CN1278802C - Process for extrusion casting piston blank of internal combustion engine with local feinforcing of metal base composite material - Google Patents
Process for extrusion casting piston blank of internal combustion engine with local feinforcing of metal base composite material Download PDFInfo
- Publication number
- CN1278802C CN1278802C CN 03134491 CN03134491A CN1278802C CN 1278802 C CN1278802 C CN 1278802C CN 03134491 CN03134491 CN 03134491 CN 03134491 A CN03134491 A CN 03134491A CN 1278802 C CN1278802 C CN 1278802C
- Authority
- CN
- China
- Prior art keywords
- alloy
- matrix alloy
- aluminium
- piston
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Pistons, Piston Rings, And Cylinders (AREA)
Abstract
The present invention relates to a technology for squeezing and casting locally reinforcing internal combustion engine piston blanks of metal base composite material, which comprises: (1) manufacturing reinforcing phase preformed members; (2) preparing matrix alloy furnace material: silicon accounts for 11 to 13%, copper accounts for 0.5 to 2.0%, magnesium accounts for 0.4 to 1.4%, manganese accounts for 0.2 to 0.9%, vanadium accounts for 0.05 to 0.27%, and aluminium is added to 100%; (4) degassing and refining: argon is filled, the argon blowing pressure is from 100 to 110 mmhg, the argon blowing time is from 6 to 8 minutes, and the refining temperature is from 780 to 810DEG. C; (5) modification treating: ternary compound modifiers which comprises 0.013 to 0.016% of Be, 0.04 to 0.06% of Ti and 0.002 to 0.004% of Te are added to alloy fusant; (6) preparing moulds; (7) pouring piston blanks. The present invention has the advantages of good quality, high efficiency, low cost, no public nuisance, etc., and is suitable for squeezing and casting locally reinforcing aluminium piston products of the metal base composite material.
Description
Technical field
The invention belongs to the machine components manufacturing process technology field, be specifically related to the local technology that strengthens the internal combustion engine blank of extrusion casting metal base composite.
Background technology
The applied metal based composites carries out the part enhancing to internal combustion engine first road annular groove and diesel engine piston combustion chamber, to adapt to the specification requirement that modern high parameter internal combustion engine improves day by day to piston details, day by day is acknowledged as an effective and feasible approach.State such as Japan and the United States, moral all has the practical product supply the market, result of use is good, and, enjoy attention at first as light high-speed diesel engine and the heavily loaded strong upgraded product of strengthening the conventional piston of the high Ni austenitic cast iron of diesel applications iron chains coil structures.Some metal-base composites that the utilization squeeze casting method is produced strengthens the automobile engine piston of first annular groove, and annual production has reached 1,000,000 scales.But compare with the huge potential demand of automobile industry, this remains inappreciable.One of its major reason is exactly that existing technical method exists technique controlling difficulty big because of its operational characteristic requirement on the making link of part enhancing pre-member, quality is unstable and the cycle is long, efficient is low, and it is high-leveled and difficult following to cause product cost to occupy, and has restricted promoting the use of of it.Continue to use existing aluminium piston alloy chemical formulation and traditional melt casting process and make also that to make the novel piston institutional framework not ideal enough, the percent defective that causes because of inclusion defects etc. in the production process is higher, and is unfavorable to the technology and the market competitiveness of this product.
Squeeze casting method is that motlten metal is injected in the pre-thermometal former of setting in a usual manner, utilize plant equipment such as hydraulic press to be power, make the drift that is fixed thereon press to former, force the molten metal in the former under 〉=70Mpa pressure effect, to form foundry goods, and under pressure solidification and crystallization.
Squeeze casting method is grafted in the preparation process of discontinuous enhancing metal-base composites, utilize the wild phase pre-member under greater than the fully good impregnation of 70Mpa high-pressure liquid parent metal to finish the formation of metal-base composites, it is the important achievement that promotes that this advanced engineering material of metal-base composites is expected to begin popularization and application on the product for civilian use, also, widen the properties of product designability and open up a new way for by the local privileged site that strengthens some products of metal-base composites.
First annular groove of internal combustion engine part and the wearability of top piston ring all have a significant effect to efficient, power, oil consumption and the discharging of whole engine, because the lubricating condition that should encircle is the poorest, in the compression-expansion stroke, but pressed to casing wall by higher atmospheric pressure, and the temperature of annular groove is very high, and its side but is subjected to higher atmospheric pressure and frictional force effect.The present softer all-aluminium piston of widespread usage makes first annular groove become weak part, loses efficacy because of premature wear usually causes piston.This phenomenon is higher at compression ratio, and is more outstanding on the bigger Diesel engine of heat load intensity.Have no alternative but adopt at a kind of Ni of containing of piston first annular groove position iron chains casting and reach 14% austenitic cast iron guard ring in order to improve this problem, can avoid the problem of this too early wear out failure in position on the work effect, but the new problem of bringing is an iron chains casting process complexity, production percent defective height, production efficiency is low, the quality control difficulty is big, reclaiming is poor, particularly when carrying out the piston heat treatment reinforcement, because of the joint portion aluminium alloy can produce internal stress with the different of the coefficient of expansion of ferroalloy, even generation breaks away from problems such as crackle.In addition, the top of piston is the highest zone of piston heat load.Especially the various special-shaped combustor section of the top land of heavy-duty diesel engine usually adopts iron chains casting heat resisting steel guard ring to increase the heat resistanceheat resistant load-bearing capacity at this place, brings a same sampling technology difficult problem and drawback with the first annular groove iron chains circle method.For improving this defective; people utilize aluminium oxide at above-mentioned position; silica; alumina silicate; the particle of carborundum etc. or short fiber and aluminium piston alloy are made the local novel piston that strengthens of so-called metal-base composites; make the wearability that is enhanced the position; the heat resistanceheat resistant load-bearing capacity; rigidity etc. all are greatly improved; because the linear expansion coefficient of metal-base composites is less than the linear expansion coefficient of aluminium piston alloy; the local cylinder prepareding gap that strengthens aluminium piston and cylinder wall of metal-base composites also can further be reduced; practice has proved the appearance of this novel advanced piston; be highly effective, accepted by increasing automobile production producer.Come out so far from the local automobile engine piston that strengthens of nineteen eighty-three first metal-base composites of Japan, over nearly 20 years, the granted amount commercial Application of this new product, annual production reaches up to a million scales.
At present the annual automobile of producing in the whole world is about 5,000 ten thousand, wherein adopt Diesel engine ten thousand of 1800-2000, potential market demand every year of visible this new product of application is at least about 100,000,000 scales.Applying one of reason of having huge contrast between the scale of novel piston and the potential demand at present is, wild phase pre-member manufacture craft is hard to tackle, and the cycle is long, and efficient is low, and the cost height is restricting the quick popularization of this product.Former two is to use squeeze casting technology to produce the local piston product that strengthens of metal-base composites, a no doubt simpler and easy difficult problem that successfully solves composite effect on the one hand therefore.But it is then incompatible with the process conditions requirement of producing article made from metal based composite material with this process to continue to use some technological parameters of general extrusion casint aluminium alloy on process conditions, even has suitable difference, has to be optimized.For example, in the Extrution casting technique of general aluminium alloy castings, for obtaining thin brilliant high-performance result and protect die life, the mould temperature is low, also will adopt the water-cooled cooling measure, and the corresponding general casting of alloy temperature is also on the low side or the like.But when extrusion casting metal base composite, for guaranteeing good composite effect, the melting of alloy and pouring temperature and mold temperature all require corresponding raising, this backspace comes and can to have influence on the material institutional framework at the non-enhancing of piston position thick, problems such as performance is on the low side, on alloy melting, air content is higher can be unfavorable for that with the more alloy liquid of field trash matrix alloy is to the intrapore good infiltration of wild phase, alloy melting temp need improve and then aggravate the degree that alloy pollutes, also have (〉=780 ℃ of higher alloy melting and pouring temperatures, even more than 800 ℃) can bring rotten incompatible (deterroration requires at 730～740 ℃) of handling material (Na salt or Sr are rotten) and its technological parameter of tradition, make modification effect bad, cause the mechanical performance infringement.
In the smelting process of alloy, the CCL of extensive use at present
4And C
2CL
6Deng chloralkane or other villaumites (zinc chloride, manganese chloride) refining scavenging.The degasification temperature requires at 730～740 ℃ more, and degassing effect is pretty good, but slag thickness in the course of reaction, inferior separating effect.Product Mn belongs to objectionable impurities to ZL 109 alloy, and product Zn is objectionable impurities to ZL109 and zl108 alloy.And in squeeze casting method, the die cavity deslagging is very poor, very easily produces the field trash waste product, and various chloride degasification deslagging agent has the generation of strong impulse smell in degassing procedure, and is all unfavorable to human body mucous membrane and environmental protection.
Summary of the invention
Technical problem to be solved by this invention is to overcome above-mentioned preparation method's shortcoming, provides a kind of extrusion casting metal base composite the local technology that strengthens the internal combustion engine blank.
Solving the problems of the technologies described above the technical scheme that is adopted is that this technology comprises the steps:
(1) makes the wild phase pre-member
Adopt local preparation method or the short fiber reinforced metal-base composite materials product porous preform preparation method who strengthens the product pre-member of metal-base composites wild phase pre-member preparation method or metal-base composites to make the wild phase pre-member;
(2) preparation matrix alloy furnace charge
Prepare the matrix alloy furnace charge by following weight ratio:
Silicon 11～13%
Copper 0.5～2.0%
Magnesium 0.4～1.4%
Manganese 0.2～0.9%
Vanadium 0.05～0.27%
Aluminium adds to 100%
(3) melting matrix alloy
Melt the aluminium stove with packing into through whole matrix alloy furnace charges of mechanic shot peening cleaning processing in advance, account for the following aluminium alloy smelting coverture of matrix alloy furnace charge gross weight 3～5% in the upper surface covering of matrix alloy furnace charge:
Sodium chloride 50%
Potassium chloride 15%
Aluminium fluoric acid sodium 25%
Calcirm-fluoride 5%
Sodium fluoride 5%
Heat fused also is superheated to 800～900 ℃, realizes the abundant fusion of refractory element, is cooled to 780～810 ℃ of refining processing temperature;
(4) degasification is concise
Scratch clean the aluminium alloy smelting coverture on alloy melt surface, feed dry industrial one-level pure argon (Ar), alloy melt is carried out Argon degasification slagging-off refining processing, Argon pressure is 100～110mm mercury column, argon blowing time is 6～8 minutes, and concise temperature is 780～810 ℃, scratches clean scum silica frost, left standstill 5～6 minutes, and entered rotten treatment step.
(5) the rotten processing
In alloy melt, add following matrix alloy charging weight percentage and be crushed to the ternary composite modifier (in the single element addition) of 5～10mm particle:
Be 0.013～0.016％
Ti 0.04～0.06％
Te 0.002～0.004％
In the said ratio, Be adds with the aluminium beryllium alloy, and wherein Be content is 5%, Ti adds with aluminum titanium alloy, wherein the content of Ti is 3%, and Te adds with monomer, and rotten treatment temperature is 780～800 ℃, be stirred to the ternary composite modifier all after the dissolving with graphite rod, left standstill 15～20 minutes, and fully stirred again subsequently, left standstill 5～10 minutes, remove scum silica frost, can pour into a mould.
(6) prepare mould
In the degasification of carrying out alloy melt and rotten treatment step, should make cast preceding coating and The pre-heat treatment to mould simultaneously.Former and drift with Piston mould is preheated to 120～150 ℃ earlier, and evenly spraying is less than the water base colloid graphite paint of the thick skim of 50 μ m with sprayer, and the preheat temperature of mould should be 350～400 ℃
(7) casting of piston blank
At first the mold cavity corresponding site in preheating fixes the wild phase forward purchasing part that is preheated to 450～600 ℃, and pours into alloy melt in 1 minute thereafter.Pouring temperature range is 760～800 ℃, in 1 minute after pouring into alloy melt, speed decline mold and punching head by 0.5 meter per second, matrix alloy melt in die cavity applies the pressure of 110～110Mpa, holds and presses for 10～30 seconds, the shaping of finishing piston blank with solidify, pouring temperature is taken off limit, the squeeze pressure capping, the pouring temperature capping, squeeze pressure takes off limit, extrusion time is decided according to the piston thickest, the heavy section casting capping, thin-wall part takes off limit, after piston solidifies, at once open mould, eject foundry goods, sprayed coating carries out the cast of next blank again.
In (2) of the present invention preparation matrix alloy burden process step, prepare the matrix alloy furnace charge by following preferred weight ratio:
Silicon 11～13%
Copper 1.0～1.5%
Magnesium 0.6～1.2%
Manganese 0.4～0.8%
Vanadium 0.10～0.2%
Aluminium adds to 100%
In (2) of the present invention preparation matrix alloy burden process step, prepare the matrix alloy furnace charge by following optimum weight ratio:
Silicon 12%
Copper 1.2%
Magnesium 1.0%
Manganese 0.6%
Vanadium 0.15%
Aluminium adds to 100%
In (5) rotten treatment process steps, the following ternary composite modifier (in the single element addition) of best adding:
Be 0.015％
Ti 0.05％
Te 0.003％
In the matrix alloy charge composition of the present invention, used manganese can be replaced with nickel, and its consumption is 0.5～3.0% of a matrix alloy furnace charge.
In the proportioning of matrix alloy furnace charge of the present invention, the preferable amount of nickel is 1.0～2.0% of a matrix alloy furnace charge.
In the proportioning of matrix alloy furnace charge of the present invention, the optimum amount of nickel is 1.5% of a matrix alloy furnace charge.
The present invention is directed to and add a small amount of V in the conventional aluminum alloy composition of metal mold gravity casting internal combustion engine, the Fe constituent content that allows to be regarded as objectionable impurities by the expanded range of＜0.5～0.7% (GB/F 1173-1995) to＜0.8～1.0%, make it under the new smelting technology condition of described alloy, reach thinner crystal grain texture, form more, a (AIFeSi) phase that has good heat resistance in 300～350 ℃ of intervals has improved the heat resistanceheat resistant load-bearing capacity of piston; In the alloy melting process, use the rotten processing of new Be-Ti-Te composite refining, improve the alloy degree of purity, reduce the scaling loss of Mg element in fusion process, thinning microstructure ensures the W phase (Al that takes the heat resistanceheat resistant load in 200～250 ℃ of intervals effectively
4Mg
5Cu
4Si
4) quantity; Adopt argon gas degasification refining to substitute the villaumite or the chloralkane scavenging of widespread usage, can reach satisfied air content control, minimizing is mingled with waste product, has eliminated environmental pollution.The present invention have high-quality, efficient, cost is low and advantage such as nuisanceless.Be applicable to the local making that strengthens aluminium piston product of extrusion casting metal base composite.
The specific embodiment
The present invention is described in more detail below in conjunction with embodiment, but the invention is not restricted to these embodiment.
Embodiment 1
The local following step of process using that strengthens the internal combustion engine blank of the extrusion casting metal base composite of present embodiment:
(1) makes the wild phase pre-member
Adopt metal-base composites wild phase pre-member preparation method, the local preparation method who strengthens the product pre-member of metal-base composites, short fiber reinforced metal-base composite materials product porous preform preparation method makes the wild phase pre-member, the preparation method of metal-base composites wild phase pre-member puts down in writing in number of patent application is 03134444.5 Chinese patent, the preparation method that metal-base composites is local to strengthen the product pre-member puts down in writing in number of patent application is 03134445.3 Chinese patent, and short fiber reinforced metal-base composite materials product porous preform preparation method puts down in writing in number of patent application is 03134443.7 Chinese patent.
(2) preparation matrix alloy furnace charge
Prepare the matrix alloy furnace charge by following weight ratio:
Silicon 12%
Copper 1.2%
Magnesium 1.0%
Manganese 0.6%
Vanadium 0.15%
Aluminium adds to 100%
Above-mentioned matrix alloy furnace charge is to add a spot of V in the standard piston alloy proportion, can make the Fe that contains in the alloy still not be harmful needle-like up to 1% o'clock at impurity F e content, and formation Chinese character shape lumps α (AlFeSi) phase, this phase constitution has good heat resistance in 300～350 ℃ of intervals, helps strengthening the heat resistanceheat resistant load-bearing capacity of piston.Make impurity F e content in the piston alloy allow from the existing world≤0.7% extend the deadline≤1.0%, help preventing the mold sticking under the gentle high pouring temperature of high mould, prolonged the life-span of mould.
(3) melting matrix alloy
Melt the aluminium stove with packing into through whole body matrix alloy furnace charges of mechanic shot peening cleaning processing in advance, the upper surface of matrix alloy furnace charge covers the following aluminium alloy smelting coverture that accounts for matrix alloy furnace charge gross weight 3～5%:
Sodium chloride 50%
Potassium chloride 15%
Aluminium fluoric acid sodium 25%
Calcirm-fluoride 5%
Sodium fluoride 5%
Heat fused also is superheated to 800～900 ℃, realizes the abundant fusion of refractory element, is cooled to 780～810 ℃ of refining processing temperature.
(4) degasification is concise
Scratch clean the aluminium alloy smelting coverture on alloy melt surface, feed dry industrial one-level pure argon (Ar), alloy melt is carried out Argon degasification slagging-off refining processing, Argon pressure is 100～110mm mercury column, argon blowing time is 6～8 minutes, and concise temperature is 780～810 ℃, scratches clean scum silica frost, left standstill 5～6 minutes, and entered rotten treatment step.If the fusing of matrix alloy overheated with insulated pouring respectively in the heating furnace of two platform independent, the concise operating procedure of degasification should be carried out after the aluminum alloy melt metaideophone is gone into holding furnace and reached the predetermined processing temperature.
High temperature argon degasification refining can make fusion temperature, degasification temperature, deterroration, pouring temperature and the mold temperature of alloy all widen to higher direction, to adapt to the forming technology technical conditions requirement of composite material piston, does not damage the mechanical performance of piston again.
(5) the rotten processing
In alloy melt, add following matrix alloy charging weight percentage and be crushed to the ternary composite modifier (in the single element addition) of 5～10mm particle:
Be 0.015％
Ti 0.05％
Te 0.003％
In the said ratio, Be adds with the aluminium beryllium alloy, and wherein Be content is 5%, Ti adds with aluminum titanium alloy, wherein the content of Ti is 3%, and Te adds with monomer, and rotten treatment temperature is 780～800 ℃, be stirred to the ternary composite modifier all after the dissolving with graphite rod, left standstill 15～20 minutes, and fully stirred again subsequently, left standstill 5～10 minutes, remove scum silica frost, can pour into a mould.
Adopt above-mentioned rotten method and rotten material, can effectively keep the stable of content of magnesium in the piston alloy, obviously reduce the oxidation loss in its reflow process, make piston heat treatment reinforcement performance more stable.Can make the local aluminium piston that strengthens of metal-base composites of extrusion casint, in that single integral Al-alloy piston requires to have under higher melting and pouring temperature and the high mold temperature situation than common extrusion casint, obtain fine grained structure, high compactness and no inclusion defects.V in the matrix alloy furnace charge can effectively promote Be-Ti-Te modifying-refining effect, and the synergy of V and Be-Ti-Te can make the secondary dendrite spacing arm (DAS) of foundry goods more tiny, σ under slow cooled and solidified condition
hCan increase more than 20%, percentage elongation δ can increase more than 1 times.
(6) prepare mould
In the degasification of carrying out alloy melt and rotten treatment step, should make cast preceding coating and The pre-heat treatment to mould simultaneously.Former and drift with Piston mould is preheated to 120～150 ℃ earlier, and evenly spraying is less than the water base colloid graphite paint of the thick skim of 50 μ m with sprayer, and the preheat temperature of mould should be 350～400 ℃, to guarantee the good composite effect of composite material reinforcement body.
(7) casting of piston blank
At first the mold cavity corresponding site in preheating fixes the wild phase forward purchasing part that is preheated to 450～600 ℃, and pours into alloy melt in 1 minute thereafter.Pouring temperature range is 760～800 ℃.In 1 minute after pouring into alloy melt, by the speed decline mold and punching head of 0.5 meter per second, the matrix alloy melt in die cavity applies the pressure of 110～170Mpa, holds and presses for 10～30 seconds, the shaping of finishing piston blank with solidify.Pouring temperature is taken off limit, the squeeze pressure capping, and the pouring temperature capping, squeeze pressure takes off limit, and extrusion time is decided according to the piston thickest, the heavy section casting capping, thin-wall part takes off limit.After piston solidifies, open mould at once, eject foundry goods, sprayed coating carries out the cast of next blank again.
Embodiment 2
Present embodiment is prepared the matrix alloy furnace charge by following weight ratio in (2) preparation matrix alloy burden process step:
Silicon 11%
Copper 0.5%
Magnesium 0.4%
Manganese 0.2%
Vanadium 0.05%
Aluminium adds to 100%
In (5) rotten treatment process steps, in alloy melt, add the ternary composite modifier (in the single element addition) that following matrix alloy charging weight percentage is crushed to 5～10mm particle:
Be 0.013％
Ti 0.04％
Te 0.002％
Other processing step is identical with embodiment 1.
Embodiment 3
Present embodiment is prepared the matrix alloy furnace charge by following weight ratio in (2) preparation matrix alloy burden process step:
Silicon 13%
Copper 2.0%
Magnesium 1.4%
Manganese 0.9%
Vanadium 0.27%
Aluminium adds to 100%
In (5) rotten treatment process steps, in alloy melt, add the ternary composite modifier (in the single element addition) that following matrix alloy charging weight percentage is crushed to 5～10mm particle:
Be 0.016％
Ti 0.06％
Te 0.004％
Other processing step is identical with embodiment 1.
Embodiment 4
In the foregoing description 1～3, used manganese can be replaced with nickel in the matrix alloy charge composition, and its consumption is 1.5% of an alloy furnace charge.Other technical process is identical with embodiment 1.
Embodiment 5
In the foregoing description 1～3, used manganese can be replaced with nickel in the matrix alloy charge composition, and its consumption is 0.5% of an alloy furnace charge.Other technical process is identical with embodiment 1.
Embodiment 6
In the foregoing description 1～3, used manganese can be replaced with nickel in the matrix alloy charge composition, and its consumption is that the consumption of nickel is 3.0% of an alloy furnace charge.Other technical process is identical with embodiment 1.
Claims (6)
1, the local technology that strengthens the internal combustion engine blank of a kind of extrusion casting metal base composite is characterized in that this technology comprises the steps:
(1) makes the wild phase pre-member
Adopt local preparation method or the short fiber reinforced metal-base composite materials product porous preform preparation method who strengthens the product pre-member of metal-base composites wild phase pre-member preparation method or metal-base composites to make the wild phase pre-member;
(2) preparation matrix alloy furnace charge
Prepare the matrix alloy furnace charge by following weight ratio:
Silicon 11～13%
Copper 0.5～2.0%
Magnesium 0.4～1.4%
Manganese 0.2～0.9%
Vanadium 0.05～0.27%
Aluminium adds to 100%
(3) melting matrix alloy furnace charge
Melt the aluminium stove with packing into through whole matrix alloy furnace charges of mechanic shot peening cleaning processing in advance, the upper surface of matrix alloy furnace charge covers the following aluminium alloy smelting coverture that accounts for matrix alloy furnace charge gross weight 3～5%:
Sodium chloride 50%
Potassium chloride 15%
Aluminium fluoric acid sodium 25%
Calcirm-fluoride 5%
Sodium fluoride 5%
Heat fused also is superheated to 800～900 ℃, realizes the abundant fusion of refractory element, is cooled to 780～810 ℃ of refining processing temperature;
(4) degasification is concise
Scratch clean the aluminium alloy smelting coverture on alloy melt surface, feed dry industrial one-level pure argon (Ar), alloy melt is carried out Argon degasification slagging-off refining processing, Argon pressure is 100～110mm mercury column, argon blowing time is 6～8 minutes, and concise temperature is 780～810 ℃, scratches clean scum silica frost, left standstill 5～6 minutes, and entered rotten treatment step;
(5) the rotten processing
In alloy melt, add the ternary composite modifier (in the single element addition) that following matrix alloy charging weight percentage is crushed to 5～10mm particle:
Be 0.013～0.016％
Ti 0.04～0.06％
Te 0.002～0.004％
In the said ratio, Be adds with the aluminium beryllium alloy, and wherein Be content is 5%, Ti adds with aluminum titanium alloy, wherein the content of Ti is 3%, and Te adds with monomer, and rotten treatment temperature is 780～800 ℃, be stirred to the ternary composite modifier all after the dissolving with graphite rod, left standstill 15～20 minutes, and fully stirred again subsequently, left standstill 5～10 minutes, remove scum silica frost, can pour into a mould;
(6) prepare mould
In the degasification of carrying out alloy melt and rotten treatment step, should make cast preceding coating and The pre-heat treatment to mould simultaneously, former and drift with Piston mould is pre-ripe in 120～150 ℃ earlier, evenly spraying is less than the water base colloid graphite paint of the thick skim of 50 μ m with sprayer, and the preheat temperature of mould should be 350～400 ℃;
(7) casting of piston blank
At first the mold cavity corresponding site in preheating fixes the wild phase forward purchasing part that is preheated to 450～600 ℃, and in 1 minute thereafter, pour into alloy melt, pouring temperature range is 760～800 ℃, in 1 minute after pouring into alloy melt, speed decline mold and punching head by 0.5 meter per second, matrix alloy melt in die cavity applies the pressure of 110～170Mpa, holds and presses for 10～30 seconds, the shaping of finishing piston blank with solidify, pouring temperature is taken off limit, the squeeze pressure capping, the pouring temperature capping, squeeze pressure takes off limit, extrusion time is decided according to the piston thickest, the heavy section casting capping, thin-wall part takes off limit, after piston solidifies, at once open mould, eject foundry goods, sprayed coating carries out the cast of next blank again.
2, according to the local bad technology of internal combustion engine hair that strengthens of the described extrusion casting metal base composite of claim 1, it is characterized in that: in (2) preparation matrix alloy burden process step, wherein by following weight ratio preparation matrix alloy furnace charge:
Copper 1.0～1.5%
Magnesium 0.6～1.2%
Manganese 0.4～0.8%
Vanadium 0.10～0.2%.
3, according to the local technology that strengthens the internal combustion engine blank of the described extrusion casting metal base composite of claim 1, it is characterized in that: in (2) preparation matrix alloy burden process step, wherein by following weight ratio preparation matrix alloy furnace charge:
Silicon 12%
Copper 1.2%
Magnesium 1.0%
Manganese 0.6%
Vanadium 0.15%
In (5) rotten treatment process steps, wherein add following ternary composite modifier (in the single element addition):
Be 0.015％
Ti 0.05％
Te 0.003％。
4, the local bad technology of internal combustion engine fine hair alive that strengthens of a kind of extrusion casting metal base composite is characterized in that this technology comprises the steps:
(1) makes the wild phase pre-member
Adopt local preparation method or the short fiber reinforced metal-base composite materials product porous preform preparation method who strengthens the product pre-member of metal-base composites wild phase pre-member preparation method or metal-base composites to make the wild phase pre-member;
(2) preparation matrix alloy furnace charge
Close by following weight ratio preparation matrix
Silicon 11～13%
Copper 0.5～2.0%
Magnesium 0.4～1.4%
Nickel 0.5～3.0%
Vanadium 0.05～0.27%
Aluminium adds to 100%
(3) melting matrix alloy furnace charge
Melt the aluminium stove with packing into through whole matrix alloy furnace charges of mechanic shot peening cleaning processing in advance, the upper surface of matrix alloy furnace charge covers the following aluminium alloy smelting coverture that accounts for matrix alloy furnace charge gross weight 3～5%:
Sodium chloride 50%
Potassium chloride 15%
Aluminium fluoric acid sodium 25%
Calcirm-fluoride 5%
Sodium fluoride 5%
Heat fused also is superheated to 800～900 ℃, realizes the abundant fusion of refractory element, is cooled to 780～810 ℃ of refining processing temperature;
(4) degasification is concise
Scratch clean the aluminium alloy smelting coverture on alloy melt surface, feed dry industrial one-level pure argon (Ar), alloy melt is carried out Argon degasification slagging-off refining processing, Argon pressure is 100～110mm mercury column, argon blowing time is 6～8 minutes, and concise temperature is 780～810 ℃, scratches clean scum silica frost, left standstill 5～6 minutes, and entered rotten treatment step;
(5) the rotten processing
In alloy melt, add the ternary composite modifier (in the single element addition) that following matrix alloy charging weight percentage is crushed to 5～10mm particle:
Be 0.013～0.016％
Ti 0.04～0.06％
Te 0.002～0.004％
In the said ratio, Be adds with the aluminium beryllium alloy, and wherein Be content is 5%, Ti adds with aluminum titanium alloy, wherein the content of Ti is 3%, and Te adds with monomer, and rotten treatment temperature is 780～800 ℃, be stirred to the ternary composite modifier all after the dissolving with graphite rod, left standstill 15～20 minutes, and fully stirred again subsequently, left standstill 5～10 minutes, remove scum silica frost, can pour into a mould;
(6) prepare mould
In the degasification of carrying out alloy melt and rotten treatment step, should make cast preceding coating and The pre-heat treatment to mould simultaneously, former and drift with Piston mould is pre-ripe in 120～150 ℃ earlier, evenly spraying is less than the water base colloid graphite paint of the thick skim of 50 μ m with sprayer, and the preheat temperature of mould should be 350～400 ℃;
(7) casting of piston blank
At first the mold cavity corresponding site in preheating fixes the wild phase forward purchasing part that is preheated to 450～600 ℃, and in 1 minute thereafter, pour into alloy melt, pouring temperature range is 760～800 ℃, in 1 minute after pouring into alloy melt, speed decline mold and punching head by 0.5 meter per second, matrix alloy melt in die cavity applies the pressure of 110～170Mpa, holds and presses for 10～30 seconds, the shaping of finishing piston blank with solidify, pouring temperature is taken off limit, the squeeze pressure capping, the pouring temperature capping, squeeze pressure takes off limit, extrusion time is decided according to the piston thickest, the heavy section casting capping, thin-wall part takes off limit, after piston solidifies, at once open mould, eject foundry goods, sprayed coating carries out the cast of next blank again.
5, according to the local technology that strengthens the internal combustion engine blank of the described extrusion casting metal base composite of claim 4, it is characterized in that: in (2) preparation matrix alloy burden process step, wherein by following weight ratio preparation matrix alloy furnace charge:
Copper 1.0～1.5%
Magnesium 0.6～1.2%
Nickel 1.0～2.0%
Vanadium 0.10～0.2%.
6, according to the local bad technology of internal combustion engine hair that strengthens of the described extrusion casting metal base composite of claim 4, it is characterized in that: in (2) preparation matrix alloy burden process step, wherein by following weight ratio preparation matrix alloy furnace charge:
Silicon 12%
Copper 1.2%
Magnesium 1.0%
Nickel 1.5%
Vanadium 0.15%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03134491 CN1278802C (en) | 2003-08-14 | 2003-08-14 | Process for extrusion casting piston blank of internal combustion engine with local feinforcing of metal base composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03134491 CN1278802C (en) | 2003-08-14 | 2003-08-14 | Process for extrusion casting piston blank of internal combustion engine with local feinforcing of metal base composite material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1488458A CN1488458A (en) | 2004-04-14 |
| CN1278802C true CN1278802C (en) | 2006-10-11 |
Family
ID=34154509
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03134491 Expired - Fee Related CN1278802C (en) | 2003-08-14 | 2003-08-14 | Process for extrusion casting piston blank of internal combustion engine with local feinforcing of metal base composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1278802C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102943192A (en) * | 2012-10-29 | 2013-02-27 | 中国兵器工业第五二研究所 | Aluminum piston manufacturing method |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100341640C (en) * | 2004-06-13 | 2007-10-10 | 李华伦 | Magnesium alloy lean liquid semi-solid impact extruding shaping technology |
| CN100340686C (en) * | 2005-09-12 | 2007-10-03 | 华南理工大学 | Directly extrusion cast high strength aluminium alloy |
| CN100347322C (en) * | 2005-09-12 | 2007-11-07 | 华南理工大学 | Extrusion cast aluminium alloy material with high strength and toughness |
| CN100423872C (en) * | 2006-11-16 | 2008-10-08 | 上海交通大学 | Extrusion casting preparation method for aluminium alloy automobile engine bracket |
| CN101538667B (en) * | 2008-08-29 | 2011-06-01 | 中山市三丰金属锻造有限公司 | High-strength and wear-resistant cocrystallized Al-Si alloy forging stock material and preparation method thereof |
| JP5848259B2 (en) * | 2010-12-22 | 2016-01-27 | 昭和電工株式会社 | Manufacturing method of brake piston shape material |
| CN103722154B (en) * | 2014-01-20 | 2016-03-30 | 滨州东海龙活塞有限公司 | By the method that copper sheathing becomes to be integrated with casting for piston |
| CN104942261A (en) * | 2014-03-25 | 2015-09-30 | 苏州慧驰轻合金精密成型科技有限公司 | Novel piston extrusion casting machine |
| CN106238708A (en) * | 2016-08-23 | 2016-12-21 | 张家港华日法兰有限公司 | A kind of anti-fracture flange production method |
| CN106271314A (en) * | 2016-08-31 | 2017-01-04 | 南京惠德机械有限公司 | A kind of high intensity fixture |
| CN108015259A (en) * | 2016-11-14 | 2018-05-11 | 江苏兄弟活塞有限公司 | A kind of inlay casting method of aluminum-based in-situ composite materials piston |
| CN107243616B (en) * | 2017-06-23 | 2019-03-01 | 重庆环鹰机械有限公司 | A kind of IC engine link rod liquid forging preparation process |
| CN111136242B (en) * | 2018-11-06 | 2022-04-08 | 有研金属复材技术有限公司 | Preparation method of heterogeneous multifunctional metal-based composite casting |
-
2003
- 2003-08-14 CN CN 03134491 patent/CN1278802C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102943192A (en) * | 2012-10-29 | 2013-02-27 | 中国兵器工业第五二研究所 | Aluminum piston manufacturing method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1488458A (en) | 2004-04-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1278802C (en) | Process for extrusion casting piston blank of internal combustion engine with local feinforcing of metal base composite material | |
| CN101078080A (en) | Creep resistance magnesium alloy and preparation method thereof | |
| CN101722288B (en) | Method for preparing local particle reinforced aluminum alloy cylinder sleeve by semi-solid casting technology | |
| CN101569926B (en) | Method for casting aluminum piston with insert ring and cooling coil pipe | |
| CN109175350A (en) | A kind of Al-Mg-Mn-Sc-Zr Al alloy powder and preparation method thereof for increasing material manufacturing | |
| CN1699612A (en) | High strength and high toughness cast magnesium alloy and preparing process thereof | |
| CN1943962A (en) | High strength aluminum alloy welding wire and its preparing method | |
| CN103846409B (en) | A kind of preparation method of the fibre reinforced composites piston peculiar to vessel with cooling oil chamber | |
| CN101538667B (en) | High-strength and wear-resistant cocrystallized Al-Si alloy forging stock material and preparation method thereof | |
| CN102943192A (en) | Aluminum piston manufacturing method | |
| CN104532036B (en) | A kind of preparation method adopting automobile waste aluminum component regeneration extrusion casint dedicated aluminium alloy | |
| CN108203780A (en) | A kind of liquid forging high-strength abrasion-proof aluminum alloy and preparation method thereof | |
| CN106636797A (en) | Squeeze casting preparation method for magnalium automobile engine support | |
| CN1529763A (en) | Aluminium allloy for casting/forging, aluminium alloy cast/forged product and producing methods | |
| CN112226655B (en) | Composite aluminum alloy wheel and manufacturing method thereof | |
| CN1173053C (en) | Copper-based alloy and method for producing cast and forge piece therefrom | |
| CN1314825C (en) | Brake facing made of magnesium borate crystal whisker and ceramic particle reinforced aluminium base composite material and its preparation process | |
| CN102366827B (en) | Extrusion casting method of cylinder cover cap of magnesium alloy automobile engine | |
| CN107937764A (en) | A kind of high tough aluminium alloy of liquid forging and its liquid forging method | |
| CN101446243B (en) | Piston made of Al/Si-Mg*Si composite material and preparation method thereof | |
| CN1557985A (en) | Modified hot-work die steel | |
| CN100371486C (en) | Magnesium alloy in high toughness, high intensity, and prepartion method | |
| CN1619003A (en) | High strength casted aluminium silicon series alloy and its preparation method | |
| CN104060183B (en) | A kind of oscillating arm bracket and production method thereof | |
| CN1215088A (en) | Composite crystal grain fining agent for aluminium and aluminium alloy and preparation process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20061011 Termination date: 20100814 |