Background technique
At present China's method of producing spiral rubber hose has been the core method or core centreless and usage has been arranged, and it is to adopt the soft core of rubber to make mould that the core method is arranged, in carrying out glue extrude, semi-cure, through fiber winding, sheath hose outer and vulcanization process, make finished product.This method also needs the demoulding to remove the flexible glue core.Two during the last ten years the most of producers of China adopt this kind method always.The major defect of this method is, complex procedures, and equipment needed thereby is many, and labor strength is big, the cost of production height, energy consumption is big.Employed flexible glue core generally can only use about 10 times just to be scrapped, and wastes greatlyyer, and the glue core is easily pulled apart during the demoulding, causes substandard products or waste product.Therefore, some producers are to some small-bore sebific ducts in recent years, as Φ 6mm~10mm, adopt the centreless method to produce, and promptly without the flexible glue core, directly extrude, twine, sulfuration and make finished product, but the circularity of sebific duct, the adhesion inequality of fiber.And to larger caliber, as the sebific duct of Φ 10mm~30mm still with there being the core method to produce.Number of patent application is 88105007, and denomination of invention discloses a kind of manufacturing process of fibre wound coreless rubber pipe for the Chinese patent application of " a kind of manufacturing process of fibre wound coreless rubber pipe ".This technological process is: with behind the sizing material heat refining of working good → through extruder extrude inner glue layer → send into carry out in the sulfurizing pot semi-cure → carrying out fiber twine in kiss-coating starch → send drying room drying → through T type extruder head sheath hose outer → send in the sulfurizing pot once more and vulcanize, it is characterized in that: a, before entering sulfurizing pot once more charges into the air of 1~8kg/cm ↑ (2) pressure in spiral rubber hose.B, in the shutoff of the two ends of the sebific duct that charges into air, and seal, with the holding tube internal pressure with clamping element.Its deficiency is: production technology is complicated, cost height, technological operation inconvenience.
Summary of the invention
The objective of the invention is to be included in the design in the sizing compound formula for a kind of novel Coreless Twining Rubber Pipe And Its Preparation Method is provided.Sebific duct directly carries out fibre threads and twines after extruder is extruded hose lining, need not to be coated with kiss-coating slurry and drying process, and wrap wire and hose lining are directly bonding.After T type extruder is extruded outer layer glue, at pan vulcanization.Adopt the bursting pressure 〉=3.0Mpa of the sebific duct of novel centreless winding method production, internal diameter is φ 5~30mm.
Purpose of the present invention can take following method to realize:
A kind of Corelesss winding hose, pipe rubber layer in comprising, crust rubber layer and manage fibre threads enhancement layer between rubber layer and the crust rubber layer described in is characterized in that:
The pipe rubber layer comprises following component in described:
Ethylene Propylene Terpolymer 3062E 100.0 weight portions,
Ancient Malong 5.0 weight portions,
Sulphur 1.5 weight portions,
Diphenylguanidine PTT 0.5 weight portion,
Accelerant B Z 2.0 weight portions,
Accelerant CZ 0.8 weight portion,
Zine oxide 5.0 weight portions,
Tackiness agent KORESIN 2.0 weight portions,
Epoxy resin 828 2.0 weight portions,
Stearic acid 1.0 weight portions,
Anti-aging agent RD 2.0 weight portions,
Tissuemat E 5.0 weight portions,
Fast carbon black 140.0 weight portions that extrude,
White carbon 10.0 weight portions,
French chalk 10.0 weight portions,
Paraffin oil 73.5 weight portions;
Described crust rubber layer comprises following component:
Ethylene Propylene Terpolymer 3062E 100.0 weight portions,
Ancient Malong 4.0 weight portions,
Sulphur 1.5 weight portions,
Promoter PZ 1.1 weight portions,
Captax 0.9 weight portion,
Accelerant CZ 2.4 weight portions,
Zine oxide 5.0 weight portions,
Stearic acid 1.5 weight portions,
Tackiness agent KORESIN 2.0 weight portions,
Anti-aging agent RD 1.8 weight portions,
Paraffin 1.4 weight portions,
Carbon black N550 80.0 weight portions,
Carbon black N330 31.0 weight portions,
Paraffin oil 61.0 weight portions.
Described fibre threads enhancement layer is a polyester line layer.
A kind of production technology of Corelesss winding hose is characterized in that it comprises the following steps:
A, that pipe rubber layer and each component of crust rubber layer in described are gone into one section of banbury respectively is mixing, reenters the mill two-stage mixing;
B, the interior glue after mixing are gone into T type extruder and are extruded;
C, on the interior pipe rubber layer of extruding, carry out the fibre threads centreless and twine;
D, on the T type extruder on described fibre threads enhancement layer sheath hose outer extrude;
E, sebific duct cut off, the digester (-tor) sulfuration, and head is cut in the sebific duct washing.
Because the present invention has adopted unique interior glue and outer glue prescription, sebific duct directly carries out fibre threads and twines after extruder is extruded hose lining, need not to be coated with kiss-coating slurry and drying process, and wrap wire and hose lining just can be closely directly bonding.The present invention has following advantage compared with prior art:
1, simplified production technology, saved cost, operated also convenient.
2, good product quality, the manufacturing efficiency height, sebific duct bursting pressure height, bursting pressure 〉=3.0Mpa has improved the safety coefficient of product greatly.
3, make the multi-sizeization of entwining tube, wide application can be produced the sebific duct product of internal diameter at φ 5~30mm.