CN1304339A - Vitreous surface and coating process therefor - Google Patents
Vitreous surface and coating process therefor Download PDFInfo
- Publication number
- CN1304339A CN1304339A CN99806974A CN99806974A CN1304339A CN 1304339 A CN1304339 A CN 1304339A CN 99806974 A CN99806974 A CN 99806974A CN 99806974 A CN99806974 A CN 99806974A CN 1304339 A CN1304339 A CN 1304339A
- Authority
- CN
- China
- Prior art keywords
- coating
- glass surface
- rinsing
- glass
- ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 63
- 239000011248 coating agent Substances 0.000 claims abstract description 58
- 238000000034 method Methods 0.000 claims abstract description 34
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 5
- 239000011521 glass Substances 0.000 claims description 48
- 239000003054 catalyst Substances 0.000 claims description 10
- KVBCYCWRDBDGBG-UHFFFAOYSA-N azane;dihydrofluoride Chemical compound [NH4+].F.[F-] KVBCYCWRDBDGBG-UHFFFAOYSA-N 0.000 claims description 8
- LDDQLRUQCUTJBB-UHFFFAOYSA-O azanium;hydrofluoride Chemical compound [NH4+].F LDDQLRUQCUTJBB-UHFFFAOYSA-O 0.000 claims description 8
- -1 polyethylene Polymers 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 6
- 239000011527 polyurethane coating Substances 0.000 abstract description 5
- 229920001730 Moisture cure polyurethane Polymers 0.000 abstract description 3
- 238000006748 scratching Methods 0.000 abstract description 2
- 230000002393 scratching effect Effects 0.000 abstract description 2
- MIMUSZHMZBJBPO-UHFFFAOYSA-N 6-methoxy-8-nitroquinoline Chemical compound N1=CC=CC2=CC(OC)=CC([N+]([O-])=O)=C21 MIMUSZHMZBJBPO-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000000266 injurious effect Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/001—General methods for coating; Devices therefor
- C03C17/003—General methods for coating; Devices therefor for hollow ware, e.g. containers
- C03C17/005—Coating the outside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/31—Pre-treatment
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Surface Treatment Of Glass (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Cleaning In General (AREA)
Abstract
The invention discloses a method for creating a decorative coating on vitreous surfaces, notably on bottles. The process involves the removal of any existing slip coating using an ammonium bifluoride solution, rinsing and drying the objects concerned. The coating is a polyurethane coating applied as a vapour curable liquid pre-polymer. The resultant coating exhibits improved adhesion and resistance to scratching and decorative finishes can be incorporated into the coating.
Description
Technical field
The present invention relates to a kind of lip-deep composition and method after being used for removing polymer coating and subsequently decorative coating being coated to cleaning from glass surface.
The compositions and methods of the invention are coated in removal has special purposes aspect the polyethylene coating on the glass surface.
Background of the present invention
Glass container for example food cans is manufactured in large quantities with the bottle that is used for wine and other beverage.In manufacture process, the outer surface with glass carries out last coating with slipping agent usually, and this makes glass have low-friction surface, and end article is easier to be transported.
Described slipping agent is that the form with coating applies, and this coating is normally by being coated on the glass surface and handling with tin oxide priming paint subsequently and the polyethylene film that makes.The glass surface that does not have this smooth coating be more rough and have great friction coefficient and the mutual frictional adhesion of adjacently situated surfaces together.This can produce the surface scratch with unacceptable degree, and makes and to be difficult to carry a large amount of glasswares.In addition, the glass surface behind the cut has ugly rough surface.
Handle with coating subsequently, adjacently situated surfaces is free to slide has each other removed above-mentioned difficult thus from.In addition, glass has the outward appearance of no marking more attractive in appearance, and this is normally welcome.The cut of also finding vial has injurious effects to its final strength.Therefore have adequate reasons and make glass manufacturer adopt coating process.
Unfortunately, the glass surface that applies with aforementioned slipping agent can not be further processed and it is to be difficult to especially be fixedly coupled putting on to form between this transparent arbitrarily, printing on glass, paint or the coating material.This makes that be coated in follow-up coating on glass lacks caking property and limited thus and can apply commercial acceptable ornamental polishing agent.
For example, the allocation and transportation of bottle or printing can damage and therefore will be rejected because of commercial being out of favour glass in violent handling process.
For handling the method for glass in ornamental mode in hope, will be obviously advantageously, coating can be removed, or the vial that does not have applying coating can be used simply.This a kind of approach in back unfortunately is not allowed to the glass decoration merchant, because glass manufacturing company least is ready to make the not glass of coating, mainly is to be found difficult to the not cated glassware of carrying.As above-mentioned, the glassware of coating is not easy to bonding mutually.In addition, even the economic benefit of glass manufacturing makes a kind of like this goods be made, the bottle of the huge amount that this method must low production cost then.Owing to these reasons, the use of the glass of smooth coating of no use is unaccepted.
Therefore, only before applying ornamental polishing agent, attempt to remove smooth coating.The prior art that is used to remove smooth coating comprises that the bottle that will apply places longer a period of time surpassing under 500 ℃ of high temperature, for example above 45 minutes.Remove and require outside the high energy, this method is still not satisfied, does not make poor adhesion between glass surface and any decorative coating that applies subsequently because it removes smooth coating fully.
The present invention proposes a kind of composition and method, the smooth coating that is coated on the glass surface with smooth coating can be removed by chemical mode thus.
The present invention's summary
Therefore,, provide a kind of method of removing polyethylene coating, it is characterized in that this method comprises the following steps: from glass surface according to first aspect present invention
(ⅱ) with described glass surface and ammonium acid fluoride (NH
4HF
2) the solution contact;
(ⅲ) the described surface after contact of rinsing;
(ⅲ) surface after the dry rinsing.
The thickness that is coated to the smooth coating of polyethylene of most of commercial vials is 75-100 μ m.Removing by said method is enough to after this coating make intrinsic decorative coating is coated on the surface.
Than above-mentioned removal technology, the use of the inventive method provides a large amount of advantages.This method obviously consumes energy still less and glass surface is not exposed to and resembles under employed high temperature of above-mentioned removal technology and the abrasive temperature of possibility.
The selection of ammonium acid fluoride is than potential glass cleaner hydrofluoric acid (H for example
2F
2) have an advantage.The hydrofluoric acid aggressivity is attacked glass surface strongly, and it can not be removed polyethylene coating and additionally not dissolve a part of goods itself from glass surface to a certain extent.This may be harmful to the structure and the intensity of vial.Find that it is solution influenced that only use in by the inventive method on the surface of glass on limited degree.Using the further shortcoming of hydrofluoric acid is to be difficult to carrying, storage and waste disposal.
Preferably, ammonium hydrogen fluoride solution is a kind of aqueous solution, and the content of ammonium acid fluoride is 2-10 weight %, and 4-8 weight % more preferably.
Preferably, ammonium hydrogen fluoride solution is contacted 5-60 second with described glass surface.Preferably, ammonium acid fluoride is remained under 25-50 ℃ the temperature.
Normally, with after ammonium acid fluoride contacts, in rinse step, carry out enough rinsings and be removed, and do not have residue to keep to guarantee all loosening in contact procedure coatings.Find in practice, film residue and ammonium hydrogen fluoride solution can be used on pressure be 20-200kPa, flow velocity be every bottle of per minute for 1-5 liter (under the situation of standard wine) spray rinsing several times, the time is 5-90 second.Leave standstill a period of time then, so that before drying, get rid of all waste materials.
Drying stage can carry out and preferably include high velocity, low pressure air source at ambient temperature.
In another aspect of this invention, provide a kind of method, it is characterized in that this method comprises the following steps: glass surface coating decorative coating
ⅰ. described glass surface is contacted with ammonium hydrogen fluoride solution;
ⅱ. the described surface after contact of rinsing; With
ⅵ. the surface after the dry rinsing; With
ⅶ. curable liquid polymerizable coating is coated on the described glass surface; And
ⅷ. the glass surface after will applying is exposed under the catalyst to make described liquid polymeric form decorative coating thus.
The polyurethane prepolymer that polymerisable coating preferably can at room temperature solidify.
Prepolymer coating can one-step method contain with prepolymer and suitable vaporous catalytic amine carrier gas the spray form mixture and use.Additionally, prepolymer coating can be coated to the surface and be exposed in the steam that contains catalyst by the surface that will apply in the curing schedule that separately carries out subsequently and solidify in spraying method.
In particularly preferred embodiments, polyurethane prepolymer coating is the form coating with the liquid prepolymer of one pack system moisture curable.Except isocyanate prepolymer, prepolymer coating can other component of inclusion for example pigment, solvent and slipping agent (siloxanes) and adhesion promotor.Preferably, polymer is to apply with a kind of spraying coating process, and wherein liquid prepolymer is to be coated on the surface.The curing of polymer can be in humidity up to carrying out under 25-40 ℃ temperature with containing in the Catalyst Steam chamber that concentration is 1000-3000ppm amines catalyst steam for 40-70%.Normally, a kind of polyurethane coating was exposed under the Catalyst Steam at least 50 seconds with needs and solidified at least 4 minutes subsequently.In the Catalyst Steam chamber, favourable situation is, recycling catalyst steam is with Catalyst Steam bombarded surface coating effectively.
Normally 15-20 μ m is thick and as described below for the face coat that is produced by this technology, fixedly is bonded to glass surface to be used as the vial coating.Decorative color and polishing agent can be sneaked into to coating.But this coating also is serigraphy.
The description of preferred embodiment
The validity of removal method of the present invention is tested in many laboratory tests and scene.Simulation test is to carry out at the standard wine with following processing region:
A does not remove glass coating, has applied polyurethane coating; With
B has removed glass coating, has applied polyurethane coating.
Glass coating is removed technology and is to use 5% ammonium hydrogen fluoride solution to carry out, and wherein bottle is soaked about 15 seconds down at 35 ℃.Be that 20-200kPa and flow velocity are that water that every bottle of per minute rises for 1-5 sprays and embathes several times with vial at hydraulic pressure subsequently.
Vial is at room temperature dry in high velocity, low pressure air stream.
Polyurethane coating is coated on the vial that is divided into two kinds of A and B.Liquid prepolymer is coated on each bottle surface, simultaneously prepolymer is gasified in Catalyst Steam to form the polyurethane surface finishing coat at vial, thickness is the 15-20 micron.Before test, vial is placed a night.
Two groups of vials are transported simulation test.
A group bottle finds to have the coating of scratching on bottle/bottle and the bottle/packing contact point between first hour of test.B group bottle finds after 3 hours coating stripping is arranged.This is acceptable industrial benchmark.
Described two groups of vials have also been carried out simple cross-hatching adhesive force experiment, and this test is to carry out according to Australian Standard AS 1580.408.4-1993 adhesive force (cross-hatching).Remove with on coating be illustrated in losing of bonding between vial and the coating.The adhesive force that records the A group is to be recorded as to have to surpass 35% adhesion loss, and the loss of the adhesive force in the B group is 0%.
To those skilled in the art is that tangible improvement of the present invention and variation are considered to be within the scope of the present invention.The foregoing description is only to be used for illustrative purposes to be not limited to scope of the present invention.
Claims (11)
1, a kind of method of removing polyethylene coating from glass surface is characterized in that, this method comprises the following steps:
(ⅰ) described glass surface is contacted with ammonium hydrogen fluoride solution;
(ⅱ) rinsing should be through the surface after the contact;
(ⅲ) surface after the dry rinsing.
2, according to the method for claim 1, it is characterized in that, described glass surface is further carried out the coating step after drying.
According to the method for claim 1 or 2, it is characterized in that 3, the concentration range content of ammonium acid fluoride is 2-10 weight %.
According to the method for claim 1 or 2, it is characterized in that 4, the concentration range content of ammonium acid fluoride is 4-8 weight %.
5, according to the method for claim 1 or 2, it is characterized in that, ammonium hydrogen fluoride solution is contacted 5-60 second with described glass surface.
6, according to the method for claim 1 or 2, it is characterized in that, ammonium acid fluoride is remained under 25-50 ℃ the temperature.
According to the method for claim 1 or 2, it is characterized in that 7, described rinse step comprises that the operating time is the 5-90 at least a spray rinsing of second.
According to the method for claim 1 or 2, it is characterized in that 8, described rinse step comprises that operating pressure is at least a spray rinsing of 20-200kPa.
According to the method for claim 1 or 2, it is characterized in that 9, glass surface is that to be included in flow velocity be that each bottle of per minute is that 1-5 rises at least a spray rinsing of operation down for vial and described rinse step.
According to the method for claim 1 or 2, it is characterized in that 10, described drying steps is to use low-voltage high speed air stream to carry out at ambient temperature.
11, a kind of method to glass surface coating decorative coating is characterized in that this method comprises the following steps:
ⅰ. described glass surface is contacted with ammonium hydrogen fluoride solution;
ⅱ. rinsing should be through the surface after the contact; With
ⅲ. the surface after the dry rinsing; With
ⅳ. curable liquid polymerizable coating is coated on the described glass surface; And
ⅴ. the glass surface after will applying is exposed under the catalyst with this and makes described liquid polymeric
Form decorative coating.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AUPP3862A AUPP386298A0 (en) | 1998-06-03 | 1998-06-03 | Vitreous surface and coating process |
AUPP3862 | 1998-06-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN1304339A true CN1304339A (en) | 2001-07-18 |
Family
ID=3808107
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN99806974A Pending CN1304339A (en) | 1998-06-03 | 1999-06-02 | Vitreous surface and coating process therefor |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP1098716A1 (en) |
JP (1) | JP2002516807A (en) |
CN (1) | CN1304339A (en) |
AU (1) | AUPP386298A0 (en) |
NZ (1) | NZ508338A (en) |
WO (1) | WO1999062645A1 (en) |
ZA (1) | ZA200006864B (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109562982A (en) * | 2016-05-12 | 2019-04-02 | 安海斯-布希英博股份有限公司 | Glass container and its manufacturing method with ink jet printing image |
CN109562983A (en) * | 2016-05-12 | 2019-04-02 | 安海斯-布希英博股份有限公司 | Glass container and its manufacturing method with ink jet printing image |
CN110527347A (en) * | 2018-05-23 | 2019-12-03 | 深圳市裕展精密科技有限公司 | Strip agent and the strip method for using the strip agent |
CN110665927A (en) * | 2019-09-16 | 2020-01-10 | 湖北久之洋红外系统股份有限公司 | Nondestructive cleaning process of optical glass for laser system |
CN114749418A (en) * | 2022-04-13 | 2022-07-15 | 安徽光智科技有限公司 | Film removing process for plastic coated lens |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6733836B2 (en) * | 2000-11-28 | 2004-05-11 | Arthur Bourne | Vitreous surface and coating process therefore |
EP2283092A1 (en) * | 2008-05-14 | 2011-02-16 | Basf Se | Method for coating glass, polyethylene or polyester containers, and suitable aqueous formulations for said coating method |
EP3375763B1 (en) | 2017-03-17 | 2019-12-25 | Anheuser-Busch InBev S.A. | A method for the manufacturing of a glass container having an inkjet printed image |
EP3375762A1 (en) * | 2017-03-17 | 2018-09-19 | Anheuser-Busch InBev S.A. | A glass container having an inkjet printed image and a method for the manufacturing thereof |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3650960A (en) * | 1969-05-06 | 1972-03-21 | Allied Chem | Etching solutions |
GB1302796A (en) * | 1970-10-23 | 1973-01-10 | ||
US4921626A (en) * | 1989-08-23 | 1990-05-01 | Automark Corporation | Glass etching composition and method of making |
-
1998
- 1998-06-03 AU AUPP3862A patent/AUPP386298A0/en not_active Abandoned
-
1999
- 1999-06-02 EP EP99924593A patent/EP1098716A1/en not_active Withdrawn
- 1999-06-02 WO PCT/AU1999/000425 patent/WO1999062645A1/en not_active Application Discontinuation
- 1999-06-02 JP JP2000551894A patent/JP2002516807A/en active Pending
- 1999-06-02 NZ NZ508338A patent/NZ508338A/en unknown
- 1999-06-02 CN CN99806974A patent/CN1304339A/en active Pending
-
2000
- 2000-11-23 ZA ZA200006864A patent/ZA200006864B/en unknown
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109562982A (en) * | 2016-05-12 | 2019-04-02 | 安海斯-布希英博股份有限公司 | Glass container and its manufacturing method with ink jet printing image |
CN109562983A (en) * | 2016-05-12 | 2019-04-02 | 安海斯-布希英博股份有限公司 | Glass container and its manufacturing method with ink jet printing image |
US11447295B2 (en) | 2016-05-12 | 2022-09-20 | Anheuser-Busch Inbev S.A. | Glass container having an inkjet printed image and a method for the manufacturing thereof |
CN109562982B (en) * | 2016-05-12 | 2023-02-21 | 安海斯-布希英博股份有限公司 | Glass container having ink-jet printed image and method of making same |
US11739024B2 (en) | 2016-05-12 | 2023-08-29 | Anheuser-Busch Inbev S.A. | Glass container having an inkjet printed image and a method for the manufacturing thereof |
CN110527347A (en) * | 2018-05-23 | 2019-12-03 | 深圳市裕展精密科技有限公司 | Strip agent and the strip method for using the strip agent |
CN110665927A (en) * | 2019-09-16 | 2020-01-10 | 湖北久之洋红外系统股份有限公司 | Nondestructive cleaning process of optical glass for laser system |
CN114749418A (en) * | 2022-04-13 | 2022-07-15 | 安徽光智科技有限公司 | Film removing process for plastic coated lens |
Also Published As
Publication number | Publication date |
---|---|
NZ508338A (en) | 2002-10-25 |
EP1098716A1 (en) | 2001-05-16 |
WO1999062645A1 (en) | 1999-12-09 |
AUPP386298A0 (en) | 1998-06-25 |
JP2002516807A (en) | 2002-06-11 |
ZA200006864B (en) | 2001-09-04 |
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C10 | Entry into substantive examination | ||
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AD01 | Patent right deemed abandoned | ||
C20 | Patent right or utility model deemed to be abandoned or is abandoned |