CN1286959C - Lubricating oil composition - Google Patents
Lubricating oil composition Download PDFInfo
- Publication number
- CN1286959C CN1286959C CN 200310103032 CN200310103032A CN1286959C CN 1286959 C CN1286959 C CN 1286959C CN 200310103032 CN200310103032 CN 200310103032 CN 200310103032 A CN200310103032 A CN 200310103032A CN 1286959 C CN1286959 C CN 1286959C
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- China
- Prior art keywords
- ester
- oxidation inhibitor
- dialkyl
- alkyl
- butylhydroxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000203 mixture Substances 0.000 title claims abstract description 41
- 239000010687 lubricating oil Substances 0.000 title claims abstract description 24
- -1 phenolic ester Chemical class 0.000 claims abstract description 62
- 230000003647 oxidation Effects 0.000 claims abstract description 50
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 50
- 150000002148 esters Chemical class 0.000 claims abstract description 23
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 150000001412 amines Chemical class 0.000 claims abstract description 11
- 150000003751 zinc Chemical class 0.000 claims abstract description 6
- 159000000009 barium salts Chemical class 0.000 claims abstract description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 3
- 159000000003 magnesium salts Chemical class 0.000 claims abstract description 3
- 239000003112 inhibitor Substances 0.000 claims description 41
- 239000003638 chemical reducing agent Substances 0.000 claims description 18
- ATFAPMGQRYMYCT-UHFFFAOYSA-N 2-hydroxy-2-phenylheptanoic acid Chemical compound CCCCCC(O)(C(O)=O)C1=CC=CC=C1 ATFAPMGQRYMYCT-UHFFFAOYSA-N 0.000 claims description 10
- 239000002199 base oil Substances 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 6
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical compound OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 claims description 6
- UUNBFTCKFYBASS-UHFFFAOYSA-N C(CCCCCCC)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCCCC Chemical compound C(CCCCCCC)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCCCC UUNBFTCKFYBASS-UHFFFAOYSA-N 0.000 claims description 5
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N pentanoic acid group Chemical group C(CCCC)(=O)O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 4
- LZNFGFWRMOOGRR-UHFFFAOYSA-N CCCCCC(C1=CC=CC=C1)(C(=O)N=C=O)O Chemical compound CCCCCC(C1=CC=CC=C1)(C(=O)N=C=O)O LZNFGFWRMOOGRR-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052788 barium Inorganic materials 0.000 claims description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- QVXGKJYMVLJYCL-UHFFFAOYSA-N 2,3-di(nonyl)-N-phenylaniline Chemical compound C(CCCCCCCC)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCCCCC QVXGKJYMVLJYCL-UHFFFAOYSA-N 0.000 claims description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 2
- XYRMLECORMNZEY-UHFFFAOYSA-B [Mo+4].[Mo+4].[Mo+4].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S Chemical compound [Mo+4].[Mo+4].[Mo+4].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S XYRMLECORMNZEY-UHFFFAOYSA-B 0.000 claims description 2
- ZQNODUJPEBLQKY-UHFFFAOYSA-N [O].P(O)(O)(=S)S Chemical compound [O].P(O)(O)(=S)S ZQNODUJPEBLQKY-UHFFFAOYSA-N 0.000 claims description 2
- 230000029936 alkylation Effects 0.000 claims description 2
- 238000005804 alkylation reaction Methods 0.000 claims description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- YIJQEKWCQYIIFO-UHFFFAOYSA-N heptyl 2-hydroxy-2-phenylheptanoate Chemical compound CCCCCCCOC(=O)C(CCCCC)(C1=CC=CC=C1)O YIJQEKWCQYIIFO-UHFFFAOYSA-N 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 abstract description 7
- 150000002751 molybdenum Chemical class 0.000 abstract description 7
- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 abstract description 7
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- 239000003963 antioxidant agent Substances 0.000 abstract description 4
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 abstract description 3
- 239000012990 dithiocarbamate Substances 0.000 abstract description 2
- 150000005846 sugar alcohols Polymers 0.000 abstract 2
- DHHCPMGCLXWUQS-UHFFFAOYSA-H P(=S)([S-])([O-])[O-].[Ba+2].P(=S)([S-])([O-])[O-].[Ba+2].[Ba+2] Chemical compound P(=S)([S-])([O-])[O-].[Ba+2].P(=S)([S-])([O-])[O-].[Ba+2].[Ba+2] DHHCPMGCLXWUQS-UHFFFAOYSA-H 0.000 abstract 1
- SQKDNFMDCCWSBT-UHFFFAOYSA-K [Cu+3].[O-]P([O-])([S-])=S Chemical compound [Cu+3].[O-]P([O-])([S-])=S SQKDNFMDCCWSBT-UHFFFAOYSA-K 0.000 abstract 1
- FBZFGVCWMGNMBQ-UHFFFAOYSA-H [Mg+2].P([O-])([O-])(=S)[S-].P([O-])([O-])(=S)[S-].[Mg+2].[Mg+2] Chemical compound [Mg+2].P([O-])([O-])(=S)[S-].P([O-])([O-])(=S)[S-].[Mg+2].[Mg+2] FBZFGVCWMGNMBQ-UHFFFAOYSA-H 0.000 abstract 1
- 159000000007 calcium salts Chemical class 0.000 abstract 1
- 150000001735 carboxylic acids Chemical group 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- LHNJPLXVGVLMQJ-UHFFFAOYSA-H tricalcium;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S LHNJPLXVGVLMQJ-UHFFFAOYSA-H 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 20
- 150000001875 compounds Chemical class 0.000 description 13
- 239000000654 additive Substances 0.000 description 10
- 230000000996 additive effect Effects 0.000 description 10
- 239000010711 gasoline engine oil Substances 0.000 description 10
- 239000010705 motor oil Substances 0.000 description 7
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
- GVDXRBYRFFVSRX-UHFFFAOYSA-N C(N)(S)=S.C(CCCCCCC)[Zn]CCCCCCCC Chemical compound C(N)(S)=S.C(CCCCCCC)[Zn]CCCCCCCC GVDXRBYRFFVSRX-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- CLKAQWSCGDNHHJ-UHFFFAOYSA-N OP(O)(S)=S.CCCCCCCC[Zn]CCCCCCCC Chemical compound OP(O)(S)=S.CCCCCCCC[Zn]CCCCCCCC CLKAQWSCGDNHHJ-UHFFFAOYSA-N 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- ZNCAMSISVWKWHL-UHFFFAOYSA-L zinc;butoxy-butylsulfanyl-oxido-sulfanylidene-$l^{5}-phosphane Chemical compound [Zn+2].CCCCOP([O-])(=S)SCCCC.CCCCOP([O-])(=S)SCCCC ZNCAMSISVWKWHL-UHFFFAOYSA-L 0.000 description 3
- YWIUVAFMNXMKHL-UHFFFAOYSA-L C(N)([S-])=S.C(CCCCCCC)[Mo+2]CCCCCCCC.C(N)([S-])=S Chemical compound C(N)([S-])=S.C(CCCCCCC)[Mo+2]CCCCCCCC.C(N)([S-])=S YWIUVAFMNXMKHL-UHFFFAOYSA-L 0.000 description 2
- UZAUWPKHSDCXCN-UHFFFAOYSA-N CCCCCCCCOP(OCCCCCCCC)(S)=S.[O] Chemical compound CCCCCCCCOP(OCCCCCCCC)(S)=S.[O] UZAUWPKHSDCXCN-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- WBRJQOHIFXIMCO-UHFFFAOYSA-N P(=S)(S)(O)O.C(CCC)[Zn]CCCCCCCC Chemical compound P(=S)(S)(O)O.C(CCC)[Zn]CCCCCCCC WBRJQOHIFXIMCO-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- RQVGZVZFVNMBGS-UHFFFAOYSA-N n-octyl-n-phenylaniline Chemical compound C=1C=CC=CC=1N(CCCCCCCC)C1=CC=CC=C1 RQVGZVZFVNMBGS-UHFFFAOYSA-N 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 150000002895 organic esters Chemical class 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 231100000241 scar Toxicity 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- 102220465832 La-related protein 1_F10A_mutation Human genes 0.000 description 1
- OEODFVSDZLWNCV-UHFFFAOYSA-K P(=S)([S-])([O-])[O-].C(C)(CC)[Zn+].C(C)(CC)[Zn+].C(C)(CC)[Zn+] Chemical class P(=S)([S-])([O-])[O-].C(C)(CC)[Zn+].C(C)(CC)[Zn+].C(C)(CC)[Zn+] OEODFVSDZLWNCV-UHFFFAOYSA-K 0.000 description 1
- YGGCYLGGLXNLIF-UHFFFAOYSA-K P(=S)([S-])([O-])[O-].C(CCCCCCC)[Mo+3]CCCCCCCC Chemical compound P(=S)([S-])([O-])[O-].C(CCCCCCC)[Mo+3]CCCCCCCC YGGCYLGGLXNLIF-UHFFFAOYSA-K 0.000 description 1
- QAPVYZRWKDXNDK-UHFFFAOYSA-N P,P-Dioctyldiphenylamine Chemical compound C1=CC(CCCCCCCC)=CC=C1NC1=CC=C(CCCCCCCC)C=C1 QAPVYZRWKDXNDK-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- GNVMUORYQLCPJZ-UHFFFAOYSA-M Thiocarbamate Chemical compound NC([S-])=O GNVMUORYQLCPJZ-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000010725 compressor oil Substances 0.000 description 1
- 125000005266 diarylamine group Chemical group 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012208 gear oil Substances 0.000 description 1
- 239000010720 hydraulic oil Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000005078 molybdenum compound Substances 0.000 description 1
- 150000002752 molybdenum compounds Chemical class 0.000 description 1
- KHYKFSXXGRUKRE-UHFFFAOYSA-J molybdenum(4+) tetracarbamodithioate Chemical compound C(N)([S-])=S.[Mo+4].C(N)([S-])=S.C(N)([S-])=S.C(N)([S-])=S KHYKFSXXGRUKRE-UHFFFAOYSA-J 0.000 description 1
- 150000004712 monophosphates Chemical class 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
- MBBWTVUFIXOUBE-UHFFFAOYSA-L zinc;dicarbamodithioate Chemical compound [Zn+2].NC([S-])=S.NC([S-])=S MBBWTVUFIXOUBE-UHFFFAOYSA-L 0.000 description 1
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- Lubricants (AREA)
Abstract
The present invention relates to a lubricating oil composition having the functions of oxidation resistance, wear resistance and attrition resistance. The lubricating oil composition is made from the components in weight percentages: 0.1 to 3.5% of dialkyl zinc dithiophosphate, dialkyl copper dithiophosphate, dialkyl magnesium dithiophosphate, dialkyl calcium dithiophosphate and dialkyl barium dithiophosphate, 0.2 to 3.0% of an antioxidant mixture of an amine antioxidant and a phenolic ester antioxidant, 0.05 to 1.5% of a molybdenum salt of dialkyl dithioic organic acid, 0.05 to 1.5% of a monohydric alcohol ester wear-resistant attrition-resistant agent or a polyhydric alcohol ester wear-resistant attrition-resistant agent generated by a monohydric alcohol or a polyhydric alcohol reacting with alkyl, arene or alkylphenol substituted by carboxylic acid, and 0.05 to 1.5% of a zinc salt, a calcium salt, a sodium salt, a barium salt and a magnesium salt of dialkyl dithiocarbamate or dialkyl dithiocarbamic acid, and balance of lubricating oil.
Description
Technical field
The present invention relates to lubricating oil composition, specifically, is a kind of internal combustion (IC) engine oil composition with the effect of antioxygen antiwear and antifriction, particularly high-grade composition oil of gasoline engine.
Background of invention
Car combustion engine is bearing the function influence of Working environment during operation with lubricating oil, and this environment such as high temperature make oil oxidation and promote the oxidation; The impurity such as compounds such as iron that exists in oil product then plays a part catalysed promoted to this oxidation.I. C. engine oil this oxygenizement during use generally is controlled to a certain extent by use oxidation inhibitor, and oxidation inhibitor can prolong the work-ing life of oil product.The general independent use dialkyl zinc dithiophosphate of I. C. engine oil in the past (ZDDP), or with the compound requirement that can satisfy oil product to antioxidant property of a spot of pentanoic type oxidation inhibitor.
Along with the employing of direct fuel injection technology, the oil engine specific power increases, and chamber temperature raises, and I. C. engine oil uses ZDDP or compound a small amount of pentanoic can not satisfy the requirement of oil product to high temperature oxidation resistance separately, the oxidation inhibitor of compound other kinds; Simultaneously, because harsh day by day environmental requirement, the installation of Exhaust Gas Catalytic Converter for Automobiles, for prolonging the work-ing life of catalytic converter, oil specification is limited the gasoline engine oil phosphorus content, SH/GF-1 is for being not more than 0.12%, SJ/GF-2 is not more than 0.10%, and SL/GF-3 is for being not more than 0.10%, and SM/GF-4 tentatively is decided to be and is not more than 0.08%, it is impossible to improve antioxygen by the add-on that strengthens ZDDP, therefore wants compound other oxidation inhibitor to remedy the antioxidant property of oil product.
Owing to control phosphorus content, limited the add-on of the ZDDP with the wear-resistant function of antioxygen.Because the increase of oil engine specific power, engine load improves, and the abrasion resistance of employed lubricating oil is proposed higher requirement, and this also requires to use the anti-wear agent of other kinds to improve the abrasion resistance of oil product.
The requirements of saving energy of Ti Gaoing more and more comes into one's own the development of the lubricating oil with energy-conserving action day by day.Further reducing friction is the main means that improve the lubricating oil energy-saving effect, generally reaches by reducing oil viscosity and adding low friction compound.
U.S. Pat 09/281747, Chinese patent CN1268556A provide a kind of lubricant that contains molybdenum compound, phenates and diaryl-amine, improve the resistance of oxidation of lubricating oil and reduce settling.Do not mention the use of phenolic ester type oxidation inhibitor and ester type wear-resistant friction reducer.
European patent EP 98309774.2, Chinese patent CN1255533A provide a kind of lubricant compositions that shows permanent oxidation stability, have improved thermostability and oxidative stability, the antioxygen anti-wear agent that wherein relates to is amine oxidation inhibitor, ashless dithio carbamate, olefine sulfide and phenol oxidation inhibitor, and only is applicable in the antiwear hydraulic oil.The use of not mentioned molybdenum salt, phenolic ester type oxidation inhibitor, ester type wear-resistant friction reducer and compound.
U.S. Pat 60/095322, Chinese patent CN1320151A provide a kind of high perofmrnace lubricating oils, its wear-resistant component that relates to is the phosphatic adducts of alkylamine alkyl acid, antioxygen component phenolic antioxidant and arylamine antioxidant are applicable to gear oil, compressor oil, circulation wet goods.The use of not mentioned ZDDP, molybdenum salt, phenolic ester type oxidation inhibitor, ester type wear-resistant friction reducer and compound.
Chinese patent CN1268553A provides a kind of lubricating oil antioxygen composition, and introduced its application in I. C. engine oil, the antioxygen component that relates to is an alkali metal salt, aromatic amine compound, organic ester and alcohol, and wherein the application of organic ester and alcohol is to make an alkali metal salt to be dissolved in the mineral oil.The use of not mentioned ZDDP, molybdenum salt, phenolic ester type oxidation inhibitor, ester type wear-resistant friction reducer and compound.
U.S. Pat 226765, Chinese patent CN1039837A provide a kind of lubricating oil composition and enriched material, are used for the lubricant formula of oil engine.Said composition is made up of the neutrality or the alkaline metal salt of the metal-salt of the partial fatty acid ester of carboxylic acid derivative, polyvalent alcohol, dialkyl curing phosphoric acid, carboxylates derivatives component, acidic organic compound, the antioxygen anti-wear agent that relates to is the metal-salt of dialkyl curing phosphoric acid, and low friction compound is the partial fatty acid ester of polyvalent alcohol.The compound use of not mentioned molybdenum salt, phenolic ester type oxidation inhibitor, ester type wear-resistant friction reducer.
U.S. Pat 199667, Chinese patent CN1042176A provide a kind of lubricating oil composition that is used for I. C. engine oil, and said composition is made up of the partial fatty acid ester of an alkali metal salt of base oil, carboxylic acid derivative component, alkaline sulfoacid or carboxylic acid, hydrocarbyl dithiophosphoric acid salt, polyvalent alcohol.The use of not mentioned molybdenum salt, amine type oxidation inhibitor, phenolic ester type oxidation inhibitor, ester type wear-resistant friction reducer and compound.
U.S. Pat 226802, Chinese patent CN1040216A provide a kind of lubricating oil composition that is used for I. C. engine oil, and said composition is made up of the partial fatty acid ester of the neutrality of the metal-salt of the alkali metal sulfonate of base oil, carboxylic acid derivative component, alkalescence or carboxylate salt, dialkyl phosphorodithioic acid, acidic organic compound or basic alkaline earth metal salt, polyvalent alcohol.The use of not mentioned molybdenum salt, amine type oxidation inhibitor, phenolic ester type oxidation inhibitor, ester type wear-resistant friction reducer and compound.
Summary of the invention
The purpose of this invention is to provide a kind of lubricating oil composition with antioxygen, wear-resistant and antifriction function.
Lubricating oil composition provided by the invention is a benchmark with the composition gross weight, comprises following component:
(A) zinc of dialkyl phosphorodithioic acid, copper, magnesium, calcium or barium salt, content are 0.1-3.5%;
(B) oxidation inhibitor, content are 0.2-3.0%;
(C) dialkyl dithio organic acid molybdenum salt, content is 0.05-1.5%;
(D) ester type wear-resistant friction reducer, content are 0.05-1.5%;
(E) zinc of dialkyldithiocarbamates ester or dialkyldithiocarbamates, calcium, sodium, barium or magnesium salts, content are 0.05-1.5%;
(F) lubricating oil, surplus.
Described component (A) is zinc, copper, magnesium, calcium, barium salt or its mixture of dialkyl phosphorodithioic acid, preferred zinc salt and mantoquita, more preferably zinc salt.Alkyl wherein is C2-C12, the alkyl or alkenyl of preferred C4-C8, preferred primary alkyl and secondary alkyl.Carbon number with two alkyl in the monophosphate can be identical, also can be different.The add-on of component (A) is 0.1-3.5%, is preferably 0.4-2.5%, more preferably 0.5-2.0%.
Described component (B) is an oxidation inhibitor, is the mixture of amine type oxidation inhibitor and phenolic ester type oxidation inhibitor, and the weight ratio of the two is 2.5: 1-1: 2.5, be preferably 1.5: 1-1: 1.5.Wherein amine type oxidation inhibitor is selected from alkylation aniline, alkylated diphenylamine and nonox, and alkyl carbon number wherein is C2-C12.Preferred dibutyl pentanoic, dioctyl diphenylamine, dinonyldiphenylamine, fourth octyl diphenylamine or nonox, more preferably fourth octyl diphenylamine.Phenolic ester type oxidation inhibitor is that molecular weight is the hydroxy phenyl carboxylicesters of 200-500, for example tertiary butyl hydroxy phenyl n-octyl propionate, the different monooctyl ester of butylhydroxy phenylpropionic acid, the own ester of butylhydroxy phenylpropionic acid, butylhydroxy phenylpropionic acid dissident ester, butylhydroxy phenylpropionic acid heptyl ester, butylhydroxy phenylpropionic acid isocyanate, butylhydroxy phenylpropionic acid ester in the ninth of the ten Heavenly Stems, butylhydroxy phenylpropionic acid ester in the different ninth of the ten Heavenly Stems, butylhydroxy phenylpropionic acid ester in the last of the ten Heavenly stems, butylhydroxy phenylpropionic acid isodecyl ester or butylhydroxy phenylpropionic acid 11 carbon carboxylicesterss etc.The add-on of component (B) is 0.2-3.0%, is preferably 0.4-2.0%, more preferably 0.4-1.5%.
Described component (C) is dialkyl dithio organic acid molybdenum salt and composition thereof, and alkyl wherein is C2-C12, the alkyl or alkenyl of preferred C4-C8, preferred primary alkyl and secondary alkyl.As the dialkyl molybdenum dithiophosphate, dialkyl phosphorodithioic acid oxygen moly-sulfide, molybdenum dialkyldithiocarbamates etc.(C) add-on is 0.05-1.5%, is preferably 0.1-1.0%.
Described component (D) is an ester type antioxygen wear-resistant friction reducer, is the monobasic or the polyol ester of the carboxylic acid generation of monobasic or polyvalent alcohol and alkyl, aromatic hydrocarbons or alkylphenol replacement.12 carbon carboxylic acid glycerine esters, 2 for example, 6-di-t-butyl-1-hydroxy phenylpropionic acid glycerine ester etc.Alcohol is preferably polyvalent alcohol, more preferably trivalent alcohol.(D) add-on is 0.05-1.5%, is preferably 0.1-1.0%.
Described component (E) is selected from (1) dialkyldithiocarbamates ester; (2) zinc of dialkyldithiocarbamates, calcium, sodium, barium or magnesium metal-salt.Be preferably the dialkyl thiocarbamate, more preferably the zinc salt of dialkyldithiocarbamates.Alkyl wherein is C2-C12, the alkyl or alkenyl of preferred C4-C8, preferred primary alkyl and secondary alkyl.(E) add-on is 0.05-1.5%, is preferably 0.1-1.0%.
Described lubricating oil is II class base oil, and its relevant physicochemical property requirement is: viscosity index 80-120, saturated hydrocarbon content 〉=90%, element sulfur content≤0.03%.
Lubricating oil composition provided by the invention has excellent antioxygen, wear-resistant and antifriction function.
Embodiment
The used additive of the present invention is commercially available, and wherein the source of the component of using among the present invention (A) includes but not limited to: 656 etc. of T202, the T203 of the T202 of Jinzhou Liu Chang, T203, T205, Xishan additive factory, ethyl corporation; The source of component (B) includes but not limited to: the IRGANOX L06 that Ciba refines, IRGANOX L57, IRGANOX L101, IRGANOX L107, IRGANOX L118, IRGANOX L115, IRGANOX L135,5510 of Lubrizol company, the Goodrite 3128 of BF Goodish Specialty Chemicals company, Goodrite3185X, Goodrite3190X29, the Vanlube DND of R.T.Vanderbilt company, Vanlube NA, Vanlube PNA, Vanlube SL, Vanlube SS, Vanlube 81, the ADPA of RIPP, T512 etc.; The source of component (C) includes but not limited to: the MolyVan A of R.T.Vanderbilt company, MolyVan L, MolyVan 822, MolyVan 855 etc.; The source of component (D) includes but not limited to: the IRGALUBE F10 that Ciba refines, IRGALUBE F10A etc.; The source of component (E) includes but not limited to: BZ, the AZ of R.T.Vanderbilt company etc. in chemical plant, river, footpath, Wuhan.
The good performance of the following example explanation present composition does not limit the present invention, reaches other and use parts in these examples, and except as otherwise noted, all umbers and percentage number average are by weight.
The antioxidant property of oil product adopts pressurization dsc (PDSC) to estimate, test method is that constant temperature when being warming up to 215 ℃ with 50 ℃/min speed, feeding flow are that 50ml/min pressure is the oxygen of 5atm, measures the oxidation induction period of oil product in the time of 215 ℃.
The antiwear and friction reduction property of oil product adopts four-ball friction and wear test machine to estimate, and test conditions is 75 ℃, 40Kg, 1200rpm.Measure wear scar diameter, the frictional coefficient of oil product.
Among the embodiment, the base oil of 10W/40 SJ/SH prescription is the base oil (II+) of the hydrogenation technique production in the II class base oil, and the base oil of 15W/40 SJ/SH prescription is the base oil of " old three covers " explained hereafter in the II class base oil.
Embodiment one
The additive of following proportioning is joined in the 10W/40 SJ/SH level gasoline engine oil, carry out the antioxygen antiwear and friction reduction property and measure.Test-results sees Table 1.
(A) butyl octyl zinc dithiophosphate 0.5%, di-secondary fourth octyl group zinc dithiophosphate 0.3%;
(B) the butyl octyl pentanoic 0.5%, tertiary butyl hydroxy phenyl n-octyl propionate oxidation inhibitor 0.4%;
(C) dioctyl phosphorodithioic acid oxygen moly-sulfide 0.5%;
(D) trivalent alcohol carboxylicesters wear-resistant friction reducer 0.2%;
(E) the dioctyl zinc dithiocarbamate 0.2%.
Embodiment two
The additive of following proportioning is joined in the 10W/40 SJ/SH level gasoline engine oil, carry out the antioxygen antiwear and friction reduction property and measure.Test-results sees Table 1
(A) zinc dibutyldithiophosphate 0.6%;
(B) the butyl octyl pentanoic 0.5%, tertiary butyl hydroxy phenyl n-octyl propionate oxidation inhibitor 0.5%;
(C) dioctyl phosphorodithioic acid oxygen moly-sulfide 0.5%;
(D) trivalent alcohol carboxylicesters wear-resistant friction reducer 0.1%;
(E) the dioctyl zinc dithiocarbamate 0.2%.
Embodiment three
The additive of following proportioning is joined in the 15W/40 SJ/SH level gasoline engine oil, carry out the antioxygen antiwear and friction reduction property and measure.Test-results sees Table 1.
(A) butyl octyl zinc dithiophosphate 0.3%, two sec-butyl zinc dithiophosphates 0.3%;
(B) the butyl octyl pentanoic 0.4%, the different monooctyl ester oxidation inhibitor 0.5% of tertiary butyl hydroxy phenyl propionic acid;
(C) fourth octyl group molybdenum dithiocarbamate 0.5%;
(D) trivalent alcohol carboxylicesters wear-resistant friction reducer 0.2%;
(E) the dioctyl zinc dithiocarbamate 0.2%.
Embodiment four
The additive of following proportioning is joined in the 15W/40 SJ/SH level gasoline engine oil, carry out the antioxygen antiwear and friction reduction property and measure.Test-results sees Table 1.
(A) zinc dibutyldithiophosphate 1.2%;
(B) the butyl octyl pentanoic 0.4%, tertiary butyl hydroxy phenyl n-hexyl propionate oxidation inhibitor 0.4%;
(C) the dibutyl dithiocaarbamate molybdenum 0.5%;
(D) trivalent alcohol carboxylicesters wear-resistant friction reducer 0.3%;
(E) fourth octyl group zinc dithiocarbamate 0.2%.
Embodiment five
The additive of following proportioning is joined in the 10W/40 SJ/SH level gasoline engine oil, carry out the antioxygen antiwear and friction reduction property and measure.Test-results sees Table 1.
(A) dioctyl zinc dithiophosphate 0.1%, fourth octyl group zinc dithiophosphate 0.3%, Zhong Ding octyl group zinc dithiophosphate 0.2%;
(B) dioctyl diphenylamine 0.4%, the different monooctyl ester oxidation inhibitor 0.4% of tertiary butyl hydroxy phenyl propionic acid;
(C) the dioctyl molybdenum dithiocarbamate 0.6%;
(D) trivalent alcohol carboxylicesters wear-resistant friction reducer 0.2%;
(E) the dioctyl zinc dithiocarbamate 0.2%.
Embodiment six
The additive of following proportioning is joined in the 10W/40 SJ/SH level gasoline engine oil, carry out the antioxygen antiwear and friction reduction property and measure.Test-results sees Table 1.
(A) dioctyl zinc dithiophosphate 0.8%, fourth octyl group zinc dithiophosphate 0.3%;
(B) dioctyl diphenylamine 0.4%, tertiary butyl hydroxy phenyl n-decyl propionate oxidation inhibitor 0.4%;
(C) the dioctyl molybdenum dithiocarbamate 0.2%;
(D) trivalent alcohol carboxylicesters wear-resistant friction reducer 0.4%;
(E) the dioctyl zinc dithiocarbamate 0.4%.
Embodiment seven
The additive of following proportioning is joined in the 10W/40 SJ/SH level gasoline engine oil, carry out the antioxygen antiwear and friction reduction property and measure.Test-results sees Table 1.
(A) zinc dibutyldithiophosphate 0.7%, Zhong Ding octyl group zinc dithiophosphate 0.5%;
(B) the dibutyl pentanoic 0.5%, tertiary butyl hydroxy phenyl heptyl propionate oxidation inhibitor 0.4%;
(C) the dioctyl molybdenum dithiophosphate 0.5%;
(D) trivalent alcohol carboxylicesters wear-resistant friction reducer 0.2%;
(E) zinc dibutyl dithiocarbamate 0.2%.
Embodiment eight
The additive of following proportioning is joined in the 15W/40 SJ/SH level gasoline engine oil, carry out the antioxygen antiwear and friction reduction property and measure.Test-results sees Table 1.
(A) the dioctyl zinc dithiophosphate 1.1%;
(B) dioctyl diphenylamine 0.5%, tertiary butyl hydroxy phenyl propionic acid isocyanate oxidation inhibitor 0.5%;
(C) the butyl octyl molybdenum dithiophosphate 0.5%;
(D) trivalent alcohol carboxylicesters wear-resistant friction reducer 0.1%;
(E) the dioctyl zinc dithiocarbamate 0.2%.
Table 1 test-results
| Wear scar diameter, mm | Frictional coefficient | PDSC inductive phase, min | |
| Embodiment one | 0.37 | 0.060 | 29 |
| Embodiment two | 0.38 | 0.082 | 32 |
| Embodiment three | 0.39 | 0.104 | 34 |
| Embodiment four | 0.35 | 0.088 | 34 |
| Embodiment five | 0.36 | 0.103 | 33 |
| Embodiment six | 0.35 | 0.093 | 29 |
| Embodiment seven | 0.35 | 0.065 | 28 |
| Embodiment eight | 0.36 | 0.080 | 28 |
| Commercially available oil * | 0.40 | 0.107 | 25 |
* commercially available oil is: Great Wall 10W/40SH gasoline engine oil.
From table the result as can be seen, lubricating oil composition of the present invention and commercially available oil phase ratio, wearing and tearing obviously reduce, friction significantly reduces, oxidation stability improves.
Claims (13)
1. the lubricating oil composition with antioxygen, wear-resistant and antifriction function is a benchmark with the composition gross weight, comprises following component:
(A) zinc of dialkyl phosphorodithioic acid, copper, magnesium, calcium or barium salt, content are 0.1-3.5%;
(B) the mixing oxidation inhibitor of amine type oxidation inhibitor and phenolic ester type oxidation inhibitor composition, content is 0.2-3.0%;
(C) dialkyl dithio organic acid molybdenum salt, content is 0.05-1.5%;
(D) monobasic or the polyol ester wear-resistant friction reducer of the carboxylic acid generation of monobasic or polyvalent alcohol and alkyl, aromatic hydrocarbons or alkylphenol replacement, content is 0.05-1.5%;
(E) zinc of dialkyldithiocarbamates ester or dialkyldithiocarbamates, calcium, sodium, barium or magnesium salts, content are 0.05-1.5%;
(F) II class lubricating oil base oil, surplus.
2. according to the described composition of claim 1, it is characterized in that described component (A) is the zinc salt or the mantoquita of dialkyl phosphorodithioic acid, alkyl wherein is C2-C12 alkyl or C2-C12 thiazolinyl, and the add-on of component (A) is 0.4-2.5%.
3. according to claim 1 or 2 described compositions, it is characterized in that described component (A) is the zinc salt of dialkyl phosphorodithioic acid, alkyl wherein is primary alkyl or the secondary alkyl of C4-C8 of C4-C8, and the add-on of component (A) is 0.5-2.0%.
4. according to the described composition of claim 1, it is characterized in that the weight ratio of amine type oxidation inhibitor and phenolic ester type oxidation inhibitor is 2.5 in the described component (B): 1-1: 2.5, the add-on of component (B) is 0.4-2.0%.
5. according to claim 1 or 4 described compositions, it is characterized in that the weight ratio of amine type oxidation inhibitor and phenolic ester type oxidation inhibitor is 1.5 in the described component (B): 1-1: 1.5, the add-on of component (B) is 0.4-1.5%.
6. according to the described composition of claim 1, it is characterized in that wherein amine type oxidation inhibitor is selected from alkylation aniline, alkylated diphenylamine and nonox.
7. according to claim 1 or 6 described compositions, it is characterized in that wherein amine type oxidation inhibitor is selected from dibutyl pentanoic, dioctyl diphenylamine, dinonyldiphenylamine, butyl octyl pentanoic or nonox.
8. according to the described composition of claim 1, it is characterized in that phenolic ester type oxidation inhibitor is that molecular weight is the hydroxy phenyl carboxylicesters of 200-500.
9. according to claim 1 or 8 described compositions, it is characterized in that phenolic ester type oxidation inhibitor is selected from tertiary butyl hydroxy phenyl n-octyl propionate, the different monooctyl ester of butylhydroxy phenylpropionic acid, the own ester of butylhydroxy phenylpropionic acid, butylhydroxy phenylpropionic acid dissident ester, butylhydroxy phenylpropionic acid heptyl ester, butylhydroxy phenylpropionic acid isocyanate, butylhydroxy phenylpropionic acid ester in the ninth of the ten Heavenly Stems, butylhydroxy phenylpropionic acid ester in the different ninth of the ten Heavenly Stems, butylhydroxy phenylpropionic acid ester in the last of the ten Heavenly stems, butylhydroxy phenylpropionic acid isodecyl ester or butylhydroxy phenylpropionic acid 11 carbon carboxylicesterss.
10. according to the described composition of claim 1, it is characterized in that described component (C) is selected from dialkyl molybdenum dithiophosphate, dialkyl phosphorodithioic acid oxygen moly-sulfide, molybdenum dialkyldithiocarbamates or its mixture.
11., it is characterized in that alkyl wherein is C2-C12 alkyl or C2-C12 thiazolinyl according to the described composition of claim 10, add-on (C) is 0.1-1.0%.
12., it is characterized in that described component (D) is selected from 12 carbon carboxylic acid glycerine esters or 2 according to the described composition of claim 1,6-di-t-butyl-1-hydroxy phenylpropionic acid glycerine ester, add-on (D) is 0.1-1.0%.
13., it is characterized in that described component (E) is a dialkyldithiocarbamates zinc according to the described composition of claim 1, alkyl wherein is C2-C12 alkyl or C2-C12 thiazolinyl, add-on (E) is 0.1-1.0%.
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| CN 200310103032 CN1286959C (en) | 2003-10-31 | 2003-10-31 | Lubricating oil composition |
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| PL2633009T3 (en) | 2010-10-26 | 2016-10-31 | Non-aqueous lubricant and fuel compositions comprising fatty acid esters of hydroxy- carboxylic acids, and uses thereof | |
| CN102690715B (en) * | 2011-03-24 | 2014-03-12 | 中国石油化工股份有限公司 | Lubricant composition for four-stroke motorcycle engine |
| CN102690711B (en) * | 2011-03-24 | 2013-12-25 | 中国石油化工股份有限公司 | Lubricant composition for gasoline engine |
| CN107353975A (en) * | 2017-06-27 | 2017-11-17 | 山西潞安太行润滑油有限公司 | A kind of lubricating oil composition for diesel engine composition |
| CN108485761A (en) * | 2018-03-22 | 2018-09-04 | 金诺斯（北京）石油化工制品有限公司 | A kind of semi-synthetic gasoline engine oil and preparation method thereof |
| CN108570347A (en) * | 2018-05-29 | 2018-09-25 | 山西潞安煤基合成油有限公司 | A kind of lubricating oil composition for diesel engine composition |
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