CN1282678C - Emulsoid for water base floor polishing agent - Google Patents
Emulsoid for water base floor polishing agent Download PDFInfo
- Publication number
- CN1282678C CN1282678C CN 200310108609 CN200310108609A CN1282678C CN 1282678 C CN1282678 C CN 1282678C CN 200310108609 CN200310108609 CN 200310108609 CN 200310108609 A CN200310108609 A CN 200310108609A CN 1282678 C CN1282678 C CN 1282678C
- Authority
- CN
- China
- Prior art keywords
- emulsion
- methyl
- monomers
- floor polishing
- water base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 238000005498 polishing Methods 0.000 title claims abstract description 16
- 239000000178 monomer Substances 0.000 claims abstract description 30
- 239000000839 emulsion Substances 0.000 claims abstract description 14
- -1 alkenyl carboxylic acid Chemical class 0.000 claims abstract description 10
- 238000004132 cross linking Methods 0.000 claims abstract description 8
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 8
- 150000003624 transition metals Chemical class 0.000 claims abstract description 8
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 3
- 239000004816 latex Substances 0.000 claims description 14
- 229920000126 latex Polymers 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 12
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 11
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 8
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 6
- IWLXWEWGQZEKGZ-UHFFFAOYSA-N azane;zinc Chemical compound N.[Zn] IWLXWEWGQZEKGZ-UHFFFAOYSA-N 0.000 claims description 5
- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical compound CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 claims description 2
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 claims description 2
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 abstract description 8
- 239000002585 base Substances 0.000 abstract description 7
- 229910052751 metal Inorganic materials 0.000 abstract description 6
- 239000002184 metal Substances 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 4
- 239000003513 alkali Substances 0.000 abstract description 2
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical compound [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- HVDAEOSLZHDODQ-UHFFFAOYSA-N P(OCCCCCCCCCCCCCCCCCC)(O)O.C(C=C)(=O)O Chemical compound P(OCCCCCCCCCCCCCCCCCC)(O)O.C(C=C)(=O)O HVDAEOSLZHDODQ-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 230000003373 anti-fouling effect Effects 0.000 abstract 1
- 238000010556 emulsion polymerization method Methods 0.000 abstract 1
- 238000005201 scrubbing Methods 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 238000003825 pressing Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 239000004160 Ammonium persulphate Substances 0.000 description 4
- 208000037656 Respiratory Sounds Diseases 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 235000019395 ammonium persulphate Nutrition 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000004579 marble Substances 0.000 description 2
- 229910052755 nonmetal Inorganic materials 0.000 description 2
- 239000004209 oxidized polyethylene wax Substances 0.000 description 2
- 235000013873 oxidized polyethylene wax Nutrition 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- VUWCWMOCWKCZTA-UHFFFAOYSA-N 1,2-thiazol-4-one Chemical class O=C1CSN=C1 VUWCWMOCWKCZTA-UHFFFAOYSA-N 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 description 1
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical group CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- WAGQPVRUQLVVFJ-UHFFFAOYSA-N dibutyl benzene-1,2-dicarboxylate 2,2,2-tributoxyethyl dihydrogen phosphate Chemical compound C(C=1C(C(=O)OCCCC)=CC=CC1)(=O)OCCCC.P(=O)(OCC(OCCCC)(OCCCC)OCCCC)(O)O WAGQPVRUQLVVFJ-UHFFFAOYSA-N 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000000472 traumatic effect Effects 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
Title | Ratio (%) |
ZnO | 14 |
(NH4) 2CO 3 | 12 |
Glycine | 20 |
Ammoniacal liquor (25%) | 30 |
Water | 24 |
Monomer | Weight | Wt% |
BA | 420 | 25 |
MMA | 302.4 | 18 |
ST | 705.6 | 42 |
MAA | 252 | 15 |
Performance | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 |
Film-formability | Very good | Very good | Very good | Very good | Very good | Very good | Very good |
60 ° of glossiness | 80 | 79 | 82 | 81 | 84 | 80 | 82 |
But recoatability | Good | Good | Good | Good | Good | Good | Good |
Water tolerance | Good | Fine | Very good | Fine | Very good | Fine | Very good |
Washing fastness | Generally | Generally | Fine | Good | Fine | Generally | Fine |
Removeability | Good | Very good | Fine | Very good | Fine | Very good | Fine |
Anti-damageability | Good | Generally | Fine | Good | Fine | Good | Fine |
Composition | Effect | Consumption (wt%) |
Water fluorine carbon surfactant (1%) isothiazolinone derivative (1.5%) organic silicone defoamer diethylene glycol ether dibutyl phthalate tributoxyethyl phosphate latex polymer (38%) oxidized polyethylene wax emulsion (35%) | Diluent wetting agent bactericide defoamer coalescent plasticizer levelling agent main film forming substance oxidized polyethylene wax emulsion | 36.30 0.90 0.03 0.02 7.5 0.8 2.4 45.68 6.17 |
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200310108609 CN1282678C (en) | 2003-11-14 | 2003-11-14 | Emulsoid for water base floor polishing agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200310108609 CN1282678C (en) | 2003-11-14 | 2003-11-14 | Emulsoid for water base floor polishing agent |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1616503A CN1616503A (en) | 2005-05-18 |
CN1282678C true CN1282678C (en) | 2006-11-01 |
Family
ID=34758644
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 200310108609 Expired - Fee Related CN1282678C (en) | 2003-11-14 | 2003-11-14 | Emulsoid for water base floor polishing agent |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1282678C (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110003728A (en) * | 2019-04-04 | 2019-07-12 | 南京瑞固聚合物有限公司 | A kind of modified aqueous acrylic acid resin dispersion and preparation method thereof |
-
2003
- 2003-11-14 CN CN 200310108609 patent/CN1282678C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN1616503A (en) | 2005-05-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: SHANGHAI SANRUI CHEMISTRY CO., LTD. Free format text: FORMER OWNER: SHANGHAI RUIPO SYNTHESIS SCIENCE DEVELOPMENT CO., LTD. Effective date: 20070817 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20070817 Address after: 200232 Shanghai Xi Road No. 237 Building No. 17 Patentee after: Shanghai Sunrise Chemical Co.,Ltd. Address before: 200233, 3 building, building 680, Guiping Road, Shanghai Patentee before: Shanghai Ruipo Technology Development Co.,Ltd. |
|
ASS | Succession or assignment of patent right |
Owner name: SHANGHAI SANRUI POLYMER MATERIAL CO., LTD. Free format text: FORMER OWNER: SHANGHAI SANRUI CHEMISTRY CO., LTD. Effective date: 20140928 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20140928 Address after: 200232 Shanghai Xi Road No. 237 Building No. 17 Patentee after: Shanghai Sunrise Polymer Materials Co.,Ltd. Address before: 200232 Shanghai Xi Road No. 237 Building No. 17 Patentee before: Shanghai Sunrise Chemical Co.,Ltd. |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20061101 |
|
CF01 | Termination of patent right due to non-payment of annual fee |