CN1307265C - Nano-antibacterial inorganic composite coloured metal coating layer material - Google Patents
Nano-antibacterial inorganic composite coloured metal coating layer material Download PDFInfo
- Publication number
- CN1307265C CN1307265C CNB2004100853693A CN200410085369A CN1307265C CN 1307265 C CN1307265 C CN 1307265C CN B2004100853693 A CNB2004100853693 A CN B2004100853693A CN 200410085369 A CN200410085369 A CN 200410085369A CN 1307265 C CN1307265 C CN 1307265C
- Authority
- CN
- China
- Prior art keywords
- oxide
- coating layer
- nano
- layer material
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Glass Compositions (AREA)
Abstract
The present invention relates to a nanometer antibacterial inorganic composite colored coating layer material for metal. The coating layer material is prepared from the following components: 32.4% of quartz containing a nanometer material accounting for 1.2% of the quartz, 16.24% of felspar, 2.01% of zirconium dioxide containing a nanometer material accounting for 0.8% of the zirconium dioxide, 28.01% of borax, 0.73% of cerium oxide, 0.22% of cupric oxide, 8.42% of sodium carbonate, 0.06% of selenium powder, 0.21% of yttrium oxide, 3.64% of fluorite, 3.6% of potassium nitrate, 0.72% of cobalt oxide, 1.63% of manganese dioxide, 0.8% of aluminium oxide containing a nanometer material accounting for 1% of the aluminium oxide, 0.21% of lanthanum oxide and 1.1% of Ag silica gel. The nanometer antibacterial inorganic composite colored coating layer material has the advantages of nontoxicity, high adherence, corrosion resistance, no oxidation, wear resistance, acid and alkali resistance, high temperature resistance and high weatherability resistance.
Description
One, technical field
The present invention relates to a kind of nano-antibacterial inorganic composite coloured metal coating layer material.
Two, background technology
Along with the progress of society, people more and more pay attention to healthy, use the favourable diseases prevention of product of environment-friendly antibacterial material, help health, particularly after SARS and " bird flu ", the human consumer obviously increases the demand of antimicrobial product, heats up rapidly in domestic antimicrobial prod market.But up to the present, also there is not directly antimicrobial metal coating layer material.
Three, summary of the invention
In order to overcome the shortcoming of prior art, the invention provides a kind of nano-antibacterial inorganic composite coloured metal coating layer material, it is nontoxic, adhesion property is good, corrosion-resistant not oxidation, wear-resisting wiping, acid and alkali-resistance, high temperature resistant, weather resisteant good.
The present invention solves the technical scheme that its technical problem takes: each component percentage composition: quartzy 22.07～54.7%, and feldspar 4.08～17.1%, zirconium dioxide 0.4～2.2%, borax 9.79～28.8%, cerium oxide 0.2～0.97%, cupric oxide 0.23～3.24%, yellow soda ash 0～8.57%, selenium powder 0～0.08%, yttrium oxide 0～0.25%, fluorite 0～3.85%, saltpetre 0～3.74%, cobalt oxide 0～0.72%, Manganse Dioxide 0～1.64%, aluminium sesquioxide 0～1.2%, lanthanum trioxide 0～0.44%, silver silica gel 0～2.36%, titanium dioxide 0～7.42%, zinc oxide 0～3.85%, talcum 0～9.38%, aluminium powder 0～2.04%, silver-colored activated carbon 0～1.4%, silver zeolite 0～2.75%, calcite 0～3.66%, Quilonum Retard 0～2.62%, tertiary sodium phosphate 0～4.29%, magnesium oxide 0～1.27.The technological process of production: by described component raw material is mixed, after screening more than 200 orders, add the part nano material again and mix, through clamping pot or converter heat 3～4 hours, back quenching in cold water.The glaze piece is put into ball mill, and 500g glaze piece is converted 400～600 milliliters in water, 35～45 minutes defibrinations, and the after vibration sieve sieves, and adjusts concentration of glaze slip, glaze slip, wet spray.
According to detecting at the antibiotic center of physics and chemistry institute of the Chinese Academy of Sciences in September, 2004, Chinese People's Anti-Japanese Military and Political College enterobacteria and staphylococcus aureus reach 96% and 98% respectively.This coated material adhesion property is good, corrosion-resistant not oxidation, wear-resisting wiping, acid and alkali-resistance, high temperature resistant, weather resisteant good.Material composition is nontoxic, and toxic substance such as not leaded, antimony, cadmium, chromium, barium does not more contain carcinogens such as nickel etc.This coated material is adjustable allots shades of colour, and bright in luster, and the gloss exquisiteness is rich in meat feeling.
Four, embodiment
Prescription A: quartzy 32.4%, wherein contain the nano material that accounts for quartzy component 1.2%, feldspar 16.24%, zirconium dioxide 2.01% wherein contains the nano material that accounts for zirconium dioxide component 0.8%, borax 28.01%, cerium oxide 0.73%, cupric oxide 0.22%, yellow soda ash 8.42%, selenium powder 0.06%, yttrium oxide 0.21%, fluorite 3.64%, saltpetre 3.6%, cobalt oxide 0.72%, Manganse Dioxide 1.63%, aluminium sesquioxide 0.8% wherein contains the nano material that accounts for aluminium sesquioxide component 1%, lanthanum trioxide 0.21%, silver-colored silica gel 1.1%.
Prescription B: quartzy 22.07%, wherein contain the nano material that accounts for quartzy component 0.8%, feldspar 13.01%, zirconium white 0.9%, borax 24.24%, cerium oxide 0.2%, cupric oxide 3.21%, titanium dioxide 6.23% wherein contains the nano material that accounts for titanium dioxide component 2.1%, zinc oxide 3.57%, wherein contain the nano material that accounts for zinc oxide component 1.5%, talcum 8.04%, aluminium powder 1.81%, silver-colored activated carbon 0.6%, silver zeolite 1.9%, calcite 3.45%, Quilonum Retard 2.57%, tertiary sodium phosphate 3.95%.
The technological process of production:
By prescription A or B raw material is mixed, after screening more than 200 orders, add the part nano material again and mix, through clamping pot or converter heat 3～4 hours, back quenching in cold water.The glaze piece is put into ball mill, and 500g glaze piece is converted 400～600 milliliters in water, 35～45 minutes defibrinations, and the after vibration sieve sieves, and adjusts concentration of glaze slip, glaze slip, wet spray.
Iron and steel scrubbing technology
A, Workpiece shaping.Selection is cut out material according to product, carries out once or secondary stretch again, and the flat wrinkle of the needs that have etc. through the mechanical workout moulding, are revised.
B, workpiece oil removing.Adopt the cleaner for metal deoiling method, as the LT-83 clean-out system, use temperature 20-100 ℃.
C, workpiece rust cleaning.Adopt dust-free blasting, remove dirt settlings such as descaling, rust, dirt and old coating fully.Workpiece surface will reach roughening treatment simultaneously, to increase the contact area of coating and matrix, increases the surperficial packing interaction of coated material and matrix.
D, spraying glaze slip.By air compressor air is sent into spray gun, air drives glaze slip from gun slot and is built-up on the workpiece equably.
E, drying.In stove through 150 ℃ of-300 ℃ of oven dry.
F, burn till.According to the needs of workpiece,, in stove, burn to 680 ℃-880 ℃ according to the use temperature of glaze.
Nano-antibacterial inorganic composite coloured metal coating layer material, except that using the part nano material, in the melting material process, because reaction at high temperature, the part material splits out the crystallization or the amorphous fine-particle of 10-100 nanometer, so the certain amount of nano composition is arranged in the matrix material.
Can be widely used in following field:
(1) communal facility: the place of the easy cross infections of bacterium such as hospital, restaurant, hotel, school, public lavatory, movie theatre, health-care facilities, sanitary facility.
(2) house decoration and urban beautification: be used in the finishing of various buildings external and internal walls and shop, bank counter, the beautifying of banister and public place, city.
(3) top coat of common cooker, automatically controlled cooker, various tableware, various stove and accessory, sterilizing-cabinet, water storage tank and various kitchen tackle etc.
(4) the mechanical cover coating of household appliances shell, irony office appliance and food-processing industry.
(5) envelope of motorbus, car, train, steamer is decorated and the decoration of toilet etc.
(6) the living this antimicrobial product of local particularly suitable of the easy evil of subway, vault and dark moist bacterium.
Claims (2)
1, a kind of nano-antibacterial inorganic composite coloured metal coating layer material is characterized in that: each component percentage composition is: quartz 22.07～54.7%, feldspar 4.08～17.1%, zirconium dioxide 0.4～2.2%, borax 9.79～28.8%, cerium oxide 0.2～0.97%, cupric oxide 0.23～3.24%, yellow soda ash 0～8.57%, selenium powder 0～0.08%, yttrium oxide 0～0.25%, fluorite 0～3.85%, saltpetre 0～3.74%, cobalt oxide 0～0.72%, Manganse Dioxide 0～1.64%, aluminium sesquioxide 0～1.2%, lanthanum trioxide 0～0.44%, silver-colored silica gel 0～2.36%, titanium dioxide 0～7.42%, zinc oxide 0～3.85%, talcum 0～9.38%, aluminium powder 0～2.04%, silver activated carbon 0～1.4%, silver zeolite 0～2.75%, calcite 0～3.66%, Quilonum Retard 0～2.62%, tertiary sodium phosphate 0～4.29%, magnesium oxide 0～1.27; The technological process of production: raw material is mixed by described component, after screening more than 200 orders, add the nanometer material mixing again, through clamping pot or converter heat 3～4 hours, back quenching in cold water, the glaze piece is put into ball mill, and 500g glaze piece is converted 400～600 milliliters in water, 35～45 minutes defibrinations, the after vibration sieve sieves, and the adjustment concentration of glaze slip, glaze slip, wet spray.
2, nano-antibacterial inorganic composite coloured metal coating layer material according to claim 1, it is characterized in that: the each component percentage composition is: quartzy 32.4%, wherein contain quartzy nano material and account for 1.2% of quartzy component, feldspar 16.24%, zirconium dioxide 2.01%, wherein the zirconium dioxide nano material accounts for 0.8% of zirconium dioxide component, borax 28.01%, cerium oxide 0.73%, cupric oxide 0.22%, yellow soda ash 8.42%, selenium powder 0.06%, yttrium oxide 0.21%, fluorite 3.64%, saltpetre 3.6%, cobalt oxide 0.72%, Manganse Dioxide 1.63%, aluminium sesquioxide 0.8%, wherein the aluminium sesquioxide nano material accounts for 1% of aluminium sesquioxide component, lanthanum trioxide 0.21%, silver-colored silica gel 1.1%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100853693A CN1307265C (en) | 2004-10-15 | 2004-10-15 | Nano-antibacterial inorganic composite coloured metal coating layer material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100853693A CN1307265C (en) | 2004-10-15 | 2004-10-15 | Nano-antibacterial inorganic composite coloured metal coating layer material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1618888A CN1618888A (en) | 2005-05-25 |
| CN1307265C true CN1307265C (en) | 2007-03-28 |
Family
ID=34766002
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100853693A Expired - Fee Related CN1307265C (en) | 2004-10-15 | 2004-10-15 | Nano-antibacterial inorganic composite coloured metal coating layer material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1307265C (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI497019B (en) * | 2007-01-30 | 2015-08-21 | Sumitomo Osaka Cement Co Ltd | Cooking utensil and method for manufacturing thereof |
| CN100410197C (en) * | 2007-02-02 | 2008-08-13 | 南安协进建材有限公司 | Method for producing metal enamel |
| CN101322497B (en) * | 2008-07-08 | 2012-07-25 | 西南科技大学 | Active stephanoporate mineral TiO2-doped composite catalytic antimicrobial material preparation and using method |
| CN103540180A (en) * | 2013-09-27 | 2014-01-29 | 安徽华印机电股份有限公司 | Metal-based nano antibacterial coating material as well as preparation method thereof |
| CN103538316A (en) * | 2013-09-27 | 2014-01-29 | 安徽华印机电股份有限公司 | Preparation method of metal-based nano antibacterial coating aluminum plate |
| CN106762018A (en) * | 2016-12-05 | 2017-05-31 | 蚌埠市国乐汽配有限公司 | A kind of box oil cooler |
| CN108640514A (en) * | 2018-06-25 | 2018-10-12 | 浙江东度文化创意有限公司 | Secret color glaze layer of celadon of sustained-release antibacterial and preparation method thereof |
| CN108675635A (en) * | 2018-06-25 | 2018-10-19 | 浙江东度文化创意有限公司 | A kind of secret color glaze of celadon and preparation method thereof |
| CN108706871A (en) * | 2018-06-25 | 2018-10-26 | 浙江东度文化创意有限公司 | Can generating negative ions glaze and preparation method thereof |
| CN111377613A (en) * | 2020-04-09 | 2020-07-07 | 张志龙 | Antibacterial ceramic glaze and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1461782A (en) * | 2002-05-30 | 2003-12-17 | 郑福权 | Lubang nanometer environmental protection paint |
| CN1472270A (en) * | 2002-08-02 | 2004-02-04 | 上海佳加室内装潢工程有限公司 | Nanometer internal wall damping latex paint |
| CN1519051A (en) * | 2003-01-22 | 2004-08-11 | 河南大学 | Spray coating fluid for fabricating photocatalysed antibafcterial ceramics |
-
2004
- 2004-10-15 CN CNB2004100853693A patent/CN1307265C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1461782A (en) * | 2002-05-30 | 2003-12-17 | 郑福权 | Lubang nanometer environmental protection paint |
| CN1472270A (en) * | 2002-08-02 | 2004-02-04 | 上海佳加室内装潢工程有限公司 | Nanometer internal wall damping latex paint |
| CN1519051A (en) * | 2003-01-22 | 2004-08-11 | 河南大学 | Spray coating fluid for fabricating photocatalysed antibafcterial ceramics |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1618888A (en) | 2005-05-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1307265C (en) | Nano-antibacterial inorganic composite coloured metal coating layer material | |
| CN102181862B (en) | Preparation method of enameled steel sheet | |
| CN112209618A (en) | Velvet ceramic rock plate and preparation method thereof | |
| CN108025947B (en) | Method for providing a Co and Ni free vitreous enamel metal coated steel substrate and primer composition for use in the method | |
| US20050196430A1 (en) | Antimicrobial enamel glaze | |
| CN107779018A (en) | A kind of multi-functional vinylacetate inner wall decorative coating | |
| CN105274424A (en) | Enamel wok with patterns on outer surface and manufacturing method of enamel wok | |
| CN103538316A (en) | Preparation method of metal-based nano antibacterial coating aluminum plate | |
| CN101611718B (en) | Dragon spring celadon antibacterial agent and application thereof | |
| CN201011079Y (en) | Inorganic composite antibiotic ceiling board | |
| CN110791760A (en) | Processing technology of enameled steel plate | |
| CN103540180A (en) | Metal-based nano antibacterial coating material as well as preparation method thereof | |
| US9974310B2 (en) | Ceramic additive formulation and method of making | |
| CN102585621B (en) | Smell purified and energy-saving decorating paint | |
| CN110526582A (en) | A kind of composite material and preparation method for coating | |
| JP5435395B2 (en) | Method for manufacturing glass article | |
| CN103351658A (en) | Energy-saving environment-friendly building decoration paint | |
| CN203715504U (en) | Colored crystal coating glass | |
| CN104844277B (en) | A kind of discoloration ecology ceramic tile capable of releasing negative ion and preparation method thereof | |
| CN115821263A (en) | Preparation method of enamel plate with texture on surface | |
| KR20120039934A (en) | Tile coating composition and tile using thereof | |
| JP2003336010A (en) | Method for producing solution for forming high purity silica film, and coating method using the same | |
| CN108706956A (en) | A kind of production technology of satin glaze entire body Dali stone ceramic tile | |
| CN110255905B (en) | Antibacterial enamel glaze slurry, preparation method and preparation method of antibacterial enamel plate | |
| CN104233164A (en) | Manufacturing method for diamond cutting edge made of nano ceramic material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |