CN1298831C

CN1298831C - Detergent bar compositions

Info

Publication number: CN1298831C
Application number: CNB038076888A
Authority: CN
Inventors: S·K·戈尔; K·库马; M·布哈塔查亚; K·R·香卡拉纳拉亚南
Original assignee: Unilever NV
Current assignee: Unilever NV
Priority date: 2002-04-02
Filing date: 2003-03-12
Publication date: 2007-02-07
Anticipated expiration: 2023-03-12
Also published as: BR0308352A; ZA200406719B; WO2003083034A1; CN1646674A; AU2003227048A1

Abstract

The present invention provides a striped detergent bar composition, comprising from 5 to 50% by weight detergent active, wherein the soap level is not greater than 25 % of the total detergent active, 0.1 to 10 % by weight of the said bar being a striping formulation comprising soap, non-soap or a mixture thereof.

Description

Detergent bar composition

Technical field

The detergent bar composition that the present invention relates to improve, said composition have the outward appearance of raggle-taggle, scored or spot, and the method for preparing said composition.

Background technology

The detergent composition that is used for laundering of textile fabrics or crust comprises surfactant system usually, its role is to assist to remove dirt.These detergent composition mainly contain the tensio-active agent of non-soap.Can also suitably contain various abrasives, weighting agent, auxiliary agent and other components, for example pigment, spices, sanitas or the like.

Because Packing Fee is cheap, the cleaning composition of solid form is cheap more a lot of than liquid form, is popular form in developing country therefore.In solid form, because its transmittability preferably, strip is popular gradually and be rapidly developed in the market of developing country.

Raggle-taggle, scored, band soap bar speckle or spot be known to everybody for many years, and have bar with or mosaic pattern special more than having of a kind of color.Originally, as washing soap, it contains coloring material, and bluing agent for example its role is to help the bleaching of clothing.But recent years, such soap bar causes that people's interest mainly comes from the possibility that exists the attracting design of generation there, and this more can make the human consumer like.The soap bar of many colors is mainly used in the skin washing now.Thereby speckle makes it have abundant outward appearance on the soap, and striped or other similar structure make it unusual.

It is more difficult than the production of scored soap bar to prepare scored nonsoap detergent bar with the method for producing scored soap bar.This be because synthetic surfactant for example to be used as the linear alkylbenzene sulphonic acid of active ingredient in detergent bar easier to be molten, the therefore trend of the striped dyestuff on detergent bar diffusion fast.This is for keeping the different colours striped separately and the distinguished while of appearance, thereby guarantee they do not fuse together satisfactorily can be in use prematurely separately and break, can or the cobble decorative pattern not arranged or, be very important in roughen at the interface with different speed dissolvings.Therefore, part as this technology, must between following conflicting requirement, obtain meticulous balance: thus (a) the mutual fusion of strip coloring matter and detergent bar become the intact part of bar and (b) the strip coloring matter can on the bar body, not spread and obtain the color of homogeneous.

Scored soap bar adopts (i) to use the soap of different colours or scarp soap (ii) to obtain pleochroic soap bar (US-A-4 by coloured soap of different strands of mould extruding usually, 196,163, Henkel) or the process medium fluid injection molding (US-A-3 that is (iii) extruding, 890,419, ArmourDial, Inc.).

The present invention does not adopt any as above die design of used complexity in (ii).As above (iii) described also inapplicable in the process medium fluid injection molding of extruding, because such fluid spreads very soon in a doughy NSD.(i) relate in the manufacturing of soap bar and the document and do not have to disclose the preparation that it is used for the NSD bar.If by (i) described scarpNSD bar for preparing, do not have the bar of any integrity, because a little less than the bounding force of NSD bar than soap bar.Therefore with the NSD bar meeting disintegration of (i) preparation, can not produce suitable striped soap bar.Therefore, can not adopt as stated in the Background Art method to prepare the detergent bar of the scored non-soap that is used for fabric washing or hard surface cleaning.The production method of developing the detergent bar of scored non-soap is very favorable, because such bar is given prompting visually, provide abundant outward appearance, and striped makes detergent bar unusual.

The objective of the invention is to prepare the detergent bar that has striped and its preparation method is provided.It is possible in the mold pressing of the detergent bar of non-soap the soap noodles with certain rheology directly being introduced forcing machine, and soap forms the striped that is different from main prescription thus.Therefore in soap, add required actives and useful component and it is spatially separated with the soap prescription and become possibility.

Summary of the invention

Therefore, the invention provides a kind of detergent bar composition that is mainly non-soap that has striped, it contains the detergent active ingredients of 5-50 weight %, and wherein soap content is no more than 25% of total detergent actives; Described 0.1-10 weight % is the striped component that contains soap, non-soap or its mixture.Described striped component contains the soap of 0-80 weight % or synthetic nonsoap detergent or its binding substances of 0-50 weight %, the inorganic filler of the water of 5-30 weight % and 0-70 weight %.

According to a preferred aspect of the present invention, provide the streaky detergent bar composition that is mainly non-soap, it contains the detergent active ingredients of 10-30 weight %, and wherein soap content is no more than 10% of total detergent actives; Described 1-5 weight % is the striped component that contains soap, non-soap or its mixture.

According to another preferred aspect of the present invention, contain the soap of 50-80 weight % by use, the dough of the inorganic filler of the water of 10-40 weight % and 0-20 weight % forms striped.

This prescription can prepare or adopt and generates active ingredient by the precursor that makes detergent actives with alkali reaction and prepare with the detergent actives that is prefabricated into.

According to a further aspect in the invention, provide to prepare the brindled method that is mainly the detergent bar composition of non-soap, it contains the detergent active ingredients of 5-50 weight %, and wherein soap content is no more than 25 weight % of total detergent actives; Described 1-5 weight % is the striped component that contains soap, non-soap or its mixture, said method comprising the steps of:

I. make the precursor and the alkali reaction of detergent actives

Ii. randomly add detergent actives, auxiliary agent, weighting agent and submember and product is become bar by mold pressing, introduce 0.1-10 weight % decorative pattern prescription in the form of slice by the weight of main formula simultaneously, its speed is the mark of the input speed of the main formula shown in the following formula: F _Soap/ F _{The bar prescription}=x/ (100-x), wherein F _SoapExpression is with the decorative pattern of the slice form input speed of streak material just of filling a prescription, F _PrescriptionThe input speed of expression main formula, x represents the shared weight of striped in per 100 weight part end formulation.

Iii. extrude the bar component together in company with the slice of striped composition.

The striped prescription is by mixing soap, non-soap or its mixture respectively, and randomly the inorganic particles with as many as 70 weight % mixes, and it is become slice prepares.

Detailed Description Of The Invention:

Essential feature of the present invention is the detergent bar composition that has striped, and it contains the detergent actives that is mainly non-soap, and constitutes striped with the striped component that contains soap or non-soap or mixture.

Detergent actives:

The main right and wrong soap of the detergent actives of using in the bar although can contain a certain amount of soap.It maybe can be the non-soap actives of negatively charged ion, nonionic, positively charged ion, zwitter-ion or amphoteric in nature that active ingredient is selected from soap, and the content of preferred especially soap is no more than 25 weight % of composition.But preferably anionic, the specific detergent actives that is used for the detergent bar technology is described in document for example tensio-active agent and washing composition, the II volume, Schwartz, Perry and Berch (Interscience Publishers, N.Y.1958) in.

The specific examples of the anion active agent that the present invention is suitable for is soap or is selected from straight chain and the on-soap of branch-alkylbenzene sulfonate, alkylsulfonate, secondary alcohol sulfate, primary alcohol sulfate,, sulfonated, sulfated alkyl ether, aliphatic acyl radical sulfonated ester, alkyl carboxylate and composition thereof.

When detergent actives was soap, total fatty material abbreviated TFM usually as, was used for representing that lipid acid and tri-glyceride residuum do not comprise corresponding cationic weight percentage in the soap.For the soap that contains 18 carbon atoms, corresponding sodium cation content is generally about 8 weight %.On demand, can adopt other positively charged ion, for example zinc, potassium, magnesium, alkylammonium and aluminium.

The term soap is represented the salt of aliphatic carboxylic acid.Thereby soap can be to be derived from soapmaking any tri-glyceride-soap commonly used the carboxylate anion can contain 8-22 carbon atom.

Other detergent-active compounds can be negatively charged ion, nonionic, positively charged ion, zwitterionic or amphoteric tensio-active agent or its mixture, and known as those skilled in the art institute, they also can add in the prescription.Especially preferably wherein the anionic detergent active ingredient contains the composition of alkylbenzene sulfonate (LAS).

The striped prescription:

Being used for making bar shaped to become the composition of striped can all be soap or non-soap, and also can use the mixture of soap and non-soap actives.Preferred striped component is the heavy 0.1-10 weight % of bar, more preferably 1-5 weight %.Preferably contain the 50-80% soap, the striped prescription that the dough of the water of 10-40% and 0-20% inorganic filler obtains by use.In the representative instance, the decorative pattern prescription can be: 77% soap, 1% salt or inorganic filler and 22% water.

Auxiliary agent:

The washing auxiliary detergent that uses in the prescription is preferably inorganic, the auxiliary agent that is suitable for for example comprises alkali metal aluminosilicate (zeolite), alkaline carbonate, tripoly phosphate sodium STPP (STPP), tetrasodium pyrophosphate (TSPP), Citrate trianion, sodium nitrilo triacetate (NTA) and binding substances thereof.The dosage of auxiliary agent is 0-30%.

Inorganic particle:

Inorganic particle is not the necessary component of prescription mutually but can mixes, especially for hard surface detergent compositions.Particle preferably contains particulate structurant and/or abrasive mutually, and it is water insoluble.The inorganic particle that is suitable for can be selected from zeolite granular, calcite, rhombspar, feldspar, silicon-dioxide, silicate, other carbonate, supercarbonate, borate, vitriol and for example poly polymkeric substance.

Most preferred inorganic particle is mixture (for example rhombspar), sodium bicarbonate, borax, sodium sulfate/potassium, zeolite, feldspar, talcum, kaolin and the silicon-dioxide of lime carbonate (for example calcite), lime carbonate and magnesiumcarbonate.Preferred especially calcite, talcum, kaolin, feldspar and rhombspar and composition thereof, this is because their low cost and color.

Can mix other conventional inorganic particulate structural agent, for example silico-aluminate, borosilicate, boroalumino silicate or the ca aluminosilicate that generates or existed on the spot.

Other additive:

Also can add for example for example polysaccharide, for example starch or treated starch and Mierocrystalline cellulose of one or more water-insoluble particulate materials of other additive.

Less important additive:

Accessory additive commonly used is preferably selected from enzyme, anti redeposition agent, white dyes, colorant, sanitas and spices, also have SYNTHETIC OPTICAL WHITNER, bleach precursor, bleach-stable agent, sequestrant, stain remover (being generally polymkeric substance) and other polymkeric substance, they also can randomly be added to 10 weight %.

Detergent formulation and striped prescription mix in extrusion with the slice form.The ratio of striped prescription torque and basic recipe torque remains on 0.3-1.5.

Here provide the embodiment of several non-limiting to illustrate comparative result by the composition of the present invention's preparation.

Embodiment:

I. torque is to the influence of striped:

Component by mixing described ratio is also extruded bar with usual manner and is prepared the detergent bar (Comparative Examples A and embodiment 1) with the described composition of table 1.In Comparative Examples A, do not introduce the striped prescription, and the described striped prescription of table 1 becomes slice and introduces in extrusion.The non-ratio of washing component and striped component of soaping is 95: 5.Keep different torques by the moisture content that changes the striped component.Measure torque with Rheocord-90 Haake.

Table 1

Nonsoap detergent bar prescription:	Composition weight %
	Composition weight %		Embodiment A	Embodiment 1
	Linear alkylbenzene sulphonic acid	20.0	Embodiment A	Embodiment 1	20.0
Auxiliary agent	Linear alkylbenzene sulphonic acid	20.0	18	18	20.0
Auxiliary agent	Tai-Ace S 150	2.5	18	18	2.5
Alkaline silicate	Tai-Ace S 150	2.5	1.5	1.5	2.5
Alkaline silicate	Inorganic particle	48.4	1.5	1.5	43.4
Submember	Inorganic particle	48.4	2.5	2.5	43.4
Submember	Water	To 100	2.5	2.5	To 100
The striped prescription:	Water	To 100	0	5	To 100
The striped prescription:	Soap	-	0	5	77% of striped prescription
Salt (specific)	Soap	-	-	1% of striped prescription	77% of striped prescription
Salt (specific)	Moisture	-	-	1% of striped prescription	22% of striped prescription

The data of the moisture content of striped prescription (embodiment 1) and corresponding torque see Table 2.Desirable commentaries on classics is apart from obtaining by regulating the base-material moisture content.Table 2 has provided the representative instance of such adjustment and the torque that the different in moisture contents level is obtained.

Table 2

The moisture content % that has the painted soap of striped	The corresponding commentaries on classics apart from (Nm)
The moisture content % that has the painted soap of striped	The corresponding commentaries on classics apart from (Nm)	29.8	2Nm
22	5Nm	29.8	2Nm
22	5Nm	18	10Nm
13	25Nm	18	10Nm

As can be seen, if the commentaries on classics of striped base-material then can obtain striped apart from being 2-25Nm, and if change apart from being 5-10Nm, then obtain best striped.(obtain) to produce the tailing effect of the striped material of homogeneous when being lower than 2Nm, and (obtaining by getting rid of the striped water content of materials) can produce the piece of the colour intensity of non-homogeneous during greater than 25Nm on the surface of bar by the striped material that contains high-moisture more.

Ii. the concentration effect of streak material:

Keep the striped soap to change apart from being 5Nm, research is based on the weight % of the different soap bar line of whole prescriptions.The composition of bar is as described in the table 1 (embodiment 1).

Table 3

The % of soap	Striped
The % of soap	Striped	＜0.2％	Almost cannot see
0.2％	Good	＜0.2％	Almost cannot see
0.2％	Good	0.5％	Good
1％	Good	0.5％	Good
1％	Good	2％	Good
4％	Good	2％	Good
4％	Good	＞4％	Launch excessive

May under striped formula concentration 0.2-4%, make detergent bar become striated to obtain to have the detergent bar of good aesthetic effect.

Iii. the transmission effect of beneficial agent:

Make detergent bar with composition as described in Table 1.In comparative example B, 2% soap and 1% white dyes are added composition and fully stirring, in embodiment 2, use 2% soap and 1% white dyes to make detergent bar form striped.Check the transmission of these white dyess on fabric.Bar with comparative example B and embodiment 2 comes the fabric of contamination with wash, and the different transmission effects of evaluating and testing white dyes of the reflectivity by measuring and fabric that cleaned that locate to pollute at 460nm (R460) by the help of uv-radiation.Select for use MacbethColour-eye 7000A reflexometer to measure.

The scheme of used detergency is as follows.Embodiment B and 2 bar are fixed on wear rate (ROW) anchor clamps.WFK 10D clothing is divided into the sample of 10 * 30cm.Sample is fixed on the pallet and with the wear rate anchor clamps bar was rubbed for 10 seconds to and fro respectively, brushes for 10 seconds subsequently.Water rinse fabric three times, drying is also measured its reflectivity.

Data are as shown in table 4.Data show, compare with the bar that is mixed with component in the prescription, and the bar that has striped has shown the transmission of enhanced white dyes.

Table 4

Detergent bar	Δ R (460) on WFK 10D
Detergent bar	Δ R (460) on WFK 10D	The bar (embodiment 2) that has striped	20
Common bar (Embodiment B)	14	The bar (embodiment 2) that has striped	20

Data show, have the detergency that the fluorescent brightening effect of the bar (embodiment 2) of striped brings and obviously are better than common bar without stripes (Embodiment B).This shows that beneficial agent can be introduced in the striped to obtain the transmission of enhanced beneficial effect.

Claims

1. the detergent bar composition that has striped, it contains the detergent actives of 5-50 weight %, wherein soap content is no more than 25% of detergent actives total amount, described 0.1-10 weight % is the striped prescription that contains soap, non-soap or its mixture, and striped prescription wherein is to contain the water of 50-80 weight % soap, 10-40 weight % and the dough of 0-20 weight % inorganic filler.

2. the detergent bar composition that has striped as claimed in claim 1, it contains the detergent actives of 10-30 weight %, wherein soap content is no more than 10% of detergent actives total amount, and described 1-5 weight % is the striped prescription that contains soap, non-soap or its mixture.

3. preparation has the method for the detergent bar composition of striped, described detergent bar composition comprises the detergent actives of 5-50 weight %, wherein soap content is no more than 25 weight % of detergent actives total amount, described 1-5 weight % is the striped prescription that contains soap, non-soap or its mixture, striped prescription wherein is to contain the water of 50-80 weight % soap, 10-40 weight % and the dough of 0-20 weight % inorganic filler, said method comprising the steps of:

I. make the precursor and the alkali reaction of detergent actives,

Ii. add detergent actives, auxiliary agent, weighting agent and submember and the gained mixture is become bar by mold pressing, introduce 0.1-10 weight % striped prescription in the form of slice by the weight of end formulation simultaneously, its speed is the mark of the input speed of the end formulation shown in the following formula: F _Soap/ F _{The bar prescription}=x/ (100-x), wherein F _SoapThe striped of the expression slice form input speed of streak material just of filling a prescription, F _{The bar prescription}The input speed and the x of expression end formulation represent the shared weight of striped in per 100 weight part end formulation.

4. method as claimed in claim 3, wherein the striped prescription is by mixing soap, non-soap or its mixture respectively, randomly mix with as many as 70 weight % inorganic fillers, and it is become slice prepares.