence	????0.2	????0.2	????0.2	Potassium hydroxide solution (45% concentration)	????1.0	????1.0	????1.0
Essence	????0.2	????0.2	????0.2	Water	In right amount to 100%

This product is that silicone premix is dissolved in the ethanol, mixes several hours, prepares up to the whole dissolvings of pre-composition.If the use plasticizer then adds plasticizer then.Next add potassium hydroxide.If make water or water/surfactant, then add then.Add essence at last.All the components all is to add under condition of stirring.This product can flood and use or spray from aerosol or non-aerosol spray agent container, and the particle size distribution that is provided is at least 100 microns at least 40% particle grain size.

The embodiment IV

Following is the representative that hair of the present invention is modified the compositions of flooding.

Component	Weight %
Component	Weight %	Silicone premix	????0.70
Essence	????0.10	Silicone premix	????0.70
Essence	????0.10	Ethanol	????25.0
The PEG60 castor oil hydrogenated	????0.60	Ethanol	????25.0
The PEG60 castor oil hydrogenated	????0.60	Water	In right amount

Said composition is that the mode by routine mixes said components and prepares.

The embodiment V

The finalize the design representative of gel combination of the following the present invention of being.

Component	Weight %
Component	Weight %	Silicone premix	????2.00
Carbopol?940 ¹	????0.75	Silicone premix	????2.00
Carbopol?940 ¹	????0.75	Triethanolamine	????1.00
Dye solution	????0.05	Triethanolamine	????1.00
Dye solution	????0.05	Essence	????0.10
Laureth-23	????0.10	Essence	????0.10
Laureth-23	????0.10	Ethanol	????20.00
DRO water	In right amount	Ethanol	????20.00

1. crosslinked polyacrylic acid is from B.F.Goodrich.

This batch is that the mode by routine mixes said components and prepares.

The embodiment VI

Be prepared as follows the compositions of flooding of the present invention.

Component	Weight %
Component	Weight %	Silicone premix	????4.00
Water	????61.000	Silicone premix	????4.00
Water	????61.000	Ethanol	????35.000

At ambient temperature all compositions are all mixed, until polymer dissolution.

Embodiment VII-VIII

Composition (weight %)	VII (spray agent)	VIII (gel)
Composition (weight %)	VII (spray agent)	VIII (gel)		Carbopol?Ultrez?10 ¹	??????-	????0.50	????A
Carbopol?934 ²	??????-	?????-	????A	Carbopol?Ultrez?10 ¹	??????-	????0.50	????A
Carbopol?934 ²	??????-	?????-	????A	Polyquaternium?10 ³	????0.075	?????-	????A
Trisodium citrate	????0.70	????0.10	????A	Polyquaternium?10 ³	????0.075	?????-	????A
Trisodium citrate	????0.70	????0.10	????A	Ethanol (degeneration)	????25.00	????20.00	????B
The different pulegol of 1- ⁴	?????-	????0.20	????B	Ethanol (degeneration)	????25.00	????20.00	????B
The different pulegol of 1- ⁴	?????-	????0.20	????B	PEG 60 castor oil hydrogenated ⁵	????0.80	????0.10	????B
Lactic acid	????0.10	????0.02	????B	PEG 60 castor oil hydrogenated ⁵	????0.80	????0.10	????B
Lactic acid	????0.10	????0.02	????B	Phenyl phenol	????0.20	????0.30	????B
Essence	????0.10	????0.25	????B	Phenyl phenol	????0.20	????0.30	????B
Essence	????0.10	????0.25	????B	CI 42045 (Blue VRS)	?????-	????0.0001	????B
Triethanolamine	?????-	????0.30	????C	CI 42045 (Blue VRS)	?????-	????0.0001	????B
Triethanolamine	?????-	????0.30	????C	Polydimethylsiloxane ⁶	????0.20		????C
Silicone premix ⁷	????0.20	????1.00	????C	Polydimethylsiloxane ⁶	????0.20		????C
Silicone premix ⁷	????0.20	????1.00	????C	Water	In right amount	In right amount

1) Carbopol Ultrez 10, supplied by BF Goodrich

2) Carbopol 934, supplied by BF Goodrich

3) polymer JR30M is supplied by Amerchol

4) Coo1act P is supplied by Takasago

5) Cremophor RH-60 is supplied by BASF

6) DC200 is supplied by Dow Corning

7) any silicone premix of embodiment I-VI

Under environmental condition, all A compositions are added in the entry, thoroughly stir, until obtaining uniform solution.All B compositions are mixed, join then in the homogeneous solution of A composition.Add all C compositions then, thoroughly mix the solution of gained.

Embodiment IX-X

Form (weight %)	IX (cream)	X (balsam, Balm)
Form (weight %)	IX (cream)	X (balsam, Balm)		Carbopol?Ultrez?10 ¹	??????-	????0.40	?A
Acrylate/C10-30 alkyl acrylate cross-linked polymer ²	????0.60	??????-	?A	Carbopol?Ultrez?10 ¹	??????-	????0.40	?A
Acrylate/C10-30 alkyl acrylate cross-linked polymer ²	????0.60	??????-	?A	Cetyl alcohol ³	????1.00	??????-	?B
Stearyl alcohol	????1.00	????0.50	?B	Cetyl alcohol ³	????1.00	??????-	?B
Stearyl alcohol	????1.00	????0.50	?B	Ammonium lauryl sulfate ⁴	?????-	????0.20	?B
The PEG100 stearate ⁵	????0.13	??????-	?B	Ammonium lauryl sulfate ⁴	?????-	????0.20	?B
The PEG100 stearate ⁵	????0.13	??????-	?B	Polyquaternium?10 ⁶	??????-	????0.10	?C
Phenyl M ' Q resin ⁸	??????-	????0.10	?C	Polyquaternium?10 ⁶	??????-	????0.10	?C
Phenyl M ' Q resin ⁸	??????-	????0.10	?C	Silicone premix ⁸	????0.50	??????-	?C
Ethanol (degeneration)	????30.00	????15.00	?C	Silicone premix ⁸	????0.50	??????-	?C
Ethanol (degeneration)	????30.00	????15.00	?C	The different pulegol of 1- ⁷	????0.50	????0.05	?C
Lactic acid	????0.15	????0.10	?C	The different pulegol of 1- ⁷	????0.50	????0.05	?C
Lactic acid	????0.15	????0.10	?C	Phenyl phenol	????0.20	????0.20	?C
The DMDM hydantoin	?????-	????0.05	?C	Phenyl phenol	????0.20	????0.20	?C
The DMDM hydantoin	?????-	????0.05	?C	EDTA four sodium	?????-	????0.30	?C
Essence	????1.00	????0.80	?C	EDTA four sodium	?????-	????0.30	?C
Essence	????1.00	????0.80	?C	Triethanolamine	????0.40	????0.20	?D
Water	In right amount	In right amount		Triethanolamine	????0.40	????0.20	?D

1) Carbopol Ultrez 10, supplied by BF Goodrich

2) Pemulen TR2 is supplied by BF Goodrich

3) Crodacol C-95 is supplied by Croda Inc.

4) Empicol AL 30, by Albright ﹠amp; The Wilson supply

5) Myrj 59, supplied by ICI Surfactants

6) Polymer JR30M is supplied by Amerchol

7) Coolact P is supplied by Takasago

8) any silicone premix of embodiment I-VI

All A compositions are dissolved in the water, are heated to 80 ℃ then.Add all B compositions then., reflux solution is cooled to 30 ℃ simultaneously under the effect of high shear mixing by heat-exchangers of the plate type.Cooldown rate maintains 1.0-1.5 ℃ minute.Add about 50% D composition then, triethanolamine mixes solution until evenly.Next add all C compositions, with the solution high shear mixing of gained until obtaining uniform particle size distribution.Stop then refluxing, prevent shear stress in finishing and the time product had infringement.Add remaining D composition, until pH value that reaches regulation and viscosity.

All compositionss that exemplify all will provide good hair gloss, hair clean feel and salubrious sense, not have over-drastic dry scalp sense.

Claims

1. hair care product comprises:

(a) about 0.05% hair gloss agent to about 10% weight, it basic composition is following mixture:

(ⅰ) the non-volatile polysiloxane fluid of refraction index at least 1.46; With

(ⅱ) be used for described polysiloxane fluid and with the non-volatile spreading agent of described polysiloxane fluid blending and

(b) about 10% ethanol to about 50% weight;

(c) about 30% water to about 89.9% weight;

Wherein when described product is spray products, the particle diameter that described product produces at least 40% spray droplet is at least 100 microns spraying, and described hair care product is got rid of and is provided at the compositions that distributes when using as the mousse form.

2. the hair care product of claim 1, wherein said compositions comprises:

(a) about 0.05% described hair gloss agent to about 10% weight;

(b) about 10% described ethanol to about 50% weight;

(c) about 30% described water to about 89.8% weight;

(d) about 0.1% scalp conditioner to about 10% weight.

3. the described spreading agent that claim 1 or 2 hair care product, wherein said hair gloss agent comprise capacity with the surface tension that reduces polysiloxane fluid at least about 5%, preferably at least about 20%, more preferably at least about 25%.

4. each hair care product in the aforementioned claim, the refraction index at least 1.48 of wherein said non-volatile polysiloxane fluid, preferably at least 1.52, more preferably at least 1.55.

5. each hair care product in the aforementioned claim, wherein said spreading agent is a polyorganosiloxane resin, preferred MQ resin.

6. each hair care product in the aforementioned claim, the aryl substitution value at least 20% of wherein said non-volatile polysiloxane fluid, preferably at least 35%, more preferably at least 50%.

7. each hair care product in the aforementioned claim, wherein said compositions comprises about 15% ethanol to about 40% weight.

8. the hair care product of claim 12, wherein said compositions comprise about 18% to about 35%, preferred about 20% ethanol to about 30% weight.

9. each hair care product in the aforementioned claim comprises about 0.1% to about 5%, the preferred about 0.2% described hair gloss agent to about 2% weight.

10. each hair care composition among the claim 2-9, wherein said scalp conditioner is selected from emollient and wetting agent and combination thereof.

10. each hair care product in the aforementioned claim also comprises and is used to hold and the packing of the described compositions that distributes.

11. aforementioned each hair care product, wherein said product is the non-washing type product.

12. the hair care product of claim 10 or 11 also comprises by compositions is applied on the hair, allows it become dry, and need not using the explanation to the use compositions of post rinse hair.

13. providing, the hair care product of claim 12, wherein said explanation allow hair become dry and not rinsing.

14. each hair care product in the aforementioned claim, wherein when described product is spray product, the spraying that described product produces has at least 50%, preferably at least 70%, and more preferably at least 80% particle diameter is at least 100 microns a spray droplet.

15. one kind is brought gloss and makes the salubrious method of scalp to hair, comprises being administered on hair and the scalp from the compositions in each the hair care product of claim 1-14.

16. the method for claim 15, wherein said compositions is applied in whole hair and the scalp with hands or hair nursing instrument.

17. the method for claim 15 or 16, wherein said compositions is administered on the hair, allows described compositions to remain on the hair dry then and does not carry out rinsing.