CN1285904A - High resistance polypropylene tube - Google Patents
High resistance polypropylene tube Download PDFInfo
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- CN1285904A CN1285904A CN98812827A CN98812827A CN1285904A CN 1285904 A CN1285904 A CN 1285904A CN 98812827 A CN98812827 A CN 98812827A CN 98812827 A CN98812827 A CN 98812827A CN 1285904 A CN1285904 A CN 1285904A
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- Prior art keywords
- pipe
- polypropylene
- tube
- preferred
- propylene
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/12—Rigid pipes of plastics with or without reinforcement
- F16L9/127—Rigid pipes of plastics with or without reinforcement the walls consisting of a single layer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention relates to a high resistance polypropylene tube especially with a high modulus of elasticity in extension, high impact strength, annular rigidity and resistance towards knocks. The inventive tube is made of polypropylene and has a modulus of elasticity in extension of 1300-2300 N/mm2 and an impact strength of 60-110 kJ/m2. The inventive tube is produced by extrusion of a plastic moulding material consisting of two constituents A and B of composition A) 80-98 mass parts of an isotactic polypropylene homopolymer as a coherent matrix constituent with a decade regularity of >95% and B) 2-20 mass parts of a copolymer, consisting of 50-70 mass parts of propylene and 30-50 mass parts of ethylene and/or other C4-C8-alpha-olefins as a dispersedly distributed elastomer component. The intrinsic viscosity ratio of both components B/A is 0.9-1.5 and the melt flow index of the moulding material is 0.15-0.8 g/10 min. The polypropylene tubes are suitable for use in waste water systems, especially as gully pipes, rainwater pipes, domestic drainpipes, or sound insulation pipes or shaft elements.
Description
The present invention relates to a kind of high strength that has, particularly have high tensile modulus of elasticity, high notched Izod impact strength, epipodium has just tried and the polypropylene tube of the high resistivity of impact load.
At first clearer and more definite, this pipe is used for the waste pipe system, particularly as drainage pipeline.
For a long time, people just know and use stone implement, concrete and cast iron to make the waste water sewer.Shortcoming is that these unbending materials rupture easily, makes the pipeline made by them often owing to displacement for example bigly, the external influence that buries deviation and other load are torn, and the infiltration of overflowing can cause surrounding soil and underground water ecological failure.
Comparatively speaking, particularly advantageous being to use by thermoplastic by the method for knowing by extruding the sewer of the different size of producing.Preferably polyethylene and polypropylene, thermoplasticity weldability that they are in light weight because of it, good and high fracture toughness, corrosion resistance and wear resistance are better than other tubing.It can ensure the high functional safety of waste water-sewer pipeline system for a long time.Other reason that this material use to increase in the pipeline field be it environment friendly, lowly lay expense and apodeictic recirculation.
In more standard and tentative standard, all comprised the regulation that is equivalent to the prior art situation: the size of plastic lined piping, material property, test method and application facet in the discharge of wastewater facility, for example EN1852, PrEN1401, CEN/TC155 WI009Dok, 155/13N322, DIN19537, DIN16961, DINV19534-1 and draft DIN19566.
Install to finish under effectively discharge of wastewater facility and the outdoor low temperature and lay the row that all still will be placed on new material at first consideration with disinfection with higher use value.Significant requirement at present all be particularly related to have the intensity that is fit to use, low-temperature flexibility and until the stable plastic tube of major diameter of 90 ℃ serviceability temperature.
Existing method improves the intensity of polypropylene tube by composite structure.According to DE9416759U1 and DE29612040U1, effective solid fiber material or enhancing braided fabric are twined, then with plastics or outer tube sheathing.Described a kind of extrusion method of producing multi-layered composite pipe among the EP0762032, its inside and outside wall is formed with filler modified different polymer material with tackifier before processing.
The pipe that this method does not strengthen composite pipe relatively has the higher compression resistance and the ability of temperature.But shortcoming is embodied in more process step, and the weight that high operating cost on the different use materials and composite structure cause increases.
According to EP0385465, the outer wall of waste water sewer is that wavy texture can improve ring stiffness.Go out to return the production method of having described the composite structure of forming by pipe and wavy outer tube in smooth thus.
Dual pipe with external profile has obtained ring stiffness effectively, but comparatively speaking the cost of production height is arranged also, shortcomings such as the big and pipe complex technique complexity of dual pipe weight.
Also introduce other in the patent documentation and improved the method for polyacrylic rigidity and toughness.Particularly (WO96/37549, DE4019456), (WO96/11216 DE4330661), produces reaction mixture (DE4001157) and adds nucleator methods such as (DE4407327) and realize for the widening of molecular weight distribution by mixing with elastomer.Though this is the part solution just, do not obtain relation corresponding to the rigidity-toughness of effective tubing of present requirement.
The purpose that the present invention is based on is, noticing under the prerequisite that the usage requirement of tubing is increased, produce and have very high tensile modulus of elasticity, rigidity and toughness simultaneously, and because its rheological properties and the material input polypropylene moulding material of extruding pipe material advantageously.
Though the process that rigidity and toughness are opposite has limited the performance improvement of heterophasic polypropylene mixture, in two-stage polymerization process, form moulding material but still can use the ZIEGLER-NATTA catalyzer by propylene and ethene, by extruding and moulding tubing, its mechanical strength has had the improvement of essence with respect to known and comparable plastic tube thus.
Theme of the present invention is a high resistance polypropylene tube, and polypropylene sewer particularly is characterized by:
Tensile modulus of elasticity is 1300～2300N/mm
2, preferred 1500～2000N/mm
2With
Notched Izod impact strength is 60～110KJ/m
2, preferred 70～100KJ/m
2, by the production of extruding of Themoplastic molding materials, this moulding material comprises two kinds of components, component A and B:
A) 80～98 mass fractions, the isotactic polypropylene homopolymer of preferred 87～97 mass fractions are as the bonding matrix component, and ten regularities are greater than 95% He
B) 2～20 mass fractions, the copolymer of preferred 3～13 mass fractions, by the propylene of 50～70 mass fractions and the ethene of 30～50 mass fractions, and/or other C
4～C
8Alpha-olefin generate, as the elastomeric component of dispersed distribution.Wherein, the ratio B/A of the intrinsic viscosity of two kinds of components is 0.9～1.5, and the melt index of this moulding material is 0.15～0.8g/min, preferred 0.2～0.5g/10min.
The combination of materials B of copolymer preferably is made up of 55～65 mass parts polypropylene and 35～45 mass parts ethene.
High tensile modulus of elasticity and high notched Izod impact strength have also caused the raising to the very important ring stiffness of tubing.
Therefore the present invention is a feature with a kind of polypropylene tube also, has the ring stiffness SN[kN/m of the solid wall pipe on smooth inside and outside surface
2], external diameter is 20mm～2000mm though do not rely on the moulding of each pipe end, the mathematical relationship below having satisfied:
190kN/m
2(10/ (SDR-1))
3〉=SN 〉=110kN/m
2(10/ (SDR-1))
3, preferred value 162 and 137kN/m
2(replacement 190 and 110kN/m
2), wherein SDR represents the ratio of external diameter and wall thickness.
The pipe that has external diameter of pipe and be 110mm and thickness of pipe wall and be the 3.7mm size means, is about 6.5～7.0kN/m corresponding to the ring stiffness value that IS09969 surveyed under 23 ℃ of temperature
2
The polypropylene tube that has external diameter and be the tube wall arbitrary configuration of 40～4000mm should meet following mathematical relationship.
2.3 * 10
6KN/m
2W 〉=SN 〉=1.3 * 10
6KN/m
2W preferred value 1.95 and 1.65 * 10
6KN/m2 (replaces 2.3 and 1.3 * 10
3KN/m
2) wherein, the ratio of the plane moment of inertia of the tube wall that the W representative is relevant with length and the cube of center of gravity diameter.
This paper has been particularly related to the pipe with interlayer tube wall, pipe with empty wall construction tube wall of the cavity that extends the strip length aspect, pipe with empty wall construction of thread-shaped cavity, has slippery inner surface, closely knit or empty, the pipe of spirality or annular corrugated outer surface, irrelevant with the moulding of pipe end separately.
Intensity makes this pipe can not rupture when measuring resistivity to outside impact load under following standard conditions well.
For estimating the fracture behaviour of plastic tube, " to the resistivity of outside impact load " in the test method in the following two kinds of technologies of standardization of application condition.
According to the circumference method of EN744, one section pipe is subjected to drop-weight impact, falls and heavily falls the position that distributes at circumference from level altitude.Can calculate impact toughness-fracture rate when the pipe fracture occurring, measure and carry out under 0 ℃, the quality of its decline weight and drop height depend on the external diameter of developmental tube, and are stipulated as standard conditions or test parameters in standard.For example following test parameters is suitable for the pipe that external diameter is 110mm: the drop height 1600mm that the quality 1.0kg-of the 0 ℃-weight that falls of-temperature falls to weighing
For plastic tube, lay in the temperature below-10 ℃, must test according to the progressively method of EN1411 in addition.By this, test section is subjected to the drop impact of fixed mass and shape at every turn, and wherein all impacts constitute a sequence by different drop heights.When reaching the pipe fracture, drop height calculates as the H50 value, promptly gives up 50% of all of developmental tube.Stipulated to fall heavy test parameters in the standard: temperature, quality and drop height, relevant with the pipe outer diameter.
For external diameter is that the canonical measure condition that is fit to of the pipe of 110mm is as follows: the 0 ℃-heavy quality 4kg-that the falls of-temperature heavy drop height 〉=1m that falls
In addition, in order to improve processing and operation technique performance, also add general additive in the Themoplastic molding materials of production polypropylene tube, heat stabilizer for example, antioxidant and/or preventing light agent, anti-static agent, lubricant oil and releasing agent, pigment/dye, metal inactivator, nucleator is filled and reinforcing material, fire retardant, the consumption of these additional materials are their general concentration.
One or more nucleators that preferably contain 0.01～2.0wt% in the polymer pipe.
The production technology of pipe is to use the upright narrow spectrum ZIEGLER-NATTA catalyzer of structure, and under the condition of the hydrogen of adding prescribed dose, before connect prepolymerization, in two-stage polymerization process: A) polymerization and the B of propylene under the temperature by 50～90 ℃ and the 20～50bar pressure) polypropylene and new propylene and ethene and/or other C that adds by these homopolymerizations
4～C
8The mixture of alpha-olefin be 40～100 ℃ in temperature, pressure is the polymerization under the condition of 5～30bar, be used for the Themoplastic molding materials of tubulation by propylene and ethylene production, this moulding material is the pipe with different-diameter of difformity tube wall by extruding and moulding.
Be aggregated in the polymerization reaction kettle of two serial connections and finish in two steps.Prepolymerization is carried out in first reactor front, and prepolymer for example changes in the ring canal reaction still, carries out polymerization then under the excessive situation of propylene liguid.The polypropylene homopolymer that first step technology is formed separates, and introduces in second reactor, here adds behind propylene and the ethene by generating corresponding copolymer formation dispersed distribution after the vapor-phase polymerization mutually.
For regulating molecular weight, in reaction system, add hydrogen.Conditions of manufacture below using in the polymerization process: polymerization procedure 1: 50～90 ℃ of temperature, preferred 60～80 ℃
Pressure 20～50bar, preferred 25～40bar polymerization procedure 2: 40～100 ℃ of temperature, preferred 60～90 ℃
Pressure 5～30bar, preferred 10～20bar
For producing moulding material of the present invention, use the upright single-minded ZIEGLER-NATTA catalyzer of structure, it is made up of multiple component, except that the solid matter component of titaniferous, also contains al-alkyl compound and external electron donor compound usually.
The aluminium oxide that becomes more meticulous, silica or magnesium chloride have high-specific surface area, can serve as the titanium halide that applies, the carrier of preferred titanium tetrachloride, and serve as electron donor, for example ether, ketone, lactone, alcohol, monobasic or polybasic carboxylic acid and their ester, the carrier of preferred phthalandione derivative.The solids fraction of titaniferous is commercial general, can be by method production known in the document (for example: DE4330661/EP0573862/WO96/11216/GALLI, Macromol, Symp.112,1-16 (1996))
Specially suitable as co-catalyst is trialkyl aluminium compound, for example triethyl aluminum.In addition, also contain external electron donor, the particularly silane of Qu Daiing in the catalyst system, preferred cyclohexyl methyl dimethoxy silane or dicyclopentyl dimethoxyl silane.
Plastic tube is pressed known method by extruding and moulding production by Themoplastic molding materials.For this reason, the polyacrylic polymer that said method obtains melts in about 200～260 ℃ extruder, and homogenizing by the annular nozzle ejection, forms stable size by cooling then.
Traditional single screw extrusion machine that the smooth feeding zone that is equipped with tubing to be processed is normally used in the production of pipe carries out in a continuous manner.For improving the produce flow, the rear end of feeding zone can be changed into the cannelure of axial interpolation.The extruder of this structure is equipped with three district's screw rods of long 20～30D (D represents diameter), and its screw rod profile relevant with task can realize plasticizing, homogenizing and the transmission to polymer melt the best.
Outlet of extruder is equipped with the tube head mould, and here melt-flow is introduced in the ring nozzle by means of conical plug or spirality distributor.Flowing of orifice plate that embeds and web core rod supporter recoverable melt is so that the pressure texture of total nozzle section is even.After melt is discharged from pipe through a more accurate equipment, be expressed to the inwall of calibration chamber by vacuum and/or forced air at this, here, melt is by quick cooling curing, and stable formation is given size, in 5～30 ℃ sufficiently long water-bath, further be cured as pipeline then, so that after this can be sawn into specific pipe range.
Industrial pipe production facility comprises and has the tube head mould, more accurate equipment, water-bath, pipe outlet, the unit extruder of the pipe saw and the groove that inclines.
Pipe of the present invention has higher tensile modulus of elasticity, notched Izod impact strength and ring stiffness.Based on distinctive rigidity of this pipe and toughness, with respect to the comparable Guan Eryan that is made by the polymer material that uses so far, used material has reduced, and therefore economic benefit is had positive effect.And small wall thickness may realize higher cooling and extruded velocity when making moulding, and it is more effective that expressing technique becomes.
Polypropylene tube is suitable for waste water system, and particularly as sewer, rainwater pipe, household drain pipe, member is advanced in sound insulation pipe or spy.
Embodiment 1～5A) embodiment's 1～3 step is described:
Finish continuously in two polymerization procedures by propylene and ethylene production moulding material of the present invention.
For this reason, use the polymerization reaction kettle of two serial connections, be equipped with general measuring equipment and possible each other product transmission.In the polymerization process, it is constant that the temperature of the regulation of two polymerization procedures, pressure and monomer ratio all will keep.The hydrogen that dosage adds is as molecular weight regulator.Forming of the reaction gas that gas-chromatography test monitoring is made up of propylene, ethene and hydrogen, guarantee the concentration ratio of prescription requirement by continuous supply.
As the ZIEGLER-NATTA catalyzer of the commercial load that buys of catalytic component use, it is applicable in monomer suspension and gas phase and is made for polypropylene.
Prepolymerization is carried out in first reactor front, it is at one independently in the prepolymerization reaction still, carried out in 15～20 ℃ the liquid propylene 2-3 minute, fixing in advance catalytic component, triethyl aluminum (TEAL) cocatalyst and external electron donor cyclohexyl methyl dimethoxy silane (CMDMS) or dicyclopentyl dimethoxyl silane (DPDMS) are added in independent then or mixing.
Formed prepolymer is in transferring to the ring canal reaction still, and here, initiated polymerization forms polypropylene homopolymer in excessive propylene liguid.Oceangoing ship material in the reactor takes out continuously and puts into intermediate receptacle, and at this, polypropylene and unreacted propylene are separated from each other by the volatilization of monomer.Then the polymer homopolymer is transferred in second reactor, wherein introduce the propylene and ethylene mixture after, form the phase of corresponding copolymer by vapor-phase polymerization as dispersed distribution.
Single screw extrusion machine (the L/D=30 of the polyacrylic polymer of Sheng Chaning under 220 ℃ as stated above, D=70mm) plasticizing in, annular nozzle (external diameter is 110mm) extruding ejection by cored bar, being shaped to external diameter by vacuum correction then is 110mm, wall thickness is the pipe of 3.7mm, then, pull out pipe and sawing by the further cooling in water-bath of known method.
The important conditions of manufacture of machine system:
Extruder temperature
Feeding zone 1～3 200/210/220 ℃
220 ℃ of discharge zones
200 ℃ of ring nozzles
-screw rod revolution 40/min
20 ℃ of the long 4m/ temperature of-water-bath
-vacuum/more accurate 200Torr
-extruded velocity 0.3m/minB) special conditions of manufacture of the embodiment 1～3:
Select the synthesis condition of use from table 1, the product performance of monomer ratio and polymer analysis are pressed polymerization procedure and embodiment ordering.C) result of embodiment 1～3 and comparing embodiment 4 and 5
Table 2 has been listed the distinctive of embodiment 1～3, support solution of the present invention material parameter and with corresponding to the Daplen PP BEC5012 of the commercial general tubing of conduct of actual techniques situation and the comparison value of Daplen HDPE CE4664.
Can find out obviously that by contrast product that the present invention produces and the pipe of making thus have good operation technique performance.D) determine with following method by embodiment 1～5 the product and the performance of moulded parts:
230 ℃/specified load of-melt index MFR ISO1133/ temperature 2.16kg
-ethylene contents infrared spectrum measurement
135 ℃ of mensuration in the sticking lamp decahydronaphthalene of-characteristic
-ten regularity infrared spectrum measurements
23 ℃ of-tensile modulus of elasticity ISO 527/ temperature
23 ℃ of-notched Izod impact strength ISO179/1eA/ temperature
23 ℃ of-ring stiffness ISO 9969/ temperature
-to a) 0 ℃ of EN744/ circumference method/temperature of the resistivity that adds impact stress
B) EN1411/ a) VICAT-softening temperature VST/B/50/ISO306 of the method/temperature-20 ℃-shape stability of being heated progressively
B) production of 23 ℃-sample of shape stability temperature HDT/B/ISO075-density ISO1183/ temperature is being tested by the polypropylene powder that described polymerization technique obtains
Stablize granulation down for 240 ℃ in the double screw extruder.By
Sample is produced in 230 ℃～260 ℃ following injection mouldings.The ginseng of sample
Before measuring, regulates number by regulation separately. table 1 embodiment of parameter unit 1 embodiment 2 embodiment 31. reactor pressure bar 33 33 33 temperature ℃ 70 70 70 hydrogen ppm, 270 270 270 TEAL/ silane mol/mol, 22 22. reactor pressure bar, 12.0 12.5 12.0 temperature ℃ 65 65 65 C2/ (C
2+ C
3) mol% 0.45 0.45 0.44 H
2/ C
2(230 ℃/2.16kg) 1.50 1.24 1.16 ten regularity % of g/10min 0.20 0.18 0.17 ethylene contents mol%, 19.5 14.5 5.6 intrinsic viscosity B/A dl/g, the 98 98 98 test standard parameter embodiment of table 2 parameter unit, 1 embodiment, 2 embodiment, 3 embodiment, 4 embodiment 5 of mol% 0.035 0.033 0.038 moulding material MFR
With Daplen PP and Daplen HDPE
BBC5012nat CE4664?nat
Compare tensile modulus of elasticity N/mm
223 ℃ 1,524 1,696 1,972 1,200 920 notched Izod impact strength kJ/m of IS0527
223 ℃ of 104 102 80 52 14 ring stiffness 1 of ISO179/leA) kN/m
223 ℃ of 5.8 6.2 6.8 4.0 3.5 couples of outside-EN744 of ISO9969 and 0 ℃/1.6kg do not rupture, and not rupturing ruptures ruptures-
The resistivity EN1411 of/2000mm impact load-20 ℃/4kg does not rupture, and not rupturing ruptures ruptures-
/ 1000mm shape stability ℃ the ISO75 that is heated
2)81 85 98 78 72
ISO306
3)70 75 87 70 65 serviceability temperatures ℃--20～+ 90-20～+ 90-20～+ 90-20～+ 90-20～+ 60 density kg/m
323 ℃ of 905 905 905 905 945 pipe of ISO1183 weighs 4) kg/m-_ _ 1.15 1.13 1.10 1.29 1.42
1)External diameter of pipe: 110mm, thickness of pipe wall: 3.7mm
2)HDT/B
3)Vicat/B
4)Identical external diameter of pipe 110mm and identical ring stiffness
Claims (7)
1. high resistance polypropylene tube, particularly polypropylene sewer is characterized by:
Tensile modulus of elasticity is 1300～2300N/mm
2, preferred 1500～2000N/mm
2And notched Izod impact strength is 60～115KJ/m
2, preferred 70～100KJ/m
2, extrude production by Themoplastic molding materials, this material is made up of A and B two components:
A) 80～98 mass fractions, the isotactic polypropylene homopolymer of preferred 87～97 mass fractions are as the bonding matrix component, and ten regularities are greater than 95% He
B) 2-20 mass fraction, the copolymer of preferred 3-13 mass fraction, by the propylene of 50～70 mass fractions, the ethene of 30-50 mass fraction and/or other C
4～C
8Alpha-olefin generate, as the elastomeric component of dispersed distribution,
Wherein the intrinsic viscosity ratio B/A of two kinds of components is 0.9～1.5, and the melt index of moulding material is 0.15～0.8g/min, preferred 0.2～0.5g/10min.
2. the polypropylene tube of claim 1 is characterized by, and has slippery inner surface and outer surface, and external diameter is the ring stiffness SN[kN/m of the solid wall pipe of 20～2000mm
2] satisfy relationship: 190kN/m
2(10/ (SDR-1))
3〉=SN 〉=110kN/m
2(10/ (SDR-1))
3, preferred value is 162 and 137kN/m
2
(replacement 190 and 110kN/m
2)
Here SDR represents the ratio of external diameter and wall thickness.
3. the polypropylene tube of claim 1 is characterized by, and external diameter is the ring stiffness SN[kN/m of the pipe of 40～4000mm
2] satisfy mathematical relationship
2.3×10
6kN/m
2·W≥SN≥1.3×10
6kN/m
2·W
Preferred value 1.95 and 1.65 * 10
6KN/m
2
(replace 2.3 and 1.3 * 10
6KN/m
2)
Here W represents the ratio of the cube of the plane moment of inertia of the tube wall relevant with length and center of gravity diameter.
4. one or multinomial polypropylene tube in the claim 1～3 is characterized by, and the result is " not rupturing " when measuring the resistivity to outside impact load under standard conditions.
5. one or multinomial polypropylene tube in the claim 1～4 is characterized by, and contain the nucleator of 0.01～2.0wt% in the Themoplastic molding materials.
6. the production and the processing technology of each or multinomial tubing in the claim 1～5, it is characterized by, the used Themoplastic molding materials of tubulation be by propylene and ethene in two-stage polymerization process, use the upright narrow spectrum ZIEGLER-NATTA catalyzer of structure, dosage adds hydrogen, and before connect under the prepolymerized condition
A) by 50～90 ℃ of temperature, under 30～50bar pressure polypropylene and
B) by this polypropylene homopolymer and new propylene and ethene and/or other C that adds
4～C
8The mixture of alpha-olefin polymerization is produced under the pressure of 40～100 ℃ temperature and 5～30bar, it is by extruding the pipe that is processed into the different-diameter with difformity tube wall.
7. the purposes of or multinomial polypropylene tube in the claim 1～5 is used for the waste pipe system, as sewer, rainwater pipe, household drain pipe, and sound insulation pipe or as the prospect pit member.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19758124.2 | 1997-12-30 | ||
| DE19758124A DE19758124C1 (en) | 1997-12-30 | 1997-12-30 | Polypropylene tube with high strength |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1285904A true CN1285904A (en) | 2001-02-28 |
| CN1133840C CN1133840C (en) | 2004-01-07 |
Family
ID=7853533
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB988128276A Expired - Fee Related CN1133840C (en) | 1997-12-30 | 1998-12-29 | High resistance polypropylene tube |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6433087B1 (en) |
| EP (1) | EP1042629B1 (en) |
| CN (1) | CN1133840C (en) |
| AU (1) | AU2417499A (en) |
| DE (2) | DE19758124C1 (en) |
| ES (1) | ES2185251T3 (en) |
| PT (1) | PT1042629E (en) |
| WO (1) | WO1999035430A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100443536C (en) * | 2003-08-05 | 2008-12-17 | 巴塞尔聚烯烃意大利有限责任公司 | Polyolefin articles |
| CN102200211A (en) * | 2010-12-30 | 2011-09-28 | 东莞市宏德电子设备有限公司 | Quick joint of connecting spray nozzle |
| CN102644806A (en) * | 2012-02-07 | 2012-08-22 | 常熟市谷雷特机械产品设计有限公司 | Building composite pipeline |
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|---|---|---|---|---|
| SE518553C2 (en) † | 1999-06-09 | 2002-10-22 | Borealis As | Profile for windows and doors of propylene block copolymer with nucleating agents and fillers |
| DE60138726D1 (en) * | 2000-11-10 | 2009-06-25 | Ineos Mfg Belgium Nv | PIPES FROM A PROPYLENE POLYMER COMPOSITION |
| EP1260545A1 (en) | 2001-05-21 | 2002-11-27 | Borealis Technology OY | Industrial polyolefin piping system |
| EP1260546A1 (en) * | 2001-05-21 | 2002-11-27 | Borealis Technology OY | Polyolefin multilayer pipe |
| EP1260528A1 (en) | 2001-05-21 | 2002-11-27 | Borealis Technology OY | Propylene polymer pipes for pipelines |
| EP1260529A1 (en) | 2001-05-21 | 2002-11-27 | Borealis Technology OY | Propylene polymers with improved properties |
| BE1014226A3 (en) * | 2001-06-15 | 2003-06-03 | Polypropylene Belgium Nv | Manufacturing method of pipes and connections with a stage stress. |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| CA2499951C (en) | 2002-10-15 | 2013-05-28 | Peijun Jiang | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
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| ATE435243T1 (en) | 2005-05-20 | 2009-07-15 | Borealis Tech Oy | HIGH MELTING FLOW POLYMER WITH IMPROVED RESISTANCE FOR TUBE APPLICATIONS |
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| WO2010037747A1 (en) * | 2008-10-01 | 2010-04-08 | Borealis Ag | New sewage pipe material with improved properties |
| US8217116B2 (en) * | 2009-07-15 | 2012-07-10 | Braskem America, Inc. | Polypropylene composition for buried structures |
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| US9683096B2 (en) * | 2010-08-19 | 2017-06-20 | Braskem America, Inc. | Polypropylene resin suitable for soft nonwoven applications |
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| JPS5624289A (en) * | 1979-07-31 | 1981-03-07 | Furukawa Electric Co Ltd | Adiabatic pipe and its manufacture |
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| DE69120601T2 (en) | 1990-05-14 | 1997-01-02 | Shell Oil Co | Polymer compositions |
| US5194471A (en) * | 1991-02-15 | 1993-03-16 | The B. F. Goodrich Company | Rigid chlorinated polyvinyl chloride compound and articles derived therefrom |
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-
1997
- 1997-12-30 DE DE19758124A patent/DE19758124C1/en not_active Revoked
-
1998
- 1998-12-29 AU AU24174/99A patent/AU2417499A/en not_active Abandoned
- 1998-12-29 DE DE59806300T patent/DE59806300D1/en not_active Revoked
- 1998-12-29 US US09/581,862 patent/US6433087B1/en not_active Expired - Fee Related
- 1998-12-29 CN CNB988128276A patent/CN1133840C/en not_active Expired - Fee Related
- 1998-12-29 EP EP98966683A patent/EP1042629B1/en not_active Revoked
- 1998-12-29 ES ES98966683T patent/ES2185251T3/en not_active Expired - Lifetime
- 1998-12-29 WO PCT/EP1998/008487 patent/WO1999035430A1/en not_active Application Discontinuation
- 1998-12-29 PT PT98966683T patent/PT1042629E/en unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100443536C (en) * | 2003-08-05 | 2008-12-17 | 巴塞尔聚烯烃意大利有限责任公司 | Polyolefin articles |
| CN102200211A (en) * | 2010-12-30 | 2011-09-28 | 东莞市宏德电子设备有限公司 | Quick joint of connecting spray nozzle |
| CN102644806A (en) * | 2012-02-07 | 2012-08-22 | 常熟市谷雷特机械产品设计有限公司 | Building composite pipeline |
| CN102644806B (en) * | 2012-02-07 | 2014-10-15 | 慈溪市输变电工程有限公司 | Building composite pipeline |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2185251T3 (en) | 2003-04-16 |
| DE59806300D1 (en) | 2002-12-19 |
| EP1042629A1 (en) | 2000-10-11 |
| WO1999035430A1 (en) | 1999-07-15 |
| EP1042629B1 (en) | 2002-11-13 |
| DE19758124C1 (en) | 1999-11-18 |
| AU2417499A (en) | 1999-07-26 |
| CN1133840C (en) | 2004-01-07 |
| PT1042629E (en) | 2003-03-31 |
| US6433087B1 (en) | 2002-08-13 |
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