CN1294192C - Manihot powder compound degradable material and its preparing method and use - Google Patents
Manihot powder compound degradable material and its preparing method and use Download PDFInfo
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- CN1294192C CN1294192C CNB021591849A CN02159184A CN1294192C CN 1294192 C CN1294192 C CN 1294192C CN B021591849 A CNB021591849 A CN B021591849A CN 02159184 A CN02159184 A CN 02159184A CN 1294192 C CN1294192 C CN 1294192C
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- tapioca starch
- wax
- composite degradation
- degradation material
- starch composite
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Abstract
The present invention discloses a compound degradable cassava powder material, a preparation method thereof and an application thereof. The degradable material is prepared from the following raw materials: cassava powder, CO2 aliphatic polycarbonate, methyl methacrylate, cis-butylene rubber, polyvinyl acetate, modified starch, urea, glyoxal, polymer wax and plasticizing agents; finished products are preapred from the raw materials through the processing steps of mixing granulation, forming, disinfection, etc. The present invention has the following advantages: polycarbonate is used to replace petroleum products so as to reduce production cost and save petroleum resources; the raw materials contain large amounts of full powder of cassava powder, so that the fruit, the stems and the leaves of the cassava are all utilized, which raises the added value of the cassava powder; the compound degradable cassava powder material has favorable machining property and wide application, and can be used for various aspects such as packaging materials of industrial products and civilian goods, tableware, etc.; the material has the advantages of complete degradation in natural environment, no public nuisance and no poison and odor, and is favorable to environmental protection.
Description
Technical field:
The present invention relates to a kind of composite degradation material, particularly a kind of Tapioca Starch composite degradation material and its production and use.
Background technology:
Plastics are as a kind of synthetic materials, and the scope of application is very wide, become indispensable integral part in people's production and the life.Plastics are bringing many whiles easily to the mankind, because the non-degradable of plastic material, also brought the serious environmental pollution, each country all begins to limit the production and sales of nondegradation material now, at present, the technology of the alternative nondegradable material of research and development is extremely urgent, and some technology is comparative maturity also, but still there is such-and-such problem, as degrading fully, production cost is too high, and machining property does not pass a test etc., makes the application of degradable material be restricted.
Summary of the invention:
The objective of the invention is to solve the defective that above-mentioned prior art exists, Tapioca Starch composite degradation material that provide a kind of and high-fallly separate, cost is low, machining property is good and its production and use.
For achieving the above object, the technical scheme below the present invention has adopted.
Tapioca Starch composite degradation material provided by the invention is defined as PNP Tapioca Starch composite biodegradable material, and this material is formulated by weight proportion by following raw material:
Tapioca Starch 35-70 part
CO
2Aliphatic polycarbonate 7-15 part
Methyl methacrylate 5-15 part
Maleic rubber 5-15 part
Polyvinyl acetate (PVA) 2-7 part
Modified starch 10-25 part
Urea 0.5-2 part
Oxalic dialdehyde 0.1-1 part
Macromolecule wax 0.1-1 part
Softening agent 0.1-1 part.
Described macromolecule wax is meant polyethylene wax, Poly Propylene Wax, liquid wax or paraffin.
Described softening agent can be glycerine triacetate, DOP or DBP.
The preparation method of described Tapioca Starch composite degradation material, be made up of following processing step:
A. the sieve screening of Tapioca Starch more than 120 orders;
B. with Tapioca Starch 35-70 part, CO
2Aliphatic polycarbonate 7-15 part, methyl methacrylate 5-15 part, maleic rubber 5-15 part, polyvinyl acetate (PVA) 2-7 part, modified starch 10-25 part, urea 0-5-2 part, oxalic dialdehyde 0.1-1 part, macromolecule wax 0.1-1 part and softening agent 0.1-1 part, weighing is after mediate the high height that mixes of unit and stir;
C. plastic uptake or injection moulding behind forcing machine granulation compressing tablet;
D. product is cut edge after the arrangement, sterilize finished product.
Tapioca Starch composite degradation material of the present invention can be used for doing sheet material, damping wrapping material, pallet or tableware etc.
The present invention has following advantage:
1. use CO
2Aliphatic polycarbonate has substituted petroleum products PE, PP, PS has reduced production cost, has saved petroleum resources.
2. contain the full powder of a large amount of Tapioca Starchs in the raw material, fruit, stem, the leaf of cassava all is used, improved the value added of Tapioca Starch.
3. this degradable material has the favorable mechanical processing characteristics, makes being widely used of product of the present invention to can be used for the wrapping material of industrial goods, civil goods, aspects such as tableware.
4. material provided by the invention can be degraded under physical environment fully, and is nuisanceless, nontoxic, tasteless, helps environment protection.
Embodiment:
Now in conjunction with specific embodiments content of the present invention is described in detail.
Embodiment 1
Weighing following raw materials according by weight ratio:
35 parts of Tapioca Starchs (choosing of 120 mesh sieves)
CO
27 parts of aliphatic polycarbonates
15 parts of methyl methacrylates
15 parts of maleic rubber
7 parts of polyvinyl acetate (PVA)
16 parts of modified starches
2 parts in urea
1 part of oxalic dialdehyde
1 part of polyethylene wax or Poly Propylene Wax
1 part of glycerine triacetate
Above-mentioned raw material is mixed through mediating the unit high-speed stirring, and compound drops into the twin screw extruder granulation after 4-roll calender compressing tablet plastics sucking moulding, and product is cut edge after the arrangement, sterilize the finished product cutlery box.
Embodiment 2
Weighing following raw materials according by weight ratio:
43 parts of Tapioca Starchs (choosing of 200 mesh sieves)
CO
210 parts of aliphatic polycarbonates
5 parts of MBS methyl methacrylates
10 parts of maleic rubber
4 parts of polyvinyl acetate (PVA)
25 parts of modified starches
1.5 parts in urea
0.5 part of oxalic dialdehyde
0.5 part in liquid wax (molecular weight is more than 30,000)
0.5 part of DOP (dioctyl phthalate (DOP))
After mediate the high height that mixes of unit and stir, compound drops into compressing tablet plastics sucking moulding after the forcing machine granulation with above-mentioned raw material weighing, and product is cut edge after the arrangement, sterilize the finished product sheet material
Embodiment 3
Weighing following raw materials according by weight ratio:
70 parts of Tapioca Starchs (choosing of 1000 mesh sieves)
CO
27 parts of aliphatic polycarbonates
5 parts of MBS methyl methacrylates
5 parts of maleic rubber
2 parts of polyvinyl acetate (PVA)
10 parts of modified starches
0.5 part in urea
0.1 part of oxalic dialdehyde
0.2 part in paraffin
0.2 part of DBP (dibutyl phthalate)
After mediate the high height that mixes of unit and stir, compound drops into compressing tablet injection moulding after the twin screw extruder granulation with above-mentioned raw material weighing, and product is cut edge after the arrangement, sterilize the finished product packing material.
Above-mentioned specific embodiment does not limit the scope of the invention, and all modifications and variations of making based on basis of the present invention all belong to the scope of protection of present invention.
Claims (7)
1. Tapioca Starch composite degradation material, it is characterized in that: described Tapioca Starch composite degradation material is to be made by the raw material of following weight part:
Tapioca Starch 35-70 part
CO
2Aliphatic polycarbonate 7-15 part
Methyl methacrylate 5-15 part
Maleic rubber 5-15 part
Polyvinyl acetate (PVA) 2-7 part
Modified starch 10-25 part
Urea 0.5-2 part
Oxalic dialdehyde 0.1-1 part
Macromolecule wax 0.1-1 part
Softening agent 0.1-1 part.
2. Tapioca Starch composite degradation material according to claim 1 is characterized in that: described macromolecule wax is meant polyethylene wax, Poly Propylene Wax, liquid wax or paraffin.
3. Tapioca Starch composite degradation material according to claim 1 is characterized in that: described softening agent is meant glycerine triacetate, dioctyl phthalate (DOP) or dibutyl phthalate.
4. the preparation method of a Tapioca Starch composite degradation material is characterized in that being made up of following processing step:
A. the sieve screening of Tapioca Starch more than 120 orders;
B. with Tapioca Starch 35-70 part, CO
2Aliphatic polycarbonate 7-15 part, methyl methacrylate 5-15 part, maleic rubber 5-15 part, polyvinyl acetate (PVA) 2-7 part, modified starch 10-25 part, urea 0.5-2 part, oxalic dialdehyde 0.1-1 part, macromolecule wax 0.1-1 part and softening agent 0.1-1 part, weighing is after mediate the high height that mixes of unit and stir;
C. plastic uptake or injection moulding behind forcing machine granulation compressing tablet;
D. product is cut edge after the arrangement, sterilize finished product.
5. the preparation method of Tapioca Starch composite degradation material according to claim 4 is characterized in that: used macromolecule wax is meant polyethylene wax, Poly Propylene Wax, liquid wax or paraffin.
6. the preparation method of Tapioca Starch composite degradation material according to claim 4 is characterized in that: used softening agent is meant glycerine triacetate, dioctyl phthalate (DOP) or dibutyl phthalate.
7. the purposes of Tapioca Starch composite degradation material as claimed in claim 1 is characterized in that it being to be used to make sheet material, damping wrapping material, pallet or tableware.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021591849A CN1294192C (en) | 2002-12-30 | 2002-12-30 | Manihot powder compound degradable material and its preparing method and use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021591849A CN1294192C (en) | 2002-12-30 | 2002-12-30 | Manihot powder compound degradable material and its preparing method and use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1511866A CN1511866A (en) | 2004-07-14 |
| CN1294192C true CN1294192C (en) | 2007-01-10 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021591849A Expired - Fee Related CN1294192C (en) | 2002-12-30 | 2002-12-30 | Manihot powder compound degradable material and its preparing method and use |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102627793B (en) * | 2012-04-11 | 2016-06-08 | 广西大学 | A kind of modified Maninot esculenta crantz. residue product as rubber filling material and preparation method |
| CN105001461A (en) * | 2015-07-24 | 2015-10-28 | 广东新华宝科技有限公司 | Corn starch degradable plastic film and preparing method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1990014388A1 (en) * | 1989-05-19 | 1990-11-29 | Agri-Tech Industries, Inc. | Injection molded biodegradable starch polymer composite |
| CN1077966A (en) * | 1991-08-01 | 1993-11-03 | 诺瓦蒙特股份公司 | The composition of starch-containing and thermoplastic resin |
| CN1099399A (en) * | 1993-08-24 | 1995-03-01 | 北京华新淀粉降解树脂制品有限公司 | Biodegradable composition containing starch and its producing method and its use |
| CN1104656A (en) * | 1993-12-31 | 1995-07-05 | 中国科学院兰州化学物理研究所 | Biodegradable films and their production |
| CN1125118A (en) * | 1994-12-24 | 1996-06-26 | 崔同祥 | Anticancer Yishoudan pill |
-
2002
- 2002-12-30 CN CNB021591849A patent/CN1294192C/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1990014388A1 (en) * | 1989-05-19 | 1990-11-29 | Agri-Tech Industries, Inc. | Injection molded biodegradable starch polymer composite |
| CN1077966A (en) * | 1991-08-01 | 1993-11-03 | 诺瓦蒙特股份公司 | The composition of starch-containing and thermoplastic resin |
| CN1099399A (en) * | 1993-08-24 | 1995-03-01 | 北京华新淀粉降解树脂制品有限公司 | Biodegradable composition containing starch and its producing method and its use |
| CN1104656A (en) * | 1993-12-31 | 1995-07-05 | 中国科学院兰州化学物理研究所 | Biodegradable films and their production |
| CN1125118A (en) * | 1994-12-24 | 1996-06-26 | 崔同祥 | Anticancer Yishoudan pill |
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| Publication number | Publication date |
|---|---|
| CN1511866A (en) | 2004-07-14 |
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Effective date of registration: 20051230 Address after: No. 120, Dongling Road, Liaoning, Shenyang, College of food science and technology, Shenyang Agricultural Uinversity Applicant after: Ma Tao Address before: Happy Street 2, Chongwen District, Beijing Applicant before: Zhao Haiyan Co-applicant before: Huang Jianping Co-applicant before: Hu Guoqing Co-applicant before: Zhao Tao Co-applicant before: Wei Zhong |
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Owner name: SHENYANG AGRICULTURE UNIVERSITY Free format text: FORMER OWNER: MA TAO Effective date: 20060512 |
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Effective date of registration: 20060512 Address after: 110161 Shenyang Agricultural Uinversity, No. 120, Dongling Road, Liaoning, Shenyang Applicant after: Shenyang Agricultural University Address before: 110161 College of food science, Shenyang Agricultural Uinversity, 120 Dongling Road, Shenyang, Liaoning Applicant before: Ma Tao |
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