CN1308113A - Copolycondensation preparation of intermediate phase carbon microsphere - Google Patents
Copolycondensation preparation of intermediate phase carbon microsphere Download PDFInfo
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- CN1308113A CN1308113A CN 00133301 CN00133301A CN1308113A CN 1308113 A CN1308113 A CN 1308113A CN 00133301 CN00133301 CN 00133301 CN 00133301 A CN00133301 A CN 00133301A CN 1308113 A CN1308113 A CN 1308113A
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- CN
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- Prior art keywords
- copolycondensation
- oil
- raw material
- intermediate phase
- mcmb
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title abstract description 5
- 229910052799 carbon Inorganic materials 0.000 title abstract description 4
- 239000004005 microsphere Substances 0.000 title abstract 3
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000010426 asphalt Substances 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 15
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000005977 Ethylene Substances 0.000 claims abstract description 12
- 239000011280 coal tar Substances 0.000 claims abstract description 8
- 239000000295 fuel oil Substances 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000003960 organic solvent Substances 0.000 claims abstract description 5
- 239000003208 petroleum Substances 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- 239000003921 oil Substances 0.000 claims description 18
- 239000002931 mesocarbon microbead Substances 0.000 claims description 17
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 8
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 6
- 239000011300 coal pitch Substances 0.000 claims description 6
- 239000012046 mixed solvent Substances 0.000 claims description 5
- 239000011295 pitch Substances 0.000 claims description 4
- 230000035484 reaction time Effects 0.000 claims description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 3
- 239000010742 number 1 fuel oil Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 12
- 238000006243 chemical reaction Methods 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000007788 liquid Substances 0.000 abstract 1
- 239000008188 pellet Substances 0.000 abstract 1
- 239000011269 tar Substances 0.000 abstract 1
- 238000006068 polycondensation reaction Methods 0.000 description 9
- 238000001914 filtration Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000004945 emulsification Methods 0.000 description 4
- 239000003350 kerosene Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 239000011294 coal tar pitch Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000010907 mechanical stirring Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- WHRZCXAVMTUTDD-UHFFFAOYSA-N 1h-furo[2,3-d]pyrimidin-2-one Chemical compound N1C(=O)N=C2OC=CC2=C1 WHRZCXAVMTUTDD-UHFFFAOYSA-N 0.000 description 1
- XVMSFILGAMDHEY-UHFFFAOYSA-N 6-(4-aminophenyl)sulfonylpyridin-3-amine Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=N1 XVMSFILGAMDHEY-UHFFFAOYSA-N 0.000 description 1
- 235000006173 Larrea tridentata Nutrition 0.000 description 1
- 244000073231 Larrea tridentata Species 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229960002126 creosote Drugs 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 239000011302 mesophase pitch Substances 0.000 description 1
- 239000011301 petroleum pitch Substances 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Landscapes
- Working-Up Tar And Pitch (AREA)
Abstract
The present invention discloses a copolycondensation preparation method of mesophease carbon microsphere. Said method uses standard medium temperature coal tar esphalt and secondary heavy oil containing low insoluble quinoline matter, and adopts the following steps: mixing and heating to make copolycondensation reaction to botain the asphalt product containing mesophase microshpere, then thermo-solving liquid mixture of coal tar and light fraction of petroleum, and feltering, and using pure organic solvent to re-extract filter residue to obtain the invented mesophase microphere. Said invention is characterized by that its adopted secondary heavy oil is the mixture of ethylene tar and raw material, and its advantaegs are: its raw material has no need of pretreatment, carbon microsphere pellets are uniform, yield can be up to 20-30 wt% and its production cost is low.
Description
The present invention relates to a kind of copolycondensation preparation method of MCMB.The technology of preparing that belongs to MCMB.
(Mesocarbon Microbeads MCMB) is a kind of type material of approximate graphite-structure to MCMB.Because it has unique laminate structure and excellent embedding characteristic, thereby it is well being used aspect high density material, active carbon with superhigh specific surface area and the lithium-ions battery electrode materials.
Each method of the system of MCMB mainly contains emulsion process and polycondensation method.At present, two kinds of methods all are that single coal tar of employing or petroleum pitch are raw material.Emulsion process is that the external phase mesophase pitch is stirred in high-temperature medium, makes it the emulsification balling-up; The polycondensation method makes isotropic pitch generate the intermediate phase microballoon through polycondensation, with the solvent extraction method microballoon is separated again.The polycondensation method is compared with emulsion process, and it is simple and be easy to the advantage of suitability for industrialized production to have technology.But the polycondensation method requires the initial bitumen raw material is carried out pre-treatment, promptly will remove the wherein quinoline insolubles of a part on the one hand, perhaps removes quinoline insolubles fully, and the opposing party will add a spot of carbon black, Graphite Powder 99 etc. as the crystal seed that generates the intermediate phase microballoon.The preprocessing process of raw material is comparatively complicated, so it has restricted the further reduction of the preparation cost of MCMB.
Purpose of the present invention is to provide a kind of copolycondensation preparation method of MCMB.This method does not need raw material is carried out pre-treatment, and microballoon separates easily, the MCMB of Using such method preparation, and the spherolite size is even, and production cost is low.
For achieving the above object, the present invention is realized by following technical proposals.Coal-tar middle oil pitch with standard is raw material with containing the lower secondary petroleum heavy oil of quinoline insolubles, after mixing, through the heating copolycondensation, obtain containing the bitumen product of intermediate phase microballoon, then, the mixed solvent of forming with the light ends of the light ends of coal tar and oil carries out thermosol to the bitumen product that contains the intermediate phase microballoon and filters, filter residue adopts the pyridine of pure organic solvent, perhaps toluene, perhaps tetrahydrofuran (THF) carries out extracting again, obtain MCMB, it is characterized in that: a. raw material secondary petroleum heavy oil is to contain the ethylene bottom oil of quinoline insolubles less than 0.5wt%; B. the medium temperature coal pitch of standard is 1: 0.1～1: 10 with the mixed weight ratio of ethylene bottom oil; C. copolycondensation carries out under 360～450 ℃, and the reaction times is 0.5～20 hour.
Below the present invention is described in detail.
The raw material that the present invention adopts is two kinds, and a kind of is the medium temperature coal pitch that meets national standard, and the content of its quinoline insolubles is less than 10wt%, and another kind is an ethylene bottom oil, and the content of its quinoline insolubles is less than 0.5wt%.These two kinds of raw materials all mainly are made of condensed-nuclei aromatics, because the condensed-nuclei aromatics molecule in the ethylene bottom oil has more aliphatic lateral chain, the resolvability of its melt fluidity, organic solvent and thermal polycondensation reactivity are all significantly better than coal-tar pitch, therefore, after in coal-tar pitch, adding ethylene bottom oil, the mix asphalt that obtains, its quinoline insolubles content is not high, do not need to handle again removal, melt fluidity is good, carbon/hydrogen atom than and polycondensation adjusted, the polycondensation temperature reduces, the intermediate phase microballoon spherolite that reaction is produced evenly and be easy to separation.Mixed by weight proportion raw material drops in the reactor, and under protection of nitrogen gas and stirring condition, heat temperature raising reacts, and the control of temperature of reaction and the length of time are mainly determined according to feed ratio.The present invention has determined the better relationship condition in feed ratio and temperature of reaction and reaction times through repeatedly experiment.The feed ratio of coal-tar pitch and ethylene bottom oil was at 1: 0.5～1: 6 o'clock, and optimal reaction temperature is 400～420 ℃, and the reaction times is between 1～15 hour.Reaction finished contain the pitch of intermediate phase microballoon, adopt the washing oil of the cheap coal tar light ends of price comparison or the kerosene of creosote and oil light ends, or diesel oil, be mixed in proportion as extractant and extract, filter, and adopt pure organic solvent toluene etc. to carry out continuous extracting to the residue after filtering, just from bitumen product, isolate the product MCMB.
With embodiment the present invention is illustrated again below.
Embodiment one:
Add after volumes are 2 liters stainless steel cauldron intensification mixing in common medium temperature coal pitch 200 grams and ethylene bottom oil 560 grams (promptly 1: 2.8 ratio); under 400 ℃, nitrogen protection and mechanical stirring, carry out copolycondensation 3 hours, obtain containing the bitumen product of intermediate phase microballoon.Then, with washing oil and kerosene is that 1: 0.15 mixed solvent carries out thermosol and filtration to above-mentioned bitumen product, re-use pyridine and in cable-styled extractor, carry out continuous extracting filtering the residual solid matter in back, obtain the MCMB that mean diameter is about 15 μ m after removing solvent and drying, its yield is 13.8%wt (is to calculate benchmark with the material asphalt).
Embodiment two:
Common medium temperature coal pitch 300 grams and ethylene bottom oil 390 grams (promptly 1: 1.3 ratio) are added after volumes are 2 liters stainless steel cauldron intensification mixing; at first under nitrogen protection and mechanical stirring, slowly be warming up to 410 ℃ and make that the part small-molecule substance is removed in the raw material with 2 ℃/minute speed; then; under this temperature and closed state, carry out copolycondensation 4 hours, and obtained containing the bitumen product of intermediate phase microballoon.Then, with washing oil and kerosene is that 1: 0.1 mixed solvent carries out thermosol and filtration to above-mentioned bitumen product, re-use toluene and in cable-styled extractor, carry out continuous extracting filtering the residual solid matter in back, obtain the MCMB that mean diameter is about 17 μ m after removing solvent and drying, its yield is 21.5wt% (is to calculate benchmark with the material asphalt).
Embodiment three:
Common medium temperature coal pitch 480 grams and ethylene bottom oil 120 grams (promptly 1: 0.25 ratio) are added after volumes are 2 liters stainless steel cauldron intensification mixing, mix and stir and carried out copolycondensation under the closed state 6 hours at 415 ℃, mechanical stirring, obtain containing the bitumen product of intermediate phase microballoon.Then, with washing oil and kerosene is that 1: 0.1 mixed solvent carries out thermosol and filtration to above-mentioned bitumen product, and use pyridine in cable-styled extractor, to carry out continuous extracting to filtering the residual solid matter in back, obtain the MCMB that mean diameter is about 12 μ m after removing solvent and drying, its yield is 26.3wt% (is to calculate benchmark with the material asphalt).
The present invention compares with existing thermal polycondensation method, and its major advantage is that raw material need not carry out preliminary treatment, and obtain The microballoon spherolite is even, and product yield generally can reach 20～30wt%, and production cost is low, has widely promotional value.
Claims (1)
1, a kind of copolycondensation preparation method of MCMB, it is with the coal-tar middle oil pitch of standard and to contain the lower secondary petroleum heavy oil of quinoline insolubles be raw material, after mixing, through the heating copolycondensation, obtain containing the bitumen product of intermediate phase microballoon, then, the mixed solvent of forming with the light ends of the light ends of coal tar and oil carries out thermosol to the bitumen product that contains the intermediate phase microballoon and filters, filter residue adopts the pyridine of pure organic solvent, perhaps toluene, perhaps tetrahydrofuran (THF) carries out extracting again, obtain MCMB, it is characterized in that: a. raw material secondary petroleum heavy oil is to contain the ethylene bottom oil of quinoline insolubles less than 0.5wt%; B. the medium temperature coal pitch of standard is 1: 0.1～1: 10 with the mixed weight ratio of ethylene bottom oil; C. copolycondensation carries out under 360～450 ℃, and the reaction times is 0.5～20 hour.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN00133301A CN1116386C (en) | 2000-11-23 | 2000-11-23 | Copolycondensation preparation of intermediate phase carbon microsphere |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN00133301A CN1116386C (en) | 2000-11-23 | 2000-11-23 | Copolycondensation preparation of intermediate phase carbon microsphere |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1308113A true CN1308113A (en) | 2001-08-15 |
| CN1116386C CN1116386C (en) | 2003-07-30 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN00133301A Expired - Lifetime CN1116386C (en) | 2000-11-23 | 2000-11-23 | Copolycondensation preparation of intermediate phase carbon microsphere |
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| Country | Link |
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| CN (1) | CN1116386C (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101811691A (en) * | 2010-04-23 | 2010-08-25 | 上海应用技术学院 | Preparation method of mesocarbon microbead |
| CN102491307A (en) * | 2011-11-25 | 2012-06-13 | 淄博矿业集团有限责任公司 | Method for preparing mesocarbon microbeads by copolycondensation |
| CN102633254A (en) * | 2011-08-27 | 2012-08-15 | 天津市贝特瑞新能源材料有限责任公司 | Applications of boric acid in preparing catalyst of intermediate phase carbon microball |
| CN102005559B (en) * | 2009-09-01 | 2013-06-05 | 天津爱敏特电池材料有限公司 | Method for preparing artificial graphite cathode material for lithium ion batteries |
| CN103165869A (en) * | 2011-12-13 | 2013-06-19 | 上海杉杉科技有限公司 | Modified intermediate phase anode material, lithium ion secondary battery and preparation method and application |
| CN103613089A (en) * | 2013-11-29 | 2014-03-05 | 神华集团有限责任公司 | Method of preparing mesocarbon microbeads by coal liquefaction residues and mesocarbon microbeads |
| CN107163969A (en) * | 2017-05-31 | 2017-09-15 | 中国科学院山西煤炭化学研究所 | A kind of method that medium temperature coal pitch prepares mesophase pitch |
| CN107720721A (en) * | 2017-08-28 | 2018-02-23 | 煤炭科学技术研究院有限公司 | MCMB and preparation method thereof |
| CN108178142A (en) * | 2018-03-02 | 2018-06-19 | 辽宁科技大学 | A kind of cocondensation polymerizing preparation method of carbonaceous mesophase spherules |
| CN109360945A (en) * | 2017-08-04 | 2019-02-19 | 天津大学 | Lithium ion battery silicon/carbonaceous mesophase spherules composite material and preparation method |
| CN113353915A (en) * | 2021-07-19 | 2021-09-07 | 中国石油化工股份有限公司 | Mesocarbon microbeads, preparation method thereof, spherical porous activated carbon material and application thereof |
| CN115340083A (en) * | 2022-08-18 | 2022-11-15 | 郑州中科新兴产业技术研究院 | Small-particle-size asphalt-based carbon microsphere and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1057319C (en) * | 1997-04-27 | 2000-10-11 | 中国科学院山西煤炭化学研究所 | Preparation of interphase carbon microball |
-
2000
- 2000-11-23 CN CN00133301A patent/CN1116386C/en not_active Expired - Lifetime
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102005559B (en) * | 2009-09-01 | 2013-06-05 | 天津爱敏特电池材料有限公司 | Method for preparing artificial graphite cathode material for lithium ion batteries |
| CN101811691A (en) * | 2010-04-23 | 2010-08-25 | 上海应用技术学院 | Preparation method of mesocarbon microbead |
| CN102633254A (en) * | 2011-08-27 | 2012-08-15 | 天津市贝特瑞新能源材料有限责任公司 | Applications of boric acid in preparing catalyst of intermediate phase carbon microball |
| CN102491307A (en) * | 2011-11-25 | 2012-06-13 | 淄博矿业集团有限责任公司 | Method for preparing mesocarbon microbeads by copolycondensation |
| CN102491307B (en) * | 2011-11-25 | 2014-07-23 | 淄博矿业集团有限责任公司 | Method for preparing mesocarbon microbeads by copolycondensation |
| CN103165869B (en) * | 2011-12-13 | 2016-01-06 | 上海杉杉科技有限公司 | Modification mesophase spherule negative material, lithium rechargeable battery and preparation method and application |
| CN103165869A (en) * | 2011-12-13 | 2013-06-19 | 上海杉杉科技有限公司 | Modified intermediate phase anode material, lithium ion secondary battery and preparation method and application |
| CN103613089B (en) * | 2013-11-29 | 2016-02-10 | 神华集团有限责任公司 | Coal liquefaction residue is utilized to prepare method and the MCMB of MCMB |
| CN103613089A (en) * | 2013-11-29 | 2014-03-05 | 神华集团有限责任公司 | Method of preparing mesocarbon microbeads by coal liquefaction residues and mesocarbon microbeads |
| CN107163969A (en) * | 2017-05-31 | 2017-09-15 | 中国科学院山西煤炭化学研究所 | A kind of method that medium temperature coal pitch prepares mesophase pitch |
| CN107163969B (en) * | 2017-05-31 | 2020-01-07 | 中国科学院山西煤炭化学研究所 | Method for preparing mesophase pitch from medium-temperature coal pitch |
| CN109360945A (en) * | 2017-08-04 | 2019-02-19 | 天津大学 | Lithium ion battery silicon/carbonaceous mesophase spherules composite material and preparation method |
| CN107720721A (en) * | 2017-08-28 | 2018-02-23 | 煤炭科学技术研究院有限公司 | MCMB and preparation method thereof |
| CN107720721B (en) * | 2017-08-28 | 2019-11-01 | 煤炭科学技术研究院有限公司 | Mesocarbon microspheres and preparation method thereof |
| CN108178142A (en) * | 2018-03-02 | 2018-06-19 | 辽宁科技大学 | A kind of cocondensation polymerizing preparation method of carbonaceous mesophase spherules |
| CN113353915A (en) * | 2021-07-19 | 2021-09-07 | 中国石油化工股份有限公司 | Mesocarbon microbeads, preparation method thereof, spherical porous activated carbon material and application thereof |
| CN115340083A (en) * | 2022-08-18 | 2022-11-15 | 郑州中科新兴产业技术研究院 | Small-particle-size asphalt-based carbon microsphere and preparation method thereof |
| CN115340083B (en) * | 2022-08-18 | 2024-03-15 | 郑州中科新兴产业技术研究院 | Small-particle-size asphalt-based carbon microsphere and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1116386C (en) | 2003-07-30 |
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Address after: 300110 North Industry Zone, Xiqing Economic Development Zone, Tianjin Patentee after: Tianjin BTR New Energy Material Co., Ltd. Address before: 300110 North Industry Zone, Xiqing Economic Development Zone, Tianjin Patentee before: Tianjin Tiecheng Battery Materials Co., Ltd. |
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Owner name: TIANJIN BTR NEW ENERGY SCEINCE AND TECHNOLOGY CO., Free format text: FORMER OWNER: TIANJIN BTR NEW ENERGY MATERIAL CO., LTD. Effective date: 20140610 |
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Free format text: CORRECT: ADDRESS; FROM: 300110 XIQING, TIANJIN TO: 301802 BAODI, TIANJIN |
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Effective date of registration: 20140610 Address after: 301802, No. nine, nine Garden Industrial Park, Baodi District, Tianjin Patentee after: Tianjin BTR New Energy Science and Technology Co., Ltd. Address before: 300110 North Industry Zone, Xiqing Economic Development Zone, Tianjin Patentee before: Tianjin BTR New Energy Material Co., Ltd. |
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Effective date of registration: 20160202 Address after: 518106 Gongming City, Guangdong province Guangming New District Office of the West community high and New Technology Industrial Park, building eighth, Patentee after: Shenzhen BTR New Energy Material Co., Ltd. Address before: 301802, No. nine, nine Garden Industrial Park, Baodi District, Tianjin Patentee before: Tianjin BTR New Energy Science and Technology Co., Ltd. |
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Address after: 518106 Gongming City, Guangdong province Guangming New District Office of the West community high and New Technology Industrial Park, building eighth, Patentee after: Beitrei New Materials Group Co., Ltd Address before: 518106 Gongming City, Guangdong province Guangming New District Office of the West community high and New Technology Industrial Park, building eighth, Patentee before: Shenzhen BTR New Energy Materials Inc. |
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Granted publication date: 20030730 |
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