CN1311293A - Moulded article products with ETPA base - Google Patents
Moulded article products with ETPA base Download PDFInfo
- Publication number
- CN1311293A CN1311293A CN00128306A CN00128306A CN1311293A CN 1311293 A CN1311293 A CN 1311293A CN 00128306 A CN00128306 A CN 00128306A CN 00128306 A CN00128306 A CN 00128306A CN 1311293 A CN1311293 A CN 1311293A
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- Prior art keywords
- molding
- decorative product
- ester
- transparent
- polar liquid
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Fats And Perfumes (AREA)
- Control And Other Processes For Unpacking Of Materials (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
A decorative product has at least one, but preferably many solid icons made of ester-terminated polyamide (ETPA) and low-polarity liquid such as mineral oil. A clear medium such as clear ETPA-based polymer, is around the icon. The medium may be in a clear jar and a wick may extend through the medium to form a candle.
Description
The present invention relates generally to ornamental household product such as candle and room freshener, and the present invention especially relates to and has the transparent weighting material that contains one or more solid shape or molding (icons) or the new and useful product of matrix.One of the present invention form preferably is a candle in glass pot, but described glass pot is the jar that simulates fruit or other identify objects.Fruit or other shape or molding are to make in order to the material of end capped polymeric amide of ester or ETPA base.
The United States Patent (USP) 5,338,187 of Elhara has disclosed a kind of solid wax chock plug that is positioned on the container top that contains easy fuel oil.The wick of wax stretches in the oil.
The United States Patent (USP) 4,427,366 of Moore has disclosed a kind of central match of the wax that is encased by the spices of content of wax thin slice, and all these things all are contained in the candle vessel of glass or pottery.
The United States Patent (USP) 5,693,277 of Widmer has disclosed on the flat sidewall of candle and has comprised the solid wax stone.
The United States Patent (USP) 4,826,428 of Lam has disclosed the candle that the little wax disk(-sc) composting of a kind of usefulness becomes.
The United States Patent (USP) 5,395,233 of Karp has disclosed the column candle of the match that a kind of clear wax shell that contains useful formation circular clearance encases.Potpourri and more transparent wax are filled in the circular clearance, are visible so that make potpourri.Match should be enough big, makes can not burn when match shell when burning.
Having the different colours skin is disclosed in the United States Patent (USP) 5,632,615 of DeGarmo with the candle that encases the mosaic of inner wax filler.
The United States Patent (USP) 5,597,300 of Wohl etc. has disclosed a kind of multilayer candle, and it contains the shell of being made by the high melting-point wax layer.The inner core of this candle is inflammable and can changes in the enclosure.Can in shell, form ornamental design.Molded outer layer is inserted candle inner core and wick in the shell subsequently, makes candle.
The United States Patent (USP) 4,855,098 of Taylor has disclosed a kind of candle composition, and it contains two kinds of paraffin and a spot of stretching tougheners with specific melting range.The stretching toughener is that a kind of fusing point is 120-130 polymkeric substance or a Microcrystalline Wax.
The United States Patent (USP) 4,568,270 of Marcus etc. has disclosed a kind of scented candle, and it contains the wax shell that encases the inner core that contains wick.Inner core is another kind of petroleum products, and it is a kind of and 5-12 weight % spices blended low melt wax or paraffin mutually.The wax shell is as the container that holds candle.
The United States Patent (USP) 5,578,089 of Elsamaloty has disclosed a kind of transparent candle of being made by the composition that comprises mineral oil and particular types mixed with polymers.Mineral oil and these mixed with polymers form the transparent polymer body that contains wick, and it burns as candle.
The United States Patent (USP) 4 of Schroder, 937,701 have disclosed a kind of security device that is used for burning candle, and described candle is made up of the outer transparent container that holds first kind of liquid such as water, the second kind of container that holds a small amount of cooling liqs and candle, and described outer transparent container encases second kind of container.
Guilfoil, the United States Patent (USP) 2,279,137 of Jr. has disclosed a kind of candle of making in transparent vessel, and described container contains rib to improve the combustionproperty of candle.
The non-wax material that is used to make candle also is known.Transfer Union Camp Corporation, Wayne, the United States Patent (USP) 5,783,657 of the Pavlin of New Jersey etc. has disclosed a kind of polymkeric substance of ETPA base, and it especially can be used as the substitute of wax.The polymkeric substance of ETPA base can be to burn with mode like the wax phase.To United States Patent (USP) 5,783, the composition of the manufacturing ETPA sill that discloses in 657 and the content of method at this with reference to quoting.ETPA also can trade mark UNICLEAR available from Union Camp Corporation.
A better example of the present invention comprises outer transparent jar such as mud crock, and it comprises the transparent ETPA polymkeric substance with fruit shape that is dispersed in the matrix or other also is ETPA base but the transparent base or the weighting material of painted molding.
The present invention also can be to contain ETPA base molding or only be the form of the transparent column candle of matrix, not have wick or other candle function, but have one or more molding to be scattered in wherein, thereby make family expenses, ornamental and/or perfumed product.
Adopt rubber or silicon moulding method to use and contain ETPA material manufacturing molding painted and other component.
Be with or without under the situation of wick, the solid molded thing is being placed in jar or the mould, adding the ETPA molten mixture then, making transparent base or weighting material.The top margin that too much wick is trimmed to the jar that all exists with jar and wick is equal.
In the present invention, term " fruit molding " is meant the molding of the fruit that comprises imitation, vegetables and other plant article that use ETPA moulding material is made.When independent use term " molding ", it refers to comprise any three dimensional shapes, and included not only have the fruit molding, and also have statuette, geometrical shape etc.
By some novel feature of the present invention, discovery the special formulation that is used for making the ETPA material of solid molded molding can be modulated into can jar or mould transparent, the coloured or colourless ETPA matrix of difference preparation or weighting material are poured on molding around, and can not make the molding distortion.
Another object of the present invention provides the method that a kind of manufacturing contains the product of ETPA base molding.
A further object of the present invention provides the product of a kind of ETPA of containing base molding, this product use can yes or no ETPA base solid or liquid filler material or matrix.
The various features of describing novelty of the present invention are sets forth in detail in appending claims all, and they have constituted the application's a part.In order to understand the present invention, its service advantages better and to use the specific purpose that can reach, can be with reference to the accompanying drawings and the description content that preferred embodiments of the present invention is described.
In the accompanying drawings:
Fig. 1 is the skeleton view of the improved pot type candle of the present invention, its lid be open and wick the burning;
Fig. 2 is the skeleton view similar with Fig. 1, but its lid is closed;
Fig. 3 is the sectional view of pot type candle of the present invention;
Fig. 4,5 and 6 is the sectional views in each step of shop drawings 3 candles; With
Fig. 7 is the skeleton view of another example of the present invention.
With reference to the accompanying drawings, be illustrated in the present invention includes among Fig. 1-3 and be labeled as 10 pot type candle usually, it comprises it better being the glass pot 12 of mud crock form, and this jar has dismountable glass cover 14, has around the lid neck or is not with rubber sealing 20.Lid among Fig. 1 is in open mode, and wick 24 burning constitute jar in the fuel of weighting material and molding.Fuel in jar is transparent weighting material 16 and molding 18.
The molding 18 that is depicted as forms of fruits or fruit shape can be made the different shape that comprises geometrical shape, statuette etc.Different shape all adopts rubber or silicon moulding method casting and uses and can make by incendiary ETPA base fuel.Like this, all inclusion finally all can exhaust by flame in the jar 12.
In the step of Fig. 5, the plastics U-shaped jig 30 that has wind spring 32 is used for supporting the top of the wick 24 that vertically is positioned at jar 12.
Weighting material 16 in the jar 12 is simulated the sweet dew around imitation fruit 18 or is looked and resembles fruit suspension in sweet dew.Weighting material 16 is polymkeric substance of ETPA base.
When genuine fruit is put into the process that begins to make the fruit molding when plate (not shown) is gone up.Then rubber or silicone compounds are poured on the fruit.This subassembly is placed in the vacuum vessel, vacuumizing from compound, this helps rubber to keep the profile and the structure of fruit.With dry in a vacuum several hours of this subassembly, make it aging then.Cut rubber then, therefrom take out fruit, make a mould.The ETPA sill that then will contain pigment is poured in the mould.Then,, make molding, again this molding is taken off from mould to solidify the ETPA material with this mold cools down.
The non-limitative example of fruit molding comprises orange, strawberry, raspberry, mixing berry, cucumber, muskmelon, apple and Chinese cassia tree branch shape.It is non exhaustive that this kind enumerated, because any other shape also is fine.Another example of the present invention can comprise plant molding such as flowers, branch, leaf etc., or any other shape.
Before disclosing detailed composition of the present invention and method, provide following big volume description earlier.
Be at least 18 weight %s extremely up to 65 weight %s available from Union Camp or its about the amount that the ETPA component of company exists with trade mark UNICLEAR 80 in molding part and weighting material or body portion, the ETPA component of this scope is also identical with top-pour layer (overpour layer) on the main weighting material top.The fragrance content of top-pour layer is higher, and its thickness is about 3-8 millimeter (about 15 gram liquid), thereby the fragrance of higher concentration can be provided when formerly opening container.In the ETPA mixture, also there is mineral oil, to improve combustioncharacteristics and also to reduce total expenses.Mineral oil in the style candle of the present invention makes people can use the wick of normal dia, but not people must adopt usually in the candle that uses UNICLEAR 80 materials separately to obtain the wick of suitable big or small flame.But other low polar liquid proxy-mineral oil.
Hexylene glycol also may reside in main weighting material and the top-pour layer with stabilization formulations.If preparation is exposed in the air, then owing to the migration of one or more components white dust may appear from the teeth outwards; And hexylene glycol can stop this migration.Hexylene glycol does not use in the molding preparation, because molding is not exposed in the air.The existence of hexylene glycol also can reduce stability of formulation, so it does not wish to adopt in the manufacturing processed of molding.In other words, hexylene glycol can make molding " become and stick with paste ", causes distortion in the demoulding and assembling process.Tetradecanoic acid also only is present in the weighting material, and is not present in the molding.Tetradecanoic acid may reside in main weighting material and the top-pour layer, becomes muddy and keeps it transparent to prevent weighting material.In molding, do not need tetradecanoic acid, because molding is opaque.In some example of the present invention, molding can be transparent, so also need some tetradecanoic acids in molding.
Capric acid/Trivent OCG is a lipid acid, and it is present in the weighting material preparation to reduce viscosity.This reduction can help following process in every way: preparation is flowed better; Make preparation " pliable and tough " (fluctuation to temperature more has recovery, makes the rimose possibility reduce to minimum) more around the molding in the Glass Containers; And by reducing fusing point improvement combustioncharacteristics.
Pigment only uses in molding, does not have pigment in weighting material.In weighting material and top-pour layer, use dyestuff, in molding, do not have dyestuff.Pigment in molding, uses pigment, because often more can resist " infiltration " weighting material on every side.This resistance is owing to the following fact, and promptly pigment is to disperse (insoluble) in medium, and dyestuff dissolving (solvable) is in medium.
Will be such as available from J﹠amp; The pigment of CM 65 RED of E Polish Co. adds in the molding material.This pigment predissolve is in Microcrystalline Wax, and described Microcrystalline Wax is to be melted in the softness in the molding material, low-melting sheet.In weighting material, use purple dye, as available from Clariant, the Violet FBL powder that is called SANDOPLAST of North Carolina, yellow and it is looked is colourless and transparent to offset it.
As mentioned above, add the viscosity that hexylene glycol is regulated weighting material,, and avoid when thermal expansion, deforming and when lighted candle, shrinking so that weighting material has kindliness.Weighting material also can adapt to the variation of molding shape and size like this.Equally, if molding cracking, little when then it ftractures than weighting material to the destruction of outward appearance.Can use other glycols or viscosity modifier to replace hexylene glycol.
Another scheme of the present invention comprises that wax or other material are in the column candle at center, and wherein molding and weighting material are around the column candle and place jar or mould.Yet, when the ETPA material is heat, the existence of the wax fragment of any paraffinic base, weighting material becomes muddy at once in the time of all can making this fragment fusion.The size of fragment is for making the size of its Flashmelt, and the paraffin core still is that the paraffin molding can not produce because the problem that its surface-area difference is produced.Be just as will be described, weighting material is in about 70-90 ℃ temperature, and it is added in the mould or jar that contains the preliminary shaping molding, and described preliminary shaping molding has been solid and has placed this mould or container.
Take another look at the method for making weighting material, behind the adding spices, stir, add dyestuff again.Find it 5 hours was the maximum duration that allows spices and dyestuff are mixed and send into container.If do not finish filling step at this moment, then weighting material can yellowing.Yet very fast the sclerosis so importantly added the top-pour layer in about 5-8 minute, but this interpolation only carries out after bottom or main weighting material have hardened, is in the top to guarantee the top-pour layer.Jig 30,32 among Fig. 5 is supporting center and the vertical wick of placing, so that molding and weighting material can be added in jar or the mould, and wick is moved.
In filling step, heating tank or mould.Find that this will help avoid the bubble between the outside surface of the internal surface of glass or moulding stock and weighting material.
Other weighting material also can use with the ETPA molding.Weighting material can be a liquid.It for example can be mineral oil or water.Weighting material must be compatible with mechanical system with chemistry with molding.In other words, weighting material must can not dissolve, be out of shape, twist or damage molding or make its painted or from molding bleed.
Form
During the composition of molding, transparent or main weighting material and top-pour layer is listed in the table below.
Table 1-molding
Table 2-master weighting material
Table 3-top-pour layer
| Component UNICLEAR 80 ETPA mineral oil #7 capric acid/Trivent OCG myristic acid hexylene glycol spices pigment dye | % by weight 52.75 44.74 0.00 0.00 0.00 2.50 0.01 0.00 preferably | Scope (% by weight) the 18-65 35-82 000 0.1-12.0 0-1 0 that allow |
| Component UNICLEAR 80 ETPA mineral oil #7 capric acid/Trivent OCG myristic acid hexylene glycol spices pigment dye | % by weight 31.25 37.25 25.00 2.00 2.00 2.50 0 0.01 preferably | Scope (% by weight) 18-65 20-75 0-35 0-7 0-7 0-12 0 0-1 that allows |
| Component UNICLEAR 80 ETPA mineral oil #7 capric acid/Trivent OCG myristic acid hexylene glycol spices pigment dye | % by weight 29.91 35.65 23.92 1.91 1.91 6.70 0.00 0.01 preferably | Scope (% by weight) 18-65 20-75 0-35 0-7 0-7 0-12 0 0-1 that allows |
In the better form of candle jar of the present invention, use 1 pound of material (453.59 gram).Like this, can be half spices in molding, half spices is in weighting material, and the inclusion of jar half weight is a molding, second half is weighting material (comprising main weighting material and top-pour layer).Like this, the top-pour layer has 15 grams, and remaining weighting material component is main weighting material.
The manufacturing processed of molding
The method of making fragrant molding is as follows:
In mixing kettle, mineral oil is heated to 90-100 ℃.Add UNICLEAR 80 ETPA, melt fully up to it.In mixing tank, begin to stir, up to mixing.Controlled temperature is 90-95 ℃.Add spices, stir up to mixing.Add pigment, mix even up to integral body.Temperature is remained on 85-90 ℃, to avoid any whole decolouring and to keep the complete of fragrance.
The manufacturing processed of transparent and top-pour layer
It is as follows to make method transparent or main weighting material:
In mixing tank, mineral oil is heated to 90-100 ℃.Add UNICLEAR 80 ETPA, melt fully up to it.Begin to stir, up to mix and product transparent.Controlled temperature is 90-95 ℃.Add triglyceride level, tetradecanoic acid and hexylene glycol.Temperature is remained on 85-90 ℃, to avoid any whole decolouring.Stirring is up to mixing and transparent.
Add spices and stirring,, add dyestuff up to mixing.This filling mixt is remained on 70-90 ℃, after with the molding tank filling, this mixture poured in the jar on the molding.When making free-standing product (free standing product), replace jar with mould.For stand alone type or " column " product, weighting material is to use the prescription more similar to the molding prescription to make, and promptly without components of triglycerides and tetradecanoic acid component, but adopts the hexylene glycol component.
Make the top-pour layer by identical process, different is to increase the perfume composition that adds, and reduces ETPA and mineral oil component.
Although in the better example of molding and weighting material, use mineral oil, can use as United States Patent (USP) 5,783 any other hydrocarbon or other non-aqueous liquid disclosed in 657.This component is commonly referred to load-polar liquid (load-polarity liquid), and this kind title is at United States Patent (USP) 5,783, the used general call to this component in 657.
The manufacturing processed of candle jar
The method of making candle shown in Figure 1 is as follows:
Bottom with heelpiece (as label, not shown) is applied to jar is glued to pad with the metal clip 22 that is fixed on wick 24 lower ends and goes up (Fig. 4).Support or jig 30 are placed on the opening of bottle, use the spring 32 that is hooked between the spring coil to tie the upper end of wick 24.To be shaped in advance then and hardened molding 18 drop into wick in jars 12 around, and jig 30 (Fig. 5) still in position.
The jar that will contain molding and wick then is placed on and is heated to about 65 ℃ in the hot drying tunnel.Then under about 70-90 ℃ temperature, will lead or transparent weighting material is poured in the jar, up to as shown in Figure 6 near jar open top.Subsequently, make main weighting material cooling and sclerosis, the fusion top-pour layer that flavour content is higher is poured on the main weighting material.
Remove wick supporting rack, the cutting wick applies pressure ring, loads onto lid, closes jar (Fig. 2).
In a kind of replacement situation of the present invention, use identical technology, but replace jar, and do not have wick with mould.Be put in the mould to a molding of making by above-mentioned composition few, mould can be little chest or square, so just can make product shown in Figure 7.Can use any mold shape and any molding shape.
Another is replaced example and is to use outer transparent container, ETPA base molding and liquid filler material.
An example that can be used as the non-ETPA based polyalcohol of the weighting material among Fig. 7 is disclosed in and transfers Bath﹠amp; Body Works is in the United States Patent (USP) 5,679,334 that is entitled as " gel air freshener and manufacture method thereof (GEL AIR FRESHENERAND MAKING THE SAME) " of Inc..This Patent publish a kind of fragrant and transparent polymkeric substance, this polymkeric substance is compatible with the basic molding of mechanical system and ETPA and can be used for making the product that is used as ornamental air freshener shown in Figure 7 with chemistry.
Like this, the simplest form of the present invention is a kind of decorative product, and it comprises and is used to make the ester-terminated polyamide of solid molded thing and the composition and the transparent medium around molding of low polar liquid.Transparent medium can be solid such as above-mentioned polymkeric substance, can be liquid maybe, and may simply be the water in container, better is transparent one or more molding of described water in liquid.Molding even can be floating matter in liquid.Perhaps, transparent medium can have other structure, as has the column candle of preferable combustioncharacteristics (if it is made with paraffin), and the transparent medium that this column candle is contained one or more ETPA base molding surrounds.
Although illustrated and described in detail particular instance of the present invention already principle application of the present invention was described, what should understand is can otherwise realize the present invention under the situation that does not depart from this principle.
Claims (24)
1. decorative product, it comprises:
At least a solid molded thing made from end capped polymeric amide of ester and low polar liquid; With
Transparent medium around molding.
2. decorative product as claimed in claim 1, wherein transparent medium is the polymkeric substance and the low polar liquid of the end capped polymeric amide of a kind of ester.
3. decorative product as claimed in claim 1, it comprises many described molding in transparent medium.
4. decorative product as claimed in claim 1, it comprises the transparent vessel that encases transparent medium.
5. decorative product as claimed in claim 1, it comprises and is used for burning fuel that comprises molding and the wick that extends at transparent medium.
6. decorative product as claimed in claim 5, it comprises the transparent vessel that encases transparent medium.
7. decorative product as claimed in claim 6, wherein transparent medium is the polymkeric substance and the low polar liquid of the end capped polymeric amide of a kind of ester.
8. decorative product as claimed in claim 1, wherein molding comprises spices and pigment.
9. decorative product as claimed in claim 8, wherein transparent medium is the polymkeric substance of the end capped polymeric amide of a kind of ester, low polar liquid, lipid acid and spices.
10. decorative product as claimed in claim 9, its medium are included in and extend in the medium with wick that forms candle and the transparent vessel that encases transparent medium.
11. decorative product as claimed in claim 10, wherein molding and medium comprise the end capped polymeric amide of ester of about 18-65 weight % respectively.
12. decorative product as claimed in claim 11, wherein low polar liquid is mineral oil, and its amount in molding and medium is about 30-85 weight %.
13. decorative product as claimed in claim 1, wherein molding comprises spices and pigment, and it is a kind of fruit molding.
14. decorative product as claimed in claim 2, wherein the polymkeric substance of the ester-terminated polyamide of transparent medium and low polar liquid also comprise triglyceride level, two pure and mild acid.
15. a decorative product, it comprises:
At least a solid molded thing; With
The transparent medium made from end capped polymeric amide of ester and low polar liquid around the molding.
16. decorative product as claimed in claim 15, wherein transparent medium comprises the wick of the transparent medium that is used to burn, low polar liquid, lipid acid and spices.
17. decorative product as claimed in claim 16, wherein molding is made by wax, and can burn it with wick.
18. a method of making decorative product, it comprises:
At least one solid molded thing of mixture casting from end capped polymeric amide of ester and low polar liquid;
This molding is placed in the container;
Form the hot filling mixt of end capped polymeric amide of ester and low polar liquid;
Hot filling mixt is poured in the container to encase molding; With
Allow filling mixt cool off, make product.
19. method as claimed in claim 18, wherein low polar liquid is mineral oil, and this method comprises heating mineral oil, and the end capped polymeric amide of ester is added in the hot mineral oil, is formed for the mixture of casting molding and forms filling mixt.
20. method as claimed in claim 19, it comprises takes out decorative product from container, and this container forms a mould.
21. method as claimed in claim 19, it comprises provides transparent vessel as container, and decorative product comprises this transparent vessel.
22. method as claimed in claim 19, it comprises wick is placed in the container, afterwards filling mixt is added in the container, is made as the candle of decorative product.
23. method as claimed in claim 18, it comprises the temperature that filling mixt is heated to about 70-90 ℃, is poured into afterwards in the container that encases molding.
24. method as claimed in claim 23, it is included in and adds lipid acid in the filling mixt, in filling mixt and molding, add spices and in molding, add pigment, after this method is included in the filling mixt cooling of addressing for the first time, the top-pour layer mixture of end capped polymeric amide of ester and low polar liquid is applied on the filling mixt of addressing for the first time, and the flavour content of top-pour layer mixture is than the content height of spices in the filling mixt of addressing for the first time.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/516,140 | 2000-03-01 | ||
| US09/516,140 US6214063B1 (en) | 2000-03-01 | 2000-03-01 | Products with ETPA-based icons |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1311293A true CN1311293A (en) | 2001-09-05 |
| CN1234830C CN1234830C (en) | 2006-01-04 |
Family
ID=24054295
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB001283065A Expired - Lifetime CN1234830C (en) | 2000-03-01 | 2000-11-10 | Moulded article products with ETPA base |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US6214063B1 (en) |
| KR (1) | KR100377634B1 (en) |
| CN (1) | CN1234830C (en) |
| CA (1) | CA2330501C (en) |
| FR (1) | FR2808281A1 (en) |
| GB (1) | GB2359821A (en) |
| IT (1) | ITMI20010396A1 (en) |
| MX (1) | MXPA01001366A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102021083A (en) * | 2010-08-11 | 2011-04-20 | 青岛金王应用化学股份有限公司 | Method for making bubble-free fruit wax |
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| US7922482B2 (en) * | 2000-12-22 | 2011-04-12 | S.C. Johnson & Son, Inc. | Candle and wick holder therefor |
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| US6552160B2 (en) | 2001-05-14 | 2003-04-22 | Arizona Chemical Company | Ester-terminated poly(ester-amides) useful for formulating transparent gels in low polarity fluids |
| US6669468B2 (en) * | 2001-09-28 | 2003-12-30 | Bath & Body Works, Inc. | Candle with polyethersulfone barrier |
| US20030126788A1 (en) * | 2001-11-07 | 2003-07-10 | Colloid Tech. Inc. | Storage stable translucent flammable article |
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-
2000
- 2000-03-01 US US09/516,140 patent/US6214063B1/en not_active Expired - Lifetime
- 2000-10-25 KR KR10-2000-0063068A patent/KR100377634B1/en not_active IP Right Cessation
- 2000-11-10 CN CNB001283065A patent/CN1234830C/en not_active Expired - Lifetime
-
2001
- 2001-01-09 CA CA002330501A patent/CA2330501C/en not_active Expired - Lifetime
- 2001-01-12 US US09/759,121 patent/US20010029696A1/en not_active Abandoned
- 2001-01-29 FR FR0101150A patent/FR2808281A1/en active Pending
- 2001-02-06 MX MXPA01001366A patent/MXPA01001366A/en unknown
- 2001-02-16 GB GB0103822A patent/GB2359821A/en not_active Withdrawn
- 2001-02-27 IT IT2001MI000396A patent/ITMI20010396A1/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102021083A (en) * | 2010-08-11 | 2011-04-20 | 青岛金王应用化学股份有限公司 | Method for making bubble-free fruit wax |
| CN102021083B (en) * | 2010-08-11 | 2013-04-24 | 青岛金王应用化学股份有限公司 | Method for making bubble-free fruit wax |
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA01001366A (en) | 2002-08-06 |
| CA2330501A1 (en) | 2001-09-01 |
| GB0103822D0 (en) | 2001-04-04 |
| GB2359821A (en) | 2001-09-05 |
| KR100377634B1 (en) | 2003-03-29 |
| US20010029696A1 (en) | 2001-10-18 |
| ITMI20010396A1 (en) | 2002-08-27 |
| US6214063B1 (en) | 2001-04-10 |
| CN1234830C (en) | 2006-01-04 |
| KR20010087127A (en) | 2001-09-15 |
| FR2808281A1 (en) | 2001-11-02 |
| CA2330501C (en) | 2006-12-12 |
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| C14 | Grant of patent or utility model | ||
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| ASS | Succession or assignment of patent right |
Owner name: BEAUTIFUL AVENUE CO., LTD. Free format text: FORMER OWNER: WASHING AND BODY PLANT CO., LTD. Effective date: 20130719 |
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