CN1307202A - High-strength steel gas cylinder - Google Patents

High-strength steel gas cylinder Download PDF

Info

Publication number
CN1307202A
CN1307202A CN 00110094 CN00110094A CN1307202A CN 1307202 A CN1307202 A CN 1307202A CN 00110094 CN00110094 CN 00110094 CN 00110094 A CN00110094 A CN 00110094A CN 1307202 A CN1307202 A CN 1307202A
Authority
CN
China
Prior art keywords
gas cylinder
bottle
steel gas
steel
high tensile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 00110094
Other languages
Chinese (zh)
Inventor
姜将
张玉成
莫立华
王汉儒
江晓东
吴平森
卢迺谦
齐瑞昌
邓红
宋维凤
徐全礼
张宇男
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHENYANG KEJIN NEW MATERIAL DEVELOPMENT GENERAL CORP
Original Assignee
SHENYANG KEJIN NEW MATERIAL DEVELOPMENT GENERAL CORP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHENYANG KEJIN NEW MATERIAL DEVELOPMENT GENERAL CORP filed Critical SHENYANG KEJIN NEW MATERIAL DEVELOPMENT GENERAL CORP
Priority to CN 00110094 priority Critical patent/CN1307202A/en
Publication of CN1307202A publication Critical patent/CN1307202A/en
Pending legal-status Critical Current

Links

Abstract

High strength steel cylinder is made of material with chemical components of (in wt%): C 0.30-0.34, Si 0.20-0.35, Mn 0.50-0.70, P less than or equal 0.015, S less than or equal 0.010, Cr 0.90-1.10, Ni 1.60-1.90, Mo 0.65-0.80, V 0.08-0.15, P+S less than or equal 0.020 and Fe (the balance). It is used in air respirator for fire fighting and other field, and has high strength and light weight.

Description

A kind of high tensile steel gas cylinder
The present invention relates to pressurized container, it is mainly used in the air respiratorresuscitator of industry uses such as assembling fire-fighting to provide utilization Metal Forming technology to make the high tensile steel gas cylinder especially, and filling medium is pressurized air.Also can fill oxygen, nitrogen or inert gas when being used for other field.
From the technical performance opinion, air respiratorresuscitator is weight reduction as much as possible under the identical prerequisite of gas-storing capacity to the outstanding request of gas cylinder.With the fire-fighting operation is example, reduces fireman's physical consumption, increases the activity duration in the scene of a fire, is significant for inherently safe that guarantees the fireman and raising fire extinguishing mitigation ability.At present air respiratorresuscitator uses mostly is 30CrMo or 35CrMo steel gas cylinder, though intensity and toughness index can satisfy existing technical standard requirement, weight is not light.
The object of the present invention is to provide a kind of high tensile steel seamless gas cylinder, it is mainly used in the air respiratorresuscitator of industry uses such as assembling fire-fighting, the intensity height, and in light weight.
The invention provides a kind of high tensile steel gas cylinder, it is characterized in that the chemical composition of this steel gas cylinder is: C0.30-0.34, Si 0.20-0.35, Mn 0.50-0.70, P≤0.015, S≤0.010, Cr 0.90-1.10, Ni 1.60-1.90, Mo 0.65-0.80, V 0.08-0.15, P+S≤0.020.
The preparation of high tensile steel gas cylinder of the present invention can be adopted following three kinds of methods:
A raw material steel pipe → pipe annealing → machining → (spinning) → heat receive the end → heat receipts mouth → machining → quenching and tempering → cover coat
B raw steel → slab annealing → machining → punching press → (drawing or spinning) → heat is received mouth → machining → quenching and tempering → cover coat
C raw bar material → excellent base annealing → extrusion moulding → (drawing or spinning) → heat is received mouth → machining → quenching and tempering → cover coat
Whether adopt the operation in the bracket in above-mentioned three kinds of technologies, can be according to the decision of technological equipment situation, relevant process parameter is:
1, blank anneal
Annealing temperature is 680 ± 10 ℃, and holding time should be not less than 6 hours, cools to the furnace below 300 ℃ and comes out of the stove.
Annealing back material hardness should be HRC≤28.
2, bottle quenches and tempering heat treatment
A quenches
Bottle kept 60 minutes at 870 ± 10 ℃, went into cooling in the oil then or cooled off in rate of cooling is not more than the quenching medium of 80% water cooling speed.
The b tempering
Bottle is at 600 ± 10 ℃ of insulations air cooling of coming out of the stove after 120 minutes.
C quenches and the holding time of tempering should change above-mentioned time For Information Only with loading volume.
Bottle tempering as early as possible after d quenches, the stand-by period in air at room temperature should be not more than 30 minutes.
3, mechanical property guarantee value after the bottle heat treatment
Mechanical property after the bottle heat treatment should be not less than numerical value shown in the table 1.
Guarantee value after the heat treatment of table 1 bottle
σ bMPa ??σ 0.2MPa 5 ????-50℃??a kv????J/cm 2
?≥1250 ??≥1100 ??≥12 ???????????≥60
The international standard ISO/DIS9809-2 that ISO (International Standards Organization) is about to pass through " tensile strength is more than or equal to the movable seamless steel gas cylinder design of the Q-tempering of 1100MPa, manufacturing and check " has positive effect for the technological progress of high tensile steel gas cylinder.China only is applicable to that at present intensity is not more than the gas cylinder standard GB5099-94 " seamless steel gas cylinder " of 1100MPa.For the low pressure that prevents gas cylinder is destroyed and low-cycle fatigue failure, above-mentioned two standards have all been stipulated bottle hydraulic bursting test and cyclic fatigue test.
The key problem in technology of high tensile steel seamless gas cylinder provided by the present invention has been to use a kind of novel high tensile steel, well-known intensity height, poor toughness, cracking resistance line expansion capability are low, being the deadly defect of high tensile steel, is the basic reason that the high tensile steel gas cylinder produces low pressure explosion and low-cycle fatigue failure.
Bursting pressure P when GB5099 and ISO/DIS9809-2 stipulate the bottle hydraulic bursting test bShould be not less than 1.6 times of hydraulic test pressure P h, i.e. P b〉=1.6P hDuring the cyclic fatigue test, the cocycle pressure of test can be nominal operating pressure P w, also can be hydraulic test pressure P h(P h=1.5P w), following circulating pressure is 10% of a cocycle pressure, and can not be greater than 3MPa.When cocycle pressure was nominal operating pressure, 80000 circulations of bottle experience did not destroy to qualified, and when cocycle pressure was hydraulic test pressure, 12000 circulations of bottle experience did not destroy to qualified.Such requirement is difficult to reach for the intensity of the ISO/DIS9809-2 regulation gas cylinder more than or equal to 1100MPa.But because high tensile steel of the present invention has the obdurability matched well, smoothly by the test of bottle cyclic fatigue.
In order to remove the worry of people to the high tensile steel gas cylinder safely, ISO/DIS9809-2 also requires axially to carry out cyclic fatigue test and bursting test after bottle wall outer surface cutting-give system ARTIFICIAL CRACK along bottle, and this regulation is the baptism to gas cylinder safely.The high tenacity of high tensile steel of the present invention makes the steel cylinder body with given size ARTIFICIAL CRACK satisfy the requirement of bursting test and fatigue test.
In addition, high tensile steel gas cylinder of the present invention is because steel matter intensity height, the good toughness of selecting for use is not less than in the other technologies index under the situation of CrMo steel cylinder body, and it is very light that weight can become, and is example with 6 litre flasks, can alleviate more than the 2kg.
In a word, the present invention compares 32CrNi with domestic 35CrMo steel gas cylinder 2MoV steel gas cylinder has the high advantage of intensity, but plasticity of the two (δ value) and impact toughness (a kValue) close, the safety reliability in the use is also about the same, and importantly bottle weight saving is more than 1/5.With overseas-built tensile strength is that the high strength steel cylinder of 1100-1400MPa is compared 32CrNi 2The MoV steel cylinder is the intensity height not only, and toughness is better, and is safe and reliable, and bottle weight also reduces slightly.Below by embodiment in detail the present invention is described in detail.
Embodiment
The 30CrNiMo that external product is made with German Mannesmann Steel tube Co., Ltd May nineteen ninety-five 8The high strength steel cylinder is an example, and chemical composition, technical performance and the contrast of mechanical property measured value of product is as follows:
Table 2 bottle material chemical composition w%
Material trademark Chemical composition
????C ????Si ????Mn ????P ????S ????Cr ????Ni ????Mo ????V
35CrMo ????0.34 ????0.24 ????0.51 ????0.020 ????0.011 ????0.95 ????0.20
Moral 30CrNiMo 8 ????0.30 ????0.24 ????0.47 ????0.013 ????0.003 ????1.95 ????1.94 ????0.35
32CrNi 2MoV-1 ????0.31 ????0.29 ????0.65 ????0.010 ????0.003 ????1.05 ????1.78 ????0.66 ????0.12
32CrNi 2MoV-2 ????0.32 ????0.24 ????0.67 ????0.008 ????0.007 ????1.05 ????1.68 ????0.72 ????0.14
32CrNi 2MoV-3 ????0.32 ????0.24 ????0.66 ????0.011 ????0.003 ????0.96 ????1.65 ????0.79 ????0.11
Table 3 bottle technical performance
Material trademark Nominal outside diameter mm Working pressure MPa Actual volume L Actual wall thickness mm Actual weight kg Fill medium Environmental Conditions temperature ℃
????35CrMo ????140 ????30 ????6.20 ????4.9 ????9.3 Air ????-40-60
Moral 30CrNiMo8 ????140 ????30 ????6.00 ????4.2 ????7.5 Air ????-40-60
32CrNi 2MoV-1 ????140 ????30 ????6.20 ????3.8 ????7.2 Air ????-40-60
32CrNi 2MoV-2 ????140 ????30 ????6.19 ????3.8 ????7.2 Air ????-40-60
32CrNi 2MoV-3 ????140 ????30 ????6.21 ????3.8 ????7.2 Air ????-40-60
Table 4 bottle mechanical properties of materials
Material trademark σ bMPa 0.2MPa ???δ 5 ??????-50℃a kvJ/cm 2
?35CrMo ????1030 ????950 ????14.0 ?????????66.8
Moral 32CrNiMo8 ????1180 ????1060 ????14.0 ?????????29.0
32CrNi 2MoV-1 ????1300 ????1260 ????14.0 ?????????82.8
32CrNi 2MoV-2 ????1300 ????1230 ????14.6 ?????????70.4
32CrNi 2MoV-3 ????1330 ????1280 ????14.0 ?????????75.2

Claims (2)

1, a kind of high tensile steel gas cylinder is characterized in that the chemical composition of this steel gas cylinder is: C 0.30-0.34, Si 0.20-0.35, Mn 0.50-0.70, P≤0.015, S≤0.010, Cr 0.90-1.10, Ni 1.60-1.90, Mo 0.65-0.80, V 0.08-0.15, P+S≤0.020.
2, the described high tensile steel gas cylinder of claim 1 is used to assemble the air respiratorresuscitator of industry uses such as fire-fighting.
CN 00110094 2000-01-31 2000-01-31 High-strength steel gas cylinder Pending CN1307202A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 00110094 CN1307202A (en) 2000-01-31 2000-01-31 High-strength steel gas cylinder

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 00110094 CN1307202A (en) 2000-01-31 2000-01-31 High-strength steel gas cylinder

Publications (1)

Publication Number Publication Date
CN1307202A true CN1307202A (en) 2001-08-08

Family

ID=4580114

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 00110094 Pending CN1307202A (en) 2000-01-31 2000-01-31 High-strength steel gas cylinder

Country Status (1)

Country Link
CN (1) CN1307202A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101818309A (en) * 2010-04-22 2010-09-01 山西太钢不锈钢股份有限公司 Air bottle steel and manufacturing method thereof
CN102277534A (en) * 2011-07-29 2011-12-14 攀钢集团有限公司 Hot rolled steel section for gas cylinders and production method thereof
CN102588734A (en) * 2012-03-06 2012-07-18 姜将 Manufacturing process of metal bottle with air-tight seal
CN104532142A (en) * 2014-10-27 2015-04-22 内蒙古北方重工业集团有限公司 40CrNi3MoV standard material

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101818309A (en) * 2010-04-22 2010-09-01 山西太钢不锈钢股份有限公司 Air bottle steel and manufacturing method thereof
CN102277534A (en) * 2011-07-29 2011-12-14 攀钢集团有限公司 Hot rolled steel section for gas cylinders and production method thereof
CN102277534B (en) * 2011-07-29 2012-12-12 攀钢集团有限公司 Hot rolled steel section for gas cylinders and production method thereof
CN102588734A (en) * 2012-03-06 2012-07-18 姜将 Manufacturing process of metal bottle with air-tight seal
CN102588734B (en) * 2012-03-06 2014-01-22 沈阳斯林达安科新技术有限公司 Manufacturing process of metal bottle with air-tight seal
CN104532142A (en) * 2014-10-27 2015-04-22 内蒙古北方重工业集团有限公司 40CrNi3MoV standard material

Similar Documents

Publication Publication Date Title
US5259200A (en) Process for the cryogenic treatment of metal containing materials
CN107042370B (en) A kind of high-Cr Ni-base high-temperature alloy welding wire and preparation process
JP3737105B2 (en) Method for manufacturing hollow body
NZ541874A (en) Thermostable and corrosion-resistant cast nickel-chromium alloy
EP2014378B1 (en) Process for producing stainless-steel pipe
CN1307202A (en) High-strength steel gas cylinder
CN114855057B (en) Production method of thin-specification high-toughness 12Cr1MoVR pressure vessel steel plate
CN103290182A (en) Thermal treatment process of low-alloy steel casting
CN101391288B (en) Tundish covering agent for smelting low-carbon high-cleanliness steel
CN104480261A (en) Spheroidizing annealing technology for wear-resistant double-metal lamination composite material
AU670114B2 (en) Aluminium alloy for hollow bodies under pressure
CN103184305B (en) Explosion-proof control method adopting electric precipitation for vanadium extraction in converter
CN102155626B (en) New method for using oxygen pipeline and spherical tank
CN106755851A (en) The Technology for Heating Processing of low alloy steel castings
EP0426367B1 (en) Steel composition
Korb et al. New iron-based ODS-superalloys for high demanding applications
CN113444859A (en) Double tempering treatment process method for 10Cr13Co13Mo5Ni3W1VE ultrahigh-strength stainless steel product
CN108774678A (en) The heat treatment method of super 13Cr tubing and casings
CN104846279A (en) Medium alloy oil well pipe and preparation method thereof
US4089679A (en) Steel alloy for zinc and aluminum die casting
Witkin et al. Design Philosophy of Pressure Vessels for Service Above 10 ksi (70 MPa)
CN115505850B (en) Alloy material, punching die and processing treatment process
RU2336133C1 (en) Method of chrome-containing steel hot working
CN117210668A (en) Heat treatment method for reducing fatigue crack growth rate of U76CrRE heat treated steel rail
CN106676443A (en) Vacuum heat treatment technology for magnesium alloy casting

Legal Events

Date Code Title Description
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C06 Publication
PB01 Publication
AD01 Patent right deemed abandoned
C20 Patent right or utility model deemed to be abandoned or is abandoned