CN1275901A - Hair styling compositions comprising anionic optical brighteners - Google Patents
Hair styling compositions comprising anionic optical brighteners Download PDFInfo
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- CN1275901A CN1275901A CN 97182434 CN97182434A CN1275901A CN 1275901 A CN1275901 A CN 1275901A CN 97182434 CN97182434 CN 97182434 CN 97182434 A CN97182434 A CN 97182434A CN 1275901 A CN1275901 A CN 1275901A
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Abstract
Disclosed is a hair styling composition comprising: an effective amount of an anionic optical brightener; a fixative polymer selected fro mthe group consisting of an amphoteric fixative polymer, an anionic fixative polymer, a nonionic fixative polymer, a silicone grafted copolymer, and mixtures thereof; wherein the 3% aqueous solution of the fixative polymer provides a viscosity of no more than about 2,000 cps; and a carrier.
Description
Invention field
The present invention relates to a kind of Haircare composition and comprise the fluorescent whitening agent that changes hair color, it can increase the gloss of hair simultaneously, and the protection hair is avoided further injury.More specifically, the present invention relates to a kind of compositions hair fixing of the styling polymer that comprises anionic optical brighteners and select.
Background of invention
People wish to recover the natural colour and the gloss of damaged hair always, wish that also the color that can change hair makes it more be rich in appeal.The hair outward appearance of consumer's sensation damaged is bad, and is difficult for combing.This indecency outward appearance comprises original hair color change and fades that gloss weakens.
Alleviating the indecency outward appearance of damaged hair and making it have the conventional route that is rich in appeal is that hair is dyed desirable color.Hair dyeed to make consumer in a period of time relatively, have stable hair color.But hair dyeing is a thing consuming time, as to bother and take a lot of trouble normally.Dyestuff also can cause chemical damage to hair, scalp and skin.The further damage that hair may be had hair dyed.Therefore, hair dyeing product and be not suitable for daily use.And then hair dyeing also may make hair seem that outward appearance is stiff, more makes hair seem to lack gloss.
Based on above-mentioned described, people need always a kind of can daily use and can change hair color, and can strengthen the gloss of hair and the hair composition that the protection hair is avoided further loss simultaneously.
In the prior art in the hair care field the known chemical compound that adopts fluorescent whitening agent or be referred to as fluorescent whitening agent, brightener or fluorescent dye, as described in the following document, US3,658,985, US4,312,855, CA1,255,603, US3,577,528, GB1,328,108, south african patent application 676,049, Europe disclose 87,060 and GB2,307,639.
The hair fixing copolymer that has different charge types is known to be can be used for reaching and keep required hair style is known.But, when charged fluorescent whitening agent in liquid medium when having the hair fixing copolymer of opposite charges, it has formed insoluble complex, can bring incompatibility and/or unstability in prescription so again.Therefore, there is requirement that a kind of hair setting composition that comprises charged fluorescent whitening agent is provided.
In the prior art and fail to provide all advantages of the present invention and effect.
Summary of the invention
The present invention relates to a kind of hair setting composition, comprise: (a) anionic optical brighteners of effective dose, (b) styling polymer is selected from both sexes styling polymer, anionic shaped polymer, nonionic styling polymer, polysiloxane grafted copolymer and their mixture; Wherein the viscosity that provides of 3% aqueous solution of styling polymer is no more than about 2000 centipoises; (c) carrier.
After above-mentioned and its feature, aspect and advantage of the present invention will specifically disclose below having read will be more obvious.
Detailed Description Of The Invention
In description and claims are specifically noted and clear limit the while of the present invention, it is believed that the present invention can understand better by following explanation.
Except as otherwise noted, all percentage number averages are that benchmark calculates with the total composition weight.Except as otherwise noted, all ratios are part by weight.Except as otherwise noted, all percent, ratio and component content do not comprise that all based on the actual content of composition solvent, filler or various component are purchased bonded material in the product.
Among the present invention, " comprising " is meant and can adds other step and other composition that can not influence the termination fruit.This term has comprised term " composition " and " basic composition ".
The document of all references all is incorporated herein by reference.Any document of quoting is not to allow the existing content of prior art to enter in the claimed technical scheme of the present invention.
Fluorescent whitening agent
Fluorescent whitening agent is that some can absorb ultraviolet light and again with the chemical compound of VISIBLE LIGHT EMISSION energy.Particularly, the fluorescent whitening agent that adopts among the present invention has absorption in the wavelength of about 1nm-420nm, is preferably main absorption peak, in the wavelength of about 360nm-830nm emission is arranged, and is preferably main emission peak; Wherein, main absorption peak is shorter than the wavelength of main emission peak.More preferably, the main absorption peak of fluorescent whitening agent of the present invention is between about 200nm-420nm wavelength, and main emission peak is between about 400nm-780nm wavelength.Fluorescent whitening agent can have or not have less important absworption peak in visible wavelength range (about 360nm-830nm).Fluorescent whitening agent (Optical brightener) is described in prior art and industrial available some other title, as fluorescent whitening agent (fluorescent whitening agents), brightener (fluorescent brighteners) and fluorescent dye (fluorescent dyes).
When adopting suitable carriers to be coated on the hair fluorescent whitening agent of the present invention, fluorescent whitening agent of the present invention can provide useful effect to hair aspect three.At first, fluorescent whitening agent can change the color of hair by the light of visible emitting scope.Secondly, fluorescent whitening agent can strengthen the gloss of hair by the light of visible emitting scope.The 3rd, fluorescent whitening agent also can protect hair to avoid absorbing the ultraviolet light damage that ultraviolet light causes.
Fluorescent whitening agent is normally based on the structure of aromatics and heteroaromatic system, and this structure provides unique feature.Fluorescent whitening agent can be classified according to its charged type.Those that to be used for anionic optical brighteners of the present invention be electronegative polar group.Four class ionic groups can be used in the anionic optical brighteners: carboxylate radical, sulfate radical, sulfonate radical and phosphate radical.Anionic optical brighteners can also be classified according to their basic structure, and this will hereinafter be described.Be preferred for anionic optical brighteners of the present invention and comprise polystyrene-based stilbene (polystyryl stilbene), triazine radical stilbene, coumarin, triazole and pyrazoline.
Preferably, the content of anionic optical brighteners of the present invention in Haircare composition is about 0.001% to about 20%, more preferably from about 0.01% to about 10%.
Polystyrene-based stilbene
Polystyrene-based stilbene is the chemical compound that a class has two or more following basic structures:
The polystyrene-based stilbene that is used for the present invention comprises those with following formula (1):
Wherein, R
101Be H, OH, SO
3M, COOM, OSO
3M, OPO (OH) OM, wherein M is H, Na, K, Ca, Mg, ammonium, single-, two-, three-or four-C
1-C
30Alkylammonium, single-, two-or three-C
1-C
30Hydroxy alkyl ammonium or use C
1-C
30-alkyl and C
1-C
30The mixture two of-hydroxyalkyl or trisubstituted ammonium; Perhaps SO
2N (C
1-C
30-alkyl)
2, O-(C
1-C
30-alkyl), CN, Cl, COO (C
1-C
30-alkyl), CON (C
1-C
30-alkyl)
2Or the alkyl of CN or 1-30 carbon atom, R
102And R
103Be SO independently of one another
3M, COOM, OSO
3M, OPO (OH) OM, wherein, M such as preceding definition; X is 0 or 1; Wherein, this chemical compound has trans coplane or cis coplane orientation; Preferred x is 1, R
101Be SO
3Na, R
102And R
103Be H; Wherein, this chemical compound has trans coplane orientation.
Suitable polystyrene-based stilbene comprises: disodium-1, and two (the 2-sulfo group styryl) biphenyl (C.I. fluorescent whitening agent 351) of 4-, trade name Tinopal CBS-X is purchased the SpecialtyChemicals from Ciba.
The triazine radical stilbene
The triazine radical stilbene is a class has triazine and stilbene structure simultaneously in a part a chemical compound.
The triazine radical stilbene that is used for the present invention comprises have following formula those chemical compounds of (2):
Wherein, R
104And R
105Be independently of one another-OCH
3Or-Cl; And An
-Be anion: carboxylate radical, sulfate radical, sulfonate radical or phosphate radical; M as previously mentioned, wherein chemical compound has trans copline orientation or cis copline orientation; Preferred compound has trans copline orientation;
Coumarin
Coumarin is the chemical compound that a class has the following formula structure:
Be used for coumarin of the present invention and comprise have following formula those of (3):
R wherein
201Be (CH
2)
1-4COOM, (CH
2)
1-4SO
3M, (CH
2)
1-4OSO
3M, (CH
2)
1-4OPO (OH) OM, wherein M is described as defined above; R
202Be H, phenyl, COO-C
1-C
30-alkyl, glucose, R
203Be OH or O-C
1-C
30-alkyl, R
204Be OH or O-C
1-C
30-alkyl, glycosides.
Triazole
Triazole is the chemical compound that a class has following basic structure:
The triazole that is used for the present invention comprises the have following formula chemical compound of (4) and (5):
Wherein, R
301Be H or chlorine; R
302Be SO
3M, COOM, OSO
3M, OPO (OH) OM; R
303Be H or SO
3M; M such as preceding definition, wherein, this chemical compound has trans coplane or cis coplane orientation; Preferred R
301And R
303Be H, and R
302Be SO
3M, wherein M is a sodium; Wherein, this chemical compound has trans coplane orientation;
Wherein, R
304And R
310In each represent SO independently
3M, COOM, OSO
3M, OPO (OH) OM, wherein M is identical with aforementioned definitions, R
305And R
311In each represent H independently, sulfonic acid group or its salt, ester or amide, hydroxy-acid group or its its salt, ester or amide, cyano group, halogen atom, the alkyl or the alkoxyl that do not replace or replace, perhaps and R
304And R
310Represent methylene dioxy, ethylidene dioxy, the inferior methoxyl group of inferior methoxyl group, trimethylene, tetramethylene, allylidene, butenylidene or Aden's dialkylene together, R
306And R
312In each represent H, halogen atom or alkyl unsubstituted or that replace, R independently
307And R
309In each represent H, halogen atom or cyano group, sulfonic acid group or its salt, ester or amide independently, hydroxy-acid group or its salt, ester or amide, and R
308Represent H, halogen atom or cyano group, sulfonic acid group or its salt, alkyl group [alkyl that is preferably partly had carbalkoxy, phenyl or the phenoxy group replacement of 1-30 carbon atom] independently by hydroxyl, the alkoxyl of a 1-30 carbon atom, cyano group, halogen, carboxyl, sulfonic acid group, alkoxyl; Alkoxyl can partly be had carbalkoxy (carbalkoxy), phenyl or the phenoxy group replacement of 1-30 carbon atom by hydroxyl, the alkoxyl of a 1-30 carbon atom, cyano group, halogen, carboxyl, alkoxyl; Phenyl, phenylalkyl or phenoxy group, they can partly be had alkoxy carbonyl group, the sulfo group of 1-30 carbon atom by halogen, cyano group, carboxyl, alkoxyl or have the alkyl or the alkoxyl replacement of 1-30 carbon atom; Wherein this chemical compound has trans coplane or cis coplane orientation; Possible cycloalkyl preferably can be had the cyclohexyl and the cyclopenta of the alkyl replacement of 1-30 carbon atom; Possible five-ring heterocycles is v-triazole, oxazole or 1,3, the 4-oxadiazole, and it can contain substituent group C
1-C
4Alkyl, halogen, phenyl, carboxyl, alkoxyl partly have alkoxy carbonyl group, cyano group, the benzyl of 1-30 carbon atom, C
1-C
30Alkoxyl, phenoxy group or sulfo group, two adjacent substituent groups of triazole and azoles group can form and replace or unsubstituted fused benzene rings; Wherein chemical compound has trans coplane orientation.
Suitable triazole comprises 2-(4-styryl-3-sulfo group phenyl)-2H-naphtho-[1,2-d] triazole (C.I.Fluorescent Brightener 46), and commodity are called Tinopal RBS, derive from Ciba SpecialtyChemicals.
Pyrazoline
Pyrazoline is the chemical compound that a class has following basic structure:
The pyrazoline that is used for the present invention comprises have following formula those of (6) and (7):
Wherein, R
401Be H or Cl, R
402Be SO
3M, COOM, OSO
3M, OPO (OH) OM, R
403With R
404Can be identical or different, each is respectively H, C
1-C
30Alkyl or phenyl, R
405Be H or Cl; M defines as described above, preferred R
401Be Cl, R
402Be SO
3M, wherein M defines as described above, R
403, R
404And R
405Be respectively H; With
Suitable pyrazoline comprises 1-[4-(2-sulfo group ethylsulfonyl) phenyl]-3-(4-chlorphenyl)-2-pyrazoline, 1-[4-(2-sulfo group ethylsulfonyl) phenyl]-3-(3,4-two chloro-6-aminomethyl phenyls)-2-pyrazoline.
Styling polymer
Be used for styling polymer of the present invention and be providing those of styling, be selected from both sexes styling polymer, anionic shaped polymer, nonionic styling polymer, silicone grafted copolymer and their mixture to hair.Styling polymer in this joint and following conditioner polymer and the difference of thickening polymer are that they have film property, and 3% the viscosity that is used for styling polymer aqueous solution of the present invention and is provided should be no more than about 2,000 centipoises.
Anionic optical brighteners of the present invention is by on the surface that is deposited on hair and bring benefit to hair.Usually Hairstyling composition is the liquid base.Therefore, wish that the prescription that comprises anionic optical brighteners is sent to anionic optical brighteners on the hair effectively in liquid medium.When anionic optical brighteners and cationic styling polymers mixing, may form insoluble complex, perhaps in prescription, produce the compatibility and/or instability problem.By selecting styling polymer, can obtain to transmit effectively the Hairstyling composition that anionic optical brighteners provides good styling from both sexes styling polymer, anionic shaped polymer, nonionic styling polymer, silicone grafted copolymer and their mixture.
The known shortcoming that the styling polymer combination can be increased benefit and/or reduce the styling polymer after making up in this area.Preferred styling polymer combination of the present invention comprises the combination of combination, both sexes styling polymer and the anionic shaped polymer of the both sexes styling polymer of Radix Betae alkalization and the both sexes styling polymer that non-Radix Betae alkalizes.When the combination of the both sexes styling polymer of the both sexes styling polymer of selecting betaninization and the alkalization of non-Radix Betae, use or do not use propellant can obtain having the mousse product of good foaming feature.The amount of the volatile solvent that this mousse product comprises in compositions usually is no more than about 30%.
The content of styling polymer is about 0.01% to about 10% weight, in the weight of compositions.When using two or more styling polymers, total amount preferably is no more than about 10% of composition weight; More preferably, every kind of styling polymer is no more than about 5% of composition weight.The both sexes styling polymer
Be used for both sexes styling polymer of the present invention and comprise as shown in the formula (1) and (2) described Radix Betae alkalization both sexes styling polymer, and the both sexes styling polymer of following formula (3) and (4) described not Radix Betae alkalization.
Radix Betae alkalization both sexes styling polymer
What (1) adopt among the present invention is dialkyl aminoalkyl (methyl) acrylates or dialkyl aminoalkyl (methyl) acrylamide of Radix Betae alkalization, and they comprise unit of following formula at least:
Wherein, R
1Expression hydrogen atom or methyl, R
2Expression has the alkylidene of 1-4 carbon atom, Y represent O or-NH-, R
3And R
4Represent hydrogen independently of one another or have the alkyl of 1-4 carbon atom, with a cationic derivative, it is by comprising at least one nitrogen-atoms that is connected with one or more aliphatic chains and optionally being formed by quaternised cationic surfactant, or forms by the cationic polymer of polyamines, poly-amino polyamide or poly--(quaternary ammonium) type, the part of amine or ammonium group formation polymer chain or be attached thereto connects.The molecular weight of these polymer is generally 500 to 2,000,000.
Comprise corresponding to the unitary amphiphilic polymers of following formula (I) and be generally the copolymer form, it also comprises unit of following formula at least except that the unit that comprises above-mentioned formula (I):
Wherein, R
1Definition as described above, R
5Expression has the alkyl or the alkenyl of 4-24 carbon atom, or has the cycloalkyl of 4-24 carbon atom.
Also can adopt terpolymer, quadripolymer or five-membered copolymer, they except that comprise unit (I) and (II), also comprise unit of following formula:
Wherein, R
6The alkyl or the alkenyl of preferred 1-3 carbon atom; R
1As preceding definition.
In total polymer weight, the unitary content of formula (I) is preferably 25-45% weight, and the unitary content of formula (II) is preferably 5-65% weight, and the unitary content of formula (III) is preferably 50% weight.
Particularly preferred polymer is for to comprise formula (I), (II) and copolymer (III), and wherein, Y represents oxygen atom, R
2Expression group-C
2H
4-, R
1, R
3And R
4The expression methyl, R
5Expression has the alkyl of 4-18 carbon atom, R
6Expression has the alkyl of 1-3 carbon atom.The mean molecule quantity of polymer is preferably 50,000 to 100,000.This polymer is purchased by Mitsubishi Chemical Corporation with trade name " Yukaforrner " or " Diaformer ".
(2) polymer that contains the unitary Radix Betae alkalization of amphion that usefully derives among the present invention by following formula:
Wherein, R
1Represent polymerisable unsaturated group, as acrylic acid, methacrylic acid, acrylamide or methacryl amine groups, x and y represent 1 to 3 integer, R independently of one another
2And R
3Represent hydrogen, methyl, ethyl or propyl group independently of one another, R
4And R
5Represent hydrogen or alkyl independently of one another, make R
4And R
5Total carbon atom number be no more than 10.
The amphiphilic polymers of particularly preferred Radix Betae alkalization comprises the following material that is purchased: for example, YUKAFORMER SM, YUKAFORMER FH, YUKAFORMER 301, YUKAFORMER 204WL, YUKAFORMER 510, YUKAFORMER M-75, YUKAFORMER R250S, Diaforrner Z-SM and Diaformer Z-W all are purchased the Corporation from Mitsubishi Chemical.
The both sexes styling polymer of Radix Betae alkalization not
What (3) adopt among the present invention is the amphiphilic polymers of not Radix Betae alkalization, this polymer is formed as acrylic acid, methacrylic acid, maleic acid, itaconic acid, fumaric acid .beta.-methylacrylic acid or α-Lv Bingxisuan and a kind of alkaline monomer copolymerization by the vinyl monomer that has at least one carboxyl, described alkaline monomer is the vinyl compound that comprises the replacement of at least one basic nitrogen atom, for example is methacrylic acid and acrylic acid dialkyl aminoalkyl ester and dialkyl aminoalkyl Methacrylamide and acrylamide.
What (4) adopt among the present invention is the amphiphilic polymers that comprises by the following monomeric not Radix Betae alkalization that obtains:
I) at least a monomer that is selected from acrylamide or Methacrylamide is replaced by alkyl on nitrogen-atoms,
Ii) at least a acidic comonomer, its comprise one or more pendant carboxylic groups and
The alkaline comonomer of iii) at least a acrylic acid and methacrylic acid, as ester, it has primary, the second month in a season and tertiary amine substituent group and quaternary ammonium-substituted base, and this product is from the quaterisation of dimethylaminoethyl methacrylate and dimethyl sulfate or dithyl sulfate.
Acrylamide that most preferred N-replaces or Methacrylamide comprise those of 2-12 carbon atom, particularly N-ethyl acrylamide, N tert butyl acrylamide, uncle's N-octyl acrylamide, N-octyl acrylamide, N-decyl acrylamide and N-dodecyl acrylamide and Methacrylamide accordingly for alkyl wherein.Acidic comonomer mainly is selected from acrylic acid, methacrylic acid, itaconic acid, maleic acid and fumaric acid, and alkyl has the maleic acid of 1-4 carbon atom or the alkyl monoester of fumaric acid.
The amino ethyl ester that preferred alkaline comonomer is a methacrylic acid, butyl amino ethyl ester, N, N '-dimethylamino ethyl ester and N-tert-butyl group amino ethyl ester.
The amphiphilic polymers of particularly preferred not Radix Betae alkalization comprises following commercially available material: for example, octyl group acrylic amine/acrylate/metering system acid butyl amino ethyl ester copolymer, its commodity are called AMPHOMER, AMPHOMER SH701, AMPHOMER 28-4910, AMPHOMER LV71 and AMPHOMER LV47, all are purchased the Starch from National; Chemical.
Anionic shaped polymer
Be used for anionic shaped polymer of the present invention and comprise that those contain the unit and the molecular weight that are obtained by carboxylic acid, sulfonic acid or phosphoric acid and are generally 500 to 5,000,000 polymer.These polymer are water-soluble polymer, and this dissolubility can obtain by neutralization.
Hydroxy-acid group can be provided by unsaturated monocarboxylic acid or dicarboxylic acids, as corresponding to those of following formula:
Wherein, n is 0 or 1 to 10 integer, and A represents optionally to be connected to the methylene on the carbon atom of saturated group, perhaps at n greater than 1 o'clock, link to each other R through hetero atom such as oxygen or sulfur with adjacent methylene group
1Expression hydrogen atom or phenyl or benzyl, R
2Expression hydrogen atom, low alkyl group or carboxyl and R
3Expression hydrogen atom, low alkyl group, CH
2COOH or phenyl or benzyl.
According to the present invention, the preferred polymer that comprises hydroxy-acid group is:
(1) homopolymer or the copolymer of acrylic or methacrylic acid or its salt, particularly following commercially available prod, trade name VERSICOL E or K and UL TRAHOLD are purchased from BASF; Trade name DARVAN No.7 is purchased the Bilt from Van der; The acrylic acid copolymer is sold with its sodium salt, and trade name RETEN 421,423 or 425, are purchased from HERCULES; With multi-hydroxy carboxy acid's sodium salt, trade name HYDAGENF is purchased from HENKEL.
(2) acrylic or methacrylic acid and single ethylene belong to the copolymer of monomer such as ethylene, styrene, vinyl or allyl ester or acrylate or methacrylate, randomly are grafted on poly-diakyl glycol such as the Polyethylene Glycol, and optionally carry out crosslinked.Other this analog copolymer comprises a kind of optionally N-alkylation and/or N-hydroxylating acrylamide monomer in its chain, as with trade name QUADRAMER 5, and those that sell by American Cyanamid.
(3) copolymer that obtains by .beta.-methylacrylic acid, in its chain, comprise vinylacetate or vinyl propionate monomers and optionally pi-allyl or methylallyl ester, vinyl ethers or the vinyl esters of other monomer such as saturated straight chain or branched carboxylic acids as those, hydrocarbon chain length is at least 5 carbon atoms, in the time of suitably, those by grafting and crosslinked polymer, are also comprised α-or vinyl esters, allyl ester or the methylallyl ester of β-cyclic carboxylic acids.The copolymer that comprises at this apoplexy due to endogenous wind comprises trade name RESYN 28-2930,28-2913 and 28-1310, by National Starch; Those that Chemicals sells.
(4) polymer that obtains by maleic acid, fumaric acid and itaconic acid or anhydride and vinyl esters, vinyl ethers, vinyl halide, phenyl vinyl derivant, acrylic acid and its ester, those as selling by ISP with trade name GANTREZ A, SP and ES.Other polymer that is included in this apoplexy due to endogenous wind is the copolymer of maleic anhydride, citraconic anhydride and itaconic anhydride and pi-allyl or methallyl ethers, in its chain, optionally comprise acrylamido or methacrylamido, or have alpha-olefin, acrylic or methacrylic acid esters, acrylic or methacrylic acid or vinyl pyrrolidone unit; Anhydride group can be by mono-esterification or monoamidesization.
(5) comprise the polyacrylamide of carboxylate group.The polymer that comprises sulfonic acid group comprises and contains vinyl sulfonic acid base, styryl sulfonic group, sulfomethylated lignin acidic group or the unitary polymer of LOMAR PWA EINECS 246-676-2 base.These polymer specifically are selected from:
I) molecular weight is 1,000 to 100,000 polyvinylsulfonic acid salt, and with the copolymer of unsaturated comonomer, described comonomer such as acrylic or methacrylic acid or its ester and replacement or unsubstituted acrylamide or Methacrylamide, vinyl esters, vinyl ethers and vinyl pyrrolidone.
Ii) poly styrene sulfonate is as by National Starch ﹠amp; Chemicals is with trade name Flexan500 and 130 sodium salts of selling.
Iii) alkali metal or alkali salt, particularly Lignosite or the sodium of the sulfonic acid that is obtained by lignin are as product of being sold by American Can Co. with trade name Marasperse C-21 and the C that is sold by Avebene
10To C
14Product.
Iv) comprise the unitary polymer of salifiable alkyl naphthalene sulfonic acid, as with trade name Darvan No.1, the sodium salt of selling by Van der Bilt.
Be the shampoo property removed that helps the liquid cosmetic composition for hair, preferably so that the neutral form of small part is used the anion hair styling polymer of the present invention that comprises anionic monomer.In said composition, the neutralization of polymer can be adopted inorganic base, and preferred potassium hydroxide carries out.But, also can use organic base, the mixture of preferred AMP (amino methyl propanol) and inorganic base and organic base is to reach the degree of neutralization of required hair setting composition.In a word, about 50 to about 100%, and preferred about 70% to about 100%, and more preferably from about the acid monomer of 80% to 100% the polymer that adopts application alkali neutralizes.
Any conventional alkali that adopts comprise organic base or inorganic base all can be used in and acidic polymer, as long as they use according to regulation of the present invention.The hydroxide of alkali metal, alkaline-earth metal and amino alcohol are the nertralizers that suits.
The example that is included in organic neutralizer suitable in the present composition comprises: amine, amino alcohol particularly, as 2-amino-2-methyl-1, ammediol (AMPD), 2-amine-2-ethyl-1, ammediol (AEPD), 2-amino-2-methyl-1-propanol (AMP), 2-amino-1-butanols (AB), monoethanolamine (MEA), diethanolamine (DEA), triethanolamine (TEA), an isopropanolamine (MIPA), diisopropanolamine (DIPA) (DIPA), triisopropanolamine (TIPA), dimethyl stearylamine (DMS) and amino methyl propanol (AMP) and its mixture.
The nertralizer that is preferred in the Haircare composition of the present invention is potassium hydroxide and sodium hydroxide.
Particularly preferred anionic shaped polymer comprises the commercially available material, as vinylacetate/.beta.-methylacrylic acid/neodecanoic acid vinyl ester copolymer, its commodity are called RESYN 28-2930, RESYN 28-2913 and RESYN 28-1310 is purchased the Starch from National; Chemicals and acrylate copolymer and acrylate/acrylamide copolymer, trade name LUVIMER 100P, ULTRAHOLD 8 and ULTRAHOLD STRONG are purchased the Corporation from BASF.
The nonionic styling polymer
The homopolymer that to be used for nonionic styling polymer of the present invention be vinyl pyrrolidone or caprolactam or the copolymer of vinyl pyrrolidone and vinylacetate are as the trade name LUVISKOL K level that provided by BASF and the product of LUVISKOL VA level.
Silicon hydrogen alkane graft copolymer
Be used for silicone grafted copolymer of the present invention and comprise that those have those copolymers that grafting weight average molecular weight on vinyl polymerization main chain (A and B monomer) and this main chain is about 1,000 to about 50000 polydimethylsiloxanemacromer macromer (C macromonomer).Preferred these copolymers comprise about 50.0 to about 99.9% A and the monomeric combination of B, about 0.1 to about 50.0% C macromonomer, and wherein, A is the vinyl monomer of lipotropy, low polarity free redical polymerization, as methacrylic acid or acrylate; B is anion or nonionic hydrophilic polar monomer, its can with the A combined polymerization, as acrylic acid, N,N-DMAA, dimethylaminoethyl methacrylate or vinyl pyrrolidone; C is the macromonomer that contains siloxanes, and its weight average molecular weight is about 1,000 to about 50,000, is benchmark with the polydimethylsiloxane.Preferred polysiloxane grafted copolymer be Tg value greater than-20 ℃ of pacts, molecular weight is those copolymers of about 10,000 to about 1,000,000.
Be applicable to that silicone grafted copolymer of the present invention comprises following those that list: wherein, the ratio of numeric representation monomer and macromonomer in copolymer, siloxane macromer S1 is a molecular weight about 20,000 polydimethylsiloxane, siloxane macromer S2 is the polydimethylsiloxane of molecular weight about 10,000.
1) 20/63/17 acrylic acid/metering system tert-butyl acrylate/siloxane macromer S2, the molecular weight of copolymer about 100,000
2) 10/70/20 DMAA/isobutyl methacrylate/siloxane macromer S2, the molecular weight of copolymer about 400,000
3) 40/40/20 acrylic acid/methyl methacrylate/siloxane macromer S1, the molecular weight of copolymer is about 400,000
4) 10/70/20 acrylic acid/metering system tert-butyl acrylate/siloxane macromer S1, the molecular weight of copolymer about 300,000
5) 25/65/10 acrylic acid/isopropyl methacrylate/siloxane macromer S2, the molecular weight of copolymer about 200,000
6) 60/25/15 N, N '-DMAA/methacrylic acid methoxy base ethyl ester/siloxane macromer 51, the molecular weight of copolymer about 200,000
7) 12/64/4/20 N, N '-DMAA/isobutyl methacrylate/methacrylic acid 2-Octyl Nitrite/siloxane macromer S1, the molecular weight of copolymer about 300,000
8) 30/40/10/20 N, N '-DMAA/isobutyl methacrylate/methacrylic acid 2-Octyl Nitrite/siloxane macromer S1, the molecular weight of copolymer about 300,000
9) 80/20 tert-butyl acrylate/siloxane macromer S2, the molecular weight of copolymer about 150,000
Carrier
Hairstyling composition of the present invention can comprise a kind of carrier.The content of carrier and kind can be according to selecting with the compatibility of other component and the characteristic of required product.Be used for Hairstyling composition of the present invention and can include but not limited to hair spray, mist, mousse, gel and cream for any product form.
Be used for carrier of the present invention and comprise water, volatile solvent, propellant and their mixture.
Be used for the water that water of the present invention comprises deionized water and comprises the natural origin of inorganic cation.Preferred deionized water.
Being used for volatile solvent of the present invention comprises lower alkyl alcohol with 1-3 carbon atom, has about 5 hydrocarbon to about 8 carbon atoms.The preferred volatile solvent is ethanol, isopropyl alcohol, pentane, hexane and heptane.
Propellant can be used for mousse and hair jelly product.When adopting propellant among the present invention, can be according to such as residue, the packing of component and whether product design is selected for leaving standstill or be inverted factors such as use.
Be used for propellant of the present invention and comprise fluorohydrocarbon,, be purchased from DuPont as Difluoroethane 152a, dimethyl ether and hydrocarbon, as propane, iso-butane, normal butane, the mixture of hydrocarbon is as LPG (liquefied petroleum gas), carbon dioxide, nitric oxide, nitrogen and compressed air.
Emulsifying surfactant
Hairstyling composition of the present invention can comprise a kind of emulsifying surfactant, so that water-fast composition is dispersed in the carrier.Water-fast composition can comprise above-mentioned hydrophobic fixed polymer, hydrophobic thickening polymer, high-melting-point conditioner and following oiliness conditioner.
The content of emulsifying surfactant and kind can be according to selecting with the compatibility of other component and the characteristic of required product.Emulsifying surfactant is selected from non-ionic surface active agent, anion surfactant, cationic surfactant, amphoteric surfactant and their mixture.
Conditioner
Hairstyling composition of the present invention can comprise a kind of conditioner.Be used for conditioner of the present invention and comprise high melting compound, oiliness compound, silicone compounds, nonvolatile solvent and their mixture.
High melting compound
Compositions can comprise that fusing point is about 25 ℃ high melting compound that is selected from aliphatic alcohol, fatty acid, fatty alcohol derivative, derivative of fatty acid, hydrocarbon, steroid and its mixture at least.Without being limited by theory, believe that these high melting compounds cover hair surface and reduce friction, therefore can make hair have slick sensation, combing easily.This a part of disclosed chemical compound that it will be appreciated by those skilled in the art that description can belong to a more than class under certain conditions, and for example some fatty alcohol derivatives also can be classified and made derivative of fatty acid.But a given classification is not to be used for limiting concrete chemical compound, does the just convenience in order to classify and to name like this.And those skilled in the art will appreciate that the fusing point with some chemical compound of required carbon number can be less than about 25 ℃ according to the length and the position of the number of two keys and position, side chain.This low-melting chemical compound is not included in this part.The limiting examples of high melting compound is seen International Cosmetic IngredientDictionary, the 5th edition, and 1993 and CTFA Cosmetic Ingredient Handbook, the 2nd edition, 1992, described document all is incorporated herein by reference.
Can be used for aliphatic alcohol of the present invention and be having about 14 to those of about 30 carbon atoms, preferably have about 16 to about 22 carbon atoms.These aliphatic alcohol can be straight or branched alcohol, also can be saturated or unsaturated alcohols, and its limiting examples comprises spermol, stearyl alcohol, pure and mild its mixture of docosane.
Can be used for fatty acid of the present invention and have about 10, preferably have about 12, more preferably have about 16 to about 22 carbon atoms to about 22 carbon atoms to about 30 carbon atoms.These fatty acids can be straight or branched acid, also can be saturated or unsaturated acids.Also comprise diacid, three acid and other polyprotic acid that meet the demands.The salt that also comprises these fatty acids.These nonlimiting examples of fatty acids comprise lauric acid, Palmic acid, stearic acid, behenic acid, decanedioic acid and its mixture.
But can be used for fatty acid and its mixture that alkyl ether that fatty alcohol derivative of the present invention and derivative of fatty acid comprise aliphatic alcohol, alkoxy fatty alcohols, the alkyl ether of alkoxy fatty alcohols, the ester of aliphatic alcohol, the fatty acid ester with hydroxyl of esterification, hydroxyl replace.The limiting examples of fatty alcohol derivative and derivative of fatty acid comprises as the methyl stearyl ether, ceteth series compound such as ceteth-1 is to ceteth-45, they are glycol ethers of spermol, the number of numeral ethylene glycol wherein; Octadecyl polyoxyethylene ether series compound such as octadecyl polyoxyethylene ether-1 are to octadecyl polyoxyethylene ether-10, and they are glycol ethers of stearyl alcohol (steareth alchohol), the number of numeral ethylene glycol wherein; 16/octadecyl polyoxyethylene ether-1 is to 16/octadecyl polyoxyethylene ether-10, they are glycol ethers of 16/stearyl alcohol (ceteareth alcohol), promptly mainly be the mixture of the aliphatic alcohol of spermol and stearyl alcohol, the wherein number of numeral ethylene glycol; The C of above-mentioned ceteth, octadecyl polyoxyethylene ether and 16/octadecyl polyoxyethylene ether
1-C
30Alkyl ether; The polyoxyethylene ether of tadenan, ethyl stearte, the stearic acid cetyl, cetin, the stearic acid stearyl, myristyl myristate, polyoxyethylene cetyl base ether stearate, polyoxyethylene stearyl base ether stearate, the polyoxyethylene lauryl ether stearate, Tego-stearate, polyoxyethylene monostearate, the polyoxyethylene distearate, propylene glycolmonostearate, the distearyl acid propylene glycol ester, the trimethylolpropane distearate, the stearic acid Isosorbide Dinitrate, the stearic acid polyglycerin ester, glyceryl monostearate, distearin, glyceryl tristearate and its mixture.
Can be used for hydrocarbon of the present invention and comprise the chemical compound that has at least about 20 carbon atoms.
Can be used for steroid of the present invention comprises as cholesteric chemical compound.
The high melting compound of preferred highly purified unification compound.Highly be preferably selected from the single pure fat alcoholic compound of pure spermol, stearyl alcohol and tadenan.Here " pure " to be meant that the purity of chemical compound is at least about 90%, preferably at least about 95%.These highly purified unification compounds provide the good hair rinsing when consumer's rinse composition the time.
Can be used for commercially available high melting compound of the present invention comprises: can available from New JapanChemical (Osaka, spermol, stearyl alcohol and the docosane of the KONOL series by name of commodity Japan) is pure and mild can be available from the NAA series of NOF (Tokyo Japan); Can be available from WAKO (Osaka, the pure tadenan of the 1-DOCOSANOL by name of commodity Japan); Can available from Akzo (ChicagoIllinois, the different fatty acid of the NEO-FAT by name of commodity USA) can be available from Witco Corp. (Dublin Ohio, HYSTRENE USA) and can be available from Vevy (Genova, DERMA Italy); With the cholesterol that can be called NIKKOLAGUASOME LA available from the commodity of Nikko.
Oiliness compound
Compositions of the present invention comprises the oiliness compound that fusing point is no more than 25 ℃, and it is selected from first kind of oiliness compound, second kind of oiliness compound and its mixture.Be used for oiliness compound of the present invention and can be volatility or fixedness chemical compound.Although the restriction that is subjected to any theory is arranged, it is believed that the penetrable hair of oiliness compound improves the hydroxyl bond of head, thereby make hair submissive.Oiliness compound can comprise first kind of oiliness compound or second kind of oiliness compound as described below.The preferred mixture that adopts first kind of oiliness compound and second kind of oiliness compound.The oiliness compound of this section is different from aforesaid high melting compound.The non-limiting example of oiliness compound is stated in following document: InternationalCosmetic Ingredient Dictionary, the 5th edition, 1993, with CTFA Cosmetic IngredientHandbook, the 2nd edition, 1992, these two parts of documents are incorporated herein by reference.
First kind of oiliness compound
Be used for aliphatic alcohol of the present invention and comprise that those have about 10 to about 30 carbon atoms, preferred about 12 to about 22 carbon atoms, more preferably from about 16 aliphatic alcohol to about 22 carbon atoms.These aliphatic alcohol can be side chain or straight chain alcohol, and can be saturated or unsaturated alcohol, preferred unsaturated alcohol.The non-limiting example of these chemical compounds comprises oleyl alcohol, palmityl alcohol, different hard alcohol, different spermol, tip-nip, octyldodecanol, octyl group decanol, capryl alcohol (octyl alcohol), capryl alcohol (caprylic alcohol), decanol and lauryl alcohol.
Be used for fatty acid of the present invention and comprise that those have about 10 to about 30 carbon atoms, preferred about 12 to about 22 carbon atoms, more preferably from about 16 fatty acids to about 22 carbon atoms.These fatty acids can be side chain or straight-chain acid, and can be saturated or unsaturated acids.The example of suitable fatty acid comprises: oleic acid, linoleic acid, isostearic acid, linolenic acid, ethyl linolenic acid, ethyl linolenic acid, arachidonic acid and castor oil acid.
The derivative of fatty acid that defines among the present invention and the example of fatty alcohol derivative comprise: the alkyl ether of the ester of aliphatic alcohol, alkoxy fatty alcohols, aliphatic alcohol, the alkyl ether of alkoxy fatty alcohols and its mixture.The indefiniteness of derivative of fatty acid and fatty alcohol derivative comprises: methyl linoleate, Ethyl linoleate, the linoleic acid isopropyl ester, oleate isodecyl ester, acid isopropyl, ethyl oleate, oleic acid octyl group dodecyl ester, oleic acid oil base ester, decyl oleate, butyl oleate, methyl oleate, stearic acid octyl group dodecyl ester, isostearic acid octyl group dodecyl ester, different Palmic acid octyl group dodecyl ester, different octyl pelargonate, octyl pelargonate, the own ester of isostearic acid, the isostearic acid isopropyl ester, different isodecyl pelargonate, Oleth-2, tetramethylolmethane four oleates, pentaerythritol tetraoctyl stearate, trihydroxy methyl propyl ester trioleate and trimethylolpropane tris isostearate.
Being used for the commercially available first kind of oiliness compound of the present invention comprises: oleyl alcohol, trade name UNJECOL90BHR, be purchased Chemical from New Japan, pentaerythritol tetraoctyl stearate and trimethylolpropane tris isostearate, trade name KAKPTI and KAKTTI, be purchased from Kokyu Alcohol (Chiba, Japan), tetramethylolmethane four oleates, has identical trade name with chemical compound, be purchased Chemical, trimethylolpropane tris oleate, trade name ENUJERUBU TP3S0 from NewJapan, be purchased Chemical from New Japan, various liquid ester, trade name SCHERCEMOL series is purchased from Scher, with the own ester of isostearic acid, trade name HIS and isostearic acid isopropyl ester, trade name ZPIS is purchased the Alcohol from Kokyu.
Second kind of oiliness compound
Be used for second kind of hydrocarbon that oiliness compound is straight chain, ring-type and side chain of the present invention, it can be saturated hydrocarbons or unsaturated hydrocarbons, as long as its fusing point is no more than about 25 ℃.These hydrocarbon have about 12 to about 40 carbon atoms, and preferred about 12 to about 30 carbon atoms, more preferably have about 12 to about 22 carbon atoms.The present invention also comprises the polymeric hydrocarbon of alkenyl monomer, as C
2-6The polymer of alkenyl monomer.These polymer can be the straight or branched polymer.Straight chain polymer has relatively short chain length usually, and total carbon atom number as previously mentioned.Branch polymer has obviously longer chain length.The number-average molecular weight of this material can non-constant width, but usually up to about 500, is preferably about 200 to about 400, and more preferably from about 300 to about 350.The present invention can also adopt various other mineral oil of level.Mineral oil is the mixture from the multiple hydrocarbon of oil acquisition.The instantiation of suitable hydrocarbon materials comprises: paraffin oil, mineral oil, dodecane, Fancol ID, hexadecane, 2-Methylpentadecane, eicosylene, different eicosylene, tridecane, the tetradecane, polybutene, polyisobutylene and its mixture.The preferred hydrocarbon that adopts is selected from mineral oil, Fancol ID, 2-Methylpentadecane, polybutene, polyisobutylene and its mixture.
Being used for commercially available second kind of oiliness compound of the present invention comprises: Fancol ID, 2-Methylpentadecane and different eicosylene, trade name PERMETHYL 99A, PERMETHYL 101A and PERMETHYL 1082, be purchased (South Plainfield New Jersey from Presperse, USA), the copolymer of isobutene. and n-butene, trade name INDOPOL H-100 is purchased (the Chicago Illinois from Amoco Chemicals, USA), mineral oil, trade name BENOL is purchased from Wltco, isoparaffin, trade name ISOPAR, be purchased from Exxon Chemical Co. (Houston Texas, USA), alpha-olefin low polymers, trade name PURESYN 6, are purchased the Co. from Mobil Chemical, and trimethylolpropane tris decanoin/three decanoins, trade name MOBIL ESTER P43 is purchased the ChemicalCo from Mobil.
Silicone compounds
The conditioner that is used for the present invention comprises silicone compounds.Silicone compounds of the present invention comprises volatile solubility or insoluble silicone conditioning agent, or the solubility of fixedness or insoluble silicone conditioning agent.So-called solubility is meant that the carrier of siloxanes and compositions is miscible, thereby forms a mutually in-phase part.So-called insoluble siloxanes and the carrier of being meant forms the discontinuous phase that separates, as the emulsion or the suspension drop form of siloxanes.
Suitable siloxanes fluids comprises poly-alkylsiloxane, poly-aryl siloxanes, poly-alkaryl siloxanes, polyether siloxane copolymer and its mixture.Also can adopt other to have the fixedness silicone compounds of hair conditioning performance.
Be used for silicone compounds of the present invention and also comprise poly-alkyl or poly-aryl siloxanes with following structural formula (I):
Wherein, R is an alkyl or aryl, and x is the integer of about 7-about 8,000." A " represents the group of the disconnected siloxane chain end of embedding.Alkyl or aryl last or that replace in the end of siloxane chain (A) can have any structure at siloxane chain (R), as long as the siloxanes that forms at room temperature is a fluid, when it is applied on the hair, can disperse, non-stimulated, nontoxic, harmless, and it is compatible with other composition of compositions, chemically stable under routine use and holding conditions, and can be deposited on the hair and conditioning hair.Suitable A group comprises hydroxyl, methyl, methoxyl group, ethyoxyl, propoxyl group and aryloxy group.Two R groups on silicon atom can be represented identical group or different groups.Preferred two R groups are represented identical group.Suitable R group comprises methyl, ethyl, propyl group, phenyl, tolyl and benzyl.Preferred silicone compounds is polydimethylsiloxane, poly-di-ethyl siloxane and PSI.Especially preferably be referred to as the polydimethylsiloxane of polydimethylsiloxane (dimethicone).Adoptable poly-alkylsiloxane for example comprises polydimethylsiloxane.These siloxanes are commercially available from General Electric Company, are ViscasilR series and SF96 series, and are purchased from DowComing, are Dow Coming 200 series.
Poly-alkaryl siloxanes fluids also can adopt, and for example, comprises PSI.These siloxanes are for example commercially available from General Electric Company, and be SF 1075 series, and be purchased Corning from Dow, be 556 cosmetics-stage fluids.
In order to strengthen the gloss characteristic of hair, the also preferred especially siloxanes that adopts high arylation of the present invention, as the poly-ethylsiloxane of high phenylating, its refraction index is about 1.46 or greater than 1.46, particularly about 1.52 or bigger.When using these high index of refraction siloxanes, they should mix with a kind of spreader as described below, as a kind of surfactant or a kind of silicone resin, to reduce the film property of surface tension and reinforcing material.
Adoptable silicone compounds comprises the polydimethylsiloxane of poly(propylene oxide) modification, though also can adopt the mixture of oxirane or oxirane and expoxy propane.The content of oxirane and expoxy propane should be enough low so that it can not disturb the dispersive property of siloxanes.These materials also are referred to as the dimethicone copolyol.
Other silicone compounds comprises the amino material that replaces.Be suitable for those siloxanes that the amino siloxanes that replaces of the present invention comprises (II) structure that has following formula:
Wherein, R is CH
3Or OH, x and y are integer independently, and depend on that required molecular weight, mean molecule quantity are 5,000 to 10,000.This polymer also is referred to as " amination polydimethylsiloxane (amodimechicone) ".
The siloxanes fluids that suitable amino replaces comprises the have following formula siloxanes of (III):
(R
1)
aG
3-a-Si-(-OSiG
2)
n-(-OSiG
b(R
1)
2-b)
m-O-SiG
3-a(R
1)
a?????(III)
Wherein G is selected from hydrogen, phenyl, hydroxyl, C
1-C
8Alkyl, preferable methyl; A is 0 or the integer of 1-3, preferred 0; B is 0 or 1, preferred 1; The summation of n+m is 1-2,000, and preferred 50-150, n can represent 0-1,999 number, preferred 49-149, m can represent 1-2,000 integer, preferred 1-10; R
1Be univalent perssad, satisfy formula C
qH
2qL, wherein, q is the integer of 2-8, L can be selected from following radicals:
-N(R
2)CH
2-CH
2-N(R
2)
2
-N(R
2)
2
-N(R
2)
3A
-
-N(R
2)CH
2-CH
2-NR
2H
2A
-
Wherein, R
2Be selected from hydrogen, phenyl, benzyl, saturated hydrocarbyl, preferably have the alkyl of 1-20 carbon atom, A
-Be the halogen ion.
The siloxanes that the amino of particularly preferred formula (III) replaces is the polymer of formula (IV), and it also is referred to as " poly-trimethyl silyl amination dimethyl siloxane ",
Wherein, n and m select according to the definite molecular weight of required compound.
Other adoptable amino siloxanes that replaces is represented by following formula V:
Wherein, R
3For having the monovalence alkyl of 1-18 carbon atom, preferred alkyl or alkenyl are as methyl; R
4Be alkyl, preferred C
1-C
18Alkylidene or C
1-C
18, preferred C
1-C
8Alkylene oxide group; Q
-Be the halogen ion, preferred chlorine; The meansigma methods of r is 2-20, preferred 2-8; The meansigma methods of s is 20-200, preferred 20-50.This type of preferred polymer is commercially available from Union Carbide, trade name " UCAR SILICONE ALE56 ".
The document that discloses the suitable dispersive silicone compounds of fixedness comprises: U.S. patent 2,826,551 (Geen), U.S. patent 3,964,500 (1976.6.22 is issued to Drakoff), US4,364,837 (Pader); And GB 849,433 (woolston).All these documents all are incorporated herein by reference.Another piece list of references is " Silicon Compound ", Petrarch System, and Inc. (1984) also is suitable very widely silicone compounds though the document provides a kind of non-exclusionism.
The dispersive siloxanes of fixedness of another kind of particularly suitable is a siloxane glue.Term " siloxane glue " is meant that these glue are the polysiloxane material herein, and its viscosity under 25 ℃ is more than or equal to 1,000,000 centistoke.Be appreciated that siloxane glue as herein described also may exist some overlapping with above-mentioned silicone compounds.This overlapping be not restriction to these materials.Petrarch has described this siloxane glue, and other document comprises: US 4,152,416 (Spitzer etc., on March 1st, 1979 authorized); Noll, Walter, siloxanes chemistry and technology (Chemistry and Technology of Silicones), New York:Academic Press 1968.Also the siloxane glue that can mention is General Eletric Silicone RubberProduct Data Sheets SE30, SE33, SE54 and SE76.These citing documents all are incorporated herein for referencial use.The weight average molecular weight of siloxane glue greater than about 200,000, generally is about 200,000-1,000,000 usually.Instantiation is polydimethylsiloxane, (polydimethylsiloxane) (ethylene methacrylic radical siloxane) copolymer, poly-(dimethyl siloxane) (diphenyl siloxane) (ethylene methacrylic radical siloxane) copolymer and its mixture.
Also can adopt a kind of silicone resin, it is highly cross-linked polymer siloxane system.In the silicone resin production process, have simple function group or two functional groups or both trifunctionals and silicane of four functional groups by introducing and introduce crosslinked.Just as known in the art, can change according to the specific silane unit that mixes in the silicone resin for forming the required degree of cross linking of silicone resin.Usually, can consider to adopt and have abundant trifunctional and four functional silicone monomeric units (thereby crosslinked fully) so that their dryings can become the silicone material of rigidity or hard film as silicone resin.The ratio of oxygen atom and silicon atom shows the crosslinked level in concrete silicone material.It will be silicone resin of the present invention usually that the ratio of oxygen atom and silicon atom is at least about 1.1 silicone material.The preferred oxygen atom was at least about 1.2: 1.0 with the ratio of silicon atom.The silane that is used to produce silicone resin comprises monomethyl, dimethyl, trimethyl, a phenyl, diphenyl, aminomethyl phenyl, a vinyl and methyl ethylene chlorosilane, and tetrachloro silicane, and the most normal employing is methyl substituted silane.Preferred resin is provided with GE SS4230 and SS4267 by General Electric.Being used for silicone resin of the present invention should provide and mix the present composition with dissolved form, and this is well known to a person skilled in the art.Although be not subjected to the restriction of any theory, it is believed that silicone resin can increase other siloxanes on hair deposition and can strengthen the gloss of hair because of its high refractive index.
Other useful silicone resin is the silicone resin powder, and as by CTFA nomenclature called after polymethyl siloxane (polysilsequioxane), it can be from Toshiba Silicones with Tospearl
TMBe purchased.
The method of producing this class silicone compounds can be referring to following document: " polymer science and engineering encyclopedia (Enclcolpedia of Polymer Science and Engineering) ", the 15th volume, second edition, 204-308 page or leaf, John wiley ﹠amp; Sons.Inc., 1989 ", the document is incorporated herein by reference.
Silicone compositions particularly silicone resin can be easily according to well known to a person skilled in the art i.e. " MDTQ " nomenclature identification of shorthand nomenclature system.In this system, siloxanes is that the various monomeric units according to the existence of forming siloxanes are described.In brief, symbol M is represented simple function unit (CH
3)
3SiO
0.5D represents two functional unit (CH
3)
2SiO; T represents trifunctional units (CH
3) SiO
1.5Q represents four functional unit SiO
2Unit symbol apostrophe such as M ', D ', T ', the substituent group of Q ' representative except that methyl, all need concrete definition at every turn.Typical replaceable substituent group is vinyl, phenyl, amino, hydroxyl etc.In the MDTQ system, perhaps the subscript with symbol indicates the unitary total number of every class (or meansigma methods) in the siloxanes, perhaps specifically indicates ratio and molecular weight is described, various unitary mol ratios all can be finished the description to silicone material.In silicone resin, T, Q, T ' and/or Q ' compare with D, D ', M and/or M ' has relative high mole, then shows the crosslinking degree height.But as preceding discussion, crosslinked aggregate level also can be represented by the ratio of oxygen and silicon.
The preferred MQ of silicone resin of the present invention, MT, MTQ, MDT and MDTQ resin.Thereby preferred siloxanes substituent group is a methyl.Preferred especially MQ resin, wherein M: Q ratio is about 0.5: 1.0-1.5: 1.0, and the mean molecule quantity of resin is about 1000 to about 10,000.
Non-volatile solvents:
The used non-volatile solvents of the present invention comprises alkylol and the polyhydric alcohol greater than 3 carbon atoms.Polyhydric alcohol comprises 1,2-propane diol or propylene glycol, 1, ammediol, hexanediol, glycerol diethylene glycol, dipropylene glycol, 1,2-butanediol and 1,4-butanediol.
Thickening polymer
Compositions can comprise a kind of thickening polymer.Thickening polymer is preferred for the hair gel.When thickening polymer existed, it played the viscosity auxiliary agent, and is different with the said fixing polymer.Thickening agent accounts for the 0.1-10% of compositions usually, and preferred about 0.2% to about 3% weight.
The useful thickening polymer of the present invention comprises crosslinked CVP Carbopol ETD2050.Preferably acrylic acid and polyene propyl group glucose crosslinked copolymers in these polymer are stated in US 2798053, and this paper is incorporated herein by reference.The example of these polymer comprises carbomers, and it is the allyl ether of acrylic acid and tetramethylolmethane, the allyl ether of sucrose or the crosslinked homopolymer of allyl ether of propylene.Other preferred thickening polymer comprises the crosslinked copolymers of methyl vinyl ether and maleic acid.The example of these polymer comprises Stabilezes.The molecular weight of preferred CVP Carbopol ETD2050 is at least about 750000; Be more preferably molecular weight at least about 1250000 CVP Carbopol ETD2050; Most preferably molecular weight is at least 3000000 CVP Carbopol ETD2050.
Other is used for thickening polymer of the present invention and comprises that those can bring those of gluey viscosity to compositions, as polymer shape cellulose ether water-soluble or that colloid is water-soluble, as the cellulose of hydroxyethyl-cellulose and hydrophobically modified with as those materials of guar gum, xanthan gum, polyvinyl alcohol, polyvinylpyrrolidone, hydroxypropyl guar gum, starch and starch derivatives.
Additive component
In compositions of the present invention, can prepare various other additive components.These compositions comprise: other conditioner, and as hydrolytic collagen, commodity are called Peptein 2000, and are commercially available from Hormel; Vitamin E, commodity are called Emix-d, and are commercially available from Eisai; Pantothenylol, commercially available from Roche; General thiazolinyl (panthenyl) ethylether, commercially available from Roche; Hydrolysis of keratin, protein, plant extract and nutrient substance; Antiseptic such as benzyl alcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate and imidazolidinyl urea; The pH regulator agent is as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; Salt is usually as potassium acetate and sodium chloride; Coloring agent is as any FD﹠amp; C or D﹠amp; The C dyestuff; Hair oxidation (bleaching) agent is as hydrogen peroxide, perborate and persulfate; Hair Reducing agent such as thioglycolate salt; Spice; And chelating agen, as disodiumedetate.With composition weight meter, the content of these selectivity compositions about 0.001-10.0% that respectively does for oneself usually, preferably about 0.01-5.0%.
Embodiment
Following embodiment further describes and illustrates the embodiment in the scope of the invention.These embodiment only are used for illustration purpose, are not limitation of the scope of the invention, can carry out multiple change to it under the prerequisite that does not deviate from the spirit and scope of the invention.Each composition provides by chemical name or CTFA name confirmation or according to following definitions.
Compositions
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | |
| Fluorescent whitening agent 1 *1 | 0.20 | ?0.10 | ??0.10 | ?0.10 | ||||
| Fluorescent whitening agent 2 *2 | - | ??0.25 | ?- | ?- | ?- | ?- | ??0.10 | ?- |
| Fluorescent whitening agent 3 *3 | - | ??- | ?0.50 | ?- | ?- | ?- | ??- | ?- |
| Fluorescent whitening agent 4 *4 | - | ??- | ?- | ?0.20 | ?- | ?- | ??- | ?0.25 |
| Fluorescent whitening agent 5 *5 | - | ??- | ?- | ?- | ?- | ?1.00 | ??0.10 | ?- |
| ????Ultrahold?8 *6 | 6.00 | ??- | ?- | ?- | ?0.50 | ?- | ??0.50 | ?- |
| ????Luviskol?VA64 *7 | - | ??3.00 | ?- | ?- | ?- | ?- | ??- | ?- |
| ????Amphomer?LV71 *8 | - | ??- | ?2.00 | ?- | ?- | ?- | ??1.50 | ?0.50 |
| ????Yukaformer?R205 *9 | - | ??- | ?- | ?2.00 | ?1.50 | ?- | ??- | ?1.00 |
| Polysiloxane grafted copolymer 1 *10 | - | ??- | ?- | ?- | ?- | ?1.50 | ??- | ?- |
| The amino methyl propanol | 0.15 | ??- | ?0.30 | ?- | ?0.04 | ?- | ??- | ?- |
| Lauramide DEA | 0.10 | ??- | ?- | ?0.10 | ?- | ?0.05 | ??- | ?0.10 |
| Triisopropylamine | - | ??- | ?- | ?0.10 | ?- | ?- | ??0.05 | ?- |
| ??Dimethicone?Copolyol ??????SH3746 *11 | 0.10 | ??- | ?0.05 | ?- | ?- | ?- | ??- | ?0.05 |
| Spice | 0.20 | ??0.20 | ?0.10 | ?0.10 | ?0.20 | ?0.20 | ??0.10 | ?0.10 |
| Deionized water | 20.0 | ??45.5 | ?20.0 | ?45.0 | ?21.0 | ?46.0 | ??20.0 | ?20.0 |
| Iso-butane/propane blend | - | ??25.0 | ?25.0 | ?- | ?15.0 | ?15.0 | ??- | ?20.0 |
| Dimethyl ether | - | ??- | ?- | ?35.0 | ?- | ?- | ??35.0 | ?- |
| Hydrolytic collagen *25 | 0.01 | ??- | ?- | ?- | ?- | ?- | ??- | ?- |
| Vitamin E *26 | 0.01 | ??- | ?- | ?- | ?- | ?- | ??- | ?- |
| Pantothenylol *27 | 0.025 | ??- | ?- | ?- | ?- | ?- | ??- | ?- |
| General thiazolinyl ethylether *28 | 0.025 | ??- | ?- | ?- | ?- | ?- | ??- | ?- |
| Ethanol | To 100% | |||||||
| Embodiment 9 | Embodiment 10 | Embodiment 11 | Embodiment 12 | Embodiment 13 | Embodiment 14 | Embodiment 15 | Embodiment 16 | |
| Fluorescent whitening agent 1 *1 | ??0.20 | ??0.10 | ??0.05 | |||||
| Fluorescent whitening agent 2 *2 | ?0.25 | ??0.20 | ||||||
| Fluorescent whitening agent 3 *3 | ?0.50 | ??0.10 | ||||||
| Fluorescent whitening agent 4 *4 | ??0.20 | ??0.05 | ||||||
| Fluorescent whitening agent 5 *5 | ??1.00 | ??0.10 | ??0.05 | |||||
| Ultrahold?Strong *12 | ??1.00 | ??1.00 | ||||||
| Luviskol?VA73W *13 | ?1.00 | |||||||
| Amphomer?28-4910 *14 | ?4.00 | ??3.00 | ??2.50 | ??1.00 | ||||
| Yukaformer?510 *15 | ??2.00 | ?2.00 | ??3.00 | ??1.50 | ??3.00 | |||
| Polysiloxane grafted copolymer 2 *16 | ??1.00 | |||||||
| The amino methyl propanol | ??0.15 | ?0.70 | ??0.50 | ??0.45 | ||||
| Laureth-23 | ??0.25 | ?0.20 | ??0.10 | ??0.15 | ??0.10 | |||
| Laureth-7 | ?0.20 | ?0.10 | ??0.10 | ??0.20 | ||||
| Dimethicone?Copolyol SH3746 *11 | ??0.10 | ??0.05 | ||||||
| DC?BY22-009 *17 | ??0.20 | ??0.20 | ??0.15 | |||||
| Propylene glycol | ??0.10 | ?0.25 | ?0.10 | ??0.25 | ??0.10 | ??0.20 | ||
| Methyl parahydroxybenzoate | ??0.15 | ?0.15 | ?0.10 | ??0.10 | ??0.15 | ??0.15 | ??0.10 | ??0.15 |
| Spice | ??0.20 | ?0.20 | ?0.10 | ??0.10 | ??0.20 | ??0.20 | ??0.10 | ??0.10 |
| Ethanol | ?12.5 | ?7.50 | ??10.0 | ??6.00 | ??15.0 | |||
| Iso-butane/propane blend | ??6.00 | ?8.00 | ?7.00 | ??10.0 | ??8.00 | ??8.00 | ??7.00 | |
| Deionized water | To 100% | |||||||
| Embodiment 17 | Embodiment 18 | Embodiment 19 | Embodiment 20 | Embodiment 21 | Embodiment 22 | Embodiment 23 | Embodiment 24 | |
| Fluorescent whitening agent 1 *1 | ??0.20 | ??0.20 | ??0.15 | |||||
| Fluorescent whitening agent 2 *2 | ??0.25 | ??0.10 | ||||||
| Fluorescent whitening agent 3 *3 | ??0.50 | ??0.10 | ||||||
| Fluorescent whitening agent 4 *4 | ??0.20 | ??0.25 | ||||||
| Fluorescent whitening agent 5 *5 | ??1.00 | ??0.10 | ||||||
| Gantrez?ES-255 *18 | ??1.00 | ??1.00 | ||||||
| Luviskol?K *19 | ??2.00 | ??3.00 | ||||||
| Amphomer?28-4910 *14 | ??4.00 | ??2.50 | ??4.00 | |||||
| Yukaformer?SM *20 | ??2.00 | ??1.00 | ??3.00 | ??1.25 | ??1.50 | |||
| Polysiloxane grafted copolymer 2 *16 | ??1.25 | |||||||
| The amino methyl propanol | ??0.15 | ??0.70 | ??0.85 | |||||
| Carbopol?940 *21 | ??1.00 | ??0.50 | ??0.50 | |||||
| Stabileze?06 *22 | ??0.25 | ??0.50 | ||||||
| Cellosize?HEC?QP *23 | ??1.50 | |||||||
| Poly?Surf?67 *24 | ??1.25 | ??1.00 | ||||||
| NaOH | ??0.28 | ??0.04 | ??0.14 | ??0.08 | ??0.14 | |||
| Laureth-23 | ??0.25 | ??0.20 | ??0.25 | ??0.15 | ??0.10 | |||
| Oleth-20 | ??0.20 | ??0.15 | ??0.25 | |||||
| Dimethicone?Copoly SH3746 *11 | ??0.10 | ??0.05 | ??0.05 | |||||
| Methyl parahydroxybenzoate | ??0.15 | ??0.15 | ??0.10 | ??0.10 | ??0.15 | ??0.15 | ??0.10 | ??0.15 |
| EDTA four sodium | ??0.10 | ??0.05 | ??0.10 | ??0.10 | ??0.10 | ??0.10 | ??0.10 | |
| Spice | ??0.10 | ??0.15 | ??0.10 | ??0.10 | ??0.20 | ??0.20 | ??0.10 | ??0.10 |
| Ethanol | ??6.00 | ??2.00 | ??4.00 | ??1.50 | ||||
| Deionized water | To 100% | |||||||
Definition
*1 fluorescent whitening agent 1: disodium-1, two (the 2-sulfo group styryl) biphenyl of 4-, trade name TinopalCBS-X is from Ciba Specialty Chemicals
*2 fluorescent whitening agents 2: disodium-4,4 '-two { [two (2-hydroxyethyl) amino-1,3,5-triazines of phenylamino-6--2-yl] amino } stilbene-2,2 '-disulfonate, trade name Tinopal UNPA-GX is from CibaSpecialty Chemicals
*3 fluorescent whitening agent 3:2-(4-styryl-3-sulfo group propyl group)-2H-benzo [1,2-d] triazole, trade name Tinopal RBS is from Ciba Specialty Chemicals
*4 fluorescent whitening agent 4:1-[4-(2 sulfo group ethylsulfonyl) propyl group]-3-(4-chloropropyl)-2-pyrazoline
*5 fluorescent whitening agent 5:1-[4-(2 sulfo group ethylsulfonyl) propyl group]-3-(3,4-two chloro-6-methyl oxygen phenyl)-2-pyrazoline
*6 Ultrahold 8: the copolymer of acrylic acid/ethyl acrylate/N tert butyl acrylamide derives from BASF
*7 Luviskol VA64: the copolymer of vinyl pyrrolidone and vinylacetate derives from BASF
*8 Amphomer LV71: octyl acrylamide/alkyl acrylate/metering system acid butyl amino ethyl ester derives from National Starch and Chemical Company
*9 Yukaformer R205: the copolymer of methoxy propyl enoyl-ethyl betanin and alkyl acrylate derives from Mitsubishi Chemical Corporation
*10 silicone grafted copolymer 1:20/63/17 acrylic acid/metering system tert-butyl acrylate/siloxane macromonomers S2, polymer molecular weight about 100000
*11 Dimethicone Copolyol SH3746: the polydimethylsiloxane that has the polyoxyethylene side chain
*12 Ultrahold Strong: the copolymer of acrylic acid/ethyl acrylate/N tert butyl acrylamide derives from BASF
*13 Luviskol VA73W: the copolymer of vinyl pyrrolidone/vinylacetate derives from BASF
*14 Amphomer 28-4910: the copolymer of octyl acrylamide/alkyl acrylate/metering system acid butyl amino ethyl ester derives from National Starch and Chemical Company
*15 Yukaformer 510: the copolymer of methoxy propyl enoyl-ethyl betanin and alkyl acrylate derives from Mitsubishi Chemical Corporation
*16 silicone grafted copolymer 2:60/25/15 N, N '-DMAA/methoxy ethyl methacrylate/siloxane macromonomers S1, polymer molecular weight about 200000
*17 DC BY22-009: siloxane microemulsion derives from Dow Corning.
*18 Gantrez ES-225: the copolymer of vinyl methyl ether and ethyl maleate, available from ISP
*19 Luviskol K30: polyvinyl pyrrolidone derives from BASF
*20 Yukaformer SM: the copolymer of methoxy propyl enoyl-ethyl betanin and alkyl acrylate derives from Mitsubishi Chemical Corporation
*21 Carbopol 940: crosslinked polyacrylic acid derives from B.F.Goodrich
*22 Stabileze 06: the crosslinked copolymers of methyl vinyl ether and maleic acid, available from ISP
*23 Cellosize HEC QP: hydroxyethyl-cellulose
*24 Poly Surf 67: hydrophobically modified hydroxyethyl cellulose derives from Aqualon Co.
*25 hydrolytic collagens: Peptein 2000 derives from Hormel
*26 vitamin Es: Emix-d derives from Eisai
*27 pantothenylol: derive from Roche
*28 general thiazolinyl ethylethers: derive from Roche
Preparation method
The hair spray product of embodiment 1-8 is suitable for following method preparation: hair fixed polymer is dissolved in part water and the ethanol.In case use anion fixed polymer such as Ultrahold 8, in a part of water and ethanol, neutralize with the amino methyl propanol.Add remaining component here, remove iso-butane/propane blend.Mix the mixture obtain, until evenly.At last, the concentrate packaging with gained advances to have in the aerosol container of iso-butane/propane blend.
The hair mousse product of embodiment 9-16 is suitable for following method preparation: hair fixed polymer is dissolved in part water and the ethanol.In case use anion fixed polymer such as Ultrahold Strong, in a part of water, neutralize with the amino methyl propanol.Add remaining component here, remove iso-butane/propane blend.Mix the mixture obtain, until evenly.At last, the concentrate packaging with gained advances to have in the aerosol container of iso-butane/propane blend.
The hair mousse product of embodiment 17-24 (hair setting gelproducts) is suitable for following method preparation: Carbopol 940 is dissolved in the part water.Add NaOH here.In another independent container, with remaining components dissolved in a part of water.Stir these two pre-compositions of blending.
Embodiment 1-24 has many advantages.For example, they can dailyly use, and can change hair color, bring gloss, and the protection hair is avoided uv damage.
Know better, embodiment as herein described and embodiment are that according to the present invention, those of ordinary skills can make various remodeling or variation under the situation that does not break away from purport of the present invention and scope for illustrative purposes.
Claims (9)
1. hair setting composition comprises:
(a) anionic optical brighteners of effective dose,
(b) styling polymer is selected from both sexes styling polymer, anionic shaped polymer, nonionic styling polymer, polysiloxane grafted copolymer and their mixture; Wherein the viscosity that provides of 3% aqueous solution of styling polymer is no more than about 2000 centipoises; With
(c) carrier.
2. according to the hair setting composition of claim 1, wherein anionic optical brighteners is selected from: polystyrene-based stilbene, triazine radical stilbene, coumarin, triazole, pyrazoline and their mixture.
3. the hair setting composition according to claim 1 comprises about 0.001% anionic optical brighteners and about 0.01% styling polymer to about 10% weight to about 20% weight.
4. according to the hair setting composition of claim 3, wherein styling polymer comprises the both sexes styling polymer of about 0.1% to about 5% Radix Betae alkalization; With about 0.1% both sexes styling polymer to the non-Radix Betae alkalization of about 5% weight.
5. according to the hair setting composition of claim 3, wherein styling polymer comprises about 0.1% to about 5% both sexes styling polymer; With about 0.1% anionic shaped polymer to about 5% weight.
6. also comprise a kind of emulsifying surfactant according to each hair setting composition of claim 1-5.
7. also comprise a kind of conditioner according to each hair setting composition of claim 1-5.
8. also comprise a kind of thickening polymer according to each hair setting composition of claim 1-5.
9. according to the hair setting composition of claim 4, wherein compositions comprises and is no more than 30% volatile solvent, and wherein compositions does not have propellant substantially.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97182434 CN1275901A (en) | 1997-09-17 | 1997-09-17 | Hair styling compositions comprising anionic optical brighteners |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97182434 CN1275901A (en) | 1997-09-17 | 1997-09-17 | Hair styling compositions comprising anionic optical brighteners |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1275901A true CN1275901A (en) | 2000-12-06 |
Family
ID=5178485
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 97182434 Pending CN1275901A (en) | 1997-09-17 | 1997-09-17 | Hair styling compositions comprising anionic optical brighteners |
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| CN (1) | CN1275901A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101288634B (en) * | 2008-06-06 | 2010-06-09 | 山东大学 | Noctilucent nutrient hair cream and preparation method thereof |
| CN102964864A (en) * | 2012-11-28 | 2013-03-13 | 华南师范大学 | Multifunctional furanone fluorescent whitening agent and preparation method thereof |
-
1997
- 1997-09-17 CN CN 97182434 patent/CN1275901A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101288634B (en) * | 2008-06-06 | 2010-06-09 | 山东大学 | Noctilucent nutrient hair cream and preparation method thereof |
| CN102964864A (en) * | 2012-11-28 | 2013-03-13 | 华南师范大学 | Multifunctional furanone fluorescent whitening agent and preparation method thereof |
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