CN1305365A - Leave-on hair compositions which contain diol - Google Patents
Leave-on hair compositions which contain diol Download PDFInfo
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- CN1305365A CN1305365A CN 99807343 CN99807343A CN1305365A CN 1305365 A CN1305365 A CN 1305365A CN 99807343 CN99807343 CN 99807343 CN 99807343 A CN99807343 A CN 99807343A CN 1305365 A CN1305365 A CN 1305365A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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Abstract
The present invention relates to a leave-on hair care composition comprising from about 3 % to 30 %, by weight, of a diol selected from the group consisting of 1,2 C5-C8-alkane diols, C2-C10-alkyl glyceryl ethers, and mixtures thereof; from about 70 % to about 97 %, by weight, of a polar solvent selected from the group consisting of water, C2-C3 monohydric alkanols, and mixtures thereof; and from about 0.015 to about 20 %, by weight, of a hair care ingredient.
Description
The cross reference of related application
The application enjoys the priority of U.S. Provisional Application number 60/091016 (inventor Daniel Wayne Michael and Errol Hoffman Wahl, application on June 29th, 1998) according to 35 USC § 119 (e) request; And the priority of U.S. Provisional Application number 60/110435 (inventor Daniel Wayne Michael and Errol Hoffman Wahl, December in 1998 application on the 1st).
Technical field
The present invention relates to the non-washing type Haircare composition, this Haircare composition can bring improved hair conditioning characteristic.This based composition contains and is selected from 1,2C
5-C
8Alkane diol or C
2-C
10The glycol of alkyl glycerol base ether.This series products can unexpectedly reduce the scared phenomenon of hair, and can not make hair that greasy feeling is arranged.These non-washing type hair products are easy to remove, and also can not accumulate on hair through using repeatedly.Said composition is applicable to as in the non-washing type articles for use such as hair tonic (tonics), hair spray, gel, mousse.
Background of invention
Hair because of contact with surrounding and because of the hair follicle sebum secreted dirty.The accumulation of sebum and environment dirt can make the hair dirt or greasy feeling is arranged, and be not attractive in appearance.For improving these effects, need hair washing regularly.
Hair washing can be removed excess sebum and environment dirt, but shortcoming is to make hair to have humidity, tangle and more not tractable situation.Frequent hair washing also can cause the hair drying because of having removed the moist composition of natural oils or other hairs.After the hair washing, can find that also hair lost " flexibility ".Frequent hair washing also can cause " sending out tip bifurcated " phenomenon, particularly long hair.Send out tip bifurcated and be meant and send out tip cracking to be divided into two or many dry, cause the hair outward appearance scared.
And many people's hair is volume from the beginning, and outward appearance is fluffy or scared.Many people are curly hair and/or hair dyeing regularly.Known this class is handled and generally can be made the hair drying, even the damage hair.The flexibility of impaired hair is poor, and has scared outward appearance.The scared people of hair outward appearance often wish to reduce the loft of hair to reduce scared outward appearance.It is scared that people generally adopt conventional conditioner to reduce.
Develop several different methods and be used for hair conditioning.Its scope does not wait to add the hair conditioning component in shampoo from washing post rinse agent, non-washing type hair conditioner water preparation and spray.Although many users would rather adopt the easy shampoo that contains conditioner, typical shampoo and conditioner mixture this in reducing damaged hair, sending out the hair of tip bifurcated or the opsonic action deficiency of the scared outward appearance aspect of the hair of volume from the beginning.
And, a large number of users select to use with hair washing mutually in the independent step (generally being) after the hair washing on hair, use conditioner composition.These hair conditioners generally are the i.e. eccysis formula conditioners of usefulness after the hair washing in the bathing process, or with the non-washing type conditioning products of the separate use of hair washing step.Eccysis formula conditioner generally contains the polysiloxanes conditioner or the quaternary ammonium compound that can be deposited on the hair.These conditioners generally are on the hair that is coated in moistening after the hair washing, eccysis from the hair then.But the beneficial effect deficiency of general eccysis formula conditioner to reducing the scared phenomenon of hair, providing for the scared user of hair.
The non-washing type conditioner according to the dispersing mode of hair product with gel, flood (tonics), hair spray or mousse form sell.These non-washing type conditioners generally also contain polysiloxane conditioner or quaternary ammonium compound.This class non-washing type conditioner generally can provide high-load conditioning compound.But when the non-washing type conditioner reduced scared phenomenon, the deposition of high-load quaternary ammonium compound and/or polysiloxanes can cause the oil slick of hair, greasy and dirty sense.And even hair washing regularly, general non-washing type conditioner still can be accumulated with use.These accumulations can be promoted greasy, the dirty sense of the hair that common product causes.
Polyhydric alcohol was widely used in the Haircare composition as wetting agent and moisturizing agent already.Find that after deliberation polyhydric alcohol comprises 1, the 2-hexanediol can impact the damage and the hair elasticity of hair, see people's work " polyhydric alcohol is to the effect of human hair " (" Japanese cosmetic The Chemicals " J.Soc.Cosmet.Chem.Jpn.31 (2), 167-175 (1997)) such as Hosokawa.Hosokawa proposes polyhydric alcohol such as glycerol, hexanediol and 3-methyl isophthalic acid, and the 3-butanediol can make hair have more elasticity.The permeability of polyhydric alcohol (for example 1,2-hexanediol) on hair that Hosokawa also proposes to contain long carbochain is higher.
Find among the present invention to contain 1,2C
5-C
8Alkane diol or C
2-C
10The non-washing type Haircare composition of alkyl glycerol base ether can provide enough opsonic actions, damages, sends out tip bifurcated to reduce or roll up the scared outward appearance of hair that causes from the beginning, and the usability of cleaning can be provided.The purpose of this invention is to provide the hair care composition, its can be after hair washing needn't rinsing, this hair care composition can provide the usability of conditioning property and cleaning simultaneously.
The present invention also aims to provide a kind of method of conditioning hair, specifically is to adopt above-mentioned composition to be used to reduce the scared outward appearance of hair.
According to content of the present invention described herein, these that the present invention is listed or other purposes and beneficial effect can be maybe will be clearly for a person skilled in the art.
Compositions of the present invention can contain described neccessary composition, and preferred or other optional components, is made up of it substantially or is made up of it.
Unless otherwise indicated, all percentage ratios among the present invention and ratio are all to account for the gross weight of compositions.Unless otherwise indicated, the percentage ratio of all components, ratio and content do not comprise being purchased solvent, filler or other impurity that exists in the product all in the actual content of composition.Unless otherwise indicated, all are measured all under 25 ℃ or room temperature and carry out.
Comprise that at these all documents of quoting all patents, all patent applications, all articles, all communiques, all pamphlets and technical data sheet are all in full in conjunction with in the present invention as a reference.
Summary of the invention
The present invention relates to the non-washing type Haircare composition, comprising the C of about 3-30% (weight)
2-C
10Alkyl glycerol base ether; The polar solvent of about 70-97% (weight) is selected from water, C
2-C
3Monohydric alcohol and their mixture.The invention still further relates to and comprise 1 of about 3-30% (weight), 2C
5-C
8Alkane diol; The compositions of the polar solvent of about 70-97% (weight), polar solvent are selected from the non-washing type carrier that contains hair care ingredient, comprise C
2-C
3Monohydric alcohol, and C
2-C
3The mixture of monohydric alcohol and water.
Other embodiment of the present invention relates to the non-washing type Haircare composition, comprising the glycol of about 3-30% (weight), is selected from 1,2C
5-C
8Alkane diol, C
2-C
10Alkyl glycerol base ether and their mixture; The polar solvent of about 70-97% (weight) is selected from water, C
2-C
3Monohydric alcohol and their mixture; And the hair care ingredient of about 0.015-20% (weight), be selected from conditioner, non-ionic surface active agent, thickening agent, essence, antiseptic, pH regulator agent, coloring agent, propellant, vitamin and derivant thereof, vitamin penetrant, hair spray spraying regulator, and their mixture; Wherein the content of hair Reducing agent is lower than about 0.1% in the Haircare composition.
Detailed Description Of The Invention
The term that is used to modify term " Haircare composition " " non-washing type " described here is meant that compositions of the present invention can be used for hair and is retained in hair.This class non-washing type compositions is different from " eccysis formula " compositions, and the latter can be used for hair, needs then to remove in modes such as washing, rinsing, wipings at once or after a few minutes.For reaching the hair conditioning effect, compositions of the present invention must be after reservation on the hair be done to hair at least.
Non-washing type compositions of the present invention can be the various product forms that can be used for hair and needn't remove.Product forms optional from gel, flood, emulsion (lotions), mousse and hair spray.
Below be description to the non exhaustive example of neccessary composition and preferred and optional member:
Glycol
Comprise about 3-30% (weight), preferably about 4-25% (weight), more preferably from about 5-20% (weight), the glycol of 7-15% (weight) most preferably from about in the present composition.This glycol can be 1,2C
5-C
8Alkane diol, C
2-C
10Alkyl glycerol base ether or their mixture.
1,2C
5-C
8Alkane diol is shown below:
R
1-CHOH-CH
2OH
R wherein
1Be propyl group, butyl, amyl group or hexyl.R
1Can be straight or branched group, preferably straight chain.Preferred alkane diol is 1, the positive pentanediol of 2-, 1, the positive hexanediol of 2-, 1, positive heptandiol of 2-or their mixture.Most preferably 1, the positive hexanediol of 2-, wherein R1 is a normal-butyl.
C
2-C
10Alkyl glycerol base ether is following formula: compound:
R
2-O-CH
2-CHOH-CH
2OH
R wherein
2Be ethyl, propyl group, butyl, amyl group, hexyl, heptyl, octyl group, nonyl or decyl.R
2Can be the straight or branched group, preferred straight chain.Preferred glyceryl ether be n-pro-pyl-, normal-butyl-, n-pentyl-, n-hexyl glyceryl ether, and their mixture.N-hexyl glyceryl ether most preferably.
Polar solvent
Also comprise polar solvent in the non-washing type Haircare composition of the present invention as the glycol liquid-carrier.Polar solvent be 25 ℃ of following dielectric constants greater than about 5.0, be preferably greater than solvents about 7.5, more preferably greater than about 10.0.Polar solvent of the present invention comprises one or more polar solvents that accounts for the about 70-97% of Haircare composition total amount (weight), preferably is about 80-95% (weight), is more preferably 85-93% (weight).
The basic polar solvent of the present composition is selected from water, C
2-C
3Monobasic alkanol and their mixture.If there is C
3The consumption of alkanol such as isopropyl alcohol should preferably not be not more than about 12% (weight), more preferably no higher than about 10% (weight) greater than about 15% (weight) of compositions.High-load C
3Monohydric alcohol is not suitable for the present invention, because of it may produce abnormal flavour.Preferred polar solvent contains water, ethanol or their mixture in mutually.
When adopting the mixture of water and alcohol, for example can adopt water-ethanol or water-isopropyl alcohol-ethanol, the content of water generally accounts for the 0.5-99% (weight) of compositions in the compositions.In this mixture, alcoholic solvent generally accounts for 0.5% (weight) of total composition to about 99% (weight).
Hair care ingredient
Compositions of the present invention can comprise various additional hair care ingredients, is used to make compositions to have more beauty treatment property or aesthetic property, or makes it have additional useful result of use." CTFA cosmetic composition handbook has been described the various indefiniteness beauty treatment compositions of taking care of hair industrial that are usually used in the 2nd edition (1992), and its full text combination in the present invention as a reference.These supplementary elements comprise: other conditioners; Surfactant is as anion, nonionic, both sexes and zwitterionic surfactant; Thickening agent such as xanthan gum, guar gum, hydroxyethyl-cellulose, methylcellulose, hydroxyethyl-cellulose, starch and starch derivatives, Carbomers ; Essence; Antiseptic; Polymer; The pH regulator agent; Coloring agent is as FD﹠amp; C or D﹠amp; Any in the C dyestuff; Polymeric plasticizer, as glycerol, diisobutyl adipate, butyl stearate and propylene glycol; Propellant; Vitamin and derivant thereof are as pantothenylol and other pantothenic acid derivatives, pantothenic acid ether; The vitamin penetrant, as contain 3 to about 12 ethylene glycol or unitary Polyethylene Glycol of propylene glycol or polypropylene glycol, hair spray spraying regulator is as having the Polyethylene Glycol of about 2000-25000 ethylene glycol unit.The independent consumption of this class optional member generally accounts for about 0.01-20.0% (weight) of compositions, preferably be about 0.05-15.0% (weight), be more preferably 0.1-10% (weight), be more preferably 0.5-8% (weight), be most preferably 1-5% (weight).Detailed description to preferred hair care ingredient sees below.
Essence/antiseptic
Contain essence and antiseptic in the preferred non-washing type Haircare composition.The present invention is when adopting glycol to reduce scared phenomenon and reaching cleaning effect, and the essence that adopts known in the art is used to make hair to have the good aroma.The consumption of essence is about 0.01-4% (weight) in the present composition, preferably is about 0.05-2.5% (weight).
The non-limiting example that is applicable to the antiseptic of non-washing type compositions of the present invention has: benzylalcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate, dimethyl dihydroxymethyl hydantoin, methyl chloride isothiazoline, Methylisothiazolinone and imidazolidinyl urea.The consumption of antiseptic is about 0.001-1% (weight) in the present composition.
Anion surfactant
Can comprise a spot of anion surfactant in the preferred compositions of the present invention.The consumption of anion surfactant is about 0.01-2%, preferably is about 0.05-1%, is more preferably 0.1-0.5%.Be applicable to that the non-limiting example of the anion foaming surfactant of the present composition sees McCutcheon " detergent and emulsifying agent ", North America version (1990) (publication of ManufacturingConfectioner Publishing company); " functional components " of McCutcheon, North America version (1992); And United States Patent (USP) 3929678 (people such as Laughlin, December in 1975 application on the 30th), all in conjunction with in the present invention as a reference.
Various anion surfactants all may be used for the present invention.The non-limiting example of anion foaming surfactant is selected from: alkyl and alkyl ether sulfate, sulphated monoglycerides, sulfonation alkene, alkylaryl sulfonate, uncle's alkane or secondary paraffin sulfonate, alkyl sulfo succinate, acyl taurine salt, acyl isethinate, alkyl glyceryl ether sulfonate, sulfonated formate, alpha-sulfonated fatty acid, alkylphosphonic, acyl glutamate, acyl sarcosinates, salts of alkyl sulfoacetates ester, acetylation polypeptide, alkyl ether carboxy acid salt, acyl-lactate, and anion fluorinated surfactants.Anion surfactant mixture also can be effectively with in the present invention.The preferred anionic surfactants surfactant is alkyl and alkyl ether sulfate.Most preferably ammonium lauryl sulfate and sodium lauryl sulfate.
Non-ionic surface active agent
Preferred compositions of the present invention can contain non-ionic surface active agent.The ionic surfactant pack that is applicable to this is drawn together any known non-ionic surface active agent, and it at room temperature is a liquid, and according to the kind of selected non-ionic surface active agent, its HLB is about 4-20.
Can comprise about 0.01-20% in the non-washing type Haircare composition of the present invention, preferably about 0.1-5%, the more preferably from about surfactant of 0.5-3%.
The non-ionic surface active agent of two quasi-representatives is pure and mild alkyl pyrrolidones of alkoxylate (particularly ethoxylation) etc., and they all are to know in the surfactant field.This class non-ionic surface active agent generally contains C
4-22, preferred C
6-16, more preferably whole C
8-14Alkyl.Also preferably contain C
18: 1Group, the oil base thiazolinyl, non-ionic surface active agent.Ethoxylated surfactant generally contains 2-12 approximately, is preferably 2.5-10,3-8 ethylene oxide group more preferably, so that the HLB of gained is about 4-10, preferably is about 5-9, is more preferably 6-8.Ethoxylated alcohol is particularly preferred in the present composition.
The particular instance of ethoxylated non-ionic surface active agent comprises: octyl group polyethoxy thing (2.5) and (5); Decyl polyethoxylate (2.5) and (5); Decyl polyethoxylate (6); Dodecyl polyethoxylate (3), tridecyl polyethoxylate (3), Oleum Cocois alkyl polyethoxylate (6.5), oil base polyethoxylate (3), and their mixture.
The present invention also is preferably the non-ionic surface active agent of propylene glycol and ethylene glycol block copolymer.This class non-ionic surface active agent is shown below:
R(EO)
n(PO)
m(EO)
nR
Wherein EO is an ethylene oxide, and PO is a propylene oxide, selects each n and m to make the total molecular weight of surfactant be about 200-8000, and each R is selected from H (preferably), and alkyl, preferably C
1-4Alkyl.This class surfactant can change n and m, makes EO content difference.The HLB value of this class surfactant generally is about 4-10 according to needs of the present invention, preferably is about 5-9, is more preferably 6-8.
The above-mentioned all kinds of inventory that is applicable to the non-ionic surface active agent of non-washing type Haircare composition of the present invention is found in United States Patent (USP) 4557853 (Collins, December was authorized on the 10th in 1985), in conjunction with in the present invention as a reference.The source that is purchased of this class surfactant is found in " detergent and emulsifying agent " the North America version (1984) of McCutcheon, McCutcheon branch company, and MC publishing company is also in conjunction with in the present invention as a reference.
The total molecular weight of preferred propylene glycol and ethylene glycol block copolymer is about 3000-10000, preferably be about 4000-8000, and each R is selected from H (preferably) and alkyl, preferably C
1-4Alkyl.The EO content of these preferred nonionic is about 20-80%, preferably is about 20-40%.
The total molecular weight of the block copolymer of other preferred propylene glycol and ethylene glycol is about 200-2000, preferably is about 500-1000, and R is H, and it is about 50% that EO content is lower than, and preferably is lower than approximately 10%, most preferably is 0%, promptly contains 100% polypropylene glycol.
Also preferred nonionic silicones surfactant among the present invention is as polysiloxanes copolyol (silicone copolyol) or polydimethylsiloxane.
Be applicable to that polydimethylsiloxane of the present invention sees Gruning, B and Koerner, (Tenside Surf.Det.26 (1989) 5 for G work " polysiloxane surfactant ", 312-317), and Schaefer, D work " polysiloxane surfactant " (Tenside Surf.Det.27 (1990) 3,154-158), and in conjunction with in the present invention as a reference.This class polysiloxane surfactant is shown below:
Wherein R and R
1Be hydrophilic modifying group, R
2Be oleophylic modification group.The hydrophilic modifying group must be more than oleophylic modification group in the preferred polysiloxane surfactant.N can be about 5-26, preferably is about 10-20, m
1Be about 1-10, preferably be about 3-7, m
2Can be 0,1 or 2, preferred 0.
The hydrophilic modifying group is preferably as follows shown in the formula:
-(CH
2)
3-O(EO)
x(PO)
y-H
Wherein EO is that ethylene oxide and PO are propylene oxides, and selects to make the molecular weight of hydrophilic modifying group to be about 300-1000 to x and y.The HLB of preferred polysiloxane surfactant is about 10-20, preferably is about 15-19, and cloud point (1% aqueous solution) is about 10 ℃-100 ℃, preferably is about 50 ℃-90 ℃.
Preferred polysiloxane surfactant has the formula shown in the formula (2), wherein R
1Be shown below:
-(CH
2)
3-O(EO)
x(PO)
y-H
N is 13-20, m
1Be 5, m
2Be 0, can change x and y makes EO: the ratio of the molecular weight of PO is about 75: 25 to about 100: 0, and the total molecular weight of polysiloxane surfactant is about 2000-10000.The most preferably example of this class polysiloxane surfactant is Abil B8843 and the Abil B8851 that GoldschmidtChemical company makes.
Polysiloxane grafted polymer
Also preferably contain silicone-grafted copolymers in the non-washing type Haircare composition of the present invention.When adopting this class silicone-grafted copolymers, its consumption is about 0.1-5%, preferably is about 0.25-2%, is more preferably 0.5-1%.
This quasi-graft copolymer can be prepared by multiple methods known in the art, comprising:
1. in radical polymerization, introduce the polysiloxanes macromonomer
Comprise silicone-grafted copolymers and preparation method thereof in this functional polyorganosiloxane polymer of birdsing of the same feather flock together, can be referring to United States Patent (USP) 5658557 (people such as Bolich, on August 19th, 1997 authorized), United States Patent (USP) 4693935 (Mazurek, JIUYUE was authorized on the 15th in 1987), and United States Patent (USP) 4728571 (people such as Clemens, on March 1st, 1988 authorized), all in conjunction with in the present invention as a reference.
2. in the atom transfer radical polymerization, introduce the polysiloxanes macromonomer
The method for preparing this base polymer generally sees people's works such as Beers " application of " activity " radical polymerization in graft copolymer is synthetic " (Polymer Preprints, in March, 1996) 571-572 page or leaf, in conjunction with in the present invention as a reference.
3. be introduced on the polysiloxane backbone above by chain transfer reaction polyvinyl being grafted to the sulfydryl that dangles
The polysiloxane copolymer that this class connects by sulfur sees United States Patent (USP) 5468477 (people such as Kumar, authorize November 21 nineteen ninety-five), with PCT patent application WO 95/03776 (transfer 3M, February 9 nineteen ninety-five is open), all the full text combination in the present invention as a reference.Other patents that comprise the structure that connects by sulfur comprise United States Patent (USP) 5032460 (people such as Kanter, authorized on July 16th, 1991, transfer 3M), and United States Patent (USP) 5362485 (people such as Hayama, on November 8th, 1994 authorized, and transferred Mitsubishi chemical company).
Polysiloxane grafted polymer is characterised in that the polysiloxanes part links to each other with the polymerization carbon based backbone through covalent bond, and is its side group.Main chain is preferably the carbochain that the ethylenically unsaturated monomer polymerization forms, but also can be the polymer chain that cellulose chain or other carbohydrate obtain, and wherein contains the polysiloxanes part as side group.Main chain also can comprise ether, i.e. C-O-C.Polysiloxanes part can be substituted with polymer and be connected, or is obtained by polymerisable monomer that contains polysiloxanes (for example ethylenically unsaturated monomer, ether and/or epoxide) and the polymerisable monomer copolymerization that do not contain polysiloxanes.
The weight average molecular weight of polysiloxane grafted polymer should be about 20,000 at least.In needs are implemented the scope of factors such as practicality of the present invention such as method, aesthetic characteristic, the property prepared, its molecular weight there is not special ceiling restriction.It is about 10,000,000 that its weight average molecular weight generally is lower than, and more generally is lower than approximately 5,000,000, typically is lower than about 3,000,000.Preferable weight-average molecular weight is about 50,000-2, and 000,000, be more preferably 75,000-1,000,000, be most preferably 100,000-750,000.
Film forming Tg and Tm are at least about-20 ℃ after the preferred graft polymers mummification of the present invention, preferably are at least about 20 ℃, and it can not crossed sticking or touch " being clamminess " like this.Transform if polymer exists, the abbreviation of Cai Yonging here " Tg " is meant the vitrification point of the non-silicone main chain of polymer, and abbreviation " Tm " is meant the crystalline melt point of non-silicone main chain.If have Tg and Tm, then preferred Tg and Tm are higher than-20 ℃ approximately, more preferably are higher than about 20 ℃.
The polysiloxane grafted polymer that is applicable to the present composition comprises " containing polysiloxanes " monomer of the polysiloxanes macromonomer side group that constitutes main chain, also comprises the monomer that does not contain polysiloxanes of the organic main chain that constitutes polymer.
Preferred polysiloxane grafted polymer contains organic main chain, the carbon backbone chain that makes of ethylenically unsaturated monomer preferably, as the vinyl polymerization main chain, also contain the polysiloxanes macromonomer (preferred especially polydialkysiloxane, most preferably polydimethylsiloxane) that is grafted on the main chain.The weight average molecular weight of polysiloxanes macromonomer should be about 500 at least, preferably is about 1000-100000, is more preferably 2000-50000, is most preferably 5000-20000.Organic main chain of imagination comprises derived from those of polymerizable ethylenically unsaturated monomer, and monomer comprises vinyl monomer and other polycondensation monomers (for example polymerizable forms the monomer of polyamide and polyester), open loop monomer (for example ethyl oxazoline and in oneself ketone) etc.This organic main chain can also be based on the main chain of cellulose chain, contains the main chain of ether etc.
The example of polymer that is suitable for and preparation method thereof specifically is found in United States Patent (USP) 4693935 (Mazurek, JIUYUE was authorized on the 15th in 1987) and United States Patent (USP) 4728571 people such as (, on March 1st, 1988 authorized) Clemens, all in conjunction with in the present invention as a reference.
The polysiloxane grafted polymer that is suitable for is also shown in european patent application 90307528.1, be disclosed as the open 0408311A2 of european patent application (people such as Hayama, on January 11st, 1991 is open), United States Patent (USP) 5061481 (people such as Suzuki, on October 29th, 1991 authorized), United States Patent (USP) 5106609 (people such as Bolich, on April 21st, 1992 authorized), United States Patent (USP) 5100658 (people such as Bolich, on March 31st, 1992 authorized), United States Patent (USP) 5100657 (people such as Ansher-Jackson, on March 31st, 1992 authorized), United States Patent (USP) 5104646 (people such as Bolich, on April 14th, 1992 authorized), U.S. Patent application 07/758319 (people such as Bolich, application on August 27th, 1991), U.S. Patent application 07/758320 (people such as Torgerson, application on August 27th, 1991), these are all in conjunction with in the present invention as a reference.
Preferred polysiloxane grafted polymer comprises following monomeric unit: at least a can be through the ethylenically unsaturated monomer of radical polymerization, and at least a can be through the ethylenically unsaturated monomer that contains polysiloxanes of radical polymerization.
Polysiloxane grafted polymer of the present invention generally contains the monomeric unit that contains polysiloxanes of 1-50% (weight) approximately, promptly contains the monomeric unit (being called " C " monomer here) of silicone monomers and the monomer that does not contain polysiloxanes of about 50-99% (weight).
The monomeric unit that does not contain polysiloxanes can be from polarity or hydrophilic monomer " A " monomer, or the monomeric mixture of polar hydrophilic and low polarity or hydrophobic monomer " B " monomer.
Hydrophobic monomer is meant the monomer that can form water-fast substantially homopolymer.Hydrophilic monomer is meant the monomer that can not form water-fast substantially homopolymer.Substantially the water-soluble homopolymer that is meant that monomer forms dissolves in distilled water (or suitable water) under 25 ℃, concentration of ordinary dissolution is 0.2% (weight), is preferably 1.0% (weight).Substantially the water insoluble homopolymer that is meant that monomer forms can not be dissolved in distilled water (or suitable water) with 0.2% (weight) concentration down at 25 ℃, does not preferably dissolve with 0.1% (weight) concentration.Be used to measure basic water solublity or water-insoluble weight average molecular weight should be about 100000, but, also should adopt it at 100000 o'clock at about dissolubility for the solubility test of heavy polymer.
The monomeric concrete amount ratio of A, B and C is variable, as long as main polymer chain dissolves in polar solvent of the present invention, and can occur being separated after the silicone-grafted copolymers mummification getting final product.
The monomeric representative instance of A comprises: acrylic acid, methacrylic acid, N, the N-DMAA, dimethyl amino ethyl methacrylate, quaternised dimethyl amino ethyl methacrylate, Methacrylamide, N tert butyl acrylamide, maleic acid, maleic anhydride and half ester thereof .beta.-methylacrylic acid, the itaconic acid, acrylamide, acrylate alcohol (acrylate alcohols), hydroxyethyl meth acrylate, diallyldimethylammonium chloride, vinyl pyrrolidone, vinyl ethers (as methyl vinyl ether), maleimide, vinylpyridine, vinyl imidazole, other polar vinyl heterocycles, styrene sulfonate, 1-propenol-3, vinyl alcohol (forming), caprolactam as vinyl-acetic ester polymerization posthydrolysis, the salt of above-mentioned acid and amine, and their mixture.Preferred A monomer comprises acrylic acid, N,N-DMAA, the salt of dimethyl amino ethyl methacrylate, quaternary ammoniated dimethyl amino ethyl methacrylate, vinyl pyrrolidone, above-mentioned acid and amine, and their mixture.
The monomeric representative instance of B is the C of acrylic or methacrylic acid
1-C
18Alcohol ester, alcohol is as methanol, ethanol, methyl cellosolve, the 1-propanol, the 2-propanol, the 1-butanols, 2-methyl isophthalic acid-propanol, the 1-amylalcohol, the 2-amylalcohol, the 3-amylalcohol, 2-methyl-1-butene alcohol, 1-methyl isophthalic acid-butanols, 3-methyl isophthalic acid-butanols, 1-methyl-1-pentene alcohol, 2-methyl-1-pentene alcohol, 3-methyl-1-pentene alcohol, the tert-butyl alcohol (2-methyl-2-propanol), Hexalin, new decanol, 2-ethyl-1-butanols, the 3-enanthol, benzylalcohol, sec-n-octyl alcohol, 6-methyl isophthalic acid-enanthol, 2-ethyl-1-hexanol, 3,5-dimethyl-1-hexanol, 3,5,5-trimethyl-1-hexanol, 1-decanol, the 1-dodecanol, the 1-hexadecanol, 1-octadecanol etc., these pure carbon numbers are about 1-18, and preferred carbon number is about 1-12; Styrene, the polystyrene macromolecular monomer; Vinyl-acetic ester; Vinyl chloride; Vinylidene chloride; Propionate; α-Jia Jibenyixi; T-butyl styrene; Butadiene; Cyclohexadiene; Ethylene; Propylene; Vinyltoluene; And their mixture.Preferred B monomer comprises n-BMA, isobutyl methacrylate, tert-butyl acrylate, metering system tert-butyl acrylate, methacrylic acid 2-Octyl Nitrite, methyl methacrylate, and their mixture.Most preferably B is selected from tert-butyl acrylate, metering system tert-butyl acrylate, and their mixture.
The polymerisable available following general formula illustration of monomer (C monomer) that contains polysiloxanes:
X(Y)
nSi(R)
3-mZ
m
Wherein X be can with the ethylenically unsaturated group of A and B monomer copolymerization, as vinyl; Y is a divalent linker; R is H, hydroxyl, low alkyl group (C for example
1-C
4Alkyl), aryl, alkaryl, alkoxyl or alkyl amino; Z is that number-average molecular weight is at least about 500 monovalence siloxane polymer part, and it does not react under copolymerization conditions substantially, and is the side group of above-mentioned vinyl polymerization main chain; N is 0 or 1; M is the integer of 1-3.The weight average molecular weight of C as mentioned above.Preferred C monomer has and is selected from following structural formula:
X-Si (R
4)
3-mZ
m(II)
In the said structure formula, m is 1,2 or 3 (preferred m=1); P is 0 or 1, preferred 0; R " is alkyl or H; Q is the integer of 2-6 in various except that (III); Q is the integer of 0-6 in (III); X is:
R
1Be H or-COOH; R
2Be H, methyl or-CH
2COOH; Z is
R
4Be alkyl, alkoxyalkyl amino, aryl or hydroxyl (preferred R
4Be alkyl), and r is the integer that is about 5-700.
What polysiloxane grafted polymer generally comprised the 50-99% that accounts for polymer weight does not contain the macromolecular monomeric unit of polysiloxanes, the unitary total amount of A and B for example, and more preferably it is about 60-98%, is most preferably 75-95%; And the monomeric unit that contains the polysiloxanes macromonomer that comprises about 1-50%, C monomeric unit for example, preferably it is about 1-40%, is more preferably 2-25%.The content of A monomeric unit can be about 1-99%, preferably about 5-80%, more preferably from about 10-50%, most preferably from about 15-40%; The content of B monomeric unit is about 0-99%, preferably is about 1-90%, is more preferably 5-85%, is most preferably 15-80%; The content of C monomeric unit is about 1-50%, preferably is about 1-40%, is more preferably 2-25%.
The specific composition of polysiloxane grafted polymer helps to determine its preparation characteristic.By suitable selection and the combination to A, B and C component, polysiloxane grafted polymer can optimum performance add in the specific support.The main chain of polysiloxane grafted polymer in the present composition (polysiloxane grafted polymer hereinafter referred to as) should dissolve in the polar solvent, does as a whole being dissolved in the polar solvent.This according to polymer under 25 ℃ with its in compositions concentration or in the concentration range of above-mentioned polysiloxane grafted polymer, whether can exist in solution or from solution, be precipitated out decision.Those skilled in the art can select in the preparation performance and the dissolubility of selected polar solvent system the monomer that is used for polymer.
Be applicable to that typical polysiloxane grafted polymer of the present invention comprises following composition:
(ⅰ) macromonomer of acrylic acid/n-BMA/polydimethylsiloxane (PDMS) macromonomer-molecular weight 20000
(ⅱ) macromonomer of dimethylaminoethyl acrylate methyl base amino-ethyl ester/isobutyl methacrylate/methacrylic acid 2-Octyl Nitrite/PDMS macromonomer-molecular weight 20000
(ⅲ) macromonomer of tert-butyl acrylate/acrylic acid/PDMS macromonomer-molecular weight 10000
(ⅳ) macromonomer of tert-butyl acrylate/acrylic acid/PDMS macromonomer-molecular weight 20000
Propellant
Also contain propellant in aerosol type hair spray and the mousse product dosage form.During application, the consumption of propellant accounts for the 3-15% of non-washing type Haircare composition, preferably is about 5-12%.Propellant can contain hydrocarbon propellants, is selected from propane, normal butane, iso-butane, pentane, isopentane and hexane, and their mixture, or the non-hydrocarbons propellant, is selected from carbon dioxide, nitrogen oxide (N particularly
2O), fluorohydrocarbon, fluorine chlorohydrocarbon, and their mixture, or the mixture of hydro carbons and non-hydrocarbons propellant.Preferred propellant is at the industrial A-46 that is called as, and it is the mixture of normal butane, iso-butane and propane, and its ratio is selected, thereby the vapour pressure of this mixture under 70 is 46psig.Another is preferred for propellant of the present invention and contains 85% isopentane and 15% iso-butane.
When not adopting propellant, non-aerosol compositions can have standard non-aerosol type atomizing pump or add air or gas mixing apparatus on its packing, is used to obtain the non-aerosol foam.
The polysiloxanes conditioner
Also can randomly contain the polysiloxane conditioner in the Haircare composition of the present invention, comprise non-volatile solvable or insoluble polysiloxanes conditioner, or the Y 7175 conditioner.But the consumption of polysiloxanes conditioner must be very low.The consumption of polysiloxanes conditioner in Haircare composition is lower than about 1% (weight), preferably is lower than 0.5% (weight), more preferably less than 0.25% (weight).Haircare composition most preferably of the present invention does not contain the polysiloxanes conditioner substantially.Substantially do not contain the consumption that is meant polysiloxanes conditioner in the non-washing type Haircare composition and be lower than about 0.1%.Employing is higher than 1% polysiloxanes conditioner can cause the deposition that is higher than required deposition, causes dirty greasy feeling.And the high deposition of polysiloxanes can cause scale problems in the disposable product.
The polysiloxanes conditioner is well known in the art.The list of references that discloses suitable silicone conditioning agent comprises United States Patent (USP) 5674478 (Dodd); United States Patent (USP) 2826551 (Geen); United States Patent (USP) 3964500 (Drakoff); United States Patent (USP) 4364837 (Pader); And United States Patent (USP) 4152416 (people such as Spitzer).These patents are all in conjunction with in the present invention as a reference.
The quaternary ammonium conditioner
Also can randomly comprise the quaternary ammonium conditioner in the hair conditioner component of Haircare composition of the present invention.But the consumption of quaternary ammonium conditioner in non-washing type Haircare composition of the present invention must be very low.The preferred consumption of quaternary ammonium conditioner in Haircare composition is lower than about 2% (weight), preferably is lower than 1.0% (weight), more preferably less than 0.5% (weight).Preferred Haircare composition of the present invention does not contain the quaternary ammonium conditioner substantially.Substantially do not contain the consumption that still is meant quaternary ammonium conditioner in the non-washing type Haircare composition and be lower than about 0.1%.Employing is higher than 1% quaternary ammonium conditioner can cause the deposition that is higher than required deposition, causes the dirty greasy feeling of hair.And can cause scale problems.
The quaternary ammonium conditioner that is applicable to this comprises: the quaternary ammonium compound that ester replaces, as monoesters, diester and three ester quaternary ammonium compounds; And the quaternary ammonium compound of amide replacement, as monoamides, diamides and Disnalon (Ferrer). quaternary ammonium compound, but be not limited only to this.The quaternary ammonium conditioner also comprises dialkyl dimethyl ammonium chloride, and wherein alkyl contains 12-22 carbon atom, derivation of self-long chain fatty acid such as hydrogenated tallow approximately.
The hair Reducing agent
Do not contain any hair Reducing agent in the non-washing type Haircare composition of the present invention; comprise TGA, TGA derivant, cysteine, N-acyl group cysteine, the salt of these chemical compounds, thioglycerol base alkyl ether; mercaptoalkyl amide, sulphite and bisulfites.The application of this class hair Reducing agent may damage hair, and in fact can make scared phenomenon more serious.The content of this class Reducing agent is lower than 0.1% in the compositions of the present invention, preferably is lower than 0.01%.
Preparation method
Non-washing type Wo 2008069000 of the present invention can be prepared by the various technology that are used to prepare personal cleansing product well known in the art.
Using method
Non-washing type Haircare composition of the present invention can be used in a usual manner to reach the effect that the present invention reduces scared phenomenon.This class using method is decided according to the type of composition therefor, but generally comprises the product of the safe and effective amount of coating on user's hair of needs nursing, and combing or brush hair is treated the hair mummification or made the hair mummification." effective dose " is meant and can reaches enough consumptions of sending out nursing efficacy.Generally on hair, apply about 1-50g.Generally embrocating or massage hair and scalp, the combing of another hands or brush hair by a hands makes compositions spread all over hair.
Preferably before the hair mummification, compositions is coated on the hair of moistening or humidity.After compositions is coated on the hair, combing or brush hair and make hair form the required hair style of user, mummification then.Or compositions is coated in do sends out, brush then or moulding forms the required hair style of user, then mummification or make its mummification.
Embodiment
Following examples are used to illustrate the present invention.Under the condition that does not deviate from spirit and scope of the invention, the technical staff in hair care formulations field can change the present invention.
Unless otherwise indicated, all umbers, percentage ratio and ratio are all by weight.Some component can be the dilute solution form that is purchased.Unless otherwise indicated, the content that provides is with the weight percent meter of active component.
Hair caring hair oil (Hajr Grooming Tonic)
Below be the typical hair caring hair oil of the present invention.
Embodiment component (weight %) 12345 61,2 pentanediols 0.00 10.00 0.00 0.00 0.00 0.001,2 hexanediol, 15.00 0.00 0.00 12.00 4.00 0.00 n-hexyl glyceryl ethers, 0.00 0.00 10.00 0.00 6.00 6.001,2 ethohexadiols, 0.00 2.00 5.00 0.00 0.00 0.00C
12/ C
13Polyethoxylate (3) 0.00 0.00 0.00 1.00 0.00 0.00 Texapon Specials 0.00 0.00 0.00 0.00 0.25 0.10 propane diols (molecular weight 725) 0.00 0.00 0.00 0.00 1.00 0.00Abil B8843 0.00 0.00 0.00 0.00 0.00 2.50 silicone-grafted copolymers 1 0.00 0.75 0.00 0.50 0.00 0.50 essence 0.10 0.10 0.10 0.10 0.20 0.20 anticorrisive agent 0.15 1.50 0.15 0.15 0.34 0.34 ethanol 0.00 81.40 70.00 0.00 0.00 0.00 water 84.75 4.25 14.75 86.25 88.21 90.36 100.00 100.00 100.00 100.00 100.00 100.00
1-60% tert-butyl acrylate/20% acrylic acid/20% polysiloxanes macromonomer (weight average molecular weight is about 10000 macromonomer), weight average molecular weight is about 150000.
Can be by conventional methods with the mixed jointly preparation compositions of said components.This based composition can provide the non-washing type hair products of usefulness, can reduce the scared situation of hair.
Non-aerosol type hair spray
Adopt following component to prepare non-aerosol type hair conditioning hair spray compositions of the present invention:
Embodiment number
Component (weight %) 789 10 11 12 13
1,2 pentanediol 10.00 0.00 10.00 0.00 0.00 0.00 0.00
1,2 hexanediol 0.00 12.00 0.00 0.00 0.00 4.00 0.00
N-hexyl glyceryl ether 0.00 0.00 0.00 25.00 10.00 6.00 6.00
1,2 ethohexadiol 0.00 1.00 5.00 2.00 5.00 0.00 0.00
Ammonium lauryl sulfate 0.00 0.00 0.00 0.00 0.00 0.25 0.10
Propylene glycol (molecular weight 725) 0.00 0.00 0.00 0.00 0.00 1.00 0.00
AbilB8851 0.00 0.00 0.00 0.00 0.00 0.00 2.50
Silicone-grafted copolymers 1 0.00 0.75 0.00 0.50 0.00 0.50 0.75
Antiseptic 0.35 0.35 0.35 0.35 0.35 0.35 0.35
Essence 1.00 1.00 1.00 1.00 0.05 0.20 0.20
Ethanol 0.00 70.00 0.00 70.00 0.00 0.00 0.00
Pantothenylol 0.05 0.02 0.00 0.02 0.05 0.00 0.00
Water 88.60 14.88 83.65 1.13 84.55 87.70 90.10
100.00?100.00?100.00?100.00?100.00?100.00?100.00
1-60% n-butyl acrylate/20% acrylic acid/20% polysiloxanes macromonomer (weight average molecular weight is about 10000 macromonomer), weight average molecular weight is about 150000.
Prepare this series products and be with glycol water-soluble and/or ethanol and mixed several minutes, until whole pre-compositions dissolvings.Add residual components then.Add essence at last.All the components all adds under mixed condition.But this product splendid attire sprays in the aerosol container in the non-aerosol type pump formula spray container and the forced air pump formula of routine.
This based composition can provide the non-washing type hair products of usefulness, can reduce the scared phenomenon of hair.
Mousse
Adopt following component to prepare non-aerosol type hair conditioning hair spray compositions of the present invention:
Embodiment number
Component (weight %) 14 15 16
1,2 hexanediol 15.00 7.50 0.00
N-hexyl glyceryl ether 0.00 0.00 10.00
Ethanol 16.13 16.13 16.13
Cocoyl amine oxide 0.65 0.65 0.65
Cocos nucifera oil diglycollic amide 0.32 0.32 0.32
C
12/ C
13Polyethoxylate (3) 0.00 0.00 2.00
Silicone-grafted copolymers 1 0.50 0.00 0.75
Essence 0.11 0.11 0.11
Water 67.29 75.29 70.04
Pre-composition total amount 100.00 100.00 100.00
Mousse
Pre-composition 93.00 93.00 93.00
Iso-butane propellant 7.00 7.00 7.00
100.00 100.00 100.00
1-60% n-butyl acrylate/20% acrylic acid/20% polysiloxanes macromonomer (weight average molecular weight is about 10000 macromonomer), weight average molecular weight is about 150000.
Mixed all the components except that iso-butane is until fully mixed, with the preparation said composition under the room temperature.Add 93 parts of these feed liquids then in the aluminum aerosol, valve fixedly is crimped on its position, pressurization at last charges into 7 parts of iso-butanes.
This based composition can provide the non-washing type hair products of usefulness, can reduce the scared phenomenon of hair.
Aerosol hair spray
Adopt following component to prepare aerosol hair spray compositions of the present invention:
Embodiment number
Component (weight %) 17
1,2 hexanediol 10.00
Polyethylene Glycol 4 0.50
Pantothenylol 0.15
Silicone-grafted copolymers
10.75
Ethanol 74.35
Sodium ethylene diamine tetracetate 1.00
Essence 0.20
Water 13.05
Hair spray pre-composition 100.00
Aerosol hair spray
Hair spray pre-composition 79.00
Iso-butane propellant 15.00
Difluoroethane propellant 6.00
100.00
1-60% n-butyl acrylate/20% acrylic acid/20% polysiloxanes macromonomer (weight average molecular weight is about 10000 macromonomer), weight average molecular weight is about 150000.
Mixed all pre-composition compositions are until polymer dissolution under the room temperature.Add this mixture then in the aerosol can that adds conventional aerosol spray tank valve, wherein the valve vacuum compressing is on tank body.Charge into propellant through valve, and add conventional aerosol spray jar actuation gear on the tank body.
This based composition can provide the non-washing type hair products of usefulness, can reduce the scared phenomenon of hair.
Gel
Adopt following component to prepare hair care gel combination of the present invention:
Embodiment number
Component (weight %) 18
1,2 hexanediol 10.00
Carbomer940 1.0
Triethanolamine 0.6
Iso stearyl polyoxyethylene ether-20 0.5
Benzophenone-4 0.1
Polyquaternary ammonium salt-11 0.5
Silicone-grafted copolymers
10.75
Essence 1.0
Antiseptic 0.1
Water 85.45
100.00
1-60% n-butyl acrylate/20% acrylic acid/20% polysiloxanes macromonomer (weight average molecular weight is about 10000 macromonomer), weight average molecular weight is about 150000.
Emulsion
Adopt following component to prepare non-washing type hair care emulsion of the present invention:
Embodiment number
Component (weight %) 19
1,2 hexanediol 15.0
Xanthan gum 1.0
Sodium benzoate 0.25
Cocoamidopropyl 0.08
Magnesium sulfate 7 hydrate 3.00
Silicone-grafted copolymers 10.05
Essence 0.05
Water 80.57
100.00
1-60% n-butyl acrylate/20% acrylic acid/20 polysiloxanes macromonomers (weight average molecular weight is about 10000 macromonomer), weight average molecular weight is about 150000.
Compositions is that the mode by routine mixes said components and prepares.This compositions provides useful non-washing type hair products, has brought the benefit that reduces the scared effect of hair.
Claims (23)
1. non-washing type Haircare composition, wherein contain:
(a) C of about 3-30% weight
2-C
10Alkyl glycerol base ether; With
(b) polar solvent of about 70-97% weight is selected from water, C
2-C
3Monohydric alcohol and their mixture.
2. non-washing type Haircare composition, wherein contain:
(a) 1 of about 3-30% weight, 2C
5-C
8Alkane diol;
(b) polar solvent of about 70-97% weight, this polar solvent are selected from the non-washing type carrier that contains hair care ingredient, comprise C
2-C
3Monohydric alcohol, and C
2-C
3The mixture of monohydric alcohol and water.
3. non-washing type Haircare composition, wherein contain:
(a) glycol of about 3-30% weight is selected from 1,2C
5-C
8Alkane diol, C
2-C
10Alkyl glycerol base ether and their mixture;
(b) polar solvent of about 70-97% weight is selected from water, C
2-C
3Monohydric alcohol and their mixture; And
(c) hair care ingredient of about 0.015-20% weight, be selected from and comprise following group: conditioner, anion surfactant, non-ionic surface active agent, thickening agent, polymer, essence, antiseptic, pH regulator agent, coloring agent, propellant, vitamin and derivant thereof, vitamin penetrant, hair spray spraying regulator, and their mixture;
Wherein the content of hair Reducing agent is lower than about 0.1% in the Haircare composition.
4. the non-washing type Haircare composition of claim 3; wherein hair care ingredient comprises anion surfactant; be selected from: alkyl and alkyl ether sulfate; Sulfated monoglyceride; sulfonation alkene; alkylaryl sulfonate; uncle's alkane or secondary paraffin sulfonate; alkyl sulfo succinate; acyl taurine salt; acyl isethinate; alkyl glycerol ether sulfonate; sulfonated methyl ester; alpha-sulfonated fatty acid; alkylphosphonic; acyl glutamate; acyl sarcosinates; alkyl sulfoacetate; acyl polypeptide; the alkyl ether carboxy acid salt; acyl-lactate, and anion fluorinated surfactants.
5. the non-washing type Haircare composition of claim 4, the agent of wherein taking care of hair also comprises non-ionic surface active agent, is selected from: the block copolymer of polysiloxane surfactant, ethylene oxide and propylene oxide, and their mixture.
6. the non-washing type Haircare composition of claim 5, wherein Haircare composition comprises that content is lower than about 2% quaternary ammonium conditioner.
7. the non-washing type Haircare composition of claim 6 is lower than about 1% polysiloxanes conditioner comprising content.
8. the non-washing type Haircare composition of claim 7 is lower than about 0.1% quaternary ammonium conditioner comprising content.
9. the non-washing type Haircare composition of claim 8 is lower than about 0.1% polysiloxanes conditioner comprising content.
10. the non-washing type Haircare composition of claim 9 wherein also comprises the silicone-grafted copolymers of about 0.1-5%.
11. the non-washing type Haircare composition of claim 3, wherein said glycol is selected from 1,2-pentanediol, 1,2-hexanediol, 1,2-heptandiol, n-hexyl glyceryl ether, and their mixture.
12. the non-washing type Haircare composition of claim 11, wherein said glycol is selected from 1,2-pentanediol, 1,2-hexanediol, 1,2-heptandiol, n-hexyl glyceryl ether, and their mixture.
13. the non-washing type Haircare composition of claim 12, wherein said glycol is 1, the 2-hexanediol.
14. the non-washing type Haircare composition of claim 12, wherein said glycol are n-hexyl glyceryl ether.
15. the non-washing type Haircare composition of claim 1, wherein the product forms of this non-washing type Haircare composition be selected from gel, flood, emulsion, mousse and spray agent.
16. the non-washing type Haircare composition of claim 12, wherein the product forms of this non-washing type Haircare composition be selected from gel, flood, emulsion, mousse and spray agent.
17. the non-washing type Haircare composition of claim 3, wherein product forms is selected from and floods and non-aerosol type hair spray, and hair care ingredient comprises:
Account for the essence of the about 0.01-4% of composition weight; And
Account for the antiseptic of the about 0.001-1% of composition weight.
18. the non-washing type Haircare composition of claim 3, wherein product forms is selected from aerosol type hair spray and mousse, and hair care ingredient comprises:
Account for the essence of the about 0.01-4% of composition weight; And
Account for the antiseptic of the about 0.001-1% of composition weight; And
A kind of propellant.
19. claim 3 the non-washing type Haircare composition, wherein product forms is selected from gel and emulsion, and hair care ingredient comprises:
Account for the essence of the about 0.01-4% of composition weight; And
Account for the antiseptic of the about 0.001-1% of composition weight; And
A kind of thickening agent.
20. a method that reduces the scared situation of hair, comprising:
(a) compositions of the claim 1 of the safe and effective amount of coating on the hair of need nursing.
21. a method that reduces the scared situation of hair, comprising:
(a) compositions of the claim 2 of the safe and effective amount of coating on the hair of need nursing.
22. a method that reduces the scared situation of hair, comprising:
(a) compositions of the claim 3 of the safe and effective amount of coating on the hair of need nursing.
23. a method that reduces the scared situation of hair, comprising:
(a) compositions of the claim 12 of the safe and effective amount of coating on the hair of need nursing.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9101698P | 1998-06-29 | 1998-06-29 | |
| US11043598P | 1998-12-01 | 1998-12-01 | |
| US60/307,895 | 1998-12-01 | ||
| US30789599A | 1999-05-10 | 1999-05-10 | |
| US60/091,016 | 1999-05-10 | ||
| US09/110,435 | 1999-05-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1305365A true CN1305365A (en) | 2001-07-25 |
Family
ID=27376731
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99807343 Pending CN1305365A (en) | 1998-06-29 | 1999-06-29 | Leave-on hair compositions which contain diol |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1091727A1 (en) |
| JP (1) | JP2002519313A (en) |
| CN (1) | CN1305365A (en) |
| AU (1) | AU4846599A (en) |
| BR (1) | BR9911639A (en) |
| WO (1) | WO2000000164A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1329018C (en) * | 1998-12-25 | 2007-08-01 | 花王株式会社 | Detergent composition |
| CN103002860A (en) * | 2010-07-13 | 2013-03-27 | 宝洁公司 | Aerosol hairspray product for styling and/or shaping hair |
| CN107669619A (en) * | 2017-09-30 | 2018-02-09 | 蚌埠科卫消毒药剂有限公司 | A kind of disposable hand-wrist bones gel and preparation method thereof |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10206759A1 (en) | 2002-02-19 | 2003-08-28 | Dragoco Gerberding Co Ag | Use of 1,2-alkanediol mixture as an antimicrobial agent, e.g. for treating body odor, acne or mycoses or preserving perishable products |
| ATE391486T1 (en) * | 2002-07-10 | 2008-04-15 | Unilever Nv | HAIR TREATMENT COMPOSITIONS |
| JP2008260785A (en) * | 2008-07-17 | 2008-10-30 | Kao Corp | Aerosol spray composition |
| JP2015209407A (en) * | 2014-04-25 | 2015-11-24 | 花王株式会社 | Hairdressing cosmetics |
| JP7542357B2 (en) | 2020-07-31 | 2024-08-30 | 川研ファインケミカル株式会社 | Hair cosmetic composition |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60243012A (en) * | 1984-05-18 | 1985-12-03 | Kao Corp | Hair setting agent |
| US4954335A (en) * | 1989-05-31 | 1990-09-04 | Helene Curtis, Inc. | Clear conditioning composition and method to impart improved properties to the hair |
| DE4140474C2 (en) * | 1991-12-09 | 1995-07-13 | Schuelke & Mayr Gmbh | Skincare additive |
| DE4234744A1 (en) * | 1992-10-15 | 1994-04-21 | Wella Ag | Hair care products |
| DE4320744A1 (en) * | 1993-06-23 | 1995-01-05 | Dragoco Gerberding Co Gmbh | Use of alkane diols in cosmetic products |
| FR2755852B1 (en) * | 1996-11-15 | 1998-12-24 | Oreal | USE OF A GLYCEROL ALKYLETHER IN A COSMETIC AND / OR DERMATOLOGICAL COMPOSITION AS AN ACTIVE INGREDIENT FOR THE TREATMENT OF SEBORRHEA AND ACNE |
-
1999
- 1999-06-29 WO PCT/US1999/014766 patent/WO2000000164A1/en not_active Application Discontinuation
- 1999-06-29 CN CN 99807343 patent/CN1305365A/en active Pending
- 1999-06-29 BR BR9911639-1A patent/BR9911639A/en not_active Application Discontinuation
- 1999-06-29 JP JP2000556749A patent/JP2002519313A/en not_active Withdrawn
- 1999-06-29 EP EP99932075A patent/EP1091727A1/en not_active Withdrawn
- 1999-06-29 AU AU48465/99A patent/AU4846599A/en not_active Abandoned
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1329018C (en) * | 1998-12-25 | 2007-08-01 | 花王株式会社 | Detergent composition |
| CN103002860A (en) * | 2010-07-13 | 2013-03-27 | 宝洁公司 | Aerosol hairspray product for styling and/or shaping hair |
| CN107669619A (en) * | 2017-09-30 | 2018-02-09 | 蚌埠科卫消毒药剂有限公司 | A kind of disposable hand-wrist bones gel and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1091727A1 (en) | 2001-04-18 |
| WO2000000164A1 (en) | 2000-01-06 |
| BR9911639A (en) | 2001-03-20 |
| JP2002519313A (en) | 2002-07-02 |
| AU4846599A (en) | 2000-01-17 |
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