CN1281784C - Composite plating layer containing carbon nano shallot ball shaped nanomaterial and its preparation method - Google Patents
Composite plating layer containing carbon nano shallot ball shaped nanomaterial and its preparation method Download PDFInfo
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- CN1281784C CN1281784C CN 200410018061 CN200410018061A CN1281784C CN 1281784 C CN1281784 C CN 1281784C CN 200410018061 CN200410018061 CN 200410018061 CN 200410018061 A CN200410018061 A CN 200410018061A CN 1281784 C CN1281784 C CN 1281784C
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- plating layer
- composite plating
- ball shaped
- carbon nano
- preparation
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 239000002131 composite material Substances 0.000 title claims abstract description 38
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 33
- 239000002086 nanomaterial Substances 0.000 title claims abstract description 24
- 238000007747 plating Methods 0.000 title abstract description 24
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 244000291564 Allium cepa Species 0.000 title 1
- 235000010167 Allium cepa var aggregatum Nutrition 0.000 title 1
- 241000234282 Allium Species 0.000 claims description 29
- 235000002732 Allium cepa var. cepa Nutrition 0.000 claims description 29
- 238000000576 coating method Methods 0.000 claims description 14
- 239000011248 coating agent Substances 0.000 claims description 11
- 229910002804 graphite Inorganic materials 0.000 abstract description 15
- 239000010439 graphite Substances 0.000 abstract description 15
- 229910018104 Ni-P Inorganic materials 0.000 abstract description 14
- 229910018536 Ni—P Inorganic materials 0.000 abstract description 14
- 239000000126 substance Substances 0.000 abstract description 9
- 239000010959 steel Substances 0.000 abstract description 5
- 229910000838 Al alloy Inorganic materials 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 229910000851 Alloy steel Inorganic materials 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 abstract description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 8
- 229910052759 nickel Inorganic materials 0.000 abstract 4
- 239000007788 liquid Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000005299 abrasion Methods 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000007772 electroless plating Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000004310 lactic acid Substances 0.000 description 3
- 235000014655 lactic acid Nutrition 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 150000002815 nickel Chemical class 0.000 description 3
- 239000001488 sodium phosphate Substances 0.000 description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 229960004249 sodium acetate Drugs 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 2
- 229940038773 trisodium citrate Drugs 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Chemically Coating (AREA)
- Electroplating Methods And Accessories (AREA)
Abstract
The present invention discloses a nickel base composite plating layer containing carbon nano onion-shaped nanomaterial and a preparation method thereof. The composite plating layer is prepared by chemical composite plating, and chemical plating liquid contains 3 to 15 g/L of carbon nano onion-shaped nanomaterial. The composite plating layer of the present invention has high wear resistance and high antiattrition performance. Under the same test condition, the wearing capacity of the nickel base composite plating layer is 1/5 of that of a Ni-P plating layer and is 1/3 of that of a Ni-P-graphite composite plating layer, the frication coefficient is only from 0.03 to 0.04, and the friction coefficients of the Ni-P plating layer and the Ni-P-graphite composite plating layer are respectively from 0.10 to 0.12 and from 0.06 to 0.07. the preparation method of the nickel base composite plating layer containing carbon nano onion-shaped nanomaterial of the present invention is simple, and the nickel base composite plating layer can be plated on the surfaces of metal parts of steel and aluminum alloy.
Description
Technical field
The present invention relates to the plating of metallic substance, especially carbon containing nanometer green onion ball shaped nano material nickel-base composite coat material
Background technology
The solid particulate that is contained in the existing various composite deposite mainly contains: silicon carbide, diamond, graphite, tungsten sulfide and moly-sulfide, but the composite deposite that contains these solid particulates at present is not very good at its wear resisting property, self-lubricating property, tribological property.
The graphite of laminate structure has obtained using widely as lubricant.In composite deposite, contain the tribological property that graphite particulate can improve coating.For example its frictional coefficient of Ni-P composite deposite that contains graphite with chemically composited coating technology preparation can be reduced to 0.06-0.07 from the 0.11-0.12 of Ni-P chemical plating, and wear rate also is reduced to original 50%.But the flaky graphite of existing this employing still is not very good as the improvement that packing material prepares its wear resisting property of chemical composite plating and antifriction performance.Carbon onion has spherical graphite layer structure nested and sealing, has good chemical stability and excellent tribological property.Existing technology can adopt the arc-over in water to prepare carbon onion, and concrete preparation process is existing detailed explanation in document [1] and document [2].Arc-over in water prepares the carbon onion nano material can carry out continuously.
[1]N.Sano，H.Wang，I.Alexandrou，et?al，Properties?of?carbon?onions?produced?byan?arc?discharge?in?water，J.Appl.Phys.，2002，92(5)：2783-2788.
[2]N.Sano，H.Wang，M.Chhowalla，I.Alexandrou，G.A.J.Amaratunga，Synthesis?of?carbon?onions?in?water，Science，2001，29(414)：506-507.
But the research about the chemical composite plating of and antifriction wear-resisting with the material preparation of carbon onion ball shaped nano yet there are no report up to now.
Summary of the invention
The purpose of this invention is to provide a kind of nickel-base composite coat that contains carbon onion ball shaped nano material, it not only has high-wear resistance, and has low frictional coefficient.
Technical scheme of the present invention is:
The nickel-base composite coat that contains carbon onion ball shaped nano material is to contain to have carbon onion ball shaped nano material in coating, and the size of nano material is in the 30-50 nanometer.
The preparation method who contains the nickel-base composite coat of carbon onion ball shaped nano material adopts chemically composited electroplating method, and the composition and the operational condition of chemically composited plating liquor are as follows:
Single nickel salt or nickelous chloride 10-35g/L
Inferior sodium phosphate or POTASSIUM BOROHYDRIDE 0.5-35g/L
Sodium wolframate 0-70g/L
Trisodium Citrate or quadrol 0-100g/L
Lactic acid 0-20mL/L
pH 4-14
Temperature 70-90 ℃
Diameter is the carbon onion ball shaped nano material 3-15g/L of 30-50nm
2-4 hour plating time
PH value with acetic acid or sodium-acetate or sodium hydroxide or ammonium sulfate adjustment solution.
Have following outstanding advantage with prior art comparison the present invention:
1) composite deposite that contains carbon onion ball shaped nano material of the present invention has high wear resisting property and good antifriction performance.Under equal test condition, its abrasion loss is 1/5 of a Ni-P coating, is Ni-P-graphite 1/3; Its frictional coefficient has only 0.03-0.04, and the frictional coefficient of Ni-P coating and Ni-P-graphite composite deposite is respectively 0.10-0.11 and 0.06-0.07.
2) to contain the method for composite deposite of carbon onion ball shaped nano material simple for the chemically composited electroplating method preparation used of the present invention, can be plated on iron and steel and Al-alloy metal piece surface, is suitable for suitability for industrialized production.
3) this above-mentioned composite deposite that contains carbon onion ball shaped nano material with high abrasion and antifriction performance; can prolong the work-ing life of metal parts; and reduction energy consumption; help environment protection, therefore have widely and use at industrial sectors such as automobile, machinery, chemical industry, aerospace.
Embodiment
Embodiment 1:
The Ni-P composite deposite that contains carbon onion ball shaped nano material with method plating on the 45# steel matrix of electroless plating.Its solution and coating method is as follows: single nickel salt 24g/L, inferior sodium phosphate 23g/L, lactic acid 5mL/L, sodium-acetate 12g/L, pH=5.5,90 ℃ of temperature, carbon onion 6g/L, 3 hours time.Frictional wear experiment is the result show: the abrasion loss that contains the Ni-P composite deposite of carbon onion be respectively Ni-P coating 1/5, Ni-P-graphite 1/2, its frictional coefficient is 0.029, and Ni-P and Ni-P-graphite frictional coefficient are 0.11 and 0.07.The Ni-P composite deposite that proof contains the carbon onion ball has high wear-resisting and antifriction performance.
Embodiment 2:
The Ni-W-P composite deposite that contains carbon onion ball shaped nano material with method plating on the 45# steel matrix of electroless plating.Its solution and coating method is as follows: single nickel salt 25g/L, sodium wolframate 65g/L, inferior sodium phosphate 22g/L, Trisodium Citrate 100g/L, lactic acid 6mL/L, ammonium sulfate 30g/L, pH=9.4,85 ℃ of temperature, carbon onion 5g/L, 2.5 hours time.The frictional wear experiment result shows that the abrasion loss of the Ni-W-P composite deposite that contains carbon onion is 1/3 of a Ni-W-P-graphite composite deposite, and its frictional coefficient is 0.036, and the frictional coefficient of general graphitiferous Ni-W-P composite deposite is 0.06-0.08.
Embodiment 3:
The Ni-B composite deposite that contains carbon onion ball shaped nano material with method plating on the 45# steel matrix of electroless plating.Its solution and coating method is as follows: nickelous chloride 30g/L, POTASSIUM BOROHYDRIDE 0.8g/L, quadrol 55g/L, sodium hydroxide 40g/L, pH=14,75 ℃ of temperature, carbon onion ball shaped nano material 11g/L, 3 hours time.Frictional wear experiment is found: the abrasion loss that contains the Ni-B composite deposite of carbon onion ball shaped nano material be respectively Ni-B coating 1/7, Ni-B-graphite composite deposite 1/3, its frictional coefficient is 0.031, and the frictional coefficient of Ni-B and Ni-B-graphite is 0.12 and 0.065.
Embodiment 4:
Aluminium alloy gives by secondary and to soak zinc or to soak admiro behind oil removing, alkaline etch and acid etching, contains the Ni-P composite deposite of carbon onion ball shaped nano material then at its coating surface with chemical plating method.Chemical plating method is with embodiment 1.Frictional wear experiment finds that the abrasion loss of aluminum alloy surface Ni-P-carbon onion composite deposite is the 1/5-1/6 of Ni-P coating, and its frictional coefficient is 0.03, and the frictional coefficient of Ni-P coating is 0.11.
Claims (1)
1. nickel-base composite coat that contains carbon onion ball shaped nano material, it is characterized in that: contain carbon onion ball shaped nano material in coating, its size is in the 30-50 nanometer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410018061 CN1281784C (en) | 2004-04-27 | 2004-04-27 | Composite plating layer containing carbon nano shallot ball shaped nanomaterial and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410018061 CN1281784C (en) | 2004-04-27 | 2004-04-27 | Composite plating layer containing carbon nano shallot ball shaped nanomaterial and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1570206A CN1570206A (en) | 2005-01-26 |
| CN1281784C true CN1281784C (en) | 2006-10-25 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 200410018061 Expired - Fee Related CN1281784C (en) | 2004-04-27 | 2004-04-27 | Composite plating layer containing carbon nano shallot ball shaped nanomaterial and its preparation method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP6598588B2 (en) * | 2015-08-25 | 2019-10-30 | 富士電機株式会社 | Sliding structure, plating bath and sliding member manufacturing method |
| CN111218588B (en) * | 2018-11-27 | 2021-05-11 | 有研工程技术研究院有限公司 | Aluminum alloy hemisphere for automobile air-conditioning compressor and preparation method thereof |
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- 2004-04-27 CN CN 200410018061 patent/CN1281784C/en not_active Expired - Fee Related
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