CN1305869A - Catalyst for preparing 2-methylfuran by gas-phase hydrogenation of furaldehyde and its application - Google Patents
Catalyst for preparing 2-methylfuran by gas-phase hydrogenation of furaldehyde and its application Download PDFInfo
- Publication number
- CN1305869A CN1305869A CN 00120872 CN00120872A CN1305869A CN 1305869 A CN1305869 A CN 1305869A CN 00120872 CN00120872 CN 00120872 CN 00120872 A CN00120872 A CN 00120872A CN 1305869 A CN1305869 A CN 1305869A
- Authority
- CN
- China
- Prior art keywords
- gas
- furaldehyde
- catalyzer
- methylfuran
- preparing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 title claims abstract description 42
- VQKFNUFAXTZWDK-UHFFFAOYSA-N 2-Methylfuran Chemical compound CC1=CC=CO1 VQKFNUFAXTZWDK-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 238000005984 hydrogenation reaction Methods 0.000 title claims abstract description 9
- 239000003054 catalyst Substances 0.000 title abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 3
- 239000001257 hydrogen Substances 0.000 claims abstract description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 230000004913 activation Effects 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 abstract 2
- 230000003213 activating effect Effects 0.000 abstract 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 9
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 6
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 230000009466 transformation Effects 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 229910052728 basic metal Inorganic materials 0.000 description 2
- 150000003818 basic metals Chemical class 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000006200 vaporizer Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QKICWELGRMTQCR-UHFFFAOYSA-N 4-[(7-chloroquinolin-4-yl)azaniumyl]pentyl-diethylazanium;dihydrogen phosphate Chemical compound OP(O)(O)=O.OP(O)(O)=O.ClC1=CC=C2C(NC(C)CCCN(CC)CC)=CC=NC2=C1 QKICWELGRMTQCR-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- JACTTWVLMNPJQA-UHFFFAOYSA-N azane;quinoline Chemical compound N.N1=CC=CC2=CC=CC=C21 JACTTWVLMNPJQA-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000012450 pharmaceutical intermediate Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000012716 precipitator Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003407 synthetizing effect Effects 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Furan Compounds (AREA)
Abstract
Description
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN00120872A CN1089035C (en) | 2000-08-04 | 2000-08-04 | Catalyst for preparing 2-methylfuran by gas-phase hydrogenation of furaldehyde and its application |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN00120872A CN1089035C (en) | 2000-08-04 | 2000-08-04 | Catalyst for preparing 2-methylfuran by gas-phase hydrogenation of furaldehyde and its application |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1305869A true CN1305869A (en) | 2001-08-01 |
CN1089035C CN1089035C (en) | 2002-08-14 |
Family
ID=4588449
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN00120872A Expired - Lifetime CN1089035C (en) | 2000-08-04 | 2000-08-04 | Catalyst for preparing 2-methylfuran by gas-phase hydrogenation of furaldehyde and its application |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1089035C (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101961652A (en) * | 2010-10-14 | 2011-02-02 | 来安县迅能催化剂有限公司 | Catalyst for preparing 2-methyl furan through gas phase hydrogenation of furfural and preparation method thereof |
CN104549319A (en) * | 2013-10-24 | 2015-04-29 | 中国石油化工股份有限公司 | Catalyst for preparing 2-methyl furan through hydrogenating furfural gas phase and preparation method of catalyst |
CN106496165A (en) * | 2016-10-31 | 2017-03-15 | 中国科学院过程工程研究所 | A kind of method of catalyzed conversion furfural |
CN106902840A (en) * | 2015-12-22 | 2017-06-30 | 中国石油天然气股份有限公司 | Catalyst for preparing 2-methylfuran by furfural gas-phase hydrogenation and preparation method thereof |
CN110054602A (en) * | 2019-04-25 | 2019-07-26 | 黑龙江大学 | A kind of method of furfural hydrogenation 2- methylfuran |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5813576A (en) * | 1981-07-14 | 1983-01-26 | Sumitomo Chem Co Ltd | Production of 2,5-dimethylfuran |
CN1116610A (en) * | 1995-08-14 | 1996-02-14 | 青岛化工医药进出口股份有限公司 | Process for extracting sodium bichromate and copper nitrate from waste catalyst from preparation of furfuryl alcohol by hydrogenation of furfural |
CN1047100C (en) * | 1995-09-15 | 1999-12-08 | 中国石油化工总公司上海石油化工研究院 | Catalyst for furfural gas-phase hydrogenization synthetizing 2-methyl furan |
CN1256965A (en) * | 1999-11-10 | 2000-06-21 | 天津大学 | Catalyst for furfural hydrogasification producing furancarbinol and preparation process thereof |
-
2000
- 2000-08-04 CN CN00120872A patent/CN1089035C/en not_active Expired - Lifetime
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101961652A (en) * | 2010-10-14 | 2011-02-02 | 来安县迅能催化剂有限公司 | Catalyst for preparing 2-methyl furan through gas phase hydrogenation of furfural and preparation method thereof |
CN101961652B (en) * | 2010-10-14 | 2013-06-26 | 来安县迅能催化剂有限公司 | Catalyst for preparing 2-methyl furan through gas phase hydrogenation of furfural and preparation method thereof |
CN104549319A (en) * | 2013-10-24 | 2015-04-29 | 中国石油化工股份有限公司 | Catalyst for preparing 2-methyl furan through hydrogenating furfural gas phase and preparation method of catalyst |
CN106902840A (en) * | 2015-12-22 | 2017-06-30 | 中国石油天然气股份有限公司 | Catalyst for preparing 2-methylfuran by furfural gas-phase hydrogenation and preparation method thereof |
CN106902840B (en) * | 2015-12-22 | 2019-06-11 | 中国石油天然气股份有限公司 | Catalyst for preparing 2-methylfuran by furfural gas-phase hydrogenation and preparation method thereof |
CN106496165A (en) * | 2016-10-31 | 2017-03-15 | 中国科学院过程工程研究所 | A kind of method of catalyzed conversion furfural |
CN106496165B (en) * | 2016-10-31 | 2018-11-20 | 中国科学院过程工程研究所 | A kind of method of catalyzed conversion furfural |
CN110054602A (en) * | 2019-04-25 | 2019-07-26 | 黑龙江大学 | A kind of method of furfural hydrogenation 2- methylfuran |
Also Published As
Publication number | Publication date |
---|---|
CN1089035C (en) | 2002-08-14 |
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Legal Events
Date | Code | Title | Description |
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C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C06 | Publication | ||
PB01 | Publication | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: ZHONGKE OIL PROJECT CO., LTD. Free format text: FORMER OWNER: SHANXI INST. OF COAL CHEMISTRY, CHINESE ACADEMY OF SCIENCES Effective date: 20081017 |
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C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20081017 Address after: 3, building 1, Tsinghua Science and Technology Park, No. 609, Zhongguancun East Road, Beijing, Haidian District Patentee after: Synefuels China Inc. Address before: 165 mailbox, Taiyuan City, Shanxi Province Patentee before: Shanxi Institute of Coal Chemistry, Chinese Academy of Sciences |
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C56 | Change in the name or address of the patentee | ||
CP02 | Change in the address of a patent holder |
Address after: 101407 Beijing city Huairou District Yanqi Economic Development Zone C District No. 1 south two Street Park Patentee after: Synefuels China Inc. Address before: 100195, Haidian District Zhongguancun East Road, No. 1, building 3, Tsinghua Science and Technology Park, pioneering building, 609, Beijing Patentee before: Synefuels China Inc. |
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C56 | Change in the name or address of the patentee |
Owner name: SYNEFUELS CHINA CO., LTD. Free format text: FORMER NAME: SYNEFUELS CHINA INC. |
|
CP01 | Change in the name or title of a patent holder |
Address after: 101407 Beijing city Huairou District Yanqi Economic Development Zone C District No. 1 south two Street Park Patentee after: SYNFUELS CHINA Address before: 101407 Beijing city Huairou District Yanqi Economic Development Zone C District No. 1 south two Street Park Patentee before: Synefuels China Inc. |
|
CP03 | Change of name, title or address | ||
CP03 | Change of name, title or address |
Address after: 101407 Beijing city Huairou District Yanqi Economic Development Zone Park south two Street No. 1 Patentee after: SYNEFUELS CHINA Inc. Address before: 101407 Beijing city Huairou District Yanqi Economic Development Zone C District No. 1 south two Street Park Patentee before: SYNFUELS CHINA |
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CX01 | Expiry of patent term | ||
CX01 | Expiry of patent term |
Granted publication date: 20020814 |