CN1286907A - Clomazone-pretilachlore herbicide for dryland and its production process - Google Patents

Clomazone-pretilachlore herbicide for dryland and its production process Download PDF

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Publication number
CN1286907A
CN1286907A CN 99116833 CN99116833A CN1286907A CN 1286907 A CN1286907 A CN 1286907A CN 99116833 CN99116833 CN 99116833 CN 99116833 A CN99116833 A CN 99116833A CN 1286907 A CN1286907 A CN 1286907A
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Prior art keywords
clomazone
missible oil
herbicide
inserts
dryland
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CN 99116833
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Chinese (zh)
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CN1108751C (en
Inventor
张建明
吴春林
张洪进
张寄伯
张治�
杨慕林
吴顶汉
顾红
王东华
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TONGZHOU ZHENGDA PESTICIDE PLANT
TONGZHOU CITY PLANT HOSPITAL
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TONGZHOU ZHENGDA PESTICIDE PLANT
TONGZHOU CITY PLANT HOSPITAL
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Priority to CN99116833A priority Critical patent/CN1108751C/en
Publication of CN1286907A publication Critical patent/CN1286907A/en
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Publication of CN1108751C publication Critical patent/CN1108751C/en
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Abstract

The dryland herbicide includes clomazone 0.36-18.0 wt% and pretilachlor 7.0-49.64 wt% as active herbicide components as well as stuffing 32.36-92.64 wt%. The stuffing for the dryland herbicide in emulsion form is dimethylabenzene while that for the dryland herbicide in wettable powder form is active carbon, white carbon or light calcium carbonate. The present invention has the advantages of high herbicide effect to annual and biennial monocotylous and dicotylous weeds and safety to latifolious crops.

Description

Clomazone-pretilachlore herbicide for dryland and manufacture method thereof
The present invention relates to a kind of weed killer herbicide and manufacture method thereof that is used for Dry crop fields such as rape, cotton, soybean, sugarcane, broad bean.
In the existing Dry crop weed killer herbicide, generally can only prevent and kill off broad-leaved Dry crop Tanaka's monocotyledon weed, not good enough to the broadleaf weed preventive effect, or dangerous to broad leaf crop.
The objective of the invention is provides a kind of clomazone-pretilachlore herbicide for dryland and manufacture method thereof in order to overcome above-mentioned weak point.This weed killer herbicide all has good preventive effect to the monocotyledon weed and the broadleaf weed in Dry crop field, and to broad leaf crop safety.
Technical scheme of the present invention: clomazone-pretilachlore herbicide for dryland includes clomazone, the third careless amine of activity of weeding composition, and filler.By weight, the percentage of each component is:
Clomazone 0.36~18.0%
The third careless amine 7.0~49.64%
Inserts 32.36~92.64%
Clomazone is an adopted name, and its chemical name is:
2-(2-benzyl chloride base)-4, the different azoles of 4-dimethyl-3-ketone
Molecular formula is: C 12H 14ClNO 2
Structural formula is:
Figure 9911683300041
The third careless amine is adopted name, and its chemical name is:
α-chloro-2,6 '-diethyl-N-(the 2-third oxygen ethyl) acetanil molecular formula is: C 17H 26ClHO 2Structural formula is:
Inserts: the inserts of the clomazone-pretilachlore herbicide for dryland of emulsion-type is a dimethylbenzene; The inserts of the clomazone-pretilachlore herbicide for dryland of wettable powder formulation is an activated carbon, or white carbon black, or precipitated calcium carbonate, or diatomite, or kaolin, or potter's clay.
The manufacture method of clomazone-pretilachlore herbicide for dryland:
1, the manufacture method of missible oil type clomazone-pretilachlore herbicide for dryland:
Produce missible oil type clomazone-pretilachlore herbicide for dryland, the 72% clomazone missible oil that raw material is produced with U.S. FMC Corp., contain clomazone 72g in the 100ml clomazone missible oil, 50% auspiciously fly special missible oil with what Switzerland Novartis Co.,Ltd produced, 100ml is auspicious to fly to contain in the special missible oil the third careless amine 50g, inserts dimethylbenzene.By weight, the shared percentage of each component is: 72% clomazone missible oil, 0.5~25%, 50% auspicious special missible oil 10~99.28%, the dimethylbenzene 0.22~89.50% of flying.These components are stirred in reactor, get product.
But the manufacture method of 2 wet-milling type clomazone-pretilachlore herbicide for dryland:
But produce wet-milling type clomazone-pretilachlore herbicide for dryland, the 72% clomazone missible oil that raw material is produced with U.S. FMC Corp., contain clomazone 72g in the 100ml clomazone missible oil, 50% auspiciously fly special missible oil with what Switzerland Novartis Co.,Ltd produced, 100ml is auspicious to fly to contain in the special missible oil the third careless amine 50g, inserts is an activated carbon, or white carbon black, or precipitated calcium carbonate, or diatomite, or kaolin, or potter's clay.By weight, the shared percentage of each component is: 72% clomazone missible oil, 0.5~20%, 50% auspicious special missible oil 14~30%, the inserts 50~85.5% of flying.Earlier with 72% clomazone missible oil and 50% auspicious fly special missible oil mixed evenly after, be sprayed in the inserts with spray-on process, mix while spray, after the mechanical uniform mixing, again through comminution by gas stream, must finished product.
Major advantage of the present invention is: to the Dry crop field one, biennial single, double cotyledon weeds all have good herbicidal effect, and to broad leaf crop safety, the succession crop noresidue is poisoned, can not cause stiff seedling of succession crops such as paddy rice, corn and residual phytotoxicity accident.
Embodiment 1:
Clomazone-pretilachlore herbicide for dryland of the present invention includes clomazone, the third careless amine of activity of weeding composition and filler.By weight, the percentage of each composition can also for:
Clomazone 0.5~1 5.0%
The third careless amine 8.0~48.0%
Inserts 37.0~91.5%
Embodiment 2:
Type of production missible oil type clomazone-pretilachlore herbicide for dryland, the 72% clomazone missible oil that raw material is produced with U.S. FMC Corp., contain clomazone 72g in the 100ml clomazone missible oil, 50% auspiciously fly special missible oil with what Switzerland Novartis Co.,Ltd produced, 100ml is auspicious to fly to contain in the special missible oil the third careless amine 50g, inserts dimethylbenzene.By weight, the shared percentage of each component is: be 72% clomazone missible oil, 5%, 50% auspicious special missible oil 12.8%, the dimethylbenzene 77.2% of flying.These components are stirred in reactor, get product.
Embodiment 3:
But wet-milling type clomazone-pretilachlore herbicide for dryland, the 72% clomazone missible oil that raw material is produced with U.S. FMC Corp., contain clomazone 72g in the 100ml clomazone missible oil, 50% auspiciously fly special missible oil with what Switzerland Novartis Co.,Ltd produced, 100ml is auspicious to fly to contain in the special missible oil the third careless amine 50g, inserts is an activated carbon, or white carbon black, or precipitated calcium carbonate, or diatomite, or kaolin, or potter's clay.By weight, the shared percentage of each component is: 72% clomazone missible oil, 20.0%, 50% auspicious special missible oil 19.2%, the inserts 60.8% of flying.Earlier with 72% clomazone missible oil and 50% auspicious fly special missible oil mixed evenly after, be sprayed in the inserts with spray-on process, mix while spray, after the mechanical uniform mixing, again through comminution by gas stream, must finished product.

Claims (3)

1, a kind of clomazone-pretilachlore herbicide for dryland that is used for the weeding of Dry crop field is characterized in that it includes the clomazone of activity of weeding composition, the third careless amine, and inserts, and by weight, the shared percentage of each component is:
Clomazone 0.36~18.0%
The third careless amine 7.0~49.64%
Inserts 32.36~92.64%
The inserts of missible oil type clomazone-pretilachlore herbicide for dryland is a dimethylbenzene, but the inserts of wet-milling type clomazone-pretilachlore herbicide for dryland is an activated carbon, or white carbon black, or precipitated calcium carbonate, or diatomite, or kaolin, or potter's clay.
2, clomazone-pretilachlore herbicide for dryland according to claim 1 is characterized in that, it includes clomazone, the third careless amine of activity of weeding composition, and inserts, by weight, the shared percentage of each component can also for:
Clomazone 0.5~15.0%
The third careless amine 8.0~48.0%
Inserts 37.0~91.5%
3, the production method of clomazone-pretilachlore herbicide for dryland is characterized in that:
The production method of missible oil type clomazone-pretilachlore herbicide for dryland, the 72% clomazone missible oil that raw material is produced with U.S. FMC Corp., contain clomazone 72g in the 100ml clomazone missible oil, 50% auspiciously fly special missible oil with what Switzerland Novartis Co.,Ltd produced, 100ml is auspicious to fly to contain in the special missible oil the third careless amine 50g, inserts dimethylbenzene, by weight, the shared percentage of each component is: 72% clomazone missible oil 0.5~25%, 50% auspiciously flies special missible oil 10~99.28%, dimethylbenzene 0.22~89.50% stirs these components in reactor, get product;
But the production method of wet-milling type clomazone-pretilachlore herbicide for dryland, the 72% clomazone missible oil that raw material is produced with U.S. FMC Corp., contain clomazone 72g in the 100ml clomazone missible oil, 50% auspiciously fly special missible oil with what Switzerland Novartis Co.,Ltd produced, 100ml is auspicious to fly to contain in the special missible oil the third careless amine 50g, and inserts is an activated carbon, or white carbon black, or precipitated calcium carbonate, or diatomite, or kaolin, or potter's clay, by weight, the shared percentage of each component is: 72% clomazone missible oil, 0.5~20%, 50% auspicious special missible oil 14~30%, the inserts 50~85.5% of flying, earlier with 72% clomazone missible oil and 50% auspicious fly special missible oil mixed evenly after, be sprayed in the inserts with spray-on process, mix, after the mechanical uniform mixing while spraying, through comminution by gas stream, get finished product again.
CN99116833A 1999-09-03 1999-09-03 Clomazone-pretilachlore herbicide for dryland and its production process Expired - Fee Related CN1108751C (en)

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CN1108751C CN1108751C (en) 2003-05-21

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003030641A1 (en) * 2001-10-05 2003-04-17 Syngenta Participations Ag Herbicidal composition
CN100366155C (en) * 2004-06-18 2008-02-06 浙江天一农化有限公司 Mixed herbicide
CN102640759A (en) * 2012-04-01 2012-08-22 广东中迅农科股份有限公司 Weeding composition for rice direct-seeding field
CN103828818A (en) * 2012-11-27 2014-06-04 浙江天丰生物科学有限公司 Weeding composition containing pretilachlor and clomazone for lotus root field
WO2015197487A3 (en) * 2014-06-25 2016-04-28 Basf Se Formulation of clomazone having reduced volatility
CN106577689A (en) * 2016-10-31 2017-04-26 浙江天丰生物科学有限公司 Ternary compound paddy field weeding composition

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19834627A1 (en) * 1998-07-31 1998-12-03 Novartis Ag Broad-spectrum pre- or post=emergence herbicidal composition
DE19834629A1 (en) * 1998-07-31 1998-12-03 Novartis Ag Broad-spectrum pre- or post=emergence herbicidal composition

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003030641A1 (en) * 2001-10-05 2003-04-17 Syngenta Participations Ag Herbicidal composition
US7338920B2 (en) 2001-10-05 2008-03-04 Syngenta Crop Protection, Inc. Herbicidal composition
CN100366155C (en) * 2004-06-18 2008-02-06 浙江天一农化有限公司 Mixed herbicide
CN102640759A (en) * 2012-04-01 2012-08-22 广东中迅农科股份有限公司 Weeding composition for rice direct-seeding field
CN103828818A (en) * 2012-11-27 2014-06-04 浙江天丰生物科学有限公司 Weeding composition containing pretilachlor and clomazone for lotus root field
WO2015197487A3 (en) * 2014-06-25 2016-04-28 Basf Se Formulation of clomazone having reduced volatility
CN106577689A (en) * 2016-10-31 2017-04-26 浙江天丰生物科学有限公司 Ternary compound paddy field weeding composition

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