CN1300354C - Overhead line and making method thereof - Google Patents

Overhead line and making method thereof Download PDF

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Publication number
CN1300354C
CN1300354C CNB2004100482551A CN200410048255A CN1300354C CN 1300354 C CN1300354 C CN 1300354C CN B2004100482551 A CNB2004100482551 A CN B2004100482551A CN 200410048255 A CN200410048255 A CN 200410048255A CN 1300354 C CN1300354 C CN 1300354C
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China
Prior art keywords
quality
pole line
engineering
deformation extent
wire rod
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Expired - Lifetime
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CNB2004100482551A
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Chinese (zh)
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CN1611620A (en
Inventor
久保范明
中本稔
南条和弘
西川太一郎
佐野忠德
大塚保之
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Sumitomo Electric Industries Ltd
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Sumitomo Electric Industries Ltd
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Abstract

This invention provided a trolley wire having sufficient strength and conductivity and excellent wear resistance and also to provide its manufacturing method. The trolley wire has a composition consisting of, by mass, >0.5 to 0.8% Sn, 0.0005 to 0.3%, in total, of at least one element selected from Ag, In, Sr, Ca, Mg and Zr, 0.01 to 0.05% oxygen and the balance Cu with inevitable impurities. This trolley wire has >=460 N/mm<SP>2</SP>tensile strength and >=60% IACS conductivity. By the addition of the above specific amount of at least one element selected from Ag, In, Sr, Ca and Mg as well as high-concentration Sn, high wear resistance in addition to high tensile strength and high conductivity can be obtained.

Description

Pole line and manufacture method thereof
Technical field
The present invention is about a kind of pole line and manufacture method thereof.Particularly about a kind of intensity, electric conductivity, the good pole line of wearability, with the manufacture method of the pole line that obtains this pole line.
Background technology
In known techniques,, adopt fine copper or contain the copper alloy of the following tin of 0.3 quality % as being configured for contacting and to the material of the pole line of electric car supply capability with the pantograph of electric car.
But electric car presents high speed in recent years, needs to increase the stringing tension force of pole line.As a kind of technology of this requirement of correspondence, open in the flat 6-8759 communique the spy of Japanese Patent Laid Open Publication and to carry out explanation.
In this technology, at first utilize continuous casting to obtain below the oxygen level 0.1 quality %, and contain the tin of 0.2~0.5 quality %, and remainder is the cast material of the formation of copper and unavoidable impurities.Then,, under the temperature more than 600 ℃, impose hot-work continuously, obtain the above wire rod of diameter 24mm with the deformation extent more than 80% to resulting cast material.Then, this wire rod under the temperature below 150 ℃, is imposed cold working with the deformation extent more than 70%, obtain the trolley wire copper alloy conductor.Resulting copper alloy conductor can be kept and known identical electric conductivity, and realizes high strength.
But, preferably can develop the resulting trolley wire copper alloy conductor of a kind of more above-mentioned known techniques, have more high strength and the good pole line of wearability.
Follow the high speed of electric car, the swiping speed of pantograph and pole line increases, and is easy to generate electric arc between pantograph and pole line.Because of this electric arc can cause producing the problem that the rate of wear of pole line increases.In above-mentioned known techniques,, but, also require further to improve about intensity and wearability in the certain characteristic that requires that satisfies aspect intensity and the electric conductivity as pole line.Particularly, need the good pole line of a kind of wearability especially from pole line simplicity of safeguarding and the aspect that reduces the replacing frequency.
Summary of the invention
Therefore, the purpose of this invention is to provide and a kind ofly have enough intensity and electric conductivity, and good pole line and the manufacture method thereof of wearability.
The present invention is by the amount that improves Sn, and other element is reached above-mentioned purpose with a certain amount of the interpolation.
Wearability pole line of the present invention, adopt tin (Sn) content greater than 0.5 quality % less than 0.8 quality %, selected at least a total content is 0.0005~0.3 quality % from silver (Ag), indium (In), strontium (Sr), calcium (Ca), magnesium (Mg) and zirconium (Zr), oxygen level is 0.01~0.05 quality %, and remainder is that copper (Cu) and unavoidable impurities constitute.And it is characterized in that: tensile strength is at 460N/mm 2More than, electric conductivity is more than 60%IACS (International AnnealedCopper Standard).
By the Sn that contains high density, can obtain more high strength and the good pole line of wearability.And Sn just by with selected at least aly add by the afore mentioned rules amount from Ag, In, Sr, Ca, Mg, Zr, can obtain high abrasion resistance on the basis of high tensile high conductivity.
On the other hand, the manufacture method of wearability pole line of the present invention is characterised in that: comprise utilize continuous casting obtain Sn content greater than 0.5 quality % less than 0.8 quality %, from Ag, In, Sr, Ca, selected at least a total content is 0.0005~0.3 quality % among Mg and the Zr, oxygen level is 0.01~0.05 quality %, remainder is the engineering of cast material of the formation of Cu and unavoidable impurities, to resulting cast material under the temperature more than 600 ℃, impose hot-work continuously with the deformation extent more than 50%, obtain the engineering of the above wire rod of diameter 20mm, this wire rod under the temperature below 150 ℃, is imposed cold worked engineering with the deformation extent more than 50%.
As utilize above-described pole line of the present invention and manufacture method thereof, can obtain having enough intensity and electric conductivity, and the good pole line of wearability.Therefore, can tackle the high speed of electric car, and can realize the simplicity that pole line is safeguarded and change the reduction of the frequency, and can expect that utilization of the present invention is in railway field that high speed further develops.
Description of drawings
Do not have
Nomenclature
Do not have
Embodiment
Below, the present invention is illustrated in further detail.
<Sn: greater than 0.5 quality % and between the 0.8 quality % 〉
The amount that makes Sn is greater than 0.5 quality %, be in order to obtain more high-intensity pole line raw material, and the amount that makes Sn is in order to suppress the reduction of electric conductivity more below 0.8 quality %.
<Ag, In, Sr, Ca, Mg, Zr's is at least a: total amount is 0.0005~0.3 quality % 〉
By in copper, adding at least a of Ag, In, Sr, Ca, Mg, Zr, can improve the intensity of copper alloy, even and because of the electric arc between pantograph and pole line generates heat, can not make copper alloy softening yet, can improve thermotolerance.
If above-mentioned Ag etc. add total amount less than 0.0005 quality % of element, then intensity and stable on heating last ascending effect are limited.And though Ag under situation about existing with metal form, has the electric conductivity higher than copper, when Ag carried out solid solution in copper alloy, the electric conductivity of copper alloy descended.So, make these total amount upper limits of adding element below 0.3 quality %, can prevent that the lead rate of pole line from descending.And by adding these elements, the casting sheet slight crack in the time of can preventing the casting of pole line raw material can suppress broken string in addition in the wire drawing engineering of pole line manufacturing stage.
<oxygen: 0.01~0.05 quality % 〉
By making the oxygen amount is 0.01~0.05 quality %, can obtain necessary electric conductivity like a cork.And, by the oxygen level of the employed cast material of manufacturing that makes pole line more than 0.05 quality %, but the generation of inhibited oxidation copper and is suppressed at that to add man-hour be the broken string of starting point with the cupric oxide.Otherwise,, be difficult to obtain high-quality pole line in the engineering after casting if oxygen amount less than 0.01 quality % then is easy to generate slight crack during hot-work.
In the chemical ingredients of pole line of the present invention, also can contain unavoidable impurities.Unavoidable impurities comprises Ni, Sb, As, Fe, Pb, Bi, P, Si, Zn, S, Se, Te etc.
<tensile strength: 460N/mm 2More than
By having 460N/mm 2Above tensile strength, the stringing tensile that can fully tackle the pole line of the high speed of following electric car strengthens.Formed tensile strength is more preferred from 480N/mm 2More than, the best is 500N/mm 2More than.Particularly the basal area when pole line is 110mm 2The time at 500N/mm 2More than, be 170mm with basal area 2The time at 460N/mm 2Below comparatively suitable.
<electric conductivity: more than the 60%IACS 〉
More than 60%IACS, can satisfy necessary electric conductivity by the electric conductivity that makes pole line as pole line.Though in pole line of the present invention, Sn concentration height, difficult obtaining high conductivity, as and do not require the interchange pole line of so high electric conductivity, pole line of the present invention is still suitable.This electric conductivity is represented with the per-cent (%IACS) to the electric conductivity of the standard annealed copper of international annealed copper standard defined 20 ℃ the time.
<utilize continuous casting to obtain the engineering of cast material 〉
The engineering that obtains cast material is good with the forging type that rotates belt (wheel belt) mode and two movable molds of this use of belt (twinbelt) mode.Cast continuously by utilizing these modes, can suppress manufacturing cost.
<cast material is imposed hot-work and obtain the engineering of wire rod
Hot-work by cast material being imposed under the temperature more than 600 ℃ more than 50% can make cast structure's miniaturization, and improves wire rod intensity.Is good as hot-work with hot rolling.Particularly carry out hot rolling continuously mutually with aforementioned casting, preferable aspect manufacturing.
By making processing temperature, can carry out hot-work like a cork more than 600 ℃.And the processibility in the time of also can making the back engineering be cold working improves.Oxidation takes place in when calendering in cast material, reduces so impregnated in when the engineering of back in the alcohol etc.When the time comes, if the cast material cooling, then reaction is difficult to carry out, and reduction becomes slow, so from this point, it also is important more than 600 ℃ that processing temperature is remained on.
By making hot worked deformation extent, can make the crystal structure miniaturization of wire rod and improve intensity more than 50%.This deformation extent is represented with [basal area before (basal area after the basal area-processing before the processing)/processing].By adding above-mentioned interpolation element,, also can obtain the pole line of sufficient intensity by the cold working of back engineering even improve the thermal distortion degree to greatest extent.In addition, hot worked deformation extent is more than 70%, and can be more than 80%.
And, be more than the 20mm by the diameter of the wire rod of hot-work gained.By forming this gauge or diameter of wire, in next engineering, can accept the cold working of high deformation extent.As a result, can make the effect of utilizing cold worked wire rod intensity to improve more remarkable.By the diameter of the wire rod of hot-work gained, also can be more than 24mm.
<wire rod is imposed cold worked engineering 〉
Obtain under the temperature below 150 ℃, imposing cold working after the above wire rod of diameter 20mm with the deformation extent more than 50%.Utilize this cold working, the intensity of wire rod is improved.The deformation extent is here also represented with [basal area before (basal area after the basal area-processing before the processing)/processing].Utilize this cold working, can obtain high-intensity pole line.
Cold working is fit to Wire Drawing.Processing temperature is getting final product below 150 ℃, also can not heat at normal temperatures and processes.Deformation extent is more than 50%.By carrying out the cold working of deformation extent more than 50%, can obtain enough intensity and improve effect.This deformation extent to be being good more than 70%, more than 75% for better.
Below, example of the present invention is described.
Engineering according to fusion → casting → hot rolling → wire drawing → goods is made pole line.In this project,, utilize the continuous casting rolling equipment to process from fusing to hot rolling.At first, the fusion copper alloy of the chemical ingredients shown in the continuous casting table 1.Then, carry out hot rolling and obtain wire rod with the deformation extent shown in the table 2.Then, to resulting wire rod, impose cold drawn silk processing with the deformation extent shown in the table 2 equally, obtaining basal area is 170mm 2Or 110mm 2Pole line.And, to the part cast material, do not impose hot rolling and promptly carry out cold drawn silk processing.
These pole lines are measured tensile strength and electric conductivity.Its result also represents in table 2 in the lump.The threshold value of tensile strength is 460N/mm 2More than, the threshold value of electric conductivity is more than 60%.
Table 1
No. Form (quality %)
Sn Ag In Sr Ca Mg Zr Oxygen
Embodiment A1 0.51 0.005 0.05 0.02
A2 0.52 0.1 0.03
A3 0.55 0.22 0.03
A4 0.51 0.03 0.02
A5 0.72 0.01 0.08 0.04
A6 0.80 0.08 0.04
A7 0.64 0.003 0.03
A8 0.62 0.0008 0.02
Comparative example B1 0.70 0.001
B2 0.70 0.008
B3 0.72 0.01 0.04
B4 0.52 0.02
B5 0.82 0.02
B6 0.45 0.03
Known C1 0.60 <0.001
C2 0.70 <0.001
Example C3 0.70 <0.001
Table 2
No. Rolling temperature (℃) Thermal distortion degree (%) Size (mm after the hot-work 2) Cold deformation degree (%) Size (mm after the cold working 2) Tensile strength (N/mm 2) Electric conductivity (%IACS)
Embodiment A1 720 90.8 30 84.4 110 500 66
A2 720 90.8 30 84.4 119 518 62
A3 720 90.8 30 84.4 110 495 65
A4 620 61.7 32 86.3 110 480 67
A5 620 83.5 21 50.9 170 475 62
A6 720 90.8 30 76.0 170 480 61
A7 620 85.0 20 65.0 110 495 63
A8 620 85.0 20 65.0 110 490 64
Comparative example B1 - ※1 30 84.4 110 410 57
B2 750 90.8 30 84.4 110 495 58
B3 620 87.9 18 33.0 170 440 61
B4 620 87.9 18 33.0 170 435 69
B5 620 66.3 30 84.4 110 480 57
B6 620 83.5 21 68.2 110 450 70
Known example C1 650 72.0 28 72.0 170 539 59
C2 650 72.0 28 72.0 170 568 55
C3 750 94.8 19 61.2 110 451 58
※ 1: do not roll and with the direct wire drawing of cast rod
Can clearly confirm by table 2, except Sn, also contain the No.A1~A8 of Sn interpolation element in addition, compare the electric conductivity height with the No.B1 that has only added Sn, B2, B5, C1~C3.These No.A1~A8 aspect tensile strength also greater than threshold value.
And, can confirm no matter whether No.B3, B4, B6 have interpolation elements such as Ag, also poor aspect tensile strength than No.A1~A8.
In addition, to the part of above-mentioned pole line, measure wear rate and carry out the evaluation of wearability.This evaluation is carried out so illustrated as following.At first, making the swiping speed of pole line and copper sintering slide block is 50km/h, with the contact load of slide block be 7kgf (68.6N), and under the state of volts DS 200V, electrical current 200A in addition, make pole line and slide block carry out 10 4Inferior swiping.Then, ask the wear area of pole line, and remove its wear area and estimate as wear rate with the swiping number of times of pantograph.Find that the more little wearability of wear rate is good more.Its result is as shown in table 3.
Table 3
No. Wear rate
Embodiment A2 0.15
Embodiment A5 0.16
Embodiment A6 0.15
Comparative example B3 0.18
Known example C1 0.19
Known example C2 0.18
※ wear rate: (mm 2/ * 10 4Pass through pantograph)
Can clearly be confirmed by table 2, also contain No.A2, A5, the A6 of Sn interpolation element in addition except Sn, compare with No.B3, C1, C2, wearability is good.No.B3 is a kind of except the Sn of high density, also contains Sn interpolation element in addition, but the little sample of the size after the hot-work, No.C1, C2 are for only having added the sample of Sn.

Claims (3)

1. a pole line is characterized in that: adopt
Tin (Sn) content greater than 0.5 quality % less than 0.8 quality %;
Selected at least a total content is 0.0005~0.3 quality % from silver (Ag), indium (In), strontium (Sr), calcium (Ca), magnesium (Mg) and zirconium (Zr);
Oxygen level is 0.01~0.05 quality %;
Remainder is that copper (Cu) and unavoidable impurities constitute;
The tensile strength of pole line is at 460N/mm 2More than;
Electric conductivity is more than 60%IACS.
2. the manufacture method of a pole line is characterized in that: comprise
Utilize continuous casting obtain Sn content greater than 0.5 quality % less than 0.8 quality %, selected at least a total content is 0.0005~0.3 quality % from Ag, In, Sr, Ca, Mg and Zr, oxygen level is 0.01~0.05 quality %, and remainder is the engineering of cast material of the formation of Cu and unavoidable impurities;
Resulting cast material in the temperature more than 600 ℃, is imposed hot-work continuously with the deformation extent more than 50%, obtain the engineering of the above wire rod of diameter 20mm; And
This wire rod in the temperature below 150 ℃, is imposed cold worked engineering with the deformation extent more than 50%.
3. the manufacture method of pole line as claimed in claim 2, it is characterized in that: hot worked deformation extent is more than 80%, cold worked deformation extent is more than 70%.
CNB2004100482551A 2003-10-28 2004-06-14 Overhead line and making method thereof Expired - Lifetime CN1300354C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2003367360A JP4171907B2 (en) 2003-10-28 2003-10-28 Trolley wire and its manufacturing method
JP2003367360 2003-10-28

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CN1611620A CN1611620A (en) 2005-05-04
CN1300354C true CN1300354C (en) 2007-02-14

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4479510B2 (en) 2005-01-17 2010-06-09 日立電線株式会社 Copper alloy conductor, trolley wire / cable using the same, and method for producing copper alloy conductor
JP5147040B2 (en) * 2006-06-21 2013-02-20 日立電線株式会社 Method for producing copper alloy conductor
JP5659845B2 (en) * 2011-02-18 2015-01-28 住友電気工業株式会社 Manufacturing method of high conductivity and high strength trolley wire

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5311285B2 (en) * 1974-07-30 1978-04-20
JPH1096036A (en) * 1996-09-24 1998-04-14 Fujikura Ltd High strength and high conductivity copper alloy wire rod

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5311285B2 (en) * 1974-07-30 1978-04-20
JPH1096036A (en) * 1996-09-24 1998-04-14 Fujikura Ltd High strength and high conductivity copper alloy wire rod

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JP2005133111A (en) 2005-05-26
TW200514856A (en) 2005-05-01
JP4171907B2 (en) 2008-10-29
TWI311157B (en) 2009-06-21

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