CN1309188A - Steel - Google Patents

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Publication number
CN1309188A
CN1309188A CN01102939A CN01102939A CN1309188A CN 1309188 A CN1309188 A CN 1309188A CN 01102939 A CN01102939 A CN 01102939A CN 01102939 A CN01102939 A CN 01102939A CN 1309188 A CN1309188 A CN 1309188A
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steel
tempering
maximum
melting
temperature
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CN01102939A
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CN1124360C (en
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R·勒帕嫩
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Ovako Steel AB
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Ovako Steel AB
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C21D1/25—Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

A chain type steel, suitable for the production of bars with a diameter of up to about 160 mm, e.g. to be used for the manufacture of heavy anchor chains, comprising, in weight-%: C 0.15 - 0.23 Si 0.10 - 0.40 Mn 1.00 - 1.50 P max. 0.025 S max. 0.025 Cr 1.50 - 2.20 Ni 0.80 - 1.50 Mo 0.30 - 0.60 Cu max. 0.30 Al < 0.2 V < 0.2 Nb < 0.2 Ti < 0.2, and the balance being Fe.

Description

A kind of steel
The present invention relates to a kind of steel, more especially a kind of chain steel (chaim type steel) is suitable for producing the most about 160mm bar of diameter product, for example, is used to make heavy anchor chain.
For many years, the artificial heavy anchor chain that is mainly used in the grappling oil platform of making of application provides bar.The diameter of the bar size of paying is up to 155mm.For coarse size, used the very low steel of a kind of carbon content, but it to melting equipment very high request is proposed, caused the many difficult problems of steel mill.The steel grade that is used for the small size anchor chain is a low alloy steel, does not possess the above required mechanical property of large size anchor chain of the about 130mm of diameter of rod.
Therefore need a kind of improved steel that is used to make heavy anchor chain, it has more excellent performance in steel mill.
For example in GB2 110 239A, a kind of steel that is used to produce anchor chain with following composition with weight percent (wt%) expression: C0.03-0.07 is disclosed; Si0.10-1; Mn1.2-2.5; Cr1.8-3; Ni1.5-3; Mo≤0.5; Nb, V, Ti total amount 0-0.10.This steel it is said the yield-point of 600MPa at least, the impelling strength that the breaking limit of 900MPa is at least arranged and have at least 40 joules during at-20 ℃ in room temperature.To the restriction of the chain steel of Yu Haiyang PetroChina Company Limited. production platform even strict more, thereby need a kind of steel that improves performance that have.
Via JP-61276956, in the past with regard to the known low-alloy hinge steel that contains chromium and nickel that can obtain tempered martensite through processing.Represent that with weight percent this ladle is drawn together: C0.20-0.30; Si0.10-0.30; Mn0.70-1.70; Cr0.40-0.70; Ni0.75-2.00; Al0.01-0.05; P≤0.03; S≤0.030.This steel quench or by the surface hardening of carburizing means after tempering so that make the microstructure tempering become martensite.In the higher zone of carbon content scope, weldability and toughness degenerate simultaneously, and the danger of quenching crack is arranged.Do not contain the danger that Mo means temper brittleness.Ni is used to remedy low chromium content, and this can make this steel become very expensive.
Via JP-52006847B, in the past with regard to known high-strength low-alloy steel chain by the rod iron preparation, this rod iron was represented to comprise with weight percentage: C0.1-0.2; Si0.1-0.5; Mn1.0-1.6; Cu0.1-0.5; Ni0.5-1.5; Cr0.30-1.0; Mo0.2-0.8; P＜0.03; S＞0.015 and acid-soluble Al0.02-0.1.Initial rod iron has high tensile strength, weldability of having improved and good workability, and also the steel chain of producing is 550-680 ℃ of tempering.Low Cr and low C content have all influenced hardening capacity, and this is deleterious to large-sized anchor chain.
The purpose of this invention is to provide the steel that a kind of mechanical property is improved and its behavior is improved in steel mill.
Adopt steel of the present invention to reach this purpose, represent that with weight percentage this ladle draws together:
C??0.15-0.23
Si?0.10-0.40
Mn?1.00-1.50
P maximum 0.025
S maximum 0.025
Cr?1.50-2.20
Ni?0.80-1.50
Mo?0.30-0.60
Cu maximum 0.30
Al?＜0.2
V??＜0.2
Nb?＜0.2
Ti?＜0.2
By the iron trim.
Embodiment according to steel of the present invention has required rights protection in subclaim requires.
Fig. 1 has shown the hardness of specimen material of laboratory melting and the graph of a relation of tempering temperature.
Fig. 2 has shown specimen material quenching back and the hardness of untempered sample and the graph of a relation of the surperficial following degree of depth of said laboratory melting.
Fig. 3 shown the specimen material of said laboratory melting quench back and tempering the hardness of sample and the graph of a relation of the surperficial following degree of depth.
Fig. 4 has shown the terminal hardening capacity figure of the specimen material of said laboratory melting.
Fig. 5 has shown the terminal hardening capacity figure of the material of full-scale melting.
Grade of steel according to the present invention be used to prepare have diameter the most about 160mm so-called K4 hinge and melting equipment do not had erosion, and this steel can obtain the extraordinary hinge finished product of quality.
As test, the chamber melting prepares the specimen material that steel ingot is of a size of 225 * 225mm by experiment.Corresponding steel ingot is swaged into the bar of diameter 140mm.This compression ratio that obtains is approximately 3, and it is not enough for ordinary production.The result who this means ordinary production can significantly be better than the test-results of discussing in the following specification sheets.
Having produced the test sample of two kinds of heterogeneities, is respectively MnCrNiMo mutation and MnCrNiMoV.
According to steel of the present invention, through after the through hardening, surface hardness and core rigidities have very little difference.
In the table I, provided the analytical results of two kinds of different steel samples.
The table I
Modification C ?Si ?Mn P ?S ?Cr ?Ni ?Mo ?Cu ?V ?Al
?MnCrNiMo ?No.129 ?0.20 ?0.30 ?1.26 ?0.008 ?0.004 ?1.80 ?1.25 ?0.45 ?0.19 ?0.022
?MnCrNiMoV ?No.131 ?0.19 ?0.24 ?1.10 ?0.007 ?0.003 ??1.78 ?1.20 ?0.33 ?0.18 ?0.10 ?0.024
Analyze this two kinds of steel samples according to the following stated.1 tempering
Fig. 1 has shown the relation of tempering hardness and tempering temperature after 1 hour.The quenching temperature of corresponding melting thing is 850 ℃ for melting thing No.129 and is 890 ℃ for melting thing No.131.Sample size is 25 * 25 * 25mm.
As can be seen from Figure 1, melting thing No.129 has showed a horizontal curve of breakpoint continuously, and this makes it insensitive to temperature variation in the tempering temperature fluctuation zone.For melting thing No.131, vanadium has caused that strong anti-tempering characteristics is being arranged below 630 ℃, but obtains a precipitous curve that temperature variation is had strong sensitivity at higher temperature.2 through hardening
Fig. 2 has shown the hardness of untempered quenching sample of diameter 140mm with the variation of the following degree of depth in surface, and Fig. 3 has shown that melting thing No.129 is 615 ℃ and the hardness of melting thing No.131 after 645 ℃ of tempering.
The quenching temperature of melting thing No.129 is 850 ℃, and melting thing No.131 is 890 ℃, all is shrend.
As what confirmed among the figure, tempering or untempered sample melting thing No.129 have all been shown best through hardening result.The surface is very little with the difference of hardness at center.3 end quenchings
Fig. 4 has shown the result of jominy end quench test.Austenitizing temperature is with identical according to the temperature of above the 2nd through hardening test.
End quenching humid test result is with very identical according to the 2nd through hardening result.Melting thing No.129 has best hardening capacity.4 mechanical propertys
The following table II has shown the quenching of bar sample of diameter 140mm and the mechanical property after the tempering.Convention according to normal hinge material test is taken a sample and thermal treatment.In hardenability test and backfire test, shown that the melting thing No.129 of best result has passed through the inspection of three different tempering temperatures.The table II
Mechanical property
The melting thing Quenching temperature ℃ Tempering temperature ℃ ?Rel ?MPa ????Rm ????MPa ????A5 ????％ ????Z ????％ ????KV,J
-40℃ -20℃ ±0℃
????129 ????850 ????615 ?822 ?917 ?17 ?63 ?83 ????134 ????138
????590 ?857 ?937 ?16 ?72 ?89 ????101 ????142
????570 ?923 ?992 ?15 ?67 ?108 ????102 ????123
?131 ?890 ????645 ?896 ?963 ?17 ?64 ????99 ????122 ????126
Requirement according to DNV 580 ?860 ?12 ?50 ????50 ????70
These two kinds of melting things have shown very similar result.The minimum tempering temperature that is allowed according to NDV (Net NorskeVeritas) K4 hinge is 570 ℃.II confirmed as table, and this requirement can not cause any problem, but did not allow any essence of alloying element to reduce simultaneously.
Approach the requirement of NDV-20 ℃ impelling strength, but only be 3, and produce will have an appointment 12 percentage reduction of area of medium casting, thereby this performance can be significantly increased the percentage reduction of area of melting matter sample.5 tests according to the full-scale product melting thing criterion of NDV approval
Burden analysis to φ 160mm bar product:
C ?Si ?Mn ?P ?S ?Cr ?Ni ?Mo ?Cu
?0.19 ?0.26 ?1.19 ?0.008 ?0.009 ?1.75 ?1.18 ?0.44 ?0.14
Al ?Sn ?Sb(ppm) As ?B(ppm) O(ppm) N(ppm)
0.015 ?0.007 ?2 ?0.008 ≤1 ?9.8 ?72
The austenitizing temperature austenitizing that the thermal treatment sensitivity analysis changes 30 minutes, 610 ℃ of cold quenching tempering, 60 minutes, water-cooled after the tempering
Sample number into spectrum Austenitizing temperature ℃ ?ReI ?MPa ?Rm ?MPa ?A5 ％ Z ％ KV-20℃ J
?1 ?840 ?890 ?958 ?18 ?70 Surpass 147*
2 ?870 ?879 ?957 ?17 ?71 Surpass 147*
3 ?910 ?879 ?957 ?18 ?72 Surpass 147*
* the tempering temperature austenitizing of the ultimate load thermal treatment sensitivity analysis of testing installation variation is 870 ℃, and 30 minutes, cold quenching tempering 60 minutes, water-cooled after the tempering
Sample number into spectrum Tempering temperature ℃ ?ReI ?MPa ?Rm ?MPa A5 ％ Z ％ KV-20℃ J
6 ?570 ?991 ?1057 ?16 ?67 Surpass 147*
7 ?590 ?925 ?999 ?17 ?69 Surpass 147*
2 ?610 ?879 ?957 ?17 ?71 Surpass 147*
8 ?630 ?838 ?914 ?20 ?72 Surpass 147*
9 ?650 ?782 ?858 ?21 ?73 Surpass 147*
* the tempering time austenitizing of the ultimate load thermal treatment sensitivity analysis of testing installation variation is 870 ℃, and 30 minutes, 610 ℃ of cold quenching tempering, water-cooled after the tempering
Sample number into spectrum Tempering time, minute ?ReI ?MPa ?Rm ?MPa ?A5 ％ Z ％ KV-20℃ J
?4 ?30 ?890 ?958 ?18 ?70 Surpass 147*
?2 ?60 ?879 ?957 ?17 ?71 Surpass 147*
?5 ?90 ?869 ?941 ?18 ?74 Surpass 147*
* the tempering postcooling speed austenitizing of the ultimate load temper brittleness of testing installation test variation is 870 ℃, and 30 minutes, 610 ℃ of the back water-cooled tempering of quenching, 60 minutes
Sample number into spectrum The tempering postcooling KV-0℃ J ?KV-20℃ ?J ?KV-40℃ ?J
?2 Water 147* 147* 147*
2L By 300 ℃＞40 minutes 147* 147* 147*
* the ultimate load of testing installation
Shrinkage degree approximately is 12 times, this facts explain compare different significantly on the performance with the laboratory test material, the laboratory test material only has and is approximately 3 times shrinkage degree, but still has improvement compared with prior art.

Claims (5)

1. hinge formula steel is suitable for producing the bar of the most about 160mm of diameter, for example, is used to make heavy anchor chain, comprises with weight percent (weight %) expression:
C??0.15-0.23
Si?0.10-0.40
Mn?1.00-1.50
P maximum 0.025
S maximum 0.025
Cr?1.50-2.20
Ni?0.80-1.50
Mo?0.30-0.60
Cu maximum 0.30
Al?＜0.2
V??＜0.2
Nb?＜0.2
Ti?＜0.2
By the iron trim.
2. according to the chain steel of claim 1, represent to comprise with weight percentage:
C??0.19-0.21
Si?0.20-0.30
Mn?1.15-1.25
P maximum 0.015
S maximum 0.020
Cr?1.65-1.75
Ni?1.15-1.25
Mo?0.42-0.48
Cu maximum 0.25
Al?＜0.2
V?????＜0.2
Nb????＜0.2
Ti????＜0.2
By the iron trim.
3. according to the chain steel of claim 2, represent to comprise with weight percentage:
C??0.18-0.20
Si?0.20-0.30
Mn?1.15-1.25
P maximum 0.015
S maximum 0.020
Cr?1.65-1.75
Ni?1.15-1.25
Mo?0.30-0.36
Cu maximum 0.25
V??0.10-0.14
Al?＜0.2
Nb?＜0.2
Ti?＜0.2
By the iron trim.
4. according to the chain steel of claim 2, quench and 615 ℃ of tempering at 850 ℃.
5. according to the chain steel of claim 3, quench and more than 630 ℃, preferably 645 ℃ of tempering at 890 ℃.
CN01102939A 2000-02-14 2001-02-13 Steel Expired - Fee Related CN1124360C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE0000458A SE515623C2 (en) 2000-02-14 2000-02-14 chains Steel
SE00004580 2000-02-14

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CN1309188A true CN1309188A (en) 2001-08-22
CN1124360C CN1124360C (en) 2003-10-15

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US (1) US20010024621A1 (en)
EP (1) EP1126042A1 (en)
JP (1) JP2001247933A (en)
CN (1) CN1124360C (en)
SE (1) SE515623C2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106222574A (en) * 2016-08-24 2016-12-14 宁波乾豪金属制品有限公司 A kind of corrosion resistant spring suspension

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MXPA05002433A (en) 2002-09-04 2005-05-27 Intermet Corp Austempered cast iron article and a method of making the same.
JP2007289979A (en) * 2006-04-23 2007-11-08 Sanyo Special Steel Co Ltd Method for producing cast slab or steel ingot made of titanium-added case hardening steel and the cast slab or steel ingot, and case hardening steel made of the cast slab or steel ingot
DE102013224851A1 (en) * 2013-12-04 2015-06-11 Schaeffler Technologies AG & Co. KG chain element
US10947610B2 (en) 2018-08-21 2021-03-16 Exxonmobil Upstream Research Company Mooring chains comprising high manganese steels and associated methods
CN113322409B (en) * 2020-02-28 2022-06-28 宝山钢铁股份有限公司 High-strength and high-toughness mining chain steel and manufacturing method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS526847B2 (en) * 1972-05-19 1977-02-25
SE430424B (en) * 1981-11-24 1983-11-14 Uddeholms Ab Ketting
JPS61276956A (en) * 1985-05-31 1986-12-06 Kito Corp Link chain
JPH03115523A (en) * 1989-09-28 1991-05-16 Kobe Steel Ltd Production of directly quenched type prehardened steel

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106222574A (en) * 2016-08-24 2016-12-14 宁波乾豪金属制品有限公司 A kind of corrosion resistant spring suspension

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SE0000458L (en) 2001-08-15
US20010024621A1 (en) 2001-09-27
SE515623C2 (en) 2001-09-10
JP2001247933A (en) 2001-09-14
CN1124360C (en) 2003-10-15
EP1126042A1 (en) 2001-08-22
SE0000458D0 (en) 2000-02-14

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