CN1286665C - Process for producing transfer printing films having a dull surface and a bright surface, and product made thereby - Google Patents

Process for producing transfer printing films having a dull surface and a bright surface, and product made thereby Download PDF

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Publication number
CN1286665C
CN1286665C CN 200310112414 CN200310112414A CN1286665C CN 1286665 C CN1286665 C CN 1286665C CN 200310112414 CN200310112414 CN 200310112414 CN 200310112414 A CN200310112414 A CN 200310112414A CN 1286665 C CN1286665 C CN 1286665C
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layer
picture
zone
text
production method
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CN1546320A (en
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陈松洲
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Guangdong Dongtian Transfer New Material Co ltd
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DONGTIAN TRANSFER MATERIALS Co Ltd
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Abstract

The present invention provides a production method for a transfer printing film with a dull surface and a bright surface and a product thereof. The present invention solves the problem of the existing printed objects of post treatment requirement for dull surface effect acquisition or difficult local acquisition of the dull surface effect. The production method of the transfer printing film of the present invention has the steps that first, a separated layer is uniformly coated or printed on a carrier film; then, a printer is used for printing a dull surface material layer on at least one region arranged on the separating layer; subsequently, a bright surface material layer is printed on region printed with no dull surface material layer by the printer; afterwards, a decorative layer and an adhesive layer are correspondingly printed on the separating layer. The transfer printing film produced by the production method of the present invention comprises the carrier film, the separating layer, the decorative layer and the adhesive layer, wherein the decorative layer comprises a protective layer; at least one region of the protective layer has the dull surface effect, and at least one region of the protective layer has the bright surface effect. When the transfer printing film of the present invention is used, some region of the printed object surface has the dull surface, and another region has the bright surface, so the decoration effect of products is increased; in addition, the hand feeling of users can be enhanced through increasing the roughness of some part of the printed object surface by the transfer printing film.

Description

Production method and goods thereof with mute face and bright transfer film
Technical field
The present invention relates to a kind of can to plastics, timber or surface-treated metal, glass, ceramic surface carry out the production method of the transfer film of hot transfer decorative, relate in particular to a kind of transfer surface that can make stock produces the transfer films of different reflections to light production method.The invention still further relates to the product that makes by this production method.
Background technology
Industrialization along with the hot transfer technique of China, applying of heat transfer film, a large amount of plastic products, timber-work, surperficial treated metal, glassware all obtain the decoration of picture and text by transfer printing, improved the class of product greatly, have increased the value of product.The hot pressing transfer film is meant the picture and text that have solid, under heating power and/or pressure effect, can be separated from carrier film together with protective layer, firmly then in the stock surface, and the print film of tool specific function.The conventional plastic cement hot pressing transfer film of tradition is by carrier film, release layer that carrier film is broken away from, and decorative layer and the following layer that plays cementation are formed, and decorative layer generally comprises protective layer, the picture and text layer that the picture and text surface is shielded.Protective layer generally is the smooth resin bed of layer of transparent that is made of polyurethane or acrylic resin, after the transfer printing, makes the object of undertaking the printing of have level and smooth, a bright surface.Along with the raising of living standard, the surface that people have not satisfied the property product all is level and smooth, this single form of light, and people's door requires the surface of some article to be mute light, more require the surface of some article not only to be mute light but also to be light; Body surface presents light or mute light, is that body surface is sliding more by the decision of the degree of roughness of body surface, and it is complete more to reflection of light, and then bright more, body surface is coarse more, and it is big more that it produces irreflexive degree to light, then apparent more mute light.If make product surface be mute light, then need product surface is carried out roughening, way in the past is frosted to be carried out on the surface of transfer printing product handle, or coats the UV gloss oil on the surface of transfer printing product, solidifies under UV-irradiation and makes its surface be mute light; More than two kinds of methods all need the product after the transfer printing is carried out post processing, both increased operation, loaded down with trivial details especially again.A kind of transfer film that can make the body transfer printing rear surface of undertaking the printing of promptly be mute light also appears now; it is to adopt the surface to have the polyester film of certain roughness as carrier film (mute light film); utilize carrier film peel off the back to protective layer stay concavo-convex; make the protective layer surface produce diffuse reflection, thereby present the effect of mute light light.This transfer film relatively is suitable for the whole surface of product requirement and is mute light effect, be mute light for the product requirement part, particularly require on certain pattern, to be mute light, remainder is light, or the situation of light and the alternate appearance of mute light, above-mentioned transfer film is obviously just inapplicable, and the product surface that is obtained by mute light film transfer printing can only slightly be mute light.
Summary of the invention
The purpose of this invention is to provide a kind of can make the stock transfer printing after, its transfer surface zones of different has different optical textures, thereby makes the stock surface portion be mute light, part is the production method of the transfer film of light.
Another object of the present invention provides a kind of transfer film with mute face and bright that is made by aforementioned production method.
For realizing above purpose, the production method of transfer film of the present invention may further comprise the steps successively:
(1) adopts coating machine or printing machine, on carrier film, evenly coat or stamp a release layer;
(2) adopt printing machine, at least one zone stamps a dulling material layer on release layer earlier; Stamp a glossy material layer again in the zone that does not stamp the dulling material layer;
(3),, stamp a picture and text layer at least in the corresponding region of above-mentioned protective layer according to designing requirement;
(4) on the picture and text layer and stamp the following layer of cementation together on the decorative layer that is not covered by the picture and text layer.
Above-mentioned production method, the dulling material in the step (2) are to add the graininess industrial chemicals that can evenly mix with it in solvent type resin or water-base resin liquid; Glossy material is solvent type resin or water-base resin, and water-base resin is water insoluble after solidifying drying.
Above-mentioned graininess industrial chemicals can be aerosil, Tissuemat E, poly-fluorine wax, alundum (Al, carbonate, mica powder, stearate, kaolin etc., also can be pearl essence, phosphor powder, titanium dioxide etc.; Solvent type resin or water-base resin can be acrylic acid, vinyl, acrylic, polyester resin.
In order to be fit to the picture and text printing of tiny site, above-mentioned production method before stamping the picture and text layer, stamps the layer of transparent printed substrate earlier, and this printed substrate also can generate when stamping the glossy material layer together.
In order to make stock present metal effect, vacuum plates an aluminium lamination to above-mentioned production method on the picture and text layer side being printed on earlier before stamping following layer.
When stock only needed the part to present metal effect, above-mentioned production method on aluminium coated, according to designing requirement, stamped acidproof or alkaline-resisting transparent ink in the zone of needs, by weak acid or weak base pond, unwanted aluminium lamination was washed off again.
Above-mentioned production method also can adopt solvent type ink to form pattern when the printing figure message layer earlier, and use printing ink is imprinted on patternless zone again; After vacuum aluminum-coated on the ink lay again in special-purpose tank by mechanism with the aluminium lamination flush away on the water color ink.
Above-mentioned production method also can be carried out vacuum aluminum-coatedly before stamping the picture and text layer earlier, again according to designing requirement, stamped acidproof or alkaline-resisting transparent ink in the zone of needs, by weak acid or weak base pond, unwanted aluminium lamination was washed off at last.
In order to make stock have the laser anti-counterfeiting function, in the aforementioned production method, also can increase a step, promptly any one deck in protective layer, printed substrate or the aluminium lamination is carried out mold pressing and handle, make it have the three dimensions visual effect.
The present invention also provides a kind of transfer film with mute face and bright that is made by production method of the present invention, and this transfer film comprises that a carrier film, a release layer, one can break away from and transfer to the decorative layer and the following layer of cementation together on the stock by heat and/or pressure from film carrier; Above-mentioned decorative layer comprises protective layer and picture and text layer, and protective layer has at least a zone to present mute light, and at least one zone presents light.
Also has a transparent printed substrate between above-mentioned protective layer and the picture and text layer.
The zone that presents mute light in the above-mentioned protective layer and the zone that presents light are alternately.
A certain picture and text is big or small corresponding in the zone that presents mute light in the above-mentioned protective layer and the picture and text layer.
A certain picture and text is big or small corresponding in the zone that presents light in the above-mentioned protective layer and the picture and text layer.
Also have a vacuum aluminium coated layer and acidproof or alkaline-resisting transparent ink layer between above-mentioned protective layer and the picture and text layer.
Also has an aluminium coated between above-mentioned picture and text layer and the following layer.
Also has an acidproof or alkaline-resisting transparent ink layer between above-mentioned aluminium coated and the following layer.
For the zone that makes protective layer after the transfer printing present light also shows slightly mute light, above-mentioned carrier film can be mute light film.
Any one deck in above-mentioned protective layer, printed substrate or the aluminium lamination has mould-pressed pictures and texts.
Production method of the present invention; because decorative layer all is to print on same printing machine; and mute light face and light face are to generate on protective layer, so the position can accurately be overlapped according to the pattern of designing requirement and other each decorative layers in the mute light zone of protective layer or light zone.
Transfer film of the present invention; because decorative layer topmost is a protective layer; and the roughness difference of zones of different in the protective layer; make it to reflection of light degree difference; thereby can be according to the design needs; utilize this transfer film transfer printing easily; make a certain zone, stock surface mute face occur; another zone occurs bright; thereby increase the ornamental of product; particularly when transfer film contained aluminium coated, the stock surface just can present bright the colorful picture of forming with the mute face of colored picture and text by metallic luster, significantly reduces the trouble that the product post processing brings.In addition, when some stock need strengthen its feel by the roughness that increases certain part of surface, for example penholder requires the part of finger contact to have certain roughness, is easy to grasp the strength of wieling the pen, and this transfer film also has the function that increases the stock feel.
Description of drawings
Fig. 1 is the structural representation of a kind of transfer film of the present invention.
Fig. 2 is the flow sheet of Fig. 1 transfer film.
Fig. 3 is the structural representation of the another kind of transfer film of the present invention.
Fig. 4 is the flow sheet of Fig. 3 transfer film.
Fig. 5 is the structural representation of the third transfer film of the present invention.
Fig. 6 is the flow sheet of Fig. 5 transfer film.
Fig. 7 is the structural representation of the 4th kind of transfer film of the present invention.
Fig. 8 is the flow sheet of Fig. 7 transfer film.
Fig. 9 is the structural representation of the 5th kind of transfer film of the present invention.
Figure 10 is the flow sheet of Fig. 9 transfer film.
Specific embodiment
As shown in Figure 1, 2, the top layer of this transfer film is a clear PET film 1, and the second layer is that the wax layer is a protective layer 3 for 2, the three layers, this layer is divided into two zones of 3a, 3b, and alternately, the 3a smooth surface is big to the reflection of light degree, present bright, the 3b surface ratio is more coarse, and luminous energy is produced diffuse reflection, presents mute face; The 4th layer is printing ink picture and text layer 4; Layer 5 is a glue-line 5.Its production method is: (1) is coated with earlier the continuous wax layer of last layer on the PET film, it is steps A, (2) on the wax layer, adopt printing machine, whenever keep at a certain distance away and stamp an acrylate resin layer that is added with carbonate earlier (amount of carbonate is decided according to the size of mute photosphere roughness, its content in resin bed can be 1%-60%, as follows), stamp an acrylate resin layer in remaining zone again, be step B, (3) print patterned layer with colored ink on acrylate resin layer, i.e. step C, (4) on patterned layer, print glue-line, i.e. step D at last.The product that obtains of transfer film transfer printing presents mute face and bright alternate image thus.
Shown in Fig. 3,4, the top layer of this transfer film is a clear PET film 1; The second layer is a wax layer 2; The 3rd layer is protective layer 3, and this layer is divided into two regional 3a, 3b, and the 3a zone is greater than the 3b zone, and the 3a smooth surface is big to the reflection of light degree, presents bright, and the 3b surface ratio is more coarse, and luminous energy is produced diffuse reflection, presents mute face; The 4th layer is printing ink picture and text layer 4, and certain part of pattern is corresponding to the 3b zone of protective layer in this picture and text layer; Layer 5 is a vacuum aluminium coated layer 6; Layer 6 is the acidproof transparent ink layer 7 that the part that aluminium lamination need keep is protected; Layer 7 is a glue-line 5.Its production method is: (1) is coated with earlier the continuous wax layer of last layer, i.e. steps A on the PET film; (2) adopt printing machine, stamp an acrylate resin layer that is added with aerosil, stamp an acrylate resin layer in remaining zone again, i.e. step B according to shape selected some zone on the wax layer of designing requirement and pattern; (3) print patterned layer with colored ink on protective layer, this patterned layer part is corresponding to the 3b zone on the protective layer, i.e. step C; (4) vacuum aluminum-coated on patterned layer, i.e. step e; (5) zone that needs to show metallic luster on aluminium coated stamps acidproof transparent ink layer 7, i.e. step F; (6) transfer film that will stamp transparent ink is the aluminium lamination that 10-60 ℃ weak acid solution flush away need not be protected, i.e. step G by temperature; (7) at printing ink picture and text layer 4 that transparent ink layer 7, no aluminium lamination cover and do not have on the protective layer 3 that stamps pattern and stamp glue-line, i.e. step D.The product that obtains of transfer film transfer printing thus, certain part of pattern present mute face, part has bright of metallic luster in addition.
Shown in Fig. 5,6, the top layer of this transfer film is a clear PET film 1; The second layer is a wax layer 2; The 3rd layer is protective layer 3, and this layer is divided into two regional 3a, 3b, and the 3a zone is greater than the 3b zone, and the 3a smooth surface is big to the reflection of light degree, presents bright, and the 3b surface ratio is more coarse, and luminous energy is produced diffuse reflection, presents mute face; The 4th layer is printed substrate 8, through mold pressing, has the 3D vision effect; Layer 5 is a printing ink picture and text layer 4, and certain part of pattern is corresponding to the 3b zone of top protective layer in this picture and text layer; Layer 6 is an aluminium coated 6; Layer 7 is alkaline-resisting transparent ink layer 7; The 8th layer is glue-line 5.Its production method is: (1) is coated with earlier the continuous wax layer 2 of last layer, i.e. steps A on the PET film; (2) on glue-line, adopt printing machine, stamp an acrylate resin layer 3b who is added with alundum (Al, stamp an acrylate resin layer 3a, i.e. step B again in remaining zone according to the shape of designing requirement and pattern selected some zone on the wax layer; (3) on 3a, 3b layer, stamp an acrylate resin layer 8 as printed substrate, i.e. step H; (4) printed substrate is carried out mold pressing, make it have the 3D vision effect, i.e. step I; (5) print patterned layer 4 with colored ink on printed substrate, this patterned layer part is corresponding to the 3b zone on the protective layer, i.e. step C; (6) vacuum plates aluminium lamination 6, i.e. step e on patterned layer; (6) zone that needs to show metallic luster on aluminium coated stamps alkaline-resisting transparent ink 7, i.e. step F; (7) transfer film that will stamp transparent ink is the aluminium lamination that 10-60 ℃ weak caustic solution flush away need not be protected, i.e. step G by temperature; (8) at transparent ink layer 7 and do not have on the printed substrate 8 stamp pattern and stamp glue-line 5, i.e. step D.The product that obtains of transfer film transfer printing thus, certain part of pattern present mute face, other parts and have bright of radium-shine metal effect.
Shown in Fig. 7,8, the top layer of this transfer film is a clear PET film 1; The second layer is a wax layer 2; The 3rd layer is protective layer 3, and this layer is divided into two regional 3a, 3b, and the 3a zone is greater than the 3b zone, and the 3a smooth surface is big to the reflection of light degree, presents bright, and the 3b surface ratio is more coarse, and luminous energy is produced diffuse reflection, presents mute face; The 4th layer is printed substrate 8; Layer 5 is a vacuum aluminium coated layer 6, and this layer is corresponding to the 3a zone of protective layer; Layer 6 is alkaline-resisting transparent ink layer 7; Layer 7 is a printing ink picture and text layer 4, and this picture and text layer is corresponding to the 3b zone of top protective layer; The 8th layer is glue-line 5.Its production method is: (1) is coated with earlier the continuous wax layer 2 of last layer, i.e. steps A on the PET film; (2) on glue-line, adopt printing machine, stamp an acrylate resin layer 3b who is added with poly-fluorine wax, stamp an acrylate resin layer 3a, i.e. step B again in remaining zone according to the shape of designing requirement and pattern selected some zone on the wax layer; (3) on 3a, 3b layer, stamp an acrylate resin layer 8 as printed substrate, i.e. step H; (4) vacuum plates aluminium lamination 6, i.e. step e on printed substrate; (5) the 3a zone corresponding to protective layer stamps alkaline-resisting transparent ink layer 7, i.e. step F on aluminium coated; (6) transfer film that will stamp protection printing ink is the aluminium lamination that 10-60 ℃ weak caustic solution flush away need not be protected, i.e. step G by temperature; (7) stamp picture and text layer 4 in the zone that does not have aluminium lamination with the colored ink cover, i.e. step C; (8) rubberised layer 5, i.e. step D on picture and text layer 4, transparent ink layer 7.The figuratum part of product that obtains of transfer film transfer printing presents mute face thus, patternless part presents bright of metal, strengthens metal effect.
Shown in Fig. 9,10, the top layer of this transfer film is a clear PET film 1; The second layer is a wax layer 2; The 3rd layer is protective layer 3, and this layer is divided into two regional 3a, 3b, and the 3b zone is greater than the 3a zone, and the 3a smooth surface is big to the reflection of light degree, presents bright, and the 3b surface ratio is more coarse, and luminous energy is produced diffuse reflection, presents mute face; The 4th layer is printed substrate 8; Layer 5 is a printing ink picture and text layer 4, and this picture and text layer is corresponding to the 3a zone of protective layer; Layer 6 is a glue-line 5.Its production method is: (1) is coated with earlier the continuous wax layer 2 of last layer, i.e. steps A on the PET film; (2) adopt printing machine, stamp an acrylate resin layer 3b who is added with Tissuemat E, stamp an acrylate resin layer 3a, i.e. step B again in remaining zone according to shape selected some zone on the wax layer of designing requirement and pattern; (3) on 3a, 3b layer, stamp an acrylate resin layer 8 as printed substrate, i.e. step H; (4) the 3a zone corresponding to protective layer adopts colored ink to stamp picture and text layer 4 on printed substrate, i.e. step H; (5) at picture and text layer 4 and do not have to stamp glue-line on the printed substrate of impression literary composition, i.e. step D.The figuratum part of product that obtains of transfer film transfer printing presents bright, patternless part and presents mute face thus, makes pattern more dazzling.
When above-mentioned 3a zone requires to show slightly the mute light time after transfer printing, above-mentioned carrier film can be mute light film.
Above-mentioned mute photosphere also can be formed by UV printing ink, also can replace carbonate, Tissuemat E etc. by colored powders such as pearl essence, phosphor powder, titanium dioxides.
More than be specifying of production method of transfer printing film of the present invention and the several embodiment of structure, but this embodiment is not in order to restriction protection scope of the present invention, all equivalences that does not break away from technical solution of the present invention are implemented or change, all should be included in the scope of the present invention.

Claims (20)

1, a kind of production method with mute face and bright transfer film in turn includes the following steps:
(1) adopts coating machine or printing machine, on carrier film, evenly coat or stamp a release layer;
(2) adopt printing machine, at least one zone stamps a dulling material layer on release layer earlier; Stamp a glossy material layer again in the zone that does not stamp the dulling material layer;
(3),, stamp a picture and text layer at least in the corresponding region of above-mentioned protective layer according to designing requirement;
(4) on the picture and text layer and stamp the following layer of cementation together on the decorative layer that is not covered by the picture and text layer.
2, production method according to claim 1 is characterized in that: the dulling material in the step (2) is to add the graininess industrial chemicals that can evenly mix with it in solvent type resin or water-base resin liquid; Glossy material is solvent type resin or water-base resin, and water-base resin is water insoluble after solidifying drying.
3, production method according to claim 2, it is characterized in that: described graininess industrial chemicals can be aerosil, Tissuemat E, poly-fluorine wax, alundum (Al, carbonate, mica powder, stearate, kaolin etc., also can be pearl essence, phosphor powder, titanium dioxide etc.; Solvent type resin or water-base resin can be acrylic acid, vinyl, acrylic, polyester resin.
4, production method according to claim 1 and 2 is characterized in that: before stamping the picture and text layer, stamp the layer of transparent printed substrate earlier, this printed substrate also can generate when stamping the glossy material layer together.
5, production method according to claim 1 and 2 is characterized in that: earlier plated an aluminium lamination being printed on the picture and text layer side vacuum before stamping following layer.
6, production method according to claim 5 is characterized in that: before stamping the picture and text layer, earlier on aluminium coated, according to designing requirement, the zone that presents metal effect at needs stamps acidproof or alkaline-resisting transparent ink, by weak acid or weak base pond, unwanted aluminium lamination is washed off again.
7, production method according to claim 1 and 2 is characterized in that: in the described step (3), adopt solvent type ink to form pattern when the printing figure message layer earlier, be imprinted on patternless zone with the water color ink that can wash again.
8, production method according to claim 7 is characterized in that: earlier vacuum plates an aluminium lamination on the picture and text layer side being printed on before stamping following layer, then in special-purpose tank by mechanism with the aluminium lamination flush away on the water color ink.
9, production method according to claim 1 and 2, it is characterized in that: before stamping described picture and text layer, carry out vacuum aluminum-coated earlier, again according to designing requirement, the zone that presents metal effect at needs stamps acidproof or alkaline-resisting transparent ink, by weak acid or weak base pond, unwanted aluminium lamination is washed off again.
10, production method according to claim 5 is characterized in that: after described protective layer, printed substrate or aluminium coated form, any one deck in protective layer, printed substrate or the aluminium lamination is carried out mold pressing handle, make it have the three dimensions visual effect.
11, the transfer film that makes of the described production method of a kind of claim 1, this transfer film comprise that a carrier film, a release layer, one can break away from and transfer to the decorative layer and the following layer of cementation together on the stock by heat and/or pressure from carrier film; It is characterized in that: described decorative layer comprises protective layer and picture and text layer, and protective layer has at least a zone to present mute light, has at least a zone to present light.
12, transfer film according to claim 11 is characterized in that: also have a transparent printed substrate between described protective layer and the picture and text layer.
13, according to claim 11 or 12 described transfer films, it is characterized in that: the zone that presents mute light in the described protective layer and the zone that presents light are alternately.
14, according to claim 11 or 12 described transfer films, it is characterized in that: a certain picture and text is big or small corresponding in the zone that presents mute light in the described protective layer and the picture and text layer.
15, according to claim 11 or 12 described transfer films, it is characterized in that: a certain picture and text is big or small corresponding in the zone that presents light in the described protective layer and the picture and text layer.
16, according to claim 11 or 12 described transfer films, it is characterized in that: also have a vacuum aluminium coated layer and acidproof or alkaline-resisting transparent ink layer between described protective layer and the picture and text layer.
17, according to claim 11 or 12 described transfer films, it is characterized in that: between described picture and text layer and the following layer aluminium coated is arranged.
18, transfer film according to claim 17 is characterized in that: also have an acidproof or alkaline-resisting transparent ink layer between described aluminium coated and the following layer.
19, according to claim 11 or 12 described transfer films, it is characterized in that: described carrier film is mute light film.
20, transfer film according to claim 18 is characterized in that: any one deck in described protective layer, printed substrate or the aluminium lamination has mould-pressed pictures and texts.
CN 200310112414 2003-11-28 2003-11-28 Process for producing transfer printing films having a dull surface and a bright surface, and product made thereby Expired - Lifetime CN1286665C (en)

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CN 200310112414 CN1286665C (en) 2003-11-28 2003-11-28 Process for producing transfer printing films having a dull surface and a bright surface, and product made thereby

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CN1286665C true CN1286665C (en) 2006-11-29

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CN102690553B (en) * 2012-06-05 2014-04-16 江苏劲嘉新型包装材料有限公司 Method for printing double smooth surfaces at one time and matting agent for printing ink
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CN107828293A (en) * 2017-10-26 2018-03-23 广东天元汇邦新材料股份有限公司 Super mute wear-resisting mould release, super mute wear-resisting transfer film and its preparation method and application
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