CN1303265A - Packaged hair colouring composition - Google Patents
Packaged hair colouring composition Download PDFInfo
- Publication number
- CN1303265A CN1303265A CN99806878.0A CN99806878A CN1303265A CN 1303265 A CN1303265 A CN 1303265A CN 99806878 A CN99806878 A CN 99806878A CN 1303265 A CN1303265 A CN 1303265A
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- composition
- hair
- alkyl
- dyestuff
- hair dying
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4966—Triazines or their condensed derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4953—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom containing pyrimidine ring derivatives, e.g. minoxidil
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/57—Compounds covalently linked to a(n inert) carrier molecule, e.g. conjugates, pro-fragrances
Abstract
Packaged hair colouring composition comprising a stable aqueous hair colouring composition comprising a compound of formula (I), wherein D is a chromophore; X and Y are independently selected from halogen and -SR', provided that at least one of X and Y is -SR', wherein R' is selected from H, C1-C4 alkyl, (CH2)nCOOH, (CH2)nCONH2, (CH2)nSO3H, (CH2)nCOOM, (CH2)nPO3H, (CH2)nOH, (CH2)nSSO3<->, (CH2)nNR''2, (CH2)nN<+>R''3, PhSSO3<->, PhSO3H, PhPO3H, PhNR''2, PhN<+>R''3, -CN, SO3<->, (CH2)2CH(SH)R''(CH2)3COOH, -CH2CHOHCH2SH, and formulas (II), (III), (IV), (V), (VI), (VII), (VIII), (IX), (X), (XI), (XII), (XIII), -CH2CH2NH2; n is an integer in the range of 1 to 4 wherein within the same molecule n is not necessarily the same integer; and M is a cation of alkaline earth metal, alkali metal, NH4<+> or NR''3<+>; L is a linking moiety; Z is selected from pyrimidine or triazine; R'' is C1-C4 alkyl; and a package for said hair colouring composition. The packaged hair colouring compositions of the present invention provide improved wash fastness of dye on hair, less colour fade over time, improved consumer acceptance in terms of providing a single packaged hair dye composition and improved product stability.
Description
Technical field
The present invention relates to a kind of composition for hair dying that comprises the packing of reactive dye compound, this reactive dye compound comprises chromophore and contains the substituent nitrogen heterocyclic ring of at least one sulfo-.
Background technology
The color of conversion hair is not the requirement that just has in the modern life.From the epoch of the Roman Empire, the color of change hair adapts to popular and variation fashion has become convention.But will obtain when initial accurately and be kept desired long color by hair still is a unapproachable target.Develop and can catch on hair accurately and the composition for hair dying of the color that can keep for a long time, its difficult partly cause is the inherent structure of hair itself, and partly cause is the necessary condition of having hair dyed effectively.
Generally speaking, along dry length, human hair's situation and structure are not regular.People's hair can be subjected to various chemistry and physical treatment, sends out, has one's hair wash, heats, perms and is exposed under the daylight as combing, brush.Like this, than the hair that newly bears near scalp, the hair of dry end generally can present more obvious damage.Color was inconsistent after this damage can cause having hair dyed, because irregular to the absorption of hair dye along hair on the dry length direction.
In case hair is caught color, just wish not fugitive color of this color, for example because caused the fading of effect of cleaning action (being also referred to as washability), perspiration, hair spray and other external factor such as daylight wishes that in addition this color can keep certain hour equably.As mentioned above, adding infringement and can cause dyestuff to be absorbed brokenly on the hair, these infringements can cause that also fading of hair broken parts increase the weight of, thereby make color on the hair along with the time, fading in various degree taken place.Another difficulty of running into for hair-dyeing usually is need a kind of like this dye system, and it without any bad effect, as makes the hair embrittlement to the hair of user and skin, or chafe, or pollutes skin (with skin dyeing).
So just need a kind of like this composition for hair dying of exploitation, its situation of fading descends, the anti-washability of being washed off improves to some extent under routine cleaning system, can on whole hair, catch the color of basic uniformity, stimulation to skin reduces, minimizing is to the dyeing of skin, the harmful effect of user hair reduced, and need a kind of being convenient and easy to of exploitation that such composition for hair dying is administered to method on the hair.
In order to solve and the relevant many problems of having hair dyed, carried out fruitful effort for many years.Developed many hair dyeing method, comprised oxidation dye, directly act on dyestuff, natural dye, metallic dyestuff and reactive dye.
GB-A-0951021 (Turner-Hall company) proposes by genuine covalent bond dye molecule to be linked to each other with the ad-hoc location of cutin fiber and makes its painted method and composition.This method comprises, by the fiber in aqueous slkali being used the Reducing agent of opening the cutin fiber disulfide bond and the clastogen that makes the hydrogen bond rupture of cutin fiber, makes that some disulfide bond of cystine are reduced into mercapto groups in the fiber, and hydrogen bond ruptures simultaneously; And make a kind of water miscible fiber reactive dye compounds by the aqueous solution that uses fibre-reactive dye, be connected on the mercapto groups as dichloro triazine dye.TGA has been disclosed as Reducing agent.
US-A-3415606 discloses a kind of people's hair dyeing method of giving, and comprises the thiol treatment hair with effective dose, uses the step of dichlorotriazine fibre-reactive dye treatment of hair then.
" mechanism of fibre-reactive dye and the reaction of hair keratoprotein ", Albert Shansky, American Perfumer and Cosmetics, in November, 1966, " have hair dyed " with fibre-reactive dye, Albert Shansky, Cosmetics and Toiletries, in November, 1976, a kind of hair dyeing method is disclosed, comprise solution (containing TGA, alkali, lithium bromide and the carbamide) treatment of hair 5 minutes with reduction-fracture H key, rinsing hair then is with dichlorotriazine fibre-reactive dye treatment of hair.
" with heterocyclic active system's synthesizing activity dyestuff and application thereof ", Dyes and Pigments 14,1990,239-263 discloses to contain and has wherein had the heterocyclic fibre-reactive dye of the substituent chloro triazine of sulfo-.
The reactive dye hair dye can be used for catching shades of colour to hair.But at color saturation, color rendering properties, accurately still need and want basic improvement in aspect such as the improvement of improvement, the hair condition of uniformity, the washability of priming color and hair damaged condition.
So need such reactive dye hair dyeing chemical compound and compositions, they can be had hair dyed effectively and avoid or reduce damage to hair, and they can be had hair dyed effectively and avoid or reduce skin irritation and/or pollution to user.
Amazing discovery is, the present invention includes the nitrogenous heterocyclic packing composition for hair dying that is replaced by at least a thio derivative, be selected from pyrimidine or triazine, the improvement of aspects such as hair conditioning, reduction hair damage and skin irritation is provided in color saturation, color rendering properties, color homogeneity, washability.
In addition, the reactive dye composition for hair dying generally comprises the composition of at least two kinds of independent packagings traditionally, normally Reducing agent and reactive dye hair dye.The composition of these independent packagings just mixed before being applied on the hair.Such blend step be we can say concerning user and is not only bothered but also inconvenient.Usually, such composition for hair dying need use after mixing as early as possible, because formed composition for hair dying can be degraded.Like this, after the mixed composition for hair dying with requirement was coated on the hair, excessive compositions just had been dropped.Have been found that reactive dye of the present invention can be combined into the mixture of unitary package, compare stability with traditional reactive dye system and improved.Unitary package colouring compositions of the present invention is suitable for being used in nonexpondable pattern (that is, in a period of time user can pack repeatedly with one have hair dyed).Find that also this reactive dye compound and compositions are stable over time, can store like this.
Unless specialize, all percentage number averages are the percetages by weight based on the weight of the final composition that will come into operation.
Summary of the invention
The invention provides the packing composition for hair dying of the packing that comprises stable moisture composition for hair dying and described composition for hair dying, described compositions comprises the chemical compound of formula I:
Wherein D is a chromophore; X and Y be independently selected from respectively halogen and-SR ', condition is that among X and the Y at least one is-SR ' that wherein R ' is selected from H, C
1-C
4Alkyl, (CH
2) nCOOH, (CH
2) nCONH
2, (CH
2) nSO
3H, (CH
2) nCOOM, (CH
2) nPO
3H, (CH
2) nOH, (CH
2) nSSO
3 -, (CH
2) nNR "
2, (CH
2) nN
+R "
3, PhSSO
3 -, PhSO
3H, PhPO
3H, PhNR "
2, PhN
+R "
3,-CN, SO
3 -, (CH
2)
2CH (SH) R " (CH
2)
3COOH ,-CH
2CHOHCH
2SH and
N is the integer of 1-4, and wherein n needs not to be identical integer in identical molecule; M is an alkaline earth metal cation, alkali metal cation, NH
4 +Or NR "
3 +
L is the coupling part;
Z is selected from pyrimidine or triazine;
R " be C
1-C
4Alkyl.
Packing composition for hair dying of the present invention has improved the washability of dyestuff on hair, has alleviated fading in time, the unitary package composition for hair dying is being provided and is improving and to have improved the acceptance of consumer to it aspect the product stability.
Detailed Description Of The Invention
The composition for hair dying of packing of the present invention comprises the composition for hair dying that contains reactive dye compound and the packing of described composition for hair dying.
Any packing that is suitable for loading reactive dye compound described here and compositions all can be used.Suitable packing example comprises bottle, pump formula foam container (pump-foamer) etc.
Composition for hair dying comprises reactive dye, and these reactive dye comprise nitrogen heterocyclic ring, chromophore part and the coupling part that nitrogen heterocyclic ring and chromophore are coupled together.
Here used reactive dye compound has the formula I structure:
Wherein D is a chromophore; X and Y be independently selected from respectively halogen and-SR ', condition is that among X and the Y at least one is-SR ' that wherein R ' is selected from H, C
1-C
4Alkyl, (CH
2) nCOOH, (CH
2) nCONH
2, (CH
2) nSO
3H, (CH
2) nCOOM, (CH
2) nPO
3H, (CH
2) nOH, (CH
2) nSSO
3 -, (CH
2) nNR "
2, (CH
2) nN
+R "
3, PhSSO
3 -, PhSO
3H, PhPO
3H, PhNR "
2, PhN
+R "
3,-CN, SO
3 -, (CH
2)
2CH (SH) R " (CH
2)
3COOH ,-CH
2CHOHCH
2SH and
N is the integer of 1-4, and wherein n needs not to be identical integer in identical molecule; M is an alkaline earth metal cation, alkali metal cation, NH
4 +Or NR "
3 +
L is the coupling part;
Z is selected from pyrimidine or triazine;
R " be C
1-C
4Alkyl;
And comprise the ester or the salt of formula I chemical compound.
The chromophore part
In the present invention, can use any chromophore part that is applicable to the dyeing substrate.The term here " chromophore " is meant any light-sensitive compound, comprises any coloured or colourless extinction material, as fluorescent whitening agent, UV absorbent, IR absorbing dye.
The chromophore that is suitable for use in this dye composition partly comprises the residue of monoazo, bisazo or polyazo dye or by the residue of the compound azo dye of they deutero-heavy metals, or anthraquinone, phthalocyanine dye, first , azomethine, dioxazine, the residue of azophenlyene, stilbene, triphenyl methane, xanthene, thioxanthene, nitryl aromatic base, α-Nai Kun, pyrene quinone or Asia puecon four carbimides.
The chromophore that is applicable to this dye composition partly comprises, those disclosed among the EP-A-0735107 (Ciba-Geigy), the document is hereby incorporated by reference, comprise wherein described, contain usually substituent group that organic dyestuff is used as improving the substituent residue of the water miscible sulfonate/ester of dye composition.
Most preferred chromophore D group used herein is how sulfonated azo chromophore, those as having in Levafix (RTM) dyestuff that is purchased from Dystar.
Nitrogen heterocyclic ring
The nitrogen heterocyclic ring here is selected from pyrimidine or triazine, preferred triazine.
Nitrogen heterocyclic ring comprises at least one sulfo-substituent group SR ', and wherein R ' is selected from H, C
1-C
4Alkyl, (CH
2) nCOOH, (CH
2) nCONH
2, (CH
2) nSO
3H, (CH
2) nCOOM, (CH
2) nPO
3H, (CH
2) nOH, (CH
2) nSSO
3 -, (CH
2) nNR "
2, (CH
2) nN
+R "
3, PhSSO
3 -, PhSO
3H, PhPO
3H, PhNR "
2, PhN
+R "
3,-CN, SO
3 -, (CH
2)
2CH (SH) R " (CH
2)
3COOH ,-CH
2CHOHCH
2SH and
N is the integer of 1-4, and wherein n needs not to be identical integer in identical molecule; M is an alkaline earth metal cation, alkali metal cation, NH
4 +Or NR "
3 +
Here the preferred R ' group that uses is CH
2COOH, CH
2CH
2OH, (COOH) CH
2CH
2(COOH), preferred CH
2COOH.
Nitrogen heterocyclic ring can replace by two SR ' groups or by a SR ' group and a halogen group, is preferably replaced by two SR ' groups.
The coupling part
This chemical compound further comprises the coupling part, and it partly couples together each nitrogen heterocyclic ring and each chromophore.Any coupling part that is adapted at using in the dye substance all can be used for the present invention.Preferably, the coupling part is selected from NR, NRC=O, C (O) NR, NRSO
2With-SO
2NR, wherein R is H or C
1-C
4Alkyl, and can be replaced: halogen, preferred fluorine or chlorine, hydroxyl, cyano group, C by following groups
1-C
4Alkoxyl, C
2-C
5Alkoxy carbonyl, carboxyl, amino-sulfonyl, sulfo group or sulfato.When heterocycle was quinoxaline or 2, preferred coupling part was NRC=O, and wherein R is H or C
1-C
4Alkyl, more preferably R wherein is H or CH
3, H particularly.
Generally, the dyestuff with formula I structure can be prepared as follows, and the precursor of the formula I dyestuff that order is suitable reacts each other, at least one contains the D-L-Z group in them, D wherein, L and Z as mentioned above, wherein at least one contains a SR ' group (wherein R ' is as mentioned above).
For example, the present invention have the formula I structure and wherein Z be that the heterocyclic dye composition of triazine can be prepared as follows, make one mole of dichloro triazine dye, as sentencing the dichloro triazine dye that trade name Procion (RTM) buys, with one mole of suitable reactant reaction that contains SR ' group from BASF.
The present invention have the formula I structure and wherein Z be that the dye composition of pyrimidine heterocyclic can be prepared as follows, make difluoro one chloropyrimide dyestuff, buy as sentencing trade name Drimalan F (RTM) and Drimarene R or K (RTM) from Clariant, or trichloropyririmidine dye buys as sentencing trade name Drimalan X from Clariant, with the suitable reactant reaction that contains SR ' group.
The reaction that initial dye composition and the reactant that contains SR ' group take place is generally carried out under the pH value of about 7-about 10 and about 0-5 ℃ temperature.
The dye composition here can be attached in the dye composite with suitable carrier material, and the type of the substrate that is colored is depended in the selection of carrier material.These carrier materials are known for a person skilled in the art.
Any carrier material that is suitable for being used in the composition for hair dying all can here use.
The present composition comprises that about 0.01%-is about 10%, and preferably about 0.1%-is about 5%, and one or more of about 3% (weight) of particularly about 0.1%-have the reactive dye compound of formula I structure.Dyestuff kind of using in each compositions and consumption depend on needed hair color and luster.
A preferred component in this composition for hair dying is a Reducing agent.Any Reducing agent that is suitable for being used in the composition for hair dying all can here use.Some typical Reducing agent used herein is listed among GB-A-951021 and the GB-A-589956, and these documents are hereby incorporated by reference.The example of suitable Reducing agent comprises TGA, thiolactic acid, dihydro Thioctacid salt, thioglycerol, mercaptopropionic acid, sodium sulfite, curing ammonium, zinc formaldehyde sulfoxylate, sodium formaldehyde sulphoxylate, sodium metabisulfite, potassium borohydrid, pegylated mercaptan and hydroquinone.What be specially adapted to here use is pegylated mercaptan.
Here another preferred composition is the hydrogen bond rupture agent.Any hydrogen bond rupture agent that is suitable for being used in the composition for hair dying all can here be used.Suitable example comprises lithium bromide, carbamide, resorcinol, catechol, dihydroxy acetone, Methanamide, potassium chloride and magnesium chloride.Here preferred especially use is carbamide.
The pH value scope of composition for hair dying of the present invention is about 11 for about 7-, preferably about 9-about 10.5.In order to keep such pH value, can contain one or more optionally buffer agents in the compositions.
The example of ealkaline buffer is an ammonium hydroxide, ethamine, di-n-propylamine, triethylamine and alkane diamidogen are as 1, the 3-diaminopropanes, anhydrous alkaline alkanolamine is as one or diethanolamine, preferred those on amino, replace fully as dimethylaminoethanol, polyalkylenepolyamines such as diethylenetriamines or heterocyclic amine such as morpholine, and alkali-metal hydroxide such as sodium hydroxide and potassium hydroxide, the hydroxide of alkaline-earth metal such as magnesium hydroxide and calcium hydroxide, basic amino acid such as L-arginine, lysine, alanine, leucine, isoleucine, hydroxylysine (oxylysine) and histidine, alkanolamine such as dimethylaminoethanol and aminoalkyl propylene glycol, and their mixture.What also be suitable for here using is to decompose to obtain HCO in water
3 -Chemical compound (below be called " one-tenth ionic compound ").The example of suitable one-tenth ionic compound is Na
2CO
3, NaHCO
3, K
2CO
3, (NH
4)
2CO
3, NH
4HCO
3, CaCO
3And Ca (HCO
3) and composition thereof.
Here the preferred buffer agent that uses is ammonium hydroxide and sodium hydroxide.
Composition for hair dying of the present invention can also comprise: thickening agent, its amount is about 20% for about 0.05%-, and is preferably about 10% from about 0.1%-, more preferably from about the about % of 0.5%-(weight).The thickening agent that is suitable for being used in this compositions is selected from oleic acid, spermol, oleyl alcohol, sodium chloride, 16/stearyl alcohol (cetearylalcohol), stearyl alcohol, synthetic thickening agent such as Carbopol, Aculyn and Acrosyl and their mixture.Here the preferred thickening agent that uses is Aculyn 22 (RTM), steareth-20 methacrylate ester copolymer; Aculyn 44 (RTM), polyurethane resin and Acusol 830 (RTM), acrylate copolymer can be by Rohm and Hass, Philadelphia, PA, USA buys.Here the additional thickener that is suitable for using comprises the sodium salt or the acrylic acid series polymeric compounds of sodium alginate or arabic gum or cellulose derivative such as methylcellulose or carboxymethyl cellulose.
Water is the preferred diluent of the present composition.But the present composition can comprise that one or more solvents are as additional diluted material.Generally speaking, being suitable for being used in solvent in the composition for hair dying of the present invention should select can be with water miscible and to not injury of skin.The solvent that is suitable for use as additional diluent comprises C
1-C
20Monobasic or polyhydric alcohol and their ether, glycerol, and monobasic and dihydroxylic alcohols and ether thereof are preferred.In these chemical compounds, the pure residue that contains 2-10 carbon atom is preferred.So preferable absorbent comprises ethanol, isopropyl alcohol, normal propyl alcohol, butanols, propylene glycol, ethylene glycol monoethyl ether, and their mixture.Water is preferred main diluent in compositions of the present invention.Here the meaning of said main diluent is the total amount that the amount of water is higher than any other diluent.
It is about 99.98% that the amount of diluent is preferably about 5%-of this composition weight, and preferably about 15%-is about 99.5%, more preferably about 99% at least about 30%-, particularly about 50%-about 98%.
The present composition can add and contain surfactant system.The surfactant that is suitable for being included in the present composition generally has the lipophilic chain of carbon number for about 8-about 22, and can be selected from anion, cation, nonionic, both sexes, zwitterionic surfactant and their mixture.
(ⅰ) anion surfactant
The suitable anion surfactant that is included in the present composition comprises alkyl sulfate; the alkyl sulfate of ethoxylation; alkyl glycerol ether sulfonate; methyl-acyl taurine salt; the acyl glycinate; the N-acyl glutamate; acyl-hydroxyethyl sulfonate; alkyl sulfo succinate; the alkyl ethoxy sulfosuccinate; α-alpha-sulfonated fatty acid; their salt and/or their ester; alkyl ethoxy carboxylate; alkyl phosphate; the alkyl phosphate of ethoxylation; alkyl sulfate; acyl sarcosinates and fatty acid/protein condensation substance, and their mixture.The a heatable brick bed base of these surfactants and/or acyl group chain length are C
12-C
22, preferred C
12-C
18, more preferably C
12-C
14
(ⅱ) non-ionic surface active agent
Compositions of the present invention can also comprise water soluble nonionic surfactant.This class surfactant comprises C
12-C
14Fatty acid one and diglycollic amide, sucrose polyfatty acid esters surfactant and have the polyhydroxy fatty acid amide surfactant of following general formula:
Preferred N-alkyl, N-alkoxyl or N-aryl oxide, polyhydroxy fatty acid amide surfactant are in the following formula: R wherein
8Be C
5-C
31Alkyl, preferred C
6-C
19Alkyl comprises straight chain and branched alkyl and thiazolinyl or their mixture, R
9Hydrogen, C typically
1-C
8Alkyl or hydroxy alkyl, preferable methyl or formula-R
1-O-R
2Group, R wherein
1Be C
2-C
8Alkyl comprises straight chain, side chain and ring-type (comprising acyl group), and preferred C
2-C
4Alkylidene, R
2Be C
1-C
8Straight chain, side chain and cyclic hydrocarbon group comprise aryl and oxygen alkyl, preferred C
1-C
4Alkyl, particularly those of methyl or phenyl.Z
2Be to have at least 2 (under the situations of glyceraldehyde) or at least 3 (under the situation of other reducing sugar) hydroxyls to be directly connected in polyhydroxy alkyl part on the chain or their alkoxy derivative (preferred ethoxylation or propenoxylated).Z
2Preferably in the reductive amination reaction, obtain, most preferably Z from reducing sugar
2It is the glycityl part.Suitable reducing sugar comprises glucose, fructose, maltose, lactose, galactose, mannose and xylose, and glyceraldehyde.As raw material, the one sugar that can utilize high glucose corn syrup, high-fructose corn syrup and high malt sugar corn syrup and list above.These corn syrup can produce Z
2Sugared mixture of ingredients.Should be understood that the suitable raw material that is not intended to get rid of other.Z
2Be preferably selected from-CH
2-(CHOH) n-CH
2OH ,-CH (CH
2OH)-(CHOH)
N-1-CH
2H, CH
2(CHOH)
2(CHOR ') CHOH)-CH
2OH, wherein n is the integer of 1-5, R ' is H or ring-type monosaccharide or polysaccharide and their oxyalkylated derivant.As mentioned above, most preferably wherein n is 4 glycityl, particularly-and CH
2-(CHOH)
4-CH
2OH.
The formula of most preferred polyhydroxy fatty acid amide is R
8(CO) N (CH
3) CH
2(CHOH)
4CH
2OH, wherein R
8Be C
6-C
19Straight chained alkyl or alkenyl group.In the chemical compound of following formula, R
8-CO-N＜can be, for example, coconut oleoyl amine, stearmide, oleamide, lauramide, myristamide, decyl amide, palmitamide, Adeps Bovis seu Bubali amide etc.
The suitable ionic surfactant pack of here using that is derived from oil is drawn together the triglyceride of the softening agent (emollient) of water miscible plant-derived and animal if any the polyglycol chain of an insertion; The lanoline of one and two glyceride of ethoxylation, many ethoxylations and the fat derivant of ethoxylation.The non-ionic surface active agent that a class used herein preferably is derived from oil has following general formula:
Wherein n is that about 5-is about 200, and preferably about 20-is about 100, and more preferably from about 30-is about 85, and wherein R comprises average about 5-20 carbon atom, the aliphatic residue of preferably about 7-18 carbon atom.
The oil ﹠ fat of this type of suitable ethoxylation comprises the polyethyleneglycol derivative of glyceryl cocoate, caproin, caprylin, tallow acid glyceride, tripalmitin, tristerin, glyceryl laurate ester, olein, ricinoleic acid glyceride, with the fatty glyceride that is derived from triglyceride such as Petiolus Trachycarpi oil, almond oil, Semen Maydis oil, preferred tallow acid glyceride and glyceryl cocoate.
Here preferred use be on the Polyethylene Glycol basis, every mole of surfactant on average contains many ethoxylations C of about 50 the ethylidene oxygen part of the 5-that has an appointment
9-C
15Fatty alcohol nonionic surfactant.
Many ethoxylations C on the Polyethylene Glycol basis that is suitable for here using
9-C
15Aliphatic alcohol comprises, C
9-C
11Pareth-3, C
9-C
11Pareth-4, C
9-C
11Pareth-5, C
9-C
11Pareth-6, C
9-C
11Pareth-7, C
9-C
11Pareth-8, C
11-C
15Pareth-3, C
11-C
15Pareth-4, C
11-C
15Pareth-5, C
11-C
15Pareth-6, C
11-C
15Pareth-7, C
11-C
15Pareth-8, C
11-C
15Pareth-9, C
11-C
15Pareth-10, C
11-C
15Pareth-11, C
11-C
15Pareth-12, C
11-C
15Pareth-13, and C
11-C
15Pareth-14.The PEG40 castor oil hydrogenated is sentenced trade name Cremophor (RTM) from BASF and is buied.PEG 7 glyceryl cocoate and PEG 20 glyceryl laurate esters are buied with trade name Cetiol (RTM) HE and Lamact (RTM) GML20 respectively from Henkel.C
9-C
11Pareth-8 buys with trade name Dobanol (RTM) 91-8 from Shell company.Here preferred especially use is the polyglycol ether of 16/octadecanol, as sentence the Ceteareth 25 that trade name Cremaphor A25 buys at BASF.
Here composite plant fat that the suitable non-ionic surface active agent that uses extracts from the fruit of Shea tree (ButyrospermumKarkii Kotschy) in addition and their derivant.Similarly, the ethoxylated derivative of Fructus Mangifera Indicae, Cortex cocois radicis and illipe butter also can be used in the compositions of the present invention.Although these are returned in the nonionic surfactants of ethoxylation, should be understood that some part can remain the vegetable oil or the fat of non-ethoxylatedization.
The ionic surfactant pack that derives from oil that other are suitable is drawn together the ethoxylated derivative of oil, cade oil, Semen Maydis oil, peach kernel oil, poppy seed oil, Oleum Pini, Oleum Ricini, soybean oil, American Avocado Tree oil, safflower oil, Oleum Cocois, hazelnut oil, olive oil, Oleum Vitis viniferae and the Oleum helianthi of almond oil, Oleum Arachidis hypogaeae semen, Testa oryzae oil, wheat germ oil, Semen Lini oil, Jojoba oil, Apricot kernel oil, Oleum Juglandis, palm-kernel oil, pistachio oil, Semen Sesami seed oil, Semen Brassicae campestris.
(ⅲ) amphoteric surfactant
The amphoteric surfactant that is applicable to the present composition comprises:
(a) the imidazoline bell surfactant of formula (VII)
R wherein
1Be C
7-C
22Alkyl or alkenyl, R
2Be hydrogen or CH
2Z, each Z is CO respectively independently
2M or CH
2CO
2M, M are H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium; And/or the ammonium derivative of formula (VIII)
R wherein
1, R
2With Z as mentioned above;
(b) the amino-alkane hydrochlorate of formula (IX)
R
1NH(CH
2)
nCO
2M
The iminodiacetic alkanoate of formula (X)
R
1N[CH
2)
mCO
2M]
2
(XI) imino group multichain alkyl salt
Wherein n, m, p and q are the numbers of 1-4, R
1Be independently selected from the group of above-mentioned definition with M; With
(c) their mixture.
The trade name of (a) class amphoteric surfactant on market that suits is Miranol and Empigen, the compound mixture a that should be understood to comprise this kind traditionally, Miranol is described to have general formula (VII), although CTFA cosmetic composition dictionary the 3rd edition has been described non-annularity structure (VIII), and the 4th edition description also has another kind of constitutional isomer, wherein R
2It is that O-connects rather than the N-connection.In practice, have the compound mixture of ring-type and non-annularity kind probably, providing two kinds of definition here is in order to solve the problem of integrity.But preferred use is acyclic kind here.
The example of (a) class amphoteric surfactant that suits comprises the chemical compound of formula XII and/or X III, wherein R
1Be C
8H
17(particularly iso-octyl), C
9H
19And C
11H
23Alkyl.Particularly preferably be such chemical compound: R wherein
1Be C
9H
19, Z is CO
2M and R
2Be H; Such chemical compound: R wherein
1Be C
11H
23, Z is CO
2M and R
2Be CH
2CO
2M; With such chemical compound: R wherein
1Be C
11H
23, Z is CO
2M and R
2Be H.
In the CTFA nomenclature, be suitable for material of the present invention and comprise coco group both sexes carboxyl propionate, coco group both sexes carboxyl propanoic acid, particularly coco group both sexes acetate and coco group both sexes diacetate (perhaps being called coco group both sexes carboxyl glycinate).The concrete product that can be purchased comprises that the following name of an article of discussing face to face weighs up the product of selling: Ampholak7 TX (the carboxymethyl Adeps Bovis seu Bubali gather propyl group amine sodium), EmpigenCDL60 and CDR 60 (Albright ﹠amp; Wilson), Miranol H2M Conc., Miranol C2MConc.N.P., Miranol C2M Conc.O.P., Miranol C2M SF, Miranol CM Special (Rhone-Poulenc); Alkateric 2CIB (Alkaril Chemicals); Amphoterge W-2 (Lonza, Inc.); Monateric CDX-38, Monateric CSH-32 (Mona Industries); Rewoteric AM-2C (Rewo Chemical Group); With Schercotic MS-2 (Scher Chemicals).The example of the amphoteric surfactant that is suitable for here using also comprises octoxinol (Octoxynol)-1 (RTM), polyoxyethylene (1) octyl phenyl ether; Nonoxynolum (Nonovynol)-4 (RTM), polyoxyethylene (4) nonylplenyl ether and Nonoxynol-9, polyoxyethylene (9) nonylplenyl ether.
Be understandable that the commercially available amphoteric surfactant of many these classes be with for example hydroxide counter ion counterionsl gegenions or with anion sulfate or the particularly Sulfated C of sulfonate
8-C
18Alcohol, C
8-C
18Ethoxylated alcohol or C
8-C
18The form production and selling of the electric neutrality complex that acylglycerol esters surfactant forms.Be also noted that, the concentration of amphoteric surfactant and part by weight are on the basis of not compound surfactant form here, any anion surfactant counter ion counterionsl gegenions are regarded as the part of whole anion surfactant component content.
Preferably the example of (b) class amphoteric surfactant comprises that N-alkyl polytrimethylene gathers-carboxymethyl amine, sell with trade name Ampholak X07 and Ampholak 7CX by Berol Nobel, the salt that also has salt, particularly tri ethanol ammonium salt and N-lauryl-Beta-alanine and N-lauryl-imino group-dipropionic acid.With trade name Deriphat, Rhone-Poulenc sells with Mirataine these materials by Henkel.
(ⅳ) zwitterionic surfactant
The water miscible auxiliary zwitterionic surfactant that is suitable for being included in the present composition comprises formula R
5R
6R
7N
+(CH
2) nCO
2The amido betaine of the alkyl betaine of M and following formula (XII)
R wherein
5Be C
11-C
22Alkyl or alkenyl, R
6And R
7Be C independently respectively
1-C
3Alkyl, M are H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium, and n, m are respectively the numerals of 1-4.Preferred betanin comprises cocamidopropyl propyl-dimethyl carboxymethyl betaine, lauryl amidopropyl dimethyl carboxymethyl betaine and Tego betanin (RTM).
Be suitable for being included in the alkyl betaine that water miscible auxiliary sulfobetaines surfactant in the present composition comprises following formula (X III):
R wherein
1Be C
7-C
22Alkyl or alkenyl, R
2And R
3Be C independently respectively
1-C
3Alkyl, M are H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium, and n and m are respectively the numerals of 1-4.Here cocamidopropyl propyl hydroxy sulfobetaines preferably.
The water miscible auxiliary amine oxide surface activating agent that is suitable for being included in the present composition comprises alkyl amine oxide R
5R
6R
7The amido amine oxide of NO and following formula (X IV):
R wherein
5Be C
11-C
22Alkyl or alkenyl, R
6And R
7Be C independently respectively
4-C
3Alkyl, M are H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium, and m is the numeral of 1-4.Preferred amine oxide comprises cocamidopropyl propyl group amine oxide, lauryl dimethylamine chloride and myristyl dimethylamine oxide.
Except the primary activity hair dye, composition for hair dying of the present invention can optionally comprise other dye materials.Be applicable to that optionally other dyestuffs in composition for hair dying of the present invention and the method comprise half-permanent dyestuff, temporary dyestuff and other dyestuff.
The selective dye that is suitable for here using comprises oxidative dyestuff.Any oxidative dyestuff of hair dyeing that is applicable to all can be used for this compositions, those that mention among the WO98/27945 for example, and the document is hereby incorporated by reference in full.
Here Ding Yi non-oxidizable dyestuff comprises the dyestuff that is called as " directly acting on dyestuff ", metal dye, metal chelate dye, fibre-reactive dye and other synthetic and natural dyes.The non-oxidizable dyestuff of many kinds is described in detail in " chemistry of Crinis Carbonisatus and physical characteristic ", and the 3rd edition, Clarence Robbins (250-259 page or leaf); " chemical characteristic of cosmetics and manufacturing ", IV volume, the 2nd edition, Maison G.De Navarre, the 45th chapter, G.S.Kass (84l-920 page or leaf); " cosmetics: science and technology ", the 2nd edition, volume II, Balsam Sagarin, the 23rd chapter, F.E.Wall (279-343 page or leaf); " science of hair nursing ", C.Zviak compiles, the 7th chapter (235-261 page or leaf) and " hair dye ", J.C.Johnson, Noyes Data Corp., Park Ridge, U.S.A. (1973), (3-91 page or leaf and 113-139 page or leaf).
About 0.001%-that the multiple additional selective material addition separately that can add in the composition for hair dying described herein is a composition weight is about 5%, and preferably about 0.01%-is about 3%, and more preferably from about 0.05%-about 2%.Such material comprises protein and polypeptide and derivant thereof; But the antiseptic of water solublity or solubilising such as DMDMHydantoin, Germall 115, methyl hydroxybenzoate, ethyl ester, propyl ester and butyl ester, EDTA, Euxyl (RTM) K400, natural antiseptic agent such as benzyl alcohol, potassium sorbate and bisabolol (bisabalol), benzoic acid, sodium benzoate and 2-phenyl phenol; Antioxidant is as sodium sulfite, hydroquinone, sodium sulfite, meta-acid formula sodium sulfite, sodium dithionite, arabo-ascorbic acid and other sulfur alcohol; Remove dying agent, as oxalic acid, sulfated castor oil, salicylic acid and sodium thiosulfate; H
2O
2Stabilizing agent is as tin compound, as sodium stannate, stannic hydroxide and stannous octoate, monoacetylaniline, Phenacetin cabosil, as magnesium silicate, hydroxyquinoline sulfate, sodium phosphate and tetrasodium pyrophosphate; With the p-hydroxy benzoate; Humidizer, as hyaluronic acid, chitin and starch-grafted sodium polyacrylate, as can be from Celanese Superabsorbent Materials, Portsmith, VA, the Sanwet that the USA place obtains (RTM) IM-1000, IM-1500 and IM-2500, description is arranged in US-A-4076663, and methylcellulose, starch, high fat alcohol, paraffin oil, fatty acid or the like; Solvent; Antibacterial is as Oxeco (phenoxy group isopropyl alcohol); Low temperature phase improver, as ammonium ion source (as NH
4Cl); Viscosity-control additive is as magnesium sulfate and other electrolyte; Quaternary ammonium compound, as stearyl, dilauryl, dihydro tallow, alkyl dimethyl ammonium chloride, two cetyl diethyl etherosulfuric acid ammoniums, two tallow alkyl dimethyl methyl ester ammonium sulfate, two soybean-based alkyl dimethyl ammonium chlorides and two cocoyl alkyl dimethyl ammonium chlorides; Hair conditioner is as siloxanes, higher alcohol, cationic polymer etc.; Enzyme stabilizers is as water-soluble calcium or borate sources; Coloring agent; TiO
2And TiO
2The Muscovitum that applies; Spice and spice solubilizing agent; And zeolite, as Balfour BV400 and derivant thereof, Ca
2+/ Mg
2+Chelating agen, as multi-carboxylate, aminopolycanboxylic acid's salt, polyphosphonic acid salt, aminopolyphosphonic acid salt etc., water softener is as sodium citrate.
With non-restrictive example the present invention is described further below.In these embodiments, all concentration is on the basis of 100% active substance, unless specialize, all percentage number averages are percetages by weight.Implication such as this paper of abbreviation specify.
Embodiment
Embodiment 1
Make the synthetic single thiacetic acid. base triasine dyes of initiation material with Procion (RTM) dyestuff
Prepare single thiacetic acid. base triamine (monothioglycolato triazine) with following reaction equation 1 described synthetic route.
Reaction scheme 1
In reaction scheme, D be chromophore and with used initial dyestuff difference.In the present embodiment, use various Procion (RTM) dyestuff that is purchased from BASF as starting material, particularly, the red MX-8B of Procion, the yellow MX-8G of Procion and the blue MX-2G of Procion.
Monochloro is for single synthesizing for the acetate triasine dyes
Prepare pure Procion (RTM) dichloro triazine dye aqueous solution (0.1mol/100ml, pH7.5).Between in this solution, slowly dripping 0.1mol TGA solution under 0-5 ℃ the temperature.TGA add finish after, with sodium carbonate and HCl the pH of system is transferred to 8.Then, order is reflected under 0-5 ℃ and the pH8 and carried out 5-8 hour.The needed response time of each dyestuff is different (the red MX-8B of Procion is 7-8 hour, and the yellow MX-8G of Procion is～6 hours, and the blue MX-2G of Procion is～5 hours).In building-up process, observe the rapid decline of pH, can it be adjusted to pH8 with buffer agent.For this partial synthesis, reaction end keeps constant being longer than to show in 5 minutes by the pH of reaction system.In this point, obtained monochloro list thiacetic acid. base triasine dyes.In end of synthesis, the pH of system dropped to be lower than pH2.Obtain monochloro list thiacetic acid. base triasine dyes compound solid in precipitation with after filtering.
Embodiment 2
Synthesizing of monothio ethanol triasine dyes
Prepare monothio ethanol triazine with following reaction equation 2 described synthetic routes.
The reaction circuit in, D be chromophore and with used initial dyestuff difference.In the present embodiment, make starting material, but other suitable dichloro triazine dye chemical compound also can be used as initiation material, as yellow MX-8G of Procion and the blue MX-2G of Procion with the red MX-8G of Procion (RTM).
The red MX-8G dyestuff of 0.1mol Procion (RTM) is dissolved in the 150ml distilled water, and joins in the flask.Flask is placed ice-water bath.Then, under agitation the 0.1mol mercaptoethanol is dropwise joined in the reactant mixture.Total interpolation time is 1 hour.In the process of adding mercaptoethanol, the pH value of reaction system remains on pH7-7.5, and the temperature of reaction system is 0-5 ℃.Order is reflected under 0-5 ℃ and the pH7.5-8 (with sodium carbonate and HCl) and carried out 5 hours then.Reaction end keeps constant being longer than to represent in 5 minutes by pH.Obtained a chlorine monothio ethanol triasine dyes in this point.With 6NHCl the pH value of system is reduced to and is lower than pH2 and comes cessation reaction.Adding KCl (total solution 35%) then in reactant mixture comes out dye precipitated.And then filter with Whatman filter paper.Precipitate obtains final dyestuff product with washing with acetone 4-5 time (each acetone consumption is 50ml).
Embodiment 3
The preparation of monothio succinic acid triazine
Prepare monothio succinic acid triazine with following reaction equation 3 described synthetic routes.
Reaction scheme 3
The reaction circuit in, D be chromophore and with used initial dyestuff difference.In the present embodiment, make starting material, but other suitable dichloro triazine dye chemical compounds also can be used as initiation material, as yellow MX-8G of Procion and the blue MX-2G of Procion with the red MX-8G of Procion (RTM).In above-mentioned reaction equation, TSA refers to be connected in mercapto succinic acid salt on the ring by its sulphur atom.
Red MX-8G dyestuff of the pure Procion of 0.1mol (RTM) and 150ml distilled water are joined in the 400ml flask.Flask is placed ice-water bath.Then, under agitation the 0.1mol mercapto succinic acid is dropwise added.The interpolation time is 1-1.5 hour.In the process of adding mercapto succinic acid, the pH value of reaction system remains on pH7.5, and the temperature of reaction system is 0-5 ℃.
Order is reflected under 0-5 ℃ and the pH7.5-8 (with sodium carbonate and HCl) and carried out 6 hours then.Reaction end keeps constant being longer than to represent in 5 minutes by pH.In this point, obtain a chlorine monothio succinic acid triasine dyes.With 6N HCl the pH value of system is reduced to and is lower than pH2 and comes cessation reaction.Adding KCl (total solution 35%) then in reactant mixture comes out dye precipitated.And then filter with Whatman filter paper.Precipitate obtains final dyestuff product with washing with acetone 4-5 time (each acetone consumption is 50ml).
Embodiment 4
Synthesizing of one-5-chloro-4-thiacetic acid. yl pyrimidines dyestuff
With following reaction equation 4 described synthetic route preparation one-5-chloro-4-thiacetic acid. yl pyrimidines dyestuffs.
The reaction circuit in, D be chromophore and with used initial dyestuff difference.In the present embodiment, use the red FB dyestuff of Drimalan (RTM) to make starting material available from Clariant, but also can replace the red FB of Drimalan (RTM) with any suitable difluoro one chloropyrimide dyestuff, as can trade name Drimalan and the dyestuff buied of Drimarene dyestuff, particularly, the red FB of Drimalan, the yellow F-R of Drimalan, the blue F-G of Drimalan, the blue F-B of Drimalan, the black F-B of the yellow F-3GL ' Drimalan of Drimalan, the golden yellow R-G2R of Drimarene, Drimarene blue R-GL, the red R-8B of DrimareneBrill and the red K-4BL of Drimarene Brill.In the superincumbent reaction equation, TGA refers to the thiacetic acid. part.
Red MX-8G dyestuff of 0.1mol Drimalan and distilled water are joined in the flask.Flask is placed ice-water bath.Under agitation the 0.1mol TGA is dropwise joined in the reactant mixture then.Total interpolation time is 1-1.5 hour.In the process of adding TGA, the pH value of reactant mixture remains on pH9.8-10, and temperature is 0-5 ℃.
Order is reflected under 5 ℃ and the pH9.8-10 (with sodium carbonate and HCl) and carried out 15 hours then.This a part of reaction end keeps constant being longer than to represent in 5 minutes by pH.In this point, one-5-chloro-4-TGA and pyrimidine dyestuff have been obtained.With 6NHCl the pH value of system is reduced to and is lower than pH2 and comes cessation reaction.In reactant mixture, add KCl (the total solution of ≈ 35%) then with dye precipitated.And then filter with Whatman filter paper.Precipitate obtains one-5-chloro-4-TGA and pyrimidine dyestuff with washing with acetone 4-5 time (each acetone consumption is about 50ml).
Embodiment 5
Make dye solution with the chemical compound for preparing according to embodiment 1, and be packaged in the suitable bottle-shaped packing.
| Russet dyestuff (Auburn dye) | |
| Composition | ????％ |
| Carbamide | ????10.00 |
| Cocamidopropyl betaine | ????0.80 |
| Press the dyestuff of the red MX-8B preparation of embodiment 1 usefulness Procion (RTM) | ????0.23 |
| Press the dyestuff of the yellow MX-GR preparation of embodiment 1 usefulness Procion | ????0.42 |
| Press the blue MX-2G of embodiment 1 usefulness Procion, the dyestuff of 125 preparations | ????0.35 |
| TGA 80% | ????9.26 |
| Triethanolamine 99% | ????50.74 |
| Ammonium hydroxide 29% | ????9.00 |
| Water | To 100 |
| Light brown dyestuff (Light Brown Dye) | |
| Composition | ????％ |
| Carbamide | ????10.00 |
| Cocamidopropyl betaine | ????0.80 |
| Press the dyestuff of the red MX-8B preparation of embodiment 1 usefulness Procion (RTM) | ????0.010 |
| Press the dyestuff of the yellow MX-GR preparation of embodiment 1 usefulness Procion | ????0.226 |
| Press the blue MX-2G of embodiment 1 usefulness Procion, the dyestuff of 125 preparations | ????0.678 |
| TGA 80% | ????9.26 |
| Triethanolamine 99% | ????50.74 |
| Ammonium hydroxide 29% | ????9.00 |
| Water | ????100 |
| The faint yellow dyestuff of champagne (Champagne Blonde) | |
| Composition | ????％ |
| Carbamide | ????10.00 |
| Cocamidopropyl betaine | ????0.80 |
| Press the dyestuff of the red MX-8B preparation of embodiment 1 usefulness Procion (RTM) | ????0.023 |
| Press the dyestuff of the yellow MX-GR preparation of embodiment 1 usefulness Procion | ????0.465 |
| Press the blue MX-2G of embodiment 1 usefulness Procion, the dyestuff of 125 preparations | ????0.512 |
| TGA 80% | ????9.26 |
| Triethanolamine 99% | ????50.74 |
| Ammonium hydroxide 29% | ????9.00 |
| Water | ????100 |
| The russet dyestuff | |
| Composition | ????％ |
| Carbamide | ????10.00 |
| Cocamidopropyl betaine | ????0.80 |
| Press the dyestuff of the red MX-8B preparation of embodiment 1 usefulness Procion (RTM) | ????0.23 |
| Press the dyestuff of the yellow MX-GR preparation of embodiment 1 usefulness Procion | ????0.42 |
| Press the blue MX-2G of embodiment 1 usefulness Procion, the dyestuff of 125 preparations | ????0.35 |
| TGA 99% | ????7.48 |
| Ammonium hydroxide 29% | ????11.48 |
| Water | ????100 |
| Light brown dyestuff | |
| Composition | ????％ |
| Carbamide | ????10.00 |
| Cocamidopropyl betaine | ????0.80 |
| Press the dyestuff of the red MX-8B preparation of embodiment 1 usefulness Procion (RTM) | ????0.010 |
| Press the dyestuff of the yellow MX-GR preparation of embodiment 1 usefulness Procion | ????0.226 |
| Press the blue MX-2G of embodiment 1 usefulness Procion, the dyestuff of 125 preparations | ????0.678 |
| TGA 99% | ????7.48 |
| Ammonium hydroxide 29% | ????11.48 |
| Water | ????100 |
| The faint yellow dyestuff of champagne | |
| Composition | ????％ |
| Carbamide | ????10.00 |
| Cocamidopropyl betaine | ????0.80 |
| Press the dyestuff of the red MX-8B preparation of embodiment 1 usefulness Procion (RTM) | ????0.023 |
| Press the dyestuff of the yellow MX-GR preparation of embodiment 1 usefulness Procion | ????0.465 |
| Press the blue MX-2G of embodiment 1 usefulness Procion, the dyestuff of 125 preparations | ????0.678 |
| TGA 99% | ????7.48 |
| Ammonium hydroxide 29% | ????11.48 |
| Water | ????100 |
| The russet dyestuff | |
| Composition | ????％ |
| Carbamide | ????10.00 |
| Cocamidopropyl betaine | ????0.80 |
| Press the dyestuff of the red MX-8B preparation of embodiment 1 usefulness Procion (RTM) | ????0.23 |
| Press the dyestuff of the yellow MX-GR preparation of embodiment 1 usefulness Procion | ????0.42 |
| Press the blue MX-2G of embodiment 1 usefulness Procion, the dyestuff of 125 preparations | ????0.35 |
| TGA 99% | ????7.48 |
| Ammonium hydroxide 47% | ????8.38 |
| Water | ????100 |
| Light brown dyestuff | |
| Composition | ????％ |
| Carbamide | ????10.00 |
| Cocamidopropyl betaine | ????0.80 |
| Press the dyestuff of the red MX-8B preparation of embodiment 1 usefulness Procion (RTM) | ????0.010 |
| Press the dyestuff of the yellow MX-GR preparation of embodiment 1 usefulness Procion | ????0.226 |
| Press the blue MX-2G of embodiment 1 usefulness Procion, the dyestuff of 125 preparations | ????0.678 |
| TGA 99% | ????7.48 |
| Ammonium hydroxide 47% | ????8.38 |
| Water | ????100 |
| The faint yellow dyestuff of champagne | |
| Composition | ????％ |
| Carbamide | ????10.00 |
| Cocamidopropyl betaine | ????0.80 |
| Press the dyestuff of the red MX-8B preparation of embodiment 1 usefulness Procion (RTM) | ????0.023 |
| Press the dyestuff of the yellow MX-GR preparation of embodiment 1 usefulness Procion | ????0.465 |
| Press the blue MX-2G of embodiment 1 usefulness Procion, the dyestuff of 125 preparations | ????0.512 |
| TGA 99% | ????7.48 |
| Ammonium hydroxide 47% | ????8.38 |
| Water | ????100 |
Can substitute chemical compound in the top dye composite by any chemical compound of embodiment 1-4 preparation.
Particularly, the packing composition for hair dying of embodiment is providing improvement aspect consumer's acceptance, because need not each composition is mixed before hair dyeing, and has improved washability.
Claims (9)
1, Bao Zhuan composition for hair dying comprises the stable moisture composition for hair dying and the packing of described composition for hair dying, and described compositions comprises the chemical compound of formula I:
Wherein D is a chromophore; X and Y be independently selected from halogen and-SR ', condition is that among X and the Y at least one is-SR ' that wherein R ' is selected from H, C
1-C
4Alkyl, (CH
2) nCOOH, (CH
2) nCONH
2, (CH
2) nSO
3H, (CH
2) nCOOM, (CH
2) nPO
3H, (CH
2) nOH, (CH
2) nSSO
3 -, (CH
2) nNR "
2, (CH
2) nN
+R "
3, PhSSO
3 -, PhSO
3H, PhPO
3H, PhNR "
2, PhN
+R "
3,-CN, SO
3 -, (CH
2)
2CH (SH) R " (CH
2)
3COOH ,-CH
2CHOHCH
2SH and
N is the integer of 1-4, and wherein in identical molecule, n needs not to be identical integer; M is an alkaline earth metal cation, alkali metal cation, NH
4 +Or NR "
3 +
L is the coupling part;
Z is selected from pyrimidine or triazine;
R " be C
1-C
4Alkyl.
2, according to the composition for hair dying of the packing of claim 1, Z wherein is a triazine.
3, according to the composition for hair dying of the packing of claim 1 or 2, wherein X and Y are-SR '.
4, according to the composition for hair dying of each packing among the claim 1-3, R ' wherein is CH
2COOH.
5, according to the composition for hair dying of each packing among the claim 1-4, L wherein is selected from NR, NRC=O, C (O) NR, NRSO
2With-SO
2NR, wherein R is H or C
1-C
4Alkyl, it can be replaced by following groups: halogen, preferred fluorine or chlorine, hydroxyl, cyano group, C
1-C
4Alkoxyl, C
2-C
5Alkoxy carbonyl, carboxyl, sulfamoyl, sulfo group or sulfato.
6, according to the composition for hair dying of each packing among the claim 1-5, L wherein is NR.
7, according to the reactive dye compound of claim 6, wherein R is selected from C
1-C
4Alkyl or H, preferred H.
8, a kind of composition for hair dying comprises:
(a) reactive dye compound of purification a kind of particulate form, that have formula I:
Wherein D is a chromophore; X and Y be independently selected from halogen and-SR ', condition is that among X and the Y at least one is-SR ' that wherein R ' is selected from H, C
1-C
4Alkyl, (CH
2) nCOOH, (CH
2) nCONH
2, (CH
2) nSO
3H, (CH
2) nCOOM, (CH
2) nPO
3H, (CH
2) nOH, (CH
2) nSSO
3 -, (CH
2) nNR "
2, (CH
2) nN
+R "
3, PhSSO
3 -, PhSO
3H, PhPO
3H, PhNR "
2, PhN
+R "
3,-CN, SO
3 -, (CH
2)
2CH (SH) R " (CH
2)
3COOH ,-CH
2CHOHCH
2SH and
N is the integer of 1-4, and wherein n needs not to be identical integer in identical molecule; M is an alkaline earth metal cation, alkali metal cation, NH
4 +Or NR "
3 +
L is the coupling part;
Z is selected from pyrimidine or triazine;
R " be C
1-C
4Alkyl; With
(b) a kind of solvent.
9, composition for hair dying according to Claim 8, wherein said solvent comprises water.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| USPCT/US98/06582 | 1998-04-02 | ||
| PCT/US1998/006582 WO1999051194A1 (en) | 1998-04-02 | 1998-04-02 | Packaged hair colouring composition |
| USPCT/US98/06,582 | 1998-04-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1303265A true CN1303265A (en) | 2001-07-11 |
| CN1200681C CN1200681C (en) | 2005-05-11 |
Family
ID=22266755
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99806878.0A Expired - Fee Related CN1200681C (en) | 1998-04-02 | 1999-04-01 | Packaged hair colouring composition |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1067900A1 (en) |
| JP (1) | JP2004500310A (en) |
| CN (1) | CN1200681C (en) |
| AU (2) | AU6948398A (en) |
| BR (1) | BR9909364A (en) |
| WO (2) | WO1999051194A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103315920A (en) * | 2008-03-10 | 2013-09-25 | 佩拉化学有限公司 | Hair treatment composition and methods |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8070830B2 (en) | 2006-03-24 | 2011-12-06 | L'oreal S.A. | Fluorescent entity, dyeing composition containing at least one fluorescent entity comprising at least one heterocycle, with at least one internal cationic charge, and method for lightening keratin materials using said at least one fluorescent entity |
| FR2912142B1 (en) * | 2007-02-05 | 2009-03-20 | Oreal | DYEING COMPOSITION COMPRISING A NAPHTHYLIMIDE FLUORESCENT COLOR, METHOD OF CLEANING KERATINIC MATERIALS FROM THAT DYE |
| EP2024444B1 (en) | 2006-03-24 | 2011-07-06 | L'Oréal | Dyeing composition containing a thiol/disulphide naphthylimide fluorescent colorant, and method for lightening keratin materials using said colorant |
| JP5431917B2 (en) | 2006-03-24 | 2014-03-05 | ロレアル | Staining composition containing a thiol / disulfide fluorescent colorant containing an interrupted alkylene chain, an orthopyridinium group, and an internal cationic charge, and a method for lightening keratin materials using said colorant |
| FR2921381B1 (en) | 2007-09-21 | 2009-10-30 | Oreal | HEMICYANINE STYRYLE THIOL / DISULFIDE DYE, TINCTORIAL COMPOSITION COMPRISING THE DYE, METHOD OF CLEANING KERATINIC MATERIALS FROM THAT COLORANT |
| FR2921377B1 (en) | 2007-09-21 | 2009-10-30 | Oreal | STYRYL COMPOUND HAVING HYDROXY (CYCLO) ALKYLAMINO THIOL / DISULFIDE PATTERN, PROCESS FOR LIGHTENING KERATINIC MATERIALS THEREFROM |
| FR2921373B1 (en) | 2007-09-21 | 2009-10-30 | Oreal | LINK ALKYLENE STYRYL INDOLE DERIVATIVE DYE, TINCTORIAL COMPOSITION COMPRISING THE DYE, METHOD FOR LIGHTENING KERATINIC MATERIALS FROM THAT COLORANT |
| FR2921376B1 (en) | 2007-09-21 | 2009-10-30 | Oreal | STYRYL TETRAHYDROQUINOLINIUM THIOL / DISULFIDE COMPOUND, PROCESS FOR CLEANING KERATINIC MATERIALS FROM THAT COLORANT |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW241289B (en) * | 1993-05-17 | 1995-02-21 | Ciba Geigy |
-
1998
- 1998-04-02 WO PCT/US1998/006582 patent/WO1999051194A1/en active Application Filing
- 1998-04-02 AU AU69483/98A patent/AU6948398A/en not_active Abandoned
-
1999
- 1999-04-01 BR BR9909364-2A patent/BR9909364A/en not_active Application Discontinuation
- 1999-04-01 EP EP99916311A patent/EP1067900A1/en not_active Withdrawn
- 1999-04-01 WO PCT/US1999/007285 patent/WO1999051195A1/en not_active Application Discontinuation
- 1999-04-01 CN CN99806878.0A patent/CN1200681C/en not_active Expired - Fee Related
- 1999-04-01 JP JP2000541967A patent/JP2004500310A/en active Pending
- 1999-04-01 AU AU34659/99A patent/AU3465999A/en not_active Abandoned
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103315920A (en) * | 2008-03-10 | 2013-09-25 | 佩拉化学有限公司 | Hair treatment composition and methods |
| CN103315920B (en) * | 2008-03-10 | 2016-05-04 | 佩拉化学有限公司 | Hair coloring compositions and method |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1067900A1 (en) | 2001-01-17 |
| JP2004500310A (en) | 2004-01-08 |
| WO1999051194A1 (en) | 1999-10-14 |
| AU3465999A (en) | 1999-10-25 |
| CN1200681C (en) | 2005-05-11 |
| AU6948398A (en) | 1999-10-25 |
| WO1999051195A1 (en) | 1999-10-14 |
| BR9909364A (en) | 2001-01-16 |
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