CN1285520C - Integral phyical chemical treating method by bathing waste water reutilization - Google Patents

Integral phyical chemical treating method by bathing waste water reutilization Download PDF

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Publication number
CN1285520C
CN1285520C CN 200410013777 CN200410013777A CN1285520C CN 1285520 C CN1285520 C CN 1285520C CN 200410013777 CN200410013777 CN 200410013777 CN 200410013777 A CN200410013777 A CN 200410013777A CN 1285520 C CN1285520 C CN 1285520C
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water
waste water
bathing waste
bathing
treatment process
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CN 200410013777
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CN1583607A (en
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崔福义
任刚
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Harbin Institute of Technology
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Harbin Institute of Technology
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Abstract

The present invention relates to a physicochemical treatment method of bathing waste water, namely an integrated physicochemical treatment method for recycling bathing waste water. The present invention comprises the steps that polyferric chloride is added into the bathing waste water for coagulating deposition; after deposition, the bathing waste water is filtered by anthracite coal-quartz sand double-layer filtering material; after filtration, the bathing waste water is loaded into a container filled with granular activated carbon absorption columns and zeolite ion exchange columns so as to be treated in the modes of activated carbon absorption and ion exchange; after absorption, the bathing waste water is filtered by an ultra filtration membrane; the bathing waste water is sterilized by ultraviolet rays. The complete set of technology is composed of independent treatment units and has the advantages of organic combination, compactness, reasonability, convenient maintenance and management, high-speed sterilization, high efficiency, simple operation of equipment and low operation cost. Besides, the technique of the present invention has obvious superiority in the aspects of technology and economy and has a high practical value.

Description

The integrated physical chemistry treatment process that bath wastewater is multiplexing
Technical field:
The present invention relates to a kind of physical chemistry treatment process of bath wastewater, can effectively remove most pollutents in the bath wastewater by this method, and make it reach the multiplexing water quality standard of bathing.
Background technology:
Because the constant tension of water resources, the utilization ratio that how to improve existing water resources has become a big research topic of water treatment field.Bathing already is city water consumption rich and influential family, one medium scale bathing pool day water loss can reach hundreds of tons.With Harbin is example, and press 600,000 people's bathings every day in the whole city's 9,500,000 populations, and on average everyone bath water amount is with 0.2m 3Calculate the then daily bathing water yield 120,000 m 3, a year water consumption reaches 0.44 hundred million m 3Labour intensity height, the stream of peoples such as industrial enterprise such as factory, colliery and hotel account for more than 30% of domestic consumption especially than many places bath water amount, and this explanation bathing is already through becoming the important consumption place of municipal water supply.Domestic each big city is considered for water saving, has generally been improved the bath water water price.As Harbin City's 2003 new water prices with bathing industry water by 5 yuan existing/m 3Bring up to 10 yuan/m 3, high water price policy will guide bathing already to manage water saving, and improves the repeating utilization factor of water.According to investigations, a kind of safe and reliable multiplexing process technology is wished to have in the bathing place more than 90%.For general sanitary sewage, the bath wastewater pollution level is lighter.With its processing and carry out reuse on the spot and not only can open up " new water source " for bathing enterprise, alleviate bathing business economic pressure, can also reduce pollution to water surrounding.China is to be conceived to water reuse in the conduct to the research majority of bath wastewater recycling processing technique and equipment at present, direct multiplexing improvement lacks systematic research to bath wastewater, also less to every contamination index in the water quality characteristics of bath wastewater, particularly waste water to the influence research of each process procedure.
Summary of the invention:
For the waste water that makes bathing can be recycled again, the invention provides a kind of treatment process to bath wastewater.Technical scheme of the present invention is as follows: the integrated physical chemistry treatment process that a kind of bath wastewater is multiplexing, and it is finished by following step: (one) drops into poly-ferric chloride in waste water, carries out coagulating sedimentation; (2) water of post precipitation filters by hard coal-quartz sand double-layer filter material; (3) water after filtering enters in the container of splendid attire granular carbon adsorption column and zeolite ion exchange column and carries out charcoal absorption and ion-exchange; (4) water after handling enters ultra-filtration membrane and filters; (5) water is carried out disinfection by ultraviolet light.In precipitation process of coagulation, the ratio of adding is 18~22 milligrams of poly-ferric chlorides of every liter of waste water, and sedimentation time is 10~17 minutes; Particle diameter is that the hard coal (1) that 0.9~1.2 millimeter quartz sand (2) and particle diameter are 1.5~2 millimeters is formed hard coal-quartz sand double-layer filter material in step (two), and the water of post precipitation passes through filtrate with 10~15 meters/hour filtering velocity.Present method is divided into four major parts: pretreatment unit, absorbing unit, film unit and uv sterilisation unit.Wherein pretreatment unit (comprising coagulating sedimentation and hard coal-quartz sand sand filtration) is mainly removed suspended substance, dregs and partial organic substances, for later unit link reduces load, prevents to stop up; Absorbing unit (comprising charcoal absorption and zeolite exchange) is mainly removed dissolved organic matter, is smelt flavor and ammonia nitrogen, and film unit is further removed small amounts of contamination and bacterium, plays the water quality effect of checking on; Uv sterilisation mainly is the deactivation residual virus, improves the reliability of hygiology index.The outstanding feature of this technology: the one, from the cell processing angle, a whole set of technology is made up of processing unit independently at bath wastewater water quality, organically combines, and compact and reasonable is convenient to maintenance management; The 2nd, emphasized hygienic reliability, it is the bacteriology index, experimental result proves, adopt ultra-filtration technique can remove bacterium more than 99.5% and 100% intestinal bacteria, uviolizing is placed on the last of technology, further kill remaining bacterium and all viral, the two has stopped pathogenic bacterium and the propagation of virus between the bathing personnel in conjunction with making multiplexing water hygiene index be lower than the tap water prescribed value.The sterilization method that present method adopts does not add chemical agent, does not produce secondary pollution and to the influential toxic substance of human health, sterilization speed is fast, and efficient height and operation of equipment are simple; The 3rd, running cost is low, with day output 100m 3Meter, the molding device wastewater recycle rate is 80~85%, reuse bath wastewater all charges per ton (containing medicament, power consumption, equipment amortization etc.) is 2.13 yuan,, is accepted by the bathing industry easily as the tap water price of commercial water far below at present.Therefore this technology is with the obvious advantage in technology and economic aspect, has very high practical value.
Description of drawings:
Fig. 1 is the synoptic diagram of step 2 in the embodiment of the present invention three, and Fig. 2 is the synoptic diagram of step 4 in the embodiment five, and Fig. 3 is the synoptic diagram of step 5 in the embodiment six.
Embodiment:
Embodiment one: the integrated physical chemistry treatment process that a kind of bath wastewater is multiplexing, it is finished by following step: (one) drops into poly-ferric chloride in waste water, carries out coagulating sedimentation; (2) water of post precipitation filters by hard coal-quartz sand double-layer filter material; (3) water after filtering enters in the container of splendid attire granular carbon adsorption column and zeolite ion exchange column and carries out charcoal absorption and ion-exchange; (4) water after handling enters ultra-filtration membrane and filters; (5) water is carried out disinfection by ultraviolet light.
Embodiment two: the difference of present embodiment and embodiment one is, in precipitation process of coagulation, the ratio of adding is 18~22 milligrams of poly-ferric chlorides of every liter of waste water, and sedimentation time is 10~17 minutes.Be preferably every liter of waste water and add 20 milligrams of poly-ferric chlorides, sedimentation time 15 minutes.Other step is identical with embodiment one.
Embodiment three: specify present embodiment below in conjunction with Fig. 1.The difference of present embodiment and embodiment one is, particle diameter is that the hard coal 1 that 0.9~1.2 millimeter quartz sand 2 and particle diameter are 1.5~2 millimeters is formed hard coal-quartz sand double-layer filter material in step (two), and the water of post precipitation passes through filtrate with 10~15 meters/hour filtering velocity.Other step is identical with embodiment one.
Embodiment four: the difference of present embodiment and embodiment one is, in step (three), water after the filtration enters in the container of splendid attire granular carbon adsorption column and zeolite ion exchange column with 10~15 meters/hour filtering velocity, and adsorbing duration of contact is 5~10 minutes.Other composition and annexation and concrete
Embodiment one is identical.
Embodiment five: specify present embodiment below in conjunction with Fig. 2.The difference of present embodiment and embodiment one is, enters water in the ultra-filtration membrane 3 through the water pump pressurization, and its pressure is 0.05~0.10Mpa.Other step is identical with embodiment one.
Embodiment six: specify present embodiment below in conjunction with Fig. 3.The difference of present embodiment and embodiment one is, what in step (five) water is carried out disinfection by ultraviolet light is UV-lamp 4,1~3 minute uv sterilisation time of the water of the UV-lamp of flowing through 4.Other step is identical with embodiment one.

Claims (5)

1, the multiplexing integrated physical chemistry treatment process of a kind of bath wastewater, it is characterized in that it finishes by following step: (one) drops into poly-ferric chloride in waste water, carry out coagulating sedimentation; (2) water of post precipitation filters by hard coal-quartz sand double-layer filter material; (3) water after filtering enters in the container of splendid attire granular carbon adsorption column and zeolite ion exchange column and carries out charcoal absorption and ion-exchange; (4) water after handling enters ultra-filtration membrane and filters; (5) water is carried out disinfection by ultraviolet light; In precipitation process of coagulation, the ratio of adding is 18~22 milligrams of poly-ferric chlorides of every liter of waste water, and sedimentation time is 10~17 minutes; Particle diameter is that the hard coal (1) that 0.9~1.2 millimeter quartz sand (2) and particle diameter are 1.5~2 millimeters is formed hard coal-quartz sand double-layer filter material in step (two), and the water of post precipitation passes through filtrate with 10~15 meters/hour filtering velocity.
2, the multiplexing integrated physical chemistry treatment process of bath wastewater according to claim 1 is characterized in that every liter of waste water adds 20 milligrams of poly-ferric chlorides, sedimentation time 15 minutes.
3, the multiplexing integrated physical chemistry treatment process of bath wastewater according to claim 1, it is characterized in that in step (three), water after the filtration enters in the container of splendid attire granular carbon adsorption column and zeolite ion exchange column with 10~15 meters/hour filtering velocity, and adsorbing duration of contact is 5~10 minutes.
4, the multiplexing integrated physical chemistry treatment process of bath wastewater according to claim 1, the water that it is characterized in that entering in the ultra-filtration membrane (3) pressurizes through water pump, and its pressure is 0.05~0.10Mpa.
5, the multiplexing integrated physical chemistry treatment process of bath wastewater according to claim 1, what it is characterized in that in step (five) water is carried out disinfection by ultraviolet light is UV-lamp (4), 1~3 minute uv sterilisation time of the water of the UV-lamp of flowing through (4).
CN 200410013777 2004-05-26 2004-05-26 Integral phyical chemical treating method by bathing waste water reutilization Expired - Fee Related CN1285520C (en)

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Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100443034C (en) * 2006-10-17 2008-12-17 西南化工研究设计院 Showering water cyclic utilization system
CN101190806B (en) * 2006-11-24 2010-04-14 上海华谊集团华原化工有限公司 Treatment method for waste water
CN101628761B (en) * 2009-08-18 2011-12-07 湖南邦普循环科技有限公司 Treatment method of nickel-cobalt-manganese wastewater generated in waste and old battery treatment process
CN102442723B (en) * 2010-10-07 2014-07-16 福建新大陆科技集团有限公司 Active carbon filter tank for preventing biological growth
CN108046440A (en) * 2017-12-14 2018-05-18 张松 A kind of bath sewage cleanser and its preparation method and application
CN109354325A (en) * 2018-12-07 2019-02-19 四川清和科技有限公司 A technique for utilizing ammonia nitrogen, total phosphorus and the COD in flocculation-zeolite and active carbon degrading waste water
CN109607897A (en) * 2018-12-17 2019-04-12 上海电机学院 A kind of water treatment cycle utilization system
CN111533334A (en) * 2020-05-09 2020-08-14 江苏澳特克环境科技有限公司 Filtering and recycling process for bathroom wastewater
CN112551784B (en) * 2020-12-28 2022-01-04 华夏碧水环保科技有限公司 Power plant desulfurization treatment reclaimed water recycling device

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